KR20170075384A - Antibacteria composite including calcium powder from shellfishes and antibacteria plastic material including the same - Google Patents

Antibacteria composite including calcium powder from shellfishes and antibacteria plastic material including the same Download PDF

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Publication number
KR20170075384A
KR20170075384A KR1020150184986A KR20150184986A KR20170075384A KR 20170075384 A KR20170075384 A KR 20170075384A KR 1020150184986 A KR1020150184986 A KR 1020150184986A KR 20150184986 A KR20150184986 A KR 20150184986A KR 20170075384 A KR20170075384 A KR 20170075384A
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KR
South Korea
Prior art keywords
weight
calcium powder
fish
resin
shellfish
Prior art date
Application number
KR1020150184986A
Other languages
Korean (ko)
Inventor
김만도
윤성호
정유정
김종영
강솔미
Original Assignee
지에스피주식회사
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Priority to KR1020150184986A priority Critical patent/KR20170075384A/en
Publication of KR20170075384A publication Critical patent/KR20170075384A/en

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/06Aluminium; Calcium; Magnesium; Compounds thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/20Compounding polymers with additives, e.g. colouring
    • C08J3/22Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Pest Control & Pesticides (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention relates to an antimicrobial composition containing calcium powder derived from fish and shellfish and an antimicrobial plastics comprising the same. More particularly, the present invention relates to an antimicrobial composition comprising calcium powder derived from fish and shellfish, And an antimicrobial plastic material containing the antimicrobial composition.

Description

[0001] The present invention relates to an antimicrobial composition comprising a calcium powder derived from fish and shellfish and an antibacterial plastic material containing the calcium powder from shellfishes and an antibacterial plastic material,

The present invention relates to an antimicrobial composition containing calcium powder derived from fish and shellfish and an antimicrobial plastics comprising the same. More particularly, the present invention relates to an antimicrobial composition comprising calcium powder derived from fish and shellfish, And an antimicrobial plastic material containing the antimicrobial composition.

Generally, since a tableware or a container made of resin is formed by molding with a press, there is a merit that it is easy to manufacture, but it has a weak strength and is deformed to a high temperature and can not store food at a high temperature. There is a problem that the food is easily damaged or altered.

In addition, when a food or a container made of a resin is put in a food for a long period of time, the container itself is filled with food, which causes the color of the container itself to be discolored. As a result, the appearance of the container is poor and the characteristic odor and color remain. There is a problem that it can not be inserted.

On the other hand, in recent years, there has been proposed a synthetic resin containing a purgative substance containing a pomegranate powder having a beneficial component and effect in the resin, and a method for producing the same (1993 Patent Application No. 18919) and an acupuncture compound containing a pomegranate ingredient (1993 Patent Application No. 18922), etc., have been used, and the above-mentioned inventions have been made by powdering nephrite having effects such as a heavy metal removal function, a malodor removing function, a plant growth promoting function, and a water quality improvement function It is contained in the resin.

The patent application No. 9318919 will be described in more detail. The pesticide powder of 100-350 mesh particles is added to the synthetic resin raw material in an amount of 5-15% and injected into the interior of the injection molding machine. Followed by heat molding.

In addition, a number of researchers such as a synthetic resin material having a leading maintenance and antibacterial effect and a manufacturing method thereof (Patent Application No. 33008 of 1998) are also being studied.

Korean Patent Application No. 33008

It is an object of the present invention to provide an antimicrobial composition capable of maintaining the freshness of a food by using an alkaline powder prepared by preparing an alkali powder through fish and shellfish such as cockles, and an antimicrobial plastic material containing the antimicrobial composition.

In particular, it is an object of the present invention to provide a plastic material having antimicrobial function by extending the shelf life by using a powder derived from fish and shellfish or by applying it to the bottom of a container to function as an antimicrobial agent or by using calcium powder derived from fish and shellfish, .

The antimicrobial composition comprising the calcium powder derived from fish and shellfish according to the present invention is characterized in that the calcium powder contains 1 to 5% by weight.

Preferably, it may further contain 2% by weight of talc and 1 to 5% by weight of natural oak.

Preferably, the calcium powder is added in an amount of 5 to 6 wt% to polyethylene (PE), 8 to 10 wt% to polystyrene (PS), 8 to 10 wt% to acrylonitrile butadiene styrene (ABS) (PET), 5 to 7 wt% to phenol resin, 5 to 6 wt% to pvcia (PVC), and 4 to 6 wt% to melamine resin to prepare a new synthetic resin material through master batching ≪ / RTI >

Preferably, the antimicrobial composition is a synthetic resin having a leading-edge maintenance and an antimicrobial activity.

In addition, the nano-antibacterial plastic resin composition according to the present invention comprises 1 to 5% by weight of calcium powder derived from fish and shellfish; 2% by weight of talc; And 1 to 5% by weight of natural wood.

Also, the method for producing a synthetic container having a line keeping and anti-microbial power according to the present invention comprises mixing 20 to 40% by weight of a low density resin, 80 to 60% by weight of a high density resin, and 5 to 40% by weight of a calcium powder derived from fish and shellfishes in a mixing machine for about 30 minutes The mixture is heated in a heating unit at 180 to 200 ° C for 5 minutes to 10 minutes, and then the fine particles are cut by a cutting means. And cooled in a cooler to 7 ° C to 8 ° C for 1 to 2 minutes and then dried in a dry part at 110 ° C to 120 ° C for 8 minutes to 10 minutes to produce a new synthetic resin material.

Here, the fish and shellfish are shellfish such as cockles, and the powder is characterized by being alkaline. In particular, it is characterized in that the shelf life is extended by utilizing the powder derived from fish and shellfish, or it is applied to the bottom of the container to function as an antibacterial agent.

According to the present invention, it is possible to easily produce an antimicrobial composition capable of maintaining the freshness of a food by using an alkaline powder produced through the production of an alkali powder through fish and shellfish such as cockles, and an antibacterial plastic material containing the antimicrobial composition.

In particular, it is an object of the present invention to provide a method for improving the antimicrobial function by extending the shelf life by using the powder derived from fish and shellfish or by applying it to the bottom of the container to function as an antimicrobial agent or by using calcium powder derived from fish and shellfish in the production of synthetic resin do.

Preferred embodiments of the antimicrobial composition comprising the fish powder derived from fish and shellfish according to the present invention and the antimicrobial plastic material containing the same are described with reference to the accompanying drawings. In this process, the thicknesses of the lines and the sizes of the components shown in the drawings may be exaggerated for clarity and convenience of explanation. In addition, the terms described below are defined in consideration of the functions of the present invention, which may vary depending on the intention or custom of the user, the operator. Therefore, the definitions of these terms should be described based on the contents throughout this specification.

First, the present invention produces calcium powder through seafood such as barley. Such calcium powder has an alkaline property and is particularly excellent in antibacterial function for maintaining the freshness of food. It is particularly noted that the calcium powder may be used as a nanoparticle unit.

The antimicrobial composition can be prepared by pulverizing talc and natural wood and pulverizing them and mixing them with calcium powder. The calcium powder is added in an amount of 5 to 6% by weight to polyethylene (PE), 8 to 10% by weight to polystyrene (PS), 8 to 10% by weight to acrylonitrile butadiene styrene (ABS) (PET), 5 to 7% by weight to phenol resin, 5 to 6% by weight to fibrin (PVC) and 4 to 6% by weight to melamine resin to form a new synthetic resin material through master batching .

Such a composition may be a synthetic resin having a maintenance and antimicrobial activity and may be extended to extend the shelf life by using the powder derived from fish and shellfish or may be applied to the bottom of the container to function as an antimicrobial agent or calcium powder derived from fish or shellfish The antibacterial function can be improved.

The powder is mixed with a thermoplastic resin to prepare dishes or containers. That is, an edible pigment of a desired color is mixed with the resin, talc, and nacreous, and the mixture is molded in a molding machine at 200 to 250 ° C to produce a container. At this time, the talc is mixed with 2% of natural sap, 2% of natural sap, 2% of calcium powder derived from fish and shellfish, 2% of edible pigment and 92% of resin.

Herein, the nacre is effective to maintain the freshness of the stored food. In this embodiment, the nacreous nacre is mined from 350 to 450 mesh particles and used. This is because in the past, when the powder having a particle size of 100 to 350 mesh has a large particle size, when it is mixed with the thermoplastic resin, the bonding force between the jade particles and the resin raw material is low and cracks are easily generated at the interface between the jade and resin. will be. Of course, above 450 mesh, the physical properties are better, but in the process of grinding, the expensive grinding machine is needed, so the cost increases. And the total weight ratio of jade is 2%, which is because it is impossible to control the color of the container at the time of 5% or more and the binding force of the jade and resin is remarkably reduced. Also, when jade is mixed at a weight ratio of 1% or less, the effect of maintaining freshness by jade is weak and meaningless.

Next, the calcium powder derived from fish and shellfish (alkaline powder) is preferably pulverized from 350 to 450 mesh, and the composition ratio thereof is suitably 1 to 5%. When the calcium powder derived from fish and shellfish is increased to 5% or more, the lime ingredient of fish and shellfish is melted into food, the strength of container is remarkably lowered, and the inherent color of kimchi may be changed into color of container. It can be seen that the inherent odor adsorption power is remarkably reduced at less than 1%. Calcium powder derived from fish and shellfish can prevent the kimchi from ripening in the container by the lime component, which is one of its ingredients, so that the original taste of kimchi can be preserved and freshness can be maintained.

Talc is used to maximize the effect of the pigment and is applied at a weight ratio of 2%. Pigment is added at a weight ratio of 1 to 5% in order to minimize the background color according to the inherent color of the jade. The pigments used are inorganic and organic dyestuffs. Organic dyes are vegetable and harmless to the human body. Which is harmless to the human body and is non-toxic. This pigment makes it possible to have a visual impression of jade in a manufactured product by selecting a color that can feel the texture and color inherent in the natural wood.

As the resin to be used, a thermoplastic resin is preferable, and a polypropylene resin can be mainly used. At this time, the resin used is harmless to the human body. Examples of the thermoplastic resin include polyethylene, polystyrene, and ABS.

The resin having the above-mentioned components is prepared. First, the jute is mined by a pulverizer to make the particles have a size of about 450 mesh. Next, the talc powder is mixed with edible pigment to prepare a mixture. Calcium powder derived from fish and shellfish and jade powder are added to the mixture, stirred, and stored at a constant temperature for a certain period of time. The powder stored for a certain period of time is mixed with a thermoplastic resin material, melted in an extruder at 200 to 250 ° C, and extruded into a pellet form to remove moisture of the material. The hot air is dried at a temperature of 60 to 80 ° C, A desired shape is produced by using an extrusion molding machine.

The present invention as described above can maximize the strength of the resin by mixing fine particles of resin (PP, PE, PS, ABS, etc.) with talc, natural wood, and calcium powder derived from fish and shellfish, Since the pigment can be mixed, various colors can be changed.

Since the talc and the natural candle and the calcium powder derived from the fish and shellfish are contained in the present invention, it is possible to prevent the foods contained in the tableware from being damaged by the far-infrared rays radiated from the talc and the natural wood, and to prevent the odor generated in the foodstuffs, It is.

On the other hand, when the kimchi is put into the container by the lime ingredient contained in the calcium powder derived from seafood, the acid content contained in the kimchi is converted into alkali, thereby preventing the kimchi from being ripened, .

In the present invention as described above, the composition ratio and the manufacturing method of each material can be easily changed by those skilled in the art within the scope of the right described in the claims.

Claims (7)

An antimicrobial composition comprising a calcium powder derived from fish and shells, wherein the calcium powder contains 1 to 5% by weight.
The method according to claim 1,
Characterized in that it further contains 2% by weight of talc and 1 to 5% by weight of natural corn.
An antimicrobial composition comprising a fish powder-derived calcium powder.
3. The method according to claim 1 or 2,
8 to 10% by weight of calcium powder to 8 to 10% by weight of acrylonitrile butadiene styrene (ABS), 8 to 10% by weight of polypropylene (PP) to polystyrene (PS) (PET), 5 to 7% by weight of phenol resin, 5 to 6% by weight of fisicide (PVC), and 4 to 6% by weight of melamine resin are added to a new synthetic resin material through master batching Antimicrobial composition.
The method of claim 3,
The anti-
Wherein said antimicrobial composition is a synthetic resin having an antimicrobial activity.
In the nano-antibacterial plastic resin,
1 to 5% by weight of a fish meal derived calcium powder;
2% by weight of talc; And
And 1 to 5% by weight of natural wood.
20 to 40% by weight of a low-density resin, 80 to 60% by weight of a high-density resin, and 5 to 40% by weight of calcium powder derived from fish and shell are mixed in a mixing machine for about 30 minutes, 0.5 to 1% And the mixture is heated in a heating zone at 180 ° C to 200 ° C for 5 minutes to 10 minutes and then cut into fine particles by a cutting means. And then dried at 110 ° C to 120 ° C for 8 minutes to 10 minutes in a dry part to produce a new synthetic resin material.
The method according to claim 6,
Shellfish are shellfish such as cockles,
Characterized in that the powder is alkaline. ≪ RTI ID = 0.0 > 11. < / RTI >
KR1020150184986A 2015-12-23 2015-12-23 Antibacteria composite including calcium powder from shellfishes and antibacteria plastic material including the same KR20170075384A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1020150184986A KR20170075384A (en) 2015-12-23 2015-12-23 Antibacteria composite including calcium powder from shellfishes and antibacteria plastic material including the same

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Application Number Priority Date Filing Date Title
KR1020150184986A KR20170075384A (en) 2015-12-23 2015-12-23 Antibacteria composite including calcium powder from shellfishes and antibacteria plastic material including the same

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20210061561A (en) * 2019-11-20 2021-05-28 주식회사 씨피알에스앤티 Polymer molded body with antimicrobial and antifungal activity and deodorant performance and method for manufacturing the same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20210061561A (en) * 2019-11-20 2021-05-28 주식회사 씨피알에스앤티 Polymer molded body with antimicrobial and antifungal activity and deodorant performance and method for manufacturing the same

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