KR20150120788A - Exhaust valve for engine - Google Patents
Exhaust valve for engine Download PDFInfo
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- KR20150120788A KR20150120788A KR1020140046905A KR20140046905A KR20150120788A KR 20150120788 A KR20150120788 A KR 20150120788A KR 1020140046905 A KR1020140046905 A KR 1020140046905A KR 20140046905 A KR20140046905 A KR 20140046905A KR 20150120788 A KR20150120788 A KR 20150120788A
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- engine
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01L—CYCLICALLY OPERATING VALVES FOR MACHINES OR ENGINES
- F01L3/00—Lift-valve, i.e. cut-off apparatus with closure members having at least a component of their opening and closing motion perpendicular to the closing faces; Parts or accessories thereof
- F01L3/02—Selecting particular materials for valve-members or valve-seats; Valve-members or valve-seats composed of two or more materials
- F01L3/04—Coated valve members or valve-seats
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- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Cylinder Crankcases Of Internal Combustion Engines (AREA)
- Laminated Bodies (AREA)
Abstract
An exhaust valve for an engine is disclosed. An exhaust valve for an engine for discharging exhaust gas generated in a combustion chamber of an engine, comprising an airgel dispersed in a polyamide-imide resin and a polyamide-imide resin in a face portion on which a flame is in contact and has a thermal conductivity of 0.60 W / A heat insulating coating layer having a degree of crystallinity can be formed.
Description
BACKGROUND OF THE
Generally, an internal combustion engine refers to an engine that converts combustion energy generated by combustion of a fuel directly into a piston or a turbine blade to convert the heat energy of the fuel into mechanical one.
A gas turbine, a jet engine, a rocket, and the like are internal combustion engines, although many of them refer to reciprocating engines that ignite and explode a mixture of fuel and air in the cylinder to move the piston.
Gas engines, gasoline engines, petroleum engines, diesel engines and the like are classified into fuels using internal combustion engines. Oil, gas and gasoline engines are ignited by electric sparks by ignition plugs (ignition), and diesel engines spontaneously ignite by injecting fuel into high temperature and high pressure air. There are four strokes and two stroke strokes depending on the stroke and operation of the piston.
Generally, it is known that the internal combustion engine of an automobile has a thermal efficiency of about 15% to 35%. Even in the maximum efficiency of the internal combustion engine, heat energy and exhaust gas emitted to the outside through the wall of the internal combustion engine, % Or more is consumed.
Since the efficiency of the internal combustion engine can be improved by reducing the amount of heat energy released to the outside through the wall of the internal combustion engine as described above, it is possible to install a heat insulating material on the outside of the internal combustion engine, to change the material or structure of the internal combustion engine, Were used to develop the cooling system.
Particularly, it is possible to improve the efficiency of the internal combustion engine and the fuel efficiency of the automobile by minimizing the heat generated in the internal combustion engine from being radiated to the outside through the wall of the internal combustion engine. In the internal combustion engine, The research on the heat insulating material and the adiabatic structure that can be maintained for a long time in the case of
The matters described in the background section are intended to enhance the understanding of the background of the invention and may include matters not previously known to those skilled in the art.
Embodiments of the present invention can provide high temperature durability by applying a heat insulating coating layer having low thermal conductivity and low volumetric heat capacity while ensuring high mechanical properties and heat resistance, And to provide an exhaust valve for an engine capable of improving the efficiency and fuel economy of an automobile.
An exhaust valve for an engine according to an embodiment of the present invention is for discharging exhaust gas generated in a combustion chamber of an engine and includes a polyamideimide resin and an airgel dispersed in the polyamideimide resin in a face portion where the flame is in contact And an insulating coating layer having a thermal conductivity of 0.60 W / m or less can be formed.
An exhaust valve for an engine according to an embodiment of the present invention is for discharging the exhaust gas generated in a combustion chamber of an engine. The exhaust valve for an engine according to the embodiment of the present invention includes a polyamide-imide resin and a polyamide- An insulating coating layer containing an airgel and having a thermal conductivity of 0.60 W / m or less can be formed.
Further, the exhaust valve for an engine according to the embodiment of the present invention is for discharging the exhaust gas generated in the combustion chamber of the engine. The exhaust valve for an engine according to the embodiment of the present invention includes a polyamide- An insulating coating layer containing an airgel dispersed in the polyamideimide resin and having a thermal conductivity of 0.60 W / m or less can be formed.
In the exhaust valve for an engine according to an embodiment of the present invention, the heat insulating coating layer may have a heat capacity of 1250 KJ / m3 K or less.
In the exhaust valve for an engine according to the embodiment of the present invention, the polyamide-imide resin may be present in an amount of 2% by weight or less in the inside of the airgel.
In the exhaust valve for an engine according to the embodiment of the present invention, the polyamide-imide resin may not exist at a depth of 5% or more of the longest diameter from the surface of the airgel.
In the exhaust valve for an engine according to the embodiment of the present invention, each of the aerogels may have a porosity of 92% to 99% in a state of being dispersed in the polyamideimide resin.
Further, in the exhaust valve for an engine according to the embodiment of the present invention, the heat-insulating coating layer may have a thickness of 50 탆 to 500 탆.
In addition, in the exhaust valve for an engine according to an embodiment of the present invention, the heat insulating coating layer may include 5 to 50 parts by weight of the airgel relative to 100 parts by weight of the polyamideimide resin.
Embodiments of the present invention can provide high temperature durability by applying a heat insulating coating layer having low thermal conductivity and low volumetric heat capacity while ensuring high mechanical properties and heat resistance, Efficiency and fuel economy of the automobile.
In addition, embodiments of the present invention can ensure high-temperature durability without using a very expensive high-temperature resistant material (such as Inconel) that increases the nickel content through increase in valve temperature reduction, Can be saved.
These drawings are for the purpose of describing an embodiment of the present invention, and therefore the technical idea of the present invention should not be construed as being limited to the accompanying drawings.
1 is a view schematically showing an exhaust valve for an engine according to an embodiment of the present invention.
2 is a photograph showing the surface of the heat-insulating coating layer obtained in the embodiment of the present invention.
3 is a photograph showing the surface of the coating layer obtained in the comparative example in comparison with the embodiment of the present invention.
Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the accompanying drawings, which will be readily apparent to those skilled in the art to which the present invention pertains. The present invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein.
In order to clearly illustrate the present invention, parts not related to the description are omitted, and the same or similar components are denoted by the same reference numerals throughout the specification.
It is to be understood that both the foregoing general description and the following detailed description of the present invention are exemplary and explanatory and are intended to provide further explanation of the invention as claimed.
In the following detailed description, the names of components are categorized into the first, second, and so on in order to distinguish them from each other in the same relationship, and are not necessarily limited to the order in the following description.
Throughout the specification, when an element is referred to as "comprising ", it means that it can include other elements as well, without excluding other elements unless specifically stated otherwise.
It should be noted that terms such as " ... unit ", "unit of means "," part of item ", "absence of member ", and the like denote a unit of a comprehensive constitution having at least one function or operation it means.
1 is a view schematically showing an exhaust valve for an engine according to an embodiment of the present invention.
Referring to FIG. 1, an
For example, the
The
The
Hereinafter, the
The
That is, in the embodiment of the present invention, an exhaust valve for an engine that can maintain high temperature durability without using a very expensive high heat resistant material (such as Inconel) that increases the nickel content through increase in valve temperature reduction, (100).
To this end, the
Furthermore, the
The heat insulating
Hereinafter, the heat
An embodiment of the present invention provides an insulating coating composition comprising a polyamideimide resin dispersed in a high boiling organic solvent or an aqueous solvent as an insulating coating layer and an airgel dispersed in a low boiling organic solvent.
Further, the heat insulating coating layer according to the embodiment of the present invention includes a polyamideimide resin and an airgel dispersed in the polyamideimide resin, and has a thermal conductivity of 0.60 W / m or less.
According to a specific embodiment of the present invention, it is possible to provide an insulating coating composition comprising a polyamideimide resin dispersed in a high-boiling organic solvent or an aqueous solvent and an airgel dispersed in a low-boiling organic solvent.
The present inventors have found that a coating composition obtained by dispersing a polyamide-imide resin and an airgel in a predetermined solvent and then mixing the coating composition and the coating layer obtained therefrom can secure a high mechanical property and heat resistance while having lower thermal conductivity and lower density, It is confirmed through experiments that the efficiency of the internal combustion engine and the fuel consumption of the automobile can be improved by reducing the heat energy applied to the internal combustion engine to the outside, thereby completing the invention.
Furthermore, the present inventors have found that the above-described coating layer is applied to part or all of the
Recently, methods of using aerogels (aerogels or air-gels) have been introduced in the field of heat insulation materials, shock absorbing materials or soundproofing materials. Such aerogels are characterized by entanglement of microstructures of about 1 / 10,000th of a hair and having a porosity of 90% or more. The main material is silicon oxide, carbon, or an organic polymer. Particularly, the airgel is a very low-density material having a high light transmittance and a very low thermal conductivity due to the above-described structural characteristics.
However, since the aerogels are highly fragile due to their high brittleness and they are easily broken even by small impacts, they are difficult to be processed into various thicknesses and shapes. Therefore, despite their excellent heat insulating properties, And other reactants are mixed, the solvent or the solute penetrates into the inside of the airgel to increase the viscosity of the compound, making it impossible to mix or mix with other materials, and the characteristics of the porous airgel can not be exhibited.
On the other hand, in the heat insulating coating composition of the embodiment, the polyamideimide resin exists in a state of being dispersed in a high-boiling organic solvent or an aqueous solvent, and the airgel is dispersed in the low-boiling organic solvent. The solvent dispersed phase of the polyamide-imide resin and the solvent dispersed phase of the airgel may be uniformly mixed without aggregation, and the heat-insulating coating composition may also have a homogeneous composition.
In addition, since the high-boiling organic solvent or the aqueous solvent and the low-boiling organic solvent are not easily dissolved or mixed with each other, the polyamideimide resin is dispersed in a high-boiling organic solvent or an aqueous solvent and the airgel is dispersed The direct contact between the polyamide-imide resin and the aerogels can be minimized until the heat-insulating coating composition of the embodiment is applied and dried. As a result, It is possible to prevent the polyamideimide resin from being infiltrated or impregnated.
The low-boiling organic solvent has a certain affinity with the high-boiling organic solvent or the aqueous solvent, so that the airgel dispersed in the low-boiling organic solvent is mixed with the polyamideimide resin dispersed in the high boiling organic solvent or the aqueous solvent So that the polyamide-imide resin can be uniformly distributed, and the polyamide-imide resin can be uniformly distributed in the high-boiling organic solvent or water-based solvent.
Accordingly, in the heat insulating coating layer obtained from the heat insulating coating composition of the embodiment, the physical properties of the airgel can be ensured to be equal to or higher than that of the airgel, and the airgel is more uniformly dispersed in the polyamideimide resin, Together, improved insulation properties can be achieved.
That is, as described above, since the thermal barrier coating layer obtained from the thermal barrier coating composition of the embodiment can maintain the physical properties and the structure itself of the airgel at the same level, the thermal conductivity and the heat resistance And it is possible to improve the efficiency of the internal combustion engine and the fuel efficiency of the automobile by reducing the heat energy applied to the internal combustion engine to the outside.
Furthermore, the heat-insulating coating layer obtained from the heat-insulating coating composition of the embodiment is applied to part or all of the exhaust valve which is a part of the internal combustion engine, thereby increasing the content of nickel (Ni) High-temperature durability can be ensured without using materials
1, the heat insulating coating layer may be applied to the
On the other hand, the thermal barrier coating composition of one embodiment can be formed by mixing the high boiling point organic solvent or a polyamideimide resin dispersed in an aqueous solvent and an aerogel dispersed in a low boiling organic solvent.
The method of mixing is not particularly limited, and a known physical mixing method may be used. For example, a method of preparing a coating composition (coating solution) by mixing the above two kinds of solvent dispersed phases, adding zirconia beads thereto, and ball milling at a temperature of room temperature and a pressure of 100 to 500 rpm have. However, the method of mixing the dispersed phase of the solvent of each of the polyamide-imide resin and the airgel is not limited to the example described above.
The heat-insulating coating composition of this embodiment can provide a heat-insulating material or a heat-insulating structure that can be maintained for a long time in an internal combustion engine subjected to repetitive high-temperature and high-pressure conditions. Specifically, It may be used for coating the inner surface of the engine or the parts of the internal combustion engine and may be used for coating the face portion and / or the neck portion of the exhaust valve as described above.
The polyamide-imide resin may have a weight average molecular weight of 3,000 to 300,000, or 4,000 to 100,000, although the examples of the polyamide-imide resin that can be included in the thermal barrier coating composition of the embodiment are not limited.
If the weight average molecular weight of the polyamide-imide resin is too small, it may be difficult to sufficiently secure the mechanical properties, heat resistance and thermal insulation of the coating layer, the coating film or the coating film obtained from the heat-insulating coating composition, and the polymer resin penetrates into the airgel Can be facilitated.
If the weight average molecular weight of the polyamide-imide resin is too large, the uniformity or homogeneity of the coating layer, the coating film or the coating film obtained from the heat-insulating coating composition may be deteriorated and the dispersibility of the airgel in the heat- Or a nozzle or the like of the coating apparatus may be blocked when applying the heat-insulating coating composition, and the time for heat-treating the heat-insulating coating composition may be increased and the heat-treating temperature may be increased.
As the aerogels, conventionally known aerogels may be used. Specifically, aerogels composed of silicon oxide, carbon, polyimide, metal carbide, or a mixture of two or more of them may be used. The airgel may have a specific surface area ranging from 100 cm 3 / g to 1,000 cm 3 / g, or from 300 cm 3 / g to 900 cm 3 / g.
The heat-insulating coating composition may contain 5 to 50 parts by weight, or 10 to 45 parts by weight, of the airgel relative to 100 parts by weight of the polyamideimide resin. The weight ratio of the polyamideimide resin and the airgel is a weight ratio of the solid content excluding the dispersion solvent.
If the content of the aerogels is too small as compared with the polyamideimide resin, it may be difficult to lower the thermal conductivity and density of the coating layer, the coating film or the coating film obtained from the heat-insulating coating composition, and it may be difficult to secure sufficient heat insulation. The heat resistance of the heat insulating film produced from the composition may be reduced.
If the content of the aerogels is too large as compared with the polymer resin, it may be difficult to sufficiently secure the mechanical properties of the coating layer, the coating film or the coating film obtained from the heat-insulating coating composition, and the heat insulating film produced from the heat- And it may be difficult to maintain the form of the coating film of the heat insulating film firmly.
The solid content of the polyamideimide resin in the high-boiling organic solvent or the aqueous solvent is not particularly limited, but the solid content may be 5 wt% to 75 wt% in consideration of uniformity and physical properties of the heat-insulated coating composition .
In addition, the solid content of the airgel in the low-boiling organic solvent is not particularly limited, but the solid content may be 5 wt% to 75 wt% in consideration of uniformity and physical properties of the heat-insulating coating composition.
As described above, since the high-boiling organic solvent or the low-boiling organic solvent and the low-boiling organic solvent are not easily dissolved or mixed with each other, the polyamideimide resin and the polyamideimide resin are mixed with each other until the heat- The direct contact between the airgel can be minimized and the polyamideimide resin can be prevented from penetrating or impregnating into the inside or the pores of the airgel.
Specifically, the boiling point difference between the high boiling organic solvent and the low boiling organic solvent may be 10 ° C or higher, 20 ° C or higher, or 10-200 ° C. As the high-boiling organic solvent, an organic solvent having a boiling point of 110 ° C or higher may be used.
Specific examples of such a high boiling solvent include anisole, toluene, xylene, methyl ethyl ketone, methyl isobutyl ketone and ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, butyl acetate, cyclohexanone, ethylene Glycol monoethyl ether acetate (BCA), benzene, hexane, DMSO, (N, N'-dimethylformamide, or a mixture of two or more thereof).
As the low-boiling organic solvent, an organic solvent having a boiling point of less than 110 캜 may be used.
Specific examples of such low-boiling organic solvents include alcohols such as methyl alcohol, ethyl alcohol, propyl alcohol, n-butyl alcohol, isobutyl alcohol, tert-butyl alcohol, acetone, methylene chloride, ethylene acetate, isopropyl alcohol, .
Specific examples of the water-based solvent include water, methanol, ethanol, ethyl acetate, or a mixture of two or more thereof.
On the other hand, according to another embodiment of the present invention, it is possible to provide an insulating coating layer containing a polyamideimide resin and an airgel dispersed in the polyamideimide resin, and having a thermal conductivity of 0.60 W / m or less.
The present inventors have found that the use of the thermal barrier coating composition of one embodiment can ensure high mechanical properties and heat resistance while having low thermal conductivity and low density and is applied to an internal combustion engine to reduce the heat energy released to the outside, An insulating coating layer capable of improving the efficiency and fuel economy of the automobile was manufactured.
Furthermore, the present inventors have found that, by using the heat-insulating coating composition of the above-described embodiment, the temperature of the exhaust valve is increased, and the high temperature durability is ensured without using a very expensive high heat resistant material which increases the content of nickel A thermal barrier coating layer was prepared.
In the heat-insulating coating layer, the aerogels are uniformly dispersed throughout the entire polyamide-imide resin area. Accordingly, physical properties, such as low thermal conductivity and low density, realized from the aerogels can be more easily ensured, The properties expressed from the polyamideimide resin, such as high mechanical properties and heat resistance, can be realized at a level equal to or higher than that of using the polyamideimide resin alone.
The heat insulating coating layer may have a low thermal conductivity and a high heat capacity. Specifically, the heat insulating coating layer may have a thermal conductivity of 0.60 W / m or less, or 0.55 W / m or less, or 0.60 W / m to 0.200 W / And the heat insulating coating layer may have a heat capacity of 1250 KJ / m3 K or less, or 1000 to 1250 KJ / m3 K.
On the other hand, as described above, the heat insulating coating composition of the embodiment includes the polyamideimide resin dispersed in the high boiling organic solvent or the aqueous solvent and the airgel dispersed in the low boiling organic solvent, and the coating composition is applied and dried Since the direct contact between the polyamide-imide resin and the airgel can be minimized, the polyamide-imide resin may not be impregnated or impregnated into the inside or the pores of the aerogels included in the finally prepared heat-insulating coating layer .
Specifically, the polyamide-imide resin may be substantially absent from the inside of the aerogel dispersed in the polyamide-imide resin. For example, the polyamide-imide resin may be contained in an amount of 2 wt% or less, or 1 % ≪ / RTI > by weight.
The airgel may be dispersed in the polyamide-imide resin. In this case, the outside of the airgel may be in contact with or bonded to the polyamide-imide resin. In the interior of the airgel, The polyamideimide resin may not be present. Specifically, the polyamideimide resin may not be present at a depth of 5% or more of the longest diameter from the surface of the airgel contained in the heat insulating coating layer.
Since the polyamide-imide resin is not impregnated or impregnated into the inside or the pores of the airgel, the airgel may have an equivalent porosity before and after the polyamide-imide resin is dispersed in the polyamide-imide resin. Specifically, Each of the aerogels included in the polyamide-imide resin may have a porosity of 92% to 99% in a state of being dispersed in the polyamideimide resin.
The heat insulating coating layer of the embodiment can provide a heat insulating material or a heat insulating structure which can be maintained for a long time in the internal combustion engine where repeated high temperature and high pressure conditions are applied. Specifically, the heat insulating coating layer of the embodiment, Or on an exhaust valve that is part of an internal combustion engine.
The thickness of the heat-insulating coating layer of the embodiment may be determined depending on the field or position to which it is applied or the required physical properties, and may be, for example, 50 to 500 탆.
The heat insulating coating layer of the embodiment may include 5 to 50 parts by weight, or 10 to 45 parts by weight of the aerogels, based on 100 parts by weight of the polyamideimide resin.
If the content of the aerogels is too small as compared with the polyamideimide resin, it may be difficult to lower the thermal conductivity and density of the heat-insulating coating layer, and it may be difficult to ensure sufficient heat insulation and heat resistance of the heat-insulating coating layer may be reduced. If the content of the aerogels is too large as compared with the polymer resin, it may be difficult to sufficiently secure the mechanical properties of the heat-insulating coating layer, cracking of the heat-insulating coating layer may occur, or the coating film form of the heat- .
The polyamideimide resin may have a weight average molecular weight of 3,000 to 300,000 or 4,000 to 100,000.
The aerogels may include at least one compound selected from the group consisting of silicon oxide, carbon, polyimide, and metal carbide.
The airgel may have a specific surface area of 100 cm 3 / g to 1,000 cm 3 / g.
The specific contents of the polyamideimide resin and the airgel include those described above with respect to the thermal barrier coating composition of one embodiment.
On the other hand, the thermal barrier coating layer of the embodiment can be obtained by drying the thermal barrier coating composition of one embodiment. The apparatus and method that can be used for drying the heat-insulating coating composition of the embodiment are not limited in any way. For example, a method of natural drying at a temperature of room temperature or higher or a method of heating to a temperature of 50 ° C or higher may be used.
For example, the thermal barrier coating composition of one embodiment may be coated on the inner surface of a coating object, such as an inner surface of an internal combustion engine or an outer surface of a component of an internal combustion engine, and semi-drying is conducted at a temperature of 50 to 200 DEG C at least once, The semi-dried coating composition may be completely dried at a temperature of 200 ° C or higher to form the heat-insulating coating layer. However, the method for manufacturing the heat-insulating coating layer of the embodiment is not limited thereto.
The present invention will be described in more detail in the following Examples. However, the following examples are illustrative of the present invention, and the present invention is not limited by the following examples.
[Examples 1 to 3]
(1) Preparation of adiabatic coating composition
A porous silica airgel (specific surface area of about 500 cm 3 / g) dispersed in ethyl alcohol and a polyamideimide resin dispersed in xylene (Solvay, weight average molecular weight of about 11,000) were injected into a 20 g reactor and zirconia beads were added 440 g) was subjected to ball milling at a rate of 150 to 300 rpm under normal temperature and pressure conditions to prepare an adiabatic coating composition (coating solution).
At this time, the weight ratio of the porous silica airgel to the polyamideimide resin is as shown in Table 1 below.
(2) Formation of thermal insulation coating layer
The obtained heat-insulating coating composition was applied to parts for automobile engines by a spray coating method. Then, after applying the heat-insulating coating composition on the part and performing primary semi-drying at about 150 ° C for about 10 minutes, the heat-insulating coating composition is re-applied and secondary semi-drying is performed at about 150 ° C for about 10 minutes . After the secondary semi-drying, the heat-insulating coating composition was applied again and completely dried at about 250 ° C for about 60 minutes to form an adiabatic coating layer on the component. The thickness of the coating layer formed at this time is as shown in Table 1 below.
[Comparative Example 1]
(PAI solution) solution of polyamideimide resin (Solvay, weight average molecular weight: about 11,000) dispersed in xylene was applied to parts for automobile engine.
After the PAI solution was applied on the component and the primary semi-drying was performed at about 150 ° C for about 10 minutes, the PAI solution was re-applied and secondary semi-drying was performed at about 150 ° C for about 10 minutes . After the second semi-drying, the PAI solution was applied again, and the resultant was completely dried at about 250 ° C for about 60 minutes to form a heat-insulating coating layer on the component. The thickness of the coating layer formed at this time is as shown in Table 1 below.
[Comparative Example 2]
(1) Preparation of Coating Composition
A porous silica airgel (specific surface area of about 500 cm 3 / g) and a polyamideimide resin dispersed in xylene (Solvay, weight average molecular weight: about 11,000) were charged into a 20 g reactor, zirconia beads were added (440 g) The coating composition (coating solution) was prepared by ball milling at a speed of 150 to 300 rpm under an atmospheric pressure condition.
At this time, the weight ratio of the porous silica airgel to the polyamideimide resin is as shown in Table 1 below.
(2) Formation of thermal insulation coating layer
A coating layer having a thickness of about 200 mu m was formed in the same manner as in Example 1. [
[Experimental Example]
1. Experimental Example 1: Measurement of thermal conductivity
The thermal conductivity of the coating layer on the parts obtained in the above Examples and Comparative Examples was measured by a thermal diffraction method using a laser flash method under normal temperature and normal pressure conditions in accordance with ASTM E1461.
2. Experimental Example 2: Measurement of heat capacity
With respect to the coating layer on the parts obtained in the above Examples and Comparative Examples, the specific heat was measured using sapphire as a reference using a DSC apparatus under normal temperature conditions according to ASTM E1269 to confirm the heat capacity.
As shown in Table 1, it was confirmed that the heat-insulating coating layers obtained in Examples 1 to 3 had a heat capacity of 1240 KJ / m 3 K or less and a thermal conductivity of 0.54 W / m or less at a thickness of 120 to 200 μm. Accordingly, the heat-insulating coating layer obtained in Examples 1 to 3 is applied to the coating of parts of the internal combustion engine, thereby reducing the heat energy released to the outside, thereby improving the efficiency of the internal combustion engine and the fuel efficiency of the automobile.
Further, the heat-insulating coating layers obtained in Examples 1 to 3 are applied to a part or all of the exhaust valve to increase the amount of nickel (Ni) by reducing the valve temperature, so that a very high heat- High-temperature durability can be ensured.
Also, as shown in FIG. 2, it can be seen that the polyamide-imide resin does not penetrate into the inside of the airgel in the heat-insulating coating layer prepared in Example 1, and the pores of the airgel are maintained at about 92% or more.
On the contrary, in the coating layer prepared in Comparative Example 2, as shown in FIG. 3, the polyamideimide resin penetrated into the airgel, and pores were hardly observed.
According to the
In addition, embodiments of the present invention can provide high-temperature durability without using a very expensive high heat resistant material (such as Inconel) that increases the nickel content by increasing the reduction of the valve temperature by applying the heat insulating coating layer And the manufacturing cost can be reduced.
While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is to be understood that the invention is not limited to the disclosed exemplary embodiments, Other embodiments may easily be suggested by adding, changing, deleting, adding, or the like of elements, but this also falls within the scope of the present invention.
11 ... stem portion
13 ... face portion
15 ... Neck Department
50 ... adiabatic coating layer
Claims (9)
Characterized in that a heat insulating coating layer having a polyamideimide resin and an airgel dispersed in the polyamideimide resin and having a thermal conductivity of 0.60 W / m or less is formed on the face portion where the flame is in contact.
Characterized in that a heat insulating coating layer including a polyamideimide resin and an airgel dispersed in the polyamideimide resin and having a thermal conductivity of 0.60 W / m or less is formed in a neck portion where an exhaust gas contacts.
Characterized in that a heat insulating coating layer containing a polyamideimide resin and an airgel dispersed in the polyamideimide resin and having a thermal conductivity of 0.60 W / m or less is formed on the neck portion where the flame is in contact with the exhaust gas The exhaust valve for the engine.
Wherein the heat insulating coating layer has a heat capacity of 1250 KJ / m < 3 > K or less.
Wherein the polyamide-imide resin is present in an amount of 2 wt% or less in the inside of the airgel.
Wherein the polyamide-imide resin is not present at a depth of 5% or more of the longest diameter from the surface of the airgel.
Wherein each of the aerogels has a porosity of 92% to 99% in a state of being dispersed in the polyamideimide resin.
Wherein the heat insulating coating layer has a thickness of 50 占 퐉 to 500 占 퐉.
Wherein the heat insulating coating layer comprises 5 to 50 parts by weight of the airgel relative to 100 parts by weight of the polyamideimide resin.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020140046905A KR101566743B1 (en) | 2014-04-18 | 2014-04-18 | Exhaust valve for engine |
| US14/542,274 US20150300215A1 (en) | 2014-04-18 | 2014-11-14 | Exhaust valve for engine |
| DE102014116837.2A DE102014116837A1 (en) | 2014-04-18 | 2014-11-18 | Exhaust valve for internal combustion engine |
| CN201410670564.6A CN105038577B (en) | 2014-04-18 | 2014-11-20 | exhaust valve for engine |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020140046905A KR101566743B1 (en) | 2014-04-18 | 2014-04-18 | Exhaust valve for engine |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20150120788A true KR20150120788A (en) | 2015-10-28 |
| KR101566743B1 KR101566743B1 (en) | 2015-11-06 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020140046905A KR101566743B1 (en) | 2014-04-18 | 2014-04-18 | Exhaust valve for engine |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US20150300215A1 (en) |
| KR (1) | KR101566743B1 (en) |
| CN (1) | CN105038577B (en) |
| DE (1) | DE102014116837A1 (en) |
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|---|---|---|---|---|
| KR101575328B1 (en) * | 2014-04-29 | 2015-12-07 | 현대자동차 주식회사 | Intake valve for engine |
| GB2568975A (en) | 2017-10-30 | 2019-06-05 | Eaton Srl | Poppet valve |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR19990044558A (en) * | 1995-09-11 | 1999-06-25 | 악커만 요아힘; 되르 클라우스 | Composites containing aerogels and adhesives, preparation methods thereof and uses thereof |
| DE19702238A1 (en) * | 1997-01-24 | 1998-08-06 | Hoechst Ag | Use of aerogels for body and / or impact sound insulation |
| JP2003307105A (en) | 2002-04-12 | 2003-10-31 | Fuji Oozx Inc | Engine valve |
| JP2005179514A (en) | 2003-12-19 | 2005-07-07 | Mitsubishi Chemicals Corp | Thermal insulation resin composition and coating and molding using it |
| CN101143981A (en) * | 2007-09-14 | 2008-03-19 | 哈尔滨工业大学 | Powder coating containing aerogel particles and preparing method thereof |
| EP2440321B1 (en) * | 2009-06-11 | 2017-11-22 | Case Western Reserve University | Low density hydrophobic material and method of making the same |
| KR101169522B1 (en) * | 2010-02-27 | 2012-07-27 | 이재환 | Aerogel coating composition |
| WO2011145758A1 (en) * | 2010-05-18 | 2011-11-24 | Kim Chang Sun | Adiabatic insulated diesel engine, and highly efficient generator engine using same |
| JP2012172619A (en) * | 2011-02-23 | 2012-09-10 | Aisin Seiki Co Ltd | Engine and piston |
| KR101414237B1 (en) | 2012-10-11 | 2014-07-01 | 연세대학교 산학협력단 | Response speed enhancing method using data pre-load and terminal device thereof |
-
2014
- 2014-04-18 KR KR1020140046905A patent/KR101566743B1/en active IP Right Grant
- 2014-11-14 US US14/542,274 patent/US20150300215A1/en not_active Abandoned
- 2014-11-18 DE DE102014116837.2A patent/DE102014116837A1/en not_active Ceased
- 2014-11-20 CN CN201410670564.6A patent/CN105038577B/en active Active
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| Publication number | Publication date |
|---|---|
| CN105038577A (en) | 2015-11-11 |
| KR101566743B1 (en) | 2015-11-06 |
| CN105038577B (en) | 2019-01-15 |
| US20150300215A1 (en) | 2015-10-22 |
| DE102014116837A1 (en) | 2015-10-22 |
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