KR20180047903A - Modified conjugated diene polymer and preparation method thereof - Google Patents

Abstract

The present invention relates to a modifier represented by chemical formula 1, a method for manufacturing the same, a modified conjugated diene polymer having a high modification ratio including a modifier-derived functional group, and a method for manufacturing the polymer. In chemical formula 1, R_1 to R_5 are as defined in the specification.

Description

Modified conjugated diene polymer and preparation method thereof < RTI ID = 0.0 >

The present invention relates to a modifier useful for modifying a polymer, a modified conjugated diene polymer containing the functional group derived from the modifier, and a process for producing the polymer.

In recent years, there has been a demand for a conjugated diene polymer having a low running resistance, excellent abrasion resistance and tensile properties as a rubber material for a tire, and also having adjustment stability represented by wet skid resistance.

In order to reduce the running resistance of the tire, there is a method of reducing the hysteresis loss of the vulcanized rubber. As the evaluation index of such vulcanized rubber, repulsive elasticity of 50 DEG C to 80 DEG C, tan delta, Goodrich heat is used. That is, a rubber material having a large rebound resilience at that temperature or a small tan δ or Goodrich heating is preferable.

Natural rubbers, polyisoprene rubbers, polybutadiene rubbers, and the like are known as rubber materials having a small hysteresis loss, but these have a problem of low wet skid resistance. Recently, a conjugated diene (co) polymer such as styrene-butadiene rubber (hereinafter referred to as SBR) or butadiene rubber (hereinafter referred to as BR) is prepared by emulsion polymerization or solution polymerization and is used as a rubber for a tire .

When the above-mentioned BR or SBR is used as a rubber material for a tire, a filler such as silica or carbon black is usually blended together in order to obtain tire required properties. However, since the affinity of the BR or SBR with the filler is poor, there is a problem that physical properties including abrasion resistance, crack resistance, workability and the like are deteriorated.

As a method for increasing the dispersibility of the filler such as SBR and silica or carbon black, there has been proposed a method of modifying the polymerizable active site of the conjugated diene polymer obtained by anionic polymerization using organolithium with a functional group capable of interacting with the filler . For example, there has been proposed a method in which the polymerization active terminal of the conjugated diene polymer is modified with a tin compound, an amino group is introduced, or an alkoxysilane derivative is modified.

In a living polymer obtained by coordination polymerization using a catalyst composition containing a lanthanide-based rare-earth element compound as a method for enhancing the dispersibility of a filler such as BR and silica or carbon black, the living active terminal is reacted with a specific coupling agent A method of denaturation by a denaturant has been developed.

However, BR or SBR modified by the above-mentioned method has a low terminal modification ratio, and therefore, the effect of improving the physical properties of the tire produced using the BR or SBR is insignificant.

JP 2012-097271A KR 10-2011-0119722 A

Disclosure of Invention Technical Problem [8] The present invention has been made to solve the problems of the prior art, and it is an object of the present invention to provide a modifier useful for modifying a polymer.

Another object of the present invention is to provide a method for producing the above modifier.

It is still another object of the present invention to provide a modified conjugated diene polymer having a high modification ratio including the functional group derived from the above modifier.

Still another object of the present invention is to provide a process for producing the above-mentioned modified conjugated diene polymer.

In order to solve the above problems, the present invention provides a denaturant represented by the following general formula (1).

 [Chemical Formula 1]

In Formula 1,

R ₁ , R ₄ and R ₅ independently of each other are substituted with one or more substituents selected from the group consisting of a linear or branched alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, and an aryl group having 6 to 30 carbon atoms, Is a monovalent hydrocarbon group of 1 to 20 carbon atoms,

R ₂ is a linear or branched alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, and an aryl group having 6 to 30 carbon atoms and having 1 to 20 carbon atoms which is unsubstituted or substituted with at least one substituent Is a hydrocarbon group,

R ₃ is a linking group represented by the following formula (2) or (3)

(2)

(3)

In Formula 2 or Formula 3,

R < ₆ > is a linear or branched alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, and an aryl group having 6 to 30 carbon atoms and having 1 to 20 carbon atoms A monovalent hydrocarbon group,

R ₇ to R ₁₀ are each independently a divalent hydrocarbon group of 1 to 20 carbon atoms which is unsubstituted or substituted with a linear or branched alkyl group having 1 to 20 carbon atoms.

The present invention also relates to a process for preparing a compound represented by the following general formula (8) (step a) by first reacting a compound represented by the following general formula (7) with an alkyl ketone compound; And a step (b) of reacting the compound represented by the formula (8) and the compound represented by the following formula (9) (step b).

(7)

[Chemical Formula 8]

[Chemical Formula 9]

[Chemical Formula 1]

In the above formulas (1), (7) to (9)

R ₁ , R ₄ and R ₅ independently of each other are substituted with one or more substituents selected from the group consisting of a linear or branched alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, and an aryl group having 6 to 30 carbon atoms, Is a monovalent hydrocarbon group of 1 to 20 carbon atoms,

R ² is a linear or branched alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, and an aryl group having 6 to 30 carbon atoms and having 1 to 20 carbon atoms which is unsubstituted or substituted with at least one substituent Is a hydrocarbon group,

A is Cl or Br,

R ₁₁ is represented by the following general formula (10) or (11)

[Chemical formula 10]

(11)

In Formula 10 or Formula 11,

R < ₆ > is a linear or branched alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, and an aryl group having 6 to 30 carbon atoms and having 1 to 20 carbon atoms A monovalent hydrocarbon group,

R ₇ to R ₁₀ are each independently a divalent hydrocarbon group of 1 to 20 carbon atoms which is unsubstituted or substituted with a linear or branched alkyl group having 1 to 20 carbon atoms.

In addition, the present invention provides a modified conjugated diene polymer comprising the functional group derived from the modifier represented by the above formula (1).

Further, the present invention provides a process for producing an organic polymer, comprising polymerizing a conjugated diene monomer in the presence of a catalyst composition comprising a lanthanide-based rare earth element-containing compound in a hydrocarbon solvent to prepare an active polymer having an organic metal bonded thereto (step 1); And a step (2) of reacting the active polymer with the modifier represented by the formula (1).

The modifier represented by the formula (1) according to the present invention has an anionic reactive group due to the introduction of an ester group, so that the modifier can easily react with the active site of the polymer, and the modifier can be easily performed.

Further, the modified conjugated diene polymer according to the present invention may have excellent affinity with a filler such as carbon black by including the functional group derived from the modifier represented by the formula (1).

In addition, the method for producing a modified conjugated diene polymer according to the present invention can easily produce a modified conjugated diene polymer having a high modification ratio by using the modifier represented by the formula (1).

Hereinafter, the present invention will be described in detail in order to facilitate understanding of the present invention.

The terms and words used in the present specification and claims should not be construed in an ordinary or dictionary sense and the inventor can properly define the concept of the term to describe its invention in the best possible way It should be construed as meaning and concept consistent with the technical idea of the present invention.

The present invention provides a modifier useful for modifying a modified conjugated diene polymer.

The modifier according to one embodiment of the present invention is characterized by being represented by the following formula (1).

[Chemical Formula 1]

In Formula 1,

R ₁ , R ₄ and R ₅ independently of each other are substituted with one or more substituents selected from the group consisting of a linear or branched alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, and an aryl group having 6 to 30 carbon atoms, Is a monovalent hydrocarbon group of 1 to 20 carbon atoms,

R ₂ is a linear or branched alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, and an aryl group having 6 to 30 carbon atoms and having 1 to 20 carbon atoms which is unsubstituted or substituted with at least one substituent Is a hydrocarbon group,

R ₃ is a linking group represented by the following formula (2) or (3)

(2)

(3)

In Formula 2 or Formula 3,

R < ₆ > is a linear or branched alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, and an aryl group having 6 to 30 carbon atoms and having 1 to 20 carbon atoms A monovalent hydrocarbon group,

R ₇ to R ₁₀ are each independently a divalent hydrocarbon group of 1 to 20 carbon atoms which is unsubstituted or substituted with a linear or branched alkyl group having 1 to 20 carbon atoms.

Specifically, in Formula 1, R ₁ , R _4, and R ₅ are each independently a monovalent hydrocarbon group having 1 to 20 carbon atoms or a monovalent hydrocarbon having 1 to 20 carbon atoms substituted with a substituent.

Wherein R _1, R ₄ and R ₅ are when a carbon number of independently caused a 1 C 1 -C 20 hydrocarbon group to each other, wherein R _1, R ₄ and R ₅ is a cycloalkyl group having 1 to 20 carbon alkyl group, having 3 to 20 carbon atoms, An aryl group having 6 to 20 carbon atoms, and an arylalkyl group having 7 to 20 carbon atoms. Concretely, R ₁ , R ₄ and R ₅ independently represent an alkyl group having 1 to 10 carbon atoms, an alkyl group having 3 to 10 carbon atoms A cycloalkyl group having 6 to 12 carbon atoms, an aryl group having 6 to 12 carbon atoms, and an arylalkyl group having 7 to 12 carbon atoms.

When R ₁ , R ₄ and R ₅ are monovalent hydrocarbons having 1 to 20 carbon atoms substituted with a substituent, R ₁ , R ₄ and R ₅ are each independently a linear or branched alkyl group having 1 to 10 carbon atoms , A cycloalkyl group having 3 to 12 carbon atoms, and an aryl group having 6 to 12 carbon atoms.

In Formula 1, R ₂ may be a divalent hydrocarbon group having 1 to 20 carbon atoms or a divalent hydrocarbon group having 1 to 20 carbon atoms substituted with a substituent.

When R ₂ is a divalent hydrocarbon group having 1 to 20 carbon atoms, R ² is an alkylene group having 1 to 10 carbon atoms such as a methylene group, an ethylene group or a propylene group; An arylene group having 6 to 20 carbon atoms such as a phenylene group and the like; Or an arylalkylene group having 7 to 20 carbon atoms as a combinator thereof. More specifically, R ² may be an alkylene group having 1 to 6 carbon atoms. When R ₂ is a divalent hydrocarbon group having 1 to 20 carbon atoms substituted with a substituent, R ₂ is a linear or branched alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, and aryl having 6 to 30 carbon atoms Or a substituent selected from the group consisting of a halogen atom and a halogen atom.

Further, in the above formula 1, R ₃ is to be caused by connection represented by the formula (2) or (3), if the connection resulting from the R ₃ is represented by Formula 2 in Formula 2, R ₆ is C 1 -C 20 1 May be a hydrocarbon group or a monovalent hydrocarbon group of 1 to 20 carbon atoms substituted with at least one substituent selected from the group consisting of a linear or branched alkyl group, a cycloalkyl group having 3 to 20 carbon atoms and an aryl group having 6 to 30 carbon atoms , R ₇ is a divalent hydrocarbon group having 1 to 20 carbon atoms or a divalent hydrocarbon group having 1 to 20 carbon atoms substituted with a linear or branched alkyl group having 1 to 20 carbon atoms. Specifically, in Formula 2, R ₆ is an alkyl group having 1 to 10 carbon atoms, or an alkenyl group having 1 to 10 carbon atoms substituted with a linear or branched alkyl group having 1 to 10 carbon atoms, and R ₇ is a group having 1 to 10 carbon atoms 10 < / RTI > alkylene group.

When R ₃ is a linking group represented by the general formula (3), R ₈ to R ₁₀ independently represent a divalent hydrocarbon group having 1 to 20 carbon atoms, or a linear or branched alkyl group having 1 to 20 carbon atoms And may be a divalent hydrocarbon group having 1 to 20 carbon atoms. Specifically, R ₈ to R ₁₀ may be independently of each other an alkylene group having 1 to 10 carbon atoms.

Specifically, the modifying agent is in formula 1, R _1, R ₄ and R ₅ are independently an alkyl group having 1 to 6 carbon atoms, which is unsubstituted or substituted with a linear or branched alkyl group having 1 to 5 carbon atoms, R ₂ is an alkylene group having 1 to 6 carbon atoms, 3, R ₆ is an alkyl group having 1 to 6 carbon atoms, and R ₇ to R ₁₀ may be an alkylene group having 1 to 6 carbon atoms.

More specifically, the modifier represented by the above formula (1) may be represented by the following formula (4), (5) or (6)

[Chemical Formula 4]

[Chemical Formula 5]

[Chemical Formula 6]

In addition, since the alkyl chain is introduced between the ester group and the amine group, the modifier may have excellent solubility in a solvent. Specifically, the modifier may have a solubility of 10 g or more in a nonpolar solvent such as 100 g of hexane at 25 ° C and 1 atm. Here, the solubility of a denaturant means a degree of dissolution that is clear without a cloudy phenomenon when observed with the naked eye. Thus, the modifier according to one embodiment of the present invention can be used as a modifier for a polymer to improve the modification ratio of the polymer.

In addition, the modifier represented by the above formula (1) according to the present invention contains a reactive functional group, a filler affinity functional group and a solvent affinity functional group for the conjugated diene polymer, thereby allowing the conjugated diene polymer to be easily modified at a high modification ratio , A rubber composition containing the same, and a molded article such as a tire produced therefrom can be improved in abrasion resistance, low fuel consumption characteristics, and processability. Specifically, the modifier of Formula 1 may contain an ester group, an amine group, an alkyl chain, and optionally an imine group in the molecule as described above, and the ester group may have high reactivity to the active site of the conjugated diene polymer Whereby the conjugated diene polymer can be modified at a high modification ratio, and consequently, the functional group substituted in the modifier can be introduced into the conjugated diene polymer at a high yield. In addition, the amine group can be further converted into a primary amino group by reacting with the conjugated diene-based polymer at the terminal thereof, thereby further improving the compatibility with the filler, particularly carbon black. In addition, the alkyl chain may increase the affinity to the polymerization solvent to increase the solubility of the modifier, thereby improving the modification ratio with respect to the conjugated diene polymer.

Further, the present invention provides a process for producing a modifier represented by the following general formula (1).

The method according to an embodiment of the present invention may include a first step of reacting a compound represented by the following general formula (7) with an alkyl ketone compound to prepare a compound represented by the following general formula (8) (step a); And a second step of reacting the compound represented by the formula (8) and the compound represented by the following formula (9) (step b).

(7)

[Chemical Formula 8]

[Chemical Formula 9]

[Chemical Formula 1]

In the above formulas (1), (7) to (9)

R ₁ , R ₄ and R ₅ independently of each other are substituted with one or more substituents selected from the group consisting of a linear or branched alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, and an aryl group having 6 to 30 carbon atoms, Is a monovalent hydrocarbon group of 1 to 20 carbon atoms,

R ₂ is a linear or branched alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, and an aryl group having 6 to 30 carbon atoms and having 1 to 20 carbon atoms which is unsubstituted or substituted with at least one substituent Is a hydrocarbon group,

A is Cl or Br,

R ₁₁ is represented by the following general formula (10) or (11)

[Chemical formula 10]

(11)

In Formula 10 or Formula 11,

R < ₆ > is a linear or branched alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, and an aryl group having 6 to 30 carbon atoms and having 1 to 20 carbon atoms A monovalent hydrocarbon group,

R ₇ to R ₁₀ are each independently a divalent hydrocarbon group of 1 to 20 carbon atoms which is unsubstituted or substituted with a linear or branched alkyl group having 1 to 20 carbon atoms.

The first reaction of step (a) may be carried out by reacting the compound of formula (7) with an alkyl ketone compound to prepare a compound represented by formula (8). The compound represented by the general formula (7) and the alkyl ketone compound may be used in a stoichiometric ratio. Specifically, the compound represented by the general formula (7) and the alkyl ketone compound may be used in a molar ratio of 1: 1 to 1: 2 It can be used. More specifically, the compound represented by Formula 7 and the alkyl ketone compound may be used in a molar ratio of 1: 2.

Here, the first reaction may be performed at a temperature ranging from 110 ° C to 160 ° C.

The alkyl ketone compound is not particularly limited, and examples thereof include methyl isopropyl ketone, methyl isobutyl ketone, cyclohexanone, methyl ethyl ketone, diisopropyl ketone, ethyl butyl ketone, methyl butyl ketone and dipropyl ketone Or a combination thereof.

The second reaction of step b) may be carried out by reacting the compound represented by formula (8) with the compound represented by formula (9) for preparing the modifier represented by formula (1). The compound represented by the formula (8) and the compound represented by the formula (9) may be used in a stoichiometric ratio. For example, the compound represented by the formula (8) and the compound represented by the formula (9) 2, and specifically may be used in a molar ratio of 1: 1.5. On the other hand, the second reaction may be carried out at a temperature ranging from 20 ° C to 60 ° C.

In addition, the present invention provides a modified conjugated diene polymer comprising a functional group derived from a modifier represented by the following general formula (1).

[Chemical Formula 1]

In Formula 1,

R ₁ , R ₄ and R ₅ independently of each other are substituted with one or more substituents selected from the group consisting of a linear or branched alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, and an aryl group having 6 to 30 carbon atoms, Is a monovalent hydrocarbon group of 1 to 20 carbon atoms,

R ₂ is a linear or branched alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, and an aryl group having 6 to 30 carbon atoms and having 1 to 20 carbon atoms which is unsubstituted or substituted with at least one substituent Is a hydrocarbon group,

R ₃ is a linking group represented by the following formula (2) or (3)

(2)

(3)

In Formula 2 or Formula 3,

R < ₆ > is a linear or branched alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, and an aryl group having 6 to 30 carbon atoms and having 1 to 20 carbon atoms A monovalent hydrocarbon group,

R ₇ to R ₁₀ are each independently a divalent hydrocarbon group of 1 to 20 carbon atoms which is unsubstituted or substituted with a linear or branched alkyl group having 1 to 20 carbon atoms.

The modified conjugated diene-based polymer according to an embodiment of the present invention may be prepared by reacting an organic polymer-bonded active polymer with a modifier represented by Formula 1 through a production method described below, and the modified conjugated diene- The polymer may include the functional group derived from the denaturant represented by the general formula (1), whereby the physical properties may be improved.

Specifically, the denaturant represented by Formula 1 may be as described above.

Specifically, the modified conjugated diene polymer may include a filler-affinity functional group and a solvent affinity functional group by including a modifier-derived functional group represented by the formula (1), and a rubber composition comprising the same and a tire The wear resistance, the low fuel consumption characteristics and the workability of the molded article of the present invention can be improved.

The modified conjugated diene polymer may have a number average molecular weight (Mn) of 100,000 g / mol to 700,000 g / mol, specifically 120,000 g / mol to 500,000 g / mol.

The modified conjugated diene polymer may have a weight average molecular weight (Mw) of 300,000 g / mol to 1,200,000 g / mol, specifically 400,000 g / mol to 1,000,000 g / mol.

The modified conjugated diene polymer may have a molecular weight distribution (Mw / Mn) of 1.05 to 5.

The modified conjugated diene polymer according to an embodiment of the present invention may have a molecular weight distribution range as described above and a weight average molecular weight The average molecular weight and the number average molecular weight may simultaneously satisfy the above-mentioned range of conditions.

Specifically, the modified conjugated diene polymer may have a molecular weight distribution of 3.4 or less, a weight average molecular weight of 300,000 g / mol to 1,200,000 g / mol, and a number average molecular weight of 100,000 g / mol to 700,000 g / mol , More specifically polydispersity of 3.2 or less, weight average molecular weight of 400,000 g / mol to 1,000,000 g / mol, and number average molecular weight of 120,000 g / mol to 500,000 g / mol.

Herein, the weight average molecular weight and the number average molecular weight are respectively polystyrene reduced molecular weights analyzed by gel permeation chromatography (GPC), molecular weight distribution (Mw / Mn) is also called polydispersity, weight average molecular weight (Mw) And the number-average molecular weight (Mn) (Mw / Mn).

In addition, the modified conjugated diene polymer according to an embodiment of the present invention may be a polymer having high linearity with a value of -S / R (stress / relaxation) at 100 ° C of 0.7 or more. In this case, -S / R represents a change in stress due to the reaction of the same amount of strain generated in the material, and is an index indicating the linearity of the polymer. Generally, the lower the -S / R value means the lower the linearity of the polymer, and the lower the linearity, the greater the rolling resistance or the rolling resistance when applied to the rubber composition. Also, the degree of branching and the molecular weight distribution of the polymer can be predicted from the above-S / R value. The lower the S / R value, the higher the degree of branching and the broader the molecular weight distribution. As a result, Characteristics are low.

Since the modified conjugated diene polymer according to an embodiment of the present invention has a high-S / R value of 0.7 or more at 100 캜 as described above, resistance characteristics and fuel consumption characteristics can be excellent when applied to a rubber composition. Specifically, the -S / R value of the modified conjugated diene polymer may be 0.7 to 1.0.

Here, the -S / R value was measured using a Mooney viscometer, for example, a large rotor of Monsanto MV2000E at 100 ° C and a rotor speed of 2 ± 0.02 rpm. Specifically, the polymer was allowed to stand at room temperature (23 ± 5 ° C) for 30 minutes or more, 27 ± 3 g was collected, filled in the die cavity, and the platen was operated to measure the Mooney viscosity while applying the torque. -S / R value was obtained by measuring the slope value of the Mooney viscosity change appearing when the torque was released.

Specifically, the modified conjugated diene polymer may have a cis-1,4 bond content of not less than 95%, more specifically not less than 98%, as measured by Fourier transform infrared spectroscopy (FT-IR). Accordingly, when applied to a rubber composition, the abrasion resistance, crack resistance and ozone resistance of the rubber composition can be improved.

The modified conjugated diene polymer may have a vinyl content of not more than 5%, more specifically not more than 2%, as measured by Fourier transform infrared spectroscopy. When the vinyl content in the polymer is more than 5%, there is a possibility that the abrasion resistance, crack resistance and ozone resistance of the rubber composition containing the polymer are deteriorated.

Herein, the intracellular cis-1,4 bond content and the vinyl content by the Fourier transform infrared spectroscopy (FT-IR) were the same as those of the conjugated diene polymer prepared by using the same cell disulfide carbon as a blank at a concentration of 5 mg / (A, baseline) near 1130 cm ^{& lt;} -1 > of the measurement spectrum, a minimum peak near 967 cm < ^-1 > (B), the minimum peak value (c) near 911 cm ^-1 indicating the vinyl bond, and the minimum peak value (d) near 736 cm ^-1 indicating the cis-1,4 bond, I think.

In addition, the present invention provides a process for producing a modified conjugated diene-based polymer comprising a modifier-derived group represented by the above formula (1).

The production process according to an embodiment of the present invention comprises polymerizing a conjugated diene monomer in the presence of a catalyst composition containing a lanthanide rare earth element-containing compound in a hydrocarbon solvent to prepare an active polymer having an organic metal bonded thereto ); And reacting the active polymer with a modifier represented by the following formula (1) (step 2).

[Chemical Formula 1]

In Formula 1,

R ₁ , R ₄ and R ₅ independently of each other are substituted with one or more substituents selected from the group consisting of a linear or branched alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, and an aryl group having 6 to 30 carbon atoms, Is a monovalent hydrocarbon group of 1 to 20 carbon atoms,

R ₂ is a linear or branched alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, and an aryl group having 6 to 30 carbon atoms and having 1 to 20 carbon atoms which is unsubstituted or substituted with at least one substituent Is a hydrocarbon group,

R ₃ is a linking group represented by the following formula (2) or (3)

(2)

(3)

In Formula 2 or Formula 3,

R < ₆ > is a linear or branched alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, and an aryl group having 6 to 30 carbon atoms and having 1 to 20 carbon atoms A monovalent hydrocarbon group,

R ₇ to R ₁₀ are each independently a divalent hydrocarbon group of 1 to 20 carbon atoms which is unsubstituted or substituted with a linear or branched alkyl group having 1 to 20 carbon atoms.

Specifically, the denaturant represented by the general formula (1) may be as described above.

Step 1 is a step for preparing an active polymer having an organometallic bond by using a catalyst composition containing a lanthanide-based rare earth element-containing compound, which is carried out by polymerizing a conjugated diene monomer in the presence of the catalyst composition in a hydrocarbon solvent .

Examples of the conjugated diene monomer include, but are not limited to, 1,3-butadiene, 2,3-dimethyl-1,3-butadiene, piperylene, 3-butyl-1,3-octadiene, -1,3-butadiene, and the like.

The hydrocarbon solvent is not particularly limited, but may be one or more selected from the group consisting of n-pentane, n-hexane, n-heptane, isooctane, cyclohexane, toluene, benzene and xylene.

The catalyst composition may be used in an amount such that the amount of the lanthanum-based rare earth element-containing compound is from 0.1 mmnol to 0.5 mmol based on 100 g of the conjugated dienic monomer. Specifically, the lanthanide rare earth element- May be used in an amount of 0.1 mmol to 0.4 mmol, more specifically 0.1 mmol to 0.25 mmol, based on 100 g of the total monomer.

The lanthanide-based rare earth element-containing compound is not particularly limited, but may be any one or two or more compounds selected from among rare earth metals having atomic numbers of 57 to 71 such as lanthanum, neodymium, cerium, gadolinium or praseodymium, , Lanthanum, and gadolinium.

The lanthanide-based rare earth element-containing compound may be at least one selected from the group consisting of the rare earth metal-containing carboxylate (for example, neodymium acetate, neodymium acrylate, neodymium methacrylate, neodymium acetate, neodymium gluconate, neodymium citrate, neodymium fumarate, Neodymium lactate, neodymium maleate, neodymium oxalate, neodymium 2-ethylhexanoate, neodymium neodecanoate, etc.); Organic phosphoric acid salts such as neodymium dibutyl phosphate, neodymium dipentyl phosphate, neodymium dihexyl phosphate, neodymium diheptyl phosphate, neodymium dioctyl phosphate, neodymium bis (1-methylheptyl) phosphate, neodymium bis (2-ethylhexyl) Phosphate, or neodymium dodecyl phosphate); Organic phosphonates such as neodymium butylphosphonate, neodymium pentylphosphonate, neodymium hexylphosphonate, neodymium heptylphosphonate, neodymium octylphosphonate, neodymium (1-methylheptyl) phosphonate, Neodymium (2-ethylhexyl) phosphonate, neodymium disilphosphonate, neodymium dodecylphosphonate or neodymium octadecylphosphonate); Organic phosphoric acid salts such as neodymium butylphosphinate, neodymium pentylphosphinate, neodymium hexylphosphinate, neodymium heptylphosphinate, neodymium octylphosphinate, neodymium (1-methylheptyl) phosphinate or Neodymium (2-ethylhexyl) phosphinate, etc.); Carbamates (e.g., neodymium dimethylcarbamate, neodymium diethylcarbamate, neodymium diisopropylcarbamate, neodymium dibutylcarbamate or neodymium dibenzylcarbamate); Dithiocarbamates (for example, neodymium dimethyldithiocarbamate, neodymium diethyldithiocarbamate, neodymium diisopropyldithiocarbamate or neodymium dibutyldithiocarbamate); (For example, neodymium methyl xanthate, neodymium ethyl xanthate, neodymium isopropyl xanthate, neodymium butyl xanthogenate, or neodymium benzyl xanthogenate); ? -diketonate (for example, neodymium acetylacetonate, neodymium trifluoroacetylacetonate, neodymium hexafluoroacetylacetonate or neodymium benzoyl acetonate); Alkoxide or allyoxide (e.g., neodymium methoxide, neodymium ethoxide, neodymium isopropoxide, neodymium phenoxide or neodymium nonylphenoxide); Halide or pseudohalide (such as neodymium fluoride, neodymium chloride, neodymium bromide, neodymium iodide, neodymium cyanide, neodymium cyanate, neodymium thiocyanate, or neodymium azide); Oxy halides (e.g., neodymium oxyfluoride, neodymium oxychloride, or neodymium oxybromide); (Cp ₃ Ln, Cp ₂ LnR, Cp ₂ LnCl, CpLnCl ₂ , CpLn (cyclooctatetraene), (C ₅ Me ₅ ) ₂ LnR, LnR ₃ , Ln (allyl) ₃ , or Ln (allyl) ₂ Cl, where Ln is a rare earth metal element and R is a hydrocarbyl group. And may include two or more mixtures.

Specifically, the lanthanide-based rare earth element-containing compound may include a neodymium compound represented by the following general formula (12).

[Chemical Formula 12]

In formula (12), R _a to R _c may independently be hydrogen or a linear or branched alkyl group having 1 to 12 carbon atoms, provided that R _a to R _c are not both hydrogen at the same time.

As specific examples, wherein the neodymium compound is Nd (neodecanoate) _3, Nd (2- ethylhexanoate) _3, Nd (2,2- diethyl decanoate) _3, Nd (2,2- dipropyl having decanoate) _3, Nd (2,2- di-butyl decanoate) _3, Nd (2,2- di-hexyl decanoate) _3, Nd (2,2- dioctyl decanoate) _3, Nd (2 -ethyl-2-propyl decanoate) _3, Nd (2- ethyl-2-butyl decanoate) _3, Nd (2- ethyl-2-hexyl decanoate) _3, Nd (2- propyl-2 butyl decanoate) _3, Nd (2- propyl-2-hexyl decanoate) _3, Nd (2- propyl-2-isopropyl decanoate) _3, Nd (2- butyl-2-hexyl decanoate ) _3, Nd (2- cyclohexyl-2-octyl decanoate) _3, Nd (2-t- butyl decanoate) _3, Nd (2,2- diethyl octanoate) _3, Nd (2,2 - dipropyl octanoate) _3, Nd (2,2- dibutyltin octanoate) _3, Nd (2,2- dihexyl octanoate) _3, Nd (2- ethyl-2-propyl-octanoate) ₃ , Nd (2-ethyl-2-hexyloctanoate Agent) _3, Nd (2,2- diethyl-no nano-benzoate) _3, Nd (2,2- dipropyl no nano-benzoate) _3, Nd (2,2- dibutyl no nano-benzoate) _3, Nd (2, 2-dihexyl no nano-benzoate) _3, Nd (2-ethyl-2-propyl-no nano-benzoate) ₃ and Nd (2-ethyl-2-hexyl-no nano-benzoate) may be at least one member selected from the group consisting of _3.

As another example, taking into consideration that the lanthanide-based rare-earth element-containing compound is more excellent in the solubility in a polymerization solvent, the conversion to a catalytically active species and the effect of improving the catalytic activity without fear of oligomerization, Wherein R _a is a linear or branched alkyl group of 4 to 12 carbon atoms, R _b and R _c are independently of each other hydrogen or a linear or branched alkyl group of 2 to 8 carbon atoms, provided that R _b and R _c are not simultaneously hydrogen Neodymium compound.

More specifically, in the above formula (12), R _a is a linear or branched alkyl group having 6 to 8 carbon atoms, R _b and R _c are each independently hydrogen or a linear or branched alkyl group having 2 to 6 carbon atoms, In this case, R _b and R _c may not be simultaneously hydrogen. Specific examples thereof include Nd (2,2-diethyldecanoate) ₃ , Nd (2,2-dipropyldecanoate) ₃ , Nd , 2-dibutyldecanoate) ₃ , Nd (2,2-dihexyldecanoate) ₃ , Nd (2,2-dioctyldecanoate) ₃ , Nd Eight) _3, Nd (2- ethyl-2-butyl decanoate) _3, Nd (2- ethyl-2-hexyl decanoate) _3, Nd (2- butyl-2-propyl decanoate) _3, Nd (2-propyl-2-hexyl decanoate) _3, Nd (2-propyl-2-isopropyl decanoate) _3, Nd (2-butyl-2-hexyl decanoate) _3, Nd (2-hexyl 2-octyldecanoate) ₃ , Nd (2-t-butyl decanoate) ₃ , Nd Naphthyl octanoate) _3, Nd (2,2- dipropyl octanoate) _3, Nd (2,2- dibutyltin octanoate) _3, Nd (2,2- dihexyl octanoate) _3, Nd (2-ethyl-2-propyl-octanoate) _3, Nd (2-ethyl-2-hexyl octanoate) _3, Nd (2,2- diethyl-no nano-benzoate) _3, Nd (2,2- di no nano-propyl benzoate) _3, Nd (2,2- dibutyl no nano-benzoate) _3, Nd (2,2- dihexyl no nano-benzoate) _3, Nd (2- ethyl-2-propyl-no nano-benzoate) ₃ and Nd (2-ethyl-2-hexylnonanoate) ₃ , and the neodymium compound may be at least one selected from the group consisting of Nd (2,2-diethyldecanoate) ₃ , Nd - dipropyl decanoate) _3, Nd (2,2- di-butyl decanoate) _3, Nd (2,2- di-hexyl decanoate) _3, and Nd (2,2- dioctyl decanoate) ₃ < / RTI >

More specifically, in Formula 12, R _a is a linear or branched alkyl group having 6 to 8 carbon atoms, and R _b and R _c are each independently a linear or branched alkyl group having 2 to 6 carbon atoms.

Thus, the neodymium compound represented by Formula (12) includes a carboxylate ligand containing an alkyl group having various lengths of at least 2 carbon atoms at the alpha (alpha) position as a substituent, thereby inducing a steric change around the neodymium center metal, It is possible to prevent the phenomenon of entanglement and, consequently, to suppress oligomerization. In addition, the neodymium compound has high solubility in a polymerization solvent and has a low neodymium ratio in a central portion, which is difficult to convert to a catalytically active species, and thus has a high conversion ratio to a catalytically active species.

In addition, the solubility of the lanthanide rare earth element-containing compound according to an embodiment of the present invention may be about 4 g or more per 6 g of the non-polar solvent at room temperature (25 캜).

In the present invention, the solubility of the neodymium compound means a degree of dissolution that is clear without cloudy phenomenon, and exhibits such high solubility that it can exhibit excellent catalytic activity.

In addition, the lanthanide rare earth element-containing compound according to an embodiment of the present invention may be used in the form of a reactant with a Lewis base. This reactant has the effect of improving the solubility of the lanthanide-based rare-earth element-containing compound in a solvent by Lewis base and storing it in a stable state for a long period of time. The Lewis base may be used in a proportion of, for example, 30 moles or less, or 1 to 10 moles, per mole of the rare earth element. The Lewis base may be, for example, acetylacetone, tetrahydrofuran, pyridine, N, N-dimethylformamide, thiophene, diphenylether, triethylamine, organic phosphorus compounds or monohydric or dihydric alcohols.

On the other hand, the catalyst composition may further comprise at least one of (a) an alkylating agent, (b) a halide and (c) a conjugated diene monomer together with the lanthanide rare earth element-containing compound.

Hereinafter, the alkylating agent (a), the halide (b), and the conjugated diene monomer (c) will be specifically described.

 (a) an alkylating agent

The alkylating agent may be an organometallic compound capable of transferring a hydrocarbyl group to another metal and serving as a cocatalyst composition. The alkylating agent is not particularly limited as long as it is used as an alkylating agent in the production of a diene polymer. The alkylating agent is soluble in a polymerization solvent, such as an organoaluminum compound, an organomagnesium compound, or an organolithium compound, Based on the total weight of the composition.

Specific examples of the organoaluminum compound include trimethylaluminum, triethylaluminum, tri-n-propylaluminum, triisopropylaluminum, tri-n-butylaluminum, triisobutylaluminum, tri- Alkyl aluminum such as aluminum, trihexyl aluminum, tricyclohexyl aluminum and trioctyl aluminum; Di-n-propyl aluminum hydride, di-n-propyl aluminum hydride, di-n-butyl aluminum hydride, diisobutyl aluminum hydride (DIBAH) Diphenyl aluminum hydride, di-p-tolyl aluminum hydride, dibenzyl aluminum hydride, phenylethyl aluminum hydride, phenyl-n-propyl aluminum hydride, phenyl isopropyl aluminum hydride, phenyl- N-propyl aluminum hydride, p-tolyl isopropyl aluminum hydride, p-tolyl-isopropyl aluminum hydride, p-tolyl isopropyl aluminum hydride, n-butyl aluminum hydride, p-tolyl isobutyl aluminum hydride, p-tolyl-n-octyl aluminum N-propyl aluminum hydride, benzyl isopropyl aluminum hydride, benzyl-n-butyl aluminum hydride, benzyl isobutyl aluminum hydride or benzyl-n-octyl aluminum hydride, etc. Dihydrocarbyl aluminum hydride; Hydrocarbylaluminum di-hydrides such as ethylaluminum dihydride, n-propylaluminum dihydride, isopropylaluminum dihydride, n-butylaluminum dihydride, isobutylaluminum dihydride or n- Hydride, and the like. Examples of the organomagnesium compound include alkylmagnesium compounds such as diethylmagnesium, di-n-propylmagnesium, diisopropylmagnesium, dibutylmagnesium, dihexylmagnesium, diphenylmagnesium and dibenzylmagnesium, and Examples of the organic lithium compound include alkyl lithium compounds such as n-butyl lithium and the like.

In addition, the organoaluminum compound may be aluminoxane.

The aluminoxane may be one prepared by reacting a trihydrocarbyl aluminum compound with water, specifically, a linear aluminoxane of the following formula (13a) or a cyclic aluminoxane of the following formula (13b).

[Chemical Formula 13a]

[Chemical Formula 13b]

In the general formulas (13a) and (13b), R is a monovalent organic group which is bonded to an aluminum atom through a carbon atom, which may be a hydrocarbyl group, x and y are independently an integer of 1 or more, , And more specifically, an integer of 2 to 50.

More specifically, the aluminoxane is selected from the group consisting of methylaluminoxane (MAO), modified methylaluminoxane (MMAO), ethylaluminoxane, n-propylaluminoxane, isopropylaluminoxane, butylaluminoxane, isobutylaluminoxane, n Hexylaluminoxane, n-hexylaluminoxane, n-octylaluminoxane, 2-ethylhexylaluminoxane, cyclohexylaluminoxane, 1-methylcyclopentylaluminoxane, phenylaluminoxane or 2,6- Dimethylphenylaluminoxane, and the like, and any one or a mixture of two or more thereof may be used.

The modified methylaluminoxane is obtained by replacing the methyl group of methylaluminoxane with a silyl group (R), specifically a hydrocarbon group having 2 to 20 carbon atoms, and specifically a compound represented by the following formula (14).

[Chemical Formula 14]

In Formula 14, R is the same as defined above, and m and n may be independently an integer of 2 or more. In the above formula (9), Me represents a methyl group.

Specifically, in Formula 14, R is a linear or branched alkyl group having 2 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, an alkenyl group having 2 to 20 carbon atoms, a cycloalkenyl group having 3 to 20 carbon atoms, An arylalkyl group having 7 to 20 carbon atoms, an alkylaryl group having 7 to 20 carbon atoms, an allyl group, or an alkynyl group having 2 to 20 carbon atoms, and more specifically, an ethyl group, an isobutyl group, a hexyl group, A linear or branched alkyl group having from 2 to 10 carbon atoms such as a methyl group, an ethyl group, a t-butyl group and the like, and more specifically an isobutyl group.

More specifically, the modified methylaluminoxane may be obtained by substituting about 50 to 90 mol% of the methyl group of methylaluminoxane with the hydrocarbon group described above. When the content of the substituted hydrocarbon group in the modified methylaluminoxane is within the above range, the alkylation can be promoted to increase the catalytic activity.

Such modified methylaluminoxane can be prepared by a conventional method, and specifically, it can be produced using alkylaluminum other than trimethylaluminum and trimethylaluminum. The alkylaluminum may be triisobutylaluminum, triethylaluminum, trihexylaluminum or trioctylaluminum, and any one or a mixture of two or more thereof may be used.

In addition, the catalyst composition according to an embodiment of the present invention may contain the alkylating agent in an amount of 1 to 200 molar equivalents, preferably 1 to 100 molar equivalents, more preferably 3 to 20 molar equivalents relative to 1 mol of the lanthanum-based rare earth element-containing compound May include. If the alkylating agent is contained in an amount exceeding 200 molar ratio, it is difficult to control the catalytic reaction during the production of the polymer, and excessive amounts of the alkylating agent may cause side reactions.

(b) Halide

Examples of the halide include, but are not limited to, a halogen group, an interhalogen compound, a hydrogen halide, an organic halide, a non-metal halide, a metal halide or an organic metal halide, One or a mixture of two or more may be used. Among them, one or a mixture of two or more selected from the group consisting of an organic halide, a metal halide, and an organometallic halide may be used as the halogen compound, considering that the catalytic activity is improved and the reactivity is improved.

Examples of the halogen group include fluorine, chlorine, bromine and iodine.

Examples of the interhalogen compound include iodine monochloride, iodine monobromide, iodine trichloride, iodopentafluoride, iodine monofluoride, iodotrifluoride, and the like.

Examples of the hydrogen halide include hydrogen fluoride, hydrogen chloride, hydrogen bromide, and hydrogen iodide.

Examples of the organic halide include t-butyl chloride (t-BuCl), t-butyl bromide, allyl chloride, allyl bromide, benzyl chloride, benzyl bromide, chloro-di-phenyl methane, bromo- But are not limited to, phenyl methyl chloride, triphenyl methyl bromide, benzylidene chloride, benzylidene bromide, methyltrichlorosilane, phenyltrichlorosilane, dimethyldichlorosilane, diphenyldichlorosilane, trimethylchlorosilane (TMSCl), benzoyl chloride, benzoyl bromide, (Also referred to as "iodoform"), tetraiodomethane, 1-iodo-2-iodo-2-methylpropionate, Iodopropane, 1,3-diiodopropane, t-butyl iodide, 2,2-dimethyl-1-iodopropane ('neopentyl (Also referred to as "benzyl iodide"), allyl iodide, iodobenzene, benzyl iodide, diphenylmethyl iodide, triphenylmethyl iodide, benzylidene iodide , Trimethylsilyl iodide, triethylsilyl iodide, triphenylsilyl iodide, dimethyldiiodosilane, diethyldiiodosilane, diphenyldiiodosilane, methyltriiodosilane, ethyltriiodo Phenyl triiodosilane, benzoyl iodide, propionyl iodide or methyl iodoformate, and the like.

In addition, the non-metallic halides include phosphorus trichloride, phosphorus tribromide, phosphorus pentachloride, phosphorus oxychloride, oxy-bromide, phosphorus, boron trifluoride, boron trichloride, boron tribromide, used silicon tetrafluoride, silicon tetrachloride (SiCl _4), tetrabromide silicon , Arsenic trichloride, arsenic tribromide, selenium tetrabromide, selenium tetrabromide, tellurium tetrachloride, tellurium tetrabromide, silicon tetrabromide, silicon tetrabromide, arsenic triiodide, tellurium tetraiodide, boron triiodide, phosphorous iodide or selenium iodide .

Examples of the metal halide include tin tetrachloride, tin tetrabromide, aluminum trichloride, aluminum tribromide, antimony trichloride, antimony trichloride, antimony tribromide, antimony tribromide, aluminum trifluoride, gallium trichloride, gallium tribromide, gallium trifluoride, There may be mentioned indium tribromide, indium trifluoride, titanium tetrachloride, titanium tetrabromide, zinc dichloride, zinc bromide, zinc fluoride, aluminum triiodide, gallium triiodide, indium triiodide, titanium iodide, zinc iodide, Germanium, tin iodide, tin iodide, antimony triiodide or magnesium iodide.

Examples of the organometallic halide include dimethylaluminum chloride, diethylaluminum chloride, dimethylaluminum bromide, diethylaluminum bromide, dimethylaluminum fluoride, diethylaluminum fluoride, methylaluminum dichloride, ethylaluminum dichloride, methylaluminum di (EASC), isobutylaluminum sesquichloride, methylmagnesium chloride, methylmagnesium bromide, ethyl bromide, ethyl bromide, ethyl bromide, ethyl bromide, ethyl bromide, Magnesium chloride, ethylmagnesium bromide, n-butylmagnesium chloride, n-butylmagnesium bromide, phenylmagnesium chloride, phenylmagnesium bromide, benzylmagnesium chloride Di-t-butyl tin dichloride, di-t-butyl tin dibromide, di-n-butyl tin dichloride, di-n-butyl tin dichloride, trimethyltin chloride, trimethyltin bromide, triethyltin chloride, triethyltinbromide, Butyl tin chloride, tri-n-butyl tin bromide, methylmagnesium iodide, dimethyl aluminum iodide, diethyl aluminum iodide, di-n-butyl aluminum iodide, Diisobutylaluminum iodide, di-n-octylaluminum iodide, methylaluminum iodide, ethylaluminum iodide, n-butylaluminum iodide, isobutylaluminum iodide, methylaluminum sesquioxide N-butylmagnesium iodide, ethylmagnesium iodide, n-butylmagnesium iodide, n-butylmagnesium iodide, , Isobutyl magnesium iodide, phenylmagnesium iodide, benzyl magnesium iodide, trimethyl tin iodide, triethyl tin iodide, tri-n-butyl tin iodide, di- And di-t-butyltin diiodide.

In addition, the catalyst composition according to an embodiment of the present invention may contain 1 to 20 molar equivalents, more preferably 1 to 5 molar equivalents, and more preferably 2 to 5 molar equivalents of the halide to 1 mol of the lanthanum-based rare earth element- Moles to 3 moles. If the halide is contained in an amount exceeding 20 molar equivalents, the removal of the catalytic reaction is not easy, and excessive halides may cause side reactions.

In addition, the catalyst composition for preparing a conjugated diene polymer according to an embodiment of the present invention may include a non-coordinating anion-containing compound or a non-coordinating anion precursor compound instead of or in combination with the halide.

Specifically, in the compound containing the non-coordinating anion, the non-coordinating anion is a sterically bulky anion which does not form a coordination bond with the active center of the catalyst system due to steric hindrance, and is a tetraaryl borate anion or tetraaryl fluoride Borate anions, and the like. In addition, the compound containing the non-coordinating anion may include a carbonium cation such as a triarylcarbonium cation together with the above-mentioned non-coordinating anion; An ammonium cation such as N, N-dialkyl anilinium cation or the like, or a relative cation such as a phosphonium cation. More specifically, the compound comprising the non-coordinating anion is selected from the group consisting of triphenylcarbonium tetrakis (pentafluorophenyl) borate, N, N-dimethylanilinium tetrakis (pentafluorophenyl) borate, triphenylcarboniumtetra 3,5-bis (trifluoromethyl) phenyl] borate, or N, N-dimethylanilinium tetrakis [3,5-bis (trifluoromethyl) phenyl] borate.

Examples of the nonpolar anionic precursors include triarylboron compounds (BE ₃ , wherein E is a pentafluorophenyl group or a 3,5-bis (trifluoromethyl) phenyl group and the like, which is capable of forming a non- And a strong electron withdrawing aryl group.

(c) a conjugated diene monomer

The catalyst composition may further comprise a conjugated diene monomer and may be a preforming catalyst composition prepared by preliminarily mixing a part of the conjugated diene monomer used in the polymerization reaction with the catalyst composition for polymerization The activity of the catalyst composition can be improved, and the conjugated diene polymer to be produced can be stabilized.

In the present invention, the term "preforming" refers to a catalyst composition comprising a lanthanide-based rare earth element-containing compound, an alkylating agent and a halogen compound, that is, a catalyst system comprising diisobutylaluminum hydride (DIBAH) A small amount of a conjugated diene monomer such as 1,3-butadiene is added in order to reduce the possibility of forming various catalyst composition active species, and pre-polymerization is carried out in the catalyst composition system together with 1,3-butadiene addition . ≪ / RTI > Also, "premix" may mean that the catalyst composition system is not polymerized and each compound is uniformly mixed.

In this case, the conjugated diene monomer used for preparing the catalyst composition may be one in which the conjugated diene monomer used in the polymerization reaction is used in an amount within a total amount of the conjugated diene monomer. For example, the lanthanide rare earth element-containing compound 1 1 to 100 molar ratio, specifically 10 to 50 molar ratio or 20 to 50 molar ratio with respect to the molar amount may be used.

The catalyst composition according to an embodiment of the present invention may contain at least one of the above-described lanthanum-based rare earth element-containing compound and at least one of an alkylating agent, a halide and a conjugated diene monomer, specifically, a compound containing a lanthanide rare earth element, Cargo, and optionally a conjugated diene-based monomer. At this time, the organic solvent may be a nonpolar solvent which is not reactive with the catalyst components described above. Specific examples include n-pentane, n-hexane, n-heptane, n-octane, n-nonane, n-decane, isopentane, isohexane, isopentane, isooctane, 2,2-dimethylbutane, cyclopentane, , Methylcyclopentane or methylcyclohexane, and the like; alicyclic hydrocarbons having 5 to 20 carbon atoms in a linear, branched, or cyclic form; A mixed solvent of aliphatic hydrocarbons having 5 to 20 carbon atoms such as petroleum ether or petroleum spirits, or kerosene; Or an aromatic hydrocarbon solvent such as benzene, toluene, ethylbenzene, xylene, etc., and any one or a mixture of two or more of them may be used. More specifically, the non-polar solvent may be any of the above-described linear, branched or cyclic aliphatic hydrocarbons or aliphatic hydrocarbons of 5 to 20 carbon atoms, more specifically, n-hexane, cyclohexane, .

In addition, the organic solvent may be appropriately selected depending on the constituent material of the catalyst composition, in particular, the kind of the alkylating agent.

Specifically, in the case of alkylaluminoxanes such as methylaluminoxane (MAO) or ethylaluminoxane as an alkylating agent, an aromatic hydrocarbon solvent can be suitably used because it is not easily dissolved in an aliphatic hydrocarbon-based solvent.

When modified methylaluminoxane is used as the alkylating agent, an aliphatic hydrocarbon-based solvent may be suitably used. In this case, a single solvent system can be realized together with an aliphatic hydrocarbon-based solvent such as hexane, which is mainly used as a polymerization solvent, so that the polymerization reaction can be more advantageous. Further, the aliphatic hydrocarbon-based solvent can promote the catalytic activity, and the reactivity can be further improved by such catalytic activity.

On the other hand, the organic solvent may be used in an amount of 20 to 20,000 mol, more specifically 100 to 1,000 mol, per mol of the lanthanum-based rare earth element-containing compound.

On the other hand, the polymerization in the step 1 may be carried out using coordination anionic polymerization or by radical polymerization, specifically, bulk polymerization, solution polymerization, suspension polymerization or emulsion polymerization, and more specifically, Can be unified.

In addition, the polymerization may be carried out by any of a batch process and a continuous process. Specifically, the polymerization in step 1 may be carried out by charging the conjugated diene monomer into the catalyst composition in an organic solvent.

Here, the organic solvent may be added in addition to the amount of the organic solvent that can be used for preparing the catalyst composition, and the specific kind may be as described above. In addition, when the organic solvent is used, the concentration of the monomer may be 3 wt% to 80 wt%, or 10 wt% to 30 wt%.

In addition, the polymerization may include a reaction terminator to complete the polymerization reaction such as polyoxyethylene glycol phosphate or the like; Or antioxidants such as 2,6-di-t-butyl paracresol and the like may further be used. In addition, an additive such as a chelating agent, a dispersing agent, a pH adjusting agent, an oxygen scavenger, or an oxygen scavenger may be further optionally added, which facilitates solution polymerization usually.

The polymerization may be temperature-raising polymerization, isothermal polymerization or constant temperature polymerization (adiabatic polymerization).

Here, the constant-temperature polymerization is a polymerization method comprising a step of polymerizing an organometallic compound in a self-reaction heat without any heat, and after the introduction of the organometallic compound, heat is applied arbitrarily to the temperature And the isothermal polymerization is a polymerization method in which the organometallic compound is added and then heat is applied to increase the heat or heat to keep the temperature of the polymer constant.

The polymerization may be carried out in a temperature range of -20 캜 to 200 캜, specifically in a temperature range of from 20 캜 to 150 캜, more specifically from 10 캜 to 120 캜 for 15 minutes to 3 hours . If the polymerization temperature is higher than 200 ° C, it is difficult to sufficiently control the polymerization reaction and the cis-1,4 bond content of the resultant diene polymer may be lowered. When the temperature is lower than -20 ° C, Speed and efficiency may be lowered.

Step 2 is a step of reacting the active polymer with the modifier represented by Formula 1 to produce a modified conjugated diene polymer.

The modifier represented by the above formula (1) may be the same as described above, or one or more of them may be mixed and used in the reaction.

The modifier represented by Formula 1 may be used in an amount of 0.5 to 20 moles per mole of the catalyst composition. Specifically, the modifier represented by the formula (1) may be used in an amount of 1 to 10 moles per mole of the catalyst composition. If the modifier is used in such an amount as to give the above range, the modifying reaction with the optimum performance can be performed, and the conjugated diene polymer having a high modification ratio can be obtained.

The reaction of step 2 may be a modification reaction for introducing a functional group into the polymer, and the reaction may be carried out at 0 캜 to 90 캜 for 1 minute to 5 hours.

In addition, the method for producing the modified conjugated diene-based polymer according to an embodiment of the present invention may be carried out by a continuous polymerization method including batch type (batch type) or one or more kinds of reactors.

After completion of the above-mentioned modification reaction, an isopropanol solution of 2,6-di-t-butyl-p-cresol (BHT) or the like may be added to the polymerization reaction system to terminate the polymerization reaction. Thereafter, the modified conjugated diene polymer can be obtained through desolvation treatment or vacuum drying treatment such as steam stripping which lowers the partial pressure of the solvent through supply of water vapor. In addition, the reaction product obtained as a result of the above-mentioned denaturation reaction may contain an unmodified active polymer together with the above-mentioned modified conjugated diene polymer.

The manufacturing method according to an embodiment of the present invention may further include at least one step of recovering and drying the solvent and unreacted monomers after the step 2, if necessary.

Further, the present invention provides a rubber composition comprising the modified conjugated diene polymer and a molded article produced from the rubber composition.

The rubber composition according to an embodiment of the present invention contains the modified conjugated diene polymer in an amount of 0.1 to 100% by weight, specifically 10 to 100% by weight, more specifically 20 to 90% by weight May include. If the content of the modified conjugated diene polymer is less than 0.1% by weight, the effect of improving the abrasion resistance and crack resistance of a molded article produced using the rubber composition, such as a tire, may be insignificant.

In addition, the rubber composition may further include other rubber components, if necessary, in addition to the modified conjugated diene polymer, wherein the rubber component may be contained in an amount of 90 wt% or less based on the total weight of the rubber composition. Specifically, it may be contained in an amount of 1 part by weight to 900 parts by weight based on 100 parts by weight of the modified conjugated diene-based copolymer.

The rubber component may be natural rubber or synthetic rubber, for example natural rubber (NR) comprising cis-1,4-polyisoprene; Modified natural rubbers such as epoxidized natural rubber (ENR), deproteinized natural rubber (DPNR), and hydrogenated natural rubber, which are modified or refined with the general natural rubber; Butadiene copolymers (SBR), polybutadiene (BR), polyisoprenes (IR), butyl rubbers (IIR), ethylene-propylene copolymers, polyisobutylene-co-isoprene, neoprene, poly Butadiene), poly (styrene-co-butadiene), poly (styrene-co-butadiene) Synthetic rubber such as polysulfide rubber, acrylic rubber, urethane rubber, silicone rubber, epichlorohydrin rubber, butyl rubber, halogenated butyl rubber and the like may be used, and any one or a mixture of two or more thereof may be used have.

In addition, the rubber composition may contain 0.1 to 150 parts by weight of a filler based on 100 parts by weight of the modified conjugated diene polymer, and the filler may be silica-based, carbon black or a combination thereof. Specifically, the filler may be carbon-bank rack.

The carbon black filler is not particularly limited, but may have a nitrogen adsorption specific surface area (measured according to N2SA, JIS K 6217-2: 2001) of 20 m 2 / g to 250 m 2 / g. The carbon black may have a dibutyl phthalate oil absorption (DBP) of 80 cc / 100 g to 200 cc / 100 g. If the nitrogen adsorption specific surface area of the carbon black exceeds 250 m ² / g, the workability of the rubber composition may deteriorate. If it is less than 20 m ² / g, the reinforcing performance by carbon black may be insufficient. If the DBP oil absorption of the carbon black exceeds 200 cc / 100 g, the workability of the rubber composition may decrease. If the DBP oil absorption is less than 80 cc / 100 g, the reinforcing performance by carbon black may be insufficient.

The silica is not particularly limited, but may be, for example, wet silica (hydrated silicic acid), dry silica (silicic anhydride), calcium silicate, aluminum silicate or colloidal silica. Specifically, the silica can be a wet silica silica having the most remarkable effect of improving the fracture characteristics and the wet grip. The silica has a nitrogen surface area per gram (N 2 SA) of 120 m 2 / g to 180 m 2 / g and a specific surface area of CTAB (cetyl trimethyl ammonium bromide) of 100 m 2 / g to 200 m 2 / g Lt; / RTI > If the nitrogen adsorption specific surface area of the silica is less than 120 m < 2 > / g, the reinforcing performance by silica may be lowered. If it exceeds 180 m < 2 > / g, If the CTAB adsorption specific surface area of the silica is less than 100 m < 2 > / g, the reinforcing performance by the silica as a filler may be deteriorated. If it exceeds 200 m < 2 > / g, the workability of the rubber composition may deteriorate.

On the other hand, when silica is used as the filler, a silane coupling agent may be used together to improve the reinforcing property and the low heat build-up.

Specific examples of the silane coupling agent include bis (3-triethoxysilylpropyl) tetrasulfide, bis (3-triethoxysilylpropyl) trisulfide, bis (2-triethoxysilylethyl) tetrasulfide, bis (3-trimethoxysilylpropyl) tetrasulfide, bis (2-trimethoxysilylethyl) tetrasulfide, 3-mercaptopropyltrimethoxysilane , 3-mercaptopropyltriethoxysilane, 2-mercaptoethyltrimethoxysilane, 2-mercaptoethyltriethoxysilane, 3-trimethoxysilylpropyl-N, N-dimethylthiocarbamoyltetrasulfide Triethoxysilylpropyl-N, N-dimethylthiocarbamoyltetrasulfide, 2-triethoxysilylethyl-N, N-dimethylthiocarbamoyltetrasulfide, 3-trimethoxysilyl Propylbenzothiazolyltetrasulfide, 3-triethoxysilylpropylbenzyltetrasulfide, 3-triethoxysilylpropylmethacrylate Monosulfide, monosulfide, 3-trimethoxysilylpropyl methacrylate monosulfide, bis (3-diethoxymethylsilylpropyl) tetrasulfide, 3-mercaptopropyldimethoxymethylsilane, dimethoxymethylsilylpropyl- N-dimethylthiocarbamoyltetrasulfide, or dimethoxymethylsilylpropylbenzothiazolyltetrasulfide. Any one or a mixture of two or more of them may be used. More specifically, in consideration of the reinforcing effect, the silane coupling agent may be bis (3-triethoxysilylpropyl) polysulfide or 3-trimethoxysilylpropyl benzothiazine tetrasulfide.

Further, in the rubber composition according to the embodiment of the present invention, since the modified conjugated diene polymer in which a functional group having a high affinity for the filler is introduced into the active site as the rubber component is used, the amount of the silane coupling agent It can be reduced more than usual. Specifically, the silane coupling agent may be used in an amount of 1 part by weight to 20 parts by weight based on 100 parts by weight of the filler. When used in the above-mentioned range, gelation of the rubber component can be prevented while sufficiently exhibiting the effect as a coupling agent. More specifically, the silane coupling agent may be used in an amount of 5 parts by weight to 15 parts by weight based on 100 parts by weight of silica.

In addition, the rubber composition according to an embodiment of the present invention may be sulfur-crosslinkable and may further include a vulcanizing agent.

The vulcanizing agent may be specifically a sulfur powder and may be included in an amount of 0.1 to 10 parts by weight based on 100 parts by weight of the rubber component. When contained in the above content range, the required elastic modulus and strength of the vulcanized rubber composition can be ensured, and at the same time, the low fuel consumption ratio can be obtained.

In addition, the rubber composition according to one embodiment of the present invention may contain various additives commonly used in the rubber industry, such as a vulcanization accelerator, a process oil, a plasticizer, an antioxidant, a scorch inhibitor, zinc white ), Stearic acid, a thermosetting resin, or a thermoplastic resin.

The vulcanization accelerator is not particularly limited and specifically includes M (2-mercaptobenzothiazole), DM (dibenzothiazyl disulfide), CZ (N-cyclohexyl-2-benzothiazyl sulfenamide) Based compound, or a guanidine-based compound such as DPG (diphenylguanidine) can be used. The vulcanization accelerator may be included in an amount of 0.1 to 5 parts by weight based on 100 parts by weight of the rubber component.

The process oil may be a paraffinic, naphthenic, or aromatic compound. More specifically, considering the tensile strength and abrasion resistance, the process oil may be an aromatic process oil, a hysteresis loss And naphthenic or paraffinic process oils may be used in view of the low temperature characteristics. The process oil may be contained in an amount of 100 parts by weight or less based on 100 parts by weight of the rubber component. When the content is included in the above amount, the tensile strength and low heat build-up (low fuel consumption) of the vulcanized rubber can be prevented from lowering.

Specific examples of the antioxidant include N-isopropyl-N'-phenyl-p-phenylenediamine, N- (1,3-dimethylbutyl) -N'- 2, 4-trimethyl-1,2-dihydroquinoline, or high-temperature condensates of diphenylamine and acetone. The antioxidant may be used in an amount of 0.1 part by weight to 6 parts by weight based on 100 parts by weight of the rubber component.

The rubber composition according to one embodiment of the present invention can be obtained by kneading by using a kneader such as Banbury mixer, roll, internal mixer or the like by the above compounding formula, and can be obtained by vulcanizing after molding, This excellent rubber composition can be obtained.

Accordingly, the rubber composition can be applied to various members such as tire tread, under-tread, sidewall, carcass coated rubber, belt coated rubber, bead filler, pancake fur, or bead coated rubber, vibration proof rubber, belt conveyor, Can be useful for the production of various industrial rubber products.

The molded article produced using the rubber composition may be one comprising a tire or tire tread.

Hereinafter, the present invention will be described in more detail with reference to Examples and Experimental Examples. However, the following examples and experimental examples are provided for illustrating the present invention, and the scope of the present invention is not limited thereto.

Manufacturing example  1: ethyl-4- ( Methyl (3 - ((4-methylpentan-2-ylidene) Amino) propyl) amino) Hexanoate  Produce

1) Preparation of N-methyl-3 - ((3-methylbutan-2-ylidene) amino) propan-

To a 2 L round bottom flask was added 168 ml of methyl isobutyl ketone to 50 g (567 mmol) of 3- (methylamino) propylamine and the temperature was raised to 130 ° C. The reaction was terminated after confirming that the 3- (methylamino) propylamine was completely consumed. The organic layer was dried by adding sodium sulfate to obtain a yellow oil (purity 95%, yield: 95%), To give the title compound of the following formula (i). The nuclear magnetic resonance spectroscopic data of ¹ H of the obtained compound of formula (i) is as follows.

(i)

(i)

^{1 H-NMR (500 MHz,} CDCl 3) δ 3.29 (t, 2H), 2.65 (t, 2H), 2.43 (s, 3H), 2.11 (d, 2H), 1.97 (m, 1H), 1.82 (m , 2H), 1.79 (s, 3H), 0.91 (d, 6H).

2) Preparation of ethyl-4- (methyl) -3 - ((4-methylpentan-2-ylidene) amino) propyl) amino) hexanoate

20 ml of acetonitrile was added to 10 g (37 mmol) of N-methyl-3 - ((3-methylbutan-2-ylidene) amino) propan-1- amine prepared in 1) above in a 2 L round bottom flask. And then the temperature was raised to 40 占 폚. After adding 5.62 g (55.5 mmol) of triethylamine thereto, 12.45 g (55.5 mmol) of ethyl 6-bromohexanoate was added and reacted with stirring for 12 hours to complete the reaction. 100 ml of hexane was added and the mixture was extracted and concentrated under reduced pressure to give the title compound of formula (ii) as a yellow oil (purity 95%, yield 90%). Nuclear magnetic resonance spectroscopic data of ¹ H of the obtained compound of formula (ii) are as follows.

(ii)

(ii)

^{1 H-NMR (500 MHz,} CDCl 3) δ 4.11 (q, 2H), 3.36 (t, 4H), 2.78 (m, 4H), 2.54 (t, 2H), 2.28 (t, 2H), 2.12 (d 2H), 1.25 (t, 3H), 0.89 (d, 2H), 1.96 (m, 12H).

Manufacturing example  2: ethyl-4- ( Methyl (3 - ((4-methylpentan-2-ylidene) Amino) propyl) amino) Butanoate  Produce

1) Preparation of N-methyl-3 - ((3-methylbutan-2-ylidene) amino) propan-

To a 2 L round bottom flask was added 168 ml of methyl isobutyl ketone to 50 g (567 mmol) of 3- (methylamino) propylamine and the temperature was raised to 130 ° C. The reaction was terminated after confirming that the 3- (methylamino) propylamine was completely consumed. The organic layer was dried by adding sodium sulfate to obtain a yellow oil (purity 95%, yield: 95%), To give the title compound of the following formula (i). The nuclear magnetic resonance spectroscopic data of ¹ H of the obtained compound of formula (i) is as follows.

(i)

(i)

^{1 H-NMR (500 MHz,} CDCl 3) δ 3.29 (t, 2H), 2.65 (t, 2H), 2.43 (s, 3H), 2.11 (d, 2H), 1.97 (m, 1H), 1.82 (m , 2H), 1.79 (s, 3H), 0.91 (d, 6H).

2) Preparation of ethyl-4- (methyl) -3 - ((4-methylpentan-2-ylidene) amino) propyl) amino) butanoate

20 ml of acetonitrile was added to 10 g (37 mmol) of N-methyl-3 - ((3-methylbutan-2-ylidene) amino) propan-1- amine prepared in 1) above in a 2 L round bottom flask. And then the temperature was raised to 40 占 폚. After 5.62 g (55.5 mmol) of triethylamine was added thereto, 10.83 g (55.5 mmol) of ethyl 4-bromobutyrate was added and reacted with stirring for 12 hours, after which the reaction was terminated. 100 ml of hexane was added, extracted and concentrated under reduced pressure to give the title compound of formula (iii) as a yellow oil (purity 95%, yield 90%). Nuclear magnetic resonance spectroscopic data of ¹ H of the obtained compound of formula (iii) are as follows.

(iii)

(iii)

^{1 H-NMR (500 MHz,} CDCl 3) δ 4.07 (q, 2H), 3.31 (t, 4H), 2.72 (t, 4H), 2.53 (t, 2H), 2.28 (m, 2H), 2.08 (d 2H), 1.18 (t, 3H), 0.89 (d, 12H).

Manufacturing example  3: ethyl-6- (4- (2 - ((4- Methylpentane -2- Iriden ) Amino) ethyl) piperazin-1-yl) hexanoate

1) Preparation of 4-methyl-N- (2- (piperazin-1-yl) ethyl) pentan-2-

To a 2 L round bottom flask was added 96.6 ml of methyl isobutyl ketone to 50 g (387 mmol) of 1- (2-aminoethyl) piperazine and the temperature was raised to 130 ° C. Thereafter, the mixture was reacted with stirring for 5 hours. After confirming that the 1-2 (-aminoethyl) piperazine was completely consumed, the reaction was terminated and sodium sulfate was added thereto. The obtained organic layer was dried to obtain a yellow oil (purity 95% %) Of the title compound of the formula (iv) below. Nuclear magnetic resonance spectroscopic data of ¹ H of the obtained compound of formula (iv) are as follows.

(iv)

(iv)

^{1 H-NMR (500 MHz,} CDCl 3) δ 3.41 (t, 2H), 2.91 (t, 4H), 2.66 (t, 2H), 2.50 (bs, 4H), 2.13 (d, 2H), 1.99 (m , ≪ / RTI > 1H), 1.81 (s, 3H), 0.89 (d, 6H).

2) Preparation of ethyl-6- (4- (2- ((4-methylpentan-2-ylidene) amino) ethyl) piperazin- 1 -yl) hexanoate

To a 2 L round bottom flask was added 20 ml of acetonitrile to 7.3 g (34.6 mmol) of 4-methyl-N- (2- (piperazin-1-yl) ethyl) pentan- After that, the temperature was raised to 60 占 폚. After adding 4.43 g (52 mmol) of triethylamine, 10.83 g (55.5 mmol) of ethyl 4-bromobutyrate was added and reacted with stirring for 12 hours to complete the reaction. 100 ml of hexane was added and the mixture was extracted and concentrated under reduced pressure to give the title compound of formula (v) as a yellow oil (purity 95%, yield 90%). Nuclear magnetic resonance spectroscopic data of ¹ H of the obtained compound of formula (v) are as follows.

(v)

(v)

¹ H-NMR (500 MHz, CDCl ₃ )? 4.10 (q, 2H), 3.39 (t, 4H), 2.66-2.29 (m, (m, 2H), 1.50 (m, 2H), 1.35 (m, 3H), 1.25 (t, 3H), 0.89 (d, 6H).

Example 1

900 g of 1,3-butadiene and 6.6 kg of n-hexane were placed in a 20 L autoclave reactor, and the temperature inside the reactor was raised to 70 占 폚. Nd (2,2-diethyl decanoate) ₃ 0.10 mmol of hexane solution, 0.89 mmol of diisobutylaluminum hydride (DIBAH), 0.24 mmol of diethylaluminum chloride, 1,3-butadiene 3.3 mmol, was added to the reactor, and polymerization was carried out for 60 minutes. Thereafter, a hexane solution containing 4.45 mmol of the compound represented by the formula (ii) prepared in Preparation Example 1 was added, followed by a denaturation reaction at 70 ° C for 30 minutes. Then, a hexane solution containing 1.0 g of a polymerization terminator and an antioxidant WINGSTAY  (Eliokem SAS, France) dissolved in hexane at 30 wt% was added. The resulting polymer was placed in hot water heated with steam and stirred to remove the solvent. The solvent was then removed by roll drying to remove the remaining solvent and water, thereby preparing a modified butadiene polymer.

Example 2

900 g of 1,3-butadiene and 6.6 kg of n-hexane were placed in a 20 L autoclave reactor, and the temperature inside the reactor was raised to 70 占 폚. Nd (2,2-diethyl decanoate) ₃ 0.10 mmol of hexane solution, 0.89 mmol of diisobutylaluminum hydride (DIBAH), 0.24 mmol of diethylaluminum chloride, 1,3-butadiene 3.3 mmol, was added to the reactor, and polymerization was carried out for 60 minutes. Thereafter, a hexane solution containing 4.55 mmol of the compound represented by the formula (v) prepared in Preparation Example 3 was added, followed by a denaturation reaction at 70 ° C for 30 minutes. Then, a hexane solution containing 1.0 g of a polymerization terminator and an antioxidant WINGSTAY  (Eliokem SAS, France) dissolved in hexane at 30 wt% was added. The resulting polymer was placed in hot water heated with steam and stirred to remove the solvent. The solvent was then removed by roll drying to remove the remaining solvent and water, thereby preparing a modified butadiene polymer.

Comparative Example

900 g of 1,3-butadiene and 6.6 kg of n-hexane were placed in a 20 L autoclave reactor, and the temperature inside the reactor was raised to 70 占 폚. Nd (2,2-diethyl decanoate) ₃ 0.10 mmol of hexane solution, 0.89 mmol of diisobutylaluminum hydride (DIBAH), 0.24 mmol of diethylaluminum chloride, 1,3-butadiene 3.3 mmol, was added to the reactor, and polymerization was carried out for 60 minutes. Then, a hexane solution containing 1.0 g of a polymerization terminator and an antioxidant WINGSTAY  (Eliokem SAS, France) dissolved in hexane at 30 wt% was added. The resulting polymer was placed in hot water heated with steam, stirred to remove the solvent, and then dried by roll to remove residual solvent and water to prepare a butadiene polymer.

Experimental Example 1

The properties of the modified butadiene polymer prepared in Examples 1 and 2 and the butadiene polymer prepared in Comparative Examples were measured in the following manner, and the results are shown in Table 1 below.

1) weight average molecular weight (Mw), number average molecular weight (Mn), and molecular weight distribution

Each of the polymers was dissolved in tetrahydrofuran (THF) for 30 minutes under the condition of 40 占 폚 and loaded on gel permeation chromatography (GPC). At this time, two columns of PLgel Olexis column and one column of PLgel mixed-C column of Polymer Laboratories were used in combination. In addition, a column of a mixed bed type was used as a new column, and polystyrene was used as a gel permeation chromatography (GPC) standard material.

2) Mooney viscosity and -S / R value

For each polymer, the Mooney viscosity (MV) was measured at 100 ° C using Rotor Speed 2 ± 0.02 rpm using Monsanto MV2000E with a large rotor. The sample used was allowed to stand at room temperature (23 ± 3 ° C) for more than 30 minutes, and then 27 ± 3 g was sampled and filled in the die cavity. Platen was operated to measure the Mooney viscosity by applying torque.

Further, the change in Mooney viscosity as the torque was released upon measurement of the Mooney viscosity was observed for 1 minute, and the -S / R value was determined from the slope value.

Example 1 Example 2 Comparative Example Denaturation denaturalization denaturalization Unmodified GPC results Mn (x 10 ⁵ g / mol) 2.56 2.60 2.64 Mw (x10 ⁵ g / mol) 6.785 6.651 6.18 Mw / Mn 3.06 2.78 2.35 MV (ML1 + 4, @ 100 C) (MU) 44.4 51.0 45.1 -S / R 0.7896 0.9254 0.5666

As shown in Table 1, it was confirmed that the modified butadiene polymers of Examples 1 and 2 according to one embodiment of the present invention had a -S / R value of 0.7 or more, which was greatly increased as compared with the butadiene polymer of Comparative Example. Thus, it can be confirmed that the modified butadiene polymer according to one embodiment of the present invention has high linearity.

Experimental Example 2

The rubber composition and the rubber specimen were prepared using the modified butadiene polymer prepared in Examples 1 to 2 and Comparative Example 2 and the butadiene polymer prepared in Comparative Example 2 and then the Mooney viscosity, % Modulus, elongation and viscoelasticity, respectively. The 300% modulus, tensile strength, elongation and viscoelasticity were indexed with the measured value of the comparative example as 100. The results are shown in Table 2 below.

Specifically, 70 parts by weight of carbon black, 22.5 parts by weight of process oil, 2 parts by weight of an antioxidant (TMDQ), 2 parts by weight of zinc oxide (ZnO) 3, and a mixture of 100 parts by weight of each of the modified butadiene polymer and butadiene polymer And 2 parts by weight of stearic acid were mixed to prepare respective rubber compositions. Then, 2 parts by weight of sulfur, 2 parts by weight of a vulcanization accelerator (CZ) and 0.5 parts by weight of a vulcanization accelerator (DPG) were added to each of the above rubber compositions and vulcanized at 160 DEG C for 25 minutes to prepare rubber specimens.

1) Mooney viscosity

The Mooney viscosity (ML1 + 4) for each rubber specimen was measured with a Monsanto MV2000E using a large rotor at 100 ° C with rotor speed 2 ± 0.02 rpm.

2) tensile strength (kg · f / cm ² ), 300% modulus (300% modulus, kg · f / cm ² )

Each vulcanized rubber composition was vulcanized at 150 캜 for 90 minutes, and the tensile strength of the vulcanized product, the modulus at 300% elongation (M-300%) and elongation at break were measured according to ASTM D412.

3) Viscoelasticity (Tan? @ 60 ° C)

The tan δ physical properties, which are most important for low fuel efficiency characteristics, were measured by DMTS 500N, Gabo, Germany. The viscoelasticity (tan δ) at 60 ° C was measured at a frequency of 10 Hz, a prestrain of 5% and a dynamic strain of 3%. At this time, the higher the tan delta value, the lower the hysteresis loss and the better the low rolling resistance, that is, the excellent fuel economy.

division Example 1 Example 2 Comparative Example ML1 + 4
(FMB: Final Master batch 76.5 78.0 57.3 Tensile index M-300% 112 106 100 The tensile strength 112 112 100 Elongation 105 115 100 DMTS Index tanδ @ 60 ° C 112 100 100

As shown in Table 2, the rubber specimens prepared using the modified butadiene polymers of Examples 1 and 2 prepared using the modifier according to one embodiment of the present invention exhibited a Mooney viscosity characteristic, a tensile characteristic and a viscoelastic characteristic It was confirmed that the rubber specimens were superior to the rubber specimens prepared using the butadiene polymers of this comparative example.

Specifically, the rubber specimens prepared using the modified butadiene polymers of Examples 1 and 2 prepared using the modifier according to one embodiment of the present invention were compared with the rubber specimens prepared using the unmodified butadiene polymer of the comparative example It was confirmed that the tan δ value at 60 ° C was equal or greatly decreased (index improved) while the modulus, tensile strength and elongation at 300% compared with the mode greatly increased. This is a result indicating that the modified butadiene polymer produced using the modifier according to an embodiment of the present invention has excellent tensile properties, excellent rolling resistance (RR) characteristics, and high fuel efficiency.

Claims (19)

A modifier represented by the following formula (1):
[Chemical Formula 1]

In Formula 1,
R ₁ , R ₄ and R ₅ independently of each other are substituted with one or more substituents selected from the group consisting of a linear or branched alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, and an aryl group having 6 to 30 carbon atoms, Is a monovalent hydrocarbon group of 1 to 20 carbon atoms,
R ² is a linear or branched alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, and an aryl group having 6 to 30 carbon atoms and having 1 to 20 carbon atoms which is unsubstituted or substituted with at least one substituent Is a hydrocarbon group,
R ₃ is a linking group represented by the following formula (2) or (3)
(2)

(3)

In Formula 2 or Formula 3,
R < ₆ > is a linear or branched alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, and an aryl group having 6 to 30 carbon atoms and having 1 to 20 carbon atoms A monovalent hydrocarbon group,
R ₇ to R ₁₀ are each independently a divalent hydrocarbon group of 1 to 20 carbon atoms which is unsubstituted or substituted with a linear or branched alkyl group having 1 to 20 carbon atoms.
The method according to claim 1,
In the above Chemical Formulas 1 to 3,
R ₁ , R ₄ and R ₅ are each independently an alkyl group having 1 to 6 carbon atoms which is unsubstituted or substituted with a linear or branched alkyl group having 1 to 5 carbon atoms,
R ₂ is an alkylene group having 1 to 6 carbon atoms,
R ₆ is an alkyl group having 1 to 6 carbon atoms,
And R ₇ to R ₁₀ are alkylene groups having 1 to 6 carbon atoms.
The method according to claim 1,
Wherein the modifier represented by the formula (1) is represented by the following formula (4), (5) or (6)
[Chemical Formula 4]

[Chemical Formula 5]

[Chemical Formula 6]

The method according to claim 1,
Wherein the modifier is a modifier for a conjugated diene-based polymer.
Reacting a compound represented by the following formula (7) with an alkyl ketone compound to prepare a compound represented by the following formula (8);
A method for producing a modified agent according to claim 1, which comprises reacting a compound represented by the formula (8) and a compound represented by the following formula (9)
(7)

[Chemical Formula 8]

[Chemical Formula 9]

[Chemical Formula 1]

In the above formulas (1), (7) to (9)
R ₁ , R ₄ and R ₅ independently of each other are substituted with one or more substituents selected from the group consisting of a linear or branched alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, and an aryl group having 6 to 30 carbon atoms, Is a monovalent hydrocarbon group of 1 to 20 carbon atoms,
R ₂ is a linear or branched alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, and an aryl group having 6 to 30 carbon atoms and having 1 to 20 carbon atoms which is unsubstituted or substituted with at least one substituent Is a hydrocarbon group,
A is Cl or Br,
R ₁₁ is represented by the following general formula (10) or (11)
[Chemical formula 10]

(11)

In Formula 10 or Formula 11,
R < ₆ > is a linear or branched alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, and an aryl group having 6 to 30 carbon atoms and having 1 to 20 carbon atoms A monovalent hydrocarbon group,
R ₇ to R ₁₀ are each independently a divalent hydrocarbon group of 1 to 20 carbon atoms which is unsubstituted or substituted with a linear or branched alkyl group having 1 to 20 carbon atoms.
The method of claim 5,
In the above formulas (1) and (7) to (11)
R ₁ , R ₄ and R ₅ are each independently an alkyl group having 1 to 6 carbon atoms which is unsubstituted or substituted with a linear or branched alkyl group having 1 to 5 carbon atoms,
R ₂ is an alkylene group having 1 to 6 carbon atoms,
R ₆ is an alkyl group having 1 to 6 carbon atoms,
And R ₇ to R ₁₀ are alkylene groups having 1 to 6 carbon atoms.
The method of claim 5,
Wherein the compound represented by Formula 7 and the alkyl ketone compound are reacted at a molar ratio of 1: 1 to 1: 2.
The method of claim 5,
Wherein the compound represented by the formula (8) and the compound represented by the formula (9) are reacted in a molar ratio of 1: 1 to 1: 2.
The method of claim 5,
Wherein the first reaction is carried out at a temperature ranging from 110 ° C to 160 ° C.
The method of claim 5,
Wherein the second reaction is carried out at a temperature ranging from 20 캜 to 60 캜.
A modified conjugated diene polymer comprising a functional group derived from a modifier represented by the following formula
[Chemical Formula 1]

In Formula 1,
R ₁ , R ₄ and R ₅ independently of each other are substituted with one or more substituents selected from the group consisting of a linear or branched alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, and an aryl group having 6 to 30 carbon atoms, Is a monovalent hydrocarbon group of 1 to 20 carbon atoms,
R ₂ is a linear or branched alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, and an aryl group having 6 to 30 carbon atoms and having 1 to 20 carbon atoms which is unsubstituted or substituted with at least one substituent Is a hydrocarbon group,
R ₃ is a linking group represented by the following formula (2) or (3)
(2)

(3)

In Formula 2 or Formula 3,
R < ₆ > is a linear or branched alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, and an aryl group having 6 to 30 carbon atoms and having 1 to 20 carbon atoms A monovalent hydrocarbon group,
R ₇ to R ₁₀ are each independently a divalent hydrocarbon group of 1 to 20 carbon atoms which is unsubstituted or substituted with a linear or branched alkyl group having 1 to 20 carbon atoms.
The method of claim 11,
The modified conjugated diene polymer represented by the following general formula (4), (5) or (6)
[Chemical Formula 4]

[Chemical Formula 5]

[Chemical Formula 6]

The method of claim 11,
Wherein the polymer has a number average molecular weight of 100,000 g / mol to 700,000 g / mol.
The method of claim 11,
Wherein the polymer has a molecular weight distribution (Mw / Mn) of 1.05 to 5. < Desc / Clms Page number 24 >
The method of claim 11,
Wherein said polymer has a value of -S / R (stress / relaxation) at 100 DEG C of at least 0.7.
1) polymerizing a conjugated diene monomer in a hydrocarbon solvent in the presence of a catalyst composition containing a lanthanide-based rare-earth element-containing compound to prepare an active polymer having an organic metal bonded thereto; And
2) A process for producing the modified conjugated diene polymer according to claim 11, which comprises reacting the active polymer with a modifier represented by the following formula
[Chemical Formula 1]

In Formula 1,
R ₁ , R ₄ and R ₅ independently of each other are substituted with one or more substituents selected from the group consisting of a linear or branched alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, and an aryl group having 6 to 30 carbon atoms, Is a monovalent hydrocarbon group of 1 to 20 carbon atoms,
R ₂ is a linear or branched alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, and an aryl group having 6 to 30 carbon atoms and having 1 to 20 carbon atoms which is unsubstituted or substituted with at least one substituent Is a hydrocarbon group,
R ₃ is a linking group represented by the following formula (2) or (3)
(2)

(3)

In Formula 2 or Formula 3,
R < ₆ > is a linear or branched alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, and an aryl group having 6 to 30 carbon atoms and having 1 to 20 carbon atoms A monovalent hydrocarbon group,
R ₇ to R ₁₀ are each independently a divalent hydrocarbon group of 1 to 20 carbon atoms which is unsubstituted or substituted with a linear or branched alkyl group having 1 to 20 carbon atoms.
18. The method of claim 16,
Wherein the catalyst composition is used in an amount such that the amount of the lanthanum-based rare-earth element-containing compound is from 0.1 mmol to 0.5 mmol based on 100 g of the conjugated diene-based monomer.
18. The method of claim 16,
Wherein the lanthanoid rare earth element-containing compound comprises a neodymium compound represented by the following formula (12): < EMI ID =
[Chemical Formula 12]

In Formula 12,
R _a to R _c are each independently hydrogen or a linear or branched alkyl group having 1 to 12 carbon atoms,
Provided that R &_lt; _a > to R &_lt; _c > are not simultaneously hydrogen.
18. The method of claim 16,
Wherein the modifier is used in a proportion of 0.5 to 20 mol based on 1 mol of the lanthanum-based rare earth element-containing compound.