KR20160067030A - Flat tubular ceramic membrane and the manufacturing method thereof - Google Patents

Flat tubular ceramic membrane and the manufacturing method thereof Download PDF

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Publication number
KR20160067030A
KR20160067030A KR1020150157660A KR20150157660A KR20160067030A KR 20160067030 A KR20160067030 A KR 20160067030A KR 1020150157660 A KR1020150157660 A KR 1020150157660A KR 20150157660 A KR20150157660 A KR 20150157660A KR 20160067030 A KR20160067030 A KR 20160067030A
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KR
South Korea
Prior art keywords
flat tubular
tubular ceramic
ceramic separator
wastewater
manufacturing
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Application number
KR1020150157660A
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Korean (ko)
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KR101801875B1 (en
Inventor
천승호
김명중
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주식회사 칸세라
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Publication of KR20160067030A publication Critical patent/KR20160067030A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D71/00Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02Inorganic material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D63/00Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/06Tubular membrane modules
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D63/00Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/06Tubular membrane modules
    • B01D63/061Manufacturing thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D63/00Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/08Flat membrane modules
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D63/00Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/08Flat membrane modules
    • B01D63/081Manufacturing thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D67/00Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0039Inorganic membrane manufacture
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/04Tubular membranes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/06Flat membranes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2325/00Details relating to properties of membranes
    • B01D2325/22Thermal or heat-resistance properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2325/00Details relating to properties of membranes
    • B01D2325/28Degradation or stability over time
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2325/00Details relating to properties of membranes
    • B01D2325/30Chemical resistance

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

Disclosed is a separation membrane for a wastewater treatment device having excellent wear resistance, chemical resistance and heat resistance. The ceramic separation membrane according to one embodiment of the present invention comprises: a main body formed by a ceramic; and a plurality of through holes which horizontally pass through the main body.

Description

Technical Field The present invention relates to a flat tubular ceramic membrane and a manufacturing method thereof,

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a waste water treatment technology, and more particularly, to a ceramic separation membrane and a method for producing the same.

In the past, the ecosystem was well maintained because human waste water and wastewater were purified by the midnight effect of nature. However, since environmental pollution is becoming serious due to population increase and industry development, researches on artificial treatment of waste water and wastewater are being actively carried out.

Among such wastewater treatment techniques, membrane separation technology capable of not only treating wastewater but also recovering and recycling effective substances contained in wastewater has been extensively studied. Membrane separation technology has many advantages in that it not only treats wastewater but also recycles and recycles the water in the wastewater with high yield, greatly reducing the load of the wastewater source.

In addition, the amount of chemicals entering the wastewater treatment is low, which can reduce the sludge that is generated, and the physical treatment of the wastewater is less likely to affect the water quality of wastewater. Since the entire system can be operated automatically, there is an advantage that the labor cost and the operating cost can be greatly reduced.

On the other hand, polymer membranes made of polymer materials such as PS, PES, PVDF have been mainly used as separation membranes for filtering out foreign substances. These membranes are widely used in general purification processes, seawater desalination processes, ultrapure water production processes, and sewage treatment processes.

However, in the treatment of livestock wastewater containing high concentrations of pollutants, which are several hundred to tens of thousands times more than those of domestic wastewater, existing membranes made of a polymer material due to the wide pH range, high temperature, high concentration and high viscosity characteristics of the samples, Chemical and heat resistance is weak, so that the replacement cycle is short. Therefore, development of a separation membrane suitable for extreme conditions is required.

The present invention is to provide a separation membrane for a wastewater treatment apparatus excellent in abrasion resistance, chemical resistance and heat resistance.

The flat tubular ceramic separator according to one aspect of the present invention includes a body formed of ceramics and a plurality of through holes horizontally penetrating the body.

According to another aspect of the present invention, the flat tubular ceramic separator may be formed by combining a plurality of pieces provided with a protrusion at one end and a groove corresponding to the protrusion at the other end.

According to another aspect of the present invention, there is provided a method of manufacturing a flat tubular ceramic separator including a main body formed of a ceramic and a plurality of through holes horizontally penetrating the main body, the method comprising the steps of: The method may include extruding and creating a plurality of pieces provided with additional parts and combining the plurality of pieces.

INDUSTRIAL APPLICABILITY According to the present invention, the abrasion resistance, chemical resistance, and heat resistance of the separation membrane become excellent, and the waste water and wastewater can be efficiently treated.

In addition, the pieces can be joined together to form a large ceramic membrane having a width of at least 0.5 m.

Figure 1 schematically illustrates a vortex generating concentrating system.
FIG. 2 is a diagram showing the operating principle of the vortex generating type enrichment system shown in FIG. 1; FIG.
FIG. 3 illustrates a separation module to which a flat tubular ceramic separator according to the present invention is applied.
4 is a cross-sectional view of the flat tubular ceramic separator of FIG. 3 taken along line AA.
5 is an enlarged fragment of the flat tubular ceramic separator of FIG.

Hereinafter, the present invention will be described in detail with reference to embodiments and drawings of the present invention. Here, the same reference numerals are used for the same components, and repeated descriptions and explanations of known configurations and techniques that may obscure the gist of the present invention are omitted. The shape and size of the components can be exaggerated.

Figure 1 schematically illustrates a vortex generative type enrichment system, and Figure 2 is a diagram illustrating the operational principle of the vortex generative enrichment system shown in Figure 1.

The flat tubular ceramic separator according to the present invention can be installed in a vortex generating type concentrating system. Accordingly, the vortex generating type enrichment system will be briefly described with reference to Figs.

The vortex generating type enrichment system shown in Figs. 1 and 2 comprises upper and lower separators 10, 30 and a vortex generator 20 for generating a vortex therebetween. When the wastewater is introduced into the concentration system, only a small amount of water passes through the separation membrane, and large-sized contaminants are trapped in the separation membrane. If the contaminants are accumulated in the separation membrane, water can not pass through the separation membrane. Therefore, the vortex generator 20 is fixed to the rotary shaft 40 and rotates to generate vortex to prevent contaminants from accumulating in the separation membranes 10 and 30 . The moisture that has passed through the separation membranes 10 and 30 is discharged to the outside through the inner holes 50a of the guide portion 50 disposed outside the separation membranes 10 and 30.

3 is a cross-sectional view of the flat tubular ceramic separator of FIG. 3 taken along line AA, FIG. 5 is a cross-sectional view of the flat tubular ceramic separator of FIG. 4, Which is an enlargement of the sculpture.

As shown in FIGS. 3 to 5, the flat tubular ceramic separator 10 includes a main body and a plurality of through holes 10a.

The body is formed of ceramic. The main body can be made by mixing raw materials such as alumina (Al 2 O 3), silicon and magnesium, adding water to the blend, kneading it, molding, sintering and processing it. Since the body is made of ceramic, the flat tubular ceramic separator 10 according to the present invention has excellent abrasion resistance, chemical resistance, and heat resistance. The body can be made in the shape of a circular plate.

The plurality of through holes 10a horizontally penetrate the main body. Thus, the flat tubular ceramic separator 10 according to the present invention has a flat tubular shape as the term "flat tubular" means. The through hole 10a may be formed in a circular or oval shape. The through holes 10a may be formed so as to communicate with each other inside the body. The moisture that has entered the inner through hole 10a of the main body through the surface portion of the separation membrane flows down to the outer periphery of the main body and falls down through the inner hole 50a of the guide portion 50 disposed at the outer periphery. Although not shown, the through hole 10a may be formed to be inclined downward from the inside to the outside. In this case, the moisture flows more easily to the outside of the body.

The flat tubular ceramic separator 10 made as described above is excellent in abrasion resistance, chemical resistance, and heat resistance, and is capable of treating waste water and wastewater stably.

On the other hand, the flat tubular ceramic separator 10 may be formed by combining a plurality of pieces provided with a protrusion at one end and a groove corresponding to the protrusion at the other end. In this case, the pieces may be extruded and then joined together to form a large ceramic. A large ceramic membrane having a width of 0.5 m or more can be produced. In this case, the cross-sectional area for treating wastewater is larger than that of the conventional separation membrane, which is effective.

A method for manufacturing the above-described flat tubular ceramic separator will be described.

First, a plurality of pieces provided with protrusions at one end and provided with grooves corresponding to the protrusions at the other end are extruded by an extrusion molding method, followed by drying and firing. Each piece consists of a through hole that horizontally penetrates the main body and the main body. Next, a plurality of pieces are combined. Since the pieces are formed by extrusion and then the pieces are combined with each other to form a flat tubular ceramic separator, a large ceramic separator having a width of 0.5 m or more can be produced.

While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is to be understood that the invention is not limited to the disclosed embodiments, but, on the contrary, is intended to cover various modifications and equivalent arrangements included within the spirit and scope of the appended claims. It will be possible. Accordingly, the true scope of protection of the present invention should be determined only by the appended claims.

10: separator 10a: through hole
20: vortex generator 30: membrane
40: rotation shaft 50: guide portion
50a: inner hole

Claims (4)

A body formed of ceramic;
A plurality of through holes horizontally penetrating the main body;
Wherein the ceramic separator is a flat tubular ceramic separator.
The method according to claim 1,
And a plurality of pieces having a protrusion at one end and a groove corresponding to the protrusion are coupled to the other end.
A method for manufacturing a flat tubular ceramic separator according to claim 1,
A step of extruding a plurality of pieces provided with protrusions at one end and provided with grooves corresponding to the protrusions at the other end;
Combining the plurality of pieces;
The method of manufacturing a flat tubular ceramic separator according to claim 1,
A wastewater treatment apparatus using the flat tubular ceramic separation membrane according to any one of claims 1 to 3.
KR1020150157660A 2014-12-03 2015-11-10 Flat tubular ceramic membrane and the manufacturing method thereof KR101801875B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020140172454 2014-12-03
KR20140172454 2014-12-03

Publications (2)

Publication Number Publication Date
KR20160067030A true KR20160067030A (en) 2016-06-13
KR101801875B1 KR101801875B1 (en) 2017-11-27

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106512751A (en) * 2016-12-01 2017-03-22 三达膜科技(厦门)有限公司 Preparation method of disc-type multi-channel plate ceramic membrane
CN109569309A (en) * 2018-12-13 2019-04-05 合肥信达膜科技有限公司 A kind of ceramic membrane production mixing extrusion equipment with choke preventing function
CN110282701A (en) * 2019-07-24 2019-09-27 杭州坚膜科技有限公司 Ceramic membrane, filter device and filtration system

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002094413A1 (en) * 2001-05-22 2002-11-28 Pall Corporation Advanced leaf disc filter segment
JP2004237173A (en) 2003-02-04 2004-08-26 Kansai Kanaami Kk Filter disk and leaf filter

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106512751A (en) * 2016-12-01 2017-03-22 三达膜科技(厦门)有限公司 Preparation method of disc-type multi-channel plate ceramic membrane
CN109569309A (en) * 2018-12-13 2019-04-05 合肥信达膜科技有限公司 A kind of ceramic membrane production mixing extrusion equipment with choke preventing function
CN110282701A (en) * 2019-07-24 2019-09-27 杭州坚膜科技有限公司 Ceramic membrane, filter device and filtration system

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