KR20170138905A - Skin Cleansing Composition - Google Patents
Skin Cleansing Composition Download PDFInfo
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- KR20170138905A KR20170138905A KR1020160077018A KR20160077018A KR20170138905A KR 20170138905 A KR20170138905 A KR 20170138905A KR 1020160077018 A KR1020160077018 A KR 1020160077018A KR 20160077018 A KR20160077018 A KR 20160077018A KR 20170138905 A KR20170138905 A KR 20170138905A
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- oil
- composition
- skin cleanser
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- 239000000203 mixture Substances 0.000 title claims abstract description 80
- 239000000344 soap Substances 0.000 claims abstract description 46
- 239000007788 liquid Substances 0.000 claims abstract description 41
- 235000015112 vegetable and seed oil Nutrition 0.000 claims abstract description 36
- 239000008158 vegetable oil Substances 0.000 claims abstract description 36
- 239000002888 zwitterionic surfactant Substances 0.000 claims abstract description 6
- 239000004094 surface-active agent Substances 0.000 claims description 27
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 25
- 229960003237 betaine Drugs 0.000 claims description 18
- -1 Carboxymethyl betaine Chemical compound 0.000 claims description 16
- 239000002280 amphoteric surfactant Substances 0.000 claims description 15
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 12
- 239000003240 coconut oil Substances 0.000 claims description 7
- 235000019864 coconut oil Nutrition 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
- 239000004615 ingredient Substances 0.000 claims description 4
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 3
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims description 3
- 229940073507 cocamidopropyl betaine Drugs 0.000 claims description 3
- 238000006386 neutralization reaction Methods 0.000 claims description 3
- 239000003921 oil Substances 0.000 claims description 3
- 235000019198 oils Nutrition 0.000 claims description 3
- KKMIHKCGXQMFEU-UHFFFAOYSA-N 2-[dimethyl(tetradecyl)azaniumyl]acetate Chemical compound CCCCCCCCCCCCCC[N+](C)(C)CC([O-])=O KKMIHKCGXQMFEU-UHFFFAOYSA-N 0.000 claims description 2
- 235000019482 Palm oil Nutrition 0.000 claims description 2
- 235000019483 Peanut oil Nutrition 0.000 claims description 2
- 235000019484 Rapeseed oil Nutrition 0.000 claims description 2
- 235000019774 Rice Bran oil Nutrition 0.000 claims description 2
- 235000019485 Safflower oil Nutrition 0.000 claims description 2
- 235000019486 Sunflower oil Nutrition 0.000 claims description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 2
- 235000019498 Walnut oil Nutrition 0.000 claims description 2
- 239000000908 ammonium hydroxide Substances 0.000 claims description 2
- 235000005687 corn oil Nutrition 0.000 claims description 2
- 239000002285 corn oil Substances 0.000 claims description 2
- 235000012343 cottonseed oil Nutrition 0.000 claims description 2
- 239000002385 cottonseed oil Substances 0.000 claims description 2
- 229940094506 lauryl betaine Drugs 0.000 claims description 2
- 239000000944 linseed oil Substances 0.000 claims description 2
- 235000021388 linseed oil Nutrition 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 claims description 2
- 239000003346 palm kernel oil Substances 0.000 claims description 2
- 235000019865 palm kernel oil Nutrition 0.000 claims description 2
- 239000002540 palm oil Substances 0.000 claims description 2
- 239000000312 peanut oil Substances 0.000 claims description 2
- 239000008165 rice bran oil Substances 0.000 claims description 2
- 235000005713 safflower oil Nutrition 0.000 claims description 2
- 239000003813 safflower oil Substances 0.000 claims description 2
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000008159 sesame oil Substances 0.000 claims description 2
- 235000011803 sesame oil Nutrition 0.000 claims description 2
- 235000012424 soybean oil Nutrition 0.000 claims description 2
- 239000003549 soybean oil Substances 0.000 claims description 2
- 239000002600 sunflower oil Substances 0.000 claims description 2
- 239000008170 walnut oil Substances 0.000 claims description 2
- UAUDZVJPLUQNMU-UHFFFAOYSA-N Erucasaeureamid Natural products CCCCCCCCC=CCCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-UHFFFAOYSA-N 0.000 claims 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 claims 1
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 claims 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 3
- 239000003599 detergent Substances 0.000 description 19
- 239000003795 chemical substances by application Substances 0.000 description 13
- 239000000047 product Substances 0.000 description 11
- 238000004517 catalytic hydrocracking Methods 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 10
- 238000007127 saponification reaction Methods 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 230000002421 anti-septic effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229940099404 potassium cocoate Drugs 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229940057950 sodium laureth sulfate Drugs 0.000 description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 2
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000013040 bath agent Substances 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 235000013355 food flavoring agent Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000008169 grapeseed oil Substances 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions
- C11D11/0005—Special cleaning or washing methods
- C11D11/0011—Special cleaning or washing methods characterised by the objects to be cleaned
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions
- C11D11/0094—Process for making liquid detergent compositions, e.g. slurries, pastes or gels
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/08—Liquid soap, e.g. for dispensers; capsuled
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/38—Products in which the composition is not well defined
-
- C11D2111/10—
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
Description
본 발명은 식물성 오일을 비누화한 천연 액상 비누를 함유하는 피부 세정제 조성물에 관한 것으로서, 보다 상세하게는 저온에서도 제품 투명성을 유지하며, 식물성 오일을 함유하는 다른 세정제 조성물과는 달리 우수한 점도를 갖고 있어 사용 편리성이 개선된 피부 세정제 조성물에 관한 것이다.The present invention relates to a skin cleanser composition containing a natural liquid soap having a saponified vegetable oil, and more particularly to a cleanser composition which maintains product transparency even at a low temperature and has excellent viscosity unlike other detergent compositions containing vegetable oils. To a skin cleanser composition having improved convenience.
최근, 피부와 환경에 안전한 천연 성분에 대한 관심 증가로 종래에 사용하고 있는 SLS(sodium lauryl sulfate) 또는 SLES(sodium laureth sulfate) 등의 합성 계면활성제를 함유하지 않은, 피부 자극을 완화하고 친환경적인 천연 성분을 주재료로 한 세정 제품들이 증가하고 있다.In recent years, there has been a growing interest in safe natural ingredients for skin and environment, and it has been known that it does not contain conventional synthetic surfactants such as SLS (sodium lauryl sulfate) or SLES (sodium laureth sulfate) The number of cleaning products based on the ingredient is increasing.
이러한 변화에 따라 최근 식물성 오일을 비누화하여 만든 천연 미용 비누와 이러한 기술을 이용하여 만든 천연 액상 미용 비누를 함유한 제품이 속속 출시되고 있으며, 이러한 천연 액상 제품은 투명한 성상에 대한 선호도가 높은 편이다.As a result of these changes, products containing natural beauty soap made by saponifying vegetable oil and natural liquid soap made by using such technology are being continuously released, and these natural liquid products have a high preference for transparent properties.
하지만, 이러한 천연 액상 미용 비누를 함유한 제품은 저온에서 동결되기 쉽고, 저온 저장시 석출되어 안정성이 저하되는 단점이 있다. 또한, 천연 성분으로 만들어 점도가 낮아 묽은 경우에는 사용시 흐름성이 강하여 손실량이 많아 사용상 및 경제상 불편함이 있고, 점도를 올리면 투명한 성상을 유지하는데 어려움이 있다. 더욱이, 점증제를 이용하여 점도를 과하게 높이는 경우 저온에서의 흐름성이 저해되어 온도가 낮은 환경에서 사용시 겔링(뭉침현상)되어 펌프로 사용하는 경우 불편한 점이 있다.However, such a product containing such a natural liquid cosmetic soap tends to be frozen at a low temperature, and has a disadvantage in that stability is deteriorated due to precipitation at low temperature storage. In addition, when the viscosity is low due to the low viscosity of the natural component, it is difficult to maintain transparency when the viscosity is increased. In addition, when the viscosity is excessively increased by using an aging agent, the flowability at low temperature is inhibited, and when the aging agent is used in a low temperature environment, the agglomeration occurs, which is inconvenient when used as a pump.
대한민국 등록특허 제1554234호는 합성 계면활성제나 비누분을 함유하지 않으면서 지방산의 함량이 높은 투명 액상 베이스의 식물성 오일을 함유하는 세정제 조성물을 개시하고 있는데, 10℃까지의 온도 범위에서 제품 투명성을 유지하고 있으며, 검화 시간을 30분 이내로 단축시킴으로써 식물성 오일의 보습력을 유지시킨 것이 특징이다. 그러나, 검화시간이 짧아 충분히 비누화되지 않고 잔존하는 염기성 물질들에 대한 검증이 이루어지지 않았으며, 점도 또한 낮아 사용 편리성이 떨어지고, 10℃ 이하, 즉 0℃ 내지 10℃까지에서의 제품 투명성은 유지되지 않아 제품 사용에 있어 한계점을 가지고 있다.Korean Patent No. 1554234 discloses a detergent composition containing a vegetable oil based on a transparent liquid base which does not contain a synthetic surfactant or soap component and has a high content of fatty acid. And the moisture retention time of the vegetable oil is maintained by shortening the saponification time to 30 minutes or less. However, since the saponification time is short, the saponification is not sufficiently performed and the basic materials remaining are not verified. Also, the viscosity is low and the ease of use is low, and the product transparency at 10 ° C or less, And it has a limitation in using the product.
또한, 대한민국 공개특허 제2012-0058721호는 식물성 오일을 함유하는 저자극 고보습 세정제 조성물에 관한 것으로, 합성 계면활성제나 비누분을 함유하지 않고 전체 지방산 중 탄소수 18개 이상인 지방산이 60중량% 이상인 식물성 오일을 검화하여 함유함으로써 피부 자극이 적으며, 보습력, 세정력, 항균성이 우수한 특징이 있지만, 보조 계면활성제를 사용하지 않고, 검화 비누액상과 폴리올만 사용하였기 때문에 저온 안정성이 떨어지며, 점도 또한 낮은 단점이 있다.Korean Patent Publication No. 2012-0058721 discloses a low stimulus, high moisture cleansing composition containing a vegetable oil, which comprises a synthetic vegetable oil containing no synthetic surfactant or soap component and having a fatty acid having a carbon number of 18 or more in the total fatty acids of 60 wt% However, since the saponification soap liquid phase and polyol are used without using an auxiliary surfactant, the low temperature stability is lowered and the viscosity is also lowered. have.
이러한 배경하에, 본 발명자들은 식물성 오일을 비누화한 액상 비누를 함유하는 조성물로서 저온에서도 제품 투명성을 유지하며 저온 흐름성이 우수할 뿐만 아니라 기포 품질도 우수하며 너무 묽지 않은 정도를 유지하는 세정제 조성물의 개발에 관하여 연구를 수행하였으며, 이에 식물성 오일을 비누화한 액상 비누와 양쪽이온성 계면활성제의 비율을 조절함으로써 상기 특성을 나타내는 세정제 조성물을 완성하기에 이르렀다.Under these circumstances, the present inventors have developed a detergent composition which maintains product transparency even at a low temperature and is excellent in low-temperature flowability as well as in bubble quality and maintains a degree of not so low, as a composition containing a liquid soap having saponified vegetable oil And a cleaning agent composition having the above characteristics was completed by controlling the ratio of the liquid soap and the amphoteric surfactant in which the vegetable oil was saponified.
본 발명의 목적은 식물성 오일을 비누화한 액상 비누를 포함하는 피부 세정제 조성물로서, 전체 조성물에 대하여 a) 식물성 오일을 비누화한 액상 비누 5 내지 20중량% 및 b) 양쪽이온성 계면활성제 2 내지 18중량%를 포함하며, 를 만족하는 피부 세정제 조성물을 제공하는 것이다.An object of the present invention is to provide a skin cleanser composition comprising a liquid soap having a saponified vegetable oil, comprising a) 5 to 20% by weight of a liquid soap saponified with vegetable oil and b) 2 to 18% by weight of a zwitterionic surfactant %, By weight based on the total weight of the composition.
본 발명의 다른 목적은 상기 피부 세정제 조성물의 제조방법을 제공하는 것이다.Another object of the present invention is to provide a method for producing the skin cleanser composition.
상기의 목적을 달성하기 위한 하나의 양태로서, 본 발명은 (a) 식물성 오일을 비누화한 액상 비누 및 (b) 양쪽이온성 계면활성제를 일정 비율로 포함하는 피부 세정제 조성물을 제공한다.In one aspect, the present invention provides a skin cleanser composition comprising (a) a liquid soap having saponified vegetable oil and (b) a zwitterionic surfactant in a certain ratio.
본 발명의 구체적인 일 실시예에 의하면, 본 발명은 조성물 전체 중량에 대하여, (a) 식물성 오일을 비누화한 액상 비누 5 내지 20중량% 및 (b) 양쪽이온성 계면활성제 2 내지 18중량%를 포함하며, 상기 (a)와 (b)의 비가 를 만족하는 피부 세정제 조성물을 제공한다.According to a specific embodiment of the present invention, the present invention provides a composition comprising (a) 5 to 20% by weight of a liquid soap saponified with vegetable oil, and (b) 2 to 18% by weight of a zwitterionic surfactant, based on the total weight of the composition , And the ratio of (a) and (b) By weight of the skin cleanser composition.
상기 식물성 오일은 특별히 이에 제한되지는 않지만, 팜유, 팜핵유, 낙화생유, 아마인유, 홍화유, 해바라기유, 콩기름, 옥수수기름, 참기름, 목화씨기름, 쌀겨기름, 유채씨 오일, 올리브 오일, 피마자 오일, 포도씨 오일, 호두 오일 및 코코넛 오일로 이루어진 군으로부터 선택되는 1종 이상이며, 구체적으로 이 중에서도 본 발명의 세정제 조성물은 코코넛 오일을 비누화한 액상 비누를 포함할 수 있다.The vegetable oil may be selected from the group consisting of palm oil, palm kernel oil, peanut oil, linseed oil, safflower oil, sunflower oil, soybean oil, corn oil, sesame oil, cottonseed oil, rice bran oil, rapeseed oil, Grape seed oil, walnut oil, and coconut oil. Specifically, the detergent composition of the present invention may include a liquid soap in which coconut oil is saponified.
본 발명의 피부 세정제 조성물에 사용되는 식물성 오일을 비누화한 액상 비누(a)는 예를 들어, 세정제 조성물 전체중량에 대하여 5 내지 20중량% 함유될 수 있고, 구체적으로 7 내지 15중량% 함유될 수 있다.The liquid soap (a) obtained by saponifying the vegetable oil used in the skin cleanser composition of the present invention may be contained in an amount of, for example, 5 to 20% by weight, specifically 7 to 15% by weight, based on the total weight of the detergent composition have.
상기 범위로 액상 비누가 함유될 때 본 발명의 세정제 조성물은 세정력을 유지하면서도 저온에서의 제품 투명도를 유지하며, 사용하기에 적절한 점도를 가지는데, 상기 액상 비누의 함량이 피부 세정제 조성물 총 중량 대비 5중량% 미만인 경우에는 세정력이 저하될 수 있으며, 20중량%를 초과하는 경우에는 점도가 과하게 높아져 저온에서의 흐름성이 없어 저온에서의 사용시 펌핑이 어렵거나 피부가 건조해질 수 있다.When the liquid soap is contained in the above range, the detergent composition of the present invention maintains the product transparency at a low temperature while maintaining the detergency, and has a viscosity suitable for use, wherein the content of the liquid soap is 5% When the amount is less than 10% by weight, the washing power may be lowered. When the amount is more than 20% by weight, the viscosity becomes excessively high and the flowability at low temperature is low.
본 발명의 세정제 조성물에 사용되는 상기 양쪽이온성 계면활성제(b)는 특별히 이에 제한되지는 않지만, 베타인형 계면활성제, 설테인형 계면활성제 또는 이미다졸린계 양성 계면활성제를 들 수 있다. 본 발명의 피부 세정제 조성물에 사용되는 양쪽이온성 계면활성제는 세정시의 기포량 및 기포 품질, 세정제 조성물의 점도 개선의 관점에서 베타인형 계면활성제(b1) 또는 설테인형 계면활성제(b2)를 사용할 수 있다. 구체적으로 베타인형 계면활성제 및 설테인형 계면활성제를 함께 사용할 수 있다.The amphoteric surfactant (b) used in the detergent composition of the present invention includes, but is not limited to, a betaine type surfactant, a sulphate type surfactant or an imidazoline type amphoteric surfactant. The amphoteric surfactant to be used in the skin cleanser composition of the present invention may be a betaine surfactant (b1) or a sulptone surfactant (b2) in view of the amount of bubbles and the quality of the foam during cleaning and the viscosity of the detergent composition have. Specifically, beta-type surfactant and sul tetan-type surfactant can be used together.
본 발명의 세정제 조성물에 사용되는 베타인형 계면활성제로는 특별히 이에 제한되지는 않지만, 코카미도프로필베타인, 라우라미도프로필베타인, 라우릴 베타인, 코코-베타인, 미리스틸베타인, 코코디메틸카복시메틸베타인, 라우릴디메틸카복시메틸베타인, 라우릴디메틸-알파-카복시에틸베타인, 세틸디메틸-카복시메틸베타인, 라우릴-비스-(2-하이드록시에틸)카복시메틸베타인, 스테아릴-비스-(2-하이드록시프로필)카복시메틸베타인, 올레일디메틸-감마-카복시프로필베타인, 라우릴-비스-(2-하이드록시프로필)알파-카복시에틸베타인, 코코디메틸설포프로필베타인, 스테아릴디메틸설포프로필베타인, 코코아미도디메틸카복시메틸베타인, 코코아미도디메틸설포프로필베타인, 라우릴아미도디메틸카복시메틸베타인, 세틸아미도디메틸카복시메틸베타인 및 스테아릴아미도디메틸설포프로필베타인으로 이루어진 군으로부터 선택되는 하나 이상을 들 수 있다.The beta-type surfactants used in the detergent compositions of the present invention include, but are not limited to, cocamidopropyl betaine, lauraimidopropyl betaine, lauryl betaine, coco-betaine, myristyl betaine, Carboxymethylbetaine, lauryldimethylcarboxymethylbetaine, lauryldimethyl-alpha-carboxyethylbetaine, cetyldimethyl-carboxymethylbetaine, lauryl-bis- (2-hydroxyethyl) Carboxypropyl betaine, lauryl-bis- (2-hydroxypropyl) alpha-carboxyethyl betaine, oleic dimethyl-gamma- But are not limited to, betaine, stearyldimethylsulfopropylbetaine, cocoamidomethyldimethylcarboxymethylbetaine, cocoamidodimethylsulfopropylbetaine, laurylamidodimethylcarboxymethylbetaine, cetylamido dimethylcarboxymethylbeta Phosphorus, and stearylamido dimethyl sulfopropyl betaine.
본 발명의 세정제 조성물에 사용되는 설테인형 계면활성제로는 특별히 이에 제한되지는 않지만, 코카미도프로필하이드록시설테인, 코코-하이드록시설테인, 코코-설테인, 에루카미도프로필하이드록시설테인, 하이드록시설테인, 라우라미도프로필하이드록시설테인, 라우릴하이드록시설테인, 라우릴설테인, 메톡시신나미도프로필하이드록시설테인, 마이리스타미도프로필하이드록시설테인, 올레아미도프로필하이드록시설테인 및 탈로우아미도프로필하이드록시설테인으로 이루어진 군으로부터 선택되는 하나 이상을 들 수 있다. Sulphate-type surfactants for use in the detergent compositions of the present invention include, but are not limited to, cocamidopropyl hydroxystane, coco-hydroxystane, coco-seltain, Hydrocracking agent, hydrocracking agent, hydrocracking agent, hydrocracking agent, hydrocracking agent, hydrocracking agent, hydrocracking agent, hydrocracking agent, hydrocracking agent, hydrocracking agent, A rock facility tenane, and a talloeliness profiled hydroxy facility tene.
본 발명의 세정제 조성물에 사용되는 양쪽이온성 계면활성제는 예를 들어 세정제 조성물 전체 중량에 대하여 2 내지 18중량% 함유될 수 있고, 구체적으로 6 내지 13중량% 함유될 수 있다. The amphoteric surfactant used in the detergent composition of the present invention may be contained, for example, in an amount of 2 to 18% by weight, specifically 6 to 13% by weight, based on the total weight of the detergent composition.
본 발명자들은 본 발명의 피부 세정제 조성물에서, 상기 (a) 식물성 오일을 비누화한 액상 비누와 (b) 양쪽이온성 계면활성제의 함량을 특정 범위의 함량과 비율로 혼합하는 경우에 점도 형성이 양호함을 확인하였으며(표 2), 이때, (b) 양쪽이온성 계면활성제의 함량에 대한 (a) 식물성 오일을 비누화한 액상 비누의 비율, 즉, 값은 0.75 내지 1 사이의 값을 가졌다(표 1). The inventors of the present invention found that in the skin cleanser composition of the present invention, when the content of the liquid soap (a) saponified vegetable oil and the content of the amphoteric surfactant (b) are mixed in a specific range of content and ratio, (B) the ratio of the liquid soap obtained by saponifying the vegetable oil with respect to the content of the amphoteric surfactant, that is, Values were between 0.75 and 1 (Table 1).
본 발명의 구체적인 일 실시예에 의하면, 상기 양쪽이온성 계면활성제 중 베타인형 계면활성제의 함량을 세정제 조성물 전체 중량 대비 1 내지 10중량%, 구체적으로 4 내지 8중량% 되도록 포함시키고, 상기 양쪽이온성 계면활성제 중 설테인형 계면활성제의 함량을 세정제 조성물 전체 중량 대비 1 내지 8중량%, 구체적으로 2 내지 5중량% 되도록 포함시킨 피부 세정제 조성물을 제공한다. According to one embodiment of the present invention, the content of the betaine surfactant in the amphoteric surfactant is 1 to 10% by weight, specifically 4 to 8% by weight based on the total weight of the detergent composition, Wherein the content of the surfactant in the surfactant is in the range of 1 to 8 wt%, more preferably 2 to 5 wt%, based on the total weight of the detergent composition.
특히, 점도가 현저히 개선된 피부 세정제 조성물을 제조하기 위해, 상기 식물성 오일을 비누화한 액상 비누와 양쪽이온성 계면활성제의 함량비를 조절하여 본 결과, 식물성 오일을 비누화한 액상 비누와 양쪽이온성 계면활성제의 함량비가 0.75:1 ~ 1:1, 구체적으로 0.8:1 ~ 0.95:1 사이에 있을 때 점도가 현저히 개선됨을 발견하였으며, 상기 양쪽이온성 계면활성제는 베타인형 계면활성제와 설테인형 계면활성제가 동시에 사용될 때 세정제 조성물의 점도가 크게 개선됨을 알 수 있었다. 이때, 베타인형 계면활성제와 설테인형 계면활성제의 비는 특별히 이에 제한되지는 않지만, 1:0.1 내지 1:8일 수 있고, 구체적으로 1:0.5 내지 1:2일 수 있다.Particularly, in order to prepare a skin cleanser composition having a remarkably improved viscosity, the content ratio of the saponified liquid soap and the amphoteric surfactant was adjusted, and as a result, the liquid soap having a saponified vegetable oil and the both- It was found that the viscosity was remarkably improved when the content ratio of the active agent was in the range of 0.75: 1 to 1: 1, specifically 0.8: 1 to 0.95: 1. The amphoteric surfactant was a betaine surfactant and a sulptone surfactant It was found that the viscosity of the detergent composition was greatly improved when used at the same time. In this case, the ratio of the betaine-type surfactant to the seletane-type surfactant is not particularly limited, but may be from 1: 0.1 to 1: 8, and more specifically from 1: 0.5 to 1: 2.
상기 식물성 오일을 비누화한 액상 비누가 상기 범위에 미치지 못하는 경우, 즉 양쪽이온성 계면활성제의 중량에 대한 액상 비누의 비가 0.75 이하인 경우에는 저온에서 흐름성이 없고 겔링될 가능성이 있었으며, 상기 식물성 오일을 비누화한 액상 비누가 상기 범위보다 많이 함량된 경우, 즉 양쪽이온성 계면활성제의 중량에 대한 액상 비누의 비가 1 이상인 경우에는 점도 향상 효과가 저하되거나 저온에서의 제품 투명도가 저하될 수 있었다. When the liquid soap obtained by saponifying the vegetable oil does not reach the above range, that is, when the ratio of the liquid soap to the weight of the amphoteric surfactant is 0.75 or less, there is no flowability at low temperatures and there is a possibility of gelation. When the amount of the saponified liquid soap is greater than the above range, that is, when the ratio of the liquid soap to the weight of the amphoteric surfactant is 1 or more, the viscosity improving effect may be lowered or the product transparency at low temperature may be lowered.
본 발명에 따른 피부 세정제 조성물은 고온뿐만 아니라 저온에서 장시간 보관하여도 다른 물질이 석출되지 않고 투명한 성상을 나타내는 특징을 가지고 있는데, 본 발명에서 상기 저온은 10℃ 이하를 의미할 수 있으며, 본 발명자들은 본 발명에 따른 피부 세정제 조성물이 0℃에서도 투명한 성상을 나타내는 것을 확인하였다. 본 발명의 일 실시예에 의하면 0℃에서 4주일간 보관하여도 투명한 제형을 유지할 수 있음을 확인하였다.The skin cleanser composition according to the present invention is characterized not only by a high temperature but also by storage for a long time at a low temperature, but without being precipitated by other substances. In the present invention, the low temperature may mean 10 ° C or less, It was confirmed that the skin cleanser composition according to the present invention exhibited a transparent property even at 0 占 폚. According to one embodiment of the present invention, it was confirmed that even when stored at 0 ° C for 4 weeks, a clear formulation can be maintained.
본 발명에서 사용된 용어 "액상 비누"란, 식물성 오일을 비누화한 액체상의 비누를 의미하며, 비제한적인 예로 순비누분이 25% 이상, 수분 및 휘발성 물질 70% 이하인 비누를 의미한다. 이는 식물성 오일과 염기성 물질의 중화 반응으로 생성될 수 있으나, 이에 제한되지 않고, 당업계에서 식물성 오일의 비누화에 사용하는 방법을 이용하여 상기 액상 비누를 제조할 수 있다. As used herein, the term "liquid soap " means a liquid soap in which a vegetable oil is saponified, and as a non-limiting example, a soap having a net soap content of 25% or more, water and less than 70% of volatile substances. The liquid soap may be produced by a neutralization reaction between a vegetable oil and a basic substance, but the present invention is not limited thereto and the liquid soap may be produced by a method used in the art for saponification of a vegetable oil.
상기 액상 비누를 만드는 필수 구성 성분으로 포함되는 상기 식물성 오일은 코코넛 오일이 바람직하지만, 이 외에 전술한 바와 같은 다양한 종류의 식물로부터 추출된 오일들도 사용할 수 있다. The vegetable oil, which is an essential component for making the liquid soap, is preferably coconut oil. However, oils extracted from various kinds of plants as described above may also be used.
또한, 상기 중화 반응에 적합한 염기성 물질은 알칼리금속의 수산화물 또는 암모늄 수산화물 등을 들 수 있는데, 구체적으로 수산화칼륨, 수산화나트륨, 수산화암모늄 및 트리에탄올아민으로 이루어진 군으로부터 선택되는 하나 이상의 물질을 들 수 있으며, 더욱 구체적으로 수산화칼륨일 수 있다.Examples of the basic substance suitable for the neutralization reaction include alkali metal hydroxides and ammonium hydroxides. Specific examples thereof include at least one substance selected from the group consisting of potassium hydroxide, sodium hydroxide, ammonium hydroxide and triethanolamine. More specifically, it may be potassium hydroxide.
본 발명에서 사용된 용어 "점도"란, 유체의 점성의 정도를 나타내는 것으로, 예를 들어, 25℃에서 12rpm으로 60초간 스핀들(spindle) 3이 장착된 브룩필드(Brookfield) LVF 점도계를 이용하여 시료의 점도를 측정한 것을 의미할 수 있다. As used herein, the term "viscosity" refers to the degree of viscosity of a fluid. For example, a Brookfield LVF viscometer equipped with a spindle 3 for 60 seconds at 25 [deg. Of the viscosity of the resin.
일반적으로 식물성 오일을 재료로 한 피부 세정제 조성물은 점도가 너무 낮아 묽은 경우에는 사용시 흐름성이 강하여 손실량이 많으므로 사용상 및 경제상 불편함이 있고, 점증제를 사용하여 점도를 너무 올리는 경우에는 사용감이 좋지 않고 거품이 빨리 나지 않는 불편함이 있으며, 제품 투명도가 저하된다. In general, a skin cleansing composition comprising a vegetable oil is too low in viscosity to be used, and when it is diluted, it has high flowability due to its high flow loss, resulting in inconvenience in use and economy. When the viscosity is increased too much by using an increasing agent, There is inconvenience that the foam does not come out quickly, and the transparency of the product is lowered.
본 발명에 따른 피부 세정제 조성물은 상기의 단점을 극복한 피부 세정제 조성물로서 우수한 점도를 갖고 있는 것이 특징인데, 본 발명에 따른 피부 세정제 조성물의 점도는 상기와 같은 조건의 브룩필드 점도계를 이용하여 측정하는 경우, 1000 cps 이상의 점도를 나타내는 것이 바람직하며, 1000 내지 3000 cps가 보다 바람직하며, 1500 내지 2500 cps의 점도를 갖는 것이 가장 바람직하나 이에 제한되지 않는다. The skin cleanser composition according to the present invention is characterized by having excellent viscosity as a skin cleanser composition that overcomes the above disadvantages. The viscosity of the skin cleanser composition according to the present invention is measured using a Brookfield viscometer under the above conditions The viscosity is preferably 1000 cps or more, more preferably 1000 to 3000 cps, and most preferably 1500 to 2500 cps, but is not limited thereto.
본 발명의 피부 세정제 조성물은 세정제 조성물로서의 기본적인 물성 및 품질을 유지하기 위하여 세정제 조성물에 통상적으로 유용하게 사용되는 보습제, 색소, 킬레이팅제, 산화방지제, 살균제, 방부제, pH 조절제, 향료, 염료 및 염(Salt) 등으로 이루어진 군에서 선택된 어느 하나 이상을 추가로 포함할 수 있다.The skin cleanser compositions of the present invention can be used as a moisturizer, a chelating agent, an antioxidant, a bactericide, an antiseptic, a pH adjuster, a flavoring agent, a dye and a salt, which are conventionally usefully used in a detergent composition in order to maintain basic physical properties and quality as a detergent composition. (Salt), and the like.
본 발명에 따르는 세정제 조성물은 인체 세정 용도로 사용될 수 있다. 보다 구체적으로는 샴푸, 폼클렌져, 바디워시, 비누, 액체 세정료, 입욕제 또는 클렌징 오일 등에 사용될 수 있으나, 이에 한정되는 것은 아니다.The detergent composition according to the present invention may be used for human body cleaning purposes. More specifically, it may be, but not limited to, shampoo, foam cleanser, body wash, soap, liquid cleansing agent, bath agent or cleansing oil.
상기의 목적을 달성하기 위한 또 하나의 양태로서, 본 발명은 조성물 전체 중량에 대하여, (a) 식물성 오일을 비누화한 액상 비누 5 내지 20중량% 및 (b) 양쪽이온성 계면활성제 2 내지 18중량%를 혼합하는 단계로서, 상기 (a)와 (b)의 비가 를 만족하도록 하는 단계를 포함하는 피부 세정제 조성물의 제조방법을 제공한다.(A) 5 to 20% by weight of a liquid soap obtained by saponifying a vegetable oil, and (b) 2 to 18% by weight of an amphoteric surfactant as the weight of the composition. %, Wherein the ratio of (a) to (b) Of the skin cleanser composition. ≪ Desc / Clms Page number 5 >
본 발명의 피부 세정제 조성물은 저온에서도 제품 투명도가 유지되며, 저온에서의 흐름성이 좋고, 점도 또한 사용하기에 적합하여 식물성 오일을 비누화한 천연 액상 비누를 함유하는 액체 세정료 등에 널리 활용될 수 있다.The skin cleanser composition of the present invention can be widely used for liquid cleansing materials containing a natural liquid soap in which the transparency of the product is maintained even at a low temperature, the flowability at low temperatures is good, the viscosity is also suitable for use and the vegetable oil is saponified .
이하, 실시예를 통하여 본 발명의 구성 및 효과를 더욱 상세히 설명하고자 한다. 이들 실시예는 오로지 본 발명을 예시하기 위한 것일 뿐 본 발명의 범위가 이들 실시예에 의해 제한되는 것은 아니다.Hereinafter, the constitution and effects of the present invention will be described in more detail through examples. These embodiments are only for illustrating the present invention, and the scope of the present invention is not limited by these embodiments.
실시예Example 1 내지 4 및 1 to 4 and 비교예Comparative Example 1 내지 4 1 to 4
(1) 피부 세정용 조성물의 제조(1) Preparation of composition for skin cleansing
하기 표 1의 각 조성(단위: 중량%)에 따라 피부 세정용 조성물을 제조하였다. 하기 표 1에 기재된 실시예의 조성물을 플라스틱 용기에 상온(25℃)과 저온(0℃)에 2주일간 보관시킨 후 각 온도에서 시료의 성상을 확인하였으며, 그 후, 상온으로 유지하여 점도 결과를 얻었다. 하기 표 1에서 세정 성분인 액상 비누(a)로는 코코넛 오일을 수산화칼륨으로 비누화한 포타슘코코에이트(코코넛 오일 칼륨 비누)를 사용하였으며, 양쪽이온성 계면활성제(b)는 베타인형 계면활성제(b1)로 코카미도프로필베타인을, 설테인형 계면활성제(b2)로 라우릴하이드록시설테인을 사용하였다. 점도는 25℃에서 12 rpm으로 60초간 스핀들 3이 장착된 브룩필드 LVF 점도계를 이용하여 시료의 점도를 측정하였다.A skin cleansing composition was prepared according to each composition (unit: wt%) shown in Table 1 below. The composition of the examples shown in the following Table 1 was stored in a plastic container at room temperature (25 ° C) and low temperature (0 ° C) for 2 weeks, and then the properties of the sample were confirmed at each temperature, and then the viscosity was maintained at room temperature . In Table 1, potassium cocoate (coconut oil potassium soap) obtained by saponifying coconut oil with potassium hydroxide was used as the liquid soap (a) as a cleaning component, and amphoteric surfactant (b) was a betaine surfactant (b1) (B2), and laurylhydroxytane was used as the surfactant. The viscosities of the samples were measured using a Brookfield LVF viscometer equipped with a spindle 3 at 25 ° C and 12 rpm for 60 seconds.
(주성분을 a,b1,b2로 표시)ingredient
(The main components are denoted by a, b1, b2)
(코코넛 오일 칼륨 비누)a: Potassium cocoate
(Coconut oil potassium soap)
(2) 물성 비교(2) Comparison of physical properties
① 저온 투명도 평가① Evaluation of low-temperature transparency
상기 표 1의 각 조성(단위: 중량%)에 따라 피부 세정용 조성물을 플라스틱 용기에 담아 저온 0℃에 2주일간 보관시킨 후 각 온도에서 시료의 성상을 확인하였다. 아래와 같은 기준으로 평가하여 그 결과를 하기 표 2에 정리하였다.The composition for skin cleansing was stored in a plastic container at a low temperature of 0 ° C for 2 weeks according to each composition (unit: wt%) shown in Table 1, and then the properties of the sample were checked at each temperature. The results are shown in Table 2 below.
◎ : 저온 상태에서 완전 투명◎: completely transparent at low temperature
○ : 저온 상태에서 미세 현탁○: Micro-suspension at low temperature
△ : 저온 상태에서 반투명?: Translucent at low temperature
× : 저온 상태에서 완전 불투명X: Completely opaque at low temperature
② 저온 흐름성(유동성) 평가② Evaluation of low-temperature flowability (fluidity)
상기 표 1의 각 조성(단위: 중량%)에 따라 피부 세정용 조성물을 플라스틱 용기에 담아 저온 0℃에 2주일간 보관시킨 후 각 온도에서 용기를 뒤집어 유동성이 있는지 확인하였다. 아래와 같은 기준으로 평가하여 그 결과를 하기 표 2에 정리하였다.The composition for skin cleansing was placed in a plastic container according to each composition (unit: wt%) shown in Table 1, and stored at a low temperature of 0 ° C for 2 weeks. The results are shown in Table 2 below.
◎ : 저온 상태에서 뒤집었을 때 3초 이내 흐름 확인◎: Confirm flow within 3 seconds when reversed at low temperature
○ : 저온 상태에서 뒤집었을 때 5초 이내 흐름 확인○: Check the flow within 5 seconds when reversing at low temperature
△ : 저온 상태에서 뒤집었을 때 유동성 거의 없음Δ: Almost no fluidity when reversed at low temperature
× : 저온 상태에서 뒤집었을 때 유동성 완전히 없음(굳은 겔 상태)X: No fluidity when reversed at low temperature (hard gel state)
③ 점도 평가③ Viscosity evaluation
상기 표 1의 각 조성(단위: 중량%)에 따라 피부 세정용 조성물을 플라스틱 용기에 담아 상온(25℃)에서 점도 결과를 얻었다. 점도는 25℃에서 12 rpm으로 60초 동안 스핀들 3이 장착된 브룩필드 LVF 점도계를 사용하여 측정하였으며, 아래와 같은 기준으로 평가하여 그 결과를 하기 표 2에 정리하였다.The composition for skin cleansing was placed in a plastic container according to each composition (unit: wt%) in Table 1 to obtain viscosity results at room temperature (25 캜). The viscosity was measured using a Brookfield LVF viscometer equipped with a spindle 3 for 60 seconds at 25 rpm at 12 rpm and evaluated according to the following criteria and the results are summarized in Table 2 below.
◎ : 1000 ~ 3000 cps (사용하기에 적당)?: 1000 to 3000 cps (suitable for use)
○ : 3000 ~ 4000 cps (사용하기에 다소 점도가 높음)○: 3000 to 4000 cps (slightly higher viscosity for use)
△ : 4000 cps 이상 (사용하기에 점도 높음)?: 4000 cps or more (viscosity is high for use)
× : 1000 cps 이하 (사용하기에 점도 묽음)X: 1000 cps or less (viscosity is diluted for use)
1Comparative Example
One
2Comparative Example
2
3Comparative Example
3
4Comparative Example
4
상기 표 2에서 보는 바와 같이, 본 발명의 피부 세정제 조성물(실시예 1 내지 4)은 비교예 1 내지 4에 비해 저온(0℃)에서도 내용물의 성상이 투명하게 유지되며, 저온에서의 흐름성(유동성)도 있어 저온 상태에서 사용시 편리하고, 사용하기에 양호한 점도가 형성됨을 확인할 수 있었다.As shown in Table 2, the compositions of the skin cleanser compositions of the present invention (Examples 1 to 4) were transparent compared to Comparative Examples 1 to 4, Flowability), which is convenient at the time of use at a low temperature, and that a good viscosity is formed for use.
Claims (12)
a) 식물성 오일을 비누화한 액상 비누 5 내지 20중량%; 및
b) 양쪽이온성 계면활성제 2 내지 18중량%
를 포함하며, 을 만족하는 피부 세정제 조성물.A skin cleanser composition comprising a liquid soap having saponified vegetable oil, wherein, for the entire composition,
a) 5 to 20% by weight of a liquid soap saponified vegetable oil; And
b) 2 to 18% by weight of amphoteric surfactants,
/ RTI > By weight of the skin cleanser composition.
조성물 전체 중량에 대하여 (a) 식물성 오일을 비누화한 액상 비누 5 내지 20중량% 및 (b) 양쪽이온성 계면활성제 2 내지 18중량%를 혼합하는 단계로서, 상기 (a)와 (b)의 비가 를 만족하도록 하는 단계를 포함하는 피부 세정제 조성물의 제조방법.A method for producing a skin cleanser composition comprising a liquid soap in which a vegetable oil is saponified,
(A) 5 to 20% by weight of a saponified liquid soap of a vegetable oil and (b) 2 to 18% by weight of a zwitterionic surfactant, wherein the ratio of (a) to (b) Of the skin cleanser composition.
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KR20210027496A (en) * | 2018-07-31 | 2021-03-10 | 킴벌리-클라크 월드와이드, 인크. | Composition comprising an antibacterial enhancer comprising sultein and a method of increasing the antibacterial effect of the composition |
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