KR20160041529A - Method for recycling paper sludges - Google Patents

Method for recycling paper sludges Download PDF

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KR20160041529A
KR20160041529A KR1020140135644A KR20140135644A KR20160041529A KR 20160041529 A KR20160041529 A KR 20160041529A KR 1020140135644 A KR1020140135644 A KR 1020140135644A KR 20140135644 A KR20140135644 A KR 20140135644A KR 20160041529 A KR20160041529 A KR 20160041529A
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sludge
mixture
paper
drying
paper sludge
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KR1020140135644A
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Korean (ko)
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김인관
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(주)엠에이디
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C23/00Auxiliary methods or auxiliary devices or accessories specially adapted for crushing or disintegrating not provided for in preceding groups or not specially adapted to apparatus covered by a single preceding group
    • B02C23/08Separating or sorting of material, associated with crushing or disintegrating
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/13Treatment of sludge; Devices therefor by de-watering, drying or thickening by heating
    • C02F11/131Treatment of sludge; Devices therefor by de-watering, drying or thickening by heating using electromagnetic or ultrasonic waves
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26DRYING
    • F26BDRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B3/00Drying solid materials or objects by processes involving the application of heat
    • F26B3/32Drying solid materials or objects by processes involving the application of heat by development of heat within the materials or objects to be dried, e.g. by fermentation or other microbiological action
    • F26B3/34Drying solid materials or objects by processes involving the application of heat by development of heat within the materials or objects to be dried, e.g. by fermentation or other microbiological action by using electrical effects
    • F26B3/347Electromagnetic heating, e.g. induction heating or heating using microwave energy
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26DRYING
    • F26BDRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B5/00Drying solid materials or objects by processes not involving the application of heat
    • F26B5/04Drying solid materials or objects by processes not involving the application of heat by evaporation or sublimation of moisture under reduced pressure, e.g. in a vacuum
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/26Nature of the water, waste water, sewage or sludge to be treated from the processing of plants or parts thereof
    • C02F2103/28Nature of the water, waste water, sewage or sludge to be treated from the processing of plants or parts thereof from the paper or cellulose industry

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  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Physics & Mathematics (AREA)
  • Hydrology & Water Resources (AREA)
  • Molecular Biology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Electromagnetism (AREA)
  • Microbiology (AREA)
  • Biotechnology (AREA)
  • Biomedical Technology (AREA)
  • Food Science & Technology (AREA)
  • Treatment Of Sludge (AREA)
  • Paper (AREA)

Abstract

Provided is a recycling method to sort and separate dried paper sludge into fiber and a filler using microwaves. The recycling method of paper sludge comprises: i) dehydrating paper sludge; ii) providing a mixture by sorting the dehydrated paper sludge into high-moisture content sludge and low-moisture content sludge and mutually mixing the two; iii) primarily drying the mixture using the current of a venturi jet stream; iv) secondarily drying the primarily dried mixture using microwaves; v) crushing the secondarily dried mixture; and vi) separating the crushed mixture into fiber and a filler.

Description

제지 슬러지의 재활용 방법 {METHOD FOR RECYCLING PAPER SLUDGES}[0001] METHOD FOR RECYCLING PAPER SLUDGES [0002]

본 발명은 제지 슬러지의 재활용 방법에 관한 것이다, 좀더 상세하게는, 본 발명은 마이크로웨이브로 건조한 제지 슬러지를 화이버와 필러로 선별 분리하여 재활용하는 방법에 관한 것이다.BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for recycling papermaking sludge. More particularly, the present invention relates to a method for selectively separating paper sludge dried by microwaves into fibers and fillers for recycling.

제지 산업에서는 제지 생산량의 10배 내지 30배 이상의 공업 용수를 사용한다. 종이 제조 공정 중 건조 공정에서 증발하는 10% 내외의 감량분을 제외하면, 전체 사용 용수의 90% 정도가 폐수로 변환되고, 이러한 폐수를 처리하는 과정에서 다량의 폐수 슬러지가 발생한다.In the paper industry, industrial water that is 10 times to 30 times the paper production is used. About 90% of the total used water is converted into wastewater, except for the wastewater which is evaporated in the drying process during the paper manufacturing process, and a large amount of wastewater sludge is generated during the treatment of such wastewater.

최근에는 제지 공정에서 발생하는 슬러지를 일반적인 폐수 처리 슬러지와 유사하게 농축, 안정화, 기계적 탈수 및 건조 과정을 거쳐서 수분 함량 80% 내외의 여과 케이크로 생산된다. 전처리가 끝난 슬러지는 매립, 소각, 해양 배출 등의 최종 처리를 통하여 재활용된다.In recent years, the sludge generated in the papermaking process is produced by filtration cake having a moisture content of about 80% through concentration, stabilization, mechanical dehydration and drying process similar to general wastewater treatment sludge. The pre-treated sludge is recycled through final treatment such as landfill, incineration, and ocean discharge.

제지 슬러지를 마이크로웨이브로 건조한 후 화이버와 필러로 선별 분리하여 재활용하는 방법을 제공하고자 한다.The paper sludge is dried by microwave, then separated by fiber and filler and recycled.

본 발명의 일 실시예에 따른 제지 슬러지의 재활용 방법은 i) 제지 슬러지를 탈수하는 단계, ii) 탈수된 제지 슬러지를 고함수율 슬러지와 저함수율 슬러지로 구분하여 상호 혼합하여 혼합물을 제공하는 단계, iii) 혼합물을 벤츄리 제트 기류에 의해 1차 건조하는 단계, iv) 1차 건조된 혼합물을 마이크로웨이브를 이용하여 2차 건조하는 단계, v) 2차 건조된 혼합물을 파쇄하는 단계, 및 vi) 파쇄된 혼합물을 파이버와 필러로 분리하는 단계를 포함한다.The method of recycling paper sludge according to one embodiment of the present invention comprises the steps of i) dewatering paper sludge, ii) separating the dewatered paper sludge into high moisture sludge and low moisture sludge, ) Drying the mixture by a venturi jet stream, iv) secondarily drying the first dried mixture using microwave, v) crushing the second dried mixture, and vi) And separating the mixture into a fiber and a filler.

제지 슬러지를 재활용하여 환경 공해를 절감할 수 있다. 또한, 재활용한 파이버와 필러는 제지 제조 및 다른 산업에도 활용할 수 있으므로 부수적인 수입을 올릴 수 있다. 그리고 제지 제조 비용을 절감할 수 있다.Environmental pollution can be reduced by recycling paper sludge. In addition, recycled fibers and fillers can be used for paper manufacturing and other industries, which can generate additional revenue. And the cost of manufacturing paper can be reduced.

도 1은 본 발명의 일 실시예에 따른 제지 슬러지의 재활용 방법을 개략적으로 나타낸 블록도이다.
도 2는 도 1의 제지 슬러지의 재활용 방법 중 1차 건조 단계를 개략적으로 나타낸 도면이다.
1 is a block diagram schematically illustrating a method of recycling paper sludge according to an embodiment of the present invention.
FIG. 2 is a schematic view showing a primary drying step in the method of recycling paper sludge of FIG. 1;

여기서 사용되는 전문용어는 단지 특정 실시예를 언급하기 위한 것이며, 본 발명을 한정하는 것을 의도하지 않는다. 여기서 사용되는 단수 형태들은 문구들이 이와 명백히 반대의 의미를 나타내지 않는 한 복수 형태들도 포함한다. 명세서에서 사용되는 "포함하는"의 의미는 특정 특성, 영역, 정수, 단계, 동작, 요소 및/또는 성분을 구체화하며, 다른 특정 특성, 영역, 정수, 단계, 동작, 요소, 성분 및/또는 군의 존재나 부가를 제외시키는 것은 아니다.The terminology used herein is for the purpose of describing particular embodiments only and is not intended to limit the invention. The singular forms as used herein include plural forms as long as the phrases do not expressly express the opposite meaning thereto. Means that a particular feature, region, integer, step, operation, element and / or component is specified, and that other specific features, regions, integers, steps, operations, elements, components, and / And the like.

다르게 정의하지는 않았지만, 여기에 사용되는 기술용어 및 과학용어를 포함하는 모든 용어들은 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자가 일반적으로 이해하는 의미와 동일한 의미를 가진다. 보통 사용되는 사전에 정의된 용어들은 관련기술문헌과 현재 개시된 내용에 부합하는 의미를 가지는 것으로 추가 해석되고, 정의되지 않는 한 이상적이거나 매우 공식적인 의미로 해석되지 않는다.Unless otherwise defined, all terms including technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. Commonly used predefined terms are further interpreted as having a meaning consistent with the relevant technical literature and the present disclosure, and are not to be construed as ideal or very formal meanings unless defined otherwise.

이하, 첨부한 도면을 참조하여 본 발명의 실시예에 대하여 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자가 용이하게 실시할 수 있도록 상세히 설명한다. 그러나 본 발명은 여러 가지 상이한 형태로 구현될 수 있으며 여기에서 설명하는 실시예에 한정되지 않는다.Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings so that those skilled in the art can easily carry out the present invention. The present invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein.

도 1은 본 발명의 일 실시예에 따른 제지 슬러지의 재활용 방법을 개략적인 블록도를 나타낸다, 도 1의 제지 슬러지의 재활용 방법은 단지 본 발명을 예시하기 위한 것이며, 본 발명이 여기에 한정되는 것은 아니다. 따라서 제지 슬러지의 재활용 방법을 다른 형태로도 변형할 수 있다.FIG. 1 shows a schematic block diagram of a method for recycling paper sludge according to an embodiment of the present invention. The method for recycling paper sludge of FIG. 1 is for illustrative purposes only and the present invention is limited thereto no. Therefore, the method of recycling paper sludge can be modified to other forms.

도 1에 도시한 바와 같이, 제지 슬러지의 재활용 방법은 제지 공장에서 배출되는 폐기물 중, 공정 슬러지 및 폐수처리 슬러지를 기계적 에너지와 마이크로파의 전기적 에너지만을 사용하여 함수율 10% 이하로 건조한다. 그리고 미분말로 분쇄한 후 건조 및 분쇄된 슬러지를 재료선별기에서 필러와 화이버로 선별 및 분리한다. 여기서, 필러는 제지 제조 원료로 재활용하고, 화이버와 기타 가연성 물질은 고형 연료화하여 제지 공장의 자체 소각로의 혼소용 대체 연료로 재활용할 수 있다. 그 결과, 제지 공장의 배출폐기물을 최소화시키고, 폐기물의 재활용률을 증대시키며, 제지 제조시 사용되는 에너지용 화석 연료의 사용량을 절감할 수 있다.As shown in FIG. 1, in the method of recycling paper sludge, the process sludge and wastewater treatment sludge are dried to a moisture content of 10% or less using only mechanical energy and electric energy of microwave among wastes discharged from paper mill. After crushing with fine powder, the dried and crushed sludge is sorted and separated by a filler and a fiber in a material separator. Here, the filler can be recycled as a raw material for paper making, and the fiber and other combustible materials can be converted into solid fuel and recycled as an alternative fuel for the paper mill's own incinerator. As a result, it is possible to minimize waste waste from paper mills, increase the recycling rate of waste, and reduce the amount of fossil fuel used for energy used in paper manufacturing.

좀더 구체적으로 먼저 탈수 과정에서는 투입된 1차 슬러지를 기계적 탈수 과정을 거쳐서 최소한의 함수율로 안정화시킨다. 그리고 혼합 공정에서는 탈수된 고함수율의 슬러지와 건조 후의 저함수율 슬러지를 적절한 비율로 혼합한다. 이 경우, 건조 공정 중의 슬러지의 부착존(sticky zone) 생성을 방지할 수 있다. More specifically, in the dehydration process, the introduced primary sludge is mechanically dewatered and stabilized at a minimum water content. In the mixing process, the dehydrated high-moisture sludge and the low-moisture sludge after drying are mixed at an appropriate ratio. In this case, sticky zones of the sludge during the drying process can be prevented.

접착성이 강한 슬러지를 건조하는 경우, 슬러지 유기 물질에 의해 전술한 부착존이 생성되어 정상 운전이 불가능하거나 설비가 크게 손상될 수 있다. 이를 방지하기 위하여 슬러지의 건조 전단계에서 젖은 슬러지와 건조 슬러지를 혼합하여 부착존이 발생할 함수율 영역을 피할 수 있다.In the case of drying the highly adhesive sludge, the above-mentioned adhesion zone is generated by the sludge organic material, and the operation can not be normally performed or the equipment may be seriously damaged. In order to prevent this, the wetting sludge and dry sludge are mixed in the pre-drying stage of the sludge, thereby avoiding the water content region where the adhesion zone occurs.

다음으로, 벤츄리 제트 기류 건조기를 이용하여 제지 슬러지를 한계 함수율까지 건조시킨다. 그리고 마이크로파 건조기를 이용하여 제지 슬러지를 평형 함수율까지 건조시킨다. 마이크로파 건조기는 열풍 건조 대비 높은 건조 효율을 얻을 수 있는 방법이며, 대류 건조 방식을 결합한 마이크로파-열풍-융합 건조 방식을 사용함므로써 일반적인 마이크로파 건조기보다 높은 건조 효율을 나타낼 수 있다. 전술한 바와 같이, 전체 건조 공정을 1차/2차로 나누어 건조하여 에너지 소비를 최소화하며, 마이크로파 건조 방식을 채택하여 에너지를 절감할 수 있다. 또한, 파쇄기를 이용하여 건조 슬러지를 적절한 크기로 미립화하여 선별 공정에서 선별성을 향상시킨다. 그리고 미립화된 건조 슬러지를 진동 스크린 등의 선별기를 이용하여 섬유소 성분(Fiber Fraction)과 충진제 성분(Filler Fraction)으로 분류한다. 제지슬러지 내에 포함된 대부분의 고형분을 이용하여 약 35%의 유기 물질(섬유소)은 고형 연료한다. 즉, 섬유소 성분은 회전드럼 성형기 등의 성형기에서 파렛형 고형 연료로 성형한다. 마지막으로, 성형된 SDF(Sludge Drived Fuel)를 사일로 또는 저장 호퍼 등에 저장한다. 그리고 약 60%의 무기 물질(필러)은 CaCO3와 Clay 등으로 분리 및 회수한다. Next, the paper sludge is dried to a limiting moisture content using a venturi jet air dryer. Then, the paper sludge is dried to an equilibrium moisture content by using a microwave dryer. The microwave dryer is a method for obtaining high drying efficiency compared to the hot air drying, and it can exhibit higher drying efficiency than a general microwave dryer by using the microwave-hot air-fusion drying method combined with the convection drying method. As described above, the entire drying process is divided into primary / secondary drying to minimize energy consumption, and energy can be saved by employing a microwave drying method. In addition, the crusher is used to atomize the dried sludge to an appropriate size to improve the selectivity in the sorting process. Then, the atomized dry sludge is classified into a fiber fraction and a filler fraction by using a sorting machine such as a vibrating screen. About 35% of organic matter (fiber) is solid fuel using most of the solids contained in paper sludge. That is, the fibrous component is molded into a pallet type solid fuel in a molding machine such as a rotary drum molding machine. Finally, the molded SDF (Sludge Drived Fuel) is stored in a silo or storage hopper. And about 60% of inorganic material (filler) is separated and recovered by CaCO 3 and Clay.

도 2는 도 1의 제지 슬러지의 재활용 방법 중 1차 건조 단계를 개략적으로 나타낸다. 도 2의 1차 건조 방법은 단지 본 발명을 예시하기 위한 것이며, 본 발명이 여기에 한정되는 것은 아니다. 따라서 1차 건조 방법을 다른 형태로도 변형할 수 있다.Fig. 2 schematically shows the primary drying step of the method of recycling paper sludge of Fig. The primary drying method of FIG. 2 is only for illustrating the present invention, and the present invention is not limited thereto. Thus, the primary drying process can be modified to other forms.

도 2에 도시한 바와 같이, 제지 슬러지를 1차 건조함으로써 2차 건조시의 에너지를 절약할 수 있다. 즉, 1차 건조 단계에서는 벤츄리 제트 기류 건조 방식을 이용하여 고속의 공기 흐름과 함께 건조 대상물이 벤츄리를 통과하는 경우, 제지 슬러지의 입자를 파괴시켜 수분을 공기 흐름에 흡수시켜 건조한다. 이 방식은 열원을 사용하지 않는 에너지 절약형이고, 대기오염물질이 발생하지 않으며, 악취가 발생하지 않아서 친환경적이다.As shown in Fig. 2, primary drying of paper sludge can save energy during secondary drying. That is, in the primary drying step, when the object to be dried passes through the venturi using a venturi jet air drying method and a high-speed air flow, the particles of the paper sludge are destroyed and moisture is absorbed into the air stream and dried. This method is energy-saving type that does not use a heat source, does not generate air pollutants, and is environment-friendly because odor is not generated.

본 발명을 앞서 기재한 바에 따라 설명하였지만, 다음에 기재하는 특허청구범위의 개념과 범위를 벗어나지 않는 한, 다양한 수정 및 변형이 가능하다는 것을 본 발명이 속하는 기술 분야에서 종사하는 자들은 쉽게 이해할 것이다.It will be understood by those skilled in the art that various changes and modifications may be made without departing from the spirit and scope of the following claims.

Claims (1)

제지 슬러지를 탈수하는 단계,
탈수된 제지 슬러지를 고함수율 슬러지와 저함수율 슬러지로 구분하여 상호 혼합하여 혼합물을 제공하는 단계,
상기 혼합물을 벤츄리 제트 기류에 의해 1차 건조하는 단계,
상기 1차 건조된 혼합물을 마이크로웨이브를 이용하여 2차 건조하는 단계,
상기 2차 건조된 혼합물을 파쇄하는 단계, 및
상기 파쇄된 혼합물을 파이버와 필러로 분리하는 단계
를 포함하는 제지 슬러지의 재활용 방법.
Dewatering the paper sludge,
Separating the dehydrated paper sludge into a high moisture sludge and a low moisture sludge and mixing them to provide a mixture,
Primary drying the mixture by a venturi jet stream,
Drying the mixture by using a microwave,
Crushing said secondary dried mixture, and
Separating the shredded mixture into a fiber and a filler
Wherein the paper sludge is recycled.
KR1020140135644A 2014-10-08 2014-10-08 Method for recycling paper sludges KR20160041529A (en)

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