KR20140083795A - 용접열영향부 인성이 우수한 고강도 오스테나이트계 강재 및 그 제조방법 - Google Patents
용접열영향부 인성이 우수한 고강도 오스테나이트계 강재 및 그 제조방법 Download PDFInfo
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 69
- 239000010959 steel Substances 0.000 title claims abstract description 69
- 238000000034 method Methods 0.000 title claims abstract description 7
- 238000004519 manufacturing process Methods 0.000 title abstract description 12
- 239000000463 material Substances 0.000 claims abstract description 30
- 229910001566 austenite Inorganic materials 0.000 claims abstract description 29
- 239000012535 impurity Substances 0.000 claims abstract description 6
- 238000001816 cooling Methods 0.000 claims description 8
- 238000005098 hot rolling Methods 0.000 claims description 5
- 238000003303 reheating Methods 0.000 claims description 5
- 230000007797 corrosion Effects 0.000 abstract description 11
- 238000005260 corrosion Methods 0.000 abstract description 11
- 239000000203 mixture Substances 0.000 abstract description 9
- 238000001556 precipitation Methods 0.000 abstract description 9
- 238000005275 alloying Methods 0.000 abstract description 2
- 239000011651 chromium Substances 0.000 description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 13
- 229910052799 carbon Inorganic materials 0.000 description 13
- 239000011572 manganese Substances 0.000 description 11
- 229910052804 chromium Inorganic materials 0.000 description 9
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 8
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 8
- 229910052748 manganese Inorganic materials 0.000 description 8
- 229910045601 alloy Inorganic materials 0.000 description 6
- 239000000956 alloy Substances 0.000 description 6
- 229910052796 boron Inorganic materials 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000003466 welding Methods 0.000 description 5
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 150000001247 metal acetylides Chemical class 0.000 description 4
- 238000005096 rolling process Methods 0.000 description 4
- 229910000975 Carbon steel Inorganic materials 0.000 description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 3
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 3
- 238000005065 mining Methods 0.000 description 3
- 229910052750 molybdenum Inorganic materials 0.000 description 3
- 239000011733 molybdenum Substances 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910000617 Mangalloy Inorganic materials 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- 238000004088 simulation Methods 0.000 description 2
- 238000005482 strain hardening Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910000963 austenitic stainless steel Inorganic materials 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910000734 martensite Inorganic materials 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/38—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0205—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips of ferrous alloys
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/20—Ferrous alloys, e.g. steel alloys containing chromium with copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/22—Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/32—Ferrous alloys, e.g. steel alloys containing chromium with boron
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/001—Austenite
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C2202/00—Physical properties
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- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Heat Treatment Of Steel (AREA)
Abstract
본 발명에 따르면, 합금성분 및 조성범위를 효과적으로 제어함으로써, 모재 및 용접부의 오스테나이트 결정립계 안정도를 향상시켜 탄화물의 석출을 제어함으로써 인성을 저하시키는 네트워크 형태의 탄화물 형성이 억제된 용접열영향부 인성이 우수한 고강도 오스테나이트계 강재를 제공할 수 있다.
또한, 상기 오스테나이트계 강재는 Cr 첨가를 통해 내식성을 향상시킴으로써 부식환경에서도 장시간 사용이 가능하다.
Description
도 2는 플럭스코어드아크용접(FCAW)을 이용하여 강재를 용접한 경우의 HAZ부의 열 사이클에 대하여 모사한 것이다.
구분 | 화학조성(중량%) | |||||
C | Mn | Cr | Mo | B | Cu | |
발명예1 | 1.21 | 19.1 | 3.2 | 0.3 | 0.005 | - |
발명예2 | 1.41 | 21.4 | 4.2 | 0.8 | 0.012 | 1.0 |
발명예3 | 1.07 | 16.9 | 2.1 | 0.5 | 0.008 | - |
발명예4 | 1.18 | 17.2 | 1.7 | 0.9 | 0.016 | - |
발명예5 | 1.34 | 20.6 | 3.8 | 0.7 | 0.007 | - |
비교예1 | 1.28 | 19.2 | 2.4 | 0.02 | 0.008 | - |
비교예2 | 1.12 | 17.8 | 3.1 | 0.4 | 0.0002 | - |
구분 | 모재 항복강도 (MPa) |
모재 인장강도 (MPa) |
HAZ 오스테나이트 분율 (체적%) |
HAZ 탄화물 분율 (체적%) |
HAZ 충격인성 (J, @-40℃) |
발명예1 | 531 | 1084 | 94.2 | 5.8 | 143 |
발명예2 | 580 | 1101 | 92.1 | 7.9 | 115 |
발명예3 | 485 | 997 | 98 | 2 | 168 |
발명예4 | 512 | 1035 | 97.3 | 2.7 | 171 |
발명예5 | 568 | 1094 | 93.5 | 6.5 | 104 |
비교예1 | 521 | 1021 | 82.7 | 17.3 | 12 |
비교예2 | 503 | 1002 | 85.2 | 14.8 | 25 |
Claims (6)
- 중량%로, C: 1.0~1.5%, Mn: 15~22%, Cr: 5%이하(0은 제외), Mo: 0.1~1%, B: 0.001~0.02%, 잔부 Fe 및 기타 불가피한 불순물을 포함하고,
용접열영향부의 미세조직이 체적 분율로 90%이상의 오스테나이트를 포함하는 용접열영향부 인성이 우수한 고강도 오스테나이트계 강재. - 청구항 1에 있어서,
상기 강재는 Cu: 2%이하를 추가로 포함하는 용접열영향부 인성이 우수한 고강도 오스테나이트계 강재. - 청구항 1에 있어서,
상기 용접열영향부는 탄화물이 체적 분율로 10%이하로 형성된 용접열영향부 인성이 우수한 고강도 오스테나이트계 강재. - 청구항 1 내지 3 중 어느 한 항에 있어서,
상기 용접열영향부는 -40℃에서의 샤르피 충격값이 50J이상인 용접열영향부 인성이 우수한 고강도 오스테나이트계 강재. - 청구항 1 내지 3 중 어느 한 항에 있어서,
상기 강재는 항복강도가 450MPa이상인 용접열영향부 인성이 우수한 고강도 오스테나이트계 강재. - 중량%로, C: 1.0~1.5%, Mn: 15~22%, Cr: 5%이하(0은 제외), Mo: 0.1~1%, B: 0.001~0.02%, 잔부 Fe 및 기타 불가피한 불순물을 포함하는 강 슬라브를 1050~1120℃에서 재가열하는 단계;
상기 재가열된 강 슬라브를 950℃이상에서 열간 마무리압연하여 열연강재를 얻는 단계; 및
상기 열연강재를 10℃/s이상의 속도로 500℃이하까지 냉각하는 단계를 포함하는 용접열영향부 인성이 우수한 고강도 오스테나이트계 강재의 제조방법.
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KR20120153920A KR101482344B1 (ko) | 2012-12-26 | 2012-12-26 | 용접열영향부 인성이 우수한 고강도 오스테나이트계 강재 및 그 제조방법 |
JP2015550309A JP6140836B2 (ja) | 2012-12-26 | 2013-12-24 | 溶接熱影響部の靭性に優れた高強度オーステナイト系鋼材及びその製造方法 |
US14/758,203 US10041156B2 (en) | 2012-12-26 | 2013-12-24 | High strength austenitic-based steel with remarkable toughness of welding heat-affected zone and preparation method therefor |
PCT/KR2013/012083 WO2014104706A1 (ko) | 2012-12-26 | 2013-12-24 | 용접열영향부 인성이 우수한 고강도 오스테나이트계 강재 및 그 제조방법 |
CN201380068614.7A CN104884661B (zh) | 2012-12-26 | 2013-12-24 | 焊接热影响区韧性优异的高强度奥氏体类钢材及其制备方法 |
EP13867247.2A EP2940173B1 (en) | 2012-12-26 | 2013-12-24 | High strength austenitic-based steel with remarkable toughness of welding heat-affected zone and preparation method therefor |
CA2896534A CA2896534C (en) | 2012-12-26 | 2013-12-24 | High strength austenitic-based steel with remarkable toughness of welding heat-affected zone and preparation method therefor |
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KR101726081B1 (ko) * | 2015-12-04 | 2017-04-12 | 주식회사 포스코 | 저온 충격 인성이 우수한 선재 및 그 제조방법 |
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FR2876708B1 (fr) * | 2004-10-20 | 2006-12-08 | Usinor Sa | Procede de fabrication de toles d'acier austenitique fer-carbone-manganese laminees a froid a hautes caracteristiques mecaniques, resistantes a la corrosion et toles ainsi produites |
KR100742833B1 (ko) * | 2005-12-24 | 2007-07-25 | 주식회사 포스코 | 내식성이 우수한 고 망간 용융도금강판 및 그 제조방법 |
KR100851158B1 (ko) * | 2006-12-27 | 2008-08-08 | 주식회사 포스코 | 충돌특성이 우수한 고망간형 고강도 강판 및 그 제조방법 |
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WO2017095049A1 (ko) * | 2015-12-04 | 2017-06-08 | 주식회사 포스코 | 저온 충격 인성이 우수한 선재 및 그 제조방법 |
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