KR20170067509A - Multi bit capacitorless dram and manufacturing method thereof - Google Patents

Multi bit capacitorless dram and manufacturing method thereof Download PDF

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KR20170067509A
KR20170067509A KR1020150174252A KR20150174252A KR20170067509A KR 20170067509 A KR20170067509 A KR 20170067509A KR 1020150174252 A KR1020150174252 A KR 1020150174252A KR 20150174252 A KR20150174252 A KR 20150174252A KR 20170067509 A KR20170067509 A KR 20170067509A
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nanowire
nanowire channels
substrate
channels
capacitorless dram
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KR101835612B1 (en
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최양규
박준영
이병현
안대철
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한국과학기술원
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    • H01L27/10802
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
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    • H01L27/1085
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/02Semiconductor bodies ; Multistep manufacturing processes therefor
    • H01L29/06Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions
    • H01L29/0657Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions characterised by the shape of the body
    • H01L29/0665Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions characterised by the shape of the body the shape of the body defining a nanostructure
    • H01L29/0669Nanowires or nanotubes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/40Electrodes ; Multistep manufacturing processes therefor
    • H01L29/41Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions
    • H01L29/413Nanosized electrodes, e.g. nanowire electrodes comprising one or a plurality of nanowires
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2924/00Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
    • H01L2924/10Details of semiconductor or other solid state devices to be connected
    • H01L2924/11Device type
    • H01L2924/14Integrated circuits
    • H01L2924/143Digital devices
    • H01L2924/1434Memory
    • H01L2924/1435Random access memory [RAM]
    • H01L2924/1436Dynamic random-access memory [DRAM]

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Abstract

A multi-bit capacitorless DRAM according to the present invention includes a substrate, a source and a drain formed on the substrate, a plurality of nanowire channels formed on the substrate, a gate insulating film formed on the plurality of nanowire channels, and a gate formed on the gate insulating film. Wherein at least two of the plurality of nanowire channels have different threshold voltages. Thus, according to the capacitorless DRAM and the method of manufacturing the same according to the present invention having the above-described structure, it is possible to realize a highly integrated multi-bit capacitorless DRAM that can operate in multiple bits.

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention [0001] The present invention relates to a multi-bit capacitorless DRAM,

The present invention relates to a capacitorless DRAM, and more particularly, to a capacitorless DRAM capable of multi-bit implementation and a method of manufacturing the same.

Dynamic random access memory (DRAM), which is one of semiconductor components that is essential for computing, consists of one transistor and one capacitor. However, since the size of the conventional DRAM must be reduced along with the size of the device, it has been considered difficult to secure a capacitor having a sufficiently large capacity. In addition, the capacitor forming process is a stumbling block due to the high step difference of the capacitor when the embedded chip is formed together with other devices. Accordingly, a capacitorless DRAM capable of storing data without a capacitor causing a complicated process is attracting attention. Since the capacitorless DRAM is not used, it has a great advantage in terms of integration and fabrication cost as compared with the conventional DRAM.

1A is a cross-sectional view schematically showing the operation principle of a conventional capacitorless DRAM, and FIG. 1B is an energy band diagram of a conventional capacitorless DRAM. The capacitorless DRAM is fabricated using a silicon-on-insulator (SOI) substrate or a general silicon substrate and a floating body device. When a predetermined voltage is applied to the gate 2 and the drain 4 of the transistor, an excess hole is generated in the channel on the drain 4 side by impact ionization. The generated excess holes are accumulated in the body 5 because there is no place to escape. The transistor having the accumulated holes differs from the threshold voltage and the current level in comparison with the case where there is no hole in the body 5, and distinguishes the '0' state from the '1' state by using the difference.

A state in which holes are accumulated in the body 5 is referred to as a '1' state, and a state in which holes are completely exhausted from the inside of the body 5 is referred to as a '0' state. That is, the conventional data of the capacitorless DRAM can exist only in two states of '0' state and '1' state. This means that only one bit of information can be stored. In other words, conventional capacitorless DRAMs can not operate with more than two bits due to the structural limitations of having only one body region (channel region).

SUMMARY OF THE INVENTION The present invention is directed to a conventional capacitorless DRAM that operates only in a single bit, and it is an object of the present invention to provide a multi-bit capacitorless DRAM having a higher integration density than conventional capacitorless DRAMs and a method of manufacturing the same.

According to an aspect of the present invention, there is provided a multi-bit capacitorless DRAM comprising: a substrate; A source and a drain formed on the substrate; A plurality of nanowire channels formed on the substrate; A gate insulating layer formed on the plurality of nanowire channels; And a gate formed on the gate insulator, wherein at least two of the plurality of nanowire channels have different threshold voltages.

Further, the two or more nanowire channels may have different threshold voltages by changing at least one of the type, the depth, the concentration, and the angle of the doping ions.

The two or more nanowire channels may have different threshold voltages by changing the shape or area of the cross section.

In addition, the two or more nanowire channels may have different cross-sectional shapes or areas by etching at least one of different types of etch materials, concentration of etch materials, etch time, vacuum degree, and etch temperature.

A controller for controlling the operation of the capacitorless DRAM; And a storage unit for storing a driving voltage for each of the plurality of nanowire channels based on a threshold voltage of the plurality of nanowire channels.

The controller may program or erase data of two or more bits by controlling a driving voltage applied to at least one of the gate and the drain.

According to another aspect of the present invention, there is provided a method of manufacturing a multi-bit capacitorless DRAM, including: (a) depositing a hard mask on a substrate; (b) etching at least a portion of the hard mask; (c) patterning the nanowire on the substrate through an anisotropic etch; (d) forming a protective film on the substrate; (e) forming a nanowire channel in the substrate through isotropic etching; (f) repeating the steps (c) and (e) to form a plurality of nanowire channels; And (g) forming a source, a drain, and a gate, wherein (f) processes each of the plurality of nanowire channels to be formed to have different threshold voltages.

In the step (f), each time the nanowire channel is formed, a dopant is injected by varying at least one of the kind, the depth, the concentration, and the implantation angle of the doping ions, Can be processed to have different threshold voltages.

In the step (f), each of the plurality of nanowire channels is formed by varying at least one of an etching material type, an etching material concentration, an etching time, a vacuum degree, and an etching temperature, Each can be processed to have a different threshold voltage.

The method may further include forming a gate insulating film on the substrate before the step (g).

According to the multi-bit capacitorless DRAM and the method of manufacturing the same according to the present invention having the above-described structure, it is possible to implement a highly integrated DRAM capable of operating in multiple bits.

1A is a cross-sectional view schematically showing the operation principle of a conventional capacitorless DRAM.
1B is an energy band diagram of a conventional capacitorless DRAM.
2A is a perspective view of a multi-bit capacitorless DRAM according to the present invention.
2B is a cross-sectional view of the multi-bit capacitorless DRAM taken along line A-A 'in FIG. 2A.
FIG. 3 is a cross-sectional view of a multi-bit capacitorless DRAM taken along the line B-B 'in FIG. 2A, illustrating a phenomenon of ionization collision.
4 is a perspective view illustrating a main configuration of a multi-bit capacitorless DRAM according to the present invention.
FIGS. 5A through 5E are diagrams illustrating steps of forming a plurality of nanowires in a multi-bit capacitorless DRAM according to the present invention.
6A through 6C are diagrams illustrating steps of forming a plurality of nanowires in a multi-bit capacitorless DRAM according to the present invention.
7A and 7B are diagrams showing only a plurality of formed nanowire channels in a highlighted state.
8A and 8B are transmission electron micrographs of a nanowire channel having different shapes or areas in a multi-bit capacitorless DRAM according to the present invention.
9A and 9B are graphs showing the operating voltage range of a multi-bit capacitorless DRAM according to the present invention.
10A is a block diagram illustrating a configuration of an apparatus for measuring the operation of a multi-bit capacitorless DRAM according to the present invention.
FIGS. 10B and 10C are diagrams showing pulse voltages of input operating voltages in the respective operation regions. FIG.
11A is a graph showing measured data in which the current value of the first operating region is outputted by the pulse-type operating voltage shown in FIG. 10B.
FIG. 11B is a graph showing measured data in which the current value of the second operating region is output by the pulse-type operating voltage shown in FIG. 10C. FIG.
12 is a flowchart illustrating a method of manufacturing a multi-bit capacitorless DRAM according to an embodiment of the present invention.

The following description of the invention refers to the accompanying drawings which illustrate, by way of example, specific embodiments that may be practiced. The described embodiments are described in sufficient detail to enable those skilled in the art to practice the invention. It should be understood that the various embodiments of the present invention are different, but need not be mutually exclusive. For example, certain features, structures, and characteristics described herein may be implemented in other embodiments without departing from the spirit and scope of the invention in connection with an embodiment. It is also to be understood that the position or arrangement of the individual components within each disclosed embodiment may be varied without departing from the spirit and scope of the invention. The following detailed description is, therefore, not to be taken in a limiting sense, and the scope of the present invention is to be limited only by the appended claims, along with the full scope of equivalents to which such claims are entitled, if properly explained. In the drawings, like reference numerals refer to the same or similar functions throughout the several views.

The multi-bit capacitorless DRAM according to the present invention includes two or more channel regions. The two or more channel regions may be formed of nanowires, and two or more nanowire channels may be formed with different intrinsic threshold voltages by different ion implantation processes or by different etching processes. Since two or more nanowire channels have different threshold voltages, they have their own operating voltages that cause a collision ionization phenomenon.

FIG. 2A is a perspective view of a multi-bit capacitorless DRAM according to the present invention, and FIG. 2B is a cross-sectional view of a capacitorless DRAM taken along line A-A 'in FIG. 2A. Particularly, FIG. 2B further shows the structure of the drain 104 by cutting off a part of the drain 104 as well. As shown in FIGS. 2A and 2B, the multi-bit capacitorless DRAM according to the present invention has a plurality of nanowire channels unlike the prior art. Although only two nanowire channels 105a and 105b are shown in FIGS. 2A and 2B, this is only for the sake of simplicity, and a larger number of nanowire channels can be included.

The multi-bit capacitorless DRAM according to the present invention includes a substrate 100, a source 103 and a drain 104 formed on the substrate 100, a plurality of nanowire channels 105a and 105b formed on the substrate 100, A gate insulating film 101 formed on the plurality of nanowire channels 105a and 105b and a gate 102 formed on the gate insulating film 101. [ On the other hand, it may further include a shallow trench isolation oxide (106) for isolation between the respective structures. The STI oxide layer 106 is intended to reduce the leakage current between the source 103 and the drain 104 or the leakage current generated between different transistors. It may be formed of a silicon oxide film (SiO 2 ) using vapor-phase chemical vapor deposition (CVD) or oxidation.

The substrate 100 may be a wafer of bulk wafers, insulating layer buried silicon wafers, insulating layer buried germanium wafers, insulating layer buried strained germanium wafers, insulating layer buried strained silicon wafers, III-V (Group 3 and 5 elements) And silicon germanium (SiGe) wafers, but is not limited thereto.

The gate insulating film 101 may be a silicon oxide film or a high-K film. More specifically, the gate insulating film 101 may be formed of silicon oxide, a nitride film, aluminum oxide, hafnium oxide, hafnium oxynitride, zinc oxide, lanthanum oxide lanthanum oxide, hafnium silicon oxide, and the like. However, the present invention is not limited thereto.

The gate 102 may be made of metal or polysilicon. That is, the gate 102 is formed of a metal such as aluminum (Al), molybdenum (Mo), magnesium (Mg), chromium (Cr), palladium (Pd), gold (Au), platinum Polycrystalline silicon, a high-concentration p-type doped polysilicon, a high-conductivity polymer or an organic material may be used. Also, the gate 102 may be made of a metal silicide film such as NiSi or a similar material, but is not limited to the above-mentioned materials.

Furthermore, the gate 102 may have a planar FET structure, a gate all around (GAA) FET structure, a FinFET structure, a double gate FET structure, a tri-gate FET structure, or an omega gate structure.

Before describing the material, the structure, and the formation method thereof with respect to the plurality of nanowire channels 105a and 105b, the driving principle of the multi-bit capacitorless DRAM according to the present invention will be described with reference to FIG.

FIG. 3 is a cross-sectional view of the capacitorless DRAM taken along the line B-B 'in FIG. 2A, illustrating the ionization collision phenomenon.

First, the first nanowire channel 105a located at the top has a unique threshold voltage. The driving voltage region can be determined according to the intrinsic threshold voltage of the first nanowire channel 105a. These are referred to as a first threshold voltage and a first driving voltage region, respectively.

When the voltage corresponding to the first driving voltage region is applied to the gate 102 and the drain 104 at this time the source 103 may be fixed at 0 V and the drain 104 is activated by impact ionization, Excess holes (portions marked with + in Fig. 3) are generated in the side channels. The generated excess holes are embedded in the body of the first nanowire channel 105a since there is no place to escape. When the excess hole is filled, the threshold voltage and the current level differ from each other in the absence of holes, and the difference between the '0' state and the '1' state can be distinguished.

On the other hand, the second nanowire channel 105b located at the bottom also has a unique threshold voltage. The driving voltage region can be determined according to the intrinsic threshold voltage of the second nanowire channel 105b. This is referred to as a second threshold voltage and a second driving voltage region, respectively.

At this time, the first threshold voltage and the second threshold voltage may be different from each other, whereby the first driving voltage region and the second driving voltage region are different. To make the first and second threshold voltages have different values, the following scheme can be used.

(1) In forming a plurality of nanowire channels, different threshold voltages may be obtained by varying at least one of the kind, depth, concentration, and angle of the doping ions.

(2) When forming a plurality of nanowire channels, different threshold voltages may be obtained by changing shapes or areas of respective cross sections. At this time, in each nanowire channel forming step, by changing at least one of the kind of the etching material, the concentration of the etching material, the etching time, the degree of vacuum and the etching temperature, the shape (triangle, circle, rhombus, Can be made different.

The second nanowire channel 105b can be formed by applying a voltage corresponding to the second driving voltage region to the gate 102 and the drain 104 (the source 103 can be fixed at 0 V) An excess hole (a portion marked with + in Fig. 3) is generated in the channel on the side of the drain 104 by impact ionization. The excess holes produced are accumulated in the body of the second nanowire channel 105b since there is no place to escape. When the excess hole is filled, the threshold voltage and the current level differ from each other in the absence of holes, and the difference between the '0' state and the '1' state can be distinguished.

Control of the intrinsic operating voltage of each of the first nanowire channel 105a and the second nanowire channel 105b results in a '0' state in each of the first nanowire channel 105a and the second nanowire channel 105b Quot; 1 " state, it is possible to store 2-bit information. By expanding this, it is possible to store 2 n bits of information when n nanowire channels are provided, thereby achieving integration of the memory.

Hereinafter, with reference to FIGS. 4, 5A to 5E, and 6A to 6C, a method of forming a plurality of nanowire channels in a multi-bit capacitorless DRAM according to the present invention will be described.

4 is a perspective view illustrating a main configuration of a multi-bit capacitorless DRAM according to the present invention. As shown in FIG. 4, the multi-bit capacitorless DRAM according to the present invention may have a plurality of nanowire channels 105a to 105i. The configurations of the source 103, the drain 104 and the gate 102 are described above, and will not be described here. Although a gate insulating film (not shown) surrounding the nanowire channels 105a to 105i is not clearly shown in Fig. 4, this is achieved by the steps of Figs. 5A to 5E and the steps of Figs. 6A to 6C, After the channels 105a to 105i are formed, a gate insulating film formation process (not shown) may be performed.

First, a substrate 100 is provided as shown in FIG. 5A. The provided substrate 100 may be a single crystal silicon substrate. In addition, the substrate 100 may be n-type or p-type depending on the type of material and may be a bulk wafer, an insulating layer buried silicon wafer, an insulating layer buried germanium wafer, an insulating layer buried strained germanium wafer, An insulating layer buried strained silicon wafer, a wafer of a III-V (Group 3 and Group 5 element) material, and a silicon germanium (SiGe) wafer.

In this embodiment, for convenience of explanation, it is assumed that a p-type silicon substrate 100 is used.

When the substrate 100 is provided, the hard mask 10 is laminated, as shown in FIG. 5B. When the hard mask 10 is laminated, the photoresist 9 is again patterned.

Then, the hard mask 10 is etched using the stacked photoresist 9 as a protective film, and then the remaining photoresist 9 is removed. When this process is performed, the state shown in FIG. 5C is obtained. In a state where the photoresist film 9 is completely removed, an anisotropic etching is performed to form a region to be a nanowire channel, and then a passivation layer 20a is formed as shown in FIG. 5D . At this time, chlorine (Cl 2 ) gas may be used for the anisotropic etching. The protective film 20a may be a polymer-based C x F y gas, and may be octafluorocyclobutane (C 4 F 8 ), which is one of them. However, the material used for the anisotropic etching or the material used for the protective film 20a is not limited to the above-mentioned materials.

As a next step, isotropic etching is used to form a separate nanowire channel with the substrate 100, as shown in Figure 5E. 5A through 5E, one first nanowire channel 105a is formed. At this time, sulfur hexafluoride (SF 6 ) may be used for isotropic etching, but is not limited thereto.

FIGS. 6A through 6C illustrate a process of forming a plurality of nanowire channels by forming another nanowire channel below the nanowire channel 105a formed by the processes of FIGS. 5A through 5E.

As shown in FIG. 6A, after the first nanowire channel 105a is formed, anisotropic etching is again performed. At this time, chlorine (Cl 2 ) gas may be used for the anisotropic etching, but the present invention is not limited thereto.

Next, as shown in FIG. 6B, a protective film 20b is formed using polymer-based octafluorocyclobutane (C 4 F 8 ), and then, as shown in FIG. 6C, sulfur hexafluoride (SF 6 ) is used for the isotropic etching process. As a result, a second nanowire channel 105b spaced a predetermined distance is formed under the first nanowire channel 105a. When this process is performed nine times, a total of nine nanowire channels 105a to 105i are formed. However, this is merely an example, and a plurality of nanowire channels can be formed by various methods.

The following description will briefly describe a process in which a plurality of nanowire channels 105a to 105i are formed. After the plurality of nanowires 105a to 105i are formed, silicon oxide is deposited and chemical-mechanical polishing is performed.

Thereafter, a patterned photoresist film is formed to remove regions where the nanowire channels 105a to 105i are present, and the silicon oxide in the exposed regions is patterned by patterning the photoresist film to form trenches.

At this time, the step of removing the photoresist layer, controlling the size of the cross section of the nanowire channels 105a to 105i through sacrificial oxidation, and curing the damage caused in the etching process may be further performed have. Next, a gate insulating film (see reference numeral 101 in Figs. 1, 3 and 8a) is formed in the nanowire channel revealed through trench formation, and a gate layer is formed on the gate insulating film.

The gate insulating film 101 may be a silicon oxide film or a high-K film. More specifically, the gate insulating film 101 may be formed of silicon oxide, a nitride film, aluminum oxide, hafnium oxide, hafnium oxynitride, zinc oxide, lanthanum oxide (lanthanum oxide), hafnium silicon oxide (hafnium silicon oxide), and the like.

Meanwhile, the gate layer may be made of metal or polysilicon. That is, the gate layer is formed of a metal such as polysilicon, aluminum (Al), molybdenum (Mo), magnesium (Mg), chromium (Cr), palladium (Pd), gold (Au), platinum (Pt) Materials, but are not limited thereto.

Then, the region to be removed from the silicon oxide and the gate layer is a region where the source and the drain are to be formed, and accordingly, appropriate patterning is performed in consideration of this. A gate insulating layer 101 is present in a region where a plurality of nanowire channels 105a to 105i are formed, silicon oxide is formed on both sides, and a gate layer is formed on the top surface.

Thereafter, a heavily doped n + type impurity ion (group 5 element of the periodic table) or a p + type impurity ion (group 3 element of the periodic table) is implanted to form the doped gate 102 and the nanohole channel 105a to 105i Source 103 and drain 104 are formed.

 At this time, instead of using a high-concentration n-type ion (group 5 of the periodic table) implanted into polysilicon as a gate layer, a metal may be used. And hydrogen annealing to relax the nanowire-shaped surface roughness.

The processes after forming the plurality of nanowires 105a to 105i are not limited to the above-mentioned processes, and can be variously performed by applying known semiconductor manufacturing processes and methods. Some of the processes after the plurality of nanowire formation 105a to 105i may be omitted or replaced with other necessary processes, and in some cases, the order may be changed or a plurality of processes may be performed simultaneously .

Figures 7A and 7B show only a plurality of nanowire channels 105a through 105i formed. The plurality of nanowire channels 105a to 105i may be spaced apart from each other by a predetermined distance.

Although FIG. 7B shows a plurality of nanowire channels 105a through 105i in the same shape and area, they can be made different in shape and area by various methods.

For example, in the etching step during the process of forming the plurality of nanowire channels 105a to 105i, if the kind or concentration of the etching material is changed, or the etching time, the degree of vacuum, or the etching temperature is changed, So that the channels 105a to 105i can be formed. A plurality of nanowire channels formed by the above method are shown in Figures 8A and 8B.

8A and 8B are transmission electron micrographs of nanowire channels 105a-105f with different shapes or areas in a multi-bit capacitorless DRAM according to the present invention. A total of six nanowire channels 105a to 105f are provided. As shown in FIG. 8A, each nanowire channel 105a-105f is different in shape or area from each other. For example, the first nanowire channel 105a is shaped differently from the other nanowire channels 105b through 105f. In addition, each of the nanowire channels 105a to 105f has a larger area as it goes down. Accordingly, the nanowire channels 105a to 105f have different threshold voltages, and operate in different driving voltage regions. Here, the driving voltage means a drain voltage causing ionization collision and a gate voltage (VG READ) used for reading.

Although Figures 8A and 8B illustrate nanowire channels having different shapes or areas, in other embodiments, the threshold voltages of each nanowire channel can be made different by different ways. In FIG. 8B, a gate insulating film 101 formed on the nanowire channel 105 is also shown.

For example, when forming a nanowire channel, the threshold voltage of each nanowire channel can be made different by varying at least one of the type, depth, concentration, and angle of ions doped in each nanowire channel.

9A and 9B are graphs showing the operating voltage range of a multi-bit capacitorless DRAM according to the present invention. Assuming two nanowire channels, four regions of the '00' state, the '01' state, the '10' state, and the '11' state can be used as memories.

9A and 9B, when the difference in magnitude of the current between the '00' state and the '01' state is used as a memory, this is referred to as a 'first operation region' Is used as a memory, this is referred to as a " second operation area ".

As shown in Figure 9a, the DRAM in order to '11' in the program (PROGRAM) the state of the initial state, so that the V PROGRAM2 operating region corresponding to the drain voltage (V D) is used, and the initial state of the DRAM 01 ', The drain voltage (V D ) of V PROGRAM1 is used. Accordingly, the number of bits usable in the multi-bit capacitorless DRAM according to the present invention is two, and when the number of bits is increased and the number of the nanowire channels is increased, the memory operates as a memory capable of storing a larger number of bits . 9B shows actual data representing the drain voltage region measured from the actually fabricated device. The drain voltage V D for programming into the '11' state is about 5.5 V and the drain voltage for programming into the '01' state V D ) becomes approximately 5V. However, it should be apparent to those skilled in the art that the drain voltage (V D ) is not limited thereto, but may be varied depending on other factors such as the length, width, insulating film thickness, and the like of the nanowire channel.

A controller (not shown) for controlling the operation of the multi-bit capacitorless DRAM according to the present invention, and a storage unit (not shown) for storing a driving voltage for each of the plurality of nanowire channels. At this time, the driving voltage for each of the nanowire channels is based on the threshold voltage inherent to each channel as described above.

9A and 9B, a controller (not shown) controls the driving voltage applied to the gate 102 and the drain 104 to program two bits of data, erase. However, if a larger number of nanowire channels is provided, more than two bits of data may be programmed or erased.

FIG. 10A is a block diagram showing a configuration of an apparatus for measuring the operation of a multi-bit capacitorless DRAM according to the present invention. FIGS. 10B and 10C are diagrams showing, in each operation region (first operation region and second operation region) In pulse form.

The pulsed operation voltage input to the gate 102 and the drain 104 causes ionization collision phenomenon in each of the nanowire channels, thereby increasing the output current (source current I S ).

The state where the output current I S is relatively high is a program state, and the state where the output current is relatively low is an erase state.

The pulsed operating voltage input in the case of the first operating region is as shown in FIG. 10B. In order to program the multi-bit capacitorless DRAM according to the present invention into the '01' state, a drain voltage (V D ) of V PROGRAM1 of FIG. 9A is applied to the drain 104. Through the drain voltage (V D ) of V PROGRAM1 , the capacitorless DRAM programmed to the '01' state is again set to '00' by the erase voltage V ERASE1 .

On the other hand, the pulse-type operating voltage input in the case of the second operation region is as shown in FIG. In order to program the capacitor-less dynamic random access memory according to the present invention the "11" state, the drain 104 is applied to the drain voltage (V D) of V PROGRAM2 of Figure 9a. The capacitorless DRAM programmed to the '11' state through the drain voltage (V D ) of V PROGRAM2 is erased to the '10' state by the erase voltage V ERASE2 .

11A shows actual data in which the current value of the first operating region is output by the pulse-type operating voltage shown in FIG. 10B. That is, when the drain voltage (V D ) of the V PROGRAM 1 is input to the drain 104, an ionization collision phenomenon occurs in the corresponding nanowire channel, so that the source current I S , which is the output current, Corresponds to the drain current I D in the region ([Delta] I SENSING1 ).

FIG. 11B shows actual data for which the current value of the second operating region is output by the pulse-type operating voltage shown in FIG. 10C. That is, when the drain voltage V D of V PROGRAM 2 is input to the drain 104, an ionization collision phenomenon occurs in the corresponding nanowire channel, and thus the source current I S , which is the output current, Corresponds to the drain current I D in the region (ΔI SENSING 2 ).

As described above, according to the multi-bit capacitorless DRAM and the method of manufacturing the same according to the present invention, unlike a conventional memory that can store (process) only a single bit, it can operate with multiple bits of two or more bits, Not only improvement but also high integration can be achieved.

Finally, a method of manufacturing a multi-bit capacitorless DRAM according to the present invention will be described with reference to FIG.

First, a hard mask is deposited on the substrate (S200). Subsequently, at least a part of the hard mask is etched (S210), before the patterning process of the photoresist film can be performed.

Thereafter, an anisotropic etching is performed to form a region to be a nanowire channel, and then a passivation layer is formed (S220, S230).

At this time, chlorine (Cl 2 ) gas may be used for the anisotropic etching. The protective film may be a polymer-based C x F y gas, and may be octafluorocyclobutane (C 4 F 8 ), which is one of them. However, the material used as a gas or a protective film used for anisotropic etching is not limited to the above-mentioned materials.

As a next step, an isotropic etching is used to form a nanowire channel separated from the substrate (S240). In this manner, a plurality of nanowire channels are formed (S230) while repeating the processes of nanowire patterning (S220), protective film formation (S230), and nanowire channel formation (S240) using anisotropic etching.

At this time, the plurality of nanowire channels to be formed may each have a different threshold voltage.

In one embodiment, each time the nanowire channel is formed, dopants may be implanted with different dopant species, depth, concentration, and / or implantation angle to provide different threshold voltages. In another embodiment, each time a nanowire channel is formed, it may be possible to have a different threshold voltage, by varying at least one of the type of etchant material, the etchant concentration, the etch time, the degree of vacuum, and the etch temperature will be.

The features, structures, effects and the like described in the embodiments are included in one embodiment of the present invention and are not necessarily limited to only one embodiment. Furthermore, the features, structures, effects and the like illustrated in the embodiments can be combined and modified by other persons skilled in the art to which the embodiments belong. Accordingly, it is intended that the present invention cover the modifications and variations of this invention provided they come within the scope of the appended claims and their equivalents.

While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is clearly understood that the same is by way of illustration and example only and is not to be taken by way of illustration, It can be seen that various modifications and applications are possible. For example, each component specifically shown in the embodiments can be modified and implemented. It is to be understood that all changes and modifications that come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.

100 ......... substrate
101 ... insulating film
102 ‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥ gate
103 ‥‥‥‥‥ Source
104 ‥‥‥‥‥‥‥ drain
105 ‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥ Nanowire channel
106 ......... STI oxide layer

Claims (9)

Board;
A source and a drain formed on the substrate;
A plurality of nanowire channels formed on the substrate;
A gate insulating layer formed on the plurality of nanowire channels; And
And a gate formed on the gate insulating film,
Wherein at least two of the plurality of nanowire channels have different threshold voltages.
The method according to claim 1,
Wherein the two or more nanowire channels have different threshold voltages by differentiating at least one of the type, depth, concentration, and angle of the doping ions.
The method according to claim 1,
Wherein the two or more nanowire channels have different threshold voltages by different shapes or areas of cross-section.
The method according to claim 1,
Wherein the two or more nanowire channels are etched differently in at least one of the type of etchant material, the concentration of the etchant material, the etch time, the degree of vacuum, and the etch temperature, thereby having different cross-sectional shapes or areas.
The method according to claim 1,
A controller for controlling operation of the multi-bit capacitorless DRAM; And
Further comprising a storage for storing a driving voltage for each of the plurality of nanowire channels based on a threshold voltage of the plurality of nanowire channels,
The controller controls a driving voltage applied to at least one of the gate and the drain to program or erase data of two or more bits.
(a) depositing a hard mask on a substrate;
(b) etching at least a portion of the hard mask;
(c) patterning the nanowire on the substrate through an anisotropic etch;
(d) forming a protective film on the substrate;
(e) forming a nanowire channel in the substrate through isotropic etching;
(f) repeating the steps (c) and (e) to form a plurality of nanowire channels;
(g) forming a source, a drain, and a gate,
Wherein the step (f) processes each of the plurality of nanowire channels to be formed such that each of the plurality of nanowire channels has a different threshold voltage.
The method according to claim 6,
The step (f)
Each time a nanowire channel is formed, a dopant is implanted at least one of a type, a depth, a concentration, and an implant angle of doping ions, so that each of the plurality of nanowire channels is processed to have a different threshold voltage A method of manufacturing a capacitorless DRAM.
The method according to claim 6,
The step (f)
Treating each of the plurality of nanowire channels to have a different threshold voltage by varying at least one of the type of etchant material, the concentration of the etchant material, the etch time, the degree of vacuum, and the etch temperature each time the respective nanowire channel is formed A method of manufacturing a multi - bit capacitorless DRAM.
The method according to claim 6,
And forming a gate insulating film on the substrate prior to the step (g).
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