KR20170063205A - Composition for long-lasting perfume and comsmetic composition comprsing the same - Google Patents

Abstract

The present invention relates to a flavor-persistent composition comprising a low viscosity polyquaternium-10 or high viscosity polyquaternium-10 flavorant and a cosmetic composition comprising same.

Description

TECHNICAL FIELD [0001] The present invention relates to a perfume composition, and a cosmetic composition containing the same.

The present invention relates to an incense-persistent composition and a cosmetic composition comprising the same.

Generally, since the fragrance ingredient has a lower intensity of the fragrance with the passage of time, it is an important task to keep the fragrance ingredient for a long period of time. Especially, a cleaning product such as shampoo, body cleanser and soap, A wash-off type composition which is applied to the scalp immediately or after a certain period of time after application to the scalp, wherein the fragrance component is used in such a cleansing product, even if the cleansing product is rinsed off with water, Technology is required.

In order to solve this problem, there is a method of increasing the sustainability by capturing the volatile flavor by using the perfume retaining agent (Fixative), but this also causes the fragrance to be less refreshing.

There is also a way to increase the inversion rate of fragrance, but this is not a fundamental solution because it raises the cost of the product and most of the products are flushed with water.

Korean Patent Registration No. 1230933 (Feb.

DISCLOSURE OF THE INVENTION The present invention is intended to provide a fragrance-sustaining composition and a cosmetic composition containing the fragrance composition which are excellent in persistence even when washed in water and have a stable formulation.

The present invention relates to a perfume composition comprising a low viscosity polyquaternium-10 or a high viscosity polyquaternium-10 perfume sustainer, wherein the low viscosity is from 300 cps to 500 cps and the high viscosity is from 1000 cps to 2500 cps Lt; / RTI > composition.

The present invention also provides a wash-off type cosmetic composition comprising the fragrance-sustaining composition.

The fragrance-persistent composition according to the present invention and the wash-off type cosmetic composition containing the same exhibit excellent fragrance persistence that maintains the fragrance strength even when washed in water, while exhibiting low viscosity polyquaternium-10 or high viscosity polyquaternium-10 The formulation stability of the composition is excellent, including an incense-retaining agent.

Hereinafter, the flavor-persistent composition according to the present invention will be described in detail.

The names of the compounds referred to herein are to be understood as meaning the International Nomenclature Cosmetic (INCI) listed on the International Cosmetic Ingredient Dictionary (ICID) issued by the Cosmetic, Toiletry and Fragrance Association (CTFA) Ingredient Name means a compound according to the IUPAC nomenclature established by the International Union of Pure and Applied Chemistry (IUPAC) if the name does not exist in the INCI Name, Means a compound corresponding to the name of a compound commonly used in the technical field of the present invention unless the compound according to the IUPAC nomenclature is present.

The flavor-persistent composition according to the present invention comprises a flavourant. The flavoring agent is a low viscosity polyquaternium-10 or a high viscosity polyquaternium-10.

The low viscosity polyquaternium-10 according to the present invention has a viscosity of 300 cps to 500 cps.

The low viscosity polyquaternium-10 according to the present invention has a nitrogen content of 1.7 to 2.2% by weight based on the total weight of the low viscosity polyquaternium-10.

In this specification, the content of nitrogen means quantitative analysis using the Kjeldahl method.

The high viscosity polyquaternium-10 according to the present invention has a viscosity of 1000 cps to 2500 cps.

The high viscosity polyquaternium-10 according to the present invention has a nitrogen content of 1.7 to 2.2% by weight based on the total weight of the high viscosity polyquaternium-10.

In the present specification, the viscosity refers to a viscosity value measured at 25 ° C and 1 atm using a viscometer LVT-RV manufactured by Brookfield Engineering Laboratories, Inc.

In one embodiment of the invention, the viscosity of the flavor-persistent composition is from 3000 cps to 5000 cps.

In one embodiment of the present invention, the fragrance persistent is a mixture of the low viscosity polyquaternium-10 and the high viscosity polyquaternium-10.

Hereinafter, the cosmetic composition according to the present invention will be described in detail.

The cosmetic composition according to the present invention comprises the aforementioned fragrance-persistent composition and is of the wash-off type.

In the present specification, the wash-off type refers to a composition for applying the cosmetic composition to the skin or hair, and then immediately or after a certain period of time, cleaning and removing with a cleaning liquid such as water.

In one embodiment of the present invention, the cosmetic composition further comprises a flavoring agent.

In the present specification, the flavoring agent is not limited thereto as long as it contains a flavor component and can release the flavor component contained in the air, and may be a plant-derived, animal-derived or synthetic component, An essential oil form in which the fragrance component is purified from an animal is preferable.

The fragrance component may be selected from the group consisting of hexanal, heptanal, benzaldehyde,? -Myrcene, azulene, nonanal, decanal, p - p-cymene, etc., but it does not limit it if it can make the smell perceptible.

In one embodiment of the present invention, the cosmetic composition is any one or more formulations selected from the group consisting of shampoos, soaps, body cleansers and cleansing foams.

In one embodiment of the present invention, the cosmetic composition further comprises a higher fatty acid alkali salt. The higher fatty acid may be at least one selected from the group consisting of lauric acid, myristic acid, palmitic acid, stearic acid, and oleic acid, but is not limited thereto as long as it enhances the cleaning effect of the cosmetic composition.

In one embodiment of the present invention, the content of the higher fatty acid alkali salt is 5 wt% to 80 wt% based on the total weight of the cosmetic composition.

In one embodiment of the present invention, the cosmetic composition further comprises at least one surfactant selected from the group consisting of an anionic surfactant, a nonionic surfactant and an amphoteric surfactant, It is not limited thereto as long as it improves the foaming effect or the cleaning effect.

The anionic surfactant is not particularly limited as long as it can be used in a conventional cosmetic composition, and includes fatty acid soap (sodium laurate, sodium palmitate, etc.); Higher alkyl sulfate ester salts (sodium lauryl sulfate, potassium lauryl sulfate and the like); Alkyl ether sulfuric acid ester salts (POE-laurylsulfuric triethanolamine, POE-laurylsulfate, etc.); N-acyl sarcosinate (such as sodium lauroyl sarcosine); Higher fatty acid amide sulfonates (N-myristoyl-N-methyltaurin sodium, coconut fatty acid methyltauride sodium, laurylmethyltauride sodium and the like); Phosphoric acid ester salts (sodium POE-oleyl ether phosphate, POE-stearyl ether phosphoric acid, etc.); Sulfosuccinic acid salts (sodium di-2-ethylhexylsulfosuccinate, sodium monooroyl monoethanolamide polyoxyethylene sulfosuccinate, sodium lauroyl polypropylene glycol sulfosuccinic acid and the like); Alkylbenzenesulfonates (sodium linear decylbenzenesulfonate, triethanolamine linear decylbenzenesulfonate, linear decylbenzenesulfonic acid, etc.); Higher fatty acid ester sulfuric acid ester salts (such as hardened coconut oil fatty acid glycerin sodium sulfate); N-acyl glutamate (monosodium N-lauroyl glutamate, disodium N-stearoyl glutamate, monosodium N-myristoyl-L-glutamic acid, etc.); Sulfuric acid oil (lot oil, etc.); POE-alkyl ether carboxylic acid; POE-alkyl allyl ether carboxylate; ? -olefin sulfonate; Higher fatty acid ester sulfonates; Secondary alcohol sulfuric acid ester salts; Higher fatty acid alkylolamide sulfates; Sodium lauroyl monoethanolamide succinate; N-palmitoyl aspartic acid ditriethanolamine; And sodium caseinate, but the present invention is not limited thereto.

As the nonionic surfactant, a lipophilic nonionic surfactant or a hydrophilic nonionic surfactant can be used and is not particularly limited as long as it can be used in a conventional cosmetic composition. Examples of the lipophilic nonionic surfactant include sorbitan fatty acid Esters (such as sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbitan trioleate, penta-2 - ethylhexyl acid diglycerol sorbitan, tetra-2-ethylhexyl acid diglycerol sorbitan and the like); Glycerin polyglycerin fatty acids (monosaccharic fatty acid glycerin, monoelucic acid glycerin, sesquioleic acid glycerin, monostearic acid glycerin,?,? '- oleic acid pyroglutamic acid glycerin, monostearic acid glycerin malic acid, etc.); Propylene glycol fatty acid esters (such as propylene glycol monostearate); Hardened castor oil derivatives; Sorbitan fatty acid esters (POE-sorbitan monooleate, POE-sorbitan monostearate, POE-sorbitan tetraoleate and the like); hydrophilic nonionic surfactants such as polyoxyethylene sorbitan fatty acid esters POE-sorbit fatty acid esters (POE-sorbitol monolaurate, POE-sorbitol monooleate, POE-sorbitol pentaoleate, POE-sorbitol monostearate, and the like); POE-glycerin fatty acid esters (POE-glycerin monostearate, POE-glycerin monoisostearate, POE-glycerin triisostearate, etc.); POE-fatty acid esters (POE distearate, POE-monodioleate, ethylene glycol distearate, etc.); POE-alkyl ethers (POE-lauryl ether, POE-oleyl ether, POE-stearyl ether, POE-behenyl ether, POE-2-octyldodecyl ether, POE-cholestanol ether, etc.); Pluronic molds (Pluronic and the like); POE / POP-alkyl ethers (POE / POP-cetyl ether, POE / POP-2-decyltetradecyl ether, POE / POP-monobutyl ether, POE / POP-hydrogenated lanolin, POE / POP-glycerin ether and the like); Tetra POE tetra POP-ethylenediamine condensation products (such as Tetronic); POE-castor oil-hardened castor oil derivative (POE-castor oil, POE-hardened castor oil, POE-hardened castor oil free monoisostearate, POE-hardened castor oil free triisostearate, POE-hardened castor oil free monopyrroglutamate monoisoprene Stearic acid diester, POE-hardened castor oil free maleic acid); POE beeswax / lanolin derivatives (POE-sorbitol beeswax); Alkanolamides (coconut fatty acid diethanolamide, lauric acid monoethanolamide, fatty acid isopropanolamide, etc.); POE-propylene glycol fatty acid esters; POE-alkylamines; POE-fatty acid amide; Sucrose fatty acid esters; Alkylethoxydimethylamine oxides; And trioleylphosphoric acid, and the like, and may be any one or more selected from the group consisting of these, but the present invention is not limited thereto.

The amphoteric surfactant may be an imidazoline-type amphoteric surfactant (2-undecyl-N, N, N- (hydroxyethylcarboxymethyl) -2-imidazoline sodium, 2- Sodium hydroxide-1-carboxyethyloxy disodium salt and the like); And a betaine surfactant (2-heptadecyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, lauryldimethylaminoacetic acid betaine, alkylbetaine, amide betaine, sulfobetaine etc.) , But the present invention is not limited thereto.

In one embodiment of the present invention, the content of the surfactant is 0.1% by weight to 30% by weight based on the total weight of the cosmetic composition.

In one embodiment of the present invention, the cosmetic composition further comprises a wetting agent, and the wetting agent may be any one or more selected from the group consisting of glycerin, sorbitol, amorphous sorbitol, polyethylene glycol and propylene glycol, It is not limited thereto as long as it imparts a moisturizing effect.

In one embodiment of the present invention, the content of the wetting agent is 0.1 wt% to 20 wt% with respect to the total weight of the cosmetic composition.

In one embodiment of the present invention, the cosmetic composition further comprises a sequestering agent, wherein the sequestering agent is selected from the group consisting of a phosphate compound or EDTA, specifically, sodium phosphate, monosodium But are not limited to, monosodium phosphate, disodium phosphate, trisodium phosphate, tetrasodium etidronate, sodium triphosphate, sodium hexametaphosphate, tetra It may be any one or more selected from the group consisting of Tetrasodium pyrophosphate, Sodium acid pyrophosphate, Disodium EDTA, and Tetrasodium EDTA, Chelate metal ions to prevent shrinkage of the composition If it does not limit it.

In one embodiment of the present invention, the content of the sequestering agent is 0.01 wt% to 0.5 wt% with respect to the total weight of the cosmetic composition.

In one embodiment of the present invention, the cosmetic composition may be formulated further comprising a cosmetically or dermatologically acceptable medium or base. These compositions may be prepared according to conventional methods in the art.

In addition, the cosmetic composition according to the present invention may contain adjuvants conventionally used in the field of cosmetics or dermatology, such as any other ingredient commonly used in cosmetics. Such adjuvants are introduced in amounts commonly used in the cosmetics or dermatological fields.

Hereinafter, specific examples of examples, comparative examples and test examples will be described in order to facilitate understanding of the present invention. However, the following examples should not be construed as limiting the invention, and ordinary variations of the person skilled in the art are possible within the scope of the invention.

[Experimental Example 1] Oil adsorption ability of an incense-retaining composition

In order to measure the adsorbing ability of the fragrance component, specifically essential oil, the oil base and the polymer component were mixed as shown in Table 1, and the remaining amount of the sunflower oil was quantified by the Rubindi method and expressed as R value.

Ingredients R value when containing oil R value when containing oil Base ^{1 )} 2.4 3.6 Base + guar hydroxypropyl trimonium chloride ^{2 )} 7.5 9.3 Base + guar hydroxypropyltrimonium chloride ^{3 )} 8.3 6.4 Base + polyquaternium -4 ⁴⁾ 13.7 5.2 Base + polyquaternium-6 ⁵⁾ 9 12.3 Base + polyquaternium-7 ⁶⁾ 6.2 6.8 Base + High Viscosity Polyquaternium-10 ⁷⁾ 39.1 24.3 Base + low viscosity polyquaternium -10 ⁸⁾ 23.2 12.4 Base + polyquaternium-11 ⁹⁾ 7.5 9.5 Base + Polyquaternium-22 ¹⁰⁾ 7.4 12.2 Base + polyquaternium-51 ¹¹⁾ 2.8 3.3 Base + polyquaternium-62 ¹²⁾ 2.1 1.7

1) 15% by weight of ALES, 15% by weight of Sunflower oil (Archer Daniels Midland Company, (PF1) Refined Sunflower Oil), 17% by weight of M-CA, 5% by weight of CME, 3.5% by weight of stearyl alcohol, %, Purified water 15% by weight / the following polymers 2) to 12) described later are the same as the composition of the above 1) except that 15% by weight of purified water in the composition of the above 1) Do.

2) KCI limited / Guarquat L80KC

3) Ashland Inc./N-HANCE 3299

4) Akzo Nobel N.V./CELQUAT H-100

5) BASF SE / Salcare SC 30

6) Solvay S.A./MIRAPOL 550SB

7) KCI limited / POLYQUTA 3000KC

8) Miwon Commercial Co., Ltd./MICONIUM PQ10-J400

9) Ashland Inc./GAFQUAT 755N

10) Lubrizol Corporation / Merquat 295

11) NOF America Corporation / Lipidure-PMB-DK

12) AMOREPICIPICK Corporation / Nanoaquasome

As shown in Table 1, it was confirmed that the high viscosity polyquaternium-10 and the low viscosity polyquaternium-10 according to the present invention had the highest amount of adsorbed oil.

 [Preparation Example 1] Preparation of wash-off type cosmetic composition

The compositions of Examples 1 to 3 and Comparative Examples 1 and 2 were prepared according to the compositions shown in Table 2 below. agi mixer at a temperature of 45 ° C. In the case of Examples 1 to 3, low-viscosity polyquaternium-10 and / or high-viscosity polyquaternium-10 were first dissolved in distilled water, .

Ingredients Example 1 Example 2 Example 3 Comparative Example 1 Comparative Example 2 Distilled water 46.88 46.88 46.78 48.38 46.98 Low viscosity polyquaternium-10 ¹⁾ 0.1 - 0.1 - - High viscosity polyquaternium-10 ²⁾ - 0.1 0.1 - - Sorbitol ^{3 )} 5 5 5 5 5 Disodium edetate ^{4 )} 0.05 0.05 0.05 0.05 0.05 Ammonium laureth (3) Sulfate ^{5 )} 30 30 30 30 30 Ammonium laureth sulfate ^{6 )} 5 5 5 5 5 Cocamidopropyl betaine ^{7 )} 10 10 10 10 10 Cherry blossom ^{8 )} 1.4 1.4 1.4 - 1.4 Polyquaternium-7 ⁹⁾ One One One One One Methylchloroisothiazolinone / methylisothiazolinone ¹⁰⁾ 0.02 0.02 0.02 0.02 0.02 Phenoxyethanol ¹¹⁾ 0.2 0.2 0.2 0.2 0.2 Citric acid monohydrate ^{12 )} 0.05 0.05 0.05 0.05 0.05 Sodium chloride ^{13 )} 0.3 0.3 0.3 0.3 0.3 Sum 100 100 100 100 100

1) Miwon Commercial Co., Ltd./MICONIUM PQ10-J400

2) KCI limited / POLYQUTA 3000KC

3) Baekwang Industry / SORBITOL (NEOSORB 70/70)

4) Neod Corporation / E.D.T.A.-2NA

5) Miwon Commercial Co., Ltd./MICOLIN EA525

6) Miwon Commercial Co., Ltd./MICOLIN A-526

7) Miwon Commercial Co., Ltd./MITAINECE (S)

8) Solvay / MIRAPOL 550 SB

9) Solvay S.A./MIRAPOL 550SB

10) KCI limited / PRESER 150KC

11) clariant / PHENOXYETHANOL P5

12) Sammi CAM / CITRIC ACID Monohydrate

13) Hanju Corporation / SALT

 [Test Example 1] Sensory evaluation of fecal sustainability

1) The synthetic leather was cut into a size of 10 cm x 10 cm.

2) The cut synthetic leather was immersed in 95% alcohol for 1 hour to remove the synthetic leather itself.

3) The deposited synthetic leather was dried at room temperature for 12 hours.

4) 2 g of the composition of Example 1 prepared in Reference Example was rubbed on synthetic leather for 1 minute, and then the applied composition was exposed to flowing water for 10 seconds to wash the applied composition.

5) 4) was repeated three times in total.

6) The synthetic leather was dried at room temperature for 12 hours.

7) The procedures of 1) to 6) were also carried out for the compositions of Examples 2 and 3 and Comparative Examples 1 and 2 prepared in Reference Example instead of the composition of Example 1, respectively.

8) Synthetic leather subjected to the processes 1) to 7) for the compositions of Examples 1 to 3 and Comparative Examples 1 and 2 was applied to an organoleptic evaluation team composed of 12 perfume experts and 6 non-perfume experts, The fragrance intensities of the synthetic pellets were evaluated from 0 to 5, and the average scores of the compositions for the total sensory evaluation were shown in Table 4 below.

Synthetic leather application composition Average score of sensory sensory evaluation Example 1 1.7 Example 2 2.6 Example 3 3.3

 [Test Example 2] Evaluation of fecal sustainability

1) Artificial skin of VITRO-SKIN manufactured by IMS Inc. was cut into a size of 10 cm x 10 cm.

2) The cut artificial skin was immersed in a glycerin-distilled water solution for 17 hours.

3) 1 g of the composition of Example 1 prepared in Reference Example was rubbed on the artificial skin for 1 minute, and then the applied composition was exposed to flowing water for 10 seconds to wash the applied composition.

4) The procedure 3) was repeated twice in total.

5) Artificial skin was allowed to dry at room temperature for 12 hours.

6) 0.6 g of artificial skin dried in 6) was collected.

7) SPME fiber (65 μm PDMS / DVB, Sigma-Aldrich Corporation, SUPELCO) was equilibrated at 50 ° C for one minute, and the fragrance components were adsorbed to the SPME fiber at 60 ° C for 5 minutes in the artificial skin.

8) The SPME fiber adsorbed on the fragrance component was desorbed at the inlet of GC-MS, product name GC-MS SYSYEM manufactured by Agilent Technologies, Inc., at 240 ° C for 5 minutes, and then the fragrance component was detected by GC-MS.

9) The procedures of 1) to 8) were carried out for the compositions of Examples 2 and 3 and Comparative Examples 1 and 2 prepared in Reference Example instead of the composition of Example 1, respectively. The artificial skin without any treatment was also subjected to the procedures of 6) to 8) as a negative control group, and the results are shown in Table 5 below.

The contents of the following Table 5 are expressed as relative mass based on the measured desorption mass of the cherry flavor which is a flavor component.

Detection concentration (μg / mL) content (%) Negative control group Not detected - Comparative Example 1 Not detected - Comparative Example 2 149.7 0.346 Example 1 145.9 0.339 Example 2 175.8 0.433

Claims (4)

10. A flavor-persistent composition comprising a low viscosity polyquaternium-10 or high viscosity polyquaternium-10 flavorant,
Wherein the low viscosity is from 300 cps to 500 cps,
Wherein the high viscosity is from 1000 cps to 2500 cps. The method according to claim 1,
Wherein the flavorant is a mixture of the low viscosity polyquaternium-10 and the high viscosity polyquaternium-10. A wash-off type cosmetic composition comprising the flavor-retaining composition of claim 1 or 2. The method of claim 3,
Wherein the cosmetic composition is at least one selected from the group consisting of shampoos, soaps, body cleansers and cleansing foams.