KR20140114294A - Paving material using carbon nano materials and manufacturing method thereof - Google Patents

Paving material using carbon nano materials and manufacturing method thereof Download PDF

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KR20140114294A
KR20140114294A KR1020140029210A KR20140029210A KR20140114294A KR 20140114294 A KR20140114294 A KR 20140114294A KR 1020140029210 A KR1020140029210 A KR 1020140029210A KR 20140029210 A KR20140029210 A KR 20140029210A KR 20140114294 A KR20140114294 A KR 20140114294A
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South Korea
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carbon
carbon nanomaterial
road
mixture
road pavement
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KR1020140029210A
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Korean (ko)
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이대열
이용희
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이대열
이용희
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    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C7/00Coherent pavings made in situ
    • E01C7/08Coherent pavings made in situ made of road-metal and binders

Abstract

BACKGROUND OF THE INVENTION 1. Field of the Invention [0002] The present invention relates to a method of manufacturing a packaging material such as a road, and more particularly to a road packaging material using carbon nanomaterial and a manufacturing method thereof. The road paving material according to the present invention is characterized by comprising 0.1 to 10 wt% of carbon nanomaterial, 50 to 60 wt% of loess and 10 to 30 wt% of a mixture containing kaolin, 0.1 to 10 wt% of carbon nanomaterial, 99.9 wt% of concrete is bonded with a bonding agent and one or more additives selected from 1 to 10 wt% of ilite, 1 to 10 wt% of wood chips or 1 to 10 wt% Is added. The production of such a road pavement material may be carried out by providing a liquid carbon nanomaterial according to a wet method or providing a powdered carbon nanomaterial in advance by a dry method, Adding the binder, and adjusting the viscosity and color of the mixture. The road pavement material according to the present invention improves the mechanical properties such as abrasion resistance, impact resistance, and vibration proof property of the packaging material by forming a network of net structure by adding carbon nanomaterial to the conventional packaging material, Freezing and snow prevention effect can be expected. Further, by adding ilite to the existing packaging material, far-infrared ray emission and anion generation effect can be expected.

Description

BACKGROUND OF THE INVENTION Field of the Invention [0001] The present invention relates to a road paving material using carbon nano materials,

BACKGROUND OF THE INVENTION 1. Field of the Invention [0002] The present invention relates to a road paving material, and more particularly, to a road paving material using carbon nanomaterial and a method of manufacturing the same.

A carbon nanomaterial is a graphite material having a hexagonal honeycomb structure formed by combining one carbon atom and adjacent carbon atoms, and includes carbon nanotubes, graphene, carbon nanofibers, and fullerene. Among the carbon nanomaterials, the carbon nanotubes have a diameter of usually several to several tens of nanometers and a length of several micrometers to tens of micrometers. It is a hollow cylindrical carbonaceous material with high mechanical strength, heat and electric conductivity, and has a wide specific surface area and is highly applicable as an additive. Fullerene is a spherical carbon nanomaterial with a ratio of major axis and minor axis of 1, and carbon nanofibers are fibrous structures having a diameter 10 times larger than that of carbon nanotubes and filled in the inside. In addition, graphene refers to a single layer of hexagonal crystal structure, and is excellent in transparency, heat, and electrical conductivity. These carbon nanomaterials have excellent electrical, mechanical and thermal properties unique to graphite, and are known as materials that can be used in a wide variety of industrial fields such as composites, coating materials, and electronic materials. However, to be.

On the other hand, ilite is a cloud-type clay mineral widely distributed in marine shale and related sediments, and has excellent ability of heavy metal adsorption and organic decomposition and deodorization. Especially, it has been recognized as a mysterious ore because of its high external extradosity and anion generation, antimicrobial activity and antiviral performance, and many studies for use as a human related product have been made.

Prior arts using such Illight as an architectural and packaging material include an environmentally friendly shore block containing ilite minerals and a method for its production (Korean Patent Application No. 10-2012-0102215), architectural finishing materials using loess, ilite and pine (Korean Patent No. 10-0861403), far-infrared radiation, deodorization, antibacterial air purifying agent (Korean Patent Laid-Open No. 10-2011-0034122), construction using loess and conifer Mullite, bricks and paints (Korean Patent No. 10-0679267) are known. These prior arts have found that the addition of Illight to the production of revetment blocks prevents the contamination of rivers, while activating the composition of vegetation growing on the revetment block, and imparting far-infrared radiation and deodorizing performance. And the like.

Disclosure of Invention Technical Problem [8] Accordingly, the present invention has been made in an effort to solve the problems of the prior art described above, and it is an object of the present invention to provide a novel road pavement material having improved mechanical properties such as abrasion resistance, impact resistance, and vibration resistance, The purpose of the method is to provide.

The gist of the present invention as a means for solving the above-mentioned technical problems is as follows.

(1) A method for producing road pavement material, comprising the steps of: (a) providing a carbon nano material in an amount of 0.1 to 10 wt% based on the total weight of the road pavement material; Preparing a liquid carbon nanomaterial by mixing a dispersant in a vessel with a solvent; And (b) adding 60 to 99.9 wt% of a packing material base material to the liquid carbon nanomaterial with respect to the total weight of the road pavement material, followed by mechanically mixing to produce a mixture.

(2) A method for producing a road paving material, comprising the steps of: (a) providing a carbon nanomaterial in powder form dispersed in advance; And (b) adding 60 to 99.9 wt% of a packing material base material to a carbon nano material in a powder form of 0.1 to 10 wt% with respect to the total weight of the road pavement material, followed by mechanically mixing to prepare a mixture Way.

(3) (c) adding a binder to the mixture; And (d) adjusting the viscosity and hue of the mixture. The method according to (1) or (2) above, further comprising:

(4) The method for producing a road pavement material according to the above (1) or (2), wherein the packaging material base material is 50 to 60 wt% of loess and 10 to 30 wt% of kaolin or 60 to 99.9 wt% .

(5) The method for producing a road pavement according to the above (1), wherein the solvent is selected from distilled water, alcohol, DMF, Methyl ethyl ketone, Way.

(6) The dispersant may be selected from the group consisting of Triton-X, sodium dodecylsulfate (SDS), carboxy methyl cellulose, polyvinyl butyral (PVB), polybutyl acetate (PAB), cellulose acetate butyrate ester (EBA) (1). ≪ / RTI >

(7) The method according to any one of (1) to (2) above, wherein the carbon nanomaterial includes at least one selected from carbon nanotubes, carbon nanofibers, carbon nano horns, fullerenes, carbon fibers, nano- ) ≪ / RTI >

(8) In the step of preparing the mixture, at least one selected from 1 to 10 wt% of one light, 1 to 10 wt% of wood chips or 1 to 10 wt% of a rubber chip is added to the total weight of the road packaging material (1) or (2).

(9) The step of mechanically mixing may include roll milling, ball milling, attrition milling, planetary milling, V mixing, jet milling, (1) or (2), wherein the method is carried out by a method selected from the group consisting of Zet Milling, Strring, and Screw Mixing.

(10) The method for manufacturing a road pavement material according to (1) or (2), wherein the mechanical mixing step is performed at a speed of 10 to 500 RPM for 5 seconds to 360 minutes.

(11) A method for producing a road pavement comprising the steps of (1) or (2), wherein a mixture containing 0.1 to 10 wt% of a carbon nanomaterial and 60 to 99.9 wt% Wherein the road pavement is combined with the road pavement.

(12) The road wrapping material according to (11), wherein the packaging material base material is 50 to 60 wt% of loess and 10 to 30 wt% of kaolin or 60 to 99.9 wt% of concrete.

(13) The road wrapping material according to (11), wherein the viscosity of the mixture is maintained at 100 to 100,000 cP.

(14) The road wrapping material according to (11), wherein the carbon nanomaterial comprises at least one selected from the group consisting of carbon nanotubes, carbon nanofibers, carbon nano horns, fullerenes, nano carbon blacks and graphenes.

(15) At least one selected from the group consisting of 1 to 10 wt% of Ilright, 1 to 10 wt% of wood chips, and 1 to 10 wt% of rubber chips is added to the total weight of the road pavement material (11). ≪ / RTI >

The road pavement material according to the present invention improves the mechanical properties such as abrasion resistance, impact resistance and vibration proofness of the packaging material by forming a net structure network by adding carbon nanomaterial to the existing packing material, and improves the drainage and thermal conductivity It is possible to expect the effect of preventing icing and snowing according to the present invention.

In addition, by adding ilite to the existing packaging material, far-infrared ray emission and anion generation effect can be expected.

1 is a flow chart of a method for manufacturing a road pavement material according to the present invention.
FIG. 2 is a schematic view showing a constituent material of a conventional road pavement material and a road pavement material according to the present invention.
FIGS. 3 and 4 are graphs showing a comparison of wear amounts of conventional road pavement materials and road pavement materials according to the present invention.

Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings. On the other hand, throughout the specification, when an element is referred to as "including" an element, it means that it can include other elements as well, without excluding other elements, unless specifically stated otherwise.

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a flowchart of a method for manufacturing a road pavement material according to the present invention. As shown in FIG. 1, the road pavement material according to the present invention has a structure in which a packing material and a carbon nano material are selected (S100, S200) by mixing them on the basis of loess or concrete, The wet method (S300) and the dry method (S400) can be performed.

On the other hand, regarding the content of the constituents of the road packaging material, the total weight of the road packaging material was used as a basis, and the amount of the solvent used in the wet method was excluded from the content standard since it was mostly removed during the curing process of the packaging material. That is, the content standard was based on the solid content of the road packaging material.

The carbon nanomaterial may include at least one selected from carbon nanotubes, carbon nanofibers, carbon nanohorns, fullerenes, nano-carbon blacks, and graphenes. The base material may be composed of loess and kaolin or may be composed of concrete do. As will be described later, the road pavement material may optionally include one or more additives selected from sunlight, wood chips, rubber chips, and the like.

The wet method (S300) includes a step (S310) of producing a liquid carbon nanomaterial by mixing a carbon nanomaterial and a dispersant in a solvent, a step (S310) of adding a conventional packing material such as loess, kaolin or concrete to the liquid carbon nanomaterial (S320) of adding the binder to the mixture (S330), and adjusting the viscosity and color of the mixture (S500).

The carbon nanomaterial plays a role of improving mechanical properties such as abrasion resistance, impact resistance, and vibration resistance of a road pavement by forming a network of a packaging material, an additive and a net structure on the basis of the base. The carbon nano material has a base on the hydrophobicity and excellent thermal conductivity Thereby improving the water-releasing ability and the warming property of the road wrapping material, thereby giving an effect of preventing icing and snowing. It is preferable that the carbon nanomaterial is added in the range of 0.1 to 10 wt% based on the total weight of the packaging material. If the content is less than 0.1 wt%, the desired effect is not expected. If the content exceeds 10 wt%, the strength of the packaging material is lowered due to the excessive volume of the carbon nanomaterial.

The solvent is not particularly limited and may be selected from distilled water, alcohol, dimethyl formamide (DMF), methyl ethyl ketone (MEK), polyol, or silicone. Dispersants for smooth dispersion of carbon nanomaterials include Triton-X, sodium dodecylsulfate (SDS), carboxy methyl cellulose (CMC), polyvinyl butyral (PVB), polybutyl acetate (PAB), cellulose acetate butyrate ester ) Or CAB (Cellulose acetate butyrate). It is preferable that the dispersant is added in a solvent for smooth dispersion when the dispersion is difficult, such as a carbon nano material, particularly a linear carbon nano material, but in the case of a particulate nano carbon black, a dispersant may not be added. It is preferable that the content of the dispersant added is in the range of 0.5 to 2 times that of the carbon nanomaterial.

As the base material, loess and kaolin emit a large amount of far-infrared rays as main components such as silica (SiO 2 ), alumina (Al 2 O 3 ), iron (Fe), magnesium (Mg), sodium It acts as a promoter. The content of the loess is preferably in the range of 50 to 60 wt%, and the content of the kaolin is in the range of 10 to 30 wt%. The ratio of the proposed loess to kaolin is a ratio derived for the effect of the additive on the basis of the ratio applied to the usual packaging material, and when it is out of the range, it is difficult to realize the desired characteristics. Also, in the case of concrete composed of cement, sand, gravel, etc., the content is preferably 60 to 99.9 wt%, based on the ratio of the general packaging material to the total packaging material.

The road paving material may include at least one additive selected from sunlight, wood chips, rubber chips and the like, if necessary. Illite is added for the purpose of generating far-infrared radiation and anion, and the wood chip plays a role of absorbing and discharging moisture and absorbing shock, and the rubber chip plays a role of keeping warm and absorbing shock. It is preferable that 1 to 10 wt% of ilite and 1 to 10 wt% of each of wood chips and rubber chips are added based on the total weight of the packaging material. The addition ratio of sunlight, wood chips and rubber chips presented is a ratio derived from the function of each additive other than yellow clay and kaolin or concrete applied to ordinary packaging materials. The characteristics become difficult to implement.

The method for performing the step S320 of mechanically mixing the carbon nanomaterial, the loess, the kaolin, or the concrete as the foundation road packing material and the optionally added additives is not particularly limited, and the roll milling, Any of a ball milling, a V mixing, an attrition milling, a planetary milling, a jet milling, a strring, or a screw mixing may be used. Can be performed in a manner selected from one.

It is preferable that the mechanical mixing conditions are controlled within such a range that sufficient dispersion can be achieved within a range in which the carbon nanomaterial is not damaged. In this respect, the mechanical mixing is preferably carried out at a speed of 10 to 500 RPM for 5 seconds to 360 minutes. If the mixing speed or time is excessive, the carbon nanomaterial is damaged and the effect of increasing the wear amount can not be expected. If the mixing speed is too short, the carbon nanomaterial is not sufficiently dispersed and is present in a loose state. I can not.

After the mechanical mixing is completed, a binder is added (S330) to add the additives used in the road pavement. The type of the binder used may be a binding agent usually used in a packaging material, and is not particularly limited in the present invention. The binder content may be added in the range of 0 to 30 wt% based on the total weight ratio of the packaging material depending on the type of the packaging material (orthopedic, amorphous). If it exceeds 30 wt%, the effect of impact absorption, moisture discharge, and warming will be lost due to excessive binder.

Alternatively, the dry method (S400) may include providing carbon nanomaterials of a homogeneous or heterogeneous powder in a pre-dispersed form (S410) instead of preparing a liquid carbon nanomaterial as in the wet method (S300) , A mechanical mixing step (S420) for the mixture as well as a wetting method (S300), and a step of adding a binder (S430). This drying method (S400) is advantageous in that the process is simple and economical as compared with the wet method (S300), but has a disadvantage in terms of dispersion of carbon nanomaterials. In the dry method, the content of the carbon nanomaterial, the loess, kaolin, or concrete as a base material packing material, and the daily light, wood chips, and rubber chips as additives, , 10 to 30 wt.% Of loess, 60 to 99.9 wt.% Of kaolin, 1 to 10 wt.% Of sunlight, 1 to 10 wt.% Of wood chips, wt%, and the rubber chip is in the range of 1 to 10 wt%.

The final mixture prepared through the wet method (S300) or the dry method (S400) may be prepared in the form of a powdery or liquid amorphous packing material (S600) after adjusting the viscosity and color (S500) Or blocks. ≪ / RTI > The viscosity can be controlled by controlling the moisture according to the final shape of the road pavement or the amorphous form of the road pavement, and the pigments can be added if necessary considering the installation environment of the road pavement material. The viscosity is preferably 100 to 100,000 cP. On the other hand, the solvent used in the wet process is mostly removed during the process of adjusting the viscosity or molding the package.

FIG. 2 is a schematic view of the conventional road pavement material and the constituent materials of the road pavement material according to the present invention. As shown in FIG. 2, when compared with a conventional roadway packaging material, the roadway packaging material according to the present invention forms a network of carbon nanomaterials and net structures, including additives such as yellow earth, kaolin or concrete, By fixing the mixed components, the mechanical properties such as abrasion resistance, impact resistance, and vibration resistance of the road pavement are improved. In addition, based on the hydrophobicity and excellent thermal conductivity of the carbon nanomaterial, the water-discharging ability and the warming property of the road pavement material are improved, and the effect of preventing icing and snowing is given.

FIGS. 3 and 4 are graphs showing a comparison of the amount of wear of the conventional road pavement material and the road pavement material according to the present invention. As shown in FIGS. 3 and 4, when carbon nanomaterials are added to road pavement materials according to their real names, the amount of wear is 1/5 of that of conventional road pavement materials, indicating excellent wear resistance. As shown in the schematic diagram of FIG. 2, this is due to the effect of fixing the constituent materials of the packaging material while forming a network of carbon nanomaterials.

Example  One

The results of measuring the amount of wear of the road pavement according to the type of carbon nano material, the effect of addition, and the mixing conditions with respect to the production of the road pavement material according to the present invention are shown in FIG.

With regard to the provision of the carbon nanomaterial, the wet method is a method in which 0.1 to 10 wt% of a homogeneous or heterogeneous carbon nanomaterial is added using distilled water, alcohol, DMF, MEK, polyol or silicon as a solvent, It is added selectively according to the type of nanomaterial. In the case of linear nanomaterials which are difficult to disperse, the liquid nanomaterial is prepared by adding 0.5 to 2 times of the carbon nanomaterial content and the particulate nanocarbon black. Respectively.

Yellow lime, kaolin, ilite, wood chips and rubber chips were added to the prepared liquid carbon nanomaterials and charged into a mechanical mixing apparatus. The mixture was uniformly mixed at 10 to 500 RPM for 5 seconds to 360 minutes. In this case, the components of the mixture are 0.1 to 10 wt% of carbon nanomaterial, 50 to 60 wt% of loess, 10 to 30 wt% of kaolin, 1 to 10 wt% of ILLITE, 1 to 10 wt% 10 wt%.

The dry method relating to the provision of the carbon nanomaterial is a method of dispersing carbon nanomaterials of the same kind or different kinds in advance and then adding loess, kaolin, ilite, wood chips and rubber chips as in the wet method, . In the dry process, the process conditions for mechanical mixing and the component content of the mixture were the same as in the wet process.

For the road packaging material mixture prepared by the wet method and the dry method, the viscosity and the color were adjusted according to the kind of the final product to finally prepare the amorphous and shaped packaging material.

Table 1 shows the results of measurement of wearing amount according to the manufacturing conditions of the manufactured packaging materials.

division Wear amount
(g)
Remarks
Carbon nano
Type of material
Before addition 3.6 - Milling conditions
: 200 RPM
x 60 minutes
Carbon nanotube 0.8 Carbon nanofiber 0.9 Nano Carbon Black 2.8 Grapina 1.0 Carbon nano
Material content
(wt%)
Less than 0.1 2.8
0.1 to 10 0.8 to 3.0 Greater than 10 3.8 Mixing condition
(Mechanical
Milling conditions)
Less than 10 RPM 2.7 Milling time
: 60 minutes
10 to 500 RPM 0.8 to 2.6 Greater than 500 RPM 3.4 Less than 5 seconds 2.8 Milling speed
: 200 RPM
5 seconds to 360 minutes 0.8 to 2.3 Over 360 minutes 2.6

Referring to Table 1, when carbon nanotubes, carbon nanofibers, and graphene except nanocarbon black were added to the types of carbon nanomaterials, the amount of wear was reduced compared to the conventional road wrapping materials regardless of the amount thereof . This is because, in the case of linear carbon nanomaterials, it is easier to form a net structure network than nano carbon black which is spherical particulate.

The addition of carbon nanomaterials showed excellent results in the range of 0.1 to 10 wt%. However, when the amount of carbon nanomaterial was less than 0.1 wt% and 10 wt%, the wear reduction was not observed.

The effect of the mixing condition on the amount of wear was reduced when the number of revolutions was 10 to 500 RPM and the time was 5 seconds to 360 minutes. When the number of revolutions is more than 500 RPM or the time is more than 360 minutes, the carbon nanomaterial is damaged by excessive energy and the wear amount is not reduced. When the number of revolutions is less than 10 RPM or less than 5 seconds, It was confirmed that the effect of reducing the wear amount was not exhibited because it was in a state of being not fully formed.

On the other hand, in the production of the road pavement material, the content of the road packaging material mixture components is 20 wt% of kaolin, 7 wt% of kaolin, 3 wt% of carbon nanomaterial, 5 wt% of wood chips, And the mechanical mixing condition was most preferable when the number of revolutions was 200 RPM and the time was 60 minutes.

Example  2

With respect to the production of road pavement material according to the present invention, the results of measuring the amount of wear of the concrete pavement material according to the kinds of carbon nano materials, the effect of addition and the mixing conditions for application to concrete pavement are shown in FIG. 4 and Table 2 do.

In connection with the provision of the carbon nanomaterial, the concrete alone, the ilite, the wood chip and the rubber chip were selectively added to the liquid carbon nanomaterial produced in the same manner as in Example 1 in the wet method, charged into the mechanical mixing apparatus, 10 to 500 RPM, and 5 seconds to 360 minutes. In this case, the components of the mixture were 0.1 to 10 wt% of carbon nanomaterial, 60 to 99.9 wt% of concrete, 1 to 10 wt% of ilite, 1 to 10 wt% of wood chips, and 1 to 10 wt% of rubber chips.

The drying method related to the provision of the carbon nanomaterial of Example 2 is the same as the method of Example 1, except that the same or different carbon nanomaterials in powder form are dispersed in advance, and then the concrete alone or the wood chips and rubber Chips were selectively added and mechanically mixed. In the dry process, the process conditions for mechanical mixing and the component content of the mixture were the same as in the wet process.

For the road packaging material mixture prepared by the wet method and the dry method, the amorphous and the shaped packaging material were finally prepared by selectively controlling the viscosity and the color depending on the kind of the final product.

Table 2 shows the results of measurement of the wear amount according to the manufacturing conditions of the manufactured packaging materials. The results are the same as those of Example 1.

division Wear amount
(g)
Remarks
Carbon nano
Type of material
Before addition 2.1 - Milling conditions
: 200 RPM
x 60 minutes
Carbon nanotube 0.4 Carbon nanofiber 0.5 Nano Carbon Black 1.9 Grapina 0.6 Carbon nano
Material content
(wt.%)
Less than 0.1 1.9
0.1 to 10 0.4 to 1.8 Greater than 10 2.6 Mixing condition
(Mechanical
Milling conditions)
Less than 10 RPM 1.9 Milling time
: 60 minutes
10 to 500 RPM 0.4 to 1.8 Greater than 500 RPM 1.8 Less than 5 seconds 2.8 Milling speed
: 200 RPM
5 seconds to 360 minutes 0.1 to 1.8 Over 360 minutes 2.1

Referring to Table 2, when carbon nanotubes, carbon nanofibers, and graphenes except nanocarbon black were added to the types of carbon nanomaterials, the amount of wear decreased compared to conventional concrete packaging materials regardless of the amount of carbon nanotubes, carbon nanofibers, and graphene . This is because, in the case of linear carbon nanomaterials, it is easier to form a net structure network than nano carbon black which is spherical particulate.

The addition of carbon nanomaterials showed excellent results in the range of 0.1 to 10 wt%. However, when the amount of carbon nanomaterial was less than 0.1 wt% and 10 wt%, the wear reduction was not observed.

The effect of the mixing condition on the amount of wear was reduced when the number of revolutions was 10 to 500 RPM and the time was 5 seconds to 360 minutes. When the number of revolutions is more than 500 RPM or the time is more than 360 minutes, the carbon nanomaterial is damaged by excessive energy and the wear amount is not reduced. When the number of revolutions is less than 10 RPM or less than 5 seconds, It was confirmed that the effect of reducing the wear amount was not exhibited because it was in a state of being not fully formed.

It is most desirable to mix 2 wt% of 1 light, 1 wt% of carbon nanomaterial and 2 wt% of rubber chips in 95 wt% of concrete, Was most preferable when the number of revolutions was 200 RPM and the time was 60 minutes.

Claims (15)

A method of manufacturing a road pavement material,
(a) 0.1 to 10 wt% of a carbon nanomaterial based on the total weight of the road pavement material, and 0.5 to 2 times of a dispersing agent based on the carbon nanomaterial content according to the kind of the carbon nanomaterial, Producing a material; And
(b) adding 60 to 99.9 wt% of a packing material base material to the liquid carbon nanomaterial with respect to the total weight of the road packaging material, followed by mechanically mixing to prepare a mixture;
The method comprising the steps of:
A method of manufacturing a road pavement material,
(a) providing a pre-dispersed powdered carbon nanomaterial; And
(b) adding 60 to 99.9 wt% of a packing material base material to a carbon nano material in a powder form of 0.1 to 10 wt% based on the total weight of the road pavement material, followed by mechanically mixing to prepare a mixture;
The method comprising the steps of:
3. The method according to claim 1 or 2,
(c) adding a binder to the mixture; And
(d) adjusting the viscosity and color of the mixture;
Further comprising the steps of:
3. The method according to claim 1 or 2,
Wherein the packing material base material is 50 to 60 wt% of loess, 10 to 30 wt% of kaolin, or 60 to 99.9 wt% of concrete.
The method according to claim 1,
Wherein the solvent is selected from distilled water, alcohol, dimethyl formamide (DMF), methyl ethyl ketone (MEK), polyol, or silicone.
The method according to claim 1,
The dispersing agent may be selected from Triton-X, sodium dodecylsulfate (SDS), carboxy methyl cellulose (CMC), polyvinyl butyral (PVB), polybutyl acetate (PAB), cellulose acetate butyrate ester (EBA), or cellulose acetate butyrate Wherein the method comprises the steps of:
3. The method according to claim 1 or 2,
Wherein the carbon nanomaterial comprises at least one selected from carbon nanotubes, carbon nanofibers, carbon nanohorns, fullerenes, carbon fibers, nanocarbon blacks, and graphenes.
3. The method according to claim 1 or 2,
1 to 10 wt% of Ilright, 1 to 10 wt% of wood chips or 1 to 10 wt% of rubber chips is added to the total weight of the roadside wrapper in the step of preparing the mixture By weight.
3. The method according to claim 1 or 2,
The mechanical mixing step may be performed by a roll milling method, a ball milling method, an attrition milling method, a planetary milling method, a V mixing method, a Zet milling method, ), A strring, or a screw mixing. The method for manufacturing a road pavement material according to claim 1,
3. The method according to claim 1 or 2,
Wherein the mechanical mixing step is performed at a speed of 10 to 500 RPM for 5 seconds to 360 minutes.
A road manufactured by the method of claim 1 or claim 2, wherein a mixture comprising 0.1 to 10 wt% of a carbon nanomaterial and 60 to 99.9 wt% Packing material. 12. The method of claim 11,
Wherein the packaging material base material is 50 to 60 wt% of loess, 10 to 30 wt% of kaolin, or 60 to 99.9 wt% of concrete.
12. The method of claim 11,
Wherein the viscosity of the mixture is maintained at 100 to 100,000 cP.
12. The method of claim 11,
Wherein the carbon nanomaterial includes at least one selected from carbon nanotubes, carbon nanofibers, carbon nanohorns, fullerenes, nano carbon blacks, and graphenes.
12. The method of claim 11,
Wherein one or more selected from the group consisting of 1 to 10 wt% of Illite, 1 to 10 wt% of wood chips or 1 to 10 wt% of rubber chips is added to the total weight of the road pavement material .
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CN113793717A (en) * 2021-09-15 2021-12-14 深圳清研皓隆科技有限公司 Graphene/nano carbon black/carbon nano tube composite conductive powder and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
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CN104927730A (en) * 2015-04-30 2015-09-23 宁波墨西科技有限公司 Graphene composite bonding material applied to pavements, graphene composite pavement and preparation method therefor
WO2017142216A1 (en) * 2016-02-18 2017-08-24 주식회사 티에이시스템 Iot-based electric heating system and method using graphene mixture
KR102068927B1 (en) * 2019-04-23 2020-01-21 황정식 Paint composition for ship and aircraft using yellow soil
CN113793717A (en) * 2021-09-15 2021-12-14 深圳清研皓隆科技有限公司 Graphene/nano carbon black/carbon nano tube composite conductive powder and preparation method thereof

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