KR20170020134A - Polymer resin composition and molded product thereof - Google Patents
Polymer resin composition and molded product thereof Download PDFInfo
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- KR20170020134A KR20170020134A KR1020150114934A KR20150114934A KR20170020134A KR 20170020134 A KR20170020134 A KR 20170020134A KR 1020150114934 A KR1020150114934 A KR 1020150114934A KR 20150114934 A KR20150114934 A KR 20150114934A KR 20170020134 A KR20170020134 A KR 20170020134A
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08K5/00—Use of organic ingredients
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
- C08L67/03—Polyesters derived from dicarboxylic acids and dihydroxy compounds the dicarboxylic acids and dihydroxy compounds having the carboxyl- and the hydroxy groups directly linked to aromatic rings
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
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Abstract
Description
The present invention relates to a polymer resin composition and a molded article using the same, and more particularly, to an environmentally friendly polymer resin composition having excellent heat resistance and appearance quality and a molded article using the same.
The polyamide (PA) resin is a linear polymeric material having repetition of an amide bond (-CO-NH-) as a main chain and is called nylon resin. PA resin is a type of engineering plastics and has excellent mechanical properties, especially chemical resistance, friction and abrasion resistance, and is widely used in general machine parts, automobile parts, electric parts and sports goods. Examples of such PA resins include nylon 6 formed by ring-opening polymerization of e-caprolactam, nylon 66 formed by ring-opening polymerization of adipic acid and hexamethylenediamine.
The PA resin is mixed with a polyester resin to improve the impact resistance and the heat resistance. However, since the PA resin and the polyester resin are not compatible with each other, the PA resin and the polyester resin are liable to be phase-separated during blending and induce an esterification reaction by melt blending or the like, Is difficult to obtain. Further, in the case of a transparent polyester, transparency deteriorates due to the inclusion of an amide component. Therefore, much research has been conducted to improve the compatibility of the PA resin and the polyester-based resin and to synthesize a copolymer that complements the physical properties of the two resins. For example, Japanese Patent Laid-Open Publication No. 51-103191 discloses a method of melt-blending polybutylene terephthalate (PBT) and nylon 6, followed by solid phase polymerization to improve the mechanical properties of the copolymer US Patent No. 5,102,935 discloses a method of forming a copolymer by inducing an ester-amide exchange reaction using p-toluenesulfone (TsOH) while melt-blending polyethylene terephthalate (PET) and nylon 66 Lt; / RTI >
However, conventional PA resins are oil-based and therefore not environmentally friendly, and generate a large amount of CO 2 when incinerated. As such, petroleum-based resins cause environmental problems such as global warming and abnormal weather, so it is required to develop environmentally friendly resin compositions that do not generate CO 2 while maintaining the merits of conventional petroleum-based resins.
Accordingly, the inventors of the present invention confirmed that a polymer resin having excellent heat resistance and appearance quality can be produced by using glass fiber (GF) and other additional resin together with the polyamide 56 resin produced from the biomass, Respectively.
An object of the present invention is to provide a polymer resin composition that is eco-friendly, has excellent heat resistance and appearance quality and can replace conventional petroleum products.
Another object of the present invention is to provide a molded product of a polymer resin containing the above composition.
In order to accomplish the above object, the present invention provides a polyamide composition comprising (A) polyamide 56 (PA 56); (B) at least one selected from the group consisting of polyester, polyamide 6 (PA 6) and polyamide 66 (PA 66); And (C) glass fiber (GF).
In order to accomplish the above other objects, the present invention provides a molded product of a polymer resin comprising the above composition.
The polymer resin composition according to the present invention is eco-friendly, and has excellent heat resistance and appearance quality, so that it can replace petroleum-based plastics in various fields such as automobile parts.
1 and 2 are scanning electron microscope (SEM) images of a molded article obtained from the polymer resin composition of Example 1 and Comparative Example 1, respectively.
The present invention relates to polyamide 56 (PA 56); At least one selected from the group consisting of polyester, polyamide 6 (PA 6) and polyamide 66 (PA 66); And a glass fiber (GF).
Hereinafter, each component will be described in detail.
Polyamide 56 (also referred to as 'nylon 56'), a component used in the resin composition according to the present invention, is a biomass-based nylon obtained from plants. The polyamide 56 has characteristics similar to those of polyamide 6 or polyamide 66 which is nylon derived from petroleum, and has excellent strength and heat resistance, so that they can be used instead. In addition, since the molded articles containing the polyamide 56 are excellent in biodegradability and environmentally friendly, it is possible to prevent the occurrence of environmental problems such as global warming and abnormal weather caused by a sudden increase in the concentration of carbon dioxide in the atmosphere.
Details of the production method and the like of the polyamide 56 are disclosed in Chinese patent application publication CN 103980486 A. Polyamide 56 can be prepared by replacing hexamethylenediamine, one of the petroleum reagents, with pentamethylenediamine, a biosynthetic intermediate. The polyamide 56 was produced by Cathay Industrial Biotech under the name " Terryl ™ PA56 ".
The polyester which is a component used in the resin composition according to the present invention is used as an application for improving the appearance quality of a molded article. Examples of the polyesters include polyethylene terephthalate (PET), polybutylene terephthalate (PBT), polytrimethylene terephthalate (PTT), glycol-modified polyethylene terephthalate (PETG), glycol-modified polycyclohexylenedimethylene terephthalate (PCTG), acid-modified polycyclohexylenedimethylene terephthalate , Polyethylene-co-isosorbide terephthalate (PEIT) and polyethylene-co-cyclohexylenedimethylene-co-isosorbide terephthalate (PECIT). Among them, it is preferable to use PETG, PCTG, PCTA, PEIT and PECIT corresponding to the copolymerized polyester.
The polyester may be polymerized from a dicarboxylic acid and a diol, as is known in the art. The dicarboxylic acid and derivatives thereof used in the polymerization of the polyester include terephthalic acid (TPA), isophthalic acid (IPA), 2,6-naphthalenedicarboxylic acid (2,6- NDA), dimethyl terephthalic acid (DMT), dimethylisophthalate (DMI), dimethyl 2,6-naphthalenedicarboxylate (2,6-NDC), dimethyl 1,4- cyclohexanedicarboxylate, and the like.
The diol used in the polymerization of the polyester may be at least one selected from the group consisting of ethylene glycol, diethylene glycol, propylene glycol, neopentyl glycol, Cyclohexanedimethanol (CHDM), and the like, but the present invention is not limited thereto.
PET, which is one example of the copolymer polyester, is a polyester resin produced by the condensation reaction of TPA and EG, and is used as a beverage container, a fiber, a film, and a thermoplastic molding material because of its strong tensile and mechanical strength and high abrasion resistance.
PETG, which is one example of the copolymerized polyester, is a polyester resin produced by copolymerizing CHDM as a diol component with the above-mentioned PET, and is excellent in transparency, processability, and chemical resistance, and thus is used as a merchandise display space and a cosmetic container.
PCTG, which is one example of the copolyester, is a polyester resin produced by copolymerizing ethylene glycol (EG) as a diol component in the PCT described above, and can be transparently injected into a high-quality cosmetic container, a food container, .
PCTA, which is one example of the copolyester, is a polyester produced by copolymerizing isophthalic acid (IPA) as a dicarboxylic acid component in the PCT described above.
One example of the copolymerized polyester, PEIT, is a polyester produced through copolymerization of PET with isosorbide monomer converted from glucose.
One example of the copolymerized polyester, PECIT, is a biomass-based polymer that is a PET substitute, and is a ternary copolymerized polyester produced through copolymerization of PEIT and CHDM described above. The PECIT can be improved in glass transition temperature and decomposition temperature by using biosmooth based isosorbide monomer. In addition, PECIT is a high molecular weight polymer that can absorb the advantages of conventional transparent plastic materials such as polycarbonate (PC), polymethyl methacrylate (PMMA) and PETG, And is superior in impact strength to PMMA. Therefore, it is excellent in chemical resistance, stain resistance, transparency and impact strength, and is suitable as a component of an environmentally friendly polymer resin composition.
The polyamide 6 (PA 6) resin is also known as 'nylon 6' and is a resin having six carbons in the repeating unit, and can be generally produced by polymerization of? -Caprolactam.
For example, in the polyamide 6 resin, a catalyst such as aminocaproic acid and a viscosity stabilizer such as acetic acid are added to an aqueous solution containing water added to? -Caprolactam, polymerization reaction is carried out at a temperature of about 260 占 폚, Followed by purification and drying.
The polyamide 66 (PA 66) resin, also known as nylon 66, is a polyamide resin produced by the reaction of an amine compound having 6 carbon atoms with an acid compound having 6 carbon atoms, and generally, hexamethylene diamine And adipic acid.
For example, the polyamide 66 resin is prepared by adding an adipic acid to an aqueous solution of hexamethylenediamine to prepare an aqueous solution of a polyamide salt, filtering and concentrating the aqueous solution, adding the aqueous solution to the polyamide salt as a viscosity stabilizer, By heating for 2 to 3 hours under a high temperature and high pressure condition, and then polymerizing at a pressure of 1.5 hours while raising the temperature to about 280 DEG C while lowering the pressure.
Glass fiber (GF), which is a component used in the resin composition according to the present invention, is used for improving the strength and heat resistance of the polyamide 56. [ The glass fiber may be coated with a coupling agent selected from the group consisting of a urethane coupling agent, a silane coupling agent and an epoxy coupling agent, and may be coated with a silane coupling agent. More preferably, it can be coated with aminosilane. The glass fiber may be coated with 0.1 to 0.3% by weight of a coupling agent to enhance mechanical strength and chemical resistance. In addition, it is preferable that the glass fiber has a particle diameter of 10 to 12 占 퐉 in terms of its orientation.
In a preferred embodiment of the present invention, the glass fiber may be a glass fiber coated with aminosilane having a particle size of 10 mu m, a length of 4 mm, and 0.1 wt%. Examples of commercially available glass fibers include CS 123D (Owens Corning), 995 (Owens Corning), and preferably CS 123D.
The polymeric resin composition according to the present invention comprises (A) from 5 to 90% by weight of the polyamide 56 (PA 56); (B) 5 to 30% by weight of at least one selected from the group consisting of polyester, polyamide 6 (PA 6) and polyamide 66 (PA 66); And (C) 5 to 70% by weight of the glass fiber.
In a preferred embodiment, the polymeric resin composition according to the present invention comprises (A) the polyamide 56 (PA 56) 55 To 70% by weight; (B) 10 to 20% by weight of at least one selected from the group consisting of the above-mentioned polyesters, PA 6 and PA 66; And (C) 20 to 30% by weight of the glass fiber.
The desired stiffness, heat resistance, chemical resistance and excellent appearance quality can be obtained within the above content range. Further, the polymer resin composition according to the present invention can be used as an environmentally friendly polymer resin by including the polyamide 56 in the above range.
Further, as a preferred example, the polymer resin composition comprises (A) a polyamide 56; (B) polyamide 6; And (C) glass fibers.
The polymer resin composition according to the present invention may further comprise an additive selected from the group consisting of an antioxidant, a lubricant, a light stabilizer, a light absorber, a transesterification inhibitor and a moisture release agent.
The antioxidant is used for inhibiting oxidation or pyrolysis of the compositions during the high temperature polymerization reaction, and preferably phenolic antioxidants, amine antioxidants, thiol antioxidants and phosphite antioxidants may be used. Specific examples of the antioxidant include 2,6-di-t-butyl-p-cresol, octadecyl-3- (4-hydroxy-3,5-di-t-butylphenyl) propionate, tetrabis (3,5-di-t-butyl-4-hydroxyphenyl) propionate] methane, 1,3,5-trimethyl-2,4,6- butyl-4-hydroxybenzyl) benzene, 3,5-di-t-butyl-4-hydroxybenzylphosphite diethyl ester, 4,4'-butylidene- tert-butylphenol), 4,4'-thiobis (3-methyl-6-t-butylphenol) or bis [3,3-bis- (4'- Butanoic acid] glycol ester; Amines such as phenyl- alpha -naphthylamine, phenyl- beta -naphthylamine, N, N'-diphenyl-p-phenylenediamine or N, N'-di- beta -naphthyl- Antioxidants; Such as thiourea, thiourea, thiourea, thiourea, thiourea, thiourea, thiourea, thiourea, thiourea, thiourea, thiourea, thiourea Antioxidants; And bis (2,4-di-t-butylphenyl) pentaerythritol diphosphite or (1,1'-biphenyl) -4, triphenylphosphite, tris (nonylphenyl) phosphite, triisodecylphosphite, And a phosphite-based antioxidant such as tetrakis [2,4-bis (1,1-dimethylethyl) phenyl] ester such as 4'-diylbisphosphonous acid, and an antioxidant different from a phosphite- It is most preferable to use them in combination. Examples of commercially available antioxidants include AO-60 (ADEKA), S-9228 (DOVER), Irgaphos-168 (ADEKA), and AO-412S (ADEKA).
In a preferred embodiment of the present invention, the antioxidant may be added in an amount of 0.1 to 0.5 parts by weight based on 100 parts by weight of the resin, and the conversion of the resin and the degree of polymerization And the productivity can be increased. Further, since the color change (yellowing) or the like of the molded article is suppressed, a molded article having excellent appearance as well as excellent heat resistance can be provided.
The lubricant may be selected from the group consisting of a metal stearate lubricant, an amide lubricant, a paraffin lubricant, and an ester lubricant. Examples of commercially available lubricants include Hi-Lube (Shinwon Chemical), Mg-St (Songwon), Ca-St (Songwon), Zn-St (Songwon), and AX-71 (ADEKA).
The light stabilizer and the light absorber are used for suppressing pyrolysis of the compositions, and may be selected from the group consisting of a horseshoe light stabilizer, a benzotriazole light absorber, and a benzophenone light absorber.
The transesterification inhibitor may be a phosphorus compound which is used for suppressing the transesterification reaction to maintain the stability of the composition and contains a hydroxyl functional group and an alkyl ester functional group.
The above moisture release is a compound capable of reacting with a hydroxyl group or a carboxyl group which is a terminal component of polyamide, and can improve not only the hydrolysis resistance of the resin composition but also the durability. That is, the moisture release is applied to an ester resin such as polyester, polyamide or polyurethane to end-cap the end of the polymer chain to prevent hydrolysis of the resin composition by water or acid It plays a role. The moisture release may be a carbodiimide compound, for example, modified phenyl carbodiimide, poly (tolylcarbodiimide), poly (4,4'-diphenylmethanecarbodiimide), poly (3, Dimethyl-4,4'-biphenylene carbododiimide), poly (p-phenylenecarbodiimide), poly (m-phenylenecarbodiimide), poly (3,3'- Diphenylmethanecarbodiimide).
In addition, various additives known to be usable in the resin composition or the molded article thereof can be included, and the specific kind and the method of obtaining it are obvious to those skilled in the art.
Further, the present invention provides a polymer resin molded article comprising the above-mentioned polymer resin composition. Specifically, the polymer resin molded article can be obtained from the polymer resin composition through a processing step such as molding. The above-mentioned polymer resin molded article can be used as parts of an automobile, an electric / electronic appliance, a home appliance, an office or a commodity, and is preferably used as a part of an automobile. Specifically, it can be used in automobiles, but not limited to, plastic parts related to instrument panel modules, plastic parts related to door trim, lamp housing related parts, wheel cover related parts, car interior / exterior garnish related parts, and door handle lever parts.
Hereinafter, the present invention will be described in more detail by way of examples. The following examples illustrate the present invention, and the scope of the present invention is not limited by the following examples.
Example 1
60% by weight of polyamide 56 (Terryl ™ 100 parts by weight of a resin consisting of 10% by weight of PCTG (JN100, SK Chemicals) and 30% by weight of glass fibers (CS 123D, Owens Corning) 0.2 part by weight of ethylenebisstearamide (Hi-Lube, Shinwon Chemical), 0.2 part by weight of phenol antioxidant (AO-60, ADEKA) and 0.2 part by weight of phosphite antioxidant (Igarfos 168, Clariant) To prepare a resin composition. The resin composition was uniformly kneaded and extruded using a biaxial kneading extruder (?: 40 mm, L / D = 40) to produce pellets.
Example 2
55% by weight of polyamide 56 (Terryl ™ PA56, Cathay Industrial Biotech), 15 weight% PCTG (JN100, SK Chemicals) and 30 weight% glass fiber (CS 123D, Owens Corning) 0.2 part by weight of ethylenebisstearamide (Hi-Lube, Shinwon Chemical), 0.2 part by weight of phenol antioxidant (AO-60, ADEKA) and 0.2 part by weight of phosphite antioxidant (Igarfos 168, Clariant) To prepare a resin composition. The resin composition was uniformly kneaded and extruded using a biaxial kneading extruder (?: 40 mm, L / D = 40) to produce pellets.
Example 3
57% by weight of polyamide 56 (Terryl ™ 100 parts by weight of a resin consisting of 13% by weight of polyamide 6 (V32512, KPI Chemtech, RV 2.5) and 30% by weight of glass fibers (CS 123D, Owens Corning) 0.2 part by weight of ethylenebisstearamide (Hi-Lube, Shinwon Chemical), 0.2 part by weight of phenol antioxidant (AO-60, ADEKA) and 0.2 part by weight of phosphite antioxidant (Igarfos 168, Clariant) To prepare a resin composition. The resin composition was uniformly kneaded and extruded using a biaxial kneading extruder (?: 40 mm, L / D = 40) to produce pellets.
Comparative Example 1
70% by weight of polyamide 56 (Terryl ™ PA56, manufactured by Cathay Industrial Biotech) and 30% by weight of glass fiber (CS 123D, Owens Corning) 0.2 part by weight of ethylenebisstearamide (Hi-Lube, Shinwon Chemical), 0.2 part by weight of phenol antioxidant (AO-60, ADEKA) and 0.2 part by weight of phosphite antioxidant (Igarfos 168, Clariant) To prepare a resin composition. The resin composition was uniformly kneaded and extruded using a biaxial kneading extruder (?: 40 mm, L / D = 40) to produce pellets.
Comparative Example 2
85% by weight of polyamide 56 (Terryl ™ PA56, manufactured by Cathay Industrial Biotech) and 15% by weight of glass fiber (995-13P, Owens Corning) 0.2 part by weight of ethylenebisstearamide (Hi-Lube, Shinwon Chemical), 0.2 part by weight of phenol antioxidant (AO-60, ADEKA) and 0.2 part by weight of phosphite antioxidant (Igarfos 168, Clariant) To prepare a resin composition. The resin composition was uniformly kneaded and extruded using a biaxial kneading extruder (?: 40 mm, L / D = 40) to produce pellets.
Comparative Example 3
100 parts by weight of a resin composed of 60% by weight of polyamide 6 (RV 2.5, Kepco Chemtex), 10% by weight of PET (BB8055, SK Chemicals) and 30% by weight of glass fibers (995-13P, Owens Corning) , 0.2 part by weight of ethylenebisstearamide (Hi-Lube, Shinwon Chemical), 0.2 part by weight of phenol antioxidant (AO-60, ADEKA) and 0.2 part by weight of phosphite antioxidant (Igarfos 168, Clariant) To prepare a resin composition. The resin composition was uniformly kneaded and extruded using a biaxial kneading extruder (?: 40 mm, L / D = 40) to produce pellets.
Comparative Example 4
100 parts by weight of a resin composed of 60% by weight of polyamide 66 (RV 2.5, INVISTA), 10% by weight of PET (BB8055, SK Chemicals) and 30% by weight of glass fibers (995-13P, Owens Corning) 0.2 part by weight of ethylenebisstearamide (Hi-Lube, Shinwon Chemical), 0.2 part by weight of phenol antioxidant (AO-60, ADEKA) and 0.2 part by weight of phosphite antioxidant (Igarfos 168, Clariant) To prepare a resin composition. The resin composition was uniformly kneaded and extruded using a biaxial kneading extruder (?: 40 mm, L / D = 40) to produce pellets.
Manufacture of Polymer Resin Molded Products
The polymeric resin compositions (pellets) prepared according to Examples 1 to 3 and Comparative Examples 1 to 4 were uniformly injected at a temperature of 250 캜 using an injection machine to obtain molded articles. The molded article was conditioned under conditions of 23 ± 2 ° C., 50 ± 5% relative humidity and used in the following tests.
Test Example One: The tensile strength Measure
The polymeric resin molded article was made into a test piece according to the American Society for Testing and Materials (ASTM) 638, and then the tensile strength was measured using a universal testing machine (Zwick Roell Z010). The results are shown in Table 1 below.
Test Example 2: Heat resistance measurement
The above-mentioned polymer resin molded article was made into a test piece according to American Society for Testing Materials (ASTM) 648, and heat resistance was measured using a heat resistance tester (HDT Tester, Toyoseiki). The results are shown in Table 1 below.
Test Example 3: Appearance Evaluation
The appearance of the molded product of the polymer resin was observed at a magnification of 100 at a scanning electron microscope (SEM) to observe the appearance of defects.
When no apparent defect was found in the SEM image, it was judged as "good". When a defect such as a pin-hole was found, it was judged as "bad" and the results were summarized in Table 1.
1 and 2 show scanning electron microscope (SEM) images of the molded articles obtained from the polymer resin compositions of Example 1 and Comparative Example 1, respectively.
As shown in Table 1, the molded articles obtained from the polymer resins of Examples 1 to 3 according to the present invention showed excellent tensile strength, heat resistance and appearance. As shown in Fig. 1, in the case of the molded article obtained from the polymer resin composition of Example 1, no apparent defect was found. In addition, the molded articles obtained from the polymer resins of Examples 1 to 3 all contain biomass-based polyamide 56, which is environmentally friendly.
On the other hand, as shown in Table 1, the molded articles obtained from the polymer resin compositions of Comparative Examples 1 to 4 exhibited poor physical properties in at least one of tensile strength, heat resistance and appearance. As shown in Fig. 2, in the molding process obtained from the polymer resin composition of Comparative Example 1, an apparent defect such as a pinhole (a portion denoted by a circle) was found. In addition, the molded articles obtained from the polymer resins of Comparative Examples 3 and 4 contain no petroleum-based polyamide 6 or 66 and thus are not environmentally friendly.
Claims (9)
(B) at least one selected from the group consisting of polyester, polyamide 6 (PA 6) and polyamide 66 (PA 66); And
(C) glass fibers (GF).
Polymer resin composition.
Wherein the polymeric resin composition comprises, based on the total weight of the composition,
(A) 5 to 90% by weight of the polyamide 56 (PA 56);
(B) 5 to 30% by weight of at least one selected from the group consisting of polyester, polyamide 6 (PA 6) and polyamide 66 (PA 66); And
(C) 5 to 70% by weight of the glass fiber.
The polyesters may be selected from the group consisting of polyethylene terephthalate (PET), polybutylene terephthalate (PBT), polytrimethylene terephthalate (PTT), glycol-modified polyethylene terephthalate (PETG), glycol-modified polycyclohexylenedimethylene terephthalate (PCTG), acid-modified polycyclohexylenedimethylene terephthalate (polyethylene-co-isosorbide terephthalate) and PECIT (polyethylene-co-cyclohexylenedimethylene-co-isosorbide terephthalate).
Wherein the glass fiber is coated with a coupling agent selected from the group consisting of a urethane-based coupling agent, a silane-based coupling agent, and an epoxy-based coupling agent.
Wherein the polymer resin composition comprises (A) a polyamide 56; (B) polyamide 6; And (C) glass fiber (GF).
Wherein the polymer resin composition further comprises an additive selected from the group consisting of an antioxidant, a lubricant, a light stabilizer, a light absorber, a transesterification inhibitor, and a moisture release agent.
Wherein the antioxidant is selected from the group consisting of a phenol-based antioxidant, an amine-based antioxidant, a thiol-based antioxidant, and a phosphite-based antioxidant.
Wherein the polymer resin molded article is an automobile part.
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| KR1020150114934A KR20170020134A (en) | 2015-08-13 | 2015-08-13 | Polymer resin composition and molded product thereof |
| PCT/KR2016/008648 WO2017026749A1 (en) | 2015-08-13 | 2016-08-05 | Polymer resin composition and molded product thereof |
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| KR1020150114934A KR20170020134A (en) | 2015-08-13 | 2015-08-13 | Polymer resin composition and molded product thereof |
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| CN109679339A (en) * | 2018-12-27 | 2019-04-26 | 会通新材料(上海)有限公司 | A kind of improvement release property and 56 composition of polyamide flexible and its application |
| CN111117237A (en) * | 2020-01-14 | 2020-05-08 | 深圳海源恒业高新材料科技研发有限公司 | Polyamide composite material and preparation method thereof |
| CN112391050A (en) * | 2020-12-22 | 2021-02-23 | 华东理工大学 | Low-water-absorption PA56/PBT composite material and preparation method thereof |
| WO2024091200A1 (en) * | 2022-10-27 | 2024-05-02 | Kordsa Tekni̇k Teksti̇l Anoni̇m Şi̇rketi̇ | Pa56/pa66 compositions and method of preparing these compositions |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51103191A (en) | 1975-03-07 | 1976-09-11 | Toray Industries | NETSUKASOSEIJUSHISOSEIBUTSUNOSEIZOHO |
| US5102935A (en) | 1988-09-13 | 1992-04-07 | Bayer Aktiengesellschaft | Free-flowing polyamide molding compounds and blends |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4595668B2 (en) * | 2004-05-21 | 2010-12-08 | 三菱化学株式会社 | Polyamide resin |
| CN101578256B (en) * | 2007-01-11 | 2014-09-10 | 三菱化学株式会社 | Cadaverine salt, aqueous cadaverine salt solution, polyamide resin, molded article and process for producing cadaverine salt and aqueous cadaverine salt solution |
| US20120016077A1 (en) * | 2009-03-30 | 2012-01-19 | Toray Industries Inc. | Polyamide resin, polyamide resin composition, and molded article comprising same |
| JP5565034B2 (en) * | 2010-03-29 | 2014-08-06 | 三菱化学株式会社 | Flame retardant polyamide resin composition and extruded product |
| JP6456604B2 (en) * | 2013-06-05 | 2019-01-23 | 旭化成株式会社 | Polyamide resin composition and molded body |
-
2015
- 2015-08-13 KR KR1020150114934A patent/KR20170020134A/en unknown
-
2016
- 2016-08-05 WO PCT/KR2016/008648 patent/WO2017026749A1/en active Application Filing
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51103191A (en) | 1975-03-07 | 1976-09-11 | Toray Industries | NETSUKASOSEIJUSHISOSEIBUTSUNOSEIZOHO |
| US5102935A (en) | 1988-09-13 | 1992-04-07 | Bayer Aktiengesellschaft | Free-flowing polyamide molding compounds and blends |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111484736A (en) * | 2019-10-17 | 2020-08-04 | 四川鑫达企业集团有限公司 | Low-temperature-resistant reinforced PA56/PA6 composite material and preparation method thereof |
| CN111621148A (en) * | 2019-12-20 | 2020-09-04 | 四川鑫达企业集团有限公司 | High-wear-resistance bio-based PA56 composite material and preparation method thereof |
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| WO2017026749A1 (en) | 2017-02-16 |
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