KR20160087180A - Antioxidant pigment composition and packing material comprising thereof - Google Patents

Antioxidant pigment composition and packing material comprising thereof Download PDF

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Publication number
KR20160087180A
KR20160087180A KR1020150005998A KR20150005998A KR20160087180A KR 20160087180 A KR20160087180 A KR 20160087180A KR 1020150005998 A KR1020150005998 A KR 1020150005998A KR 20150005998 A KR20150005998 A KR 20150005998A KR 20160087180 A KR20160087180 A KR 20160087180A
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pigment composition
packaging material
antioxidant
antioxidant pigment
present
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KR1020150005998A
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Korean (ko)
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김진웅
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김진웅
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/01Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/014Stabilisers against oxidation, heat, light or ozone
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/04Carbon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K15/00Anti-oxidant compositions; Compositions inhibiting chemical change
    • C09K15/02Anti-oxidant compositions; Compositions inhibiting chemical change containing inorganic compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/16Applications used for films
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/066LDPE (radical process)

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wrappers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The antioxidant pigment composition and packaging material of the present invention have an excellent antioxidative effect. When the antioxidant pigment composition according to one aspect of the present invention is included in the packaging material, the progress of rancidity of foods and the like in the packaging material can be slowed, It is possible to maintain the freshness of the food and increase the preservation period of the food. In addition, the antioxidant pigment composition and packaging material of the present invention can be safely used as a food packaging material and can be used as a sanitary packaging material for various foods in which oxidation and bacterial decay are easily occurred. Thus, degradation and browning of food, Can be significantly improved. As a result, it is possible to prevent a loss due to corruption or the like in the course of distribution of food or the like.

Description

TECHNICAL FIELD [0001] The present invention relates to an antioxidant pigment composition and packaging materials containing the antioxidant pigment composition.

To a pigment composition having excellent antioxidative effect and a packaging material containing the pigment composition.

The packaging materials used to pack foods such as foods and steel products and flowers are made of polyethylene, polypropylene and polycarbonate resin. These resins are excellent in transparency and flexibility, , Industrial goods, and the like.

Conventionally, a lot of research and development has been carried out in order to give antimicrobial and antioxidant functions of packaging materials. Antibacterial bioceramics made by mixing antimicrobially treated polyethylene inner surface and antimicrobial vacuum packing bag composed of nylon and polyethylene with ceramic powder containing inorganic antibacterial substance Packaging films, antibacterial films using silver ions, and the like. On the other hand, it is difficult to search for appropriate antioxidant materials and pursue economical efficiency for packaging materials having an antioxidant function for inhibiting the oxidation of food, and for reasons such as the degree of oxidation inhibition by vacuum packaging materials, R & D is relatively slow. A low - density polyethylene film containing fine powder of jade has been developed, but it has been shown that the freshness of the food is prolonged.

Accordingly, there is a need for a packaging material which is antioxidant-functionalized and has safety ensured by inhibiting oxidation of products to be packaged such as food, steel and the like.

A pigment composition having excellent antioxidative effect and a packaging material containing the same are provided.

The antioxidant pigment composition according to one embodiment of the present invention includes shungite.

In the antioxidant pigment composition according to one aspect of the present invention, the antioxidant pigment composition comprises a 1: 1 weight ratio of the shigid and low density polyethylene (LDPE).

In the antioxidant pigment composition according to one aspect of the present invention, the antioxidant pigment composition contains a 1: 1 weight ratio of the water-absorbing pigment and polypropylene (PP).

In the antioxidant pigment composition according to one aspect of the present invention, the antioxidant pigment composition contains the above-mentioned shigudate and polyethylene terephthalate (PET) in a weight ratio of 1: 1.

The packaging material according to another embodiment of the present invention includes an antioxidant pigment composition containing shungite.

In a packaging material according to one aspect of the present invention, the packaging material comprises 6 to 30% by weight of the antioxidant pigment composition and 94 to 70% by weight of high density polyethylene (HDPE).

In a packaging material according to one aspect of the present invention, the packaging material comprises 6 to 30% by weight of the antioxidant pigment composition and 94 to 70% by weight of polypropylene (PP).

In the packaging material according to one aspect of the present invention, the packaging material is used for food, steel products, or mulching.

The antioxidant pigment composition and packaging material of the present invention have an excellent antioxidative effect. When the antioxidant pigment composition according to one aspect of the present invention is included in the packaging material, the progress of rancidity of foods and the like in the packaging material can be slowed, It is possible to maintain the freshness of the food and increase the preservation period of the food.

In addition, the antioxidant pigment composition and packaging material of the present invention can be safely used as a food packaging material and can be used as a sanitary packaging material for various foods in which oxidation and bacterial decay are easily occurred. Thus, degradation and browning of food, Can be significantly improved. As a result, it is possible to prevent a loss due to corruption or the like in the course of distribution of food or the like.

In addition, the packaging material containing the antioxidant pigment composition according to one aspect of the present invention can be used not only as a food but also as a packaging material for steel products, thereby preventing oxidation of steel products and preventing corrosion. In the export of steel products, To increase exports and increase the national competitiveness of the steel industry.

The present invention also relates to an antioxidant pigment composition or a shungite of the present invention. The antioxidant pigment composition of the present invention can be used in various fields such as packaging for preventing oxidization in addition to foods and steel products, and packaging materials for flower, mulching for agricultural use, Is not limited to a film such as a vinyl film, but may be used in addition to plastic compositions and pulp (or paper).

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a schematic view showing a method for producing an antioxidant pigment composition and a packaging material according to one aspect of the present invention.

In the following description of the present invention, a detailed description of known functions and configurations incorporated herein will be omitted when it may unnecessarily obscure the subject matter of the present invention. In addition, the terms described below are established in consideration of the functions of the present invention, and these may vary depending on the intention of the manufacturer or custom in the industry, and the definition should be based on the contents throughout the specification.

Hereinafter, the antioxidant pigment composition and packaging material according to one aspect of the present invention will be described in detail.

Antioxidant pigment compositions and packaging materials in the present invention include shungite. Is a natural nano-structured complex containing 30 to 40% by weight of carbon and 70 to 60% by weight of silicate as a carbon-containing rock, and may be aluminum, magnesium, potassium, sulfur, calcium, It is a substance containing trace elements. In a study of Schujgid, it was found that the spunganite carbon material consists of small globules of 2 to 30 nanometers in size, forming nanostructures, and having natural fullerene and high-order fullerene particle structures. In addition, the variant form of carbon is a mineral that is not coal, not graphite, and does not change into diamond. It has adsorption and ion exchange properties. It absorbs substances harmful to human body, Are known to be concentrated and stored.

The present invention uses such a water-soluble antioxidant as an antioxidant for pigment compositions and packaging materials. The pigment composition and packaging materials containing water-absorbing agents show excellent antioxidative effects in foods and steel products, .

In the antioxidant pigment composition according to one aspect of the present invention, the antioxidant pigment composition comprises a 1: 1 weight ratio of the shigid and low density polyethylene (LDPE). In addition, the antioxidant pigment composition contains a 1: 1 weight ratio of the above-mentioned water-soluble polymer and polypropylene (PP). In addition, the antioxidant pigment composition includes the above-mentioned shiitgid and polyethylene terephthalate (PET) at a weight ratio of 1: 1.

The packaging material comprising an antioxidant pigment composition according to one aspect of the present invention also includes a shigy gum. In the packaging material according to one aspect of the present invention, the packaging material comprises 6 to 30% by weight of an antioxidant pigment composition containing a shigudate, and 94 to 70% by weight of high density polyethylene (HDPE). In addition, the packaging material comprises 6 to 30% by weight of an antioxidant pigment composition containing shigudate and 94 to 70% by weight of polypropylene (PP). If the amount of the antioxidant pigment composition exceeds 30% by weight in the packaging material according to one aspect of the present invention, it is difficult to form the packaging material, which is a major cause of an increase in manufacturing cost in terms of economy. Therefore, in the packaging material according to one aspect of the present invention, the antioxidant pigment composition is 6 to 30% by weight, and it may preferably be 20% by weight in order to have excellent antioxidative function.

In addition, in order to impart an antioxidative function to the pigment composition and the packaging material, the saccharide contained in the antioxidant pigment composition according to one aspect of the present invention may contain polyethylene terephthalate (PET), high density polyethylene (HDPE) polyethylene, HDPE), polyethylene terephthalate glycol (PETG), nylon, polycarbonate (PC), polyvinyl chloride (PVC), thermoplastic polyurethane And ultra high molecular weight polyethylene (UHMWPE). However, the materials used together for imparting antioxidant functions are not limited to the above examples.

The antioxidant pigment composition and packaging material of the present invention have an excellent antioxidative effect. When the antioxidant pigment composition according to one aspect of the present invention is included in the packaging material, the progress of rancidity of foods and the like in the packaging material can be slowed, It is possible to maintain the freshness of the food and increase the preservation period of the food.

In addition, the antioxidant pigment composition and packaging material of the present invention can be safely used as a food packaging material and can be used as a sanitary packaging material for various foods in which oxidation and bacterial decay are easily occurred. Thus, degradation and browning of food, Can be significantly improved. As a result, it is possible to prevent a loss due to corruption or the like in the course of distribution of food or the like.

In the packaging material according to one aspect of the present invention, the packaging material may be used for food, steel products, or mulching. That is, the packaging material of the present invention can be used for foods to perform safe distribution and preservation of freshness of foods, and as a packaging material for steel products, thereby preventing oxidation of steel products and preventing corrosion. In addition, it can be used as a packaging material for flowers to prevent oxidation of flowers and plants, and can be used for agricultural (agricultural use) mulching such as mulching in pepper fields.

In addition, the antioxidant pigment composition and the packaging material of the present invention may be used in a variety of applications such as a plastic composition, pulp (paper) or the like in addition to a film of vinyl or the like in order to impart an antioxidative function thereto. It is not.

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a schematic view showing a method for producing an antioxidant pigment composition and a packaging material according to one aspect of the present invention. Hereinafter, the degree of rancidity due to packaging was examined by storing almonds having a low moisture content and a high lipid content in the packaging materials of the examples manufactured according to the manufacturing method of FIG.

Comparative Example

The plastic packaging material is manufactured using high density polyethylene, Lotte Chemical 7000/7100 or SK Chemical 8800 product.

Example 1

Preparation of antioxidant pigment compositions

In order to prepare the antioxidant pigment composition, 300 kg of shigid and 300 kg of low density polyethylen (LDPE) were mixed in a pigment maker, and the pigment was melted at a temperature of 180 ° C to 220 ° C, and then the pigment was cut .

Preparation of packaging material (when 6% by weight of antioxidant pigment composition is included)

12 kg of the antioxidant pigment composition of Example 1 and 188 kg of high density polyethylene (HDPE) were mixed using a blender to produce a packaging material. After melting at a temperature of 170 ° C to 200 ° C in an extruder for vinyl production, the plastic packaging material is sized and pulled out in the form of an inflated bubble, and then rolled up in roll form.

Example 2

Preparation of antioxidant pigment compositions

In order to prepare the antioxidant pigment composition, 300 kg of shigid and 300 kg of low density polyethylen (LDPE) were mixed in a pigment maker, and the pigment was melted at a temperature of 180 ° C to 220 ° C, and then the pigment was cut .

Preparation of packaging material (when 10% by weight of antioxidant pigment composition is included)

20 kg of the antioxidant pigment composition of Example 1 and 188 kg of high density polyethylene (HDPE) were mixed using a blender to prepare a packaging material. After melting at a temperature of 170 ° C to 200 ° C in an extruder for vinyl production, the plastic packaging material is sized and pulled out in the form of an inflated bubble, and then rolled up in roll form.

Example 3

Preparation of antioxidant pigment compositions

In order to prepare the antioxidant pigment composition, 300 kg of shigid and 300 kg of low density polyethylen (LDPE) were mixed in a pigment maker, and the pigment was melted at a temperature of 180 ° C to 220 ° C, and then the pigment was cut .

Preparation of packaging material (when 15% by weight of antioxidant pigment composition is included)

To prepare the packaging material, 30 kg of the antioxidant pigment composition of Example 1 and 188 kg of high density polyethylene (HDPE) were mixed using a blender. After melting at a temperature of 170 ° C to 200 ° C in an extruder for vinyl production, the plastic packaging material is sized and pulled out in the form of an inflated bubble, and then rolled up in roll form.

Example 4

Preparation of antioxidant pigment compositions

In order to prepare the antioxidant pigment composition, 300 kg of shigid and 300 kg of low density polyethylen (LDPE) were mixed in a pigment maker, and the pigment was melted at a temperature of 180 ° C to 220 ° C, and then the pigment was cut .

Preparation of packaging material (when 20% by weight of antioxidant pigment composition is included)

40 kg of the antioxidant pigment composition of Example 1 and 188 kg of high density polyethylene (HDPE) were mixed using a blender to produce a packaging material. After melting at a temperature of 170 ° C to 200 ° C in an extruder for vinyl production, the plastic packaging material is sized and pulled out in the form of an inflated bubble, and then rolled up in roll form.

Using the packaging materials prepared in the above Comparative Examples and Examples 1 to 4, the freshness of the food was allowed to stand at 63 캜 for one week, and then the acid value and the peroxide value were measured using the stored almonds. The almonds were stored in the packaging materials prepared in Comparative Examples and Examples 1 to 4 and then subjected to an aptitude test in Esfood Guardian Co., Ltd. Based on the amount of reagent consumed according to the following method of measuring the acid value and peroxide value .

The test report was prepared by Esfood Guardian Co., Ltd. The results are shown in the following FIG. 2 to FIG. 6 and are summarized in Table 1 below.

Acid value Peroxide value (meq / kg) Comparative Example 1.90 6.00 Example 1 2.10 4.00 Example 2 2.00 4.00 Example 3 1.90 3.00 Example 4 1.90 1.00

The acid value is one of the measures to determine the quality of the fat, which means the mg of potassium hydroxide (KOH) required to neutralize the free fatty acids contained in 1 g of fat. It is preferable that the acid value of the edible oil is 1 or less.

At peroxide value, the oxidation of the fat begins from the production of peroxide, so the peroxide value, which indicates the amount of peroxide produced, is used as an indicator of the degree of oxidation of the fat. Since the peroxide is reduced by polymerization and decomposition at the same time as it is produced, the amount of peroxide actually measured as the peroxide value is not the total amount of peroxide produced, but the amount excluding the reduced amount due to polymerization and decomposition at the production amount. That is, do. In the early stage of oxidation of peroxides, the rate of peroxide is higher than the rate of decrease, so the peroxide value increases with the oxidation. However, when peroxides are accumulated due to oxidation, the peroxide peroxide value decreases because the rate of peroxide is higher than that of peroxide. Therefore, the peroxide value is high in the initial stage of oxidation of the oil. The principle of measurement of peroxide value is as follows. When potassium iodide (KI) is reacted with the fat, iodine (I) is liberated quantitatively from potassium iodide by peroxide. The iodine titration method, which titrates this with a standard solution of sodium thiosulfate in the presence of a starch indicator, is widely used because of its high reliability. The peroxide value is expressed in milliequivalents (meq / kg) of peroxide oxygen converted from the milliequivalent of iodine liberated per 1 kg of fat. By measuring the amount of peroxide generated by oxidation of the fat, Lt; RTI ID = 0.0 > efficacy. ≪ / RTI >

Referring to the results of Table 1, it can be seen that the acid value in Comparative Example 1 and Examples 1 to 4 is not less than 1, and that the acid value is not possible to be edible, and there is no significant difference in the acid value between Comparative Examples and Examples.

However, when comparing the peroxide value, it was found that the peroxide value was 6.00 in Comparative Example 1, but the peroxide value dropped from 4.00 to 1.00 in the packaging material containing the antioxidant pigment composition according to one aspect of the present invention. That is, when the antioxidant pigment composition of Example 1 contained 6 wt% of the antioxidant pigment composition and the antioxidant pigment composition of Example 2 contained 10 wt% of the antioxidant pigment composition of Example 2, the peroxide value was 4.00 It can be seen that the progress of the rancidity decreased by 33.3%. Compared with the comparative example, when the antioxidant pigment composition of Example 3 contained 15% by weight of the antioxidant pigment composition, the peroxide value fell to 3.00, indicating that the extent of rancidity was reduced by 50.0%. In Example 4 Compared with the comparative example, when the antioxidant pigment composition was contained in 20 wt% of the packaging material, the peroxide value fell to 1.00, indicating that the degree of rancidity was reduced by 83.3%.

Thus, when the antioxidant pigment composition according to one aspect of the present invention is included in the packaging material, it is possible to slow the progress of rancidity of foods and the like in the packaging material, to suppress the oxidation of the food to maintain the freshness of the food, It will increase.

In addition, the packaging material containing the antioxidant pigment composition according to one aspect of the present invention can be used not only as a food but also as a packaging material for steel products, thereby preventing oxidation of steel products and preventing corrosion. In the export of steel products, To increase exports and increase the national competitiveness of the steel industry.

The present invention also relates to an antioxidant pigment composition or a shungite of the present invention. The antioxidant pigment composition of the present invention can be used in various fields such as packaging for preventing oxidization in addition to foods and steel products, and packaging materials for flower, mulching for agricultural use, Is not limited to a film such as a vinyl film, but may be used in addition to plastic compositions and pulp (or paper).

While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is to be understood that the invention is not limited to the disclosed embodiments, but, on the contrary, It will be understood that various modifications and applications are possible. For example, each component specifically shown in the embodiments can be modified and implemented. It is to be understood that all changes and modifications that come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.

Claims (8)

An antioxidant pigment composition comprising shungite.
The method according to claim 1,
The antioxidant pigment composition according to claim 1, wherein the antioxidant pigment composition comprises a 1: 1 weight ratio of the low density polyethylene (LDPE).
The method according to claim 1,
The antioxidant pigment composition according to claim 1, wherein the antioxidant pigment composition comprises a polyglycolic acid (PP) and a polypropylene (PP) in a weight ratio of 1: 1.
The method according to claim 1,
The antioxidant pigment composition according to claim 1, wherein the antioxidant pigment composition comprises 1: 1 by weight of polyethylene terephthalate (PET).
A packaging material comprising an antioxidant pigment composition comprising shungite.
6. The method of claim 5,
Wherein the packaging material comprises 6 to 30% by weight of the antioxidant pigment composition and 94 to 70% by weight of high density polyethylene (HDPE).
6. The method of claim 5,
Wherein the packaging material comprises 6 to 30% by weight of the antioxidant pigment composition and 94 to 70% by weight of polypropylene (PP).
6. The method of claim 5,
Characterized in that the packaging material is for food, steel products or mulching.

KR1020150005998A 2015-01-13 2015-01-13 Antioxidant pigment composition and packing material comprising thereof KR20160087180A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20180060614A (en) * 2016-11-29 2018-06-07 영농조합법인 에코팩키징연구소 Method for manufacturing antibiotic vacuum compression plastic film for food-packaging applying micro C-60 and plastic film made by the method thereof
KR101968316B1 (en) * 2017-10-25 2019-04-22 주식회사 더네이처코리아 Medical container containing biodegradable polymer plastics
KR20200025239A (en) * 2018-08-29 2020-03-10 주식회사 삼보케미칼 Pet sheet having good maintenaance effect of multilaer food freshing and food tray product using thereof
KR102080274B1 (en) * 2018-08-27 2020-04-23 주식회사 삼보케미칼 Sheet having good maintenaance effect of multilaer food freshing and food tray product using thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20180060614A (en) * 2016-11-29 2018-06-07 영농조합법인 에코팩키징연구소 Method for manufacturing antibiotic vacuum compression plastic film for food-packaging applying micro C-60 and plastic film made by the method thereof
KR101968316B1 (en) * 2017-10-25 2019-04-22 주식회사 더네이처코리아 Medical container containing biodegradable polymer plastics
KR102080274B1 (en) * 2018-08-27 2020-04-23 주식회사 삼보케미칼 Sheet having good maintenaance effect of multilaer food freshing and food tray product using thereof
KR20200025239A (en) * 2018-08-29 2020-03-10 주식회사 삼보케미칼 Pet sheet having good maintenaance effect of multilaer food freshing and food tray product using thereof

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