KR20180052057A - Method and Portable Apparatus to Make either Functional Cosmetics or Functional Beverages with Molecular Hydrogen by Ready-Built-in When Packing or Bottling and or DIY on the Spot - Google Patents

Abstract

The present invention relates to a method for generating molecular hydrogen gas by using a method of electrolyzing water and then adding the same to cosmetic water or beverage and generating a part of hydrogen dissolved into a nano-micrometer size as desired, and to a method for manufacturing hydrogenated cosmetic water or functional beverage in a more economical and portable way, thereby providing functional beverage and cosmetic water (cosmetics) made in a DIY (do it yourself) form. More particularly, the present invention relates to a technology including a hydrogen generating device, a gas-selective permeable membrane, a nano-bubble generating device, and an ultrasonic wave irradiator which are intended to be dissolved in the cosmetic water or beverage.

Description

TECHNICAL FIELD [0001] The present invention relates to a functional cosmetic or functional beverage containing a molecular hydrogen or a functional beverage, or Bottling and or DIY on the Spot}

The present invention relates to a method of producing a molecular hydrogen gas by using water tourmaline or electrolytic electrolysis through an electrode or by using two methods simultaneously, and then adding it to cosmetics, drinking water or food materials, It is a method that can produce a part of dissolved hydrogen according to the purpose as a nano-micrometer sized bubble. It is more economical and convenient to carry, and maintains freshness of agricultural and marine life by utilizing excellent antioxidant function of hydrogenated water, functional beverage or hydrogen. Or antioxidant activity, and thus to a functional drinking water or a lotion (product) made in the form of DIY (Do It Yourself). More specifically, the present invention relates to a hydrogen generating device, a gas-selective permeable membrane, a nano bubble generating device, and a technique including use of ultrasound or tourmaline for dissolving in cosmetic lotion, drinking water or food materials.

According to recent research reports, most of the causes of the body are caused by the generation of reactive oxygen species. At the same time as this study, the antioxidative activity of molecular hydrogen is most strongly influenced by the antioxidant activity of active oxygen, It was introduced in famous journals such as Medicine. Molecular hydrogen effect of metabolic syndrome diseases including diabetes, hypertension, and hyperlipidemia in humans and animals have been carried out in clinical trials, the effect of removing active oxygen can be found through hundreds of research reports. In addition to this, clinical trials showed that diet, athlete, and anti-aging are also effective. In particular, in the case of a hydrogen-containing water containing nano bubbles, a stronger effect can be obtained in a shorter time than a general hydrogen-containing water by changing the size of water molecules and the water absorption rate into the body. As a result, it can be said that the antioxidative efficiency is further improved when it is present in the water of the nano bubble.

In the present invention, the effects of antioxidative power, anti-cell senescence, and healing function according to the addition of hydrogen to cosmetics to be carried out in the present invention are as follows. First, the phenomenon caused by cell senescence indicates a state in which the cell is weakened by stress exposure, (Apoptosis) of the programmed cells according to the degree of death. When cells die, cells are supplied from adult stem cells to maintain their function in order to maintain the number of cells for each organ to function.

Thus, our bodies are maintained by cells that are constantly born.

Anti-aging needs to be thought at the cellular level. The phenomenon of visible aging is all due to cell dysfunction. So to prevent aging, you need to control the function of the cell level. It is possible to inhibit the deterioration and damage of stem cells and tissue cells by discriminating the stress level at the level of the cells and excluding the stress.

As a result of the deterioration, the cells must begin with a programmed cell death known as apoptosis. Depending on the degree of deterioration or damage, it may also be an aging cell or a cancer cell.

In particular, it is possible to prevent the degradation of the gene due to oxidative degradation of the gene (DNA) during oxidative stress, the obstruction of intracellular transport due to oxidative deterioration of the cell membrane, the disruption of energy production due to oxidative degradation of mitochondria, Develops, aging, onset, and cancer occur at the cell, organ, and body levels.

 In particular, the effectiveness of molecular hydrogen as a defense against the toxicity of hydroxy-radicals among active oxygen species (ROS) is known to be most effective, and hydrogen therapy is under study to treat the aging of cells and the aging of the body.

  Research has also revealed that hydrogen gas has the effect of preventing skin damage caused by ultraviolet rays and inhibiting skin aging, and it is now possible to trust that hydrogen is a substance that can help skin aging. (H2O) m, Modulates Basal and UV-Induced Gene Expressions in Human Skin In Vivo. Plos One: 2013, April 24)

  According to the study, exposure to hydrogen gas for 2 hours after acute exposure to ultraviolet rays on the buttock skin with little exposure to ultraviolet rays resulted in reduced skin inflammation and DNA damage due to ultraviolet rays. Specifically, the collagenase MMP-1 increased expression when irradiated with ultraviolet light, but decreased by 58.9% when exposed to hydrogen gas. IL-6, IL-1β and COX-2, which are inflammation inducers, also decreased by 35.4%, 23.7% and 36.1%, respectively, when exposed to hydrogen gas. As such, hydrogen acts to reduce active oxygen which promotes skin aging by the effect of reduction of active oxygen of skin cells.

  In order for hydrogen-containing water or cosmetic lotion to have a useful effect, it exhibits its function only when hydrogen is present in a molecular phase, that is, in a gaseous phase, in water or a lotion at a certain concentration or more. It is reported that the effect is usually obtained when hydrogen is at least 300 to 400 ppb or higher.

The present invention provides a functional water or cosmetic lotion which is capable of producing gaseous hydrogen excellent in antioxidant effect during movement and dissolving the produced gas in cosmetic lotion or water so as to be added with the function of hydrogen, When hydrogen is dissolved in drinking water or water, nano-micrometer-sized bubbles are also generated. When sprayed onto the skin, its function is not limited to the effect of the lotion, and the antioxidant effect of hydrogen (hydrogen effect + ) To maximize the function of lotion or drinking water

The present invention relates to a method of dissolving and dissolving hydrogen and a produced gas which are excellent in antioxidant effect in cosmetic or drinking water or a target solution and, in particular, by inserting the contents of existing cosmetics into the apparatus of the present invention as they are, It also included a method for allowing hydrogen to be dissolved for cosmetics or well-being to be converted into foods and foods with excellent antioxidant power. When generating hydrogen-containing functional water contained in the container of this device, nano-micrometer-sized bubbles are also produced. When used on skin, the function is not limited to the effect of lotion, and the antioxidant effect (effect of hydrogen + effect of nano bubble ) ≪ / RTI > which is a technique for simultaneously obtaining a positive effect on the human body, particularly an effective effect on the skin.

The present invention relates to a method of generating a molecular hydrogen gas by using a method of electrolyzing water and then adding it to cosmetics or drinking water, and to generate a part of hydrogen dissolved in a nano-micrometer size as desired It is not only capable of producing hydrogenated lotion or functional beverage in a more economical and portable way but also can be easily carried in the form of DIY (Do It Yourself), so that it can be used as a highly functional drinking water containing high antioxidant function, (Product) can be produced immediately before use.

In addition, by utilizing the excellent antioxidant function of hydrogen generated through the apparatus of the present invention, the freshness of the agricultural and marine life and shiitake can be remarkably increased to increase the shelf life and shelf life, or the freshness of the foods or food materials in the refrigerator and the freshness of beverages and fruits, Hydrogen penetrates into all materials, and the healthier life of well-being can be expected through the excellent antioxidant effect of hydrogen.

도2는 본 발명에서 기존에 생산되고 있는 화장품의 용기의 변형 또는 손상 없이 용기자체를 뚜껑을 열든지 닫은 상태로 그대로 상부수조에 삽입 또는 넣어 수소를 함유한 수소화장품 또는 수소를 함유한 물을 만드는 장치이다.

도4는 기체투과형격막을 이용하여 상부수조와 하부수조 구분이 없이 전원에 의한 전기분해 장치도 없이 오직 도시바 중앙 연구소의 구보 데쓰하루 낭씨(東京 대학 물리학과 전공)는 좋은 물을 연구할 때 지하수가 어떤 광물과 접촉하여 전기 분해를 일으키고「좋은 물」로 변했다는 가설을 세워 진행하고 있었습니다.
그 결과 토르마린 가루가 수돗물에 들어가 좋은 물로 변화시킨다는 것을 발견했습니다. 그 후，많은 실험 끝에，토르마린은 0.3 μ으로 분쇄해도 결정 양단에 플러스와 마이너스의 극성을 갖고 있다.양극의 전위차는 100만 볼트에 이르기도 한다. 원석의 플러스 극과 마이너스 극을 유도선으로 연결하면 0.06 mA의 전류가 측정되는 전기석으로 토르마린 결정의 양단에 플러스 전극과 마이너스 전극이 자연적이며 영구적으로 유지하는 특성을 갖고 물을 만나면 자가전기분해에 의한 분자수소가스가 발생되는 Tourmaline(토르말린) 광물질이나 수소가스발생이 일시적이지만 Metal Hydride인 마그수소(MgH2)나 알루미늄 또는 산호 등만으로 PET나 P.P 또는 P.E. 등과 같이 개폐/밀폐/주사기주입형이 가능한 생활재활용 용기에 담아 천정 또는 바닥 또는 양쪽에 가스형투과격막을 부착하여 사용직전에 자가전기분해작용을 위해 사용전에 토르말린이 담긴 부분을 열어 물을 채우고 용기를 잠근후 물과 토르말린이 만나 반영구적으로 생성해 내는 분자수소가스가 기체투과형격막을 통해 밖으로 배출되는 것을 이용하여 냉장고나 스파 또는 욕조 등에 넣거나 또는 음용수 물병이나 음용수조통 또는 와인 또는 맥주 또는 막걸리 등에 통채로 담가서 수소의 강력한 항산화작용기능을 이용해 식자재나 음식물의 유통 및 판매과정상 산폐를 억제하고 신선도를 유지하며 식자재나 농수축산물의 생장율이나 면역율을 높여 폐사율을 줄이고 냉장고내 모든 음식물에 수소가 항상 흡수용존될 수 있는 웰빙 수단으로 사용될 수 있는 휴대간편하고 가정에서나 야외에서 필수 생활용품으로 사용할 수 있는 형태의 기본 설계도이다.

도5는 도4의 형태를 (초)소형의 Tablet 형태로 제작하여 음료수나 화장품 또는 제약시럽 또는 식품 포장제나 용기에 제습제 실리카겔을 넣듯이 위치와 크기는 용기나 목적에 따라 소형으로 축소 대형으로 확대 등의 형태로 제품의 용기나 포장제안에 제품 충진이나 포장시 미리 삽입하여 유통판매하는 형태로서의 다양한 사례를 설명하는 도면이다.

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a view showing an apparatus for producing hydrogen-containing lotion or water containing nano-micrometer hydrogen bubbles used in Example 1 of the present invention. FIG.

FIG. 2 is a cross-sectional view showing a state in which the container itself is inserted into or inserted into the upper water tank with the lid opened or closed without deforming or damaging the container of the cosmetics produced in the present invention to make hydrogen- Device.

Fig. 4 is a graph showing the results of the comparison of the groundwater flow rate and the groundwater flow rate when studying good water, without using the gas permeable diaphragm, It was hypothesized that it was brought into contact with minerals to cause electrolysis and turned into "good water."
As a result, we found that tourmaline powder enters the tap water and turns it into good water. After much experimentation, the tourmaline has positive and negative polarity at both ends of the crystal even when it is crushed at 0.3 μ. The potential difference of the positive electrode reaches 1 million volts. Tourmaline is a tourmaline measuring 0.06 mA of current when the positive and negative poles of a stone are connected by a lead wire. The positive and negative electrodes are natural and permanently held at both ends of the tourmaline crystal. Tourmaline, which generates molecular hydrogen gas and hydrogen gas are temporarily generated, but recycling is possible such as PET, PP or PE by opening / closing / syringe injection type only with metal hydride MgH2, aluminum or coral In a container, a gas permeable diaphragm is attached to the ceiling or the bottom or both sides. Before use, the electrolytic membrane is opened to open the portion containing the tourmaline, and the water is filled, the container is closed, and water and tourmaline are mixed with each other. Using the fact that the molecular hydrogen gas is discharged to the outside through the gas permeable diaphragm Dango, spas, bathtubs, etc., or immersed in potable water, drinking water, wine, or beer or makgeolli, using the powerful antioxidant function of hydrogen to control the distribution and sale of foodstuffs and foodstuffs, It is a basic design drawing that can be used as a well-being means to increase the growth rate and immunity rate of water and to reduce the mortality rate and to always absorb and dissolve hydrogen in all foods in the refrigerator.

FIG. 5 is a cross-sectional view showing a state in which the shape of FIG. 4 is formed into a small (small) tablet shape, and the position and size of the container are changed to small size and reduced size And the like in the form of a product container or a packaging proposal, which is inserted into the product at the time of filling or packing, and distributed and sold.

The present invention relates to a process for producing gaseous hydrogen which is excellent in antioxidant effect on the move, dissolving the produced gas in the skin lotion or water and also producing nano-micrometer-sized bubbles, As a method for simultaneously obtaining a positive effect on the human body, such as anti-aging by antioxidant effect (effect of hydrogen + effect of nano bubble), necessary steps are hydrogen gas production process, selective permeation process of produced gas, A process for dissolving the gas in cosmetic lotion or water, and an ultrasonic stimulation process for smoothly inducing penetration into the skin after spraying on the skin.

1) The hydrogen gas production process uses a catalytic agent of a platinum group, which serves as a catalyst and an electrode, to generate hydrogen gas by inducing electrolysis of water, and then to produce a hydrogen gas To the bottom of the container with lotion or water. At this time, ultrasonic waves are used to smoothly move the gas.

2) Through the modification of the surface of the transferred hydrogen gas, the dissolution of the gaseous hydrogen in the functional water and the lotion can be maximized through the membrane having the maximized specific surface area. In the above process, the water-containing lotion or water in which hydrogen is dissolved is applied to the skin through an atomizer. The ultrasonic module added with the ultrasonic function is attached to the upper lid of the apparatus including the spraying apparatus of the present invention, so that the effect can be further enhanced by spraying the lotion and using it for massaging. The present invention is a technique including the above-described treatment process, a spray container, and other devices.

3) The cosmetic product and the water which are already sold on the device of the present invention may be packed in a container without deforming or deteriorating the appearance of the bottle to prepare hydrogen-containing lotion or water.

Example 1)

   The gas separation (GS) -type membrane was prepared by adding ultrapure water to the upper and lower vessels, separating the upper and lower vessels, and using a polymer organic membrane as a diaphragm between the nickel electrodes to produce gaseous hydrogen from the cathode through electrolysis. This is an example of an experiment using a container in which the upper part and the lower part are separated so as to be segregated vertically so that liquids are completely isolated from each other. The container used in the experiment was an acrylic container with a volume of 100 ml and a volume of 100 ml. The upper part was completely closed in the form of a screw cap and the lower part was provided with an electrolysis device to generate gaseous hydrogen. At this time, the voltage used in the electrolysis was theoretically flowed with a current of 5.4 A of 3 V, so that 0.1 mol of hydrogen was generated per hour. During the electrolysis, the hydroxyl ions and oxygen generated at the anode were blocked from moving toward the cathode through the cation membrane for primary electrolysis, and the generated oxygen gas was completely discharged to the outside of the vessel. In order to facilitate the upward movement of the hydrogen gas generated from the lower part through the container interlayer, the lower gas pressure was maintained at a higher level than the atmospheric pressure by keeping the gas pressure generated when the gas flowed upward from the liquid to the lower part . The water in the upper vessel which selectively passes only the gaseous hydrogen through the membrane installed in the middle improves the dissolution efficiency of the gas by separately installing the stirrer and the ultrasonic wave in the inside so that the gas hydrogen can be dissolved more easily and quickly. A pressure gaseous exclusion facility was installed in the lid of the vessel to discharge gas to the outside when the pressure exceeded 0.2 bar.

In order to measure the dissolved concentration of hydrogen in water, DH-35A was used. The average temperature of the water injected into the upper and lower vessels used in the experiment was 20 ° C and atmospheric pressure.

Experimental results show that the rate of change of dissolved hydrogen per hour in the water of the upper 100 ml increased with time. Specifically, 26 ppb after 1 minute, 69 ppb after 2 minutes, 183 ppb after 5 minutes, 471 ppb after 10 minutes and 1,018 ppb , And the value satisfying the 400 ppb standard indicating the effective effect of hydrogen in water from 10 minutes later was sufficiently satisfied.

Example 2) Hydrogen gas having a purity of 99.999% was produced at a rate of 0.1M per hour by the electrolysis method using ultrapure water, and the resulting gas was passed through the gas selective permeable membrane through the plastic container for hydrogenation Gaseous hydrogen was permeated and dissolved in the liquid inside the vessel. For this purpose, 5ml of skin cosmetics was placed in the container in advance, and the amount of dissolved water in the cosmetics was measured over time. As a result of the experiment, it was confirmed that the dissolved hydrogen was detected in the cosmetics after 2 hours. The amount of dissolved water was 230 ppb after 4 hours, 540 ppb after 8 hours and 1,300 ppb after 24 hours. The equipment used in the experiment has the same structure as in Fig.

Claims (8)

If you want to add hydrogen or oxygen to cosmetics or drinking water, electrolysis by electrodes in the lower water tank of this hydrogen generating unit, or electrolysis of silicate minerals that have independent self-electrolytic power without external electrical energy when combined with water It is a kind of natural mineral with the characteristic of generating electricity by generating electricity only as a kind of tourmaline or magnesium hydrogen (MgH2), or hydrogen alone, such as aluminum or corals, or after electrolysis and tourmaline or hydrogen generation Hydrogen is produced at the same time by combining substances, and then only the gas is selectively permeated through a synthetic resin such as PE, PET, or PP permeable to hydrogen permeable nanofiber or Nanofiber instead of a breathable and permeable diaphragm or gas permeable diaphragm In a way that is characterized by its use for useful purposes And internal or bath or a lotion, or a cosmetic or functional water or food can mask pack method and apparatus for dissolving a dissolved gas such as hydrogen or other The apparatus of claim 1, wherein the upper tank is provided with a cosmetic container or an existing cosmetic container filled with liquid (glass / PET / PP, etc.) in a sealed state or with a cap or lid opened, The hydrogen gas generating water tank is miniaturized like a tablet and inserted into a packaging container such as a cosmetic product or a food or beverage container at the time of filling the contents together or after the filling, And to allow the molecular hydrogen to be slowly dissolved in the product contents immediately prior to use,
Using the gas-permeable type diaphragm, only the gas-permeable diaphragm, only the tourmaline or the self-generated hydrogen (MgH 2) which generates the molecular hydrogen when it comes into contact with the water without the separation of the upper tank and the lower tank, Only the minerals are placed in a recycling container that can be opened and closed with PET or PP or PE. The gas permeable diaphragm is attached to the ceiling, the floor or both sides, and the part containing the self- After filling or sealing the container, or when water and tourmaline meet, semi-spherical hydrogen generation is generated, or hydrogen peroxide is sealed in the gas permeable membrane together with water to form hydrogen tablets. Immediately prior to placing the hydrogen tablets in the product, slowly release the molecular hydrogen gas through the gas permeable diaphragm Or by putting it into a cosmetics, a refrigerator, a spa or a bathtub, or by putting it in a small tablet form such as drinking water, drinking water, or wine or beer or makgeolli or pharmaceutical or food, or by immersing it in a powerful antioxidant function of hydrogen, A method and apparatus for controlling the distribution and sale of food, maintaining normal freshness, maintaining the freshness, increasing the growth rate or immunity rate of foodstuffs and agricultural products, reducing the mortality rate, and being used as a well-being means in which hydrogen can always be absorbed and dissolved in all foods in the refrigerator. Household goods
In order to maximize the prevention of gas or gas deaeration from the outside of the inner tank by using the first and second paragraphs, the method and equipment of double packing or coating treatment for maximizing aluminum or other airtight, Of the water in the upper tank is minimized to minimize the deaeration of the hydrogen by minimizing the air layer on the water surface of the upper tank or the water in the lower tank is charged and the amount of the water supplied for electrolysis is decreased, A method or apparatus having a function of notifying the water supply timing by the sensor of the lower tank when the amount of water is almost consumed A container or an accessory material made by mixing a skin-stimulating agent such as ultrasonic / galvanic / electro-ionophore / high frequency / low frequency, a natural ore such as tourmaline or germanium, Or in the case of drinking water, the method and apparatus for attaching and detaching a convenient head-top in the case of drinking water is not limited to the shape or shape described in the specification. Wherein the functional gas is an insoluble gas such as oxygen, hydrogen, carbon dioxide, and carbon monoxide, and is made of one or a mixture thereof. Mixed beverages comprising one or a mixture of these, using claims 1 and 2 3; A component selected from juice, plant, enzyme, coffee, tea, green tea or extract thereof; Or mixtures thereof; and a method and apparatus for the instantaneous production of portable, functional drinking water containing nano-bubbles How to use the functional water manufactured by paragraphs 1, 2, and 3 for the purpose of supplying feeds and beverages necessary for breeding of aquatic products such as aquatic aquaculture and poultry

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