KR20160100690A - Toilet detergent compositions - Google Patents

Abstract

Provided is a toilet cleaner having a specific gravity of 0.9-1.1. According to an embodiment of the present invention, provided is a solid toilet cleaning product comprising a frame inside of the toilet cleaner. According to the present invention, the cleaner is not located inside a water tank, and has little risk of directly corroding the tank. Thus, the cleaner has maximized cleaning ability by using a chlorine-based bleaching component, and can be conveniently used by being injected into the water tank.

Description

Toilet detergent compositions

BACKGROUND OF THE INVENTION 1. Field of the Invention [0001] The present invention relates to a toilet cleaner, and more particularly, to a toilet cleaner having a reduced risk of corrosion of a toilet and an excellent cleaning ability.

Traditionally, there is a method of brushing directly with a liquid or powder cleaner to remove pollutants (sticky substances, calcium, lime deposits, iron oxide, etc.), odors, bacteria and fungi in the toilet, It is not a pleasant process.

Recently, there have been many automatic and continuous toilet cleaning products using the flush system of the toilet to replace the direct brushing method, which are classified into two categories. First, when the product (solid) is put in the water tank of the toilet, the cleaning component is gradually eluted, and the water in the tank becomes the cleaning liquid, so that the toilet is cleaned when the toilet is lowered. . The second type is called rim-block type, in which solid or liquid cleaning agent is put on the rim of the toilet, and the cleansing agent is dissolved every time the water goes down to clean the toilet.

U.S.A. Patent No. 6,192,524, In-Tank type of toilet cleaners proposed in Black do not contain virtually any excellent cleaning component since they contain a strong cleaning component such as chlorine bleach, which increases the risk of corrosion of the components in the toilet tank. Therefore, the cleaning power of the in-tank toilet cleaner is insufficient, and when the size of the cleaning agent is reduced, the user often goes around the tank and blocks the drain pipe.

U.S.A. Patent No. 4,777,670 and the European Patent Application No. < RTI ID = 0.0 > 1, < / RTI > EP-0538957 and EP-0785315, U.S. Pat. Patent No. 6,178,564 B1 and 6,230,334 B1, when a high concentration of cleaning liquid flows when the water sweeps for the first time, and when the later water that passes below the toilet sweeps, the efficiency of the cleaning liquid decreases and the efficiency of Rim- - The block itself may appear dirty with contaminants. And there is the inconvenience of removing the product container after use.

Therefore, the present invention is not located in the tank or the rim of the toilet, but rather remains in the form of an In-Tank cleaning agent due to the residues inside the toilet, so there is no danger of tank corrosion and inconvenience such as ineffective cleaning of the Rim- And to provide a toilet cleaning agent capable of reducing the amount of the cleaning agent.

The present invention provides a toilet cleaning agent having a specific gravity similar to that of water and moving with water without falling or sinking when it is put into a water tank and remaining in the rim of the toilet.

In order to solve the above problems, the inventors of the present invention provide a toilet cleaning agent which is similar in specific gravity to water and can move along with water to remain in the rim region of the toilet.

Specifically, the inventors of the present invention have recognized the problems of the detergent of the tank type and the rim block type, and have continued their research on a new type of toilet cleaner, thus completing the present invention.

The present invention can provide a toilet cleaner having a specific gravity of 0.9 to 1.1. The toilet cleaner has a specific gravity similar to that of water so that when it is poured into a water tank, it does not float or sink to the water surface of the tank, but can move to a rim along with water. That is, the toilet bowl cleaner may remain in the rim of the toilet to discharge the cleansing component, so that there is no need to worry about damage to the parts located inside the water tank (water tank), so that it includes a detergent such as chlorine bleaching component or oxidizer And may further include various components for obtaining a strong cleaning effect.

The detergent of the present invention may be selected from the group consisting of trichloroisocyanuric acid, sodium dichloroisocyanuric acid, sodium dichloroisocyanurate dihydrate, calcium hypochlorite, bromochlorodimethyl hydantoin, dichlorodimethyl hydantoin, trichloromelamine, It may contain at least one selected from the group consisting of perborate monohydrate, sodium perborate tetrahydrate, calcium peroxide, zinc peroxide, percarbamide, -olefin sulfonate, and sodium percarbonate, preferably trichloroisocyanurate Sulfuric acid, sulfuric acid, sulfuric acid, sulfuric acid, sulfuric acid, sulfuric acid, sulfuric acid, sulfuric acid,

One embodiment of the present invention is a process for the preparation of a trichloroacetic acid salt of trichloro isocyanuric acid, sodium dichloroisocyanuric acid, sodium dichloroisocyanurate dihydrate, calcium hypochlorite, bromochlorodimethyl hydantoin, dichlorodimethyl hydantoin, trichloro At least one cleaning component selected from the group consisting of melamine, sodium perborate monohydrate, sodium perborate tetrahydrate, calcium peroxide, zinc peroxide, percarbamide,? -Olefin sulphonate, and sodium percarbonate; And a porous bead or a foaming agent.

The porous beads of the present invention may include at least one selected from the group consisting of glass bubbles, porous silica, and porous ceramics.

The porous bead of the present invention may be contained in an amount of 20 to 80% by weight based on the total weight of the composition for cleaning a toilet bowl.

The porous beads included in the toilet bowl cleaning composition may have a diameter of 5 to 30 micrometers, and preferably 10 to 25 micrometers.

The cleaning composition of the present invention may further include components commonly used in the art, so long as the object of the present invention is not impaired.

An embodiment of the present invention provides a toilet cleaner having a frame in a solid toilet cleansing composition.

As used herein, the term "solid" means having a constant shape or volume at room temperature, and refers to a state in which the particles are aggregated and maintained in shape by mutual attraction.

The frame located inside the detergent may be radially connected about the cleaning composition. The frames are surrounded by a cleaning composition and the frame may be disassembled or separated while the cleaning composition of the core connecting the frame is dissolved. That is, the interior of the solid detergent has a frame (skeleton) structure so as not to be sucked into the sewer before the use of the detergent is completed. The skeletal structure is coupled with a solid detergent as a center, and after the solid detergent has been eluted, the seams disappear, so that the frames can not be connected any more and are separated.

Referring to FIG. 1, a frame according to an embodiment of the present invention may be configured in a radial form.

As used herein, the term "radial" refers to a shape extending from a central point to a quadrangle, wherein the cleaning agent of the present invention maintains its shape by the presence of the cleaning composition of the present invention in the central region where the frames are radial Structure. The interval between the frames is not particularly limited.

1 is a view showing one embodiment of the cleaning agent of the present invention.

FIG. 1 is a view showing a state in which a spherical cleaning agent having a frame therein is dissolved, for example. Specifically, in a first form with the frame inside and the outer surface of the frame surrounded by a solid detergent, as the solid detergent is eluted (Fig. 1A), the solid detergent that was finally connecting the frame could no longer function , The internal skeletal structure is disintegrated. 1B is a view showing a state in which a detergent composition connecting frames is in a process of being dissolved, and FIG. 1C is a view showing a state in which a composition connecting frames is melted and frames are separated. Separate frames may flow with the water through the drainage duct and be discharged outside the toilet. The length and thickness of the frame can be appropriately adjusted according to the structure and condition of the toilet bowl used, and are not particularly limited. Preferably, however, the frame needs to serve to support the cleaning components while the detergent composition is dissolved, so that a water-insoluble material can be used.

2 is a view showing a state where the cleaning agent of the present invention is dissolved in the rim and the cleaning liquid is discharged. Referring to FIG. 2, the water flowing from the water tank through the stopper into the toilet passes through the rim hole, but a part of the water moves inside the rim of the toilet surrounding the bowl. Since this space communicates with the bowl hole, which is the lower part of the toilet bowl, if the present invention is remained inside the toilet surrounding the bowl, the water contained in the bowl becomes a cleaning liquid of a certain concentration and the chlorine bleach contained in the solid detergent The resulting chlorine gas disinfects the entire bowl to prevent contamination up to the top of the toilet where the cleaning liquid does not reach.

The cleaning agent of the present invention may have a specific gravity of 0.9 to 1.1. If the specific gravity is less than the specific gravity range, there is a possibility that when the cleaning agent of the present invention is applied to the tank, it floats on the water surface and does not move to the toilet together with water. It is deposited on the bottom of the tank when the cleaning agent of the present invention is added to the tank, which is not desirable for the purpose of the present invention.

According to one embodiment of the present invention, the cleaning agent of the present invention may have a diameter of 30 to 70 mm so as to remain in the rim and to release the cleaning component.

The composition for cleaning a toilet included in the detergent of the present invention may include a porous bead or a foaming agent to have the specific gravity range. The porous beads may include at least one selected from the group consisting of hollow glass beads, porous silica, and porous ceramics. For the purpose of the present invention, glass beads may be used.

The porous bead of the present invention may be contained in an amount of 20 to 80% by weight based on the total weight of the composition for cleaning a toilet bowl. For the purpose of the present invention, the detergent containing the composition for cleaning a toilet bowl of the present invention preferably has a specific gravity of 0.9 to 1.1. When the content of the porous beads is in the above range, the detergent of the present invention may have a desired specific gravity .

The porous beads included in the toilet bowl cleaning composition may have a diameter of 5 to 30 micrometers, and preferably 10 to 25 micrometers.

The frames located within the detergent composition of the present invention may have a total specific gravity of from 0.01 to 0.03, and preferably the frame may be a water-soluble block.

According to another embodiment of the present invention, the detergent of the present invention may contain an inorganic / organic blowing agent in the detergent composition to have a specific gravity of 0.9 to 1.1.

Examples of the foaming agent include azo dicarbonamide (ADCA), dinitroso pentamethylenetetramine (DPT), p, p'-oxybisbenzenesulfonylhydrazide (OBSH) and the like, which are inorganic or organic foaming agents which are inorganic foaming agents .

The foaming agents may generate bubbles during the mixing and heating of the toilet bowl cleaner composition, thereby controlling the specific gravity appropriately.

Another embodiment of the present invention provides a toilet cleanser comprising the cleaning composition and frame having a specific gravity of 0.9 to 1.1. The toilet cleaner is radially connected to one or more frames within the solid toilet cleansing composition so that the frames can be separated when the cleaning composition that is present in the radial center and connects the frames is dissolved.

Because it is not located inside the water tank, there is less risk of direct corrosion of the tank, so the chlorine bleaching component can be used to maximize the cleaning power.

Since it is not located on the outside like a rim block detergent, there is little risk of contamination or damage to aesthetics, so that it can be used comfortably.

It can be easily used by putting it in a water tank and exhibits excellent cleaning power.

When the cleaning agent of the present invention is used, the cleaning agent can be automatically removed while the structure is dismantled, so that it can be conveniently used.

BRIEF DESCRIPTION OF THE DRAWINGS The accompanying drawings, which are incorporated in and constitute a part of the specification, illustrate exemplary embodiments of the invention and, together with the description of the invention, It should not be construed as limited.
FIG. 1 is a view showing an elution process of a detergent composition according to an embodiment of the present invention. FIG. 1 (a) shows a state in which a frame is radially contained, and in use, the frame is fixed by a detergent composition. As can be seen in (c), when the detergent composition is completely consumed and all of the cleaner composition is consumed, the frames may be separated and discharged through the drain.
Fig. 2 is a view showing a distribution of water containing a detergent component when using a detergent in the form of a rim block. Fig. As can be seen from FIG. 2, the water remained in the rim portion according to the present invention does not include the cleaning component, and therefore, the rim and the rim hole portion are not cleaned.
FIG. 3 is a graph showing distribution of cleaning components when a cleaning agent according to an embodiment of the present invention is used. Cleaning components can reach all parts of the toilet where water from the water tank remains.
4A to 4D are views showing a state where a cleaning product containing a frame is put into a water tank and discharged to a drain port according to another embodiment of the present invention. Referring to FIG. 4A, it can be seen that the cleaning product of the present invention has a specific gravity similar to that of water when it is poured into a water tank, so that it is kept in a state where it sinks on the bottom of a water tank or does not float on water. FIG. 4B is a view showing a state in which the cleaning product of the present invention flows together with water when the lever is pressed, the packing is opened, and the rim portion. FIG. 4C shows a state in which the cleaning component remains in the bowl hole and is eluted. FIG. 4D is a view showing a state where the detergent composition is completely dissolved and the frames are moved to the drain along the trap in a decomposed state. FIG.
FIG. 5 is a vertical view of the toilet from above, showing the appearance of the cleaning product remaining in the rim portion.

Hereinafter, the present invention will be described in more detail with reference to the following examples. However, the embodiments according to the present invention can be modified into various other forms, and the scope of the present invention should not be construed as being limited to the above-described embodiments. The embodiments of the present invention are provided by way of example to facilitate a specific understanding of the present invention.

<Comparison of results according to glass beads content>

A toilet cleaning composition having the compositions of the following Examples and Comparative Examples 1-2 was prepared.

The following glass beads were prepared by using HGMS-0.6 of cospheric company.

Example (1) Comparative Example (1) Comparative Example (2) SDIC 15 40 9.5 LAS 15 15 3 AOS 5 5 2 sulphate of soda 24.5 39.5 0 incense 0.5 0.5 0.5 Glass Bead 40 0 85

The composition components were mixed to prepare a spherical shape having a frame as an internal structure. The composition was poured into a sphere shape after the frame was fixed to a small spherical composition so that it could not be decomposed until the composition was fully dissolved. In Example 1 and Comparative Example 1-2, the specific gravity including the frame 1.

Example 1 contained 40% by weight of glass beads relative to the total weight of the detergent composition. Using the composition of Example 1, a toilet cleanser having a specific gravity of about 1 was prepared and, as a result, the water was moved to the inside of the toilet together with water when it was dropped.

Cleansing products of Comparative Example 1 made of the composition cleansing product specific gravity is the time of preparation to the tank to 1.53 g / cm ³ does not go to the toilet bowl interior sink Comparative Example (2) of the in a specific gravity of 0.73 g / cm ³ When put into the tank, it floated on the water and did not move into the toilet.

<Comparison with existing products>

Comparative Example (3) is a product (product name: 119 toilet flushing sterilization, manufacturer: LGHI Healthcare Co., Ltd.) containing a toilet bowl cleaner in a non-mist starter, Comparative Example (4) BREP POWER ACTIVE, manufacturer: Henkel).

The following are the results of the questionnaire survey of 50 housewives for Example (1) and Comparative Examples (3) and (4).

The results are shown in the following five points. The higher the value, the better the evaluation.

Example (1) Comparative Example (3) Comparative Example (4) Cleaning power 4.9 2.3 3.6 Bleaching power 4.8 2.1 3.1 Pollution prevention 4.8 1.2 3.8 Degree of corrosion of toilet bowl One One One

The present invention is superior in cleaning power and bleaching power to the toilet-type toilet cleaner (Comparative Example (3)) and the Rim-Block type toilet cleaner (Comparative Example (4)). In particular, the pollution-preventing effect was remarkably superior to the in-tank type product of Comparative Example 3.

The cleaning product of the present invention had a superior cleaning effect as described above, and had no risk of corrosion of the toilet tank similar to Comparative Examples 3 and 4.

1: cleaning composition
10: frame
100: Water tank
101: Packing
200: rim
210: rim-hole
300: bowl
310: bowl hole
400: Trap

Claims (23)

A toilet cleaner having a specific gravity of 0.9 to 1.1. The toilet cleaner of claim 1, wherein the toilet cleanser has a diameter of 30 to 70 mm and remains within the rim of the toilet to release the cleansing component. The toilet cleaner of claim 1, wherein the toilet cleaner comprises a porous bead or a foaming agent. The toilet cleaner according to claim 3, wherein the porous bead comprises at least one selected from the group consisting of glass bubbles, porous silica, and porous ceramics. 4. The process of claim 3 wherein said blowing agent is selected from the group consisting of azo dyes, azodicarbonamide (ADCA), dinitroso pentamethylenetetramine (DPT), and p, p'-oxybisbenzenesulfonylhydrazide (OBSH) Wherein the cleaning agent comprises at least one selected from the group consisting of: The cleaning composition of claim 3, wherein the detergent is selected from the group consisting of trichloroisocyanuric acid, sodium dichloroisocyanuric acid, sodium dichloroisocyanurate dihydrate, calcium hypochlorite, bromochlorodimethyl hydantoin, dichlorodimethyl hydantoin, trichloro Characterized in that it comprises at least one selected from the group consisting of sodium carboxymethylcellulose, melamine, sodium perborate monohydrate, sodium perborate tetrahydrate, calcium peroxide, zinc peroxide, percarbamide, alpha-olefin sulfonate, and sodium percarbonate. detergent. A toilet cleaning product in which one or more frames are provided within a solid toilet cleansing composition. The method of claim 7, wherein the frames located inside are radially connected about the cleaning composition,
Wherein the frames are separated when the cleaning composition of the core connecting the frames is dissolved. The toilet cleaning product according to claim 7, wherein the frame is a water-soluble block having a total specific gravity of 0.01 to 0.03. 8. The toilet cleaning composition according to claim 7, wherein the composition for cleaning a toilet is selected from the group consisting of trichloroisocyanuric acid, sodium dichloroisocyanuric acid, sodium dichloroisocyanurate dihydrate, calcium hypochlorite, bromochlorodimethyl hydantoin, It is characterized in that it contains at least one selected from the group consisting of toluene, trichloromelamine, sodium perborate monohydrate, sodium perborate tetrahydrate, calcium peroxide, zinc peroxide, percarbamide, alpha -olefin sulfonate, and sodium percarbonate Toilet cleaning products. 8. A toilet cleaning product according to claim 7, wherein the detergent has a specific gravity of 0.9 to 1.1 and a diameter of 30 to 70 mm. 8. The toilet cleaning product of claim 7, wherein the toilet cleansing composition comprises a porous bead or a foaming agent. The toilet cleaning product according to claim 7, wherein the porous beads include at least one selected from the group consisting of glass bubbles, porous silica, and porous ceramics. 13. The toilet cleaning product according to claim 12, wherein the porous beads are contained in an amount of 20 to 80% by weight based on the total weight of the toilet cleaning composition. 13. The toilet cleaning product of claim 12, wherein the porous bead has a diameter of 5 to 30 micrometers. 8. The process of claim 7 wherein said blowing agent is selected from the group consisting of azo dyes, azodicarbonamide (ADCA), dinitrosoopentamethylenetetramine (DPT), and p, p'-oxybisbenzenesulfonylhydrazide (OBSH) Wherein the at least one selected from the group consisting of: &lt; RTI ID = 0.0 &gt; 1, &lt; / RTI &gt; A toilet cleaning product comprising a composition for cleaning a toilet bowl and a frame and having a specific gravity of 0.9 to 1.1,
Wherein at least one frame is radially connected to the interior of the solid toilet flushing composition so that the frames are separated when the cleaning composition that is present in the radial center and connects the frames is dissolved. But are not limited to, trichloroisocyanuric acid, trichloroisocyanuric acid, sodium dichloroisocyanuric acid, sodium dichloroisocyanurate dihydrate, calcium hypochlorite, bromochlorodimethyl hydantoin, dichlorodimethyl hydantoin, trichloromelamine, At least one oxidizing agent selected from the group consisting of sodium perborate tetrahydrate, calcium peroxide, zinc peroxide, percarbamide,? -Olefin sulfonate, and sodium percarbonate; And
A porous bead or a foaming agent. The toilet cleaning composition according to claim 18, wherein the porous beads comprise at least one selected from the group consisting of glass bubbles, porous silica, and porous ceramics. The toilet cleaning composition according to claim 18, wherein the porous bead is contained in an amount of 20 to 80% by weight based on the total weight of the toilet cleaning composition. The toilet cleaning composition according to claim 18, wherein the porous beads have a diameter of 5 to 30 micrometers. 19. The process of claim 18, wherein the blowing agent is selected from the group consisting of azo dyes, azodicarbonamide (ADCA), dinitrosoopentamethylenetetramine (DPT), and p, p'-oxybisbenzenesulfonylhydrazide Wherein the composition comprises at least one selected from the group consisting of water, alcohol, and water. The toilet cleaning composition according to claim 18, wherein the composition for cleaning a toilet has a specific gravity of 0.9 to 1.1.

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