KR20110121988A - Elastic fiber structure and method of fabricating the same - Google Patents

Elastic fiber structure and method of fabricating the same Download PDF

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KR20110121988A
KR20110121988A KR1020100041538A KR20100041538A KR20110121988A KR 20110121988 A KR20110121988 A KR 20110121988A KR 1020100041538 A KR1020100041538 A KR 1020100041538A KR 20100041538 A KR20100041538 A KR 20100041538A KR 20110121988 A KR20110121988 A KR 20110121988A
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fiber
polyester
heat
weight
elastic
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KR1020100041538A
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Korean (ko)
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KR101206821B1 (en
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윤병섭
정진호
이동훈
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웅진케미칼 주식회사
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    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4326Condensation or reaction polymers
    • D04H1/435Polyesters
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D10/00Physical treatment of artificial filaments or the like during manufacture, i.e. during a continuous production process before the filaments have been collected
    • D01D10/02Heat treatment
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/28Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
    • D01D5/30Conjugate filaments; Spinnerette packs therefor
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/28Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
    • D01D5/30Conjugate filaments; Spinnerette packs therefor
    • D01D5/34Core-skin structure; Spinnerette packs therefor
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/14Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01GPRELIMINARY TREATMENT OF FIBRES, e.g. FOR SPINNING
    • D01G15/00Carding machines or accessories; Card clothing; Burr-crushing or removing arrangements associated with carding or other preliminary-treatment machines
    • D01G15/02Carding machines
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/542Adhesive fibres
    • D04H1/55Polyesters
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/06Load-responsive characteristics
    • D10B2401/061Load-responsive characteristics elastic
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2503/00Domestic or personal
    • D10B2503/06Bed linen
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2505/00Industrial
    • D10B2505/12Vehicles

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Nonwoven Fabrics (AREA)

Abstract

PURPOSE: An elastic fiber structure and a method for manufacturing the same are provided to ensure soft and light touch property. CONSTITUTION: An elastic fiber structure comprises: 5-80 wt% of hollow polyester fiber with 20-60 % of hollowness; 5-80 wt% of stretch fiber containing composite fiber comprising polyester polymers with 0.63-1.30 of natural viscosity and polymers with 0.45-0.56 of viscosity; and 5-80 wt% of thermal bonding binder polyester fiber. The composite fiber is selected from the group consisting of side-by-side type, sheath-core type, and eccentricity sheath-core type.

Description

탄성 섬유 구조체 및 이의 제조방법{ELASTIC FIBER STRUCTURE AND METHOD OF FABRICATING THE SAME}Elastic fiber structure and manufacturing method thereof {ELASTIC FIBER STRUCTURE AND METHOD OF FABRICATING THE SAME}

본 발명은 부드러우면서도 탄성회복 성능이 지속적으로 우수하게 발휘되고, 친환경인 탄성 섬유 구조체 및 이의 제조방법에 관한 것이다.The present invention relates to an elastic fiber structure and a method for producing the same, which is soft and elastic recovery performance is continuously excellent.

일반적으로 생활 속에서 사용되는 완충재용 소재 중 가장 광범위하게 사용되고 있는 것이 폴리우레탄 발포체(통상적으로 "스폰지"라 칭함)이며, 가볍고 탄성이 좋으며 값이 싸다는 장점 때문에 많이 사용되고 있다. 그러나, 폴리우레탄 수지를 성글게 발포한 폴리우레탄 발포체는 특유의 냄새가 있고, 시간이 경과함에 따라 황변 현상이 발생하고, 발포 셀 자체의 부식으로 탄성이 저하되고 먼지가 발생하며, 재활용이 어려운 단점이 있었다.In general, the most widely used cushioning material used in everyday life is a polyurethane foam (commonly referred to as "sponge"), and is widely used due to its advantages of being light, elastic, and inexpensive. However, polyurethane foams with a sparse foam of polyurethane resin have a peculiar smell, yellowing phenomenon occurs over time, elasticity decreases due to corrosion of the foam cell itself, dust is generated, and recycling is difficult. there was.

따라서, 폴리우레탄 발포체를 대체할 소재에 대한 많은 관심이 고조되고 있지만, 만족할 만한 효과를 나타내는 소재가 제시되지 못하고 있는 실정이다.Therefore, a great deal of attention is being paid to the material to replace the polyurethane foam, but the situation that the material showing a satisfactory effect has not been presented.

이에, 대한민국 특허공개 제1990-8073호에서는 융점이 100℃-220℃인 섬유형성성중합체로 되어 있고, 섬유축에 연속하는 1개 이상의 중공을 갖되 그 중공율이 5-80%이며, 연신 후의 단사섬도가 0.5-30데니어로서 권축수가 3-40개/인치, 섬유장이 10-150㎜인 열접착성 섬유가 제안된 바 있으나, 탄성이 많이 부족하고, 섬유 자체의 강도가 떨어져 내구성이 떨어지는 단점이 있다.Thus, Korean Patent Publication No. 1990-8073 discloses a fiber-forming polymer having a melting point of 100 ° C.-220 ° C., having one or more hollows continuous to the fiber axis, and having a hollow ratio of 5-80%, after stretching. Heat-adhesive fibers with single yarn fineness of 0.5-30 denier, 3-40 sheets / inch of crimp, and 10-150 mm of fiber length have been proposed, but lack of elasticity and poor strength due to low strength of the fiber itself. There is this.

또한, 대한민국 특허발명 제908340호에서는 폴리에스터 콘쥬게이트 화이버(polyester conjugate fiber) 10 ∼ 70중량%, 실리콘이 첨가된 오일로 표면 처리한 폴리에스터 콘쥬게이트 화이버(polyester conjugate fiber) 10 ∼ 70중량%, 저융점 열융착 바인더 화이버 10 ∼ 70중량% 및 폴리에스터 또는 폴리스티렌의 심초형 복합 융착 화이버 10 ∼ 70중량%로 구성되어지되 각각의 원료들을 혼합하고 카딩하여 단층 또는 다층으로 웹(web)을 적층한 다음, 적층된 웹을 미늘(barb)이 있는 니들(needle)을 이용하여 니들 펀칭하는 방법으로 결합하여 시트(sheet)를 형성하고, 시트를 건조로(dry box)와 가열 로울러에 통과시켜 융착 결합시킨 것을 특징으로 하는 고탄성 부직포가 제안되었으나, 콘쥬게이트 화이버와 열융착 바인더 화이버 2종으로 혼합하여 웹 적층하여 제조된 것으로 부직포의 강도가 떨어져 반복 사용 시 탄성 구조의 지속성이 떨어지게 되어 탄성과 반발 회복 기능이 저하될 가능성이 크고, 표면의 터치감이 우레탄 폼과 차이가 클 우려가 있다.In addition, Korean Patent Invention No. 908340 discloses 10 to 70% by weight of polyester conjugate fiber, 10 to 70% by weight of polyester conjugate fiber surface-treated with oil containing silicon, It is composed of 10 to 70% by weight of low melting point heat-sealing binder fiber and 10 to 70% by weight of the sheath type composite fusion fiber made of polyester or polystyrene, and each web is mixed and carded to laminate a web in a single layer or multiple layers. Next, the laminated web is bonded by needle punching using a needle with a barb to form a sheet, and the sheet is passed through a dry box and a heating roller to be fusion bonded. Although a highly elastic nonwoven fabric has been proposed, it is produced by mixing webs by mixing two kinds of conjugate fibers and heat-sealed binder fibers to produce a nonwoven fabric. Greater possibility degrees repeat durability of the elastic structure is dropped during use to be elastic and resilient recovery degraded away, the touch feeling of greater concern is different from the polyurethane foam surface.

그 밖에 대한민국 특허공개 제2008-80144호에서는 섬유 구상체를 몰드 내에서 열 성형하여 얻어지는 성형품에 있어서, 해당 섬유 구상체가, (a) 비탄성 폴리에스테르와 해당 비탄성 폴리에스테르의 융점보다 40℃ 이상 낮은 융점을 갖는 탄성 열가소성 엘라스토머가 배치된 복합 단섬유로서, 해당 비탄성 폴리에스테르가 복합 단섬유 표면의 25 내지 49%를 차지하도록 노출되어 있는 복합 단섬유와, (b) 폴리트리메틸렌테레프탈레이트계 단섬유로 구성되고, 그의 섬유 교락점의 일부가 가요성 열고착점에서 열 고착되어 있는 것을 특징으로 하는 고탄성 섬유 구상체로 이루어지는 성형품이 제안되었으나, 구상체를 형성시키기 위한 특별한 설비가 필요하여 제조 비용의 증가가 초래된다. In addition, Korean Patent Publication No. 2008-80144 discloses a molded article obtained by thermoforming a fibrous spherical body in a mold, wherein the fibrous spherical body has a melting point of at least 40 ° C lower than the melting point of (a) the inelastic polyester and the inelastic polyester. A composite short fiber in which an elastic thermoplastic elastomer having a compound is disposed, wherein the inelastic polyester is exposed so that 25% to 49% of the surface of the composite short fiber is formed, and (b) a polytrimethylene terephthalate-based short fiber Although a molded article consisting of a highly elastic fiber spherical body has been proposed, wherein a part of its fiber entanglement is thermally fixed at a flexible hot-fixing point, special equipment for forming the spherical body is required, resulting in an increase in manufacturing cost. do.

게다가 기존의 단섬유 파이버로 부직포를 단순히 적층하여 열처리하고, 성형틀에서 찍어낼 경우, 부직포의 표면 터치가 딱딱한 단점이 있다.In addition, when the nonwoven fabric is simply laminated with a conventional short-fiber fiber, and heat-treated, and taken out of the mold, the surface touch of the nonwoven fabric has a hard disadvantage.

따라서, 카 시트 류의 커버 패드, 차량 내장재의 내피 재, 침구류의 매트리스, 방석용 패드, 브래지어 심지용, 스키복 또는 방한복의 패딩 재 등의 완충재로서의 응용성과 경제성을 높이기 위해 기존의 설비를 최대한 사용하여 제조가 가능하고, 부드러운 터치를 나타내면서도 높은 반발탄성과 내구성이 우수한 소재의 개발이 요구된다.Therefore, the existing equipment can be used as much as possible to improve the applicability and economy as cushioning materials such as car seat cover pads, vehicle interior linings, bedding mattresses, cushion pads, bra wicks, ski clothes or winter wear padding materials. It is required to develop a material which can be manufactured by using, exhibits a soft touch and has excellent high resilience and durability.

상기와 같은 문제점을 해결하기 위하여 본 발명의 목적은 부드러우면서도 반발탄성과 내구성이 우수하고 친환경인 탄성 섬유 구조체 및 이의 제조방법을 제공하는 것이다.In order to solve the above problems, an object of the present invention is to provide a soft yet resilient elasticity and durability and environmentally friendly elastic fiber structure and its manufacturing method.

상기 목적을 달성하기 위해 본 발명은 중공률 20~60%인 중공 폴리에스테르 섬유 5~80중량%, 고유점도(Intrinsic Viscosity;IV) 0.63~1.30인 폴리에스테르계 고분자와 고유점도 0.45~0.56인 폴리에스테르계 고분자로 이루어진 복합섬유를 포함하는 스트레치 섬유 5~80중량% 및 융점 110~180℃인 열융착 바인더 폴리에스테르 섬유 5~80중량%를 포함하는 탄성 섬유 구조체를 제공한다.In order to achieve the above object, the present invention provides a polyester-based polymer having an intrinsic viscosity of 0.45 to 0.56 with a hollow polyester fiber 5 to 80% by weight, intrinsic viscosity (IV) of 0.63 to 1.30. It provides an elastic fiber structure comprising 5 to 80% by weight of a stretch fiber comprising a composite fiber consisting of an ester-based polymer and 5 to 80% by weight of a heat-sealing binder polyester fiber having a melting point of 110 to 180 ° C.

또한, 본 발명은 상기 복합섬유가 사이드-바이-사이드형, 시스-코어형, 편심 시스-코어형으로 이루어진 군에서 선택되는 섬유인 것을 특징으로 한다.In addition, the present invention is characterized in that the composite fiber is selected from the group consisting of side-by-side type, sheath-core type, eccentric sheath-core type.

또한, 본 발명은 상기 스트레치 섬유가 고유점도 0.90~1.30인 폴리트리에틸렌 테레프탈레이트와 고유점도 0.45~0.56인 폴리에틸렌 테레프탈레이트로 이루어진 사이드 바이 사이드 형의 스트레치 섬유인 것을 특징으로 한다.In addition, the present invention is characterized in that the stretch fiber is a side-by-side type of stretch fiber composed of polytriethylene terephthalate having an intrinsic viscosity of 0.90 to 1.30 and polyethylene terephthalate having an intrinsic viscosity of 0.45 to 0.56.

또한, 본 발명은 상기 열융착 바인더 폴리에스테르 섬유가 중공 열융착 바인더 폴리에스테르 섬유인 것을 포함한다.In addition, the present invention includes that the heat-sealed binder polyester fibers are hollow heat-sealed binder polyester fibers.

또한, 본 발명은 상기 중공 폴리에스테르계 섬유가 강도 2~5g/d, 신도 30~60%, 압축률 10~50%, 압축회복률 80~100%이고, 상기 폴리에스테르계 스트레치 섬유가 강도 2~5g/d, 신도 40~80%, 권축수 10~17개, 권축도 14~20, 수축률 2~10%, 섬유장 20~90mm이고, 상기 열융착 폴리에스테르계 섬유가 강도 2~5g/d, 신도 20~60%, 권축수 5~15개, 권축도 10~20, 수축률 2~8%인 것을 특징으로 하여 가볍고 부드러우면서도 우수한 탄성을 나타내는 탄성 섬유 구조체를 제공한다.In addition, the present invention is the hollow polyester fiber is strength 2 ~ 5g / d, elongation 30 ~ 60%, compression rate 10 ~ 50%, compression recovery rate 80 ~ 100%, the polyester stretch fiber 2 ~ 5g strength / d, elongation 40 to 80%, crimp number 10 to 17, crimping degree 14 to 20, shrinkage rate 2 to 10%, fiber length 20 to 90 mm, the heat-sealing polyester fiber is 2 to 5 g / d, Elongation 20 ~ 60%, crimp number 5 ~ 15, crimping degree 10 ~ 20, shrinkage rate of 2 to 8, characterized in that it provides an elastic fiber structure showing a light, soft and excellent elasticity.

또한, 본 발명은 상기 중공 폴리에스테르 섬유의 굵기가 4~15 데니어이고, 상기 폴리에스테르계 스트레치 섬유는 2~9 데니어이고, 상기 열융착 바인더 폴리에스테르 섬유는 2~10 데니어인 것을 특징으로 한다.In addition, the present invention is the thickness of the hollow polyester fiber 4 ~ 15 Denier, the polyester-based stretch fibers are 2 to 9 denier, the heat-sealing binder polyester fibers are characterized in that 2 to 10 denier.

또한, 본 발명은 상기 탄성 섬유 구조체가 단섬유 열융착 부직포인 것이 다양한 용도에 적용되기에 좋다.In addition, the present invention is preferably applied to a variety of applications that the elastic fiber structure is a short-fiber heat-sealed nonwoven fabric.

또한, 본 발명은 상기 부직포의 두께가 5~50mm인 것이 탄성과 완충성을 나타내기에 좋다.In addition, the present invention is that the thickness of the nonwoven fabric is 5 to 50mm is good for showing elasticity and cushioning properties.

또한, 본 발명은 중공률 20~60%인 중공 폴리에스테르계 섬유 5~80중량%, 고유점도 0.63~1.30인 폴리에스테르계 고분자와 고유점도 0.45~0.56인 폴리에스테르계 고분자로 이루어진 복합섬유를 포함하는 스트레치 섬유 5~80중량% 및 융점 110~180℃인 열융착 바인더 폴리에스테르계 섬유 5~80중량%를 혼합하여 단섬유 혼합체를 이루는 섬유 혼합단계; 상기 단섬유 혼합체를 웹으로 제조하는 카딩단계; 상기 카딩단계를 거친 단섬유 혼합체를 80~200℃에서 열처리하는 열처리단계; 및 상기 열처리된 단섬유 혼합체를 냉각하여 탄성 섬유 구조체가 제조되는 냉각단계를 포함하는 탄성 섬유 구조체의 제조방법을 제공한다.In addition, the present invention includes a composite fiber consisting of 5 to 80% by weight hollow polyester fiber having a 20% to 60% hollow fiber, a polyester polymer having an intrinsic viscosity of 0.63 to 1.30 and a polyester polymer having an intrinsic viscosity of 0.45 to 0.56. A fiber mixing step of forming a short fiber mixture by mixing 5 to 80% by weight of the stretch fiber and 5 to 80% by weight of the heat-sealing binder polyester fiber having a melting point of 110 to 180 ° C; A carding step of manufacturing the short fiber mixture into a web; A heat treatment step of heat treating the short fiber mixture passed through the carding step at 80 to 200 ° C .; And a cooling step of cooling the heat treated short fiber mixture to produce an elastic fiber structure.

이하 본 발명에 첨부된 도면을 참조하여 본 발명의 바람직한 실시예를 상세히 설명하기로 한다. 우선, 도면들 중, 동일한 구성요소 또는 부품들은 가능한 동일한 참조부호를 나타내고 있음에 유의하여야 한다. 본 발명을 설명함에 있어, 관련된 공지기능 혹은 구성에 대한 구체적인 설명은 본 발명의 요지를 모호하지 않게 하기 위하여 생략한다.Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the accompanying drawings. First of all, it should be noted that in the drawings, the same components or parts denote the same reference numerals as much as possible. In describing the present invention, detailed descriptions of related well-known functions or configurations are omitted in order not to obscure the subject matter of the present invention.

본 명세서에서 사용되는 정도의 용어 "약", "실질적으로" 등은 언급된 의미에 고유한 제조 및 물질 허용오차가 제시될 때 그 수치에서 또는 그 수치에 근접한 의미로 사용되고, 본 발명의 이해를 돕기 위해 정확하거나 절대적인 수치가 언급된 개시 내용을 비양심적인 침해자가 부당하게 이용하는 것을 방지하기 위해 사용된다.The terms "about "," substantially ", etc. used to the extent that they are used herein are intended to be taken to mean an approximation of, or approximation to, the numerical values of manufacturing and material tolerances inherent in the meanings mentioned, Accurate or absolute numbers are used to help prevent unauthorized exploitation by unauthorized intruders of the referenced disclosure.

본 발명의 탄성 섬유 구조체는 중공률 20~60%인 중공 폴리에스테르 섬유 5~80중량%, 고유점도 0.63~1.30인 폴리에스테르계 고분자와 고유점도 0.45~0.56인 폴리에스테르계 고분자로 이루어진 복합섬유를 포함하는 스트레치 섬유 5~80중량%및 융점 110~180℃인 열융착 바인더 폴리에스테르 섬유 5~80중량%를 포함할 수 있는데, 상기 중공 폴리에스테르 섬유, 바인더 폴리에스테르 섬유 및 스트레치 섬유의 혼합비에 따라 요구되는 특징이 발현될 수 있다.The elastic fiber structure of the present invention is a composite fiber consisting of a polyester-based polymer having an intrinsic viscosity of 0.45 to 0.56 and a polyester-based polymer having an intrinsic viscosity of 0.4 to 0.56 It may include 5 to 80% by weight of the stretch fiber containing 5 to 80% by weight of the heat-sealing binder polyester fiber melting point 110 ~ 180 ℃, according to the mixing ratio of the hollow polyester fiber, binder polyester fiber and stretch fiber Required features can be expressed.

따라서, 본 발명의 탄성 섬유 구조체는 모두 폴리에스테르계 섬유로 구성되고, 섬유 간 접착에 있어서도 별도의 유기용제 등이 포함된 접착제 사용 없이 섬유 구조체 내의 저융점 열융착 바인더 섬유에 의해 열접착되므로, 기존에 사용되어 온 폴리우레탄 발포체 특유의 냄새, 시간이 경과함에 따라 황변 현상이 발생하며, 발포 셀 자체의 부식으로 탄성이 저하되어 먼지가 발생하고, 재활용이 어려운 문제 등을 나타내는 폴리우레탄 발포체의 단점을 보완할 뿐만 아니라 폴리우레탄 발포체와 비교하여 유사하거나 우월한 탄성, 형태안정성 및 화학적 안정성이 있는 환경친화적인 효과가 있다.Therefore, the elastic fiber structure of the present invention is all composed of polyester-based fibers, and is also thermally bonded by the low melting point heat-sealed binder fibers in the fiber structure without the use of an adhesive containing a separate organic solvent in the inter-fiber adhesion, The odor peculiar to the polyurethane foams used in the process, yellowing phenomenon occurs over time, and the elasticity of the foam cells themselves decreases due to corrosion of the foam cells. As well as complementary, there are environmentally friendly effects with similar or superior elasticity, shape stability and chemical stability compared to polyurethane foams.

구체적으로 설명하면, 중공률 20~60%인 중공 폴리에스테르 섬유는 섬유 내 중공으로 인해 중공사를 포함하지 않는 제품보다 경량화된 제품의 제조가 가능하고, 탄성이 높게 발휘되는 역할을 한다. 2~6엽 중공구금을 사용하여 방사되어 제조되며 주로 3엽 중공구금을 사용한다. 중공률은 하기 식에 따라 계산될 수 있다. Specifically, the hollow polyester fiber having a hollow ratio of 20 to 60% is capable of producing a lighter product than a product that does not include hollow fiber due to the hollow in the fiber, and serves to exhibit high elasticity. It is produced by spinning using 2 ~ 6 leaf hollow block and mainly uses 3 leaf hollow block. The hollow ratio can be calculated according to the following formula.

중공률(%)= 중공부의 단면적/섬유의 전단면적(중공부 단면적 포함) ㅧ 100Hollow rate (%) = cross section of hollow part / shear area of fiber (including hollow section) 단면 100

본 발명의 중공 폴리에스테르계 섬유는 중공률이 20~60%, 바람직하게는 30~40%가 좋다. 중공률이 20% 미만이면, 섬유 단면의 크기가 크게 되어 탄성이 낮아져 완충성이 높게 발휘되지 않을 우려가 있으며, 60%를 초과하면, 섬유의 강도와 신도 등의 물성이 저하되고 카딩성이 낮아지는 문제가 있다. 본 발명의 중공 폴리에스테르계 섬유는 강도 2~5g/d, 신도 30~60%, 압축률 10~50%, 압축회복률 80~100%인 것이 요구되는 강도가 유지되면서 탄성이 발현되기에 좋다.The hollow polyester fiber of the present invention has a hollow ratio of 20 to 60%, preferably 30 to 40%. If the porosity is less than 20%, the size of the fiber cross-section is large, the elasticity is low, there is a fear that the cushioning properties are not exhibited high. There is a problem. Hollow polyester fiber of the present invention is good to express the elasticity while maintaining the strength required to be 2 ~ 5g / d, 30 ~ 60% elongation, 10 ~ 50% compression rate, 80 ~ 100% compression recovery rate.

또한, 고유점도 0.63~1.30인 폴리에스테르계 고분자와 고유점도 0.45~0.56인 폴리에스테르계 고분자로 이루어진 복합섬유를 포함하는 스트레치 섬유는 탄성률, 압축회복성을 나타내는 역할을 하는데, 상기 복합섬유는 그 형태가 사이드-바이-사이드형, 시스-코어형, 편심 시스-코어형 일 수 있다. 바람직하게는 고유점도 0.90~1.30인 폴리트리메틸렌 테레프탈레이트(PTT)와 고유점도 0.45~0.56인 폴리에틸렌 테레프탈레이트(PET)로 이루어진 사이드 바이 사이드 형의 스트레치 섬유가 탄성을 높게 나타내기에 좋다. 상기 두 가지 형태의 점도를 갖는 복합섬유 형태는 점도 차이에 따라 상기 각 점도를 갖는 고분자의 서로 다른 성질이 나타나게 되어 탄성이 우수하게 발휘될 수 있다. 상기 범위를 벗어나면 방사팩 내의 안정성이 낮아져서 고분자간의 결합력이 나빠지거나 방사 시 폴리머 용융점도차에 의한 곡사 발생으로 방사 작업성이 불량해지는 문제가 발생하므로 섬유를 구성하는 각 고분자의 점도 범위를 유지하도록 하여 서로간의 상용성을 유지하는 것이 중요하다. 본 발명의 스트레치 섬유는 강도 2~5g/d, 신도 40~80%, 권축수 10~15개, 권축도 14~20, 수축률 2~10%, 섬유장 20~90mm인 것이 우수한 탄성을 나타내기에 좋다.In addition, the stretch fiber comprising a composite fiber made of a polyester polymer having an intrinsic viscosity of 0.63 to 1.30 and a polyester polymer having an intrinsic viscosity of 0.45 to 0.56 serves to exhibit elastic modulus and compressive recovery. It may be a side-by-side type, sheath-core type, eccentric sheath-core type. Preferably, the side by side type stretch fiber composed of polytrimethylene terephthalate (PTT) having an intrinsic viscosity of 0.90 to 1.30 and polyethylene terephthalate (PET) having an intrinsic viscosity of 0.45 to 0.56 may exhibit high elasticity. The composite fiber form having the viscosity of the two forms may be excellent in elasticity because the different properties of the polymer having each of the viscosity appears according to the difference in viscosity. If it is out of the above range, the stability in the spin pack is lowered, so that the bonding strength between the polymer is bad or the spinning workability is poor due to the bending of the polymer due to the melt viscosity difference during spinning, so that the viscosity range of each polymer constituting the fiber to be maintained It is important to maintain compatibility with each other. The stretch fiber of the present invention exhibits excellent elasticity of 2 to 5 g / d, 40 to 80% elongation, 10 to 15 crimps, 14 to 20 crimps, 2 to 10% shrinkage, and 20 to 90 mm long fiber. good.

또한, 융점 110~180℃인 열융착 바인더 폴리에스테르계 섬유는 저온에서도 섬유간 접착을 하여 형태안정성을 유지하는 역할을 하는데, 기존의 250℃ 정도의 일반 폴리에스테르보다 저온에서 열처리를 해도 그와 유사한 물성을 갖게 되고, 저온 열처리가 가능하여 추후 융착을 위한 열처리 비용이 감소되는 효과가 있다. 융점이 110℃ 미만인 경우, 제품으로 제조 시 내열성이 저하될 우려가 있으며, 180℃를 초과하면 열처리 비용 절감의 효과가 없다. 한편, 본 발명은 상기 열융착 바인더 폴리에스테르계 섬유로서, 중공 열융착 바인더 폴리에스테르계 섬유인 것이 사용될 수 있는데, 융점이 110~180℃ 이면서 5~50%의 중공률을 갖는 중공 형태의 섬유는 기존의 열접착성 섬유에 비하여 추가적인 효과는 열융착 후에도 사 내부의 중공효과로 경량화에도 기여한다. 본 발명의 열융착 폴리에스테르계 섬유는 강도 2~5g/d, 신도 20~60%, 권축수 5~15개, 권축도 10~20, 수축률 2~8%인 것이 제품으로 제조 시 형태안정성 유지와 경량성, 부드러운 촉감을 나타내기에 좋다.In addition, the heat-sealing binder polyester fiber having a melting point of 110 ~ 180 ℃ to maintain the shape stability by bonding between fibers at low temperatures, similar to the heat treatment at a low temperature than conventional polyester of about 250 ℃ It has physical properties and can be subjected to low temperature heat treatment, thereby reducing the heat treatment cost for fusion. If the melting point is less than 110 ℃, there is a fear that the heat resistance during the manufacturing of the product is lowered, if it exceeds 180 ℃ there is no effect of reducing the heat treatment cost. On the other hand, the present invention may be used as the heat-sealing binder polyester fiber, a hollow heat-sealing binder polyester fiber, the hollow fiber having a melting rate of 110 ~ 180 ℃ and 5 to 50% Compared with the existing heat-adhesive fiber, the additional effect contributes to the weight reduction due to the hollow effect inside the yarn even after heat sealing. Heat-sealed polyester fiber of the present invention has a strength of 2 ~ 5g / d, 20 ~ 60% elongation, 5 ~ 15 crimps, 10 ~ 20 crimping, 2 ~ 8% shrinkage to maintain morphological stability when manufacturing the product It is good to show light weight, soft touch.

또한, 본 발명은 상기 중공 폴리에스테르 섬유의 굵기가 4~15 데니어이고, 상기 폴리에스테르계 스트레치 섬유는 2~9 데니어이고, 상기 열융착 바인더 폴리에스테르 섬유는 2~10 데니어인 것이 최종 제품의 탄성과 강도가 좋고, 부드러운 촉감을 나타내는데, 본 발명의 탄성 섬유 구조체를 구성하는 섬유의 굵기가 각각 상기 범위 미만이면, 섬유의 강도와 신도가 낮아게 되고, 상기 범위를 초과하면 최종 제품으로 제조 시 중량이 너무 커지며 표면 터치가 거칠어질 우려가 있다.In addition, the present invention is the thickness of the hollow polyester fiber 4 ~ 15 Denier, the polyester-based stretch fibers are 2 to 9 denier, the heat-sealing binder polyester fibers are 2 to 10 denier is good elasticity and strength of the final product, showing a soft touch, the elastic fiber structure of the present invention When the thickness of the fibers constituting the is less than the above range, respectively, the strength and elongation of the fiber is low, and when the above range is exceeded, the weight is too large and the surface touch may be rough when manufactured as a final product.

한편, 본 발명의 탄성 섬유 구조체는 중공 폴리에스테르계 섬유 5~80중량%, 폴리에스테르계 스트레치 섬유 5~80중량% 및 열융착 바인더 폴리에스테르계 섬유 5~80중량%인 함량으로 포함되도록 하는 것이 부드러운 터치와 더불어 탄성, 강도, 내구성을 나타내기에 좋은데, 중공 폴리에스테르계 섬유가 5중량%미만이면, 최종 제품의 중량이 너무 많이 나갈 우려가 있고, 폴리에스테르계 스트레치 섬유가 5중량% 미만이면, 탄성 발현이 저하되며, 열융착 바인더 폴리에스테르계 섬유가 5중량% 미만이면, 최종 제품의 결속력이 약해져 강도가 저하되되는 문제가 있다. 반면, 중공 폴리에스테르계 섬유가 80중량%를 초과하면 최종 제품의 압축영구줄음율이 낮아질 우려가 있으며, 폴리에스테르계 스트레치 섬유가 80중량%를 초과하면 섬유(fiber)의 수축으로 인해 섬유 구조체의 밀도가 올라가 탄성보다는 강력이 너무 강해지고 터치도 거칠게 될 우려가 있고, 열융착 바인더 폴리에스테르계 섬유가 80중량%를 초과하면 반발 탄성력이 낮아지고 최종 제품의 촉감이 딱딱하게 굳어 터치가 불량해질 우려가 있다. On the other hand, the elastic fiber structure of the present invention is to be included in the content of 5 to 80% by weight hollow polyester fiber, 5 to 80% by weight polyester stretch fiber and 5 to 80% by weight of the heat-sealing binder polyester fiber It is good for showing elasticity, strength and durability with soft touch. If the hollow polyester fiber is less than 5% by weight, the final product may weigh too much, and if the polyester stretch fiber is less than 5% by weight, When the elastic expression is lowered and the heat-sealing binder polyester fiber is less than 5% by weight, there is a problem that the binding force of the final product is weakened and the strength is lowered. On the other hand, if the hollow polyester-based fiber exceeds 80% by weight, the compressive permanent shrinkage of the final product may be lowered, and if the polyester-based stretch fiber exceeds 80% by weight of the fiber structure due to shrinkage of the fiber (fiber) If the density rises and the strength is stronger than elasticity, the touch may be rough, and if the heat-sealing binder polyester fiber exceeds 80% by weight Repulsive elasticity is lowered and the touch of the final product is hardened, there is a fear that the touch is poor.

최종 물성에 있어서는 반복압출줄음율이 80%이하, 바람직하게는 10~80%이거나 반발탄성이 55%이상, 바람직하게는 55~90%인 제품이 탄성이 우수하면서 우수한 탄성을 오랫동안 유지하기에 좋다. 상기 범위를 넘어서면 반복압축에 의한 형태변형 및 반발탄성의 저하 현상이 발생하는 단점이 있다.In the final physical properties, products having a repetitive extrusion reduction ratio of 80% or less, preferably 10 to 80% or repulsive elasticity of 55% or more, preferably 55 to 90% are excellent in elasticity and excellent in maintaining excellent elasticity for a long time. . Beyond the above range, there is a disadvantage in that the shape deformation and rebound elasticity degradation phenomenon due to repeated compression occurs.

따라서, 요구되는 물성을 위해 각 섬유의 비율을 용도에 맞게 상기 범위 내에서 조절하여 사용하는 것이 좋다.Therefore, it is good to use the ratio of each fiber within the said range according to a use for the required physical property.

본 발명의 탄성 섬유 구조체는 상기 중공 폴리에스테르계 섬유, 폴리에스테르계 스트레치 섬유 및 열융착 바인더 폴리에스테르계 섬유를 용도에 맞는 혼합비로 제조된 단섬유 열융착 부직포인 것이 기존의 부직포 제조설비로도 용이하게 제조가능하며, 탄성이 요구되는 다양한 용도에 적용되기에 좋다. 상기 부직포의 두께가 5~50mm인 것이 탄성과 완충성을 나타내기에 좋으며, 두께가 5mm미만이면 두께가 얇아서 손으로 눌렀을 때 탄성효과 발현이 약해질 우려가 있으며, 50mm를 초과하면 부직포 열처리시에 내부로 열전달이 어려워 형태안정성이 떨어지게 된다.The elastic fiber structure of the present invention is a short-fiber heat-sealed nonwoven fabric made of a blending ratio of the hollow polyester fiber, polyester stretch fiber, and heat-sealed binder polyester-based fiber in accordance with the purpose, and is easily used as a conventional nonwoven fabric manufacturing facility. It can be manufactured, and is suitable for various applications requiring elasticity. When the thickness of the nonwoven fabric is 5 to 50mm, it is good to show elasticity and cushioning properties. If the thickness is less than 5mm, the thickness is so thin that the elastic effect may be weakened when pressed by hand. As heat transfer is difficult, shape stability decreases.

도 1은 본 발명의 바람직한 일실시예에 따른 탄성 섬유 구조체의 제조 공정도이다. 도 1을 참조하면, 본 발명의 탄성 섬유 구조체는 섬유 혼합단계 S100, 카딩단계 S200, 열처리단계 S300 및 냉각단계를 포함하여 제조될 수 있다. 본 발명의 탄성 섬유 구조체는 새로운 장치를 이용할 필요 없이 섬유 혼합 비율과 열처리 온도를 조절하고, 기존의 부직포 제조하는 장치를 사용하여 제조함으로써 부직포 제조가 용이하여 비용 절감이 가능하다.1 is a manufacturing process diagram of the elastic fiber structure according to an embodiment of the present invention. Referring to FIG. 1, the elastic fiber structure of the present invention may be manufactured including a fiber mixing step S100, a carding step S200, a heat treatment step S300, and a cooling step. The elastic fiber structure of the present invention can be manufactured by using a nonwoven fabric manufacturing apparatus by adjusting the fiber mixing ratio and heat treatment temperature without using a new device, it is easy to manufacture a nonwoven fabric, it is possible to reduce the cost.

구체적으로 설명하면, 섬유 혼합단계 S100에서, 중공률 20~60%인 중공 폴리에스테르계 섬유 5~80중량%, 고유점도 0.63~1.30인 폴리에스테르계 고분자와 고유점도 0.450~0.560인 폴리에스테르계 고분자로 이루어진 복합섬유를 포함하는 스트레치 섬유 5~80중량% 및 융점 110~180℃인 열융착 바인더 폴리에스테르계 섬유 5~80중량%를 요구되는 물성에 맞도록 혼합비를 조절하여 혼합하여 단섬유 혼합체를 제조하는 혼합단계를 진행한다.Specifically, in the fiber mixing step S100, 5 to 80% by weight of the hollow polyester fiber having a hollow ratio of 20 to 60%, a polyester polymer having an intrinsic viscosity of 0.63 to 1.30 and a polyester polymer having an intrinsic viscosity of 0.450 to 0.560 5 to 80% by weight of the stretch fiber comprising a composite fiber consisting of 5 to 80% by weight of the heat-sealing binder polyester fiber having a melting point of 110 ~ 180 ℃ mixed by adjusting the mixing ratio to meet the required physical properties Proceed with the mixing step to prepare.

다음으로, 단섬유 혼합체를 웹으로 제조하는 카딩단계를 거친 후 상기 카딩단계를 거친 단섬유 혼합체를 80~200℃에서 열처리하되, 상기 열처리는 상기 온도에서 열풍으로 컨베이어 벨트 방식으로 열처리하고, 최종 롤러에서 다시 열처리를 하여 열처리단계를 진행시키는 것이 좋은데, 상기 온도는 각 섬유의 물성을 저하시키지 않고 촉감을 유지하도록 하기에 좋고, 열풍은 제조된 웹의 형태를 망가뜨리지 않고 균일한 건조가 이루어지도록 하기에 좋다.Next, after the carding step of manufacturing the short fiber mixture as a web, the heat treatment of the short fiber mixture after the carding step at 80 ~ 200 ℃, the heat treatment is heat treated in a conveyor belt method with hot air at the temperature, the final roller It is good to proceed to the heat treatment step by heat treatment again, the temperature is good to maintain the touch without deteriorating the physical properties of each fiber, hot air to ensure uniform drying without damaging the shape of the manufactured web Good for

이후, 상기 열처리된 단섬유 혼합체를 냉각하여 탄성 섬유 구조체가 제조되는 냉각단계를 진행함으로써 본 발명의 탄성 섬유 구조체를 완성할 수 있다.  Subsequently, the elastic fiber structure of the present invention may be completed by cooling the heat treated short fiber mixture to proceed a cooling step in which the elastic fiber structure is manufactured.

상술한 바와 같이 본 발명의 탄성 섬유 구조체는 중공 폴리에스테르계 섬유, 폴리에스테르계 스트레치 섬유 및 열융착 바인더 폴리에스테르계 섬유를 포함하도록 하여 가볍고, 부드러운 터치를 나타내면서도 탄성과 내구성이 탁월한 효과가 있다. As described above, the elastic fiber structure of the present invention includes hollow polyester fibers, polyester stretch fibers, and heat-sealed binder polyester fibers to provide a light, soft touch and excellent elasticity and durability.

또한, 본 발명의 탄성 섬유 구조체는 구조체를 구성하는 섬유의 혼합비를 다양하게 하여 각 섬유의 특성이 다양하게 발휘되도록 조절이 용이하여, 요구되는 용도에 다양하게 적용할 수 있는 효과가 있다.In addition, the elastic fiber structure of the present invention can be easily adjusted so as to exhibit various characteristics of each fiber by varying the mixing ratio of the fibers constituting the structure, there is an effect that can be applied to various applications.

또한, 본 발명의 탄성 섬유 구조체는 모두 폴리에스테르계 섬유로 구성되고, 섬유 간 접착 시 별다른 접착제 사용 없이 섬유 구조체 내의 저융점 열융착 바인더 섬유에 의해 열접착 되므로, 기존의 폴리우레탄 발포체와 비교하여 유사하거나 우월한 탄성을 지니면서도 형태안정성과 화학적 안정성을 나타내며 환경친화적인 효과가 있다.In addition, since the elastic fiber structure of the present invention is all composed of polyester-based fibers, and is thermally bonded by the low-melting hot-melt binder fibers in the fiber structure without using any adhesive when bonding between fibers, it is similar to the conventional polyurethane foam It has excellent elasticity, but exhibits form stability and chemical stability, and has an environmentally friendly effect.

또한, 본 발명의 방법은 기존의 장치를 사용함으로써 부직포 제조가 용이하고 비용 절감 효과가 있다.In addition, the method of the present invention is easy to manufacture non-woven fabrics by using the existing apparatus and there is a cost saving effect.

본 발명의 탄성 섬유 구조체는 카 시트 류의 커버 패드, 차량 내장재의 내피 재, 침구류의 매트리스, 방석용 패드, 브래지어 심지용, 스키복 또는 방한복의 패딩 재 등의 완충재에 적용되는 효과가 있다.The elastic fiber structure of the present invention has an effect that is applied to a cushioning material, such as car seat cover pads, vehicle interior materials, bedding mattresses, cushion pads, bra wicks, ski clothes or winter clothing padding material.

도 1은 본 발명의 바람직한 일실시예에 따른 탄성 섬유 구조체의 제조 공정도.
도 2는 본 발명의 탄성 시료에 대한 측정기기의 개략도로서 (a)영구압축줄음율 측정 기계, (b) 반발탄성 측정 기계.
1 is a manufacturing process of the elastic fiber structure according to an embodiment of the present invention.
Figure 2 is a schematic diagram of the measuring device for the elastic sample of the present invention (a) permanent compression rate measuring machine, (b) rebound elasticity measuring machine.

하기의 실시예를 통하여 좀 더 상세하게 설명하고자 한다.Through the following examples will be described in more detail.

실시예 1Example 1

중공률 34%, 섬도 8.0 데니어, 강도 3.3g/d, 신도 51%, 압축률 46%, 압축회복률 91%, 중공률 30%, 섬유장 64mm인 중공 폴리에틸렌 테레프탈레이트(PET) 섬유(섬유 A) 45중량%, 섬도 2.5데니어, 강도 2.8g/d, 신도 105%, 크림프신장률 52%, 회복률 32%, 수축률 96%, 섬유장 64mm이되 고유점도 0.95인 폴리트리메틸렌 테레프탈레이트(PolyteTrimethylene Terephthalate;PTT)와 고유점도 0.52인 폴리에틸렌 테레프탈레이트(Polyethylene terephthalate;PET)로 이루어진 사이드 바이 사이드 형의 스트레치 섬유(섬유 B) 45중량%, 섬도 4.4 데니어, 강도 3.6g/d, 신도 40%, 권축수 9.4개, 권축도 16.5, 수축률 6.4%, 섬유장 64mm인 열융착 바인더 폴리에틸렌 테레프탈레이트 섬유(섬유 C) 10중량%를 혼합하여 단섬유 혼합체를 구성하여 카딩기에서 믹싱한 후, 혼합체를 웹으로 제조하는 카딩단계를 거쳐 이를 170℃ 열풍으로 컨베이어벨트 방식으로 열처리하고, 150℃인 최종 롤러에서 한 번 더 열처리를 한 후 상온에서 냉각하여 두께 15mm이고 중량 330 g/m2인 부직포를 제조하였다.Hollow Poly 34%, Fineness 8.0 Denier, Strength 3.3g / d, Elongation 51%, Compression 46%, Compression Recovery 91%, Hollow 30%, Hollow Polyethylene Terephthalate (PET) Fiber 64mm Fiber (Fiber A) 45 PolyTrimethylene Terephthalate (PTT) with weight%, fineness 2.5 denier, strength 2.8 g / d, elongation 105%, crimp elongation 52%, recovery rate 32%, shrinkage 96%, fiber length 64mm, intrinsic viscosity 0.95 45% by weight of side by side type stretch fiber (fiber B) made of polyethylene terephthalate (PET) having an intrinsic viscosity of 0.52, fineness 4.4 denier, strength 3.6 g / d, elongation 40%, crimping water 9.4, crimping Figure 16.5, shrinkage rate of 6.4%, filament length 64mm heat-sealing binder polyethylene terephthalate fiber (fiber C) by mixing 10% by weight to form a short fiber mixture and mixing in a carding machine, the carding step of manufacturing the mixture into a web After this, it is conveyed by 170 ℃ hot air After the heat treatment by the ear belt method, and further heat treatment at the final roller at 150 ℃ and cooled at room temperature to prepare a non-woven fabric having a thickness of 15mm and a weight of 330 g / m 2 .

실시예 2Example 2

섬유 A는 70중량%, 섬유 B는 20중량% 및 섬유 C는 10중량%로 혼합하여 실시예 1과 같이 제조하여 두께 15mm이고 중량 300 g/m2인 부직포를 제조하였다.70% by weight of fiber A, 20% by weight of fiber B and 10% by weight of fiber C were prepared as in Example 1 to prepare a nonwoven fabric having a thickness of 15 mm and a weight of 300 g / m 2 .

실시예 3Example 3

섬유 A는 20중량%, 섬유 B는 70중량% 및 섬유 C는 10중량%로 혼합하여 실시예 1과 같이 제조하여 두께 15mm이고 중량 350 g/m2인 부직포를 제조하였다.20% by weight of fiber A, 70% by weight of fiber B and 10% by weight of fiber C were prepared as in Example 1 to prepare a nonwoven fabric having a thickness of 15 mm and a weight of 350 g / m 2 .

실시예 4Example 4

섬유 A는 35중량%, 섬유 B는 35중량% 및 섬유 C는 30중량%로 혼합하여 실시예 1과 같이 제조하여 두께 15mm이고 중량 410 g/m2인 부직포를 제조하였다.Fiber A was prepared by mixing in 35% by weight, fiber B 35% by weight and fiber C 30% by weight to prepare a nonwoven fabric having a thickness of 15mm and weight 410 g / m 2 .

비교예 1 Comparative Example 1

섬유 A는 4중량%, 섬유 B는 11중량%, 섬유 C는 85중량%인 것을 제외하고는 실시예 1과 동일하게 실시하였다.The same procedure as in Example 1 was conducted except that fiber A was 4% by weight, fiber B was 11% by weight, and fiber C was 85% by weight.

비교예 2Comparative Example 2

섬유 A는 5중량%, 섬유 B는 85중량%, 섬유 C는 10중량%인 것을 제외하고는 실시예 1과 동일하게 실시하였다.The same procedure as in Example 1 was conducted except that the fiber A was 5% by weight, the fiber B was 85% by weight, and the fiber C was 10% by weight.

비교예 3Comparative Example 3

섬유 A는 85중량%, 섬유 B는 5중량%, 섬유 C는 10중량%인 것을 제외하고는 실시예 1과 동일하게 실시하였다.
Fiber A was carried out in the same manner as in Example 1 except that 85% by weight, fiber B was 5% by weight, and fiber C was 10% by weight.

* 시험방법* Test Methods

1) 압축영구 줄음율 (실온 및 70℃)1) Compression permanent reduction rate (room temperature and 70 ℃)

시험편은 한 변 길이 50 mm 이상 및 두께 20 mm 이상의 정사각형으로 제작하였으며, 압축판으로 시험편 두께의 50%까지 압축 고정하고, 상온 혹은 70℃의 항온조 내에서 연속 22시간 유지한 후, 압축판 제거 후 상온에서 30분간 방치 후 두께를 측정하여 하기의 식으로 계산하였다.The test piece was made in a square of 50 mm or more in length and 20 mm or more in thickness, and was compressed and fixed to 50% of the thickness of the test piece with a compression plate, and maintained for 22 hours in a constant temperature or 70 ° C constant temperature bath. After leaving for 30 minutes at room temperature, the thickness was measured and calculated by the following equation.

C = (t 0-t 1)/t 0 × 100 C = ( t 0 - t 1 ) / t 0 × 100

C: 영구압축줄음율 (%)C: permanent compression rate (%)

t0 및 t1:시험 전/후 시험편의 두께 (mm)t 0 and t 1 : Thickness of test piece before and after test (mm)

2) 반발탄성2) resilience

시험편은 한 변 길이 50 mm 이상 및 두께 50 mm 이상의 정사각형으로 제작하였으며, 무게 16g, 지름 16mm의 강철 볼을 500mm의 높이에서 시험편에 낙하시켜 최대 반발 높이를 측정한 후, 3개의 시험편 각각에서 1분 이내 연속으로 최소 3회 이상의 반발값을 측정하여 중앙값을 반발탄성값(%)으로 하였다.The test piece was made into a square with a side length of 50 mm or more and a thickness of 50 mm or more. A steel ball with a weight of 16 g and a diameter of 16 mm was dropped on the test piece at a height of 500 mm, and the maximum rebound height was measured. At least three times or more of rebound values were measured continuously, and the median value was made into the rebound elastic value (%).

도 2는 본 발명의 탄성 시료에 대한 측정기기의 개략도로서 (a)영구압축줄음율 측정 기계, (b) 반발탄성 측정 기계를 나타낸다.2 is a schematic diagram of a measuring device for an elastic sample of the present invention, showing (a) a permanent compression rate measuring machine and (b) a rebound elasticity measuring machine.

3) 공기 저항성(공기 투과도; Air permeability)3) Air resistance (Air permeability)

측정 규격은 보통 ASTM F778-88 또는 JIS P 8117(2회 평균값)을 사용하나, 본 발명에서는 JIS P 8117(2회 평균값)을 사용하였다.As a measurement standard, ASTM F778-88 or JIS P 8117 (average twice) was used, but in the present invention, JIS P 8117 (average twice) was used.

측정방법은 먼저 시료의 두께를 2회 측정하여 평균값(단위: mm)을 구한 후 2.5cm×2.5cm 의 크기로 시험편을 준비한다. 상기 준비된 건조(dry) 상태의 시료를 자동 펌포로미터(Automated Permporometer, 제조사: PMI(Porous Materials Inc.), 모델명: CFP-1200-AEL)장치에 장착하고 공기유입선(air inlet line)을 연결한다. In the measurement method, first measure the thickness of the sample twice to find the average value (unit: mm), and then prepare the specimen in the size of 2.5cm × 2.5cm. The prepared dry sample is mounted on an automated permporometer (manufacturer: Porous Materials Inc.), model name: CFP-1200-AEL, and connected to an air inlet line. do.

이후, 장치에 연결된 컴퓨터 프로그램의 메인 메뉴(Main menu)에서 실행(Execute)의 자동테스트(autotest) 버튼을 클릭하고, 쇼 어드벤스드 세팅wm(show advanced settings)를 클릭하여 나오는 화면에 측정할 압력범위를 입력하고 파일 위치와 이름, 시료명, 시료 두께 등을 입력한다. 테스트 타입(test type)에서 공기투과(air permeametry)를 선택 후 테스트(test)를 시작한다. 분석이 끝나고 보고서(report)를 출력할 때 투과 시험 보고서(permeability test report)에서 어떤 계수로 표현할 것인지 선택 (Darcy, Gurley, Frazier, Rayl)한 후, 하기 식으로 계산되는 성적서 Gurley method (JIS P 8117) 2회 평균값을 기재하였다.
After that, click Execute autotest button in the main menu of the computer program connected to the device, and click show advanced settings. Enter the file location, name, sample name, and sample thickness. Select air permeametry from the test type and start the test. When the report is finished after the analysis, select the coefficients to be expressed in the permeability test report (Darcy, Gurley, Frazier, Rayl), and then report the Gurley method (JIS P 8117). ) The average value of two times is described.

Calculation  Calculation

Figure pat00001

Figure pat00001

4) 감성평가4) Emotional Evaluation

부직포 표면을 눌러보아 부드러운 정도를 평가하였다.
The softness was evaluated by pressing the nonwoven surface.

구분division 실시예 1Example 1 실시예 2Example 2 실시예 3Example 3 실시예 4Example 4 비교예 1Comparative Example 1 비교예 2Comparative Example 2 비교예 3Comparative Example 3 섬유 A (중량%)Fiber A (% by weight) 4545 7070 2020 3535 44 55 8585 섬유 B (중량%)Fiber B (% by weight) 4545 2020 7070 3535 1111 8585 55 섬유 C (중량%)Fiber C (% by weight) 1010 1010 1010 3030 8585 1010 1010 부직포 두께(mm)Nonwoven Thickness (mm) 1515 1515 1515 1515 1515 1515 1515 최종열처리 온도(℃)Final heat treatment temperature (℃) 150150 150150 150150 150150 150150 150150 150150 영구압축줄음율
(70℃,%)
Permanent compression
(70 ℃,%)
5757 7575 4242 7070 3030 5050 8282
반발탄성(%)Resilience (%) 6565 5757 4646 7272 2020 5252 5353 공기 저항성 (sec/100ℓ)Air resistance (sec / 100ℓ) 0.190.19 0.150.15 0.170.17 0.260.26 0.450.45 0.160.16 0.130.13 중량(g/m2)Weight (g / m 2 ) 330330 300300 350350 410410 550550 470470 270270 감성평가
부직포 표면 누름
Emotional Evaluation
Nonwoven surface pressed
부드러움Softness 조금
딱딱함
a little
crustiness
매우 부드러움Very soft 딱딱함crustiness 딱딱함crustiness 조금
부드러움
a little
Softness
조금
부드러움
a little
Softness

표 1의 결과로 보아, 중공 PET 섬유의 비율이 올라가면 전체적인 중량이 경량화되고 공기 저항성이 낮아진다(공기 투과가 잘 된다). 또한, 스트레치사의 비율이 올라가면 탄성률이 좋아지며, 열융착 바인더 섬유의 비율이 올라가면 형태안정성이 증가한다는 것을 확인하였다. As a result of Table 1, when the ratio of the hollow PET fiber is increased, the overall weight is reduced and the air resistance is low (good air permeation). In addition, it was confirmed that the elastic modulus is improved when the ratio of the stretch yarn is increased, and the shape stability is increased when the ratio of the heat-sealed binder fiber is increased.

더불어, 실시예 1,2,4는 비교예 1~3보다 더 우수한 탄성을 나타내고, 실시예 1,3에 있어서는 부드러운 촉감 면에서는 더욱 우수한 효과를 나타낸다는 것을 확인하였다.In addition, it was confirmed that Examples 1, 2 and 4 exhibited more excellent elasticity than Comparative Examples 1 to 3, and Examples 1 and 3 exhibited more excellent effects in terms of soft touch.

이상에서 설명한 본 발명은 전술한 실시예 및 첨부된 도면에 의해 한정되는 것이 아니고, 본 발명의 기술적 사상을 벗어나지 않는 범위 내에서 여러 가지 치환, 변형 및 변경이 가능함은 본 발명이 속하는 기술 분야에서 통상의 지식을 가진 자에게 있어서 명백할 것이다.It will be apparent to those skilled in the art that various modifications and variations can be made in the present invention without departing from the spirit or scope of the inventions. It will be clear to those who have knowledge of.

Claims (9)

중공률 20~60%인 중공 폴리에스테르계 섬유 5~80중량%, 고유점도 0.63~1.30인 폴리에스테르계 고분자와 점도 0.45~0.56인 폴리에스테르계 고분자로 이루어진 복합섬유를 포함하는 스트레치 섬유 5~80중량% 및 융점 110~180℃인 열융착 바인더 폴리에스테르계 섬유 5~80중량%를 포함하는 탄성 섬유 구조체.Stretch fiber 5 ~ 80 comprising a composite fiber composed of a hollow polyester fiber having a porosity of 20% to 60% 5 to 80% by weight, a polyester polymer having an intrinsic viscosity of 0.63 to 1.30 and a polyester polymer having a viscosity of 0.45 to 0.56 An elastic fiber structure comprising 5 to 80% by weight of the heat-sealing binder polyester fiber having a weight% and melting point 110 ~ 180 ℃. 제1항에 있어서,
상기 복합섬유는 사이드-바이-사이드형, 시스-코어형, 편심 시스-코어형으로 이루어진 군에서 선택되는 섬유인 탄성 섬유 구조체.
The method of claim 1,
The composite fiber is an elastic fiber structure is a fiber selected from the group consisting of side-by-side type, sheath-core type, eccentric sheath-core type.
제1항에 있어서,
상기 스트레치 섬유는 고유점도 0.90~1.30인 폴리트리에틸렌 테레프탈레이트와 고유점도 0.45~0.56인 폴리에틸렌 테레프탈레이트로 이루어진 사이드 바이 사이드 형의 스트레치 섬유인 탄성 섬유 구조체.
The method of claim 1,
The stretch fiber is a side-by-side type of stretch fiber composed of polytriethylene terephthalate having an intrinsic viscosity of 0.90 to 1.30 and polyethylene terephthalate having an intrinsic viscosity of 0.45 to 0.56.
제1항에 있어서,
상기 열융착 바인더 폴리에스테르계 섬유는 중공 열융착 바인더 폴리에스테르 섬유인 탄성 섬유 구조체.
The method of claim 1,
The heat-sealed binder polyester fiber is an elastic fiber structure is a hollow heat-sealed binder polyester fiber.
제1항에 있어서,
상기 중공 폴리에스테르계 섬유는 강도 2~5g/d, 신도 30~60%, 압축률 10~50%, 압축회복률 80~100%이고, 상기 폴리에스테르계 스트레치 섬유는 강도 2~5g/d, 신도 40~80%, 권축수 10~15개, 권축도 14~20, 수축률 2~10%, 섬유장 20~90mm이고, 상기 열융착 폴리에스테르계 섬유는 강도 2~5g/d, 신도 20~60%, 권축수 5~15개, 권축도 10~20, 수축률 2~8%인 탄성 섬유 구조체.
The method of claim 1,
The hollow polyester fiber has a strength of 2 ~ 5g / d, elongation 30 ~ 60%, compression rate 10 ~ 50%, compression recovery 80 ~ 100%, the polyester stretch fiber has a strength of 2 ~ 5g / d, elongation 40 ~ 80%, 10-15 crimps, 14-20 shrinkage, 2-10% shrinkage, 20-90mm fiber length, the heat-sealed polyester fiber has a strength of 2-5g / d, elongation 20-60% , 5-15 crimps, 10-20 crimps, 2-8% shrinkage.
제1항에 있어서,
상기 중공 폴리에스테르계 섬유는 굵기가 4~15 데니어이고, 상기 폴리에스테르계 스트레치 섬유는 2~9 데니어이고, 상기 열융착 바인더 폴리에스테르계 섬유는 2~10 데니어인 탄성 섬유 구조체.
The method of claim 1,
The hollow polyester fiber has a thickness of 4 to 15 denier, the polyester stretch fiber is 2 to 9 denier, the heat-sealing binder polyester fibers are 2 to 10 denier.
제1항에 있어서,
상기 탄성 섬유 구조체는 단섬유 열융착 부직포인 탄성 섬유 구조체.
The method of claim 1,
The elastic fiber structure is a short fiber heat-sealed nonwoven fabric elastic fiber structure.
제7항에 있어서,
상기 부직포는 두께 5~50mm인 탄성 섬유 구조체.
The method of claim 7, wherein
The nonwoven fabric is 5 to 50mm thick elastic fiber structure.
중공률 20~60%인 중공 폴리에스테르계 섬유 5~80중량%, 고유점도 0.63~1.30인 폴리에스테르계 고분자와 고유점도 0.45~0.56인 폴리에스테르계 고분자로 이루어진 복합섬유를 포함하는 스트레치 섬유 5~80중량% 및 융점 110~180℃인 열융착 바인더 폴리에스테르계 섬유 5~80중량%를 혼합하여 단섬유 혼합체를 이루는 섬유 혼합단계;
상기 단섬유 혼합체를 웹으로 제조하는 카딩단계;
상기 카딩단계를 거친 단섬유 혼합체를 80~200℃에서 열처리하는 열처리단계; 및
상기 열처리된 단섬유 혼합체를 냉각하여 탄성 섬유 구조체가 제조되는 냉각단계;
를 포함하는 탄성 섬유 구조체의 제조방법.
5 to 80% by weight of hollow polyester fiber having a 20% to 60% hollow fiber, a polyester fiber having an intrinsic viscosity of 0.63 to 1.30, and a stretch fiber comprising a composite fiber comprising a polyester polymer having an intrinsic viscosity of 0.45 to 0.56 A fiber mixing step of forming a short fiber mixture by mixing 80% by weight and 5 to 80% by weight of a heat-sealing binder polyester fiber having a melting point of 110 to 180 ° C;
A carding step of manufacturing the short fiber mixture into a web;
A heat treatment step of heat treating the short fiber mixture passed through the carding step at 80 to 200 ° C .; And
A cooling step of cooling the heat treated short fiber mixture to produce an elastic fiber structure;
Method of producing an elastic fiber structure comprising a.
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KR20150101611A (en) * 2014-02-27 2015-09-04 주식회사 휴비스 Non-woven Fabric Having Excellent Air Permeability and Elasticity, and Artificial Leather Using the Same
KR101655871B1 (en) * 2016-02-11 2016-09-08 (주)태기산자 Pure Foam and a Manufacturing Method for Cosmetic
WO2017138771A1 (en) * 2016-02-11 2017-08-17 (주)태기산자 Pure foam for cosmetics and manufacturing method thereof
WO2022145874A1 (en) * 2020-12-29 2022-07-07 코오롱인더스트리 주식회사 Spunbond non-woven fabrics having sheath-core structure and manufacturing method thereof

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