KR20160088007A - Metallic thermal solution and device. - Google Patents

Abstract

The present invention relates to a floor mat coated with a heat-providing nonferrous metal liquid, and more specifically, to a floor mat coated with a heat-providing metal liquid which induces the generation of heat within the floor mat, thereby increasing the comfort of the user. In the traditional Ondol architecture where high energy consumption by the floor is unavoidable, the floor mat of the present invention can significantly reduce energy costs. The floor mat of the present invention allows heat provided by a heat source on the floor alone to elevate, radiate and diffuse inside a room, thereby providing heat sufficiently throughout the room while consuming less energy. Also, the floor mat of the present invention, when heated, radiates infrared rays which is beneficial for blood circulation, alleviation of pain, rheumatism and arthritis.

Description

{Metallic thermal solution and device.

[0001] The present invention relates to a laminate to which a solution for heating a metal substance with a non-ferrous metal is applied, and more particularly to a laminate to which a solution for heating a metal substance is applied, .

BACKGROUND ART [0002] Techniques related to a conventional heating body or a carbon fiber for manufacturing the same have been disclosed in Utility Model Registration No. 0350509 (2004.05.04) related to a low density flat heating element having a conductive portion woven and woven by a conductive material to have a very low warp yarn density Patent Document 1: Japanese Patent Application Laid-Open No. 2005-0081314 (2005.08.19) related to a heating element body having a low-density surface heating element using a carbon fiber yarn, a carbon yarn as a weaving yarn, A method of manufacturing a heating element fabric using a fiber, and a utility model registration No. 0389288 (Jun. 30, 2005) related to a heating element woven with carbon yarn so as to minimize cutting or shorting due to improvement in heat generation function and rupture, Cotton weave heating body '.

1 is a schematic block diagram of a carbon fiber manufacturing apparatus according to the prior art.

Since the carbon-based heat generating material must maintain conductivity, the carbon and graphite are supplemented to secure the conductivity. However, when used excessively, the adhesion of the coating solution deteriorates and a stable resistance value can not be maintained. do.

In addition, electricity is generated as a mediator, and therefore, there is a danger of electricity.

As a result, the need for self - heating through the exothermic solution is increasing without power, and there is a continuing demand for the plates that prevent the majors of electric accidents and improve the thermal efficiency of the elderly and children.

Korean Patent Registration No. 10-0754322 (2007. 08. 27)

The purpose of the present invention is to solve the problems of the prior art as described above, and it is an object of the present invention to reduce the time for reaching the target temperature of the heating element coated with the finally prepared heating solution, It is aimed at enhancing the thermal effect of the plank.

In addition, the base plate coated with the exothermic solution radiates far-infrared rays, thereby contributing to health promotion.

In addition, the long plate coated with the exothermic solution provides a function to quickly perform the heat diffusion rate after radiating.

In order to solve the above problems, the present invention provides a long plate to which a heat generating solution for a metal material is applied, 3 or more of Se, Mn, Ag, Pt, Cu, Zn, Mg, Sn, Fe, Mo, Co, V, Ge, Tln and Sr, An equalizer 215 for equalizing the respective metal powder pulverized in the individual dry milling machine 210 by the same ratio and an equalizer 215 for equalizing the metal powder from the equalizer 215, And the metal powder sufficiently agitated through the primary agitator 220 is calcined at a temperature of 1,800 ° C. to 1,900 ° C. for at least 24 hours in a nitrogen atmosphere, And a high-temperature heating furnace (225) for heating the calcined metal powder A fine powder shredder 235 for crushing the metal powder in a mass form from the quencher 230 into a metal fine powder having an average particle size of 3,000 mesh or more from the quencher 230, A second agitator 240 which is selected from 2Na-EDTA and Ca-EDTA, which are coupling agents, is added to the metal fine powder pulverized from the pulverized metal powder, the water is sequentially added thereto, and the mixture is stirred at 100 to 150 rpm for 1 hour to 2 hours, A first reaction tank 245 for adding ion colloidal germanium to metal fine powder particles coated with a coupling agent through a car stirrer 240 and then reacting at 30 ° C to 50 ° C for 2 hours or more, A second reaction tank 250 for adding an ion colloidal synthetic metal to the metal solution that has passed through the second reaction tank 245, and a drier 255 for drying the metal powder solution passed through the second reaction tank 250, From the dryer 255, A third stirrer 260 for adding a thickening agent to the metal powder solution and agitating the dispersion for 10 minutes to 30 minutes at a rate of 50 to 100 rpm so as to be dispersed well, and a dispersing agent in the solution obtained in the third stirrer 260, A fourth stirrer 265 for stirring the mixture for 30 minutes or more at a rate of 10 to 50 rpm so as to be dispersed well and a heating solution 500 having a uniform layer applied through the fourth stirrer 265, (400).

According to the present invention, as a traditional culture of ondol, since the structure of the floor is inevitably used a lot of energy, the fuel cost can be remarkably reduced by using the long plate coated with the heating solution of the present invention.

It uses only the heat source of the floor and radiates it. It uses heat energy to heat up the heat. The heat is released by the heat, and the heat is diffused inside the room to radiate the warmth, warming every corner,

Far infrared rays are radiated during fever, and the effects are also helping human health such as blood circulation promotion, pain relief, rheumatism and arthritis.

1 is a schematic block diagram of a carbon fiber manufacturing apparatus according to the prior art.
2 is an embodiment of a laminate on which a heat generating solution of a metal material is applied.
3 is a view showing an individual dry mill of a long plate coated with a heat generating solution of a metal material.
Fig. 4 is an embodiment of an equivalent period equivalent to four metal particles of a long plate coated with a heating solution of a metal substance.
5 shows the inside of a stirrer of a long plate coated with a heat generating solution of a metal material.
6 is an example of a quencher of a long plate coated with a heating material solution of a metal material
Fig. 7 shows one embodiment of producing a base plate to which a heating solution of a metal substance is applied.
8 is a perspective view of a base plate to which a heat generating solution of a metal material is applied.
9 is a cross-sectional view of a base plate to which a heating solution of a metal substance is applied.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, a laminate to which a heating solution of a metal material of the present invention is applied will be described in detail with reference to the accompanying drawings.

2 is an embodiment of a laminate on which a heat generating solution of a metal material is applied.

2, a non-ferrous metal and a metal material such as Ni, In, Al, Ti, Zr, Vi, Ba, Se, Mn, Ag, Pt, Cu, Zn, Mg, Sn, Fe, , Ge, Tln, and Sr, and a plurality of three or more individual dry mills 210 for pulverizing the respective metal materials to an average particle size of 1 mm to 5 mm.

For example, if Ni, Al, and Ti are selected, an individual dry mill 200 for dry milling Ni, an individual dry mill 200 for dry milling Al, and an individual dry mill 200 for dry milling Ti .

In each dry mill, Ni, Al and Ti should be pulverized to have an average particle size of about 1 mm to 5 mm.

The commonality of non-ferrous metals and metal substances such as Ni, In, Al, Ti, Zr, Vi, Ba, Se, Mn, Ag, Pt, Cu, Zn, Mg, Sn, Fe, Mo, Co, V, Ge, Tln and Sr Are metals that act in the direction of diffusing heat.

Since these materials are mixed with other metal materials and have a more stable structure, they are subjected to a pulverizing process in order to mix various materials together.

The individual dry pulverizer 210 functions to pulverize the metal material into a powder.

3 is a view showing an individual dry mill of a long plate coated with a heat generating solution of a metal material.

As shown in Fig. 3, the wet grinding machine and the dry grinding machine can be divided into a wet grinding machine and a dry grinder.

In the dry mill, the average particle size is reduced to 1 to 5 mm.

When a dry mill having a more excellent performance is employed, powder can be pulverized to a size of 0.1 mm to 0.3 mm.

In each individual dry mill, the milled metal particles become equivalent in the same ratio.

FIG. 2 shows an equivalence device 215 that equates each of the metal powders ground in the individual dry mill with the same ratio.

In the present invention, metal powders in the form of particles are measured at the same rate through individual dry mills and then introduced.

An equivalent weight 215 is shown for equalizing each of the metal powders pulverized in the individual dry pulverizer in the same ratio so that each metal powder can equally be equivalent in the equivalent weight.

The equivalent weight can be preferably employed as an electronic precision balance.

There is shown a primary agitator 220 which is stirred at the same rate from the equivalents so that the mixed metal powders can be mixed sufficiently.

Fig. 4 is an embodiment of an equivalent period equivalent to four metal particles of a long plate coated with a heating solution of a metal substance.

The metal powders, equally charged through the equivalents, are collected together and stirred to mix together.

FIG. 2 shows a primary agitator 220 stirring the mixed metal powder in the same ratio from the equivalents.

5 shows the inside of a stirrer of a long plate coated with a heat generating solution of a metal material.

As shown in FIG. 5, the metal powders are sufficiently agitated in an agitator.

FIG. 2 shows a high-temperature stirrer 225 for calcining the metal powder sufficiently stirred through the primary stirrer in a nitrogen atmosphere at 1,800 ° C. to 1,900 ° C. for at least 24 hours.

Calcination is an operation of heating a substance to a high temperature to remove a part or all of volatile components. For example, in the case of magnesium carbonate, the containing carbonate group is removed at 800 to 900 ° C, and the calcined magnesia can be obtained.

In the present invention, the metal powder is heated at 1,800 ° C. to 1,900 ° C. for 24 hours or more to remove volatile components.

As atmosphere gas, inert gas is generally used. Nitrogen gas is very inexpensive and has a lot of air, so it is very stable gas, it does not affect the atmosphere, and it is harmless to human body.

The atmospheric gas is for preventing the oxidation of the metal. Since the metal powder tends to bond with oxygen at a high temperature, nitrogen gas is added to remove or exclude oxygen to prevent oxidation.

FIG. 2 shows a quencher 230 for quenching the calcined metal powder from the high-temperature heating.

6 is an example of a quencher of a long plate coated with a heating material solution of a metal material

As shown in FIG. 6, the quencher serves to cool the heated metal powders from the high-temperature heater 225 at a high rate.

A drum cooler is often used as the cooler, and FIG. 6 is a view showing the inside of the cooler.

In the present invention, it is also possible to quench in air without employing a separate quencher. That is, it can be cooled in the air as it is.

In FIG. 2, there is shown a fine powder mill 235 for pulverizing the metal powder in the form of mass in the quenching process from the quencher to metal fine powder having an average particle size of 3,000 mesh or more.

Through the quench machine, the metal powder is in a massive form (lump).

This mass is again pulverized into fine powder.

3,000 meshes are 3,000 meshes within 1 inch (2.54 cm) and are the sizes through which they pass.

The fine metal powder produced through the fine powder mill is passed through a secondary agitator.

FIG. 2 shows a second agitator (2Na-EDTA and Ca-EDTA), which is selected from coupling agents such as 2Na-EDTA and Ca-EDTA, is added sequentially to the metal fine powder pulverized from the pulverizer, and stirred at 100 to 150 rpm for 1 to 2 hours 240 are shown.

The coupling agent is a substance for increasing the bonding force between the dissimilar materials having different surface properties.

EDTA is a colorless crystalline powder that binds to metals via four carboxylate salts and two amine groups.

It has the characteristic of making almost all metal ions and water-soluble chelates, and is also called ethylenediaminetetraacetic acid as the formula C10H16N2O8.

For reference, EDTA is a colorless crystalline powder with a melting point of 240 ° C (decomposition). Its solubility in water is 0.2 g in 100 mℓ of water at 22 ° C and does not dissolve in ethanol, ether and the like.

A chelate is a substance capable of ionic bonding with a metal. A chelate is a Latin word meaning a tongue. In a metal complex, two or more sites of a ligand are bound to the same metal ion. As a result, An example of a chelating agent is an ethylidamine (1,2-diaminoethane), and two amino groups are bonded to the same atom to form a chelate.

2Na-EDTA is a well-known chelating agent (metal ion sequestering agent) that binds with various metal ions to form a complex salt, which is a very stable substance compared to other kill tracers. The incorporation of metal ions into cosmetics can cause rancidity, alteration and discoloration of cosmetics.

The substance used for blocking the metal ion is a sequestering agent. The sodium salt of ethylenediaminetetraacetic acid (EDTA) (Exodium edetate) is the most common.

Ca-EDTA also binds to metal ions to form stable chelate compounds.

2 also shows a first reaction vessel 245 in which ion colloidal germanium is added to metal fine powder particles coated with a coupling agent through the secondary agitator and then reacted at a temperature of 30 ° C. to 50 ° C. for 2 hours or more. .

A colloid is a state in which the substance is dispersed. The colloid state in which fine particles having a particle size of 1 nm to 100 nm and larger than ordinary molecules or ions are dispersed in a gas or a liquid is called a colloid state. For example, Lt; / RTI >

In the present invention, an ion colloid is an ion or a colloid.

In other words, it means either ion or colloidal.

Ion colloidal germanium is ionic germanium or colloidal germanium.

When germanium comes into contact with the human body, the germanium ions enter the body and the harmful substances in the body are discharged to the outside of the body, cleansing the body, cleansing the blood, helping circulation, and improving the function of the body.

Next, a secondary reaction tank 250 is shown in which an ion colloidal synthetic metal is added to a metal solution that has passed through the primary reaction tank and reacted.

In the present invention, the term " general metal " means at least one metal of a non-ferrous metal and a metal, and the term " ion colloidal " means a colloidal state of the metal or an ion metal.

Also, a dryer 255 for drying the metal powder solution passed through the secondary reaction tank is shown.

In the dryer, the moisture of the metal powder solution is removed so as to be an appropriate concentration of the solution.

Preferably, the metal powder solution is dried to have a water content value of 5 ppm or less.

Next, a tertiary stirrer 260 is shown in which a thickener is added to the moisture-controlled metal powder solution from the drier and stirred so as to be dispersed at a rate of 50 to 100 rpm for 10 to 30 minutes or more.

A thickener is a drug which is added to a colloid solution, a polymer solution or the like to increase the viscosity of the colloid solution or polymer solution, thereby imparting thixotropy. Adhesives, cements, latexes, paints, cosmetics, etc. However, there are many kinds of thickeners used depending on the subject.

In the present invention, the thickening agent is preferably selected from acrylic resin, polyol, and inorganic binder.

Finally, it can be seen that a fourth agitator 265 is shown in which a dispersant is added to the solution obtained in the third agitator and agitated so as to be dispersed well at a rate of 10 to 50 rpm for 10 minutes to 30 minutes.

A dispersant is a substance that is added to prevent agglomeration of microparticles when particles and agglomerated particles are pulverized into small particles and colloidal particles. Adsorbing materials such as surfactants and high molecular materials are used. Peptizers are also included in the dispersant.

The solution obtained through the fourth stirrer becomes the exothermic solution to be obtained in the present invention.

When applying the heating solution of the present invention, only the heat source of the floor is used, and the heat is radiated by using the heat source as the heat energy to raise the heat, and heat is generated to emit heat. At the same time, It serves to increase the heat further.

Fig. 7 is an embodiment of production of a laminate on which a heating solution of a metal substance is applied

(Ni, In, Al, Ti, Zr, Vi, Ba, Se, Mn, Ag, Pt, Cu, Zn, Mg, Sn, Fe, Mo, Co, V, Ge, Tln, and Sr), and pulverizing each of the metal materials to an average particle size of 1 mm to 5 mm.

Next, a second step 715 of equalizing each of the metal powders pulverized in the first step in the same ratio is shown.

A third step 720 of stirring the mixed metal powder in equal proportions from the second step is shown.

In addition, there is a fourth step (725) of calcining the metal powder sufficiently agitated through the third step in a nitrogen atmosphere at a temperature of 1,800 ° C. to 1,900 ° C. for at least 24 hours, and the metal powder calcined from the fourth step And a fifth step 730 of quenching.

In the fifth step, there is a sixth step (735) of pulverizing the metal powder in a massive form into a metal fine powder having an average particle size of 3,000 mesh or more during the quenching step. In the sixth step, 2Na- EDTA, and Ca-EDTA, sequentially adding water, and then stirring at a rate of 100 to 150 rpm for 1 hour to 2 hours.

There is an eighth step (745) of adding ion colloidal germanium to the metal fine powder particles coated with the coupling agent through the seventh step and then reacting at a temperature of 30 ° C. to 50 ° C. for 2 hours or more, And a ninth step (750) in which the ion colloidal synthetic metal is added to the metal solution through the reaction.

The tenth step (755) is a step of drying the metal powder solution after the ninth step. In the tenth step, the thickening agent is added to the moisture-controlled metal powder solution and dispersed at a rate of 50 to 100 rpm for 10 minutes to 30 minutes And a twelfth step (760) in which the dispersing agent is added to the solution obtained in the eleventh step and stirred for 10 to 30 minutes at a rate of 10 to 50 rpm so as to be well dispersed, ).

FIG. 8 is a perspective view of a long plate coated with a heat generating solution of a metal material, and FIG. 9 is a sectional view of a long plate coated with a heating solution of a metal material.

The heating plate 500 having the metal substance heating solution coated thereon according to the present invention is manufactured by uniformly applying the heating solution 500 on the upper side of the base plate 400.

At this time, the long plate 400 is installed on the bottom of the building and serves to increase the room temperature by generating heat in the room through the heating solution 500 applied on the upper plate 400.

The plate having the metal material heating solution applied thereto radiates heat only by using the heat source 500 using the heat source 500 as a thermal energy to radiate heat to generate heat and emit heat, And a heating solution (500) for heating the heating plate (400) to a higher temperature.

According to the present invention, fuel costs can be reduced by up to 35% as part of energy savings. In the present invention, far-infrared rays are radiated in the case of fever, and as a result of this, an additional effect of assisting human health such as blood circulation promotion, pain relief, rheumatism and arthritis can be obtained.

The scope of the present invention is defined by the appended claims rather than the detailed description and all changes or modifications derived from the meaning and scope of the claims and their equivalents are to be construed as being included within the scope of the present invention do.

210: Individual dry mill 200: Equivalent
220: primary stirrer 225: high temperature heater
230: Rapid cooling machine 235: Pulverizer
240: Secondary mixer 245: Primary mixer
250: Secondary reaction tank 255: Dryer
260: Third stirrer 265: Fourth stirrer
400: plate 500: exothermic solution

Claims (1)

In a base plate to which a heating solution for a metal substance is applied,
Among the non-ferrous metals and the metallic materials, 3, 3, and 4 of the Ni, In, Al, Ti, Zr, Vi, Ba, Se, Mn, Ag, Pt, Cu, Zn, Mg, Sn, Fe, Mo, Co, V, Ge, Three or more individual dry mills (210) for selectively pulverizing the respective metal materials to an average particle size of 1 mm to 5 mm;
An equalizer 215 for equalizing the respective metal powders pulverized in the individual dry pulverizer 210 in the same ratio;
A primary stirrer 220 for stirring the metal powder mixed in the same ratio from the equivalents 215 and mixed;
A hot agitator 225 for calcining the metal powder sufficiently agitated through the primary agitator 220 at a temperature of 1,800 ° C. to 1,900 ° C. for 24 hours or more in a nitrogen atmosphere;
A quencher (230) for quenching the calcined metal powder from the high temperature heater (225);
A fine powder crusher 235 for crushing the metal powder in a mass form from the quencher 230 into a metal fine powder having an average particle size of 3,000 mesh or more during the quenching process;
2Na-EDTA or Ca-EDTA, which is a coupling agent, is added to the metal fine powder pulverized from the fine powder mill 235, and water is added sequentially, and then the mixture is agitated at a speed of 100 to 150 rpm for 1 hour to 2 hours 240;
A primary reaction tank 245 for adding ion colloidal germanium to the metal fine powder particles coated with the coupling agent through the secondary agitator 240 and then reacting at 30 ° C to 50 ° C for 2 hours or more;
A secondary reaction tank 250 for adding an ion colloidal synthetic metal to the metal solution which has passed through the primary reaction tank 245 and reacting;
A dryer 255 for drying the metal powder solution that has passed through the secondary reaction tank 250;
A tertiary stirrer 260 for adding a thickener to the moisture-controlled metal powder solution from the dryer 255 and agitating the solution at a rate of 50 to 100 rpm for 10 minutes to 30 minutes so as to be well dispersed;
A fourth agitator 265 for adding a dispersant to the solution obtained in the third agitator 260 and agitating the dispersion for 10 minutes to 30 minutes at a rate of 10 to 50 rpm so as to be well dispersed;
And a long plate (400) having a uniform layer coated with the exothermic solution (500) produced through the fourth agitator (265).

Images