KR20160058399A - Developing sticky trap for preventing insects by using insect pheromone - Google Patents

Abstract

The present invention relates to an environment-friendly trap for attracting insects, the trap comprising: an attracting trap part in which a tricky agent is formed on a substrate; and a pheromone lure formed on the attracting trap part. The present invention has merits in that insecticidic components are not used to thereby be harmless to humans, environmental pollution can be minimized, and effects can be maintained for a long time without degrading attraction performance by means of insect pheromone, and thereby the price efficiency is relatively excellent.

Description

Development of sticky traps for insect control using pheromone {Developing sticky trap for insect pheromone}

The present invention relates to the development of sticky traps for insect control using pheromones.

In general, pests (such as flies, mosquitoes, moths, and stinks) are powerful mediators of the epidemic. These diseases include typhoid fever, paratyphoid salmonella, protozoal disease, tuberculosis, leprosy, parasites, bacterial dysentery, cholera, cerebrospinal saliva and salmonellosis, causing dirt, discomfort and sleep disturbances, have.

Unlike these insect pests, Thripworm is not a mediator of infectious diseases but it is known to be more than 6,000 subspecies in 8 subspecies and 700 subspecies in the world, and 2 subspecies, 30 genera and 50 species ('94 Korean Insect House) are known in Korea. have. The major thrips that cause damage to crops include Taiwan thripworm, thripworm, convex thripworm, tangerine thripworm, Akashi thornworm, and Hawaiian thripworm. However, since September 2003, The insect pests such as yellow thrips and cucumber thrips have begun to appear, and these insects are suffering the most damage now. Also, it is known as the greatest insect pests of the domesticated or unfermented adults with large amount of summer or autumn crops. The larvae crawl through the epidermis of leaves or branches before curing, making a silvery tunnel, and eating leaves to slow shoot growth. As a result, the damaged leaves are almost completely removed during winter.

One of the ways to effectively treat these infectious and non-infectious insects is with pesticides, which has the disadvantage of harmful effects on humans.

As a method to overcome the disadvantages described above, a physical trapping method (for example, sticky) is attracted by using characteristics of a highly developed insect pest and the adhesive force is widely used.

However, since the capturing method loses the capturing effect in a short period of time, the supporting member including the adhesive layer is treated together, resulting in cost increase and waste of resources.

In order to maximize the attracting effect, various kinds of insect attracting ingredients are used together. One of the components capable of attracting the pests is an insect pheromone of the insect pest and a compound containing the insect pheromone. Insect pheromones are highly species-specific and can be used to synthesize them to capture a large number of desired insect pests. It can also be attracted simply by varying compositional proportions of the insect pheromone components or components of the two species even in closely related closely related species. And the insect pheromone is very sensitive to sensitivity, so it can exert a great effect even in a trace amount. In addition, the insect pheromone material has little toxicity and is harmless to the human body, and there is little possibility of environmental pollution. Therefore, many studies using insect pheromone and its application have been made.

However, the insecticidal effect of the insect pheromone has been reported to be very large, but a lot of research is needed in terms of commercial aspects including price.

Particularly, the existing insect pheromone insect induction traps have disadvantages in that the insect persistence and the attracting effect efficiency are poor because the insect pheromone composition and the adhesive composition are dispersed and mixed and applied.

In addition, while the effect of the insecticidal pheromone composition may be further sustained, it is often the case that the insect trapped on the attractant trap region is not constant over time to saturation and is inconsistent with the duration of the insecticidal pheromone composition, (Due to overuse of relatively expensive insecticide pheromone composition).

Korean Patent Publication No. 10-2010-0013183

An object of the present invention is to provide an insect attracting trap which is harmless to the human body and can minimize environmental pollution.

Another object of the present invention is to provide an insect attracting trap capable of exhibiting a long-term effect.

It is still another object of the present invention to provide a method for insect pest control which minimizes insecurity, pollution, and the generation of odor caused by the property of capturing and leaving insects for a long period of time without affecting the rapid induction of insects by insect pheromone To provide an insect attractor trap.

The present invention relates to an environmentally friendly insect attracting trap capable of improving cost efficiency even while improving incentive sustainability and attractiveness effect efficiency. To this end, the eco-friendly insect-attracting trap of the present invention has a structure in which the entrapment trap portion consumed periodically can be exchanged because the insect pheromone composition is housed in the porous capsule and is detachably coupled to the attracting trap portion.

In the case of insect attracting traps using existing insect pheromone, the insect trapping area is trapped in the trap area and the time to reach the saturation state and the duration of the insect pheromone composition are unstable, so that the insect pheromone composition using the relatively expensive insect pheromone composition This is to solve the problem that can not be done.

Further, the present invention has disadvantages in that insecticidal pheromone composition and adhesive composition are dispersed and mixed and applied in the case of conventional insect pheromone insect attracting traps, resulting in poor incentive sustainability and attractiveness effect efficiency. This is because the insect pheromone can be dissolved or dispersed in the course of dispersing and mixing the insecticidal pheromone composition and the adhesive composition or in the course of application, Method.

Further, the environmentally friendly insect-attracting trap of the present invention can have an antibacterial property to adsorb bacteria, and a deodorizing effect to adsorb surrounding odor particles by adding a functional substance. This is because the insects are physically trapped and left to stand for a long time, thereby minimizing pollution, pollution, and odor due to the pollution, so that they can be arranged and applied in a more various places or spaces.

Hereinafter, the present invention will be described in detail.

The present invention relates to a method for producing an insecticidal pheromone composition comprising an attractant trap 102 having a sticky composition formed on a substrate and a pheromone lure 103 formed on the human trap 102, Which is an environmental insect attracting trap. Specifically, a system in which an insect is attracted to an attracting trap portion on which a sticking composition is formed on a substrate and is captured, and a system for inducing an insect by a pheromone lure formed on the attracting trap portion (specifically, formed on a substrate of an attracting trap portion) to be. The pheromone lure is a device containing a volatile aromatic material including an insect pheromone component which can be used for a long time, and has a structure capable of attaching and detaching a substrate on which a pressure-sensitive adhesive consumed in a relatively short period of time is formed. Therefore, it is possible to capture insects for a long period of time only by detaching and attaching the consumed base material, and the cost efficiency is extremely excellent. In addition, there is an advantage that it is harmless to the human body and is environment-friendly because it does not use a pesticide ingredient. (The meaning of the consumed material is that the insect is physically captured from the adhesive layer of the base material and consumption of the adhesive component over time, Refers to a substrate with reduced captivity due to the consumption of the adhesive space by the substrate or a missing substrate.)

In one example of the present invention, in addition to the insect pheromone component, it may further include an attractant component capable of attracting insects. The attractant can be used, for example, in a sticking composition or mixed with an insect pheromone component. A purified compound or an environmentally friendly substance can be exemplified, and in the case of a purified compound, an environmentally friendly compound harmless to the human body is not greatly limited. For example, an additive or a compound obtained by refining sugar can be exemplified.

In one embodiment of the present invention, the manhunt trap portion 102 may further include a release film covering the adhesive composition. Generally, the release film serves to protect the adhesive composition formed on the base material of the artificial trap portion, and serves to prevent deterioration or deformation of the adhesive property with time of the adhesive agent until use. Usually, the release film preferably has a size smaller than that of the substrate so as to cover all of the adhesive composition formed on the substrate of the attracted trap portion. In general, the release film has a structure that can be separated from the adhesive surface immediately before use, and a coating layer capable of imparting peelability and adhesion to the surface of the release film in contact with the adhesive surface can be formed. A polyester based film; A coating composition comprising a silicone-based binder resin and a conductive polymer on one side thereof; And a coating layer prepared by applying the coating layer. However, the present invention is not limited thereto and can be easily applied and applied in the art, so that detailed description will be omitted.

In one embodiment of the present invention, the base material may include an artistic trap region 101 formed with a pressure-sensitive adhesive composition, and a blank region in which the adhesive composition is not formed, and may include a hole penetrating a portion of the blank region have. In general, the blank region is preferably the end portion of the substrate surface, and the lead-in trap portion region may mean the remaining portion of the blank region. And an adhesive composition may be applied to the lead trap section area. Although the size of the area of the lead trapping area is not limited, it is preferably about 60 to 95% of the area of the lead trapping area.

In one embodiment of the present invention, the pheromone lure may be a structure that is coupled by a fixation device. The fixing device serves to couple the manhole trap part and the pheromone lure, and the manhole trap part and the pheromone lure are detachable from the fixing device. Therefore, the spent human traps can be separated and a new human traps can be attached and used. Conversely, the spent pheromone lures can be separated and used with new pheromone lures attached. Further, the fixing device may be formed at any position of the base material, but preferably the base end portion or the end intermediate portion may be exemplified. For example, the fixing device may be a ring, a hooking slot device, an adhesive, or the like. The fastening device may have a role of coupling the hand traps and the fastening device, and a function of fixing the fastening device to a wall or the like. At least one of the fixing devices may be formed on one side of the substrate, and the fixing device may include a space penetrating or non-penetrating at a predetermined position of the substrate, preferably at a predetermined distance from the distal side. However, the present invention is not limited thereto, and is not limited as long as it can be fixed to a wall. The hooking device, the penetrating space, and the non-penetrating space may be hung on a hook member formed of a nylon cord, a wire, a ring, or the like.

In one embodiment of the present invention, the pheromone lure 103 includes a ring 105, and the ring 105 may be connected to the perforated hole. The ring may be a perforated hole, for example a hooking slot device.

In one embodiment of the present invention, the pheromone lure may be formed at a portion of the blank region. The ring may illustrate the structure of a common key ring that may be connected to a perforated hole.

In one embodiment of the present invention, the pheromone lure 103 is in the form of a porous capsule, and the insect pheremone composition may be contained in the porous capsule. The form of the pheromone lure is not particularly limited but may be a structure having a capsule type structure including one or two or more pores so that the pheromone component is well volatilized. . In addition, the pheromone lure may have an open / close structure to open the inner space. The pheromone lures have a configuration that can be coupled to the anchoring device and can be joined by, for example, a ring, a strap, and an adhesive. Preferably, the pheromone lure is bonded to the ring, and in this case, a perforated pore structure capable of binding to the ring can be formed in the pheromone lure.

In one embodiment of the present invention, the manhunt trap portion 102 may further include an insecticidal pheromone composition. This is advantageous not only in attracting by the insect pheromone lure but also an effect of being directly attracted from the surface on which the adhesive composition layer is formed, so that the attraction effect can be further improved. The method for forming the insecticidal pheromone composition is generally various, but a preferable form may be a method for applying the insecticidal pheromone composition.

Also, one composition selected from the insecticidal pheromone composition and the adhesive composition may be applied on the substrate, and the other composition may be formed in a lattice structure on the formed composition. In detail, one composition selected from an insecticidal pheromone composition and a sticky composition can be applied and formed on a substrate using, for example, a spray coating method, and the remaining one composition is applied on the coated composition in a lattice structure to form . The lattice spacing of the insecticidal pheromone composition or the adhesive composition may be, for example, 100 占 퐉 to 10 mm. The method of forming the insecticidal pheromone composition or the adhesive composition into a lattice structure can be carried out by placing a patch with a lattice structure (for example, a lattice pattern in a checkerboard form) and then applying the applied composition onto the insect pheromone composition and the frame An insecticidal pheromone composition or a sticking composition in the form of a lattice structure can be formed. This makes it possible to improve the directionality of the insect pheromone and the adhesive force of the adhesive composition more effectively, thereby increasing the capturing effect.

In one embodiment of the present invention, the manhunt trap portion 102 may include a color that emits a specific wavelength having an insect attracting effect. For example, white, yellow, yellow and blue colors may be exemplified, and they may be used in combination. In the case of the attracting trap portion, generally, the color of the substrate of the attracting portion can be used in a manner such as printing or printing.

In one embodiment of the present invention, the adhesive composition is selected from styrene-isoprene-styrene block copolymer, hydrocarbon resin, paraffin oil, polybutene, Phenolic antioxidants, cyclohexane, hydrocarbon resin and isohexane And may include one or more components. In addition, it may further include graftone, hydrogenated resin, h resin, petroleum resin, sis resin and polyisobutylene. However, the present invention is not limited thereto, and it is not limited as long as it is a component or a compound capable of capturing an insect by physical adhesion.

In one embodiment of the present invention, the insecticidal pheromone composition comprises (Z) -9-tricosene ((Z) -9-Tricosene), (5R, 6S) -6-acetoxy-5-hexadecanoide (R) -Lavandulylacetate (2-Isopropenyl-5-methyl-4-hexen-1-yl acetate), Neryl (S Heptadecane, (7Z, 11Z, 13E) -hexadecatrienal ((7Z, 11Z, 13E) -Hexadecatrienal), N-methylbutanoate (7Z, 11Z) -Hexadecadienal), methyl (2E, 4E, 6Z) -decatrienoate (Methyl (2E, 4E, 6Z) , 4Z) -decadienoate (Methyl (2E, 4Z) -Decadienoate). Such insecticidal pheromone compositions are particularly effective in attracting flies, mosquitoes, thrips, moths, and mosses. However, the present invention is not limited to the above-mentioned insect pheromone component, and the insect pheromone component capable of attracting other insects can be appropriately adjusted according to the purpose and use.

In one embodiment of the present invention, the insecticidal pheromone composition comprises 50 to 150 parts by weight of (5R, 6S) -6-acetoxy-5-hexadecanolide with respect to 100 parts by weight of (Z) (7Z, 11Z, 13E) -hexadecatriene in an amount of 15 to 90 parts by weight, preferably 5 to 30 parts by weight, of N, N-dimethylformamide (R) 5 to 50 parts by weight of methyl (2E, 4E, 6Z) -decatrienoate and 15 to 60 parts by weight of methyl (2E, 4Z) - hexadecadienes, And decadienoate in an amount of 5 to 50 parts by weight. Insect pheromones are not only targeted to a specific insect but can be broadly targeted depending on the identity of the system, gate, river, tree, fruit, genus or species. Therefore, if the content of the insect pheromone is adjusted in the above-described range, the range and the degree of capture of the target target constituent group can be improved.

In one embodiment of the present invention, the insecticidal pheromone composition and the adhesive composition may further include one or more components independently selected from activated carbon powder, silica gel, and zeolite. The component can impart porosity to the insecticidal pheromone composition, the adhesive composition or the insecticidal pheromone adhesive layer containing it, thereby controlling the directional effect and persistence of the insecticidal pheromone. Therefore, insects can be trapped more effectively. In addition, a physical impact is applied to the insect pheromone composition, the adhesive composition and the insecticidal pheromone adhesive layer containing the entrapment trap portion or the release film while removing the entrainment trap portion or the release film. Such a physical impact can further activate the directional effect.

In one embodiment of the present invention, the sizes of the activated carbon powder, silica gel or zeolite particles may independently be 100 nm to 100 μm. Preferably 200 nm to 10 占 퐉, and more preferably 500 nm to 1 占 퐉. If the particle size is too large, it may be difficult to form an insect pheromone adhesive layer using the spray coating method and the persistence may be reduced. Therefore, the attractiveness effect does not increase significantly, but the sustainability decreases remarkably, and the capture efficiency can be reduced. If the particle size is too small, the persistence may increase significantly, but the attraction efficiency may be significantly reduced and the capture efficiency may also be reduced.

In one embodiment of the present invention, the preparation of the silica gel and the method for preparing the insecticidal pheromone composition including the silica gel is a known method. The sodium silicate solution is precipitated in the gel form by adding an acid (usually sulfuric acid) Silica gel can be produced. Further, the method for preparing silica gel, activated carbon and zeolite by mixing and dispersing the insecticidal pheromone composition and the adhesive composition is well known in the art, so that further explanation is omitted.

In one embodiment of the present invention, the adhesive composition may be formed on the substrate and formed, and the insecticidal pheromone composition may be applied on the adhesive composition. Such a method is well known in the art, so that further explanation is omitted.

In one embodiment of the present invention, the insecticidal pheromone composition and the adhesive composition may further include one or more components independently selected from germanium powder, elvan powder, biotite powder, flesh powder, and ceftin earth powder .

The germanium powder, the elvan powder, the biotite powder, the biocide powder and the heavenly earth powder are functional materials, which have an effect of releasing anion and far-infrared rays, particularly, antibacterial properties for adsorbing bacteria and deodorizing effect for adsorbing odor particles And has excellent characteristics. These effects can be minimized in an unclean environment, pollution, and odor caused by insects being physically trapped and left to stand for a long time, so that they can be arranged and applied in more places or spaces.

Particularly noteworthy here is that very small insect pheromones are highly effective in attracting insects. Therefore, the insect pheromone can be maintained for a long time due to the action of adsorbing the odor particles as described above. Even if the insect pheromone is adsorbed and maintained, a small amount of insect pheromone continuously volatilizes over time, resulting in a more persistent entrapment effect.

In one embodiment of the present invention, the insecticidal pheromone composition and the adhesive composition are independently selected from one or two selected from an antioxidant, a light stabilizer, a lubricant, a dispersant, a pigment, a flavor, a viscosity regulator, a surfactant, an organic solvent and a compatibilizer Or more. Such additives may be, for example, dispersants, lubricants and surfactants for stabilizing the dispersion and for the compatibility of the emulsion resin with an inorganic compound or the like. Examples of such additives include Disperbyk-190 (BYK), Orotan-1850E (DOW) and the like, and Surfynol 104 (Airproduct) under the trade name of surfactants. In the case of antioxidants, 2,6-di-t-butyl-p-cresol, butylated hydroxyanisole, 2,6- Di-t-butyl-4-hydroxyphenyl) propionate, 2,2'-methylene-bis- (4- Butylphenol), 4,4'-thiobis (3-methyl-6-t-butylphenol), 4,4'- (3-t-butyl-4-hydroxy-5-methylphenyl) propionyloxy] ethyl], 2,4,8,10- Tetraoxaspiro [5,5] undecane, 1,1,3-tris (2-methyl-4-hydroxy-5-t-butylphenyl) butane, 1,3,5-trimethyl- (3 ', 5'-di-t-butyl-4'-hydroxyphenyl) ) Propionate] methane, 1,3,5-tris (3 ', 5'-di-t-butyl-4'-hydroxybenzyl) , 5H) trion and tocopherol. Examples of the light stabilizer include phenyl salicylate, butylphenyl salicylate, octyl phenyl salicylate, 2- (2'-hydroxy-5 ' -Methylphenyl) benzotriazole, 2- (2'-hydroxy-3-5'-butylphenyl) hydroxymethylphenylbenzotriazole And 2- (2'-hydroxy-3'-t-butylmethylphenyl) benzotriazole. In the case of an organic solvent, it is usually used very well and is well known, so that it is not limited. However, hexane is generally used in the art in general. However, the present invention is not limited thereto, and the above additives and other additives may be easily used in the art.

In one embodiment of the present invention, the insecticidal pheromone composition, the adhesive composition and the insecticidal pheromone adhesive layer containing the same are formed by knife coating, reverse roll coating, roll coating Coating, extrusion coating, cast coating, dip coating, spray coating, air-knife coating, air knife coating, calender coating, curtain coating, knife coating, foam coating and the like, and spray coating may be preferably exemplified. Further, since this is usually easily and suitably processable in the art, further explanation is omitted.

In one example of the present invention, the insecticidal pheromone composition can be prepared by the following method. In the present invention, the formulation may be a gel, a solid or a liquid, preferably a solid or a gel. At this time, as a water-soluble polymer used as a gelling agent in the gel phase formulation, there are natural water-soluble polymer and synthetic water-soluble polymer. The kind of the water-soluble polymer is not particularly limited, and examples thereof include cotton, agar, alginic acid, starch, guar gum, carrageenan, gelatin, gellan gum and locust bean gum. Examples of the synthetic water-soluble polymer include sodium carboxymethyl cellulose, carbomer, polyvinyl alcohol, cellulose derivatives, polymethacrylic acid, and polyvinyl pyrrolidone. Solid formulations may illustrate methods of absorbing or supporting the insecticidal pheromone composition on a rubber septa. Preferably, the formulation is a solid formulation, and the rubber septa can be used in a pheromone lure or fixed.

In one embodiment of the present invention, the insecticidal pheromone composition may be absorbed or supported on a rubber septa and loaded or immobilized in a pheromone lure.

In one embodiment of the present invention, the substrate, the attractant trap, the fixture, and the pheromone lure can independently have a constant shape and include, for example, rectangular, triangular, rhombic, circular, polygonal, But not limited to, polygonal, polygonal, non-polygonal, polygonal, polygonal, polygonal, polygonal, It is possible to exemplify a rectangular plate shape, which is advantageous in handling and manufacturing processes. However, the present invention is not limited thereto, and the shape can be appropriately modified depending on the purpose, purpose and characteristics.

In one embodiment of the present invention, the substrate, the manhole trap, the fixing device, and the material of the pheromone lure can be independently applied to paper, wood, metals, nonmetals and various resins, . Examples of the resin include polyethylenes, polypropylenes, polyamides, polyacetals, saturated polyesters, fluorine resins, and vinyl chloride resins. resin, polystyrene, methacrylic resin, polycarbonate, polyphenylene oxide, polysulfone, polyphenylene sulfide, methylpentene resin, and the like. polybutylene terephthalate, pentene resin, polyethylene terephthalate, polycarbonate, nylon, polyurethane, general polystyrene (GPPS), high strength polystyrene (HIPS), acrylonitrile butadiene styrene - one or two selected from acrylonitrile (SAN), polyvinyl chloride (PVC), mixtures thereof and copolymers thereof Can be exemplified. However, it is not limited thereto. And can be appropriately selected and used according to the requirements of the object and characteristics.

In one embodiment of the present invention, the manhole trap portion may include a grid pattern. Specifically, a grid pattern may be formed on the base material of the lead-in trap portion, and preferably, longitudinal and longitudinal lines may be repeatedly spaced apart from each other on the base surface in the direction in which the adhesive is formed. The grid pattern has a role of being able to grasp how much trapped insects are captured and to confirm or measure them. In general, the process can be performed using a method such as printing before the adhesive composition is formed on the substrate.

The arrangement space of the environmentally friendly insect-attracting trap of the present invention may be a vertical structure such as a wall; Close to vertical structure; Or structures connected by strings and wires; Lt; / RTI > However, the present invention is not limited to this, and it is possible to arrange suitable places according to the use environment and the amount of insects.

The environmentally friendly insect attracting trap using the insect pheromone of the present invention is harmless to the human body and has an advantage of minimizing environmental pollution.

Further, the eco-friendly insect attracting trap using the insect pheromone of the present invention is capable of exhibiting a long-term effect and providing an insect attracting trap which is relatively excellent in cost efficiency.

In addition, the environmentally friendly insect attracting trap using the insect pheromone of the present invention has a little effect on the rapid attraction of insects, and the insects are physically trapped and left for a long time, Can be minimized and can be arranged and applied to more various places or spaces.

1 is a view showing an environmentally friendly insect attracting trap according to an embodiment of the present invention.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Reference will now be made in detail to the embodiments of the present invention, examples of which are illustrated in the accompanying drawings. The following drawings are provided by way of example so that those skilled in the art can fully understand the spirit of the present invention. Therefore, the present invention is not limited to the following drawings, but may be embodied in other forms, and the drawings presented below may be exaggerated in order to clarify the spirit of the present invention. Hereinafter, the technical and scientific terms used herein will be understood by those skilled in the art without departing from the scope of the present invention. Descriptions of known functions and configurations that may be unnecessarily blurred are omitted.

In addition, the insects referred to in the present specification do not mean insects having anatomical significance but may mean populations including pests, insects, and the like.

(Production Example 1)

10 g of (Z) -9-tricosene, 1 g of butylated hydroxyanisole and 1 g of phenyl salicylate were mixed in 1 L of hexane, and the mixture was stirred for 10 minutes at a rate of 200 rpm for 10 minutes at room temperature Followed by stirring to prepare an insect pheromone composition.

3 kg of hydrocarbons resin, 0.1 kg of paraffin oil, 1.3 kg of polybutene, 70 g of phenolic antioxidants, and 2 kg of cyclohexane were put into a stirrer, followed by aging in which the mixture was aged at room temperature for 60 minutes. Followed by a primary stirring step of stirring at a speed of 50 rpm for 2 hours, a secondary stirring step of further adding 1,5 kg of a styrene-isoprene-styrene block copolymer and stirring at a speed of 40 rpm for 4 hours, 2 kg was further added and the mixture was stirred for 30 minutes at a speed of 50 rpm to obtain a mixture obtained through a third stirring step. In order to further supplement 2 kg of volatile isohexane and 2 kg of cyclohexane, a pressure-sensitive adhesive composition was prepared by supplementing with 0.2 kg of isohexane, which is 10% by weight of the input weight%, and 0.2 kg of cyclohexane .

(Production Example 2)

Insecticidal pheromone composition was prepared in the same manner as in Preparation Example 1, except that 10 g of (5R, 6S) -6-acetoxy-5-hexadecanolide was used instead of 10 g of (Z) -9-tricosene.

An insecticidal pheromone adhesive composition was prepared in the same manner as in Preparation Example 1, except that the insecticidal pheromone composition was used in place of the insecticidal pheromone composition of Production Example 1.

(Production Example 3)

An insecticidal pheromone composition was prepared in the same manner as in Preparation Example 1, except that 10 g of heptadecane was used instead of 10 g of (Z) -9-tricosene.

An insecticidal pheromone adhesive composition was prepared in the same manner as in Preparation Example 1, except that the insecticidal pheromone composition was used in place of the insecticidal pheromone composition of Production Example 1.

(Production Example 4)

An insecticidal pheromone composition was prepared in the same manner as in Preparation Example 1, except that 10 g of (5R, 6S) -6-acetoxy-5-hexadecanoide was further added to hexane.

An insecticidal pheromone adhesive composition was prepared in the same manner as in Preparation Example 1, except that the insecticidal pheromone composition was used in place of the insecticidal pheromone composition of Production Example 1.

(Production Example 5)

Except that 30 g of (R) -labenduryl acetate and 10 g of Neryl (S) -2-methylbutanoate were added in place of 10 g of (Z) -9-tricosene .

An insecticidal pheromone adhesive composition was prepared in the same manner as in Preparation Example 1, except that the insecticidal pheromone composition was used in place of the insecticidal pheromone composition of Production Example 1.

(Production Example 6)

Except that 10 g of (7Z, 11Z, 13E) -hexadecatrienal and 30 g of (7Z, 11Z) -hexadecadienal were added instead of 10 g of (Z) -9- An insect pheromone composition was prepared in the same manner.

An insecticidal pheromone adhesive composition was prepared in the same manner as in Preparation Example 1, except that the insecticidal pheromone composition was used in place of the insecticidal pheromone composition of Production Example 1.

(Production Example 7)

Except that 10 g of methyl (2E, 4E, 6Z) -decatrienoate and 10 g of methyl (2E, 4Z) -decadienoate were added in place of 10 g of (Z) 1, insecticidal pheromone composition was prepared.

An insecticidal pheromone adhesive composition was prepared in the same manner as in Preparation Example 1, except that the insecticidal pheromone composition was used in place of the insecticidal pheromone composition of Production Example 1.

(Preparation Example 8)

10 g of (5R, 6S) -6-acetoxy-5-hexadecanolide, 30 g of (R) -ribenzyl acetate, 10 g of Neryl 10 g of methyl (2E, 4E, 6Z) -decatrienoate and 10 g of methyl (2E, 4Z, 13E) -hexadecatrienal, ) -Decadienoate (30 g) was further added to hexane to prepare an insecticidal pheromone composition.

An insecticidal pheromone adhesive composition was prepared in the same manner as in Preparation Example 1, except that the insecticidal pheromone composition was used in place of the insecticidal pheromone composition of Production Example 1.

(Preparation Example 9)

10 g of the insecticidal pheromone composition of Preparation Example 1 was deposited on 100 g of silica gel (pH 6.0) to prepare an insecticidal pheromone composition deposited with silica gel.

An insecticidal pheromone adhesive composition was prepared in the same manner as in Preparation Example 1, except that the insecticidal pheromone composition deposited with silica gel was used in place of the insecticidal pheromone composition of Production Example 1.

(Preparation Example 10)

10 g of germanium powder having a particle size of less than about 0.5 탆, 10 g of elvan powder, 5 g of biotite powder, 5 g of granite powder and 5 g of ground powder were further added to an agitator before the aging step to mix , An insecticidal pheromone sticking composition was prepared in the same manner as in Production Example 8.

(Example 1)

The adhesive composition according to Preparation Example 1 was applied to a polyethylene resin substrate surface of a plate type having a width of 15 cm and a length of 20 cm by spray coating method to prepare an adhesive trapping portion having a pressure sensitive adhesive layer. . The insecticidal pheromone composition according to Preparation Example 1 was absorbed in rubber septa (604040-10; J.G. Finneran) and carried on a pheromone lure in the form of a porous capsule to prepare a parlor monorail.

A hole having a diameter of about 3 cm is formed in the upper part of the blank space in which the adhesive layer of the handy trap part is not formed, more specifically, the upper part of the blank space, and the pheromone lure is connected and bonded (fixed) The manned trap was prepared.

(Example 2)

An environmentally friendly insect attracting trap was prepared in the same manner as in Example 1, except that the insecticidal pheromone composition according to Preparation Example 2 was used instead of Preparation Example 1.

(Example 3)

An environmentally friendly insect attracting trap was prepared in the same manner as in Example 1, except that the insecticidal pheromone composition according to Preparation Example 3 was used instead of Preparation Example 1.

(Example 4)

An eco-friendly insect trap was prepared in the same manner as in Example 1, except that the insecticidal pheromone composition according to Preparation Example 4 was used instead of Preparation Example 1.

(Example 5)

An environmentally friendly insect attracting trap was prepared in the same manner as in Example 1, except that the insecticidal pheromone composition according to Preparation Example 5 was used instead of Preparation Example 1.

(Example 6)

An environmentally friendly insect attractant trap was prepared in the same manner as in Example 1, except that the insecticidal pheromone composition according to Preparation Example 6 was used instead of Preparation Example 1.

(Example 7)

An environmentally friendly insect attracting trap was prepared in the same manner as in Example 1, except that the insecticidal pheromone composition according to Preparation Example 7 was used instead of Preparation Example 1.

(Example 8)

An environmentally friendly insect attractant trap was prepared in the same manner as in Example 1, except that the insecticidal pheromone composition according to Preparation Example 8 was used instead of Preparation Example 1.

(Example 9)

An environmentally friendly insect attracting trap was prepared in the same manner as in Example 1, except that the insecticidal pheromone composition according to Production Example 9 was used instead of Preparation Example 1.

(Example 10)

Environmentally friendly insect attracting traps were prepared in the same manner as in Example 1 except that the insecticidal pheromone composition according to Preparation Example 10 was used instead of Preparation Example 1.

(Example 11)

The pressure-sensitive adhesive composition according to Preparation Example 10 was applied on a plate-shaped polyethylene resin substrate having a width of 15 cm and a width of 20 cm using an injection coating method, and then the above insecticide composition was applied to the above- The compositions were applied in the form of a lattice structure at intervals of about 1 mm. Specifically, a patch was placed on a grid-like grid in the form of a checkerboard on top of the adhesive composition applied on the substrate, and the insect pheromone composition was applied to the frame to form a layer in a lattice structure form to prepare an attracting trap.

An environmentally friendly insect attracting trap was prepared in the same manner as in Example 1, except that the above-mentioned attracting trap portion was used in place of the attracting trap portion of Example 1.

(Comparative Example 1)

An insect attractant trap was prepared according to a conventional method by using a pressure-sensitive adhesive composition containing no insect pheromone instead of the insecticidal pheromone adhesive composition according to Preparation Example 1.

Table 1 below shows the results of capturing degree and persistence stability characteristics with time of insect pheromone adhesive layer according to Examples 1 to 11 and Comparative Example 1. In the experiment, 10 eco-friendly insect traps according to Examples 1 to 11 and Comparative Example 1 were kept at room temperature without direct sunlight for 1, 15, 30, 45 and 60 days, Total 5 experiments were performed. Values for this were normalized to natural numbers from 1 to 5.

Table 2 shows antibacterial and deodorization rates according to Examples 1, 4, and 8 to 11 according to presence or absence of functional materials including germanium powder, elvan powder, biotite powder, As shown in FIG. The antimicrobial activity was measured according to the method of KS J 4206, and Staphylococcus aureus ATCC 6538 and Pseudomonas aeruginosa ATCC 27853 were used as experimental strains. The substrates according to Examples 1, 4 and 8 to 11 were cut into 100 X 10 X 15 mm, placed in a medium together with the test strain, cultured at 30 (占 1.5) 占 폚 for 24 hours, and then the number of bacteria was measured. Deodorization rate was measured according to KFIA-FI-1004, and the deodorization rate was measured by injecting 500 ppm of ammonia gas into the sample container. (Less than 10% was marked with - in view of the deviation from the error.) The degree of odor was measured by a sensory test using the 5-point method (5-very weak, 4-weak, 3-normal, 2-severe and 1-severe). The experiment was carried out five times in total by using the environmentally friendly insect induction traps according to Examples 1, 4 and 8 to 11. Ten environmental-friendly insect-attracting traps were left for 30 days at room temperature without direct sunlight to conduct insecticidal tests on insects trapped.

Characteristics of Insect Pheromone Adhesive Layer

It was confirmed that the trapping effect by the insecticidal pheromone composition according to the composition or the composition ratio in Examples 8 to 11 was further improved in the environmentally friendly insect attracting trap comprising the insecticidal pheromone composition of the present invention.

In particular, when the insecticidal pheromone composition was applied in the form of a capsule by gelation, the stability was further improved.

However, the insect attracting trap of Comparative Example 1 which does not contain the insect pheromone component has a relatively low insect trapping effect.

Characteristics according to presence or absence of functional material

Based on the results shown in Table 1, it was confirmed that the insect pheromone composition volatilizes and attracts insects. In the case of Example 9, it is confirmed that porosity of the insect pheromone is improved due to silica gel. These results suggest that the volatilization of insect pheromone components is generally due to the proper porosity, and the volatilization of insect pheromone components decreases with time. In addition, deterioration of the insect pheromone attracting effect due to the adsorption effect due to the porous structure was not confirmed.

In Examples 10 and 11, germanium powder, elvan powder, and tourmaline powder. It was directly or indirectly confirmed that the antimicrobial effect and the deodorizing effect by the functional materials such as the biotite powder, the bentonite powder and the heavenly earth powder were activated. As can be seen from the results of Table 1, in Examples 10 and 11 including the functional substance causing deodorizing effect, insecticidal pheromone induction due to adsorption and adverse effect of capturing effect were not observed , It was possible to minimize the occurrence of odor due to the deodorizing effect. This may be due to the fact that insect pheromone is extremely effective in inducing insects. Therefore, it was found through experiments that the effect of insect pheromone on the insect attracting effect was not affected even though it had an action of adsorbing odor particles. In addition, even if the insect pheromone is adsorbed and maintained, a small amount of insect pheromone is continuously volatilized with time, and as a result, it is confirmed that the insect pheromone has a more continuous insect capturing effect.

Accordingly, the eco-friendly insect-attracting trap of the present invention is a structure in which a porous capsule containing an insecticidal pheromone composition is detachably coupled to an attracting trap portion, thereby enabling replacement of a periodically consumed attracting trap portion, thereby improving attractiveness and attracting effect efficiency , And the cost efficiency can be improved.

Further, unlike the insect-attracted traps applied and dispersed and mixed with the conventional insecticidal pheromone composition and adhesive composition, the insect pheromone may be degraded or not properly dispersed in the process of dispersing, mixing or applying the insect pheromone. And is suitably applied and applied so as to solve the problem of the process in which the directionality is reduced or decreased.

While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is to be understood that the invention is not limited to the disclosed embodiments, but, on the contrary, Those skilled in the art will recognize that many modifications and variations are possible in light of the above teachings.

It is to be understood that both the foregoing general description and the following detailed description are exemplary and explanatory and are intended to provide further explanation of the invention as claimed.

101: Human Trap Area
102:
103: Pheromone lure
104: Fixing device
105: Ring

Claims (14)

1. An environmentally friendly insect-attracting trap comprising an attracting trap portion having a pressure-sensitive adhesive composition formed on a substrate and a pheromone lure formed on the human trap portion, wherein the pheromone lure contains an insect pheromone composition. The method according to claim 1,
Wherein the attraction trap portion further comprises a release film covering the adhesive composition. The method according to claim 1,
Wherein the base material comprises a hollow trap area formed with a pressure-sensitive adhesive composition and a blank area in which no pressure-sensitive adhesive is formed, and includes a hole penetrating a part of the blank area. The method of claim 3,
Wherein said pheromone lure comprises a ring, said ring being connected to said perforated hole. The method of claim 3,
Wherein the pheromone lure is formed at a portion of the margin region. The method according to claim 1,
Wherein the pheromone lure is in the form of a porous capsule, and the insect pheromone composition is contained inside the porous capsule. The method according to claim 1,
Wherein the manhole trap further comprises an insecticidal pheromone composition. 8. The method of claim 7,
Wherein one composition selected from the insecticidal pheromone composition and the adhesive composition is applied and formed on the substrate and the remaining one composition is formed in a lattice structure on the formed composition. The method according to claim 1,
Wherein the manhole trap includes a color that emits a specific wavelength with an insect attractant effect. The method according to claim 1,
Wherein said adhesive composition comprises one or more components selected from styrene-isoprene-styrene block copolymer, hydrocarbon resin, paraffin oil, polybutene, antioxidant, cyclohexane, hydrocarbon resin and isohexane traps. The method according to claim 1,
The insecticidal pheromone composition comprises (Z) -9-tricosene, (5R, 6S) -6-acetoxy-5-hexadecanolide, (R) -ribenzyl acetate, Neryl (7Z, 11Z) -hexadecane, methyl (2E, 4E, 6Z) -decatrienoate and methyl (2E, 4Z) ) -Decadienoate. ≪ / RTI > 12. The method of claim 11,
Wherein the insecticidal pheromone composition comprises 50 to 150 parts by weight of (5R, 6S) -6-acetoxy-5-hexadecanolide, 15 to 150 parts by weight of (R) 5 to 30 parts by weight of Neryl (S) -2-methyl butanoate, 5 to 30 parts by weight of heptadecane, 5 to 20 parts by weight of (7Z, 11Z, 13E) -hexadecatrienal, 15 to 60 parts by weight of methyl (2E, 4E, 6Z) -decatrienoate and 5 to 50 parts by weight of methyl (2E, 4Z) -decadienoate, ≪ / RTI > wherein the organic trap comprises one or more components selected from the group consisting of: The method according to claim 1,
Wherein the insecticidal pheromone composition and the adhesive composition further comprise one or more components independently selected from activated carbon powder, silica gel, and zeolite. The method according to claim 1,
Wherein the insecticidal pheromone composition and the pressure sensitive adhesive composition further comprise one or more components independently selected from the group consisting of germanium powder, elvan powder, biotite powder, bentonite powder and celestial powder.

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