KR20120097121A - Photo-catalytic microfiber fabric - Google Patents

Photo-catalytic microfiber fabric Download PDF

Info

Publication number
KR20120097121A
KR20120097121A KR1020110016485A KR20110016485A KR20120097121A KR 20120097121 A KR20120097121 A KR 20120097121A KR 1020110016485 A KR1020110016485 A KR 1020110016485A KR 20110016485 A KR20110016485 A KR 20110016485A KR 20120097121 A KR20120097121 A KR 20120097121A
Authority
KR
South Korea
Prior art keywords
resin
mixed
flame retardant
layer
alone
Prior art date
Application number
KR1020110016485A
Other languages
Korean (ko)
Inventor
이혜아
Original Assignee
이혜아
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 이혜아 filed Critical 이혜아
Priority to KR1020110016485A priority Critical patent/KR20120097121A/en
Publication of KR20120097121A publication Critical patent/KR20120097121A/en

Links

Images

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0059—Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/345—Nitriles
    • D06M13/348—Nitriles unsaturated, e.g. acrylonitrile
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
    • D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/16—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with oil varnishes, i.e. drying oil varnishes, preferably linseed-oil-based; factice (sulfurised oils), Turkish birdlime, resinates reacted with drying oils; naphthenic metal salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/30—Flame or heat resistance, fire retardancy properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/06—Properties of the materials having thermal properties
    • D06N2209/067—Flame resistant, fire resistant

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

PURPOSE: A photo-catalyst flame retardant fabric using microfiber is provided to enhance efficiency and to prevent fire development. CONSTITUTION: A photo-catalyst flame retardant fabric using microfiber contains ultra microfiber fabric layer(1); a flame retardant layer(2) containing 10-40 wt% of resin, 20-60 wt% of frame retardant, 5-10 wt% of additives, and 20-60 wt% of organic solvent; and an ink absorption layer(3) containing 10-40 wt% of resin, 10-30 wt% of filler, 5-20 wt% of additive and 20-60 wt% of solvent. The filler is titanium dioxide (TiO2), silica, and titanium dioxide (TiO2), and silica.

Description

초극세사를 이용한 광촉매 방염원단{Photo-catalytic Microfiber Fabric}Photocatalytic Flame Retardant Fabric Using Microfiber {Photo-catalytic Microfiber Fabric}

본 발명은 초극세사를 이용한 광촉매 방염원단에 관한 것으로, 더욱 자세히는 극세사 원단을 광촉매 및 방염화하여, 특히 세척시 그 효과가 우수하고, 사용 시에 화재가 발생했을 경우에 화재의 확산을 방지하고 인명과 재산의 피해를 최소화 하고자 하는 것이다.
The present invention relates to a photocatalyst flame retardant fabric using microfiber, and more particularly, photocatalyst and flame retardant to the microfiber fabric, particularly excellent in the cleaning, and prevents the spread of fire in the event of a fire in use and life saving Minimize damage to property and property.

기존에는 실사용 소재의 표면에 실사 인쇄를 한 후 방염제를 뿌리기도 했으나, 상기의 방법은 확실한 방염효과를 기대할 수 없을 뿐 아니라 오히려 방염제가 코팅층에 손상을 주고 결국 인쇄층에도 손상이 가서 변질되어 장기간 사용할 수 없는 단점이 있었다. In the past, the flame retardant was sprayed after the actual printing on the surface of the actual material, but the above method cannot expect a definite flame retardant effect, but rather the flame retardant damages the coating layer and eventually damages the print layer, resulting in deterioration. There was a disadvantage that can not be used.

실용등록 제0324743호의 잉크젯 실사용 방염 소재는, 원단층과 코팅층을 포함하며 상기 원단층은 방염사로 구성되고 상기 코팅층은 친수성 수지와 흡수 충진제와 계면활성제가 배합되어 구성되는 것으로, 방염사를 사용하여 재직한 원단을 사용하고 방염제를 처리하지 않기 때문에, 실사 코팅액에 들어가는 수지나 첨가제로 인하여 방염효과가 떨어지는 경향이 있으며, 방염사가 고가여서 경제적으로 부담되고, 다양한 소재에 적용하기가 어려운 단점이 있다. Practitioner registration No. 0324743 inkjet practical flame retardant material comprises a fabric layer and a coating layer, the fabric layer is composed of a flame retardant yarn and the coating layer is composed of a hydrophilic resin, absorbent filler and a surfactant is mixed, using a flame retardant yarn Since the fabric is used and does not treat the flame retardant, there is a tendency that the flame retardant effect is lowered due to the resin or additives that enter the actual coating solution, the flame retardant is expensive and economically burdened, it is difficult to apply to various materials.

이에 방염효과가 탁월하고, 악기 등 중요제품을 원활하게 닦을 수 있는 방염원단에 대한 발명이 필요하다.
Therefore, the invention is required for an excellent flame retardant, flame retardant fabric that can wipe the important products such as instruments smoothly.

본 발명은 상기의 문제점을 해결하기 위하여 창안된 것으로, 극세사 직물층(1)을 구성하고, 상기 직물층에 수지로서 아크릴수지, 폴리우레탄수지, 수용성 아크릴수지, PVA수지, 양이온성 수지, EVA 수지, PVC 수지등을 단독 또는 혼합하여 사용하고, 방염제로서 Decabromodiphenyloxide, Decabromodiphenylethane, Antimony trioxide, Antimony pentoxide, Aluminum hydroxide, Hexabromocyclododecane, Urea, Borax(Na2B4O7) 들 중 하나 이상 혼합하여 사용하고, 충진제로서 지당(TiO2), 실리카, 탄산칼슘 등을 단독 또는 혼합하여 사용하여, 각각의 방염제와 잉크흡수제를 구성하고 이를 코팅하여 방염층(2) 상부에 잉크흡수층(3)을 구성한 후, 최종적으로 광촉매 코팅층(4)을 구성함으로서, 발색성과 내구성, 내수성을 향상시키면서, 먼지흡착 및 방염(防炎)의 효과를 극대화하는 원단을 구성하는 것을 본 발명의 목적으로 한다.
The present invention was devised to solve the above problems, and constitutes a microfiber fabric layer (1), wherein the fabric layer is an acrylic resin, polyurethane resin, water-soluble acrylic resin, PVA resin, cationic resin, EVA resin as a resin. , PVC resin or the like alone or mixed, and used as a flame retardant mixed with one or more of Decabromodiphenyloxide, Decabromodiphenylethane, Antimony trioxide, Antimony pentoxide, Aluminum hydroxide, Hexabromocyclododecane, Urea, Borax (Na 2 B 4 O 7 ), As the sugar (TiO 2 ), silica, calcium carbonate, or the like alone or in combination to form a flame retardant and an ink absorber and coating it to form an ink absorbing layer (3) on top of the flame retardant layer (2), and finally By constituting the photocatalyst coating layer 4, it is seen that a fabric which maximizes the effect of dust adsorption and flame retardance while improving color development, durability and water resistance is seen. It is an object of the invention.

본 발명 초극세사를 이용한 광촉매 방염원단을 통하여, 고급악기 및 가구의 먼지 흡착제 등으로 사용될 경우 보다 그 효율성을 높일 수가있고, 화재가 확산되는 것을 방지하고 이로 인한 잠재 피해도 줄일 수 있는 것이 가장 큰 효과이고, 방염제의 사용으로 인해 발생할 수 있는 잉크의 번짐 현상이나 발색성이 저하되는 문제점을 해소하여 그 효과가 큰 발명이라 하겠다.
Through the photocatalyst flame retardant fabric using the microfiber of the present invention, when used as a high-grade instrument and furniture dust adsorbent, it is possible to increase the efficiency more, to prevent the spread of fire and to reduce the potential damage due to this is the greatest effect In order to solve the problem of bleeding or color development of the ink, which may occur due to the use of a flame retardant, the effect is great.

도 1은 본 발명의 확대단면도
■ 도면의 주요부분에 사용된 주요부호의 설명 ■
1 : 극세사 직물층 2 : 방염층 3 : 코팅층 　 1 is an enlarged cross-sectional view of the present invention
■ Explanation of the major symbols used in the main parts of the drawings ■
DESCRIPTION OF SYMBOLS 1 microfiber fabric layer 2 flame resistant layer 3 coating layer

도 1은 본 발명의 확대단면도로서 도면을 참고로 본 발명의 방염원단의 구성을 공정순으로 상세히 설명하고자 한다. 1 is an enlarged cross-sectional view of the present invention with reference to the drawings will be described in detail in the order of the structure of the flame retardant fabric of the present invention.

우선 극세사 섬유 직물을 사용하여 직물층(1)을 구성하고; First constructing the fabric layer 1 using the microfiber fiber fabric;

수지로서 아크릴수지, 폴리우레탄수지, 수용성 아크릴수지, PVA수지, 양이온성 수지, EVA 수지, PVC 수지 등을 단독 또는 혼합하여 10~40wt% 사용하고, 방염제(防炎制)로서 Decabromodiphenyloxide, Decabromodiphenylethane, Antimony trioxide, Antimony pentoxide, Aluminum hydroxide, Hexabromocyclododecane, Urea, Borax(Na2B4O7) 중에서 하나 이상 혼합하여 20~60wt%로 사용하고, 첨가제로서 미네랄오일, 지방산유 등을 단독 또는 혼합하여 5~10wt%로 사용하고, 용제로서 MEK(메틸에틸케톤), Toluene(톨루엔), Methanol(메탄올), 증류수 등을 단독 또는 혼합하여 20~60wt%로 사용하여 구성한 방염제(코팅액)를 사용하여 상기 직물층(1)을 코팅하여 방염층(2)(Flame retardant floor)을 구성하고; As resin, 10 ~ 40wt% of acrylic resin, polyurethane resin, water soluble acrylic resin, PVA resin, cationic resin, EVA resin, PVC resin, etc. are used alone or mixed.Decabromodiphenyloxide, Decabromodiphenylethane, Antimony as flame retardant Trioxide, Antimony pentoxide, Aluminum hydroxide, Hexabromocyclododecane, Urea, Borax (Na 2 B 4 O 7 ) mixed with one or more used at 20 ~ 60wt%, mineral oil, fatty acid oil, etc. alone or mixed as an additive 5 ~ 10wt %, And using the flame retardant (coating solution) composed of 20 to 60wt% of MEK (methyl ethyl ketone), Toluene (toluene), Methanol (methanol), distilled water alone or mixed as a solvent, 1) coating to form a flame retardant floor (2);

수지로서 아크릴수지, 폴리우레탄수지, 수용성 아크릴수지, PVA수지, 양이온성 수지, EVA 수지, PVC 수지 등을 단독 또는 혼합하여 10~40wt% 사용하고, 충진제로서 지당(TiO2), 침강성 실리카, 탄산칼슘 등을 단독 또는 혼합하여 10~30wt% 사용하고, 첨가제로서 미네랄오일, 지방산유, 염료고착제, 형광증백제 등을 단독 또는 혼합하여 5~20wt%로 사용하고, 용제로서 MEK(메틸에틸케톤), Toluene(톨루엔), Methanol(메탄올), 증류수 등을 단독 또는 혼합하여 20~60wt%로 사용하여 구성한 잉크흡수제(코팅액)를 사용하여 상기 방염층(2)을 코팅하여 잉크흡수층(3)을 구성함으로, 3중층의 본 발명의 방염원단을 구성한다. As resin, 10 ~ 40wt% of acrylic resin, polyurethane resin, water soluble acrylic resin, PVA resin, cationic resin, EVA resin, PVC resin, etc. are used alone or mixed, and the filler is TiO 2 , precipitated silica, carbonic acid. 10-30 wt% of calcium or the like is used alone or mixed, and mineral oil, fatty acid oil, dye fixing agent, fluorescent brightener, etc. are used alone or mixed at 5-20 wt%, and MEK (methyl ethyl ketone) is used as a solvent. , Toluene (toluene), Methanol (methanol), distilled water, etc. alone or mixed using an ink absorber (coating liquid) composed of 20 to 60wt% to coat the flame resistant layer (2) to form an ink absorbing layer (3) This constitutes a flame retardant fabric of the present invention in a triple layer.

참고로 위에서 사용되어지는 수지류, 첨가제, 용제들은 소재에 적용할 잉크와 용도에 따라서 선택적으로 사용되어진다.
For reference, the resins, additives, and solvents used above may be selectively used depending on the ink and the application to be applied to the material.

상기의 공정에 의해 본 발명은 도 1의 방염원단의 단면구조도에 도시한 바와 같이, 하단부부터 극세사 직물층(1) - 방염층(2) - 잉크흡수층(3)-광촉매층(4)으로 구성되며, 특히 방염층(2)의 코팅액에 혼합된 방염제에 의해 잉크의 흡수력이 저하되어 잉크가 번질 수 있기 때문에 잉크흡수층(3)을 구성함으로써 직물층 전면(前面)에 잉크 번짐 현상을 방지하고 발색력을 향상시키면서 방염의 효과는 극대화 시킨다.
By the above process, the present invention is composed of a microfiber fabric layer (1)-flame retardant layer (2)-ink absorbing layer (3)-photocatalyst layer (4) from the lower end, as shown in the cross-sectional structure of the flame retardant fabric of Figure 1 In particular, since the absorbing power of the ink is reduced by the flame retardant mixed in the coating solution of the flame retardant layer 2, and the ink may spread, the ink absorbing layer 3 is formed to prevent ink bleeding on the entire surface of the fabric layer and to develop color development power. Maximize the effect of flame retardant while improving.

상기의 공정에 의해 본 발명의 극세사 방염원단을 구성함에 있어, 기본적인 방염효과의 극대화 외에, 방염제를 사용함에도 발색성, 내구성, 내수성이 우수하고 잉크의 번짐 현상이 거의 없는 방염층(2) 및 잉크흡수층(3)코팅제의 구성을 위해서, 하기와 같이 4가지의 혼합비율을 달리한 코팅제제로 코팅회수를 달리하여 방염원단을 제조하고, 발색성, 잉크 번짐 정도 등 여러 가지 물성(物性)을 비교하여 보았다. In constructing the microfiber flame retardant fabric of the present invention by the above process, in addition to maximizing the basic flame retardant effect, the flame retardant layer (2) and the ink absorbing layer excellent in color development, durability, water resistance and little ink bleeding phenomenon even when using a flame retardant (3) For the composition of the coating agent, a flame retardant fabric was prepared by varying the number of coatings with a coating agent having four different mixing ratios as follows, and compared various physical properties such as color development and ink smearing.

실 시 예 1 (단위 : wt %) Example 1 (Unit: wt%) 방염제resist 잉크흡수제Ink absorber 수지Suzy PVC 수지 : 15~25PVC resin: 15 ~ 25 PVC 수지 : 20~25PVC resin: 20 ~ 25 방염제/ 충진제Flame Retardant / Filler Decabromodiphenyloxide : 10~20
Antimony trioxide : 5~10Decabromodiphenyloxide: 10 ~ 20
Antimony trioxide: 5 ~ 10 TiO2 : 3~8
Silica : 2~8 TiO 2 : 3 ~ 8
Silica: 2 ~ 8 첨가제additive 미네랄오일 : 5~10 Mineral oil: 5 ~ 10 미네랄오일 5~10 Mineral oil 5 ~ 10 용제solvent MEK, Toluene, Methanol : 40~60MEK, Toluene, Methanol: 40 ~ 60 MEK, Toluene, Methanol : 40~60 MEK, Toluene, Methanol: 40 ~ 60 기타Etc 5~105 to 10 5~10 5 to 10

실시예 1은, Example 1,

수지로서 PVC 수지를 사용하는데,PVC resin is used as the resin,

방염제는 PVC 수지 15~25wt, 방염제로서 Decabromodiphenyloxide 10~20wt%에 Antimony trioxide 5~10wt% 혼합, 미네랄오일 5~10wt% 첨가하고, 용제로서 MEK(메틸에틸케톤)+Toluene(톨루엔)+Methanol(메탄올)을 40~60wt% 등으로 제조하고, Flame retardant is 15 ~ 25wt of PVC resin, 5 ~ 10wt% of Antimony trioxide mixed with 10 ~ 20wt% of Decabromodiphenyloxide as flame retardant, 5 ~ 10wt% of mineral oil is added, and MEK (methylethylketone) + Toluene (toluene) + Methanol (methanol ) To 40 to 60wt%,

잉크흡수제는 PVC 수지 15~25wt%, 충진제로서 TiO2 3~8wt%에 Silica 2~8w% 혼합, 미네랄오일 5~10wt% 첨가하고, 용제로서 MEK(메틸에틸케톤)+Toluene(톨루엔)+Methanol(메탄올)을 40~60wt% 등으로 제조한다.Ink absorber 15 ~ 25wt% of PVC resin, Silica 2 ~ 8w% mixed with TiO 2 3 ~ 8wt% as filler, add 5 ~ 10wt% of mineral oil, MEK (methyl ethyl ketone) + Toluene (Toluene) + Methanol as solvent (Methanol) to 40 to 60wt%.

또한, 기타 첨가제로는 가소제(可塑劑), UV흡수제, 소포제(消泡劑) 등이 함유된다. 이렇게 구성한 소재는 Solvent-base 잉크에 출력이 가능한 방염원단을 구성한다.
In addition, other additives include a plasticizer, a UV absorber, an antifoaming agent, and the like. This material constitutes a flame retardant fabric that can be printed on solvent-based inks.

실 시 예 2 (단위 : wt %) Example 2 (Unit: wt%) 방염제resist 잉크흡수제Ink absorber 수지Suzy 아크릴수지 : 20~25Acrylic resin: 20 ~ 25 아크릴수지, 폴리우레탄수지 : 25~35 Acrylic resin, polyurethane resin: 25 ~ 35 방염제/ 충진제Flame Retardant / Filler Decabromodiphenyloxide : 25~30
Antimony trioxide : 10~15Decabromodiphenyloxide: 25 ~ 30
Antimony trioxide: 10 ~ 15 Silica : 5~10 Silica: 5 ~ 10 첨가제additive 미네랄오일 : 2~5 Mineral oil: 2 ~ 5 미네랄오일, 지방산유 : 5~10 Mineral oil, fatty acid oil: 5 ~ 10 용제solvent MEK, Toluene, Methanol : 30~40MEK, Toluene, Methanol: 30 ~ 40 MEK, Toluene, Methanol : 40~60 MEK, Toluene, Methanol: 40 ~ 60 기타Etc 1010 --

실시예 2는,Example 2,

방염제의 수지로서는 아크릴수지를 20~25wt% 혼합하고, 다른 제재의 종류는 실시예 1과 동일하게 사용하되 방염제의 첨가량은 늘이고 용제의 첨가량은 줄여서 제조하고,As the resin of the flame retardant, 20-25 wt% of acrylic resin is mixed, and other kinds of materials are used in the same manner as in Example 1, but the amount of flame retardant is increased and the amount of solvent is reduced.

잉크흡수제의 수지로는 아크릴수지와 폴리우레탄수지 25~35wt% 사용하고, 충진제로는 Silica 단독으로 5~10wt%, 첨가제로 미네랄오일과 지방산유를 혼합하여 5~10wt%, 그 외 용제는 실시예 1과 동일하게 혼합하여 제조한다.25 ~ 35wt% of acrylic resin and polyurethane resin are used as resin of ink absorber, 5 ~ 10wt% of Silica alone, 5 ~ 10wt% of mineral oil and fatty acid oil are mixed with additives. It manufactures by mixing similarly to Example 1.

이렇게 구성한 소재는 Water-base Pigment 잉크에 출력이 가능한 방염원단을 구성한다.
This material constitutes a flame retardant fabric that can be printed on water-base pigment ink.

실 시 예 3 (단위 : wt %) Example 3 (Unit: wt%) 방염제 1, 2Flame retardant 1, 2 잉크흡수제Ink absorber 수지Suzy 아크릴수지 : 20~40Acrylic resin: 20 ~ 40 PVC 수지 : 15~25 PVC resin: 15 ~ 25 방염제/ 충진제Flame Retardant / Filler Decabromodiphenyloxide : 20~30
Antimony trioxide : 10~15Decabromodiphenyloxide: 20 ~ 30
Antimony trioxide: 10 ~ 15 TiO2 : 3~8
Silica : 2~8 TiO 2 : 3 ~ 8
Silica: 2 ~ 8 첨가제additive 미네랄오일 : 2~5 Mineral oil: 2 ~ 5 미네랄오일 : 5~10 Mineral oil: 5 ~ 10 용제solvent MEK, Toluene, Methanol : 20~40MEK, Toluene, Methanol: 20 ~ 40 MEK, Toluene, Methanol : 40~60 MEK, Toluene, Methanol: 40 ~ 60 기타Etc 5~105 to 10 5~105 to 10

실시예 3에서, In Example 3,

방염제 1, 2는 혼합 제재의 종류는 실시예 1과 동일하게 하되 아크릴수지의 최대첨가량을 늘리고 대신 용제의 최소첨가량을 줄이는 방법으로 전체 혼합비율을 달리하여 제조하고, 잉크흡수제는 실시예 1의 잉크흡수제와 동일하다
Flame retardants 1 and 2 are prepared in the same manner as in Example 1, but by increasing the maximum amount of acrylic resin and reducing the minimum amount of solvent instead of changing the total mixing ratio, the ink absorber is prepared in Example 1 Same as absorbent

실 시 예 4 (단위 : wt %) Example 4 (Unit: wt%) 방염제 1Flame retardant 1 방염제 2Flame retardant 2 잉크흡수제Ink absorber 수지Suzy 아크릴수지 : 20~40Acrylic resin: 20 ~ 40 아크릴수지 : 20~25Acrylic resin: 20 ~ 25 PVC 수지 : 15~25 PVC resin: 15 ~ 25 방염제/ 충진제Flame Retardant / Filler Decabromodiphenyloxide : 20~30
Antimony trioxide : 10~15Decabromodiphenyloxide: 20 ~ 30
Antimony trioxide: 10 ~ 15 Decabromodiphenyloxide : 25~30
Antimony trioxide : 10~15Decabromodiphenyloxide: 25 ~ 30
Antimony trioxide: 10 ~ 15 TiO2 : 3~8
Silica : 2~8 TiO 2 : 3 ~ 8
Silica: 2 ~ 8 첨가제additive 미네랄오일 : 2~5 Mineral oil: 2 ~ 5 미네랄오일 : 2~5 Mineral oil: 2 ~ 5 미네랄오일 : 5~10 Mineral oil: 5 ~ 10 용제solvent MEK, Toluene, Methanol : 20~40MEK, Toluene, Methanol: 20 ~ 40 MEK, Toluene, Methanol : 30~40MEK, Toluene, Methanol: 30 ~ 40 MEK, Toluene, Methanol : 40~60 MEK, Toluene, Methanol: 40 ~ 60 기타Etc 5~105 to 10 1010 5~105 to 10

실시예 4에서,In Example 4,

방염제 1은 실시예 3의 방염제 1,2와 동일하게 제조하고, 방염제 2는 실시예 2의 방염제와 동일하게 제조하며, 잉크흡수제는 실시예 1의 잉크흡수제와 동일하게 제조한다. Flame retardant 1 is prepared in the same manner as flame retardant 1,2 of Example 3, flame retardant 2 is prepared in the same manner as flame retardant of Example 2, and the ink absorber is prepared in the same manner as the ink absorber of Example 1.

상기 표 1~4까지의 4가지 실시예에 의한 각각의 코팅액을 직물에 나이프코팅(블레이드코팅)법 또는 콤마코팅법을 이용하여 표 5에서와 같은 방법으로 원단에 처리하여 각각의 잉크젯 실사용 방염원단을 제조한다. 이 때 실시예 1, 2에서는 직물지의 전면에만 1차 방염제 코팅과 2차 잉크흡수제코팅을 실시하고, 실시예 3, 4에서는 직물지의 후면에도 방염제 코팅을 실시한다.
Each coating solution according to the four examples of Tables 1 to 4 above was treated to fabric using a knife coating (blade coating) method or a comma coating method on the fabric as shown in Table 5, and each inkjet practical use Manufacture the fabric. At this time, in Examples 1 and 2, the first flame retardant coating and the second ink absorbent coating are applied only to the front surface of the textile paper, and in Examples 3 and 4, the flame retardant coating is also applied to the rear surface of the textile paper.

직물 후면Fabric rear 전면 1차 코팅Front primary coating 전면 2차 코팅Front secondary coating 전면 3차 코팅Front tertiary coating 실시예Example 1 One ?? 방염제resist 잉크흡수제Ink absorber ?? 실시예Example 2 2 ?? 방염제resist 잉크흡수제Ink absorber ?? 실시예Example 3 3 방염제 1Flame retardant 1 방염제 2Flame retardant 2 잉크흡수제Ink absorber ?? 실시예Example 4 4 방염제 1Flame retardant 1 방염제 2Flame retardant 2 잉크흡수제Ink absorber ??

실시예 1~4에 의해 달리 제조한 4가지 방염원단에 대해서 표 6에서와 같이 4가지 물성(物性)검사를 실시하여 그 결과를 좋은 점수에서 낮은 점수까지 우수 〉양호 〉나쁨 및, 거의 없음 〉 약간 있음 〉 다소 있음 으로 표기하였다.
Four physical property tests were performed on four different fabrics prepared differently according to Examples 1 to 4 as shown in Table 6, and the results were excellent from good to low scores. Slightly present> Somewhat present.

발색성Color development 잉크 번짐Ink smear 내구성durability 내수성Water resistance 실시예Example 1 One 우수Great 거의 없음Almost none 우수Great 우수Great 실시예Example 2 2 양호Good 약간 있음Has a little 양호Good 양호Good 실시예Example 3 3 우수Great 거의 없음Almost none 우수Great 양호Good 실시예Example 4 4 양호Good 다소 있음Somewhat 양호Good 양호Good

결과적으로, 실시예 1의 경우가 발색성, 잉크 번짐, 내구성, 내수성에서 모두 최고 점수가 나와 가장 결과가 좋았고, 그 다음으로 실시예 3, 실시예 2, 실시예 4 순으로 드러났다.As a result, the case of Example 1 showed the highest score in all of color development, ink bleeding, durability, and water resistance, and the best result was shown, followed by Example 3, Example 2, and Example 4.

이에 방염효과를 극대화 하면서도 발색성과 잉크 번짐, 내구성, 내수성의 효과를 높이기 위해서, 코팅법에 있어서 직물층(1)의 후면까지 코팅하지 않아도 되며, 방염제, 충진제, 첨가제 등의 혼합비율을 과도하게 높이지 않아도 되는 것을 확인할 수 있으며, 실시예1의 경우가 방염원단으로서의 우수한 품질을 나타냈으나 본 발명의 범위 내에서 방염층(2), 잉크흡수층(3)을 응용하여 구성할 수 있다.Therefore, in order to maximize the flame retardant effect and to enhance the effects of color development, ink bleeding, durability and water resistance, it is not necessary to coat the back of the fabric layer 1 in the coating method, and excessively increase the mixing ratio of the flame retardant, filler, and additives. In the case of Example 1, the excellent quality as a flame retardant fabric was shown, but the flame retardant layer 2 and the ink absorbing layer 3 can be applied within the scope of the present invention.

상기 잉크흡수층(3) 다음으로 광촉매층(4)을 구성하게 되는데 광촉매층은 통상의 광촉매 물질을 스프레이 또는 침전방식을 이용하여 광촉매층(4)를 구성하게 된다. 따라서, 본 발명을 고급 악기 또는 가구의 먼지 제거 등의 도구로 사용될 경우 세균번식등을 억제하여 보관상의 이로움을 배가 할수 있는 것이다.
Next to the ink absorbing layer 3, a photocatalyst layer 4 is formed. The photocatalytic layer forms a photocatalyst layer 4 by spraying or depositing a conventional photocatalyst material. Therefore, when the present invention is used as a tool for removing dust of high-quality musical instruments or furniture, it is possible to double the benefits of storage by suppressing bacterial propagation.

Claims (2)

방염원단에 있어서,
극세사 직물층(1)과;
수지로서 아크릴수지, 폴리우레탄수지, 수용성 아크릴수지, PVA수지, 양이온성 수지, EVA 수지, PVC 수지 등을 단독 또는 혼합하여 10~40wt% 사용하고, 방염제(防炎制)로서 Decabromodiphenyloxide, Decabromodiphenylethane, Antimony trioxide, Antimony pentoxide, Aluminum hydroxide, Hexabromocyclododecane, Urea, Borax(Na2B4O7) 중에서 하나 이상 혼합하여 20~60wt%로 사용하고, 첨가제로서 미네랄오일, 지방산유 등을 단독 또는 혼합하여 5~10wt%로 사용하고, 유기용제로서 MEK(메틸에틸케톤), Toluene(톨루엔), Methanol(메탄올) 등을 단독 또는 혼합하여 20~60wt%로 혼합 구성한 방염제로 코팅한 방염층(2)과;
상기 방염층에 수지로서 아크릴수지, 폴리우레탄수지, 수용성 아크릴수지, PVA수지, 양이온성 수지, EVA 수지, PVC 수지 등을 단독 또는 혼합하여 10~40wt% 사용하고, 충진제로서 지당(TiO2), 침강성 실리카, 탄산칼슘 등을 단독 또는 혼합하여 10~30wt% 사용하고, 첨가제로서 미네랄오일, 지방산유, 염료고착제, 형광증백제 등을 단독 또는 혼합하여 5~20wt%로 사용하고, 용제로서 MEK(메틸에틸케톤), Toluene(톨루엔), Methanol(메탄올), 증류수 등을 단독 또는 혼합하여 20~60wt%로 사용하여 구성한 잉크흡수층(3)과;
상기 잉크흡수층(3)에 광촉매층(4)을 구성하여 4중층으로 구성되는 것을 포함하는
초극세사를 이용한 광촉매 방염원단
In flame retardant fabric,
Microfiber fabric layer 1;
As resin, 10 ~ 40wt% of acrylic resin, polyurethane resin, water soluble acrylic resin, PVA resin, cationic resin, EVA resin, PVC resin, etc. are used alone or mixed.Decabromodiphenyloxide, Decabromodiphenylethane, Antimony as flame retardant Trioxide, Antimony pentoxide, Aluminum hydroxide, Hexabromocyclododecane, Urea, Borax (Na 2 B 4 O 7 ) mixed with one or more used at 20 ~ 60wt%, mineral oil, fatty acid oil, etc. alone or mixed as an additive 5 ~ 10wt A flame retardant layer (2) coated with a flame retardant used in% and mixed with 20 to 60 wt% of an organic solvent alone or mixed with MEK (methyl ethyl ketone), Toluene (toluene), Methanol (methanol) and the like;
Acrylic resin, polyurethane resin, water-soluble acrylic resin, PVA resin, cationic resin, EVA resin, PVC resin and the like are used alone or mixed in the flame retardant layer, and 10 to 40 wt% is used as fat filler (TiO 2 ), 10-30 wt% of precipitated silica, calcium carbonate, or the like alone or mixed, and 5 to 20 wt% of mineral oil, fatty acid oil, dye fixing agent, optical brightener, etc., alone or mixed, and MEK (solvent) as solvent An ink absorbing layer (3) composed of 20 to 60 wt% of methyl ethyl ketone), Toluene (toluene), Methanol (methanol), distilled water or the like alone or mixed;
Comprising a photocatalyst layer 4 to the ink absorbing layer 3 comprises a quadruple layer
Photocatalyst Flame Retardant Fabric Using Microfiber
극세사 직물층(1)을 구성하고;
수지로서 아크릴수지, 폴리우레탄수지, 수용성 아크릴수지, PVA수지, 양이온성 수지, EVA 수지, PVC 수지 등을 단독 또는 혼합하여 10~40wt% 사용하고, 방염제(防炎制)로서 Decabromodiphenyloxide, Decabromodiphenylethane, Antimony trioxide, Antimony pentoxide, Aluminum hydroxide, Hexabromocyclododecane, Urea, Borax(Na2B4O7) 중에서 하나 이상 혼합하여 20~60wt%로 사용하고, 첨가제로서 미네랄오일, 지방산유 등을 단독 또는 혼합하여 5~10wt%로 사용하고, 유기용제로서 MEK(메틸에틸케톤), Toluene(톨루엔), Methanol(메탄올) 등을 단독 또는 혼합하여 20~60wt%로 사용하여 구성한 방염제(코팅액)를 사용하여 상기 직물층(1)을 코팅하여 방염층(2)(Flame retardant floor)을 구성하고;
수지로서 아크릴수지, 폴리우레탄수지, 수용성 아크릴수지, PVA수지, 양이온성 수지, EVA 수지, PVC 수지 등을 단독 또는 혼합하여 10~40wt% 사용하고, 충진제로서 지당(TiO2), 침강성 실리카, 탄산칼슘 등을 단독 또는 혼합하여 10~30wt% 사용하고, 첨가제로서 미네랄오일, 지방산유, 염료고착제, 형광증백제 등을 단독 또는 혼합하여 5~20wt%로 사용하고, 용제로서 MEK(메틸에틸케톤), Toluene(톨루엔),
Methanol(메탄올), 증류수 등을 단독 또는 혼합하여 20~60wt%로 사용하여 구성한 잉크흡수제(코팅액)를 사용하여 상기 방염층(2)을 코팅하여 잉크흡수층(3)을 구성한 후, 최종적으로 광촉매층(4)을 구성한 4중층으로 구성하는 것을 포함하는 초극세사를 이용한 광촉매 방염원단Constitute a microfiber fabric layer 1;
As resin, 10 ~ 40wt% of acrylic resin, polyurethane resin, water soluble acrylic resin, PVA resin, cationic resin, EVA resin, PVC resin, etc. are used alone or mixed.Decabromodiphenyloxide, Decabromodiphenylethane, Antimony as flame retardant Trioxide, Antimony pentoxide, Aluminum hydroxide, Hexabromocyclododecane, Urea, Borax (Na 2 B 4 O 7 ) mixed with one or more used at 20 ~ 60wt%, mineral oil, fatty acid oil, etc. alone or mixed as an additive 5 ~ 10wt %, And using the flame retardant (coating solution) composed of 20% to 60wt% of MEK (methyl ethyl ketone), Toluene (toluene), Methanol (methanol), etc. alone or mixed as an organic solvent (1) ) To form a flame retardant floor (2);
As resin, 10 ~ 40wt% of acrylic resin, polyurethane resin, water soluble acrylic resin, PVA resin, cationic resin, EVA resin, PVC resin, etc. are used alone or mixed, and the filler is TiO 2 , precipitated silica, carbonic acid. 10-30 wt% of calcium or the like is used alone or mixed, and mineral oil, fatty acid oil, dye fixing agent, fluorescent brightener, etc. are used alone or mixed at 5-20 wt%, and MEK (methyl ethyl ketone) is used as a solvent. , Toluene,
Methanol (methanol), distilled water, etc. alone or mixed using an ink absorber (coating solution) composed of 20 to 60wt%, and then the coating layer (2) to form an ink absorption layer (3), and finally a photocatalyst layer Photocatalyst flame retardant fabric using ultra-microfibers comprising four layers comprising (4)
KR1020110016485A 2011-02-24 2011-02-24 Photo-catalytic microfiber fabric KR20120097121A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1020110016485A KR20120097121A (en) 2011-02-24 2011-02-24 Photo-catalytic microfiber fabric

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020110016485A KR20120097121A (en) 2011-02-24 2011-02-24 Photo-catalytic microfiber fabric

Publications (1)

Publication Number Publication Date
KR20120097121A true KR20120097121A (en) 2012-09-03

Family

ID=47108528

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020110016485A KR20120097121A (en) 2011-02-24 2011-02-24 Photo-catalytic microfiber fabric

Country Status (1)

Country Link
KR (1) KR20120097121A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101443975B1 (en) * 2012-11-12 2014-11-03 김효석 printing textile manufacture method and printing textile
WO2016195248A1 (en) * 2015-06-05 2016-12-08 Gllepe Co., Ltd. Fluorescent flex sheet and method of manufacturing the same
CN108658387A (en) * 2018-06-06 2018-10-16 浙江理工大学 A kind of photocatalysis-microbial degradation unified water treating apparatus and method
CN111021077A (en) * 2019-12-31 2020-04-17 南通耐力纺织科技有限公司 Textile fabric coating with good flame retardant property
KR102278824B1 (en) * 2020-11-30 2021-07-20 주식회사 덕성 Manufacturing method of eco-friendly cloths using non-halogen flame retardant component and Cloths thereby

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101443975B1 (en) * 2012-11-12 2014-11-03 김효석 printing textile manufacture method and printing textile
WO2016195248A1 (en) * 2015-06-05 2016-12-08 Gllepe Co., Ltd. Fluorescent flex sheet and method of manufacturing the same
CN108658387A (en) * 2018-06-06 2018-10-16 浙江理工大学 A kind of photocatalysis-microbial degradation unified water treating apparatus and method
CN111021077A (en) * 2019-12-31 2020-04-17 南通耐力纺织科技有限公司 Textile fabric coating with good flame retardant property
KR102278824B1 (en) * 2020-11-30 2021-07-20 주식회사 덕성 Manufacturing method of eco-friendly cloths using non-halogen flame retardant component and Cloths thereby

Similar Documents

Publication Publication Date Title
KR20120097121A (en) Photo-catalytic microfiber fabric
EP3689631B1 (en) Method for forming image and ink set
KR100743107B1 (en) The retardant fabrics for real pictures in ink-jet
JP2017144628A (en) Recording method
CN101921521A (en) Nano-titanium water-based coating having long-acting resistance to formaldehyde
JP2013095078A (en) Ink jet recording method
US9322130B2 (en) Textile fabric sheet having stain and liquid resistance and the preparation method thereof
EP2923850B1 (en) Recording method
CN102275368A (en) Fireproof inkjet type light box cloth and production method thereof
CN1196600C (en) Ink-jet printable macroporous material
JP2016210838A (en) Aqueous inkjet ink for humidity conditioning base material, and method for producing decorated humidity conditioning base material
CN107236396A (en) A kind of water-base ink prints the pretreatment liquid of artificial leather
KR200408418Y1 (en) The retardant fabrics for real pictures in ink-jet
KR20090054289A (en) Photo-catalytic microfiber fabric
KR101004170B1 (en) About formation plotter output fabric high efficient one coating system
JP3969255B2 (en) Inkjet recording paper for water-based dye ink
WO2020181792A1 (en) Coated cardboard suitable for high-speed ink-jet printing and preparation method therefor
JP6600483B2 (en) Water-based inkjet ink for humidity control substrate and method for producing decorated humidity control substrate
KR20070032161A (en) The ribbon fabrics for both printer ink and chinese ink
KR100794908B1 (en) A textile
JP6160748B2 (en) Inkjet recording method
CN106626860B (en) A kind of semi-transparent polishing sheet of cuticula and preparation method thereof
JP2013049813A (en) Method of manufacturing decorative building material, and decorative building material
JP7288357B2 (en) Ink set, laminate, method for producing laminate, and recording method
CN206308889U (en) A kind of uvioresistant self-cleaning type curtain wall aluminium plate

Legal Events

Date Code Title Description
WITN Withdrawal due to no request for examination