KR20160139118A - Manufacturing apparatus of hydrolysis fuel - Google Patents

Abstract

Disclosed is an apparatus for producing hydrolyzed fuel, designed to continuously produce hydrolyzed fuel through a plurality of oil-water separation tanks. According to the present invention, modified water which is not brought into contact with oil in the oil-water separation tank can be recycled after being collected into a first mixing tank.

Description

TECHNICAL FIELD [0001] The present invention relates to an apparatus for producing hydrofluoric acid fuel,

The present invention relates to an apparatus for producing hydrous fuel, which is capable of continuously producing hydrous fuel through a plurality of oil separation tanks, recovering reformed water not associated with oil in an oil separation tank to a first mixing tank, The present invention relates to a hydrolysis fuel producing apparatus capable of performing hydrolysis.

In recent years, efforts have been made to reduce harmful substances such as carbon dioxide, nitrogen compounds, and sulfur compounds emitted by consumption of fossil fuels in connection with global warming. These efforts are being implemented in a variety of ways such as biofuels, solar cells, wind power generation, wave power generation, and hydrogen gas energization. Nevertheless, if manufacturing and logistics industries restrict the use of fossil fuels, We must also take measures to prevent it.

Accordingly, Korean Patent No. 1328151 discloses a method of producing a stable emulsion fuel by pulverizing and mixing fuel oil such as water, light oil, kerosene or heavy oil using magnetic force, and in the same concept, , No. 2010-0134016, and Japanese Patent Laid-Open No. 2005-206773. However, the treatment of hydrogen peroxide, which is a derivative, is ineffective, resulting in a lower stability and a lower efficiency as a fuel.

As another example, Japanese Patent Application Laid-Open No. 2011-253621 discloses a method for increasing the water content by using an enzyme as a catalyst and using tourmaline or other minerals, and in Korean Patent Publication No. 2014-0101532, by using ultrasonic waves and a metal catalyst A method is proposed in which the efficiency of reforming is increased by increasing the water content.

However, the above technology does not disclose a technique for continuously producing hydrocarbons, and particularly, it releases environmentally unreacted reformed water, thereby causing environmental pollution.

It is an object of the present invention to provide a method for producing hydrolysable fuel which can continuously produce hydrolysable fuel through a plurality of oil separation tanks and which can recover reclaimed water not associated with oil in the oil separation tank to the first mixing tank for recycling Device.

An object of the present invention is to provide an oil tank in which oil is stored and a heater for heating stored oil is built in; A water circulation pipe for circulating water through a water circulation pump is formed on the side surface of the water circulation pipe, a water circulation pipe for circulating the water is formed on the side surface of the water circulation pipe, The circulation tube has a A water tank in which a first catalyst housing is formed; An enzyme tank for storing an enzyme for removing hydrogen peroxide from the reformed water; The oil is introduced through the oil inlet pipe connected to the oil tank, the water is introduced through the water inlet pipe connected to the water tank, the enzyme is introduced through the enzyme supply pipe connected to the enzyme tank, A first mixing tank in which an air jet nozzle for injecting air is provided so that the mixed liquid is uniformly dispersed and maintained by stirring; A second mixing tank in which an air injection nozzle for injecting air to stir the mixed liquid introduced through a first mixed liquid inlet pipe provided with a mixer for generating a mixed liquid connected to the first mixing tank and generating a mixed fuel is provided, Wow; A third mixing tank in which an air jet nozzle for injecting air to stir the mixed liquid introduced through the second mixed liquid inlet pipe provided with a mixer for generating a mixed liquid which is connected to the second mixing tank and flows as hydrous fuel is installed, Wow; The mixed liquid flowing through the third mixed liquid inlet pipe provided with the mixer for generating the mixed liquid which is connected to the third mixed tank and is flowing as the hydrous fuel is stored and the stored mixed liquid is mixed with the oil, A water separation tank in which a combined hydrous fuel is formed in the upper layer and water which is not combined with oil is formed in the lower layer to cause water separation; A floating boundary surface detecting means installed in the oil-water separating tank and having a specific weight between the specific gravity of water of the upper layer and the specific gravity of water in the lower layer; A water pipe connecting the first mixing tank and the oil-water separation tank so as to collect the water formed below the water-flowing interface sensing means into the first mixing tank; And a hydro-fuel extracting pipe for connecting the water-oil separating tank and the hydro-alcoholic fuel tank so as to send the hydrolytic fuel formed on the upper side of the water-soluble interface detecting means to the hydro-hydrocarbons tank. .

The hydrous fuel producing apparatus according to the present invention can continuously produce the hydrous fuel through a plurality of oil water separating tanks and recover the reformed water not combined with the oil in the oil separating tank to the first mixing tank for recycling Can be effective.

1 is a schematic view of an apparatus for producing hydrous fuel according to the present invention,
FIG. 2 and FIG. 3 are views showing the operation of the water separation detection means in the hydrolysis fuel production apparatus according to the present invention.

BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, an apparatus for producing hydrous fuel according to the present invention will be described in detail with reference to the accompanying drawings. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a schematic view of a hydrolysis fuel producing apparatus according to the present invention.

Referring to the drawings, an apparatus for producing a hydrous fuel according to the present invention is an apparatus for producing a hydrous fuel by reforming water and then causing modified water to adhere to oil molecules. The apparatus includes an oil tank 110, a water tank 120 A plurality of oil water separation tanks 170, a water interface surface sensing means 200, a water pipe 300, and a singer fuel tank 130. The first to third mixing tanks 140, And an extracting pipe 400.

The oil tank 110 is provided with a heater 111 for storing the oil supplied from the oil supply cylinder 10 and for heating the stored oil. The heater heats the oil to about 30 ° C to 40 ° C so that water can be well coupled to the oil.

The water tank 120 stores the water supplied from the water supply cylinder 20, and the heater 121 and the ultrasonic oscillator 122 are built in.

The heater 121 heats the water to about the same as the oil temperature or about 10 캜 so that the water can be well combined with the oil.

The ultrasonic oscillator 122 resonates water to facilitate ionization of water. Preferably, the ultrasonic oscillator comprises three ultrasonic oscillators. One of the three ultrasonic oscillators has a band of 28 kHz, the other ultrasonic oscillator has a band of 40 kHz, and the other ultrasonic oscillator has a band of 70 kHz to 100 kHz, and water is supplied by three ultrasonic oscillators Thereby generating a fine resonance. It is effective to increase the ionization efficiency by resonating the water using an ultrasonic oscillator having different frequency bands. Here, the plurality of ultrasonic oscillators are not sequentially operated with each other but are simultaneously operated while being in contact with water as a whole, and water is randomly resonated, but is continuously circulated through a water circulation pipe described later, The resonance frequency is maximized.

A water circulation pipe 123 for circulating water through a water circulation pump is formed on a side surface of the water tank 120, A first catalyst housing 124 is formed.

At this time, tourmaline (tourmaline) and obsidian pearlite are contained in the first catalyst housing 125, and water molecules are ionized to H ₃ O ₂ ^- by reaction with tourmaline and obsidian pearlite. Thus, the water in the water tank 120 is reformed to be able to bind to the oil by the first catalyst while circulating the water circulation pipe 121 continuously. Here, the reforming reaction of water with tourmaline and obsidian pearlite has already been sufficiently explained in the prior art mentioned in the prior art, and since the reforming fuel is currently available on the market, a detailed description thereof will be omitted.

The enzyme tank 130 is a tank in which an enzyme for removing hydrogen peroxide from the reformed water is stored. In the reaction of the first catalyst described above, hydrogen peroxide such as H ₂ O ₂ is generated in addition to H ₃ O ₂ ^- , so hydrogen peroxide must be removed. Therefore, catalase or manganese dioxide capable of removing hydrogen peroxide is contained in the enzyme tank.

In the meantime, the oil, water, and the enzyme are introduced into the first mixing tank 140 and are firstly stirred with each other. To this end, the oil inlet pipe 112 is connected to the oil tank 110 in the first mixing tank 140 The water inlet pipe 125 is connected to the water tank 120 and the enzyme inlet pipe 131 is connected to the enzyme tank 130.

Therefore, oil flows into the first mixing tank 140 through the oil inlet pipe 112 connected to the oil tank 110 and water flows in through the water inlet pipe 126 connected to the water tank 120 And the enzyme is introduced through the enzyme supply pipe 131 connected to the enzyme tank 130. The first mixing tank 140 is provided with an air injection nozzle 141 for injecting air into the mixed liquid. The oil, water, and enzyme are firstly stirred by the air to be sprayed, And hydrogen peroxide, such as H ₂ O ₂ formed by the first catalytic reaction, is removed by the enzyme provided in the enzyme tank.

In the present invention, a plurality of mixing tanks are provided. The second mixing tank 150 is provided with an air injection nozzle 151 for injecting air to secondarily mix the mixed liquid introduced through the first mixed liquid inlet pipe 142 connected to the first mixing tank 140 And an air injection nozzle 161 for injecting air to thirdarily stir the mixed liquid introduced through the second mixed liquid inlet pipe 152 connected to the second mixing tank 150 160 may be further provided. It is of course also possible to install more more mixing tanks (..., N-1 mixing tanks, N mixing tanks, N + 1 mixing tanks, ...) as needed.

Therefore, according to the present invention, the water and the oil are uniformly dispersed and maintained by the multiple agitation of the mixing tanks 140 to 160, and the hydrogen peroxide is completely removed.

Meanwhile, the mixed liquid of the third mixing tank 160, which is the final mixing tank, is finally introduced into the oil-water separation tank 170 through the third mixed liquid inlet pipe 161.

At this time, the first to third mixed solution inlet pipes 142, 152, and 162 are provided with a mixer 180 for generating a mixed solution as hydrous fuel, respectively. The mixer 180 is a known inline mixer or a vortex mixer. The mixed liquid dispersed and held in the mixing tanks 140 to 160 passes through the mixer 180, and the reformed water under high pressure and high speed is coupled to the oil to become the hydrous fuel The water bound to the oil is not easily separated from the oil. That is, the mixed liquid, which is dispersed and held in the first mixing tank 140, passes through the mixer 180 installed in the first mixed liquid inlet pipe 142, and a part of the mixed liquid is generated as the hydrous fuel and the reformed water And the oil pass through the mixer 180 installed in the second mixed liquid inlet pipe 152 and the third mixed liquid inlet pipe 162, and a certain portion of the oil is produced as hydrous fuel.

The oil-water separating tank 170 is composed of a plurality of tanks, and the mixed liquid is stored through the mixed liquid inlet pipe 162 connected to the third mixing tank 160 as a final mixed tank. When the stored mixture reaches a predetermined time The difference causes water to be formed in the upper layer, in which water is combined with the oil, and water in the lower layer, which is not combined with the oil, is formed in the lower layer, and a water-oil separation interface is formed in the upper and lower layers. That is, the hydrolyzed fuel generated while passing through the mixer 180 has a specific gravity of about 0.8 and the water not produced as hydrous fuel has a specific gravity of 1 and is formed in the lower layer, and a water-oil separation interface is formed between the hydrous fuel and water.

On the other hand, the water-oil separating tank 170 is provided with a water pipe 300 and a hydro-fuel extracting pipe 400. The water water pipe 300 connects the first mixing tank 140 and the oil water separating tank 170. The hydrocracking fuel extracting pipe 400 connects the oil water separating tank 170 and the water tank 500 It is a pipe to connect.

Therefore, the mixed liquid in the oil separation tank 170 separated into the upper layer and the lower layer primarily discharges water in the lower layer, while the water in the lower layer is collected in the first mixing tank 140 through the water pipe 300, The hydrous fuel is extracted into the hydrous fuel tank 500 through the hydrous fuel extracting pipe 300 and used as fuel.

Here, the present invention includes a water interface surface sensing means 200 installed in the water separating tank and float having a specific gravity between the specific gravity of water of the upper layer and the specific gravity of the water of the lower layer is elevated along the water separation interface.

The water interface boundary surface sensing unit 200 senses the water interface and lowers the water below the water interface boundary as the water is recovered to the water pipe so that the hydrous fuel is extracted to the water tank through the hydro-fuel extraction pipe.

More specifically, as shown in FIGS. 2 and 3, the water interface boundary surface sensing means 200 is fixed at the bottom of the water separation tank 170 at one end and passes through the ceiling of the water separation tank 170 at the other end A fixed guide rod 210; A lower end stopper 220 fixed to the lower end of the guide rod 210, an upper stopper 230 fixed to the upper side of the guide rod 210 in the oil water separating tank 270, A float 240 guided and lowered by the guide bar 210 between the lower stopper 220 and the upper stopper 230 along the water splitting boundary with a specific gravity of the float 240, A magnet (250) providing magnetic force; And a magnetic force sensor 260 mounted on the bottom surface of the upper stopper 230 to detect the position of the float by recognizing the magnetic force of the magnetic force.

The water pipe (300) and the hydro-fuel extracting pipe (400) are provided with open / close valves (310, 410) for receiving the signal of the magnetic force sensor (460)

Accordingly, some of the mixed liquor flowing into the oil water separating tank 170 is divided into hydrous fuel and partially reformed water, which is not combined with oil. As time elapses, due to the difference in specific gravity, Water is disposed and a water-oil separation interface is formed between the water and the water. At this time, the float 440 has a specific gravity of about 0.9, which is the ratio between the specific gravity of the hydrous fuel and the specific gravity of water, and is disposed at the oil-water separation interface.

When the water separation interface is stabilized, the opening of the water shutoff valve 310 by the magnetic force sensor 460 causes water in the lower layer to flow into the first mixing tank 140 along the water pipe 300, The float 440 descends. 3, when the lower end stopper 420 is touched, the magnetic force sensor 460 recognizes the magnetic force of the magnet 450, closes the water shutoff valve 310, The opening / closing valve 410 of the fuel extraction pipe is opened to allow the hydrous fuel to be extracted into the hydro-fuel tank 500. [

The oil-water separation sensing means configured as described above can separate and discharge the water separated into two layers of the oil-water separation tank.

The lower stopper 220 may be received in a depression groove 171 formed in the bottom of the oil separation tank and the upper surface of the lower stopper 220 may be received in the bottom of the oil separation tank 170 . That is, if the float 240 touches the bottom surface of the oil-water separating tank 170, all the water is discharged. If the bottom stopper 220 is seated on the bottom of the oil-water separating tank and protruded, The upper end of the lower end stopper 220 is connected to the bottom of the oil water separating tank 170 and the upper end of the lower end stopper 220 is connected to the bottom of the oil water separating tank 170. [ So that the lower end stopper is accommodated in the recessed groove 171. [

The first mixing tank 140 is further provided with a heater 143 for heating the reformed water recovered from the oil separation tank 170 to the first mixing tank 140 by the water flow pipe 300 desirable. In the first mixing tank 140, water is introduced into the water tank and the oil-water separation tank, respectively. The water supplied from the water tank is water heated to a predetermined temperature by the heater, and the water introduced from the oil- The temperature of the mixed liquid in the first mixing tank can be maintained at a predetermined temperature by providing the heater 140 in the first mixing tank.

The second catalyst housing 190 may further be formed at a rear end of the mixer 180 installed in the first to third mixed solution inlet pipes 142, 152 and 162. A catalyst for preventing the discoloration of the generated hydrocarbons is built in the second catalyst housing 190 to maintain the clear color of the hydrous fuel and to maintain the stabilized state by increasing the adhesion force of the water molecules on the surface of the oil molecules . The second catalyst is preferably a ceramic ball having a particle size of 5-20 mm. The second catalyst is filled in the second catalyst housing to allow the mixed oil to pass through the voids.

The composition of the second catalyst is, in terms of% by weight, copper powder 15-25, nickel powder 10-15, titanium powder 5-10, zeolite powder 10-20, silver powder 1-2, platinum powder 1-2, sepiolite powder 6- 12, rhodium powder 0.2-0.5, and the remaining tourmaline powder are mixed to form a ceramic ball.

Copper is a typical transition metal. It is added to increase the adhesion to the oil surface by removing microfine bacteria existing in water. If it is added in an amount of less than 15% by weight, dispersibility will not be exhibited, If it exceeds 10% by weight, nickel and tourmaline having magnetic properties may be deteriorated.

In addition, the nickel has a strong magnetic property and is added to perform the complementary function with the tourmaline described above. Since it has a complementary nature, the nickel should be added in a range of 10-15% by weight for rate equilibrium with other components do.

In addition, the titanium is added as a paramagnetic material for deoxidation, and is added only to the extent of functional expression within the range of 5-10 wt% because it is expensive.

The zeolite is a kind of aluminum silicate mineral, also known as zeolite, and is a typical far-infrared ray emitting material and has a property of ion exchange. Therefore, in the present invention, because of the property of selectively adsorbing a polar substance by the action of cations in the crystal structure by utilizing such ion-exchange property, it acts as a molecular sieve, so that water molecules are strongly adhered to the surface of oil molecules If it is added in an amount of more than 20% by weight, the adsorption of the other components is hindered. If it is added in an amount of less than 10% by weight, ion exchangeability is deteriorated.

Silver is added so as to keep water molecules stable due to its low contact resistance, and platinum is used as a catalyst for dehydrogenation. However, these are all expensive, and when added in an excessive amount, adherence of water molecules is deteriorated, so a small amount should be added within the above range.

The sepiolite is called a meerschaum which is a round tubular variant and has excellent properties for bleaching and refining oil (oil). In the present invention, it is added in order to maintain a clear color of the mixed oil by bleaching. If it exceeds 12% by weight, a reaction product is formed due to the reaction with silver, so that the catalytic reaction is reduced. When the added amount is less than 6% by weight, It should be limited to the above range.

The rhodium is a kind of alloying agent for curing platinum and is added to prevent discoloration. Particularly, since rhodium is very expensive, it can not be used in an excessive amount. In particular, since the redness increases, a small amount of rhodium is added because it hinders clear color retention.

The operation and effect of the hydrolysis fuel producing apparatus according to the present invention thus configured will be described.

The oil in the oil tank is heated to a predetermined temperature and then flows into the first mixing tank. The water in the water tank is modified by the water circulated in the water circulation pipe, which is resonated by the ultrasonic oscillator and heated to a predetermined temperature, and flows into the first mixing tank. The enzyme in the enzyme tank also enters the first mixing tank.

In the first mixing tank, the mixture is dispersed and held by the injected air, and is sequentially transferred to the second mixing tank and the third mixing tank. In the course of the transfer, the water reformed by the mixer is combined with the oil, And the generated hydrous fuel is prevented from being discolored by the second catalyst of the second catalyst housing.

The mixed liquid is first introduced into one of the plurality of oil separation tanks, and then the hydrous fuel and the water are separated by the specific gravity difference. The separated water is recovered to the first mixing tank through the water tap water and recycled . Then, the hydrocarbons are extracted into the hydrocarbons tank through the hydrocarbons extraction pipe and used as the fuel. At this time, the present invention is advantageous in that it is eco-friendly and useful for energy saving because the reformed water not combined with the oil is not discharged to the outside, but is recovered and reused.

In this case, the oil-water separating time in the oil-water separating tank takes about 5 to 10 minutes, while the mixed oil in the third mixing tank is supplied to the other oil-water separating tank so that the oil- Can be continuously produced.

While the invention has been shown and described with respect to the specific embodiments thereof, it will be understood by those skilled in the art that various changes and modifications may be made without departing from the spirit and scope of the invention as defined by the appended claims. Anyone with it will know easily.

110: Oil tank 120: Water tank
130: Enzyme tank 140 to 160: First to third mixing tanks
170: Oil-water separation tank 200: Oil-water interface sensing means
300: water tube 400: singer fuel extract tube

Claims (5)

An oil tank in which oil is stored and in which a heater for heating the stored oil is incorporated;
A water circulation pipe for circulating water through a water circulation pump is formed on the side surface of the water circulation pipe, a water circulation pipe for circulating the water is formed on the side surface of the water circulation pipe, The circulation tube has a A water tank in which a first catalyst housing is formed;
An enzyme tank for storing an enzyme for removing hydrogen peroxide from the reformed water;
The oil is introduced through the oil inlet pipe connected to the oil tank, the water is introduced through the water inlet pipe connected to the water tank, the enzyme is introduced through the enzyme supply pipe connected to the enzyme tank, A first mixing tank in which an air jet nozzle for injecting air is provided so that the mixed liquid is uniformly dispersed and maintained by stirring;
A second mixing tank in which an air injection nozzle for injecting air to stir the mixed liquid introduced through a first mixed liquid inlet pipe provided with a mixer for generating a mixed liquid connected to the first mixing tank and generating a mixed fuel is provided, Wow;
A third mixing tank in which an air jet nozzle for injecting air to stir the mixed liquid introduced through the second mixed liquid inlet pipe provided with a mixer for generating a mixed liquid which is connected to the second mixing tank and flows as hydrous fuel is installed, Wow;
The mixed liquid flowing through the third mixed liquid inlet pipe provided with the mixer for generating the mixed liquid which is connected to the third mixed tank and is flowing as the hydrous fuel is stored and the stored mixed liquid is mixed with the oil, A water separation tank in which a combined hydrous fuel is formed in the upper layer and water which is not combined with oil is formed in the lower layer to cause water separation;
A floating boundary surface detecting means installed in the oil-water separating tank and having a specific weight between the specific gravity of water of the upper layer and the specific gravity of water in the lower layer;
A water pipe connecting the first mixing tank and the oil-water separation tank so as to collect the water formed below the water-flowing interface sensing means into the first mixing tank;
And a hydro-fuel extracting pipe connecting the water-oil separating tank and the hydro-fuel tank so as to discharge the hydro-fuel formed on the upper side of the flow-through interface sensing means to the hydro-hydro-fuel tank.
2. The apparatus according to claim 1, wherein the flow-
A guide rod fixed at one end to the bottom of the water separation tank and fixed at the other end through the ceiling of the water separation tank;
A lower end stopper fixed to a lower end of the guide rod;
An upper stopper fixed to the upper side of the guide rod in the oil-water separation tank;
A float having a specific gravity between the specific gravity of the hydrous fuel and the specific gravity of the water, the float being guided by the guide rod between the lower stopper and the upper stopper along the water boundary dividing surface;
A magnet installed in the float to provide a magnetic force;
And a magnetic force sensor mounted on a bottom surface of the first stopper to detect the position of the float by recognizing the magnetic force of the magnetic force.
3. The method of claim 2,
Wherein the lower stopper is accommodated in a depressed groove formed in the bottom of the oil water separating tank and the upper surface of the lower stopper is received in conformity with the bottom surface of the oil water separating tank.
3. The method according to claim 1 or 2,
Wherein the first mixing tank is further provided with a heater for heating the reformed water recovered from the oil separation tank to the first mixing tank by the water flow pipe.
3. The method according to claim 1 or 2,
Wherein a second catalyst housing for preventing discoloration of the generated hydrocarbons is installed at a rear end of the mixer installed in the first mixed liquid inlet pipe to the third mixed liquid inlet pipe.

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