KR20150113672A - Hair cleansing composition - Google Patents

Abstract

The present invention relates to a hair cleansing composition with excellent cleansing power, maintained with softness of hair during rinsing and, specifically, to a hair cleansing composition, with excellent foaming power and soft hair during rinsing while using a cationic polymer with an amount similar to the existing product by controlling a kind and content of various surfactants, and with reduced generation of droopy hair or scalp trouble by reducing the amount of the cationic polymer absorbed in hair.

Description

[0001] Hair cleansing composition [0002]

The present invention relates to a hair cleansing composition which is excellent in cleansing power and maintains the softness of hair during rinsing. By controlling the kinds and contents of various surfactants, it is possible to use a cationic polymer having a similar amount to a conventional product, The present invention relates to a hair cleansing composition which reduces the amount of a cationic polymer adsorbed on hair and reduces hair shedding or scalp trouble during rinsing.

Shampoo is a hair cleansing cosmetic which is used to remove contamination of scalp and hair and to keep hair clean and beautiful. It is easy to combing, softness, smoothness, glossiness, reduction of friction on the surface of hair, prevention of static electricity , Hair protection, and the like.

Wet hair when shampooing usually has negative charge because pH is higher than isoelectric point 3.67. Thus, in general, the shampoo composition can be prepared by adsorbing the cationic polymer to the hair by means of different ionic properties using a cationic polymer with a positive charge, thereby preventing hair tangling through the hair coating and enhancing the volume of the hair Conditioning effect.

However, when the amount of the cationic polymer adsorbed on the hair increases, there is a feeling of sticking to each other and a feeling of being touched, and there is a heavy texture, and there is a hair sagging phenomenon and hair styling is not performed well, . Also, if the residual amount of the cationic polymer in the scalp and hair is increased by repeated use, it may cause scalp trouble.

Accordingly, there is a need for a hair cleansing composition that is capable of exhibiting a conditioning effect while retaining the softness of the hair upon rinsing, while having excellent washing power.

Korean Patent Publication No. 10-2005-0088226 (published on September 2, 2005)

Accordingly, the present inventors have found that, when used together with an anionic surfactant, an amino acid surfactant, and an amphoteric surfactant in which a cationic polymer is appropriately combined, the hair washing power and the softness of hair during rinsing can be maintained, It is possible to reduce the residual amount, and the present invention is completed.

Accordingly, it is an object of the present invention to provide a composition for cleaning hair which has reduced hair adsorption rate of a cationic polymer while maintaining hair washing power and softness.

In order to achieve the above object, the cationic polymer is added in an amount of 0.1 to 1% by weight based on the total weight of the composition; 1 to 20% by weight, based on the total weight of the composition, of an anionic surfactant; 0.1 to 5% by weight, based on the total weight of the composition, of an amino acid-based surfactant; And an amphoteric surfactant in an amount of 0.5 to 10% by weight.

The composition of the present invention is excellent in bubble power and excellent in hair washing power, maintains hair softness upon rinsing, and lowers the hair adsorption rate of the cationic polymer, thereby preventing hair shedding or scalp trouble during prolonged use.

FIG. 1 is a graph showing the results of evaluating hair softness, residual amount of hair of a cationic polymer, and foaming power during rinsing when using the shampoo compositions of Examples 1 to 5 and Comparative Examples 1 to 9.
Fig. 2 is a graph showing the results of measuring the hair frictional force in wet state when using the shampoo compositions of Examples 6 to 11 and Comparative Examples 10 to 13. Fig.
FIG. 3 is a graph showing the results of measurement of the residual amount of hair of the cationic polymer when the shampoo compositions of Examples 6 to 11 and Comparative Examples 10 to 13 were used.
Fig. 4 is a graph showing the foam force evaluation results of the shampoo compositions of Examples 6 to 11 and Comparative Examples 10 to 13. Fig.

The present invention relates to a composition for hair cleansing which is excellent in detergency and maintains hair softness upon rinsing, and includes a cationic polymer together with an anionic surfactant, an amino acid surfactant and an amphoteric surfactant in appropriate combination.

Specifically, the cationic polymer is a substance used to give a conditioning effect after hair washing. When the amount of the cationic polymer in the composition is reduced to reduce the amount of hair remaining, the conditioning effect is lowered. In order to improve the conditioning effect, There is a contradiction that when the amount of the polymer is increased or the polymer having a high degree of cationic substitution is used, the residual amount of hair is increased. In order to solve such a problem, the present invention provides a hair cleansing composition which contains a cationic polymer in the same amount as that of a conventional product, while controlling the type and content of the surfactant, thereby reducing the residual amount of hair of the cationic polymer while maintaining the conditioning effect .

The cationic polymer to be used in the present invention is not particularly limited as long as it is usually used in a hair cleansing composition. Examples of the cationic polymer include polyquaternium-6, polyquaternium-7, polyquaternium-10, poly Quaternium-11, Polyquaternium-24, Polyquaternium-47 and the like; A cationic guar gum derivative and the like can be used. For example, polymers from the company Amerchol Corp. (Edison, NJ), a salt of hydroxyethyl cellulose reacted with a trimethylammonium substituted epoxide, referred to as polyquaternium-10 in the industrial sector (CTFA) (POLYMER) Available in JR, LR, and LK series; (Edison, NJ), a polymeric quaternary ammonium salt of hydroxyethylcellulose reacted with a lauryldimethylammonium-substituted epoxide, referred to in the industry (CTFA) as polyquaternium-24. Cationic cellulose, available from Polymer LM-200, can be used. Also, the cationic guar gum derivatives that can be used in the present invention include, for example, the cationic polygalactomannan gum derivatives described in U.S. Patent No. 4,298,494, which is commercially available under the trade name JAGUAR; A hydroxypropyltrimethylammonium derivative of guar gum (CTFA name, guar hydroxypropyl trimonium chloride) commercially available under the trade names Jaguar C-13S and Jaguar C-17; And Jaguar C-16, a hydroxypropylated cationic guar derivative known as Jaguar LS. Other materials include, but are not limited to, quaternary nitrogen-containing cellulose ethers (such as those described in U.S. Patent No. 3,962,418) and copolymers of ecteine cellulose and starch (such as those described in U.S. Patent No. 3,958,581) . Preferably, the composition of the present invention may use at least one selected from the group consisting of hydroxypropyl guar hydroxypropyl trimonium chloride, polyquaternium-10 and guar hydroxypropyl trimonium chloride as the cationic polymer.

In the composition of the present invention, the cationic polymer is used in an amount of 0.1 to 1% by weight based on the total weight of the composition. If the amount is less than 0.1% by weight, the conditioning effect is insignificant. If the amount is more than 1% by weight, the scalp and hair are worn and the feeling of use is impaired due to heavy texture.

The composition of the present invention uses an anionic surfactant in order to increase the foaming power and to exhibit excellent detergency. The anionic surfactant is not particularly limited as long as it is ordinarily used in a hair cleansing composition, but the following can be used.

(1) Alkylbenzenesulfonates in which the alkyl group has 9 to 15, preferably 11 to 14 carbon atoms in straight or branched chain form. And particularly preferably a linear alkylbenzene sulfonate having an alkyl chain having about 12 carbon atoms.

(2) Alkyl sulfates formed by sulfation of alcohols having 8 to 22 carbon atoms, preferably 12 to 16 carbon atoms. Alkyl sulfates of the formula ROSO ₃ M + - has a (wherein R is a C8-22 alkyl group and M is a monovalent and (or) a divalent cation).

(3) a paraffin sulfonate in which the alkyl moiety has 8 to 22 carbon atoms, preferably 12 to 16 carbon atoms. These surfactants are commercially available as Hostapur SAS from Hoechst Celanese.

(4) olefin sulfonates having 8 to 22 carbon atoms, preferably 12 to 16 carbon atoms. Most preferably sodium, available as Bio burst (Bioterge) AS 40 (trademark) C ₁₄ -C ₁₆ a-olefin sulfonate.

(5) Alkyl ether sulfates derived from alcohols having 8 to 22, preferably 12 to 16 carbon atoms, ethoxylated with less than 30 moles, preferably less than 12 moles of ethylene oxide. Most preferably from 2 moles of average ethoxylation, and is commercially available as Standopol ES-2 (R) from Sodium Lauryl Ether Sulfate.

(6) Alkyl glyceryl ether sulfonate having 8 to 22 carbon atoms, preferably 12 to 16 carbon atoms in the alkyl moiety.

(7) a compound of the formula: R ¹ CH (SO ₃ -M +) CO ₂ R ² wherein R ¹ is about C ₈ to C ₁₈ , preferably C ₁₂ to C ₁₆ linear or branched alkyl, C ₁ to C ₆ , preferably C ₁ straight chain or branched chain alkyl, and M ⁺ represents a 1 or 2 cations cation.

(8) secondary alcohol sulfates having 6 to 18 carbon atoms, preferably 8 to 16 carbon atoms.

(9) Fatty acyl isethionate having a carbon number of 10 to 22, sodium cocoyl isethionate is preferable.

(10) A dialkyl sulfosuccinate having 3 to 20 carbon atoms in the alkyl group.

Preferably, at least one selected from the group consisting of ammonium laureth (3EO) sulfate, ammonium lauryl sulfate, sodium laureth (3EO) sulfate and sodium lauryl sulfate can be used as the anionic surfactant.

In the composition of the present invention, the anionic surfactant is used in an amount of 0.5 to 60% by weight, preferably 0.75 to 40% by weight, more preferably 1 to 20% by weight based on the total weight of the composition. If the amount is less than 0.5% by weight, foam is not sufficiently generated to deteriorate the detergency. If the amount is more than 60% by weight, irritation to the scalp may make the scalp and hair dry overall.

The amino acid surfactant used in the composition of the present invention is a natural anionic surfactant having excellent washing power and little stimulation to scalp or hair. The amino acid surfactant is not particularly limited as long as it is usually used in a hair cleansing composition, but the following can be used.

(1) the formula RCON (CH ₃₎ CH ₂ CH ₂ CO ₂ M (wherein R is a carbon number of about 10 to about 20 alkyl or alkenyl, and M is a water-soluble cation such as ammonium, sodium, potassium and tri alkanol ammonium ≪ / RTI > alkanoyl sarcosinate. Most preferably sodium lauroyl sarcosinate.

(2) a taurate having 8 to 16 carbon atoms, preferably cocoyl methyl taurate.

(3) glycinates having 8 to 16 carbon atoms or glutamate, cocoyl glycinate or cocoyl glutamate.

Preferably, as the amino acid surfactant, sodium lauroyl sarcosinate can be used.

In the composition of the present invention, the amino acid surfactant is used in an amount of 0.1 to 10% by weight based on the total weight of the composition. If the content is less than 0.1% by weight, the effect is insignificant. If the content is more than 5% by weight,

The amphoteric surfactant used in the composition of the present invention is not particularly limited as long as it is ordinarily used in a hair cleansing composition, but includes aliphatic secondary and tertiary amines, preferably nitrogen, The aliphatic radical can be linear or branched and one of the radicals includes an ionizable water-soluble group, such as carboxy, sulfonate, sulfate, phosphate or phosphonate. Examples of materials include, but are not limited to, cocamidopropyl betaine, camphor acetate, cocamphor acetate, camphor propionate, co-camphodipropionate, cocamidopropyl hydroxysultaine, cetyldimethyl betaine, cocamidopropyl PG- Chloride phosphate, cocodimethylcarboxymethylbetaine, cetyldimethylbetaine and mixtures thereof. Preferably, as the amphoteric surfactant, at least one selected from cocidopropyl betaine and sodium citocotate can be used.

In the composition of the present invention, the amphoteric surfactant is used in an amount of 0.1 to 10% by weight based on the total weight of the composition. If the amount is less than 0.1% by weight, the effect is insignificant. If the amount is more than 10% by weight, the feeling of use and hair remaining on the hair are increased.

When the cationic polymer is used only with the amino acid surfactant and the amphoteric surfactant, the softness of the hair during rinsing can be increased, but the amount of residual hair of the cationic polymer is increased. Therefore, in the composition of the present invention, an anionic surfactant is used in combination in order to improve bubble power while controlling such phenomenon. When a cationic polymer and an anionic surfactant form a complex, an electrically neutral coacervate is formed. Such a coacervate is attached to the hair during rinsing to show softness. Further, the amount of hair remaining in the cationic polymer is influenced by the physical properties of the coacervate.

The composition for hair cleansing of the present invention can be specifically formulated by a conventional method known in the art as a shampoo composition.

The hair cleansing composition of the present invention may contain additives conventionally used in the art and may include at least one additive selected from, for example, preservatives, flavors, pH adjusting agents, viscosity controlling agents, moisturizing agents, and bactericides. Such additives may be contained in the range of, for example, 0.001 to 10% by weight, depending on the kind of each additive, based on the total weight of the composition according to the present invention. And the remaining amount is water (such as purified water).

In addition, in addition to the above-mentioned additives, a solvent such as an alcohol or a ketone, a herbal extract, a fruit extract, a vitamin and a pigment may be selectively contained.

The preservative may be selected from the group consisting of p-hydroxybenzoic acid methyl, paraoxybenzoic esters, methylparaben, methylchloroisothiazolinone, methylisothiazolinone, and the like. The perfume can be selected from the group consisting of natural flavors (fruit flavor, herb flavor, ) Or a combination flavor. The pH adjusting agent may be selected from inorganic acids, organic acids and salts thereof, and may be selected from, for example, citric acid, sodium citrate, phosphoric acid, sodium phosphate and sodium phosphate.

The viscosity modifier may be selected from the group consisting of carboxyvinyl polymer, glycols (such as propylene glycol) and oils (including natural oils such as coconut oil, And vegetable oils), and the like. The sterilizing agent may be selected from chlorohexadine, triclosan, sulfur and conazole derivatives.

Hereinafter, the present invention will be described in more detail with reference to Examples and Test Examples. However, the present invention is not limited to these examples and test examples.

[Referential Example 1] Examples 1 to 5 and Comparative Examples 1 to 9 Preparation of a composition

The shampoo compositions of Examples 1 to 5 and Comparative Examples 1 to 9 were prepared using the conventional shampoo manufacturing method (A: cationic polymer, B: anionic surfactant, B ': Amino acid surfactant; C: amphoteric surfactant). However, polyquaternium-10 has higher molecular weight and higher substitution degree than other types of cationic polymers, and thus has a higher amount of cationic hair adhesion to the hair. Therefore, using less amount than other types of cationic polymers A composition was prepared.

Example 1 Example 2 Example 3 Example 4 Example 5 Comparative Example 1 Comparative Example 2 water to 100 to 100 to 100 to 100 to 100 to 100 to 100 A Hydroxypropyl guar hydroxypropyl trimonium chloride
(Jaguar LS, Solvay product) 0.4 - - 0.4 0.4 - - Polyquaternium-10 (high molecular weight)
(Polyquata 3000KC, product of KCI) - 0.3 - - - - 0.3 Guar hydroxypropyltrimonium chloride
(Jaguar C500, Solvay product) - - 0.4 - - 0.3 - B Ammonium laureth (3EO) sulfate 7.5 7.5 7.5 7.5 7.5 7.5 7.5 Ammonium lauryl sulfate 5 5 5 5 - 5 5 Sodium laureth (3EO) sulfate - - - - - - - Sodium lauryl sulfate - - - - - - - B ' Sodium lauroyl sarcosinate
(Miami L-30, Miwon) One 2 2 One 5 - - C Cocamide propyl betaine
(Mitaine (S), Miwon) 2 One 2 - 2 - - Sodium oxycodoacetate
(Miconol CM, Miwon) - - - 2 - - - EDTA-2Na - - - - - - - Sodium citrate - - - - - - -

Comparative Example 3 Comparative Example 4 Comparative Example 5 Comparative Example 6 Comparative Example 7 Comparative Example 8 Comparative Example 9 water to 100 to 100 to 100 to 100 to 100 to 100 to 100 A Hydroxypropyl guar hydroxypropyl trimonium chloride
(Jaguar LS, Solvay product) 0.4 0.4 0.4 - 0.4 - 0.4 Polyquaternium-10 (high molecular weight)
(Polyquata 3000KC, product of KCI) - - - 0.3 - 0.3 - Guar hydroxypropyltrimonium chloride
(Jaguar C500, Solvay product) - - - - - - - B Ammonium laureth (3EO) sulfate 7.5 - 7.5 7.5 - - - Ammonium lauryl sulfate 5 - 5 5 - - - Sodium laureth (3EO) sulfate - 7.5 - - - - - Sodium lauryl sulfate - 5 - - - - - B ' Sodium lauroyl sarcosinate
(Miami L-30, Miwon) - - 5 5 10 10 10 C Cocamide propyl betaine
(Mitaine (S), Miwon) 5 5 - - 5 5 - EDTA-2Na - - - - - - - Sodium citrate - - - - - - -

[Test Example 1]

The feeling of use of the shampoo compositions of Examples 1 to 5 and Comparative Examples 1 to 9 was evaluated in terms of hair softness upon rinsing, residual amount of hair of cationic polymer and bubble strength as shown in Table 3 below.

1) Softness of hair during rinsing

Ten professional panels directly used the shampoo compositions of Examples 1 to 5 and Comparative Examples 1 to 9, and then sensed the softness at the time of rinsing. At this time, one point was set on the basis of Comparative Example 1, and a score of 1 point to 9 points was given to the other composition. The higher the score, the better the conditioning effect.

2) Amount of hair remaining

1 g of the shampoo solution of Examples 1 to 5 and Comparative Examples 1 to 9 and 10 g of lukewarm tap water (30 to 35 ° C) were rubbed for 1 minute on a Wool Swatch (cloth of 5 cm x 5 cm of white wool 100%) and rinsed The red color (a value) was measured using a colorimeter (Chroma meter CR-400, KONICA MINOLTA SENSING INC.) After immersing in a 0.5% solution of Rubin dye for 3 minutes. Rubin dyes are anionic pigments, which are ion-bound to a cationic polymer or cationic polymer-anionic surfactant complex adsorbed on the hair, so that the amount remaining on the hair can be estimated by measuring the degree of dyeing, Which means that the amount of residue adsorbed on the hair is high.

3) Foam force

Ten professional panels directly used the shampoo compositions of Examples 1 to 5 and Comparative Examples 1 to 9, and then subjected to sensory evaluation on bubble power. At this time, 5 points were set on the basis of Comparative Example 1, and scores of 1 to 9 were given to other compositions. The higher the score, the better the bubble power.

The evaluation results are shown in the following Table 3 and FIG. 1 (it is preferable that the evaluation score of hair softness is high, the residual amount of hair is low, and the bubble power score is high in rinsing).

Rinse hair softness 1) Hair remaining amount 2) Bubble power 3) Example 1 8 12 7 Example 2 9 23 6 Example 3 7 10 7 Example 4 8 12 6 Example 5 9 19 4 Comparative Example 1 One 12 5 Comparative Example 2 3 26 5 Comparative Example 3 5 30 6 Comparative Example 4 5 36 4 Comparative Example 5 4 20 3 Comparative Example 6 5 27 3 Comparative Example 7 8 30 2 Comparative Example 8 9 42 2 Comparative Example 9 8 31 2

As shown in Table 3, Examples 1 to 5 and Comparative Examples 7 to 9 were evaluated as having high hair softness upon rinsing. In other words, hair softness was excellent in the presence of cationic polymer, amino acid surfactant, and amphoteric surfactant. Thus, the softness of hair during rinsing was determined by the inclusion of amino acid surfactant and amphoteric surfactant Is an important factor.

However, in Comparative Examples 7 to 9, the residual amount of hair of the cationic polymer was very high. When the content of the amino acid surfactant exceeded the proper amount, the conditioning effect was maintained, but the residual amount of hair of the cationic polymer was increased, .

In comparison between Example 2 and Comparative Example 2 and Example 1 with Comparative Example 3, it is important that all of the anionic surfactant, amino acid surfactant and amphoteric surfactant are present in an appropriate amount together with the cationic polymer And the presence or absence of any one of these components does not help lower the residual amount of hair of the cationic polymer while maintaining the conditioning effect.

[Reference Example 2] Examples 6 to 11 and Comparative Examples 10 to 13

The shampoo compositions of Examples 6 to 11 and Comparative Examples 10 to 13 were prepared using the conventional shampoo manufacturing method (A: cationic polymer, B: anionic surfactant, B ': Amino acid surfactant; C: amphoteric surfactant).

Example 6 Example 7 Example 8 Example 9 Example 10 water to 100 to 100 to 100 to 100 to 100 A Hydroxypropyl guar hydroxypropyl trimonium chloride 0.4 - 0.4 - - Polyquaternium-10 (high molecular weight) - 0.4 - 0.4 - Guar hydroxypropyltrimonium chloride - - - - 0.4 B Ammonium laureth (3EO) sulfate 7.5 7.5 7.5 7.5 7.5 Ammonium lauryl sulfate 5 5 5 5 5 B Sodium lauroyl sarcosinate One One One One One C Cocamide propyl betaine - One One - One Sodium oxycodoacetate One - - One - incense One One One One One Dimethiconol One One One One One Citric acid 0.05 0.05 0.05 0.05 0.05 salt 0.2 0.2 0.2 0.2 0.2 EDTA-2Na 0.05 0.05 0.05 0.05 0.05 Sodium citrate 0.1 0.1 0.1 0.1 0.1

Example 11 Comparative Example 10 Comparative Example 11 Comparative Example 12 Comparative Example 13 water to 100 to 100 to 100 to 100 to 100 A Hydroxypropyl guar hydroxypropyl trimonium chloride - - 0.4 0.4 0.4 Polyquaternium-10 (high molecular weight) - - - - - Guar hydroxypropyltrimonium chloride 0.4 0.4 - - - B Ammonium laureth (3EO) sulfate 7.5 7.5 - 7.5 7.5 Ammonium lauryl sulfate 5 5 - 5 5 B Sodium lauroyl sarcosinate One - 10 - 2 C Cocamide propyl betaine - - 5 2 - Sodium oxycodoacetate One - - - - incense One One One One One Dimethiconol One One One One One Citric acid 0.05 0.05 0.05 0.05 0.05 salt 0.2 0.2 0.2 0.2 0.2 EDTA-2Na 0.05 0.05 0.05 0.05 0.05 Sodium citrate 0.1 0.1 0.1 0.1 0.1

[Test Example 2] Formulation comparison test

The feeling of use of the shampoo compositions of Examples 6 to 11 and Comparative Examples 10 to 13 was evaluated in terms of the hair friction during wetting, the amount of hair remaining in the cationic polymer and the foaming power, as shown in Table 6 below.

1) Wet combing force

Using a combing machine (COMBING TESTER SK-3A, TECHNO-HASHIMOTO), the hair tress was immersed in a 10% aqueous solution of each of the shampoo compositions of Examples 6 to 11 and Comparative Examples 10 to 13 for 3 minutes Thereafter, the tires were combed while spraying water through the shower in both directions from the apparatus, and the value of the friction force (N) applied at that time was measured five times and the average value thereof was determined. The larger the value, the greater the resistance value, indicating that the conditioning effect is low.

2) Amount of hair remaining

1 g of the shampoo solution of Examples 4 and 5 and Comparative Example 9 and 10 g of lukewarm tap water (30 to 35 ° C) were rubbed for 1 minute on a Wool Swatch (cloth of 5 cm x 5 cm of white wool 100%) and rinsed, The red color (a value) was measured using a chromometer (CR-400, KONICA MINOLTA SENSING INC.) By immersing in a 0.5% rubin-dye solution for 3 minutes. Rubin dyes are anionic pigments, which are ion-bound to a cationic polymer or cationic polymer-anionic surfactant complex adsorbed on the hair, so that the amount remaining on the hair can be estimated by measuring the degree of dyeing, Which means that the amount of residue adsorbed on the hair is high.

3) Foam force

SITA foam tester (SITA foam tester R-2000, SITA Msstechnik GmbH). Specifically, 250 ml of a 5% aqueous solution of each of the shampoo compositions of Examples 6 to 11 and Comparative Examples 10 to 13 was stirred at 800 rpm for 20 seconds to prepare a set of 0 to 5 sets, (mm) was measured. The faster and higher the initial bubble generation, the better the foaming power.

The evaluation results are shown in Table 6 and Figs. 2 to 4 below.

Wet friction
(N) Example 6 Example 7 Example 8 Example 9 Example 10 Example 11 Comparative Example 10 Comparative Example 11 Comparative Example 12 Comparative Example 13 Average 0.1975 0.1624 0.2025 0.1823 0.2263 0.2163 0.3525 0.1825 0.3252 0.2529 Integral value 203.1275 197.2635 202.3241 199.3822 211.23 207.82 266.89 189.24 235.27 225.98 Amount of cation polymer adsorbed Example 6 Example 7 Example 8 Example 9 Example 10 Example 11 Comparative Example 10 Comparative Example 11 Comparative Example 12 Comparative Example 13 1 time 13.388 23.574 13.623 25.232 13.393 15.281 12.362 35.232 13.523 12.648 5 times 14.13 27.394 13.823 24.832 14.383 15.921 14.664 37.243 14.263 13.295 10 times 12.526 24.305 13.284 25.234 15.723 16.182 15.844 42.135 14.975 13.97 Bubble force (mm) Example 6 Example 7 Example 8 Example 9 Example 10 Example 11 Comparative Example 10 Comparative Example 11 Comparative Example 12 Comparative Example 13 0 set 0 0 0 0 0 0 0 0 0 0 1 set 572 345.5 562 382 620 615 420 240 556 582 2 sets 682 559.5 682 572 692 682 650 560 674 650 3 sets 712 722.5 710 689 711 691 694 620 693 672 4 sets 724 736 712 729 730 720 696 681 712 673 5 sets, 726 738.5 711 720 729 727 693 683 723 693

As shown in Table 6, it can be seen that Examples 6 to 11 according to the present invention exhibit remarkably low hair-like frictional force during wetting and excellent conditioning effect as compared with Comparative Examples 10, 12 and 13. In particular, the comparison of Example 10, Example 11, and Comparative Example 10 containing the same cationic polymer showed that the amount of cationic polymer adsorbed was comparable to that of the Example, The composition of the present invention may provide a sufficient conditioning effect without increasing the amount of the cationic polymer used.

In Examples 6 to 11, the foamability was also excellent, and it was found that the composition of the present invention was excellent in both cleaning power and conditioning effect.

On the other hand, in the case of Comparative Example 11, which does not include an anionic surfactant, the hair frictional force at the time of wetting is equivalent to that of the Examples, but the amount of hair adsorbed by the cationic polymer is remarkably high, and the use of an amino acid surfactant and an amphoteric surfactant It can be seen that the bubble force is not sufficiently exhibited.

Claims (6)

0.1 to 1% by weight, based on the total weight of the composition, of a cationic polymer;
1 to 20% by weight, based on the total weight of the composition, of an anionic surfactant;
0.1 to 5% by weight, based on the total weight of the composition, of an amino acid-based surfactant; And
And an amphoteric surfactant in an amount of 0.5 to 10% by weight. The hair washing apparatus according to claim 1, wherein the cationic polymer is at least one selected from the group consisting of hydroxypropyl guar hydroxypropyl trimonium chloride, polyquaternium-10, and guar hydroxypropyl trimonium chloride. Composition. The hair according to claim 1, wherein the anionic surfactant is at least one selected from the group consisting of ammonium laureth (3EO) sulfate, ammonium lauryl sulfate, sodium laureth (3EO) sulfate and sodium lauryl sulfate Cleaning composition. The hair cleansing composition according to claim 1, wherein the amino acid surfactant is sodium lauroyl sarcosinate. The hair cleansing composition according to claim 1, wherein the amphoteric surfactant is at least one selected from cocidopropyl betaine and sodium cam camphor acetate. 6. The composition for hair cleaning according to any one of claims 1 to 5, wherein the composition has a reduced amount of hair remaining in the cationic polymer.

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