KR20120092349A - The paint for prevention dew condensation and method producting thereof - Google Patents
The paint for prevention dew condensation and method producting thereof Download PDFInfo
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- KR20120092349A KR20120092349A KR1020110012346A KR20110012346A KR20120092349A KR 20120092349 A KR20120092349 A KR 20120092349A KR 1020110012346 A KR1020110012346 A KR 1020110012346A KR 20110012346 A KR20110012346 A KR 20110012346A KR 20120092349 A KR20120092349 A KR 20120092349A
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- condensation
- imogolite
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- 239000003973 paint Substances 0.000 title claims abstract description 37
- 238000009833 condensation Methods 0.000 title claims description 35
- 230000005494 condensation Effects 0.000 title claims description 17
- 238000000034 method Methods 0.000 title claims description 17
- 230000002265 prevention Effects 0.000 title claims description 7
- IKNAJTLCCWPIQD-UHFFFAOYSA-K cerium(3+);lanthanum(3+);neodymium(3+);oxygen(2-);phosphate Chemical compound [O-2].[La+3].[Ce+3].[Nd+3].[O-]P([O-])([O-])=O IKNAJTLCCWPIQD-UHFFFAOYSA-K 0.000 claims abstract description 25
- 229910052590 monazite Inorganic materials 0.000 claims abstract description 25
- 239000001023 inorganic pigment Substances 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- 239000002270 dispersing agent Substances 0.000 claims abstract description 10
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 9
- 239000000839 emulsion Substances 0.000 claims abstract description 9
- 239000011347 resin Substances 0.000 claims abstract description 9
- 229920005989 resin Polymers 0.000 claims abstract description 9
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910003452 thorium oxide Inorganic materials 0.000 claims abstract description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims description 27
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims description 25
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 24
- 239000000463 material Substances 0.000 claims description 18
- 241000723353 Chrysanthemum Species 0.000 claims description 17
- 235000007516 Chrysanthemum Nutrition 0.000 claims description 17
- 238000004519 manufacturing process Methods 0.000 claims description 16
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 14
- 239000002562 thickening agent Substances 0.000 claims description 9
- 239000007864 aqueous solution Substances 0.000 claims description 8
- 239000011259 mixed solution Substances 0.000 claims description 8
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 7
- 239000004599 antimicrobial Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 230000008021 deposition Effects 0.000 claims description 2
- 239000008187 granular material Substances 0.000 claims 2
- 238000010521 absorption reaction Methods 0.000 abstract description 3
- 230000008014 freezing Effects 0.000 abstract 1
- 238000007710 freezing Methods 0.000 abstract 1
- 238000009413 insulation Methods 0.000 description 10
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 239000012774 insulation material Substances 0.000 description 5
- 239000000919 ceramic Substances 0.000 description 4
- 238000011033 desalting Methods 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 239000003242 anti bacterial agent Substances 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004794 expanded polystyrene Substances 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000011491 glass wool Substances 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
- E04B1/76—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
- E04B1/78—Heat insulating elements
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A30/00—Adapting or protecting infrastructure or their operation
- Y02A30/24—Structural elements or technologies for improving thermal insulation
- Y02A30/244—Structural elements or technologies for improving thermal insulation using natural or recycled building materials, e.g. straw, wool, clay or used tires
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- Engineering & Computer Science (AREA)
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- Architecture (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Plant Pathology (AREA)
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- Acoustics & Sound (AREA)
- Electromagnetism (AREA)
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- Structural Engineering (AREA)
- Paints Or Removers (AREA)
Abstract
Description
본 발명은 결로방지 페인트 및 그 제조방법에 관한 것이며, 더욱 상세하게는 나노 크기의 다공성 이모골라이트(imogolite)의 흡습성과 통기성을 이용하여 피도체 표면에서 대기 중의 습기를 흡수하여 결로점에서 표면 결로를 억제하고, 평상시에는 함유한 습기를 방출하는 결로방지 페인트 및 그 제조방법에 관한 것이다.The present invention relates to an anti-condensation paint and a method for manufacturing the same, and more particularly, by absorbing moisture in the atmosphere on the surface of a subject by using hygroscopicity and breathability of nano-sized porous imogolite. The present invention relates to a condensation preventing paint and a method of manufacturing the same, which suppresses the amount of moisture and usually releases moisture contained therein.
일반적으로 건축구조물에서는 외부의 기후조건에 영향을 받지 않고 가능한 실내의 온도를 일정하게 유지하기 위해 여러 가지의 단열재를 사용하고 있다. 그러나 이러한 단열재의 사용에도 불구하고 건축물 내외부의 온도차에 의한 열 손실율이 높아 에너지 낭비의 큰 요인이 되고 있다.In general, building structures use a variety of insulation materials to keep the room temperature as constant as possible without being affected by external weather conditions. However, despite the use of such insulation, the heat loss rate due to the temperature difference between the inside and outside of the building is high, which is a large factor of energy waste.
따라서 실내공기의 습도 조절을 위해 습기를 실외로 방출시키거나 제습기를 설치하는 방법을 사용하고 있으나 실내공기와 콘크리트 벽의 온도차이로 인해 결로가 생성되어 해결책이 되지 못하기 때문에 단열로 인하여 결로를 억제하고자 하였다.Therefore, in order to control the humidity of indoor air, moisture is released to the outside or a dehumidifier is installed.However, condensation is generated due to the temperature difference between the indoor air and the concrete wall. Was intended.
기존의 건축물에는 외부와의 열전도를 차단하기 위하여 일반적으로 발포폴리스티렌, 글래스울, 석면 등과 같은 단열재를 사용하고 있으며, 건축물 외부에는 미관을 고려하여 수성도료를 각각 별도의 목적으로 사용한다.Existing buildings generally use thermal insulation materials such as expanded polystyrene, glass wool, asbestos, etc. to block heat conduction from the outside, and water-based paints are used for separate purposes in consideration of aesthetics on the exterior of the building.
그러나 기존 단열재만으로는 열차단 효과가 확실하지 못하여 냉난방시 에너지 활용효율이 높지 못하며, 기존 단열재의 사용시 단열 및 결로방지 효과를 더 높이기 위해서는 단열재의 두께가 두꺼워져야 하고, 또한 단열소재를 사용함에 있어서 소재특성에 따른 제한조건이 있으며, 단열재의 두께에 비례하여 벽체의 두께가 두꺼워져 건축물의 실제 사용면적이 감소하며 건축비용의 상승이 불가피했다.However, the thermal insulation effect is not certain with the existing insulation alone, so the energy utilization efficiency is not high when cooling and heating.In order to increase the insulation and condensation prevention effect when using the existing insulation, the thickness of the insulation must be thick and the material characteristics in using the insulation material. In addition, the thickness of the wall is thickened in proportion to the thickness of the insulation, so that the actual use area of the building is reduced and the construction cost is inevitable.
따라서 열을 방사, 방출하는 특수 성질을 지닌 세라믹 단열재료를 도료에 첨가하여 건축물의 단열 및 결로 방지 효과를 최대한 부여하고자 개발된 도료인 단열페인트가 개발되었으며, 유류저장탱크 등과 같이 안전상의 이유로 외부의 열을 차폐할 필요성이 있는 분야는 물론, 결로현상을 방지하고 에너지 효율을 높이기 위하여 일반 주택이나 아파트의 외벽 등에도 사용되고 있다.Therefore, an insulating paint, a paint developed to give the maximum insulation and condensation prevention effect of buildings by adding ceramic insulation materials with special properties to radiate and radiate heat, was developed.For safety reasons, such as oil storage tanks, In addition to the field that needs to shield the heat, in order to prevent condensation and increase the energy efficiency, it is used in the exterior walls of ordinary houses or apartments.
단열 페인트는 SiO2와 Al2O3를 주성분으로 하는 세라믹 분말과 탄산칼슘을 페인트에 혼합한 페인트(대한민국 등록특허 제 10-0500601호)가 주로 사용되었고, 또한 에어로겔을 이용하여 단열효과를 시도하는 페인트(대한민국 공개특허 제 10-2010-0085472호)가 공개되었다. As the heat insulating paint, ceramic powder mainly composed of SiO 2 and Al 2 O 3 and paints mixed with calcium carbonate (Korean Patent No. 10-0500601) were mainly used. Paint (Korean Patent Publication No. 10-2010-0085472) has been published.
하지만 이러한 종래의 페인트는 세라믹 및 무기안료분말을 페인트에 고르게 분산시키기 어려울 뿐만 아니라, 페인트를 장기간 방치하는 경우 세라믹 분말이 침강되는 문제가 있다. 또한 에어로겔은 단가가 비싸고 취급이 용이하지 않으므로 그 사용이 매우 제한적이다.However, such a conventional paint is not only difficult to evenly disperse the ceramic and inorganic pigment powder in the paint, there is a problem that the ceramic powder is settled when the paint is left for a long time. In addition, since airgel is expensive and not easy to handle, its use is very limited.
또한 종래의 결로 방지법은 원인이 되는 대기 중 수분 흡수보다는 단열효과에 기인하여 결로를 방지하는 것으로 근본적인 결로 방지가 되지 못하고 있는 실정이다.In addition, the conventional condensation prevention method is to prevent the dew condensation due to the insulation effect rather than the moisture absorption in the air as a cause is not the fundamental condensation prevention.
본 발명은 상기한 바와 같은 종래의 문제점을 해결하기 위한 것으로, 본 발명의 목적은 내수성 및 통기성이 우수한 에멀젼 수지와 흡습성이 뛰어난 안료 및 이모골라이트를 사용하여 시공도막 두께 1㎜이하의 시공으로도 피도체 표면에서 대기 중의 습기를 흡수하여 결로점에서 표면결로를 억제하고, 평상시에는 함유한 습기를 방출하는 기능을 반복하는 형태의 도막성능을 가진 수성도료 제조기술과 음이온 및 항균작용이 동시에 구현되는 결로방지 페인트 및 그의 제조방법을 제공하는 것이다.The present invention is to solve the conventional problems as described above, the object of the present invention is to use a coating film thickness of 1mm or less using an emulsion resin having excellent water resistance and breathability, pigment and imogolite excellent in hygroscopicity It absorbs moisture from the air on the surface of the object, suppresses surface condensation at the dew point, and realizes an anionic and antimicrobial effect simultaneously with an aqueous coating manufacturing technology having a coating film function of repeating a function of releasing moisture contained in a normal time. It is to provide an anti-condensation paint and a method of manufacturing the same.
상기한 바와 같은 본 발명의 목적을 달성하기 위하여, 본 발명에 따른 결로방지 페인트는 31 ~ 43 중량 %의 물과; 0.05 ~ 0.15 중량 %의 항균제; 0.2 ~ 0.4 중량 %의 분산제; 30 ~ 50 중량 %의 무기안료; 17 ~ 27 중량 %의 아크릴에멀젼수지; 0.05 ~ 0.15 중량 %의 증점제; 0.3 ~ 0.5 중량 %의 소포제; 및 0.05 ~ 0.15 중량 %의 조막제; 를 포함하여 형성된 것을 특징으로 한다.In order to achieve the object of the present invention as described above, the anti-condensation paint according to the present invention is 31 to 43% by weight of water; 0.05-0.15 weight percent antimicrobial agent; 0.2 to 0.4 weight percent dispersant; 30-50% by weight of inorganic pigments; 17 to 27% by weight of acrylic emulsion resin; 0.05 to 0.15 weight percent thickener; Antifoaming agent of 0.3 to 0.5% by weight; And 0.05 to 0.15% by weight of a film forming agent; Characterized in that formed.
본 발명에 따른 결로방지 페인트에 있어서, 상기 무기안료는 20 ~ 26 ㎛ 입상인 국화석 62.5 ~ 72.5 중량 %와 20 ~ 26 ㎛ 입상인 모나자이트 5 ~ 10 중량 % 및 이모골라이트 20 ~ 30 중량 %를 포함하여 형성된 것을 특징으로 한다.In the anti-condensation paint according to the present invention, the inorganic pigment includes 62.5 to 72.5 wt% of chrysanthemum stone 20 to 26 μm granular, 5 to 10 wt% of monazite 20 to 26 μm granular, and 20 to 30 wt% of imogolite Characterized in that formed.
본 발명에 따른 결로방지 페인트에 있어서, 상기 모나자이트는 5 ~ 17 중량 %의 산화토륨을 함유하는 것을 특징으로 한다.In the anti-condensation paint according to the present invention, the monazite is characterized in that it contains 5 to 17% by weight of thorium oxide.
본 발명에 따른 결로방지 페인트에 있어서, 상기 이모골라이트는 0.1 ~ 3몰 농도의 과염소산수용액 70 중량 %와, 테트라에톡시실란과 염화알루미늄이 1:2의 중량비율로 혼합된 혼합액 30 중량 %가 혼합되고, pH가 7 ~ 8이 되도록 수산화나트륨을 포함하여 형성된 것을 특징으로 한다.In the anti-condensation paint according to the present invention, the imogolite is 70% by weight of the aqueous solution of perchloric acid at a concentration of 0.1 to 3 mol, and 30% by weight of the mixed solution of tetraethoxysilane and aluminum chloride in a weight ratio of 1: 2. The mixture is characterized in that formed by including sodium hydroxide so that the pH is 7 to 8.
상기한 바와 같은 본 발명의 목적을 달성하기 위하여, 본 발명에 따른 결로방지 페인트 제조방법은 31 ~ 43 중량 %의 물에 0.05 ~ 0.15 중량 %의 항균제를 혼합하는 제1과정;상기 제1과정에서 생성된 물질에 0.2 ~ 0.4 중량 %의 분산제를 혼합하는 제2과정; 상기 제2과정에서 생성된 물질에 30 ~ 50 중량 %의 무기안료를 혼합하는 제3과정; 상기 제3과정에서 생성된 물질에 17 ~ 27 중량 %의 수용성 아크릴에멀젼수지를 혼합하는 제4과정; 상기 제4과정에서 생성된 물질에 0.05 ~ 0.15 중량 %의 증점제를 혼합하는 제5과정; 상기 제5과정에서 생성된 물질에 0.3 ~ 0.5 중량 %의 소포제를 혼합하는 제6과정; 및 상기 제6과정에서 0.05 ~ 0.15 중량 %의 조막제를 혼합하는 제7과정;으로 이루어지는 것을 특징으로 한다.In order to achieve the object of the present invention as described above, the anti-condensation paint production method according to the present invention is a first step of mixing 0.05 ~ 0.15% by weight of the antimicrobial agent in 31 to 43% by weight of water; A second step of mixing 0.2 to 0.4 wt% of a dispersant in the resulting material; A third step of mixing an inorganic pigment of 30 to 50 wt% with the material produced in the second step; A fourth step of mixing 17 to 27% by weight of a water-soluble acrylic emulsion resin with the material produced in the third step; A fifth step of mixing 0.05 to 0.15% by weight of a thickener with the material produced in the fourth step; A sixth step of mixing 0.3 to 0.5 wt% of an antifoaming agent with the material produced in the fifth step; And a seventh step of mixing 0.05 to 0.15% by weight of the deposition agent in the sixth step.
본 발명에 따른 결로방지 페인트 제조방법에 있어서, 상기 제3과정에서는 상기 무기안료가 20 ~ 26 ㎛ 입상인 국화석 62.5 ~ 72.5 중량 %와 20 ~ 26 ㎛ 입상인 모나자이트 5 ~ 10 중량 % 및 이모골라이트 20 ~ 30 중량 %을 포함하여 이루어지는 것을 특징으로 한다.In the anti-condensation paint manufacturing method according to the present invention, in the third step, the inorganic pigment is 62.5 ~ 72.5% by weight of chrysanthemum of 20 ~ 26 ㎛ granular and 5 ~ 10% by weight of monazite of 20 ~ 26 ㎛ granular and imogolite It is characterized by including 20 to 30% by weight.
본 발명에 따른 결로방지 페인트 제조방법에 있어서, 상기 모나자이트는 5 ~ 17 중량 %의 산화토륨을 함유하는 것을 특징으로 한다.In the method for producing a condensation preventing paint according to the present invention, the monazite is characterized in that it contains 5 to 17% by weight of thorium oxide.
본 발명에 따른 결로방지 페인트 제조방법에 있어서, 상기 이모골라이트는 0.1 ~ 3몰 농도의 과염소산수용액 70 중량 %와 테트라에톡시실란과 염화알루미늄이 중량비가 1:2의 혼합비율의 혼합액 30 중량 %를 혼합한 후 pH가 7~8이 되도록 수산화나트륨을 포함하여 형성되는 것을 특징으로 한다.In the method for preparing anti-condensation paint according to the present invention, the imogolite is 70% by weight of the aqueous solution of 0.1-3 mol perchlorate and 30% by weight of the mixed ratio of tetraethoxysilane and aluminum chloride in a weight ratio of 1: 2. After mixing, characterized in that formed by including sodium hydroxide so that the pH is 7 ~ 8.
본 발명은 도막시공이 간편하고 두께 1㎜이하의 도막을 시공하더라도 대기 중의 습기를 흡수 또는 방출을 반복함으로써 결로발생을 방지하고 단열재의 단열효과를 더욱 높여 실내의 온도를 일정하게 하며 음이온의 발생과 탈취 및 항균효과가 뛰어나다.The present invention is easy to construct a coating film, even if the coating film of less than 1mm thickness to prevent moisture condensation by repeating the absorption or release of moisture in the atmosphere to further increase the thermal insulation effect of the insulation material to maintain a constant temperature in the room and Excellent deodorization and antibacterial effect.
도 1은 본 발명의 실시예에 따른 결로방지 페인트 제조방법을 나타낸 플로차트.
도 2는 본 발명의 실시예에 따른 무기안료의 제조방법을 나타낸 플로차트.
도 3은 본 발명의 실시예에 따른 이모골라이트의 제조방법을 나타낸 플로차트.1 is a flow chart showing a method for manufacturing anti-condensation paint according to an embodiment of the present invention.
2 is a flow chart showing a method for producing an inorganic pigment according to an embodiment of the present invention.
Figure 3 is a flow chart showing a method for producing imogolite according to an embodiment of the present invention.
이하, 본 발명을 더욱 상세하게 설명한다.Hereinafter, the present invention will be described in more detail.
본 발명에 따른 결로방지 페인트는 물과 항균제, 분산제, 무기안료, 아크릴에멀젼수지, 증점제 소포제 및 조막제를 포함하여 형성된다.The anti-condensation paint according to the present invention is formed by containing water and antibacterial agent, dispersant, inorganic pigment, acrylic emulsion resin, thickener defoamer and film forming agent.
상기 결로방지 페인트를 구성하는 물질의 바람직한 혼합비율은 물 31 ~ 43 중량 %(가장 바람직하게는 37 중량 %), 항균제 0.05 ~ 0.15 중량 %(가장 바람직하게는 0.1 중량 %), 분산제 0.2 ~ 0.4 중량 %(가장 바람직하게는 0.3 중량 %), 무기안료 30 ~ 50 중량 %(가장 바람직하게는 40 중량 %), 아크릴에멀젼수지 17 ~ 27 중량 %(가장 바람직하게는 22 중량 %), 증점제 0.05 ~ 0.15 중량 %(가장 바람직하게는 0.1 중량 %), 소포제 0.3 ~ 0.5 중량 %(가장 바람직하게는 0.4 중량 %) 및 조막제 0.05 ~ 0.15 중량 %(가장 바람직하게는 0.1 중량 %)이다.The preferred mixing ratio of the material constituting the anti-condensation paint is 31 to 43% by weight of water (most preferably 37% by weight), 0.05 to 0.15% by weight of antimicrobial agent (most preferably 0.1% by weight), and 0.2 to 0.4% by weight of dispersant. % (Most preferably 0.3% by weight), inorganic pigment 30-50% by weight (most preferably 40% by weight), acrylic emulsion resin 17-27% by weight (most preferably 22% by weight), thickener 0.05-0.15 Weight% (most preferably 0.1 weight%), antifoaming agent 0.3 to 0.5 weight% (most preferably 0.4 weight%) and film forming agent 0.05 to 0.15 weight% (most preferably 0.1 weight%).
상기 항균제와 분산제, 증점제, 소포제 및 조막제는 당업계에서 일반적으로 이용되는 것으로 이의 종류는 한정하지 않는다.The antimicrobial agent and dispersant, thickener, antifoaming agent and film forming agent are generally used in the art and are not limited thereto.
상기 무기안료는 국화석과 모나자이트 및 이모골라이트로 혼합되어 구성되며, 바람직한 혼합비율은 국화석 62.5 ~ 72.5 중량 %(가장 바람직하게는 67.5 중량 %)와 모나자이트 5 ~ 10 중량 %(가장 바람직하게는 7.5 중량 %) 및 이모골라이트 20 ~ 30 중량 %(가장 바람직하게는 25 중량 %)이다.The inorganic pigment is composed of chrysanthemum, monazite and imogolite, and the preferred mixing ratio is 62.5 to 72.5% by weight (most preferably 67.5% by weight) of chrysanthemum and 5 to 10% by weight of monazite (most preferably 7.5%). %) And 20-30% by weight of imogolite (most preferably 25% by weight).
아울러 상기 국화석과 모나자이트의 바람직한 크기는 20 ~ 26 ㎛ 입상이며, 상기 이모골라이트의 바람직한 크기는 0.01 ~ 0.05 ㎛ 입상이다.In addition, the preferred size of the chrysanthemum and monazite is 20 ~ 26 ㎛ granular, the preferred size of the imogolite is 0.01 ~ 0.05 ㎛ granular.
상기 국화석과 모나자이트, 이모골라이트의 입도 편차가 크기 때문에 상기 무기안료는 바로 혼합하는 것이 어려우므로 진동 밀을 이용하여 혼합하는 것이 바람직하다.Since the particle size variation of the chrysanthemum stone, monazite, and imogolite is large, it is difficult to mix the inorganic pigments directly, so it is preferable to mix using a vibration mill.
국화석은 화쇄암(火碎岩) 중에 스며든 광액의 광물 성분이 방사상으로 침전되어 여러 가지 꽃잎 모양의 결정을 이룬 것으로, 선캄브리아대의 화석이라고 간주되는 것 중에는 암석이 기계적으로 변형되거나 또는 변성작용을 받았기 때문에 화석과 닮은 모양을 이룬 경우가 많다.Chrysanthemum is a mineral crystal of minerals that penetrates into the rock, and forms a variety of petal-like crystals. Because of this, they often look like fossils.
상기 국화석은 빛에너지를 받아 전자가 계속해서 이동하여 정공이 곳곳에서 발생하기 때문에 반영구적으로 향균, 살균, 탈취를 함은 물론 유기물 분해, 초진수성기능이 있다.Since the chrysanthemum receives light energy, electrons continue to move, and holes are generated in various places, thus semi-permanently antibacterial, sterilizing, and deodorizing, as well as organic matter decomposition and herbicidal functions.
상기 모나자이트는 5 ~ 17 중량 %의 산화토륨을 함유하는 것이 바람직하며, 상기 산화토륨이 함유된 모나자이트는 음이온을 방출한다.The monazite preferably contains 5 to 17% by weight of thorium oxide, and the monazite containing the thorium oxide releases anions.
상기 이모골라이트는 0.1 ~ 3몰 농도(가장 바람직하게는 0.1몰 농도)의 과염소산수용액 70 중량 %와, 테트라에톡시실란과 염화알루미늄이 1:2의 중량비율로 혼합된 혼합액 30 중량 %을 혼합하여 60 ~ 80℃(바람직하게는 80℃)로 가열하며 1 ~ 3 시간(가장 바람직하게는 1시간) 동안 반응시켜 제조하는 것이 바람직하다.The imogolite is mixed with 70% by weight of an aqueous solution of perchloric acid at a concentration of 0.1 to 3 moles (most preferably 0.1 mole) and 30% by weight of a mixed solution of tetraethoxysilane and aluminum chloride in a weight ratio of 1: 2. It is preferably prepared by heating to 60 ~ 80 ℃ (preferably 80 ℃) and reacted for 1 to 3 hours (most preferably 1 hour).
상기 0.1 ~ 3 몰 농도의 과염소산수용액은 증류수에 과염소산을 넣고 2시간동안 반응시켜 제조한다.The aqueous solution of perchloric acid at a concentration of 0.1 to 3 moles is prepared by adding perchloric acid to distilled water and reacting for 2 hours.
그리고 상기 이모골라이트는 pH가 2 ~ 3.5의 산성을 나타내므로 강알칼리성인 수산화나트륨을 첨가하여 pH가 7 ~ 8이 되도록 중화시키는 것이 바람직하다. In addition, since the imogolite exhibits an acidity of 2 to 3.5, it is preferable to neutralize the pH to 7 to 8 by adding sodium hydroxide which is strongly alkaline.
그리고 중화되어 pH 7 ~ 8인 상기 이모골라이트를 20,000 RPM 원심분리기로 탈염 처리 후 세정하고, 100 ~ 300℃로 2일 동안 가열하며 건조함으로써 본 발명에 사용되기에 바람직한 이모골라이트를 얻을 수 있다.In addition, the imogolite, which is neutralized and has a pH of 7 to 8, is washed after desalting with a 20,000 RPM centrifuge, and heated and dried at 100 to 300 ° C. for 2 days, thereby obtaining a preferred imogolite for use in the present invention. .
그러나 본 발명에 있어서 사용되는 이모골라이트는 상기에 기재된 것이 바람직하나, 이에 한정하지 않고 시중에 공개된 다양한 제품을 사용할 수 있다.However, the imogolite used in the present invention is preferably described above, but is not limited thereto, and various commercially available products can be used.
본 발명에 따른 결로방지 페인트의 제조방법은 31 ~ 43 중량 %의 물에 0.05 ~ 0.15 중량 %의 항균제를 혼합하는 제1과정(S1)과, 상기 제1과정(S1)에서 생성된 물질에 0.2 ~ 0.4 중량 %의 분산제를 혼합하는 제2과정(S2), 상기 제2과정(S2)에서 생성된 물질에 30 ~ 50 중량 %의 무기안료를 혼합하는 제3과정(S3), 상기 제3과정(S3)에서 생성된 물질에 17 ~ 27 중량 %의 수용성 아크릴에멀젼수지를 혼합하는 제4과정(S4), 상기 제4과정(S4)에서 생성된 물질에 0.05 ~ 0.15 중량 %의 증점제를 혼합하는 제5과정(S5), 상기 제5과정(S5)에서 생성된 물질에 0.3 ~ 0.5 중량 %의 소포제를 혼합하는 제6과정(S6) 및 상기 제6과정(S6)에서 0.05 ~ 0.15 중량 %의 조막제를 혼합하는 제7과정(S7)으로 이루어진다.Method for producing a condensation preventing paint according to the present invention is a first step (S1) of mixing 0.05 to 0.15% by weight of the antimicrobial agent in 31 to 43% by weight of water, 0.2 in the material produced in the first step (S1) The second process (S2) of mixing the dispersant of 0.4% by weight, the third process (S3) of mixing the inorganic pigment of 30 to 50% by weight with the material produced in the second process (S2), the third process In the fourth step (S4) of mixing 17 to 27% by weight of the water-soluble acrylic emulsion resin to the material produced in (S3), 0.05 to 0.15% by weight of a thickener is mixed to the material produced in the fourth process (S4) In the fifth process (S5), the sixth process (S6) and the sixth process (S6) of 0.05 to 0.15% by weight of mixing the antifoaming agent 0.3 ~ 0.5% by weight to the material produced in the fifth process (S5) It consists of a 7th process (S7) of mixing a film forming agent.
상기 제1과정(S1)에서의 항균제와 제2과정(S2)에서의 분산제, 상기 제5과정(S5)에서의 증점제, 상기 제6과정(S6)에서의 소포제 및 상기 제7과정(S7)에서의 조막제는 당업계에서 일반적으로 이용되는 것으로 이의 종류는 한정하지 않는다.The antibacterial agent in the first step (S1) and the dispersant in the second step (S2), the thickener in the fifth step (S5), the antifoaming agent in the sixth step (S6) and the seventh step (S7) The film forming agent in is generally used in the art, and its kind is not limited.
상기 무기안료는 국화석과 모나자이트 및 이모골라이트로 혼합되어 구성되며, 바람직한 혼합비율은 국화석 62.5 ~ 72.5 중량 %(가장 바람직하게는 67.5 중량 %)와 모나자이트 5 ~ 10 중량 %(가장 바람직하게는 7.5 중량 %) 및 이모골라이트 20 ~ 30 중량 %(가장 바람직하게는 25 중량 %)이다.The inorganic pigment is composed of chrysanthemum, monazite and imogolite, and the preferred mixing ratio is 62.5 to 72.5% by weight (most preferably 67.5% by weight) of chrysanthemum and 5 to 10% by weight of monazite (most preferably 7.5%). %) And 20-30% by weight of imogolite (most preferably 25% by weight).
아울러 상기 국화석과 모나자이트의 바람직한 크기는 20 ~ 26 ㎛ 입상이며, 상기 이모골라이트의 바람직한 크기는 0.01 ~ 0.05 ㎛ 입상이다.In addition, the preferred size of the chrysanthemum and monazite is 20 ~ 26 ㎛ granular, the preferred size of the imogolite is 0.01 ~ 0.05 ㎛ granular.
상기 국화석과 모나자이트, 이모골라이트의 입도 편차가 크기 때문에 상기 무기안료는 바로 혼합하는 것이 불가능하므로 진동 밀을 이용하여 혼합하는 것이 바람직하다.Since the particle size variation of the chrysanthemum, monazite, and imogolite is large, it is not possible to directly mix the inorganic pigment, and it is preferable to mix using a vibration mill.
상기 모나자이트는 5 ~ 17 중량 %의 산화토륨을 함유하는 것이 바람직하며, 상기 산화토륨이 함유된 모나자이트는 음이온을 방출한다.The monazite preferably contains 5 to 17% by weight of thorium oxide, and the monazite containing the thorium oxide releases anions.
상기 이모골라이트는 0.1 ~ 3몰 농도(가장 바람직하게는 0.1몰)의 과염소산수용액 70 중량 %와 테트라에톡시실란과 염화알루미늄을 1:2의 중량비로 혼합한 혼합액 30 중량 %를 혼합하여 60 ~ 95℃(가장 바람직하게는 80℃)로 가열하며 1 ~ 3 시간 동안 반응시켜 제조하는 것이 바람직하다.The imogolite is mixed by mixing 70 wt% of an aqueous solution of perchloric acid at a concentration of 0.1 to 3 mol (most preferably 0.1 mol) with 30 wt% of a mixed solution of tetraethoxysilane and aluminum chloride in a weight ratio of 1: 2. It is preferably prepared by heating to 95 ° C. (most preferably 80 ° C.) and reacting for 1-3 hours.
상기 0.1 ~ 3 몰 농도의 과염소산은 증류수에 과염소산을 넣고 2시간 동안 반응시켜 제조한다.The perchloric acid of the 0.1 ~ 3 molar concentration is prepared by putting perchloric acid in distilled water and reacted for 2 hours.
상기 이모골라이트는 pH가 2 ~3.5의 산성을 나타내므로 강알칼리성인 수산화나트륨을 첨가하여 pH가 7 ~ 8이 되도록 중화시키는 것이 바람직하다.Since the imogolite exhibits an acidity of 2 to 3.5, it is preferable to neutralize the pH to 7 to 8 by adding sodium hydroxide which is strongly alkaline.
그리고 중화되어 pH 7 ~ 8인 상기 이모골라이트를 20,000 RPM 원심분리기로 탈염 처리 후 세정하고, 100 ~ 300℃로 2일 동안 가열하며 건조함으로써 본 발명에 사용되기에 바람직한 이모골라이트를 얻을 수 있다.In addition, the imogolite, which is neutralized and has a pH of 7 to 8, is washed after desalting with a 20,000 RPM centrifuge, and heated and dried at 100 to 300 ° C. for 2 days, thereby obtaining a preferred imogolite for use in the present invention. .
그러나 본 발명에 있어서 사용되는 이모골라이트는 이에 한정하지 않고 시중에 공개된 다양한 제품을 사용할 수 있다.However, the imogolite used in the present invention is not limited thereto, and various products disclosed on the market can be used.
본 발명에 따른 결로방지 페인트의 제조에 사용되는 이모골라이트는 다음과 같이 제조된다.Imogolites used in the production of anti-condensation paints according to the invention are prepared as follows.
먼저 0.1몰 농도의 과염소산수용액을 만들기 위해 증류수에 과염소산을 2시간 동안 80℃로 가열하며 반응시킨다.First, perchloric acid is reacted with distilled water by heating to 80 ° C. for 2 hours in order to prepare a 0.1 molar perchloric acid solution.
테트라에톡시실란과 염화알루미늄수용액이 1:2의 중량비로 혼합한 혼합액을 상기 0.1몰 농도의 과염소산수용액에 투입하여 1시간 동안 반응시킨다.A mixed solution of tetraethoxysilane and an aqueous aluminum chloride solution in a weight ratio of 1: 2 was added to the aqueous solution of perchloric acid at a 0.1 molar concentration and reacted for 1 hour.
이렇게 반응된 혼합액의 pH는 3 ~ 5의 산성을 나타내므로 수산화나트륨을 첨가하여 상기 혼합액의 pH가 7 ~ 8이 되도록 한다.Since the pH of the mixed solution thus reacted shows an acidity of 3 to 5, sodium hydroxide is added so that the pH of the mixed solution is 7 to 8.
상기 수산화나트륨을 첨가하여 pH가 7 ~ 8이 된 혼합액을 20000 RPM의 원심분리기로 탈염처리한 후 세정하고 100℃ 이상으로 2일 동안 가열하며 건조함으로써 본 발명에 사용되는 이모골라이트를 얻을 수 있다.The imogolite used in the present invention can be obtained by adding the sodium hydroxide and desalting the mixed solution having a pH of 7 to 8 with a centrifuge at 20000 RPM, then washing and heating at 100 ° C. or higher for 2 days. .
그러나 본 발명에 있어서 사용되는 이모골라이트는 상기 기술된 내용으로 제조한 것이 바람직하지만 이에 한정하지 않고 시중에 공개된 다양한 제품을 사용하여도 무방하다.However, the imogolite used in the present invention is preferably manufactured according to the above-described contents, but is not limited thereto, and various commercially available products may be used.
무기안료는 국화석 67.5 중량 %와 모나자이트 7.5 중량 % 및 이모골라이트 25 중량 %을 혼합하여 구성한다.The inorganic pigment is composed by mixing 67.5 wt% chrysanthemum stone, 7.5 wt% monazite and 25 wt% imogolite.
상기 국화석과 모나자이트의 바람직한 크기는 20 ~ 26 ㎛ 입상이며, 상기 이모골라이트의 바람직한 크기는 0.01 ~ 0.05 ㎛ 입상이다.Preferred sizes of the chrysanthemum and monazite are 20 to 26 μm granular, and preferred sizes of the imogolite are 0.01 to 0.05 μm granular.
상기 무기안료는 국화석과 모나자이트 및 이모골라이트의 입도 편차가 크기 때문에 분산이 어려우므로 진동 밀을 사용하여 혼합한다.Since the inorganic pigment is difficult to disperse because the particle size variation of chrysanthemum, monazite and imogolite is large, it is mixed using a vibration mill.
상기 물질들을 디졸바를 이용하여 1000 RPM으로 30분간 혼합하여 제조한다.The materials are prepared by mixing at 1000 RPM for 30 minutes using a dissolva.
이와 같이 제조된 결로방지 페인트의 점도는 125Ku(Krebs-Stomer Viscometer)이다.The viscosity of the anti-condensation paint prepared in this way is 125Ku (Krebs-Stomer Viscometer).
이상에서 설명한 바와 같이 본 발명에 따른 결로방지 페인트 및 그 제조방법은 실시예에 불과한 것으로서, 본 발명은 상기한 실시예에 한정되지 않고, 이하 특허청구범위에서 청구하는 본 발명의 요지를 벗어남이 없이 본 발명이 속하는 분야에서 통상의 지식을 가진 자라면 누구든지 다양하게 변경하여 실시할 수 있는 범위까지 본 발명의 기술적 정신이 있다고 할 것이다.As described above, the anti-condensation paint according to the present invention and its manufacturing method are only examples, and the present invention is not limited to the above-described embodiments, without departing from the gist of the present invention as claimed in the following claims. Anyone with ordinary knowledge in the field of the present invention will have the technical spirit of the present invention to the extent that it can be variously modified.
Claims (8)
0.05 ~ 0.15 중량 %의 항균제;
0.2 ~ 0.4 중량 %의 분산제;
30 ~ 50 중량 %의 무기안료;
17 ~ 27 중량 %의 아크릴에멀젼수지;
0.05 ~ 0.15 중량 %의 증점제;
0.3 ~ 0.5 중량 %의 소포제; 및
0.05 ~ 0.15 중량 %의 조막제;
를 포함하여 형성된 것을 특징으로 하는 결로방지 페인트.31 to 43 weight percent water;
0.05-0.15 weight percent antimicrobial agent;
0.2 to 0.4 weight percent dispersant;
30-50% by weight of inorganic pigments;
17 to 27% by weight of acrylic emulsion resin;
0.05 to 0.15 weight percent thickener;
Antifoaming agent of 0.3 to 0.5% by weight; And
0.05 to 0.15% by weight of a film forming agent;
Condensation prevention paint, characterized in that formed including.
상기 제1과정(S1)에서 생성된 물질에 0.2 ~ 0.4 중량 %의 분산제를 혼합하는 제2과정(S2);
상기 제2과정(S2)에서 생성된 물질에 30 ~ 50 중량 %의 무기안료를 혼합하는 제3과정(S3);
상기 제3과정(S3)에서 생성된 물질에 17 ~ 27 중량 %의 수용성 아크릴에멀젼수지를 혼합하는 제4과정(S4);
상기 제4과정(S4)에서 생성된 물질에 0.05 ~ 0.15 중량 %의 증점제를 혼합하는 제5과정(S5);
상기 제5과정(S5)에서 생성된 물질에 0.3 ~ 0.5 중량 %의 소포제를 혼합하는 제6과정(S6); 및
상기 제6과정(S6)에서 0.05 ~ 0.15 중량 %의 조막제를 혼합하는 제7과정(S7);
으로 이루어지는 것을 특징으로 하는 결로방지 페인트의 제조방법.A first step (S1) of mixing 0.05 to 0.15% by weight of the antimicrobial agent to 31 to 43% by weight of water;
A second step (S2) of mixing 0.2 to 0.4 wt% of a dispersant with the material produced in the first step (S1);
A third step (S3) of mixing an inorganic pigment of 30 to 50% by weight with the material produced in the second step (S2);
A fourth step (S4) of mixing 17 to 27% by weight of a water-soluble acrylic emulsion resin with the material produced in the third step (S3);
A fifth step (S5) of mixing a thickener of 0.05 to 0.15% by weight with the material produced in the fourth step (S4);
A sixth step (S6) of mixing 0.3 to 0.5 wt% of an antifoaming agent with the material produced in the fifth step (S5); And
A seventh step (S7) of mixing 0.05 to 0.15% by weight of the deposition agent in the sixth step (S6);
Method for producing a condensation preventing paint, characterized in that consisting of.
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KR101535151B1 (en) * | 2013-05-16 | 2015-07-09 | 정영 | Functional finishing material composition for building interior having hygroscopicity and moisture proof property, and method of preparing the same |
KR20160052123A (en) * | 2014-11-04 | 2016-05-12 | 이정화 | water paints composition for anti-sweating |
KR101960047B1 (en) | 2018-11-28 | 2019-03-19 | 이정규 | Excellent waterproof and insulation performance paint and manufacturing method thereof |
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JP2000351921A (en) | 1999-06-10 | 2000-12-19 | Aisin Chem Co Ltd | Dew condensation-preventing and antibacterial and antifungal coating material composition |
KR100497254B1 (en) * | 2003-04-18 | 2005-06-23 | 주식회사 이파엘지종합특수방수 | Dew condensation prevent method of construction for building |
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KR101535151B1 (en) * | 2013-05-16 | 2015-07-09 | 정영 | Functional finishing material composition for building interior having hygroscopicity and moisture proof property, and method of preparing the same |
KR20160052123A (en) * | 2014-11-04 | 2016-05-12 | 이정화 | water paints composition for anti-sweating |
KR101960047B1 (en) | 2018-11-28 | 2019-03-19 | 이정규 | Excellent waterproof and insulation performance paint and manufacturing method thereof |
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