KR20170038291A - Foamed material with nonwoven fabric layer on one side or both sides and cosmetics comprising the same - Google Patents

Foamed material with nonwoven fabric layer on one side or both sides and cosmetics comprising the same Download PDF

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Publication number
KR20170038291A
KR20170038291A KR1020150137442A KR20150137442A KR20170038291A KR 20170038291 A KR20170038291 A KR 20170038291A KR 1020150137442 A KR1020150137442 A KR 1020150137442A KR 20150137442 A KR20150137442 A KR 20150137442A KR 20170038291 A KR20170038291 A KR 20170038291A
Authority
KR
South Korea
Prior art keywords
foam
cosmetic
nonwoven fabric
cosmetic composition
present
Prior art date
Application number
KR1020150137442A
Other languages
Korean (ko)
Inventor
안태환
최민호
김진일
Original Assignee
코오롱인더스트리 주식회사
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 코오롱인더스트리 주식회사 filed Critical 코오롱인더스트리 주식회사
Priority to KR1020150137442A priority Critical patent/KR20170038291A/en
Publication of KR20170038291A publication Critical patent/KR20170038291A/en

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Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D34/00Containers or accessories specially adapted for handling liquid toiletry or cosmetic substances, e.g. perfumes
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0241Containing particulates characterized by their shape and/or structure
    • A61K8/0279Porous; Hollow
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/046Aerosols; Foams
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/87Polyurethanes
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/87Application Devices; Containers; Packaging

Abstract

The present invention relates to a foam having a non-woven layer on one side or both sides and a cosmetic comprising the foam. The foam of the present invention is harmless to the human body and has excellent physical properties such as chemical resistance, shape retention, durability, elasticity, feel and the like. In addition, when the present invention is used for supporting a cosmetic, the cosmetic composition is well filled, the cosmetic composition can be homogeneously carried for a long period of time, and a proper amount of the cosmetic composition can be discharged when the cosmetic composition is taken, . Therefore, when the foam according to the present invention is used, the cosmetic composition can be easily carried or used, so that it can be easily creased even when going out.

Description

FIELD OF THE INVENTION [0001] The present invention relates to a foam having a nonwoven fabric layer on one side or both sides thereof, and a cosmetic product containing the foam. BACKGROUND OF THE INVENTION 1. Field of the Invention [0002]

The present invention relates to a foam having a non-woven layer on one side or both sides and a cosmetic comprising the foam.

The foam and the sponge are materials having a porous structure. Due to their structure, they are well absorbed, elastic, and shock-absorbable, and are used for various purposes such as automobiles, electronics, industrial and household products, cosmetics, It is required to develop a foam using a new material according to

Materials such as polyurethane, NBR, SBR, NR, PVA, EVA, and sea surface are used as a kind of cosmetic tool that uses a cosmetic foam for carrying cosmetic material or applying cosmetic material to the skin. It is necessary to develop suitable materials such as chemical resistance, durability, and feeling according to cosmetic formulation and use.

BACKGROUND ART [0002] In the past, cosmetic compositions were filled and packed in vacuum containers, pump containers or glass containers. However, recently, as the frequency of use of cosmetic compositions increases, A demand for a convenient cosmetic composition is increasing.

In order to make use of the cosmetic composition and convenience of carrying it, the cosmetic composition was carried on sponge made of various materials, but it was not easy to find a material excellent in terms of durability, chemical resistance, filling ability, retention ability and exhausting ability. Therefore, there is a need to develop a material suitable for supporting a cosmetic composition, and research on this has been continued.

Korean Patent Publication No. 10-2013-0083852

In order to solve the problems of the prior art as described above, it is an object of the present invention to provide a foam excellent in durability, chemical resistance, elasticity and feeling.

It is another object of the present invention to provide a cosmetic comprising the foam having excellent durability, chemical resistance, elasticity and feeling (uniformly discharging cosmetic composition).

In order to achieve the above object,

The present invention provides a foam having a porous structure, which has a nonwoven fabric layer on one side or both sides.

In one embodiment, the foam having a porous structure is a polyether ester elastomer, a polyurethane, an acrylonitrile-butadiene rubber (NBR), a styrene butadiene rubber (SBR), a natural rubber (NR), polyvinyl chloride, polyethylene, an ethylene vinyl acetate ), One selected from the group consisting of silicone, latex, film type, styrene isoprene styrene (SIS), styrene ethylene butylene styrene (SEBS), polyvinyl alcohol (PVA), silicone elastomer, nitrile, butyl, polyether and neoprene Or more.

In another embodiment, the foam may be a cosmetic material.

In another embodiment, the foam may be a cosmetic application.

In another embodiment, the material of the foam may further comprise an antibacterial material.

In another embodiment, the nonwoven fabric layer may be at least one material selected from the group consisting of polyether ester, polyester, polypropylene, nylon and polyurethane.

In another embodiment, the nonwoven layer may comprise an antimicrobial material.

The present invention also provides a cosmetic comprising the foam and the cosmetic composition carried on the foam.

The foam of the present invention is harmless to the human body and has excellent physical properties such as chemical resistance, shape retention, and durability. In addition, when the present invention is used for supporting a cosmetic, the cosmetic composition is well filled, the cosmetic composition can be homogeneously carried for a long period of time, and a proper amount of the cosmetic composition can be discharged when the cosmetic composition is taken, . Therefore, when the foam according to the present invention is used, the cosmetic composition can be easily carried or used, so that it can be easily creased even when going out.

The present invention relates to a foam having a non-woven layer on one side or both sides and a cosmetic comprising the foam.

The present invention is characterized by further improving the physical properties such as durability, chemical resistance, elasticity, feeling of use (uniformly discharging cosmetic composition) by having a nonwoven fabric layer on one side or both sides of a foam having a porous structure.

Hereinafter, the present invention will be described in detail.

The present invention provides a foam having a porous structure, which has a nonwoven fabric layer on one side or both sides.

The porous structure refers to a state having a lot of small pores inside or on the surface. The shape and the number of the pores may vary depending on the kind of the cosmetic composition, and the structure may be different depending on the shape of the foam. For example, the porous structure may have a three-dimensional network structure, an open cell shape, or the like.

The foam may be formed by foaming a specific polymer resin. In addition, porosity can be formed by putting a specific substance in it and then dissolving it or removing the substance through chemical reaction or the like. In addition, the resin may be processed into a nonwoven fabric, or the particulate resin may be sintered to form pores. However, the present invention is not particularly limited thereto, and can be produced by methods known in the art.

When the foam is formed by foaming, the foam process can be controlled to control the pore size and porosity of the foam, distribution of pores, density and the like according to the application. Generally, according to the art, foaming is possible by appropriately adjusting the amount and type of foaming agent, kind and amount of foaming gas, foaming temperature and pressure, and other additives, and such control is obvious to those skilled in the art.

In addition, the foam may have a number of pores of 5 to 2000 ppi (part per inch), a pore size of 0.01 to 5 mm, and a density of 0.01 to 0.5 g / cm 3, which can be appropriately adjusted according to the composition of the cosmetic.

The material of the foam may be a conventionally used polymer resin and is preferably a polyether ester elastomer, a polyurethane, an acrylonitrile-butadiene rubber (NBR), a styrene butadiene rubber (SBR), a natural rubber (NR) , Polyethylene, EVA (Ethylene Vinyl Acetate), silicone, latex, film type, SIS (Styrene Isoprene Styrene), SEBS (Styrene Ethylene Butylene Styrene), PVA (Polyvinyl Alcohol), silicone elastomer, nitrile, butyl, polyether and neoprene Or a material containing at least one member selected from the group consisting of For example, the material of the foam may be made of a polyether ester elastomer alone or may be a mixture of a polyetherester elastomer and a polyurethane. In addition, the polymer resin may contain additives such as an antibacterial material. Examples of the antibacterial material include urushiol, cardanol, polyol derived from castor oil, and silver nanofibers.

The polyetherester elastomer resin, which is one example of the material of the foam, includes a hard segment composed of a diol and a dicarboxylate (or dicarboxylic acid), a soft segment composed of a polyol and a dicarboxylate (or dicarboxylic acid) But is not limited thereto. Specifically, a polyetherester elastomer resin having a hard segment of butanediol and dimethyl terephthalate and a soft segment of a polyether polyol and a dimethyl terephthalate may be used as the elastomer resin, A high molecular weight polyetherester elastomer resin can be prepared by subjecting a diol and a polyol to a first ester exchange reaction (or an esterification reaction), and then polycondensing the diol and the polyol in a separate reactor. The kind of the diol and the polyol are not particularly limited, and they may be used alone or in combination of two or more. Examples of the dicarboxylate (or dicarboxylic acid) include dimethylterephthalate, terephthalic acid, dimethyl isophthalate, isophthalic acid, dimethyl naphthalate, naphthalene dicarboxylic acid, adipic acid, azelaic acid, (Butylene glycol), monoethylene glycol, diethylene glycol, propylene glycol, and neopentyl glycol, and examples of the polyol may be polytetramethylene glycol, polyethylene glycol, polypropylene glycol, and the like. .

Examples of the material of the foam include polyether-based urethane and polyester-based urethane.

The nonwoven fabric refers to a nonwoven fabric prepared by directly spinning fibers constituted by the nonwoven fabric manufacturing method, and the nonwoven fabric may be a spunbond nonwoven fabric or a melt-brown nonwoven fabric.

As an example of the nonwoven fabric, the spunbond nonwoven fabric means a nonwoven fabric manufactured by a spunbond method as a method of bonding webs. The spunbond method is a method in which a polymer for producing fibers is directly melted and sprayed and then bonded with heat or physical force to form a nonwoven fabric. The fibers are long connected during the spraying process.

The spunbond nonwoven fabric is not particularly limited and can be produced by a method known in the art. An example of a method for producing a spunbonded nonwoven fabric is as follows:

In the spinning process, the polymer is melted to have a constant viscosity in the spinner, then supplied to the filter device and radiated as a continuous filament through the spinning nozzle, and is transferred to the cooling chamber when the filament is radiated from the spinneret. The air stream flows through the filaments and the melted filaments become solidified. In the spunbond nonwoven fabric manufacturing method, the high-speed air stream is supplied in parallel to the filaments to stretch the individual filaments, so that the filament can be stretched and cooled by a single process.

Since the fibers are connected without breaking, the spunbond nonwoven fabric is excellent in tensile strength, durability and chemical resistance, and therefore, the foam having a spunbond layer on one side or both sides has durability, chemical resistance, elasticity, In terms of physical properties.

The thermoplastic polymer may be used as a raw material of the nonwoven fabric. Preferably, a polyetherester, a polyester, a polypropylene, a nylon, and a polyurethane may be used.

Antibacterial materials such as urushiol, cardanol, polyol derived from castor oil, silver nanofibers and the like may be added to the raw material of the nonwoven fabric.

The nonwoven layer positioned on one side or both sides of the foam means a layer made of a nonwoven fabric and the nonwoven layer can be bonded to one side or both sides of the foam by various methods known in the art, A meltblown nonwoven fabric manufactured by a manufacturing method can also be applied as the nonwoven fabric layer of the present invention. For example, the thermoplastic fiber having a low melting point may be melted to bond the nonwoven fabric layer to one side or both sides of the foam. The ultrasonic bonding or infrared ray applicator may be used as the mechanism used in the heat sealing method, but the present invention is not limited thereto .

The fiber diameter of the nonwoven fabric may be 0.3 to 30 탆, preferably 1 to 20 탆.

The density of the nonwoven fabric may be 0.03 to 0.4 g / m 2 , preferably 0.05 to 0.2 g / m 2 .

The foam may be used for cosmetics. The ease of carrying the cosmetics means that the cosmetics are stored and carried by the user before use, and when the user uses the cosmetics, an appropriate amount of cosmetics should be discharged and applied to the skin. At this time, the foam for supporting the cosmetic may be applied to the skin by being put on the cosmetic application port (also referred to as puff), or may be applied directly in contact with the skin without a separate applicator. That is, the foam for use in cosmetics needs to have chemical resistance, durability, filling ability, retention ability, dischargeability, and the like.

The cosmetic composition may be a cosmetic composition of water in oil in which water is dispersed in the form of an external oil. By controlling the ratio of oil to water, it is possible to control the physical properties such as viscosity, the degree of loading on the porous foam, and the degree of discharge during pressurization. However, in accordance with the viscosity of the present invention, cosmetic materials such as an underwater type, solubilized type, and oil type can be used as well as a water-in-oil type cosmetic.

The foam may also be used for cosmetic application. The ease of application of the cosmetic is intended to apply the cosmetic composition to the user's skin at the time of use, that is, another cosmetic is put on the application port to bring the applicator into contact with the skin, thereby delivering the cosmetic to the skin.

The present invention also provides a foam having a porous structure, which has a nonwoven fabric layer on one side or both sides thereof, and a cosmetic product comprising the foamed cosmetic composition.

The above-mentioned support refers to holding and holding an arbitrary substance or component.

The cosmetic composition of the present invention can be used as a makeup primer, a makeup base, a foundation, a skin cover, a lipstick, a lip gloss, a face powder, a lip liner pencil, an Ibron pencil, an eye shadow, a cheek collar, a compact powder, a twin cake, , Eye shadow, concealer, blusher, powder foundation, lotion, skin or airless formulation, and the like.

When the cosmetic composition is in a liquid phase, it tends to be difficult to carry and store when it is in a solid state. However, when a cosmetic composition containing the foam of the present invention is used, it is preferable that the liquid cosmetic composition and the cream- can do. When the cosmetic composition is in a solid phase, it can be supported on the foam to reduce instantaneous changes in properties of the solid phase due to external impacts such as heat or allergies. When the cosmetic composition is used, the foam serves to fix the contents, There are advantages to be able to.

Hereinafter, the present invention will be described in more detail with reference to Production Examples and Examples. However, the following Preparation Examples and Examples are for illustrating the present invention, and the present invention is not limited by the following Production Examples and Examples, and can be variously modified and changed.

Manufacturing example  One. Cosmetics  Preparation of composition

A W / O emulsion type composition was prepared by a conventional method in the art.

Manufacturing example  2. Spun bond  Production of nonwoven fabric

A spunbonded nonwoven fabric was prepared by a conventional method in the art.

Example  One. Polyether ester  Fabrication of foam foamed with elastomer resin

The transesterification reaction was carried out while introducing dimethylterephthalate, butanediol and polytetramethylene glycol constituting a soft segment of the elastomer into an ester exchange reactor, adding tetrabutoxytitanate (TBT) as an ester exchange reaction catalyst, and heating the mixture .

After completion of the ester exchange reaction, tetrabutoxytitanate (TBT) was uniformly added to the oligomer prepared as a polycondensation catalyst and transferred to a polycondensation reaction tube using a transfer pipe. (3- (3,5-di-tert-butyl-4-hydroxyphenyl-propionamide) as an antioxidant by using an injection device in transferring the prepolymer. ) And N, N'-trimethylenebis- (3-3,5-di-t-butyl-4-hydroxyphenyl) propionamide) were dispersed in butanediol.

The prepolymer mixture transferred to the polycondensation reaction tube was subjected to condensation polymerization stepwise while being depressurized to prepare a polyetherester elastomer resin.

Thereafter, foams were foamed according to a generally known method in the art to foam polyetherester elastomer resin.

Example  2. On one side Spun bond The nonwoven fabric layer  Manufacture of foam having

2-1.

A foam having a spunbonded nonwoven fabric layer having a fiber diameter of 10 mu m and a density of 0.15 gr / m < 2 > on one side was bonded to the foam prepared in Example 1 and the spunbonded nonwoven fabric of Production Example 1 using a heat fusion method, .

2-2.

The polyether-based urethane foam and the spunbonded nonwoven fabric of Preparation Example 1 were bonded to each other using a thermal fusion method to prepare a foam having a spunbonded nonwoven fabric layer having a fiber diameter of 10 mu m and a density of 0.15 g / m < 2 > .

Claims (8)

A foam having a porous structure, characterized in that it has a non-woven layer on one side or both sides. The method according to claim 1,
The foam having the porous structure may be selected from the group consisting of a polyether ester elastomer, a polyurethane, an acrylonitrile-butadiene rubber (NBR), a styrene butadiene rubber (SBR), a natural rubber (NR), polyvinyl chloride, polyethylene, EVA (Ethylene Vinyl Acetate) , At least one selected from the group consisting of latex, film type, SIS (Styrene Isoprene Styrene), SEBS (Styrene Ethylene Butylene Styrene), PVA (polyvinyl alcohol), silicone elastomer, nitrile, butyl, polyether and neoprene Wherein the foam is made of a material selected from the group consisting of:
The method according to claim 1,
Wherein the foam is for supporting a cosmetic.
The method according to claim 1,
Wherein the foam is for application to cosmetics.
3. The method of claim 2,
Wherein the foam material further comprises an antimicrobial material.
The method according to claim 1,
Wherein the nonwoven fabric layer is at least one material selected from the group consisting of polyether ester, polyester, polypropylene, nylon and polyurethane.
The method according to claim 1,
Wherein the nonwoven fabric layer comprises an antimicrobial material.
A cosmetic comprising the foam according to claim 1, and a cosmetic composition supported on the foam.
KR1020150137442A 2015-09-30 2015-09-30 Foamed material with nonwoven fabric layer on one side or both sides and cosmetics comprising the same KR20170038291A (en)

Priority Applications (1)

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KR1020150137442A KR20170038291A (en) 2015-09-30 2015-09-30 Foamed material with nonwoven fabric layer on one side or both sides and cosmetics comprising the same

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Application Number Priority Date Filing Date Title
KR1020150137442A KR20170038291A (en) 2015-09-30 2015-09-30 Foamed material with nonwoven fabric layer on one side or both sides and cosmetics comprising the same

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20190050172A (en) * 2017-11-02 2019-05-10 경기대학교 산학협력단 Hydro colloid composition for medical use, medical dressing including the hydro colloid composition
KR20190068041A (en) 2017-12-08 2019-06-18 (주)아모레퍼시픽 Carrier unit having improved elasticity and cosmetic goods comprising the same

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20130083852A (en) 2012-01-13 2013-07-23 (주)아모레퍼시픽 Carrier for cosmetic composition comprising foamed urethane layer structure

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20130083852A (en) 2012-01-13 2013-07-23 (주)아모레퍼시픽 Carrier for cosmetic composition comprising foamed urethane layer structure

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20190050172A (en) * 2017-11-02 2019-05-10 경기대학교 산학협력단 Hydro colloid composition for medical use, medical dressing including the hydro colloid composition
KR20190068041A (en) 2017-12-08 2019-06-18 (주)아모레퍼시픽 Carrier unit having improved elasticity and cosmetic goods comprising the same

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