KR20200003340A - Manufacturing method of hollow fiber reinforcement using spiral circle fabric - Google Patents

Manufacturing method of hollow fiber reinforcement using spiral circle fabric Download PDF

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Publication number
KR20200003340A
KR20200003340A KR1020180076185A KR20180076185A KR20200003340A KR 20200003340 A KR20200003340 A KR 20200003340A KR 1020180076185 A KR1020180076185 A KR 1020180076185A KR 20180076185 A KR20180076185 A KR 20180076185A KR 20200003340 A KR20200003340 A KR 20200003340A
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hollow fiber
fiber membrane
manufacturing
reinforcement
spiral
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KR1020180076185A
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Korean (ko)
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나혜리
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나혜리
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    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D1/00Woven fabrics designed to make specified articles
    • D03D1/0035Protective fabrics
    • D03D1/0043Protective fabrics for elongated members, i.e. sleeves
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D3/00Woven fabrics characterised by their shape
    • D03D3/02Tubular fabrics
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/08Hollow fibre membranes
    • B01D69/082Hollow fibre membranes characterised by the cross-sectional shape of the fibre
    • D03D15/0094
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/43Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads with differing diameters
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D37/00Circular looms
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2403/00Details of fabric structure established in the fabric forming process
    • D10B2403/03Shape features
    • D10B2403/033Three dimensional fabric, e.g. forming or comprising cavities in or protrusions from the basic planar configuration, or deviations from the cylindrical shape as generally imposed by the fabric forming process

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Woven Fabrics (AREA)

Abstract

The present invention relates to a method for manufacturing a spiral circle fabric which has excellent internal and external pressure and high tensile force by manufacturing a solid reinforcing material woven by a spiral tubular fabric of a hollow fiber membrane, and allows water to flow in a vortex shape by a spiral tissue having excellent roundness, and causes zero fuzz and whiskering. According to the present invention, a reinforcing support body in which wefts (1) and warps (2) are woven by filament yarns or monofilament yarns and special yarns is included. A method for manufacturing a new fabric improves roundness to allow the coating thickness to be constant and thus to provide a new function of a reinforcing material which maintains the pore size of a membrane by changing the angle of a screw thread or changing the thickness and type of a thread (monofilament and special yarns). According to the present invention, a spiral circle fabric reinforcing material produced in a circular loom has excellent internal and external water pressure and high tensile force by using a solid support body which is woven, improves flexibility of a hollow fiber membrane by using mono-filament, and enhances binding force with a coating layer by increasing unevenness of the support body for reinforcement. In addition, a separation filtration layer, which is a coating layer, can be prevented from being detached by reforming the support body for reinforcement on the surface, and pores inside a film can be controlled by treating an internal coagulation solution, thereby obtaining excellent water permeability and increasing stability of pores.

Description

나선관형직물을 이용한 중공사막 보강재 제조방법{Manufacturing method of hollow fiber reinforcement using spiral circle fabric}Manufacturing method of hollow fiber reinforcement using spiral circle fabric}

본 발명은 중공사막의 나선관형직물(spiral circle fabric)로 직조된 견고한 보강재를 제조함으로써 우수한 내외 압력과 높은 인장력을 가지며, 진원도가 뛰어난 나선형의 조직으로 인해 물이 와류형으로 흐르게하고 하고 보풀(fuzz) 및 모우(whiskering)가 제로가 되는 나선관형직물 보강재 제조 방법을 말한다.The present invention has a good internal and external pressure and high tensile force by manufacturing a solid reinforcement woven from a spiral circle fabric of the hollow fiber membrane, and the water flows in a vortex due to the spiral structure with excellent roundness and fluff ) And a method of manufacturing a spiral tubular fabric reinforcement with zero whiskering.

현재까지는 중공사막의 보강재로는 브레이드(brider) 편조된 것을 주로 사용해왔다. 막은 코팅 후 코팅층이 가지는 치수안정성이 생명인데 활성층 코팅막이 고온의 유기 용매와 고압의 의해 치수안정성을 갖기는 매우 어렵다. 게다가 종래의 고분자 섬유 브레이드 강화 중공사막은 고온의 유기 용매성 액체 하에서 활성층막 뿐만 아니라 브레이드 보강재 자체의 치수도 함께 변한다. 이처럼, 치수 안정성이 상실되면, 브레이드와 활성층간의 계면에 상당한 응력이 발생하여 활성층 막에 손상을 초래하는 문제점이 있다. 브레이드로 편조된 보강재는 기계특성상 모우(whiskering), 보풀(fuzz)로 불균일한 코팅에 의한 누수의 발생 등과 같은 막 물성의 저하를 가져온다. 브레이드로 보강재 제품의 길이가 짧아 고분자 코팅시 불량률이 높고 생산성이 떨어진다.Until now, braid braided materials have been mainly used as reinforcing materials for hollow fiber membranes. The film has a dimensional stability of the coating layer after coating, but it is very difficult for the active layer coating film to have dimensional stability due to the high temperature of the organic solvent and high pressure. In addition, conventional polymer fiber braid reinforced hollow fiber membranes change not only the active layer membrane but also the dimensions of the braid reinforcement itself under high temperature organic solvent liquid. As such, if the dimensional stability is lost, there is a problem that a significant stress is generated at the interface between the braid and the active layer causing damage to the active layer film. Braided braided reinforcement causes deterioration of membrane properties such as whiskering and leakage caused by uneven coating due to fuzz. The braid has a short length of reinforcement products, resulting in high defect rate and low productivity when coating polymers.

본 발명은 상기 종래기술의 문제점을 해결하기 위한 것으로, 보강재를 제조할 때 필라멘트 또는 모노(mono)사와 특수사를 가지고 원형직기로 제직된 나산관형직물(spiral circle fabric) 보강재를 사용함으로써 기존대비 진원도가 높아져 코팅의 두께 치수를 일정하게 하고 신율을 최소화하여 막의 기공 크기를 안정시키는데 그 목적이 있다.The present invention is to solve the problems of the prior art, when manufacturing the reinforcement by using a spiral circle fabric (spiral circle fabric) reinforcement woven with a circular loom with filament or mono (mono) and special yarns The purpose is to stabilize the pore size of the membrane by increasing the uniformity of the thickness of the coating and minimizing elongation.

상기한 문제점을 새로운 생각에서 해결하려는 것이 발명을 하게 된 이유이다.The reason for inventing is to solve the above problems with new ideas.

브레이드(brider) 편조 조직은 치수 변형이 많은 조직이나 원형직기(spiral circle loom)으로 제직된 조직은 치수가 안정화되는 최대의 직물 조직이다.Braid braided tissue is tissue with many dimensional deformations or tissues woven with a spiral circle loom, which is the largest textile tissue whose dimensions are stabilized.

중공사막의 보강재는 원형직기로 제직된 나선관형직물(spiral circle fabric)로 위사(1) 및 경사(2)는 필라멘트사 또는 모노사와 특수사로 직조된 보강용 지지체를 포함하는 것을 특징으로 한다.The reinforcing material of the hollow fiber membrane is a spiral circle fabric (spiral circle fabric) woven with a circular loom, characterized in that the weft yarn (1) and the warp yarn (2) comprises a reinforcing supporter woven from filament yarn or mono yarn and special yarn.

위사(1)의 샤틀(a, b) 수를 2개 이상을 함으로써 나사선의 각도를 달리 할 수 있고, 위사(1) 샤틀수(a,b) 2개 이상 실의 굵기와 종류(모노-필라멘트 및 특수사)를 달리함으로써 진원도가 높아져 코팅의 두께가 일정해지니 막의 기공 크기가 유지되어 새로운 보강재의 기능을 부여 할 수 있게 된다.The angle of the thread can be changed by making two or more of the number of the shafts (a, b) of the weft yarn (1), and the thickness and type of the thread (mono-filament) of two or more threads of the weft yarn (1) And the special yarn), the roundness is increased, so that the thickness of the coating becomes constant, thereby maintaining the pore size of the membrane, thereby imparting the function of the new reinforcement.

나선식 조직은 물을 회전(와류)을 시켜 수투율을 높일 수 있으며, 관 내부의 이물질의 부착을 막으며 부착된 이물질을 떨어지게 한다.Spiral tissue can increase the water transmission rate by rotating the water (vortex), and prevents foreign matter from adhering to the inside of the tube and causes the attached foreign matter to fall off.

경사(2)는 실의 굵기와 수량에 따라 수투율을 조절할 수 있고 조직상의 위 경, 방향의 신율이 아주 적어 막의 기공크기가 안정된다.The inclination (2) can control the water permeability according to the thickness and quantity of the yarn, and the pore size of the membrane is stabilized because the elongation of the texture and direction is very small.

원형직기에서 생산된 나선관형직물(spiral circle fabric) 보강재는 종래의 생산방식과는 다르다. 생산능력이 기존보다 4배 이상이며 개선에 따라 더 이상 높일 수 있다. 또한 후처리 없이 위사(1)의해 관의 진원도가 높고 외부의 높은 압력에도 조직이 유지되며 원심회복력이 높다.Spiral circle fabric reinforcement produced in circular looms is different from conventional production methods. The production capacity is four times more than before and can be further increased by improvement. In addition, the weft yarn (1) without the post-treatment, the roundness of the tube is high, the tissue is maintained even at high external pressure and the centrifugal recovery power is high.

또한 직물조직이므로 신율이 적고 인장강도가 높아 코팅한 막의 기공크기가 변형이 없으며, 기계상 보풀(fuzz) 및 모우(whiskering)가 생기지 않아 코팅 시 막의 기공크기가 유지되며, 보강재 길이가 무한정이므로 코팅의 균일도와 생산성이 아주 높다.In addition, because the fabric structure has low elongation and high tensile strength, there is no deformation of the pore size of the coated membrane, and there is no mechanical fuzz and whiskering. Uniformity and productivity are very high.

이상 설명한 바와 같이, 본 발명의 중공사막의 나선관형직물(spiral circle fabric) 보강재는 직조된 견고한 지지체를 사용함으로써 우수한 내외 수압과 높은 인장력을 가지며, 모노-필라멘트를 사용함으로써 중공사막의 유연성이 향상되고 보강용 지지체의 요철이 증가되어 코팅층과의 결속력이 강화된다.As described above, the spiral circle fabric reinforcement of the hollow fiber membrane of the present invention has excellent internal and external hydraulic pressure and high tensile strength by using a woven rigid support, and the flexibility of the hollow fiber membrane is improved by using mono-filament. The unevenness of the reinforcing support member is increased to strengthen the binding force with the coating layer.

또한 보강용 지지체를 표면에 개질 처리함으로써 코팅층인 분리 여과층의 탈착을 방지할 수 있으며, 내부응고액을 처리함으로써 막의 내부 포어 조절이 가능하여 뛰어난 수투과율을 기대할 수 있으며 기공의 안정성이 높다.In addition, by modifying the surface of the reinforcing support to prevent desorption of the separation filtration layer of the coating layer, by treating the internal coagulation solution can be adjusted the pore of the membrane can be expected excellent water permeability and high porosity stability.

도 1은 나선관형직물(spiral circle fabric)의 도면이다.
도 2는 나선관형직물(spiral circle fabric)의 절단면도이다.
도 3은 나선관형직물(spiral circle fabric)의 조직도이다.
도 4는 나선관형직물(spiral circle fabric)의 표면사진이다.
도 5는 나선관형직물(spiral circle fabric)로 만들어진 보강재 사진이다.
1 is a view of a spiral circle fabric.
2 is a cutaway view of a spiral circle fabric.
3 is a schematic diagram of a spiral circle fabric.
4 is a photograph of the surface of a spiral circle fabric.
5 is a photograph of the reinforcement made of spiral circle fabric (spiral circle fabric).

원형직기(circler loom)에서 방사형으로 배열된 경사(warp)(2,3)가 교차하여 개구(shed)를 형성하면 위사(weft)(1) 샤틀(shuttle)(a, b)이 개구 속으로 회전하면서 동시에 통과하여 제직되며 연속으로 반복 되어 보강재의 관(A)의 형태로 생산된다.In a circular loom, when warp (2,3) arranged radially intersect to form an shed, a weft (1) shuttle (a, b) enters the opening. Rotating and weaving at the same time while being rotated and is repeated in succession to produce the form of the pipe (A) of the reinforcement.

위사(1)의 샤틀(a, b) 수량에 따라 나선(spiral) 리드 각도가 주어지며, 경사(warp) (2,3)수량을 조절에 의해 수투율을 조정할 수 있다.Spiral lead angles are given according to the number of shafts (a, b) of the weft yarn (1), and the water transmittance can be adjusted by adjusting the warp (2,3) quantity.

Claims (5)

중공사막 보강재는 원형직기로 제직된 나선관형직물(spiral circle fabric)형 중공사막 보강재.Hollow fiber membrane reinforcement is a spiral circle fabric type hollow fiber membrane reinforcement woven into a circular loom. 위사 1(a)와 (b)를 샤틀 2개, 4개 이상으로 한 중공사막 보강재.Hollow fiber membrane reinforcement which made weft 1 (a) and (b) two or more shackles. 위사 1 및 경사 2는 합성섬유, 모노-필라멘트, 금속사 및 특수사로 하는중공사막 보강재.Weft 1 and warp 2 are hollow fiber membrane reinforcements made of synthetic fiber, mono-filament, metal yarn and special yarn. 위사 1(a)와 (b)를 샤틀 2개, 4개 이상으로 하고 위사를 (a) (b) 이상 다른 재질과 굵기를 사용한 중공사막 보강재.A hollow fiber membrane reinforcement using at least two weft yarns (a) and (b) with at least two shafts and a different weft yarn thickness from at least (a) (b). 보강용 지지체를 표면에 개질(이온화)함으로써 코팅층인 분리여과층의 탈착을 방지하는 중공사막 보강재.A hollow fiber membrane reinforcing material which prevents desorption of a separation filtration layer which is a coating layer by modifying (ionizing) a reinforcing supporter on the surface.
KR1020180076185A 2018-07-01 2018-07-01 Manufacturing method of hollow fiber reinforcement using spiral circle fabric KR20200003340A (en)

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