KR20170077517A - Modifying agent, preparation method of modified conjugated diene polymer using the modifying agent and modified conjugated diene polymer - Google Patents
Modifying agent, preparation method of modified conjugated diene polymer using the modifying agent and modified conjugated diene polymer Download PDFInfo
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- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/25—Incorporating silicon atoms into the molecule
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/22—Incorporating nitrogen atoms into the molecule
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
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Abstract
The present invention relates to a rubber modifier compound, a process for producing a modified conjugated diene polymer using the same, a modified conjugated diene polymer produced from the above process, a rubber composition comprising the modified conjugated diene polymer, and a tire produced from the rubber composition . The resulting rubber modifier compound can be used as a modifier for rubber modifiers, particularly as a modifier for conjugated diene polymers, and bonded to the conjugated diene polymer chain to easily introduce a filler-affinity functional group. Therefore, the modified conjugated diene polymer produced by using the rubber modifier compound may have an excellent affinity with a filler, and as a result, a work product (e.g., a tire) produced from a rubber composition containing the polymer may have a tensile strength, The abrasion resistance and the wet road surface resistance property can be excellent.
Description
The present invention relates to a rubber modifier compound, a process for producing a modified conjugated diene polymer using the same, a modified conjugated diene polymer produced from the above process, a rubber composition comprising the modified conjugated diene polymer, and a tire produced from the rubber composition .
In recent years, as a rubber material for a tire, a conjugated diene polymer having low rolling resistance, excellent abrasion resistance, tensile properties, and adjustment stability typified by a wet skid resistance has been required in recent years in response to demand for low fuel consumption in automobiles.
In order to reduce the rolling resistance of the tire, there is a method of reducing the hysteresis loss of the vulcanized rubber. As the evaluation index of such vulcanized rubber, repulsive elasticity of 50 DEG C to 80 DEG C, tan delta, Goodrich heat, and the like are used. That is, a rubber material having a large rebound resilience at that temperature or a small tan δ or Goodrich heating is preferable.
Natural rubbers, polyisoprene rubbers, polybutadiene rubbers, and the like are known as rubber materials having a small hysteresis loss, but these have a problem of low wet skid resistance. Recently, a conjugated diene (co) polymer such as styrene-butadiene rubber (hereinafter referred to as SBR) or butadiene rubber (hereinafter referred to as BR) is prepared by emulsion polymerization or solution polymerization and is used as a rubber for a tire . Of these, the greatest advantage of solution polymerization over emulsion polymerization is that vinyl structure content and styrene content, which define rubber properties, can be arbitrarily controlled and molecular weight and physical properties, etc., can be controlled by coupling, It can be adjusted. Therefore, it is easy to change the structure of the finally prepared SBR or BR rubber, and it is possible to reduce the movement of chain ends due to bonding or modification of chain ends and to increase the bonding force with a filler such as silica or carbon black, It is widely used as rubber material for tires.
When such a solution-polymerized SBR is used as a rubber material for a tire, the glass transition temperature of the rubber is increased by increasing the vinyl content in the SBR, so that the tire required properties such as running resistance and braking force can be controlled, Adjustment can reduce fuel consumption.
The solution-polymerized SBR is prepared by using an anionic polymerization initiator, and chain ends of the formed polymer are bonded or denatured by using various modifiers.
For example, US Pat. No. 4,397,994 discloses a technique in which an active anion at the chain terminal of a polymer obtained by polymerizing styrene-butadiene in a nonpolar solvent using alkyllithium, a monofunctional initiator, is bonded using a binder such as a tin compound Respectively.
On the other hand, carbon black and silica are used as reinforcing fillers for tire treads. When silica is used as a reinforcing filler, low hysteresis loss property and wet skid resistance are improved. However, silica having a hydrophilic surface compared to carbon black on the hydrophobic surface has a disadvantage that the affinity with the rubber is low and the dispersibility is poor. Therefore, in order to improve the dispersibility or to provide the bond between the silica and the rubber, It is necessary to use a lingering agent.
Accordingly, a method of introducing a functional group having affinity or reactivity with silica to the end of the rubber molecule has been attempted, but the effect is insufficient.
Therefore, it is necessary to develop a rubber having high affinity with a filler including silica.
Disclosure of Invention Technical Problem [8] Accordingly, the present invention has been made keeping in mind the above problems occurring in the prior art, and an object of the present invention is to provide a rubber modifier compound capable of providing a filler, particularly a silica-based filler affinity functional group.
Another object of the present invention is to provide a modified conjugated diene-based polymer containing the functional group derived from the compound for rubber modifier.
It is still another object of the present invention to provide a process for producing a modified conjugated diene polymer using the compound for rubber modifier.
It is still another object of the present invention to provide a rubber composition comprising the modified conjugated diene polymer.
Still another object of the present invention is to provide a tire made from the rubber composition.
In order to solve the above problems, there is provided a compound represented by the following general formula (1).
A compound represented by the following formula (1):
[Chemical Formula 1]
In Formula 1,
R 1 to R 3 independently of one another Alkyl having 1 to 20 carbon atoms,
A and B are independently of each other alkylene having 1 to 20 carbon atoms.
The present invention also provides a modified conjugated diene polymer comprising a functional group derived from a compound represented by the above formula (1).
The present invention also relates to a process for producing an active polymer having at least one terminal thereof bound to an alkali metal by polymerizing a conjugated diene monomer or an aromatic vinyl monomer and a conjugated diene monomer in the presence of an organic alkali metal compound in a hydrocarbon solvent ); And a step (2) of reacting the active polymer with the compound represented by the formula (1).
In addition, a rubber composition comprising the modified conjugated diene polymer is provided.
Further, a tire made from the rubber composition is provided.
The compound represented by the formula (1) according to the present invention can be used as a modifier for rubber dyes, particularly as a modifier for a conjugated diene polymer, and can be bonded to the conjugated diene polymer chain to easily introduce a filler-affinity functional group.
In addition, the modified conjugated diene polymer according to the present invention may have excellent affinity with a filler, especially with a silica-based filler, because a functional group derived from a compound represented by the formula (1), for example, a siloxane group and an amine group, is bonded to the polymer chain.
Further, by using the compound represented by the formula (1), the modified conjugated diene polymer having an excellent modification ratio can be easily produced by the production process according to the present invention.
In addition, the rubber composition according to the present invention may have excellent processability by including a modified conjugated diene polymer having excellent affinity with the filler. As a result, the processed product (for example, a tire) Strength, abrasion resistance, and wet road surface resistance characteristics.
Hereinafter, the present invention will be described in detail in order to facilitate understanding of the present invention.
The terms and words used in the present specification and claims should not be construed in an ordinary or dictionary sense and the inventor can properly define the concept of the term to describe its invention in the best possible way It should be construed as meaning and concept consistent with the technical idea of the present invention.
The present invention provides a compound for a rubber modifier capable of providing an affinity functional group with a reinforcing filler, particularly a silica filler.
The compound according to an embodiment of the present invention is represented by the following general formula (1).
A compound represented by the following formula (1):
[Chemical Formula 1]
In Formula 1,
R 1 to R 3 independently of one another Alkyl having 1 to 20 carbon atoms,
A and B are independently of each other alkylene having 1 to 20 carbon atoms.
Specifically, in Formula 1, R 1 to R 3 independently represent Alkyl having 1 to 10 carbon atoms, and A and B independently of each other may be alkylene having 1 to 10 carbon atoms.
In the above formula (1), R 1 to R 3 independently represent Alkyl having 1 to 6 carbon atoms, and A and B independently of each other may be alkylene having 1 to 6 carbon atoms.
More specifically, the formula (1) may be represented by the following formula (2).
(2)
In addition, the compound represented by Formula 1 may be a rubber modifier as described above.
Specifically, the compound represented by Formula 1 may be a modifier for a conjugated diene-based polymer. Here, the conjugated diene-based polymer may be a conjugated diene-based monomer homopolymer or a copolymer of a conjugated diene-based monomer and an aromatic vinyl-based monomer.
The present invention also provides a modified conjugated diene polymer comprising a functional group derived from a compound represented by the following formula (1).
[Chemical Formula 1]
In Formula 1,
R 1 to R 3 independently of one another Alkyl having 1 to 20 carbon atoms,
A and B are independently of each other alkylene having 1 to 20 carbon atoms.
The modified conjugated diene polymer according to an embodiment of the present invention includes a functional group derived from a compound represented by the formula (1), and the modified conjugated diene polymer may be modified by a compound represented by the formula (1).
The modified conjugated diene polymer has siloxane groups and amine groups bonded to the polymer chain, and thus can have excellent affinity with fillers, particularly silica-based fillers. Thus, the rubber composition containing the modified conjugated diene polymer can have excellent processability because of its excellent compounding property with the filler, and consequently the molded article produced using the rubber composition, such as the tensile strength, Wear resistance and wet road surface resistance can be improved.
In addition, the modified conjugated diene polymer may have a number average molecular weight of 1,000 g / mol to 2,000,000 g / mol, specifically 10,000 g / mol to 1,000,000 g / mol.
The modified conjugated diene polymer may have a weight average molecular weight of from 10,000 g / mol to 3,000,000 g / mol, and specifically from 100,000 g / mol to 2,000,000 g / mol.
The modified conjugated diene polymer may have a polydispersity index of 0.5 to 10, and more preferably 1 to 4.
The modified conjugated diene polymer may have a vinyl content of 5% by weight or more, specifically 10% by weight or more, more specifically 10% by weight to 50% by weight. When the vinyl content is in the above range, Can be adjusted to an appropriate range. Therefore, when the tire is applied to a tire, it is excellent in physical properties required for a tire such as a running resistance and a braking force, and also has an effect of reducing fuel consumption.
At this time, the vinyl content indicates the content of the 1,2-added conjugated diene monomer, not 1,4-added to 100% by weight of the conjugated diene-based polymer composed of the vinyl group-containing monomer or the conjugated diene-based monomer.
In addition, the present invention provides a process for producing a modified conjugated diene polymer using the compound represented by the above formula (1).
The production method according to an embodiment of the present invention is a method of polymerizing an aromatic vinyl monomer or an aromatic vinyl monomer and a conjugated diene monomer in the presence of an organic alkali metal compound in a hydrocarbon solvent and polymerizing an active polymer having at least one terminal thereof with an alkali metal (Step 1); And reacting the active polymer with the compound represented by the formula (1) (step 2).
Step 1 is a step for preparing an active polymer having at least one terminal thereof bound with an alkali metal and is carried out by polymerizing a conjugated diene monomer or a conjugated diene monomer and an aromatic vinyl monomer in the presence of an organic alkali metal compound in a hydrocarbon solvent .
The polymerization of step 1 may be carried out using a conjugated diene monomer alone or a conjugated diene monomer and an aromatic vinyl monomer as monomers. That is, the polymer produced by the above production method according to one embodiment of the present invention may be a homopolymer derived from a conjugated diene monomer, or a copolymer derived from a conjugated diene monomer and an aromatic vinyl monomer.
When the modified conjugated diene-based polymer is a copolymer of a conjugated diene-based monomer and an aromatic vinyl-based monomer, the copolymer may be a random copolymer.
Here, the above-mentioned "random copolymer" may indicate that constituent units constituting the copolymer are randomly arranged.
Examples of the conjugated diene monomer include, but are not limited to, 1,3-butadiene, 2,3-dimethyl-1,3-butadiene, piperylene, 3-butyl-1,3-octadiene, -1,3-butadiene, and the like.
When the conjugated diene-based monomer and the aromatic vinyl-based monomer are used together as the monomer, the conjugated diene-based monomer has a unit derived from the conjugated diene-based monomer in the finally produced modified conjugated diene-based polymer in an amount of 60% by weight or more, In an amount of 60 wt% to 90 wt%, more specifically 60 wt% to 85 wt%.
Examples of the aromatic vinyl monomer include, but not limited to, styrene,? -Methylstyrene, 3-methylstyrene, 4-methylstyrene, 4-propylstyrene, 1-vinylnaphthalene, 4-cyclohexylstyrene, 4- -Methylphenyl) styrene and 1-vinyl-5-hexyl naphthalene.
When the conjugated diene-based monomer and the aromatic vinyl-based monomer are used together as the monomer, the amount of the aromatic vinyl-based monomer-derived unit in the finally produced modified conjugated diene-based polymer is 40% by weight or less, , More preferably from 10% by weight to 40% by weight, and still more specifically from 15% by weight to 40% by weight.
Here, the "derived unit" may be an element, a structure, or the substance itself due to a substance.
The hydrocarbon solvent is not particularly limited, but may be one or more selected from the group consisting of n-pentane, n-hexane, n-heptane, isooctane, cyclohexane, toluene, benzene and xylene.
The organic alkali metal compound may be used in an amount of 0.01 mmol to 10 mmol based on 100 g of the monomer.
The organic alkali metal compound is not particularly limited and includes, for example, methyl lithium, ethyl lithium, propyl lithium, n-butyl lithium, s-butyl lithium, t- Phenyl lithium, 1-naphthyl lithium, n-eicosyllithium, 4-butylphenyl lithium, 4-tolyl lithium, cyclohexyllithium, 3,5-di-n-heptylcyclohexyllithium, At least one member selected from the group consisting of lithium, sodium, potassium, sodium, potassium, sodium, sodium, potassium, sodium, potassium, alkaline earth metal salts such as sodium hydride, sodium hydride, sodium hydride, sodium hydride, sodium hydride, .
The polymerization of Step 1 may be carried out by adding a polar additive if necessary, and the polar additive may be added in an amount of 0.001 to 50 parts by weight based on 100 parts by weight of the total of the monomers. Specifically, it may be added in an amount of 0.001 to 10 parts by weight, more specifically 0.005 to 0.1 part by weight, based on 100 parts by weight of the total amount of monomers.
The polar additive may be selected from the group consisting of tetrahydrofuran, ditetrahydrofuryl propane, diethyl ether, cycloalcohol ether, dipropyl ether, ethylenedimethyl ether, ethylene dimethyl ether, diethyl glycol, dimethyl ether, tertiary butoxyethoxyethane, bis (3-dimethylaminoethyl) ether, (dimethylaminoethyl) ethyl ether, trimethylamine, triethylamine, tripropylamine and tetramethylethylenediamine.
In the production method according to an embodiment of the present invention, when the conjugated diene-based monomer and the aromatic vinyl-based monomer are copolymerized by using the polar additive, the random copolymer can be easily formed .
The polymerization in the step 1 may be carried out through the temperature-raising polymerization or may be carried out through the constant temperature polymerization.
The polymerization may be carried out in a temperature range of -20 캜 to 200 캜, specifically, in a temperature range of 0 캜 to 150 캜, more specifically, 10 캜 to 120 캜.
Step 2 is a step of reacting the active polymer with a compound represented by the formula (1) to produce a modified conjugated diene polymer.
Herein, the compound represented by Formula 1 may be as described above.
The compound represented by the formula (1) may be used in a proportion of 0.01 mol to 10 mol based on the total molar amount of the organic alkali metal compound.
The reaction of Step 2 according to an embodiment of the present invention may be a modification reaction for introducing a functional group into the polymer, and each of the reactions may be carried out at a temperature range of 0 ° C to 90 ° C for 0 minutes to 5 hours.
The manufacturing method according to an embodiment of the present invention may further include at least one of a solvent and unreacted monomer recovery and drying as needed after the step 2.
Further, the present invention provides a rubber composition comprising the modified conjugated diene polymer.
The rubber composition according to an embodiment of the present invention may contain 10% by weight or more, specifically 10% by weight to 100% by weight, more specifically 20% by weight to 90% by weight, of the modified conjugated diene polymer have. If the content of the modified conjugated diene polymer is less than 10% by weight, the effect of improving the abrasion resistance and crack resistance of a molded article produced using the rubber composition, such as a tire, may be insignificant.
In addition, the rubber composition may further include other rubber components, if necessary, in addition to the modified conjugated diene polymer, wherein the rubber component may be contained in an amount of 90 wt% or less based on the total weight of the rubber composition. Specifically, it may be contained in an amount of 1 part by weight to 900 parts by weight based on 100 parts by weight of the modified conjugated diene-based copolymer.
The rubber component may be natural rubber or synthetic rubber, for example natural rubber (NR) comprising cis-1,4-polyisoprene; Modified natural rubbers such as epoxidized natural rubber (ENR), deproteinized natural rubber (DPNR), and hydrogenated natural rubber, which are modified or refined with the general natural rubber; Butadiene copolymers (SBR), polybutadiene (BR), polyisoprenes (IR), butyl rubbers (IIR), ethylene-propylene copolymers, polyisobutylene-co-isoprene, neoprene, poly Butadiene), poly (styrene-co-butadiene), poly (styrene-co-butadiene) Synthetic rubber such as polysulfide rubber, acrylic rubber, urethane rubber, silicone rubber, epichlorohydrin rubber, butyl rubber, halogenated butyl rubber and the like may be used, and any one or a mixture of two or more thereof may be used have.
The rubber composition may include 0.1 to 200 parts by weight of a filler based on 100 parts by weight of the modified conjugated diene polymer. The filler may be a silica filler, a carbon black filler, or a combination thereof.
On the other hand, when a silica-based filler is used as the filler, a silane coupling agent may be used together to improve the reinforcing property and the low heat build-up.
Specific examples of the silane coupling agent include bis (3-triethoxysilylpropyl) tetrasulfide, bis (3-triethoxysilylpropyl) trisulfide, bis (2-triethoxysilylethyl) tetrasulfide, bis (3-trimethoxysilylpropyl) tetrasulfide, bis (2-trimethoxysilylethyl) tetrasulfide, 3-mercaptopropyltrimethoxysilane , 3-mercaptopropyltriethoxysilane, 2-mercaptoethyltrimethoxysilane, 2-mercaptoethyltriethoxysilane, 3-trimethoxysilylpropyl-N, N-dimethylthiocarbamoyltetrasulfide Triethoxysilylpropyl-N, N-dimethylthiocarbamoyltetrasulfide, 2-triethoxysilylethyl-N, N-dimethylthiocarbamoyltetrasulfide, 3-trimethoxysilyl Propylbenzothiazolyltetrasulfide, 3-triethoxysilylpropylbenzyltetrasulfide, 3-triethoxysilylpropylmethacrylate Monosulfide, monosulfide, 3-trimethoxysilylpropyl methacrylate monosulfide, bis (3-diethoxymethylsilylpropyl) tetrasulfide, 3-mercaptopropyldimethoxymethylsilane, dimethoxymethylsilylpropyl- N-dimethylthiocarbamoyltetrasulfide, or dimethoxymethylsilylpropylbenzothiazolyltetrasulfide. Any one or a mixture of two or more of them may be used. More specifically, in consideration of the reinforcing effect, the silane coupling agent may be bis (3-triethoxysilylpropyl) polysulfide or 3-trimethoxysilylpropylbenzothiazine tetrasulfide.
In the rubber composition according to the embodiment of the present invention, since the modified conjugated diene polymer having a functional group having a high affinity for the silica-based filler introduced into the active site is used as the rubber component, The compounding amount can be reduced more than usual. Specifically, the silane coupling agent may be used in an amount of 1 part by weight to 20 parts by weight based on 100 parts by weight of the silica-based filler. When used in the above-mentioned range, gelation of the rubber component can be prevented while sufficiently exhibiting the effect as a coupling agent. More specifically, the silane coupling agent may be used in an amount of 5 parts by weight to 15 parts by weight based on 100 parts by weight of silica.
In addition, the rubber composition according to an embodiment of the present invention may be sulfur-crosslinkable, and may further include a vulcanizing agent.
The vulcanizing agent may be specifically a sulfur powder and may be included in an amount of 0.1 to 10 parts by weight based on 100 parts by weight of the rubber component. When contained in the above content range, the required elastic modulus and strength of the vulcanized rubber composition can be ensured, and at the same time, the low fuel consumption ratio can be obtained.
In addition to the above-mentioned components, the rubber composition according to one embodiment of the present invention may contain various additives commonly used in the rubber industry, specifically vulcanization accelerators, process oils, plasticizers, antioxidants, scorch inhibitors, zinc white ), Stearic acid, a thermosetting resin, or a thermoplastic resin.
The vulcanization accelerator is not particularly limited and specifically includes M (2-mercaptobenzothiazole), DM (dibenzothiazyl disulfide), CZ (N-cyclohexyl-2-benzothiazyl sulfenamide) Based compound, or a guanidine-based compound such as DPG (diphenylguanidine) can be used. The vulcanization accelerator may be included in an amount of 0.1 to 5 parts by weight based on 100 parts by weight of the rubber component.
The process oil may be a paraffinic, naphthenic or aromatic compound. More specifically, considering the tensile strength and abrasion resistance, the process oil may be an aromatic process oil, a hysteresis loss And naphthenic or paraffinic process oils may be used in view of the low temperature characteristics. The process oil may be contained in an amount of 100 parts by weight or less based on 100 parts by weight of the rubber component. When the content is included in the above amount, the tensile strength and low heat build-up (low fuel consumption) of the vulcanized rubber can be prevented from lowering.
Specific examples of the antioxidant include N-isopropyl-N'-phenyl-p-phenylenediamine, N- (1,3-dimethylbutyl) -N'- 2, 4-trimethyl-1,2-dihydroquinoline, or high-temperature condensates of diphenylamine and acetone. The antioxidant may be used in an amount of 0.1 part by weight to 6 parts by weight based on 100 parts by weight of the rubber component.
The rubber composition according to one embodiment of the present invention can be obtained by kneading by using a kneader such as Banbury mixer, roll, internal mixer or the like by the above compounding formula. Further, the rubber composition can be obtained by a vulcanization step after molding, This excellent rubber composition can be obtained.
Accordingly, the rubber composition can be applied to various members such as tire tread, under-tread, sidewall, carcass coated rubber, belt coated rubber, bead filler, pancake fur, or bead coated rubber, vibration proof rubber, belt conveyor, Can be useful for the production of various industrial rubber products.
In addition, the present invention provides a tire produced using the rubber composition.
The tire may be a tire or a tire tread.
Hereinafter, the present invention will be described in more detail with reference to Examples and Experimental Examples. However, the following examples and experimental examples are provided for illustrating the present invention, and the scope of the present invention is not limited thereto.
As the modifier used in Examples 1 and 2, compounds represented by the following Formula 2 according to one embodiment of the present invention were used.
(2)
Example 1
290 g of styrene, 780 g of 1,3-butadiene, 5500 g of n-hexane and 0.124 g of DTP (2,2-di (2-tetrahydrofuryl) propane) as a polar additive were placed in a 20 L autoclave reactor, And the temperature was raised to 50 占 폚. When the internal temperature of the reactor reached 50 캜, 4 mmol of n-butyllithium was charged into the reactor to conduct an adiabatic reaction. After 20 minutes, 20 g of 1,3-butadiene was added to cap the SSBR terminal with butadiene. After 5 minutes, 0.181 g of a denaturant was added and reacted for 15 minutes ([DTP] / [act. Li] = 2.3, [denaturant] / [act. Li] = 1.0). Thereafter, the polymerization reaction was stopped using ethanol, and 45 ml of a solution in which 0.3 wt% of BHT (butylated hydroxytoluene) as an antioxidant was dissolved in hexane was added. The resultant polymer was put into hot water heated with steam and stirred to remove the solvent. The solvent was then removed by roll drying to remove the remaining solvent and water to prepare a modified styrene-butadiene copolymer.
Example 2
350 g of styrene, 600 g of 1,3-butadiene, 5500 g of n-hexane and 0.86 g of DTP (2,2-di (2-tetrahydrofuryl) propane) as a polar additive were placed in a 20 L autoclave reactor, And the temperature was raised to 50 占 폚. When the internal temperature of the reactor reached 50 캜, 4 mmol of n-butyllithium was charged into the reactor to conduct an adiabatic reaction. After 20 minutes, 20 g of 1,3-butadiene was added to cap the SSBR terminal with butadiene. After 5 minutes, 0.181 g of a denaturant was added and reacted for 15 minutes ([DTP] / [act. Li] = 2.3, [denaturant] / [act. Li] = 1.0). Thereafter, the polymerization reaction was stopped using ethanol, and 45 ml of a solution in which 0.3 wt% of BHT (butylated hydroxytoluene) as an antioxidant was dissolved in hexane was added. The resultant polymer was put into hot water heated with steam and stirred to remove the solvent. The solvent was then removed by roll drying to remove the remaining solvent and water to prepare a modified styrene-butadiene copolymer.
Comparative Example 1
A commercially available styrene-butadiene copolymer (5025-2HM grade, LANXESS) was used in the experiment.
Comparative Example 2
A commercially available modified styrene-butadiene copolymer (TUFDENETM 3835, Asahi) was used in the experiment.
Experimental Example 1
The weight average molecular weight (Mw), the number average molecular weight (Mn), the molecular weight distribution (MWD), the component analysis and the pattern viscosity (Mw) of each of the modified conjugated diene type copolymers prepared in Examples 1, MV) were measured. The results are shown in Table 1 below.
1) Component analysis
The styrene derived unit (SM) and vinyl content in each copolymer were measured by NMR.
2) Molecular weight analysis
The weight average molecular weight (Mw) and number average molecular weight (Mn) of each copolymer were measured by GPC (Gel Permeation Chromatograph) analysis under the condition of 40 캜. In this case, two columns of PLgel Olexis manufactured by Polymer Laboratories and a PLgel mixed-C column were used in combination, and all of the new columns were of mixed bed type. Also, PS (polystyrene) was used as a GPC reference material in molecular weight calculation. The polydispersity index (PDI) was calculated as the ratio (Mw / Mn) of the weight average molecular weight to the number average molecular weight measured by the above method.
3) Mooney viscosity analysis
The Mooney viscosity of each copolymer was measured by MV-2000 (Alpha Technologies) at a temperature of 100 ° C for 4 minutes after preheating two samples each weighing 15 g or more for 1 minute.
Experimental Example 2
In order to comparatively analyze the physical properties of the rubber compositions comprising the modified conjugated diene copolymers prepared in Examples 1 and 2 and Comparative Examples and the molded articles produced therefrom, tensile properties, vulcanization properties and viscoelastic properties were measured Respectively. The results are shown in Table 2 below.
1) Preparation of rubber composition
Each rubber composition was manufactured through a first stage kneading and a second stage kneading process. At this time, the amount of the substance excluding the modified conjugated diene copolymer is shown based on 100 parts by weight of the modified conjugated diene copolymer. In the first stage kneading, 137.5 parts by weight of each of the modified conjugated diene-based copolymers, 70 parts by weight of silica, 100 parts by weight of bis (3-triethoxysilylpropyl) tetrasulfide as a silane coupling agent, 11.2 parts by weight of feed, 25 parts by weight of process oil (TDAE), 2 parts by weight of antioxidant (TMDQ), 3 parts by weight of zinc oxide (ZnO), 2 parts by weight of stearic acid and 1 part by weight of wax Kneaded. At this time, the temperature of the kneader was controlled and a primary blend was obtained at an outlet temperature of 150 캜. In the second-stage kneading, after cooling the above-mentioned primary blend to room temperature, 1.75 parts by weight of a rubber accelerator (CZ), 1.5 parts by weight of sulfur powder and 2 parts by weight of a vulcanization accelerator were added to the kneader and subjected to a curing process at 150 for 20 minutes A rubber composition was prepared. At this time, the silica used had a nitrogen adsorption specific surface area of 175 m2 / g and a CTAB adsorption of 160 m2 / g.
2) Tensile properties
Tensile properties of each test piece were measured in accordance with the tensile test method of ASTM 412, and the tensile strength at the time of cutting the test piece and the tensile stress at 300% elongation (300% modulus) were measured. Specifically, the tensile properties were measured at a rate of 50 cm / min at room temperature using a Universal Test Machin 4204 (Instron) tensile tester.
3) Viscoelastic properties
The viscoelastic properties were measured by using a dynamic mechanical analyzer (TA) at a frequency of 10 Hz in a twist mode at various measuring temperatures (-60 ° C to 60 ° C) to measure tan δ. The payne effect is expressed as the difference between the minimum value and the maximum value at 0.28% to 40% of the variation. The higher the temperature of 0 ° C tan δ, the better the wet road surface resistance. The lower the tan δ of 60 ° C, the lower the hysteresis loss and the lower the rolling resistance (fuel economy).
As shown in Table 2, the tensile properties and the viscoelastic properties of the rubber compositions comprising the modified styrene-butadiene copolymers of Examples 1 and 2 prepared using the modifier according to one embodiment of the present invention were comparable to those of Comparative Example 1 And the copolymer of Comparative Example 2 were compared with each other.
Specifically, the styrene-butadiene copolymer of Comparative Example 1 in which the rubber composition containing the modified styrene-butadiene copolymer of Examples 1 and 2 prepared using the modifier according to one embodiment of the present invention was not modified, The tan δ value at 0 ° C was increased and the tan δ value at 60 ° C was decreased compared to the modified rubber composition and the commercially available modified styrene-butadiene copolymer of Comparative Example 2. This is a result indicating that the modified styrene-butadiene copolymer produced using the modifier according to an embodiment of the present invention is excellent in resistance and rolling resistance characteristics on a wet road surface and fuel efficiency can be high.
Also, the rubber composition comprising the modified styrene-butadiene copolymers of Examples 1 and 2 prepared using the modifier according to one embodiment of the present invention includes the styrene-butadiene copolymer of Comparative Example 1 in which the rubber composition was not denatured And the ΔG 'value of the modified styrene-butadiene copolymer of Comparative Example 2 was almost half as low as that of the conventional rubber composition. This is a result indicating that the rubber composition containing the modified styrene-butadiene copolymer according to an embodiment of the present invention may have excellent silica dispersibility.
Claims (24)
[Chemical Formula 1]
In Formula 1,
R 1 to R 3 independently of one another Alkyl having 1 to 20 carbon atoms,
A and B are independently of each other alkylene having 1 to 20 carbon atoms.
In Formula 1,
R 1 to R 3 independently of one another Alkyl having 1 to 10 carbon atoms,
A and B are independently of each other alkylene of 1 to 10 carbon atoms.
In Formula 1,
R 1 to R 3 independently of one another Alkyl having 1 to 6 carbon atoms,
A and B are independently of each other alkylene of 1 to 6 carbon atoms.
Wherein the compound represented by Formula 1 is represented by Formula 2:
(2)
Wherein said compound is a rubber modifier.
Wherein the compound is a modifier for a conjugated diene-based polymer.
Wherein the conjugated diene-based polymer is a copolymer of a conjugated diene-based monomer homopolymer or a conjugated diene-based monomer and an aromatic vinyl-based monomer.
[Chemical Formula 1]
In Formula 1,
R 1 to R 3 independently of one another Alkyl having 1 to 20 carbon atoms,
A and B are independently of each other alkylene having 1 to 20 carbon atoms.
Wherein the polymer is a copolymer of a conjugated diene-based monomer homopolymer or a conjugated diene-based monomer and an aromatic vinyl-based monomer.
Wherein the polymer has a number average molecular weight of 1,000 g / mol to 2,000,000 g / mol.
Wherein the polymer has a polydispersity index of from 0.5 to 10.
Wherein the polymer has a vinyl content of 5 wt% or more.
2) reacting the active polymer with a compound represented by the following formula (1): < EMI ID =
[Chemical Formula 1]
In Formula 1,
R 1 to R 3 independently of one another Alkyl having 1 to 20 carbon atoms,
A and B are independently of each other alkylene having 1 to 20 carbon atoms.
Wherein the organic alkali metal compound is used in an amount of 0.01 mmol to 10 mmol based on 100 g of the total of monomers.
The organic alkali metal compound may be at least one selected from the group consisting of methyl lithium, ethyl lithium, propyl lithium, n-butyl lithium, s-butyl lithium, t- Lithium, n-octyl lithium, n-octyl lithium, n-eicosyllithium, 4-butylphenyl lithium, 4-tolyl lithium, cyclohexyllithium, Wherein the modified conjugated diene polymer is at least one member selected from the group consisting of lithium alkoxide, sodium alkoxide, potassium alkoxide, lithium sulfonate, sodium sulfonate, potassium sulfonate, lithium amide, sodium amide, potassium amide and lithium isopropylamide Gt;
Wherein the polymerization of the step 1) is carried out by further adding a polar additive.
Wherein the polar additive is added in an amount of 0.001 to 50 parts by weight based on 100 parts by weight of the total of monomers.
Wherein the compound represented by the formula (1) is a compound represented by the following formula (2): < EMI ID =
(2)
Wherein the compound represented by the formula (1) is used in a proportion of 0.01 mol to 10 mol based on the molar amount of the organic alkali metal compound.
Wherein the rubber composition comprises 0.1 to 100% by weight of the modified conjugated diene polymer.
Wherein the rubber composition comprises from 0.1 to 150 parts by weight of a filler based on 100 parts by weight of the polymer.
Wherein the filler is a silica-based filler, a carbon black filler, or a combination thereof.
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| CN110099930A (en) * | 2017-10-25 | 2019-08-06 | 株式会社Lg化学 | Modified conjugated diene quasi polymer and preparation method thereof |
| KR20210038390A (en) * | 2019-09-30 | 2021-04-07 | 주식회사 엘지화학 | Modified conjugated diene-based polymer, method for preparing thereof and rubber composition comprising the same |
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| DE10353063B4 (en) | 2003-11-13 | 2006-03-02 | Wacker-Chemie Gmbh | A process for the preparation of (N-organylaminoorganyl) - and (N, N-diorganylaminoorganyl) triorganylsilanes and (N-cyclohexylaminomethyl) trimethoxysilane and [N, N-bis (N ', N'-dimethylaminopropyl) aminomethyl] triorganylsilane obtainable by this process |
| JP4442259B2 (en) | 2004-03-11 | 2010-03-31 | 住友化学株式会社 | Modified diene polymer rubber and process for producing the same |
| JP6359797B2 (en) | 2012-10-17 | 2018-07-18 | 住友ゴム工業株式会社 | Rubber composition for tire and pneumatic tire |
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| CN110099930A (en) * | 2017-10-25 | 2019-08-06 | 株式会社Lg化学 | Modified conjugated diene quasi polymer and preparation method thereof |
| US11041025B2 (en) | 2017-10-25 | 2021-06-22 | Lg Chem, Ltd. | Modified conjugated diene-based polymer and method for preparing the same |
| CN110099930B (en) * | 2017-10-25 | 2022-02-08 | 株式会社Lg化学 | Modified conjugated diene polymer and preparation method thereof |
| KR20210038390A (en) * | 2019-09-30 | 2021-04-07 | 주식회사 엘지화학 | Modified conjugated diene-based polymer, method for preparing thereof and rubber composition comprising the same |
| WO2021066561A1 (en) * | 2019-09-30 | 2021-04-08 | 주식회사 엘지화학 | Modified conjugated diene-based polymer, method for producing same, and rubber composition comprising same |
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