KR20110090189A - Camouflage printed fabrics used in tent covers with excellent waterproof - Google Patents

Camouflage printed fabrics used in tent covers with excellent waterproof Download PDF

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KR20110090189A
KR20110090189A KR1020100009828A KR20100009828A KR20110090189A KR 20110090189 A KR20110090189 A KR 20110090189A KR 1020100009828 A KR1020100009828 A KR 1020100009828A KR 20100009828 A KR20100009828 A KR 20100009828A KR 20110090189 A KR20110090189 A KR 20110090189A
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weight
polyurethane
parts
camouflage
fabric
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KR101473375B1 (en
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용 균 정
응 호 이
찬 우 김
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코오롱패션머티리얼 (주)
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M17/00Producing multi-layer textile fabrics
    • D06M17/04Producing multi-layer textile fabrics by applying synthetic resins as adhesives
    • D06M17/10Polyurethanes polyurea
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/18Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/20Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/40Layered products comprising a layer of synthetic resin comprising polyurethanes
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D1/00Woven fabrics designed to make specified articles
    • D03D1/0035Protective fabrics
    • D03D1/0047Camouflage fabrics
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/402Coloured
    • B32B2307/4026Coloured within the layer by addition of a colorant, e.g. pigments, dyes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/726Permeability to liquids, absorption
    • B32B2307/7265Non-permeable
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2375/00Polyureas; Polyurethanes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10Repellency against liquids
    • D06M2200/12Hydrophobic properties
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/02Moisture-responsive characteristics
    • D10B2401/021Moisture-responsive characteristics hydrophobic
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2505/00Industrial
    • D10B2505/18Outdoor fabrics, e.g. tents, tarpaulins

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Aiming, Guidance, Guns With A Light Source, Armor, Camouflage, And Targets (AREA)
  • Tents Or Canopies (AREA)

Abstract

PURPOSE: A tent cover fabric of camouflage dyeing is provided to ensure excellent fastness of water repellence, water proof, and blocking property. CONSTITUTION: A tent cover fabric of camouflage dyeing contains camouflage dyed fabric, a polyurethane adhesive layer, a first polyurethane coating layer, and a second polyurethane coating layer. The polyurethane adhesive layer(B) contains polyurethane resin and water dispersion TiO_2. The first polyurethane coating layer(C) contains polyurethane resin and copper phthalocyan pigment.

Description

방수성이 우수한 위장날염 천막덮개 원단{Camouflage printed Fabrics used in tent covers with excellent waterproof}Camouflage printed Fabrics used in tent covers with excellent waterproof}

본 발명은 내수도, 내한굴곡, 치수변화율, 블로킹성 등이 모두 우수한, 다시말해 복합기능성을 구비함과 동시에 국방규격서 KDC 8305-R0011-1에 명시된 파장별(600~860㎚) 근적외선 영역(600~860㎚)별 반사율을 만족시켜 방수성이 우수한 위장날염 천막덮개 원단에 관한 것이다.The present invention is excellent in water resistance, cold resistance, dimensional change rate, blocking property, etc., that is, having complex functionalities, and at the same time, the wavelength-specific (600-860 nm) near-infrared region (600 to 860 nm) specified in KDC 8305-R0011-1. It relates to a camouflage tent cover fabric excellent in water resistance by satisfying the reflectance by ~ 860nm).

보다 구체적으로, 본 발명은 코팅 처리에 의해서도 기존 위장성능이 유지되어 사람의 시야나 적외선 야간 관측 장비에도 위장효과가 계속 발현되면서도, 내수도, 세탁내구성 등의 기능성이 뛰어나 방수, 단열, 외부습기 차단 등이 가능하여 장병의 생존성 확보와 군장비의 효율적 관리가 가능한 천막덮개 원단에 관한 것이다.More specifically, the present invention maintains the existing gastrointestinal performance even by the coating treatment, while the gastrointestinal effect is continuously expressed in the human visual field or infrared night vision equipment, and has excellent functionality such as water resistance, laundry durability, and the like. The present invention relates to a tent cover fabric capable of securing soldiers' viability and efficiently managing military equipment.

국가방위의 목적으로 작전 수행 중 적에게 노출되어 생명에 위협을 받지 않기 위해서는 기본적으로 주위환경과 구분이 되지 않게하여 생존성을 보장받아야 하기에 날염기술에 적외선 반사율 기술(Infrared ray reflectance technology)을 적용하여 위장성능이 우수한 군용 섬유제품이 개발되고 있다. 특히 숙영 시 장병들의 휴식 및 취침을 통해 전투력을 향상시키기 위한 천막 덮개의 경우 야간 시에 주변환경과 유연하게 대응할 수 있어야 한다. 이를 위해서 종래에 천막덮개로 사용되는 원단은 4도 얼룩무늬를 통해 국내 녹지나 산림지대와 같은 주변 환경 하에서 위장효과(Camouflage effect)를 발휘하여 가시영역에서 주변 환경과 육안 구분이 어렵게 하며 근적외선영역(Near-Infrared)에서는 주위환경과의 반사율 수치와 명암차이를 조절을 통해 야간의 망원경, 적외선 야간관측장비에 의한 탐지 및 관측을 회피할 수 있는 기능성을 부여하였다.Infrared ray reflectance technology is applied to the printing technology because it must be indistinguishable from the surrounding environment in order to be exposed to the enemy during the operation for national defense and not be threatened with life. Therefore, military textile products having excellent camouflage performance have been developed. In particular, the tent cover to improve combat power through resting and sleeping by soldiers during camping should be able to flexibly respond to the surrounding environment at night. To this end, the fabric used as a tent cover conventionally exhibits a camouflage effect under the surrounding environment such as the green area or the forest area through the 4 degree stain pattern, making it difficult to distinguish the surrounding environment from the naked eye in the visible region. Near-Infrared) provides the functionality to avoid the detection and observation by night telescope and infrared night vision equipment by adjusting the reflectance value and contrast difference with surrounding environment.

군용 섬유제품에 대한 위장날염처리에 있어서 미국과 유럽 등의 경우, 적외선 야간 시각장비의 발달로 인해 보다 완벽한 위장효과를 거두기 위해 적외선 파장(민감도) 범위를 1,000~1,500nm까지 적외선 영역대의 상한치를 점차 확대하고 있으며, 최근에는 적외선 야간 시각장비에서도 은폐가 가능한 디지털 위장날염과 투습방수 같은 고기능성이 복합적으로 처리된 섬유제품개발에 집중하고 있으며, 우리군도 섬유제품에 대한 위장효과 증대 및 작전 수행 시에 국가적 위상과 병력들의 생존성 확보를 위해서는 세계적 수준에 손색이 없는 위장용 군관련 섬유제품개발이 필요하다.In the U.S. and Europe, in the gastrointestinal printing treatment of military textile products, the upper limit of the infrared wavelength range is gradually increased from 1,000 to 1500 nm in order to achieve a more perfect gastrointestinal effect due to the development of infrared night vision equipment. Recently, we have been focusing on the development of complex processed textile products such as digital camouflage printing and breathable waterproofing, which can be concealed by infrared night vision equipment. In order to secure the national status and survivability of troops, it is necessary to develop camouflage military-related textile products that are in line with world-class quality.

물론, 국내에서도 4도 얼룩무늬나 디지털 무늬의 위장효과를 극대화하기 위하여 주로 활동하는 지역의 산림지대 등의 환경조건(식물, 바위, 흙)하에서 가시영역과 근적외선영역에서 유사한 색상과 빛의 반사율을 통해 위장용 목적으로 사용되는 섬유제품에 주간 작전 시 시야에 의해 주변 환경과 쉽게 구분되지 않아야 하며 국방규격서(KDC 8305-R0011-1)에서 명시한 600~860nm의 범위에서의 얼룩무늬 전투복으로 사용되는 4색(카키색, 녹색 및 갈색, 흑색)이 각각 요구하는 파장별 요구 반사율 범위에 존재해야만 한다.Of course, in Korea, similar color and light reflectance in the visible and near-infrared areas can be achieved under environmental conditions (plants, rocks, soils) such as forest areas in areas where 4 degrees are used to maximize the camouflage effect of spots and digital patterns. Textile products used for camouflage purposes should not be easily distinguished from the surroundings by visibility during daytime operations, and used as speckled combat clothing in the 600-860 nm range specified in the Defense Standard (KDC 8305-R0011-1). Colors (khaki, green and brown, black) must each be in the required reflectance range for each wavelength required.

하지만, 현재 군에서 사용되는 위장날염된 군용천막덮개의 경우, 기존 위장효과가 후처리 가공(발수, 난연, 코팅 등)에 의해서 가시영역에서의 색상과 근적외선영역(700~860nm)에서의 고유 반사율(Reflectance, %)과 명암 차이가 발생하여 위장효과가 저하되거나 사라지게 되어 결과적으로는 육안이나 적외선 야간 탐색장비에 의해 위치가 노출되게 된다. However, in the case of camouflage printed military tent cover used in the current military, the existing gastrointestinal effect is the color in the visible region and the intrinsic reflectance in the near infrared region (700-860 nm) by post-treatment (water repellent, flame retardant, coating, etc.). (Reflectance,%) and contrast difference occur and the gastrointestinal effect is reduced or disappeared. As a result, the position is exposed by the naked eye or infrared night search equipment.

이에 근래에는 첨단화 되어가고 있는 군 장비의 발전에 발맞추어 위장용 군관련 섬유제품에 대한 군과 장병들의 요구치가 높아지고 있으며, 특히 경계가 소홀히 될 수 있는 야간 숙영 시 천막 위치가 노출되면 주간에 비해 더욱 큰 병력손실을 얻을 수 있으며 이는 전투에서의 패배로도 이어질 수 있기에 이를 예방하기 위한 위장날염 효과의 유지와 적외선 야간 시각장비를 무력화는 물론, 극한의 혹한환경에서도 최신 군장비의 보존과 장병들의 체온 및 쾌적성을 유지할 수 있는 천막덮개 원단에 대한 개발이 요구되고 있다. Recently, in line with the development of advanced military equipment, military and soldiers' demand for camouflage military-related textile products is increasing, especially when the tent location is exposed during night camping, which can be neglected. This can lead to a great loss of troops, which can lead to defeat in combat, so that the gastrointestinal printing effect is prevented and the infrared night vision equipment is disabled, as well as the preservation of the latest military equipment and temperature of soldiers in extreme cold conditions. There is a demand for development of a tent cover fabric that can maintain comfort.

그러므로, 본 발명에서는 기존 위장날염 천막덮개 원단에 코팅 처리 시 발생하던 외관색상과 파장별 반사율 변화를 개선하여 위장성능이 저해되는 문제점을 해결함과 동시에 계절환경에 따른 천막 내부의 기후조건을 유지를 위한 기능성(방한, 방풍, 방수 등) 및 반복 사용에도 내구성이 우수한 군용 천막덮개 원단을 제공하여야 하며 원단의 대상은 섬유소재에 무관하게 적용할 수 있어야 한다.Therefore, the present invention solves the problem that the camouflage performance is impaired by improving the change in appearance color and the reflectance change by wavelength when coating the existing camouflage tent cover fabric, while maintaining the climatic conditions inside the tent according to the seasonal environment. Military tent cover fabric with excellent functionality (cold protection, windproof, waterproof, etc.) and durability against repeated use should be provided and the object of the fabric should be applicable regardless of the textile material.

천막덮개용 원단의 경우 KS K 0590 방법으로 측정한 초기발수도가 5급이고, KS K ISO 6330(B2) 방법으로 5회 세탁후 KS K 0590 방법으로 측정한 발수도가 3급 이상이고, KS K 0591의 저수압법으로 측정한 내수도가 10,000㎜H2O 이상이고, KS M 6893(-20℃에서 40,000회) 방법으로 측정한 내한굴곡성이 5,000㎜H2O 이상이고, KS K ISO 5077 방법으로 측정한 치수변화율은 경사방향 및 위사방향 모두 ±2% 이내이고, KS K 0760 방법으로 측정한 블로킹성이 4급 이상이고, KS K 0700 방법으로 측정한 일광견뢰도, KS K 0430 방법으로 측정한 세탁견뢰도, KS K 0715 방법으로 측정한 땀 견뢰도 및 KS K 0650 방법으로 측정한 마찰견뢰도 모두가 각각 4.5급 이상인 물성들이 요구되고 있다.In case of fabric for tent cover, the initial water repellency measured by KS K 0590 method is 5th grade, and after washing 5 times by KS K ISO 6330 (B2) method, water repellency measured by KS K 0590 method is 3rd grade or higher, KS The water resistance measured by the low water pressure method of K 0591 is 10,000 mmH 2 O or more, the cold resistance bend measured by the KS M 6893 (40,000 times at -20 ° C) method is 5,000 mmH 2 O or more, and KS K ISO 5077 The rate of dimensional change measured by the method is within ± 2% in both the inclined direction and the weft direction. The blocking property measured by the KS K 0760 method is higher than the fourth grade, Properties of washing fastness, sweat fastness measured by KS K 0715 method and friction fastness measured by KS K 0650 method are all required to be 4.5 grade or more.

상기와 같은 요구 물성을 만족시킬 수 있는 종래 천막덮개용 원단으로는 국방규격서 KDC 8305-R0011-1에 명시된 근적외선 영역별 반사율을 만족하도록 위장 날염된 원단(A) 상에 폴리테트라플루오르에틸렌 필름(PTFE필름)을 열경화성 접착제로 라미네이팅시킨 천막덮개용 원단이 유일하였다.Conventional tent cover fabrics that can satisfy the above required physical properties include polytetrafluoroethylene film (PTFE) on camouflage-printed fabrics (A) to satisfy the reflectance for each near-infrared region specified in Defense Standard KDC 8305-R0011-1. The fabric for the tent cover in which the film) was laminated with a thermosetting adhesive was the only one.

그러나, PTFE필름이 라미네이팅된 종래의 천막덮개용 원단은 천막덮개용 원단의 상기 요구물성들은 만족시키고 위장 날염된 원단의 위장효과를 PTFE필름의 라미네이팅 후에도 계속 유지하는 장점은 있으나, 원단 상에 폴리우레탄 수지를 직접처리후 응고, 경화시키는 방식에 비해 공정이 복잡하고, 제조원가도 고가이고, 다양한 제품 적용에 어려운 문제점이 있었다.However, the conventional tent cover fabric laminated with PTFE film satisfies the above properties of the tent cover fabric and maintains the camouflage effect of the camouflage printed fabric even after laminating the PTFE film, but the polyurethane on the fabric Compared to the method of solidifying and curing the resin directly, the process is complicated, manufacturing costs are high, and there are problems in applying various products.

한편, 국방규격서 KDC 8305-R0011-1에 명시된 근적외선 영역별 반사율을 만족하도록 위장 날염된 원단(A)상에 폴리우레탄 수지를 습식 및/또는 건식방식으로 직접 처리한 후 이를 응고, 경화시켜 1층 또는 다층의 폴리우레탄수지 코팅층을 형성하는 방법으로 천막덮개용 원단을 제조하려는 시도가 있었으나, 이 경우 천막덮개용 원단의 상기 요구물성을 만족시킬 수 있으나 위장 날염된 원단의 위장효과가 크게 저하되는 문제점으로 현재까지 상용화 되지 못하였다.On the other hand, the polyurethane resin is directly treated by wet and / or dry method on the camouflage-printed fabric (A) to satisfy the near-infrared reflectivity specified in KDC 8305-R0011-1, and then solidified and cured. Or attempts to manufacture a tent cover fabric by a method of forming a multi-layer polyurethane resin coating layer, but in this case can satisfy the above requirements of the fabric for the tent cover, but the camouflage effect of the camouflage printed fabric is greatly reduced It has not been commercialized so far.

본 발명의 과제는 국방규격서 KDC 8305-R0011-1에 명시된 근적외선 영역별 반사율을 만족하도록 위장 날염된 원단(A) 상에 폴리우레탄 수지를 직접 처리 후 응고시키는 방식으로 폴리우레탄 접착층과 폴리우레탄 코팅층들이 형성되어 제조공정이 간소화되고 제조원가는 저렴하게 하면서, 폴리우레탄 접착층과 폴리우레탄 코팅층 형성 후에도 이들을 형성하기 이전인 위장 날염된 원단의 위장 효과를 그대로 유지하여 위장 효과가 뛰어나고, 텐트덮개용 원단에 요구되는 발수도 등의 복합기능성들을 충족시키는 텐트덮개용 원단을 제공하는 것이다.The problem of the present invention is that a polyurethane adhesive layer and a polyurethane coating layer are formed by directly solidifying the polyurethane resin on the camouflage-printed fabric (A) to satisfy the near-infrared region-specific reflectivity specified in KDC 8305-R0011-1. It is formed to simplify the manufacturing process and reduce the manufacturing cost, while maintaining the camouflage effect of the camouflage printed fabric before forming them even after forming the polyurethane adhesive layer and polyurethane coating layer, excellent camouflage effect, which is required for the tent cover fabric To provide a tent cover fabric that satisfies the complex functionalities such as water repellency.

본 발명은 이와 같은 과제들을 달성하기 위해서, (i) 국방규격서 KDC 8305-R0011-1에 명시된 근적외선 영역별 반사율을 만족하도록 위장 날염된 원단(A); (ⅱ) 상기 원단(A)상에 습식코팅방식으로 형성되어, 폴리우레탄 수지 100 중량부를 기준으로 수분산성 TiO2 10~14중량부를 함유하는 폴리우레탄 접착층(B); (ⅲ) 상기 폴리우레탄 접착층(B) 상에 습식코팅 방식으로 형성되어, 폴리우레탄 수지 100중량부 기준으로 쿠퍼 프탈로시안 피그멘트(Copper phthalocyanine pigment) 4~6중량부를 함유하는 제1폴리우레탄 코팅층(C); 및 (ⅳ) 상기 제1폴리우레탄 코팅층(C) 상에 건식코팅 방식으로 형성되어 폴리우레탄 수지 100중량부를 기준으로 용제형 TiO2 15~25중량부를 함유하는 제2폴리우레탄 코팅층(D)으로 구성된 천막덮개용 원단을 제공한다.The present invention to achieve the above problems, (i) camouflage-printed fabric (A) to satisfy the near-infrared region-specific reflectivity specified in the defense standard KDC 8305-R0011-1; (Ii) a polyurethane adhesive layer (B) formed on the fabric (A) by a wet coating method and containing 10-14 parts by weight of water dispersible TiO 2 based on 100 parts by weight of polyurethane resin; (Iii) a first polyurethane coating layer formed on the polyurethane adhesive layer (B) by a wet coating method and containing 4 to 6 parts by weight of copper phthalocyanine pigment based on 100 parts by weight of the polyurethane resin. (C); And (iii) a second polyurethane coating layer (D) formed on the first polyurethane coating layer (C) by a dry coating method and containing 15 to 25 parts by weight of a solvent type TiO 2 based on 100 parts by weight of a polyurethane resin. Provide fabric for tent cover.

본 발명은 발수도, 내수도, 내한굴곡성, 치수변화율, 블로킹성 및 세탁, 일광 등의 각종 견뢰도가 우수함과 동시에 국방규격서 KDC 8305-R0011-1에 명시된 근적외선 영역별 반사율을 만족하여 위장효과가 뛰어나고, 제조공정이 간소화되고 제조원가가 저렴한 효과가 있다.The present invention is excellent in camouflage effect by satisfying the reflectivity for each near-infrared region specified in National Defense Standard KDC 8305-R0011-1, as well as excellent water repellency, water resistance, cold resistance, dimensional change rate, blocking property, and fastness of washing and daylight. Therefore, the manufacturing process is simplified and the manufacturing cost is low.

도 1은 본 발명에 따른 천막덮개용 원단의 단면 개략도.1 is a schematic cross-sectional view of the fabric for the tent cover according to the present invention.

이하, 첨부한 도면 등을 통해 상세하게 설명한다.Hereinafter, the present invention will be described in detail with reference to the accompanying drawings.

먼저, 본 발명에 따른 천막덮개용 원단은 도 1에 도시된 바와 같이 (i) 국방규격서 KDC 8305-R0011-1에 명시된 근적외선 영역별 반사율을 만족하도록 위장 날염된 원단(A); (ⅱ) 상기 원단(A)상에 습식코팅방식으로 형성되어, 폴리우레탄 수지 100 중량부를 기준으로 수분산성 TiO2 10~14중량부를 함유하는 폴리우레탄 접착층(B); (ⅲ) 상기 폴리우레탄 접착층(B) 상에 습식코팅 방식으로 형성되어, 폴리우레탄 수지 100중량부 기준으로 쿠퍼 프탈로시안 피그멘트(Copper phthalocyanine pigment) 4~6중량부를 함유하는 제1폴리우레탄 코팅층(C); 및 (ⅳ) 상기 제1폴리우레탄 코팅층(C) 상에 건식코팅 방식으로 형성되어 폴리우레탄 수지 100중량부를 기준으로 용제형 TiO2 15~25중량부를 함유하는 제2폴리우레탄 코팅층(D)으로 구성된다.First, the tent cover fabric according to the present invention, as shown in Figure 1 (i) camouflage-printed fabric (A) to satisfy the reflectance for each near infrared region specified in the defense standard KDC 8305-R0011-1; (Ii) a polyurethane adhesive layer (B) formed on the fabric (A) by a wet coating method and containing 10-14 parts by weight of water dispersible TiO 2 based on 100 parts by weight of polyurethane resin; (Iii) a first polyurethane coating layer formed on the polyurethane adhesive layer (B) by a wet coating method and containing 4 to 6 parts by weight of copper phthalocyanine pigment based on 100 parts by weight of the polyurethane resin. (C); And (iii) a second polyurethane coating layer (D) formed on the first polyurethane coating layer (C) by a dry coating method and containing 15 to 25 parts by weight of a solvent-based TiO 2 based on 100 parts by weight of a polyurethane resin. do.

도 1은 본 발명에 따른 천막덮개용 원단의 단면 개략도이다.1 is a schematic cross-sectional view of a fabric for a tent cover according to the present invention.

상기 위장 날염된 원단(A)은 천연섬유사, 합성섬유사 및 천연섬유사와 합성섬유의 혼방사 중에서 선택된 1종 또는 2종 이상의 원사로 제직된 원단 등이다.The camouflage-printed fabric (A) is a fabric woven from one or two or more kinds of yarns selected from natural fiber yarns, synthetic fiber yarns and mixed yarns of natural fiber yarns and synthetic fibers.

구체적으로, 상기 위장 날염된 원단(A)는 폴리에스테르/면 혼방사, 폴리에스테르/레이온 혼방사 또는 나일론/폴리에스테르 혼방사로 제직 되거나 이들 중 2종 이상으로 교직되거나, 경량성과 신축성을 부여하기 위해 나일론/면 혼방사 또는 폴리에스테르/폴리우레탄 혼방사로 제직되거나 이들 중 2종 이상으로 교직된 직물 등으로서, 본 발명에서는 상기 위장 날염된 원단(A)의 섬유 소재를 특별하게 한정하지 않는다.Specifically, the camouflage printed fabric (A) is woven with polyester / cotton blended yarn, polyester / rayon blended yarn or nylon / polyester blended yarn or woven into two or more of them, or nylon / to give lightness and elasticity. As a woven fabric made of cotton blended yarn or polyester / polyurethane blended yarn or interwoven with two or more of them, the present invention does not specifically limit the fiber material of the camouflage printed fabric (A).

또한, 상기 위장 날염된 원단(A)은 아라미드 등과 같은 고강력 원사로 구성되어, 위장 날염된 원단(A)은 KS K 0535 방법으로 측정한 경사방향의 인열강도가 1,700cN 이상이고, 위사방향의 인열강도가 1,600cN 이상인 원단도 포함한다.In addition, the camouflage printed fabric (A) is composed of a high-strength yarn such as aramid, camouflage printed fabric (A) has a tear strength of 1,700 cN or more in the oblique direction measured by KS K 0535 method, weft direction It also includes fabrics with a tear strength of at least 1,600 cN.

상기 폴리우레탄 접착층(B)의 단위면적당 중량은 3~5g/㎡이고, 제1폴리우레탄 코팅층(C)의 단위면적당 중량은 20~25g/㎡이고, 제2폴리우레탄 코팅층(D)의 단위면적당 중량은 25~30g/㎡인 것이 바람직하다.The weight per unit area of the polyurethane adhesive layer (B) is 3 ~ 5g / ㎡, the weight per unit area of the first polyurethane coating layer (C) is 20 ~ 25g / ㎡, per unit area of the second polyurethane coating layer (D) It is preferable that a weight is 25-30 g / m <2>.

본 발명의 천막덮개용 원단은 상기 원단(A)에 폴리우레탄 접착층(B), 제1폴리우레탄 코팅층(C) 및 제2폴리우레탄 코팅층(D)들을 형성한 후에도 이들을 형성하기 이전의 위장 날염된 원단(A)과 동일하게 국방규격서 KDC 8305-R0011-1에 명시된 근적외선 영역별 반사율을 만족하여 위장 효과가 뛰어나다The fabric for the tent cover of the present invention is the camouflage printing before forming the polyurethane adhesive layer (B), the first polyurethane coating layer (C) and the second polyurethane coating layer (D) on the fabric (A) before forming them Like the fabric (A), the camouflage effect is excellent because it satisfies the reflectance for each near infrared region specified in KDC 8305-R0011-1.

또한, 본 발명의 천막덮개용 원단은 KS K 0590 방법으로 측정한 초기발수도가 5급이고, KS K ISO 6330(B2) 방법으로 5회 세탁후 KS K 0590 방법으로 측정한 발수도가 3급 이상이고, KS K 0591의 저수압법으로 측정한 내수도가 10,000㎜H2O 이상이고, KS M 6893(-20℃에서 40,000회) 방법으로 측정한 내한굴곡성이 5,000㎜H2O 이상이고, KS K ISO 5077 방법으로 측정한 치수변화율은 경사방향 및 위사방향 모두 ±2% 이내 이고, KS K 0760 방법으로 측정한 블로킹성이 4급 이상이고, KS K 0535 방법으로 측정한 경사방향의 인열강도가 1,700cN 이상이고, 위사방향의 인열강도가 1,600cN 이상이고, KS K 0700 방법으로 측정한 일광견뢰도, KS K 0430 방법으로 측정한 세탁견뢰도, KS K 0715 방법으로 측정한 땀 견뢰도 및 KS K 0650 방법으로 측정한 마찰견뢰도 모두가 각각 4.5급 이상으로 복합기능성을 구비한다.In addition, the fabric for the tent cover of the present invention is the initial water repellency measured by KS K 0590 method 5 grade, after washing five times by KS K ISO 6330 (B2) method, the water repellency degree measured by KS K 0590 method 3 grade The water resistance measured by the low water pressure method of KS K 0591 is 10,000 mmH 2 O or more, the cold resistance bend measured by the KS M 6893 (40,000 times at -20 ° C.) method is 5,000 mmH 2 O or more, The dimensional change rate measured by the KS K ISO 5077 method is within ± 2% in both the inclined direction and the weft direction. The degree is more than 1,700 cN, the tear strength in the weft direction is more than 1,600 cN, the light fastness measured by KS K 0700 method, wash fastness measured by KS K 0430 method, sweat fastness measured by KS K 0715 method and KS All of the fastness of friction measured by K 0650 method is 4.5 or more, .

본 발명의 천막덮개용 원단은 일반적으로는 천막 위장을 위해 사용시 위장 날염된 원단(A)이 외부로 향하도록 설치, 사용된다. 그러나, 설상에서 천막 위장을 하는 경우에는 제2폴리우레탄 코팅층(D)이 외부로 향하도록 설치, 사용될 수도 있다.The tent cover fabric of the present invention is generally installed and used so that the camouflage-printed fabric (A) faces outward when used for tent camouflage. However, when the tent camouflage on snow, the second polyurethane coating layer (D) may be installed and used to face the outside.

구체적으로, 본 발명은 폴리우레탄 접착층(B)에 함유된 수분산성 TiO2가 코팅 전 천막덮개 원단에서 조사되는 근적외선 영역에서의 파장의 대부분의 빛을 산란시키는 역할을 하며, 제1폴리우레탄 코팅층(C)에 함유된 쿠퍼 프탈시안 피그멘트(Copper phthalocyanine pigment)가 일부 투과된 근적외선 영역 별 빛을 흡수 또는 반사하여 코팅 전 위장 날염된 천막덮개의 근적외선 영역 별 고유 반사율 수치를 유지할 수 있게 작용한다.Specifically, the present invention serves to scatter most of the wavelength of the wavelength in the near-infrared region irradiated from the tent cover fabric before the water-dispersible TiO 2 contained in the polyurethane adhesive layer (B), the first polyurethane coating layer ( The copper phthalocyanine pigment contained in C) absorbs or reflects light of some transmitted near infrared region to maintain the unique reflectance value of the near infrared region of the camouflage printed tent cover before coating.

또한, 이것은 상기 폴리우레탄 접착층(B)에 의해서만 발휘할 수 있는 것이 아니라 제1폴리우레탄 코팅층(C)까지 처리되어야만 상기 위장효과 유지성능을 발휘하며 이는 제1폴리우레탄 코팅층(C)의 두께가 3~5g/으로 얇은 층으로 구성되어 일부 빛의 투과에 의한 것으로 볼 수 있다. In addition, this can not be exerted only by the polyurethane adhesive layer (B), but only to the first polyurethane coating layer (C) to exhibit the gastrointestinal effect retention performance, which is 3 ~ 3 thickness of the first polyurethane coating layer (C) It consists of a thin layer at 5 g / and can be considered to be due to some light transmission.

또한, 제2폴리우레탄 코팅층(D)의 경우, 위장효과를 유지하면서 내수도와 외부환경에 의한 내구성을 보장하기 위한 것으로 본 발명의 코팅 3층 구조(원단 포함 4층구조)가 만족해야만 본 발명의 효과에서 명시한 기능성을 발휘할 수 있다. In addition, the second polyurethane coating layer (D), in order to ensure the durability by the water resistance and the external environment while maintaining the gastrointestinal effect of the present invention only if the coating three-layer structure (four-layer structure including the fabric) of the present invention is satisfied. The functionality specified in the effect can be achieved.

다음으로는, 본 발명에 따른 천막덮개용 원단을 제조하는 방법 중 일례를 상세하게 살펴본다.Next, look at one example of the method for producing a tent cover fabric according to the present invention in detail.

먼저, 국방규격서 KDC 8305-R0011-1에 명시된 근적외선 영역별 반사율을 만족하도록 위장 날염된 원단(A)을 준비하고, 상기 위장 날염된 원단(A)을 준비하고, 상기 위장 날염된 원단(A)을 발수처리 및 열시레(Heat-cire) 처리한다.First, the camouflage printed fabric (A) is prepared to satisfy the reflectance for each near infrared region specified in the defense standard KDC 8305-R0011-1, the camouflage printed fabric (A) is prepared, and the camouflage printed fabric (A) It is treated with water repellent and heat-cire.

다음으로는, 발수처리 및 열시레 처리된 상기의 위장 날염된 원단(A)상에 폴리우레탄 수지 100중량부를 기준으로 수분산성 TiO2 10~14중량부를 함유하는 폴리우레탄 수지 조성물을 습식코팅 방식으로 처리하여 폴리우레탄 접착층(B)을 형성한다.Next, the polyurethane resin composition containing 10-14 parts by weight of water dispersible TiO 2 based on 100 parts by weight of the polyurethane resin on the above-described camouflage-printed fabric (A) subjected to water repellent treatment and heat treatment was wet coated. Treatment to form a polyurethane adhesive layer (B).

이때, 사용되는 폴리우레탄 수지 조성물의 일례로는 폴리우레탄 수지(K-133) 100중량부를 기준으로, 톨루엔(용매) 50~70중량부와, 수분산성 TiO2(White 1560) 10~14 중량부와, 무황변형 이소시아네이트(H.C.W) 1중량부로 구성된 폴리우레탄 수지 조성물이 사용될 수 있다.At this time, as an example of the polyurethane resin composition used, 50 to 70 parts by weight of toluene (solvent) and 10 to 14 parts by weight of water dispersible TiO 2 (White 1560) based on 100 parts by weight of polyurethane resin (K-133). And, a polyurethane resin composition composed of 1 part by weight of sulfur-free isocyanate (HCW) can be used.

다음으로는, 상기 폴리우레탄 접착층(B) 상에 폴리우레탄 수지 100중량부 기준으로 쿠퍼 프탈로시안 피그멘트(Copper phthalocyanine pigment 4~6중량부를 함유하는 폴리우레탄 수지 조성물을 습식코팅 방식으로 처리하여 제1폴리우레탄 코팅층(C)을 형성한다.Next, the polyurethane resin composition containing 4 to 6 parts by weight of copper phthalocyanine pigment based on 100 parts by weight of the polyurethane resin on the polyurethane adhesive layer (B) is treated by a wet coating method. 1 Polyurethane coating layer (C) is formed.

이때 사용되는 폴리우레탄 수지 조성물의 일례로는 폴리우레탄 수지(MP-868K) 100중량부를 기준으로 디메틸포름아마이드(용매) 37~38중량부와, 쿠퍼 프탈시안 피그멘트(CI Pigment Yellow 7 : SW Green 902) 4~6중량부와, 무황변형 이소시아네이트(H.C.W) 1중량부로 구성된 폴리우레탄 수지 조성물이 사용될 수 있다.Examples of the polyurethane resin composition used at this time include 37 to 38 parts by weight of dimethylformamide (solvent) based on 100 parts by weight of polyurethane resin (MP-868K), and Cooper phthalian pigment (CI Pigment Yellow 7: SW Green) 902) A polyurethane resin composition composed of 4 to 6 parts by weight and 1 part by weight of sulfur-free isocyanate (HCW) may be used.

다음으로는 상기 제1폴리우레탄 코팅층(C)상에 폴리우레탄 수지 100중량부를 기준으로 용제형 TiO2 15~25중량부를 함유하는 폴리우레탄 수지 조성물을 건식코팅 방식으로 처리하여 제2폴리우레탄 코팅층(D)을 형성한다.Next, the polyurethane coating composition containing 15 to 25 parts by weight of the solvent-based TiO 2 based on 100 parts by weight of the polyurethane resin on the first polyurethane coating layer (C) by a dry coating method to the second polyurethane coating layer ( Form D).

이때 사용되는 폴리우레탄 수지 조성물의 일례로는 폴리우레탄 수지(DS-902) 100중량부를 기준으로, 톨루엔(용매) 30중량부와, 디메틸포름아마이드(용매) 5중량부와, SiO2(E-170) 3중량부와, 용제형 TiO2(KPU W/N 1300) 15~25중량부로 조성된 폴리우레탄 수지 조성물이 사용될 수 있다.Examples of the polyurethane resin composition used at this time include 30 parts by weight of toluene (solvent), 5 parts by weight of dimethylformamide (solvent), and SiO 2 (E-) based on 100 parts by weight of polyurethane resin (DS-902). 170) A polyurethane resin composition composed of 3 parts by weight and 15 to 25 parts by weight of a solvent type TiO 2 (KPU W / N 1300) may be used.

이하, 실시예를 통하여 본 발명을 보다 구체적으로 살펴본다.Hereinafter, the present invention will be described in more detail with reference to Examples.

그러나, 본 발명은 하기 실시예에 의해 그의 권리범위가 한정되는 것은 아니다.However, the present invention is not limited by the following examples.

실시예 1Example 1

국방규격서 KDC 8305-R0011-1에 명시된 근적외선 영역별 반사율을 만족하도록 위장 날염된 원단(A)상에 폴리우레탄 수지(K-133) 100중량부, 톨루엔 64중량부, 수분산성 TiO2(White 1560) 10중량부 및 무황변형 이소시아네이트(H.C.W) 1중량부로 구성된 폴리우레탄 수지 조성물을 습식코팅 방식으로 처리하여 폴리우레탄 접착층(B)을 형성하였다.100 parts by weight of polyurethane resin (K-133), 64 parts by weight of toluene, and water-dispersible TiO 2 (White 1560) on the camouflage-printed fabric (A) to satisfy the reflectance for each near infrared region specified in KD 8305-R0011-1. Polyurethane resin composition consisting of 10 parts by weight and 1 part by weight of sulfur-free isocyanate (HCW) was treated by a wet coating method to form a polyurethane adhesive layer (B).

다음으로는, 상기 폴리우레탄 접착층(B)상에 폴리우레탄 수지(MP868K) 100중량부, 디메틸포름아마이드(DMF) 37.5 중량부, 쿠퍼 프탈시안 피그멘트(CI Pigment : SW Green 902) 5중량부 및 무황변형 이소시아네이트(H.C.W) 1중량부로 구성된 폴리우레탄 수지 조성물을 습식코팅 방식으로 처리하여 제1폴리우레탄 코팅층(C)을 형성하였다.Next, 100 parts by weight of polyurethane resin (MP868K), 37.5 parts by weight of dimethylformamide (DMF), 5 parts by weight of phthalphthalic pigment (CI Pigment: SW Green 902) on the polyurethane adhesive layer (B), and The polyurethane resin composition composed of 1 part by weight of sulfur-free isocyanate (HCW) was treated by a wet coating method to form a first polyurethane coating layer (C).

다음으로는, 상기 제1폴리우레탄 코팅층(C)상에 폴리우레탄수지(DS-962) 100중량부, 톨루엔 30중량부, 디메틸포름아마이드(DMF) 5중량부, SiO2(E-170) 3중량부 및 용제형 TiO2(KPU W/N 1300) 20중량부로 구성된 폴리우레탄 수지 조성물을 건식코팅 방식으로 처리하여 제2폴리우레탄 코팅층(D)을 형성하여 4층 구조의 천막덮개용 원단을 제조하였다.Next, 100 parts by weight of polyurethane resin (DS-962), 30 parts by weight of toluene, 5 parts by weight of dimethylformamide (DMF), and SiO 2 (E-170) 3 on the first polyurethane coating layer (C). A polyurethane coating composition composed of 20 parts by weight of a weight part and a solvent type TiO 2 (KPU W / N 1300) was treated by a dry coating method to form a second polyurethane coating layer (D) to manufacture a fabric for a tent cover having a four-layer structure. It was.

실시예 2~실시예 3Example 2-Example 3

폴리우레탄 접착층(B) 형성에 사용된 폴리우레탄 수지 조성물, 제1폴리우레탄 코팅층(C) 형성에 사용된 폴리우레탄 수지 조성물 및 제2폴리우레탄 코팅층(D) 형성에 사용된 폴리우레탄 수지 조성물 각각의 성분 비율을 아래 <표 1>과 같이 변경한 것을 제외하고는 실시예 1과 동일한 방법으로 천막덮개용 원단을 제조하였다.Each of the polyurethane resin composition used to form the polyurethane adhesive layer (B), the polyurethane resin composition used to form the first polyurethane coating layer (C) and the polyurethane resin composition used to form the second polyurethane coating layer (D), Fabric for tent cover was prepared in the same manner as in Example 1 except that the component ratio was changed as shown in Table 1 below.

(단위 : 중량부)(Unit: parts by weight) 구분
division
실시예 1Example 1 실시예 2Example 2 실시예 3Example 3 실시예 4Example 4
폴리우레탄
접착층(B)용
폴리우레탄
수지 조성물
Polyurethane
Adhesive layer (B)
Polyurethane
Resin composition
K-133K-133 100100 100100 100100 100100
톨루엔toluene 6464 6464 6464 6464 White 1560White 1560 1010 1212 1414 1212 H.C.WH.C.W 1One 1One 1One 1One 제1폴리우레탄 코팅층(C)용 폴리우레탄 수지 조성물Polyurethane Resin Composition for First Polyurethane Coating Layer (C) MP 868KMP 868K 100100 100100 100100 100100 D.M.FD.M.F 37.537.5 37.537.5 37.537.5 37.537.5 SW Green 902SW Green 902 55 55 55 66 H.W.CH.W.C 1One 1One 1One 1One 제2폴리우레탄 코팅층(D)용 폴리우레탄 수지 조성물Polyurethane Resin Composition for Second Polyurethane Coating Layer (D) DS-962DS-962 100100 100100 100100 100100 톨루엔toluene 3030 3030 3030 3030 D.M.FD.M.F 55 55 55 55 E-170E-170 33 33 33 33 KPU W/N 1300KPU W / N 1300 2020 2020 2020 2020

상기 실시예 1 내지 실시예 4로 제조된 천막덮개용 원단은 국방 규격서 KDC 8305-R0011-1에 명시된 근적외선 영역별 반사율을 만족함과 동시에 KS K 0590 방법으로 측정한 초기발수도가 5급이고, KS K 0535 방법으로 측정한 경사방향의 인열강도가 1,700cN 이상이고, 위사방향의 인열강도가 1,600cN 이상이고, KS K ISO 6330(B2) 방법으로 5회 세탁후 KS K 0590 방법으로 측정한 발수도가 3급 이상이고, KS K 0591의 저수압법으로 측정한 내수도가 10,000㎜H2O 이상이고, KS M 6893(-20℃에서 40,000회) 방법으로 측정한 내한굴곡성이 5,000㎜H2O 이상이고, KS K ISO 5077 방법으로 측정한 치수변화율은 경사방향 및 위사방향 모두 ±2% 이내 이고, KS K 0760 방법으로 측정한 블로킹성이 4급 이상이고, KS K 0700 방법으로 측정한 일광견뢰도, KS K 0430 방법으로 측정한 세탁견뢰도, KS K 0715 방법으로 측정한 땀 견뢰도 및 KS K 0650 방법으로 측정한 마찰견뢰도 모두가 각각 4.5급 이상 이였다.Fabrics for the tent cover prepared in Examples 1 to 4 satisfy the reflectance for each near-infrared region specified in the defense standard KDC 8305-R0011-1, and the initial water repellency measured by the KS K 0590 method is 5th grade, KS Tear strength in the inclined direction measured by K 0535 method is 1,700 cN or more, tear strength in the weft direction is 1,600 cN or more, and washed five times by KS K ISO 6330 (B2) method and measured by KS K 0590 method. Water repellency is grade 3 or higher, water resistance measured by KS K 0591's low water pressure method is 10,000 mmH 2 O or more, and cold resistance bend resistance measured by KS M 6893 (40,000 times at -20 ° C) is 5,000 mmH 2 O or more, and the rate of dimensional change measured by the KS K ISO 5077 method is within ± 2% in both the warp direction and the weft direction, and the blocking property measured by the KS K 0760 method is higher than the 4th grade, and measured by the KS K 0700 method. Daylight fastness measured by KS K 0430 method Wash fastness measured by KS K 0715 method The sweat fastness and friction fastness measured by KS K 0650 method were all 4.5 or higher.

A : 위장 날염된 원단
B : 폴리우레탄 접착층
C : 제1폴리우레탄 코팅층
D : 제2폴리우레탄 코팅층
A: Camouflage Printed Fabric
B: polyurethane adhesive layer
C: first polyurethane coating layer
D: second polyurethane coating layer

Claims (6)

(i) 국방규격서 KDC 8305-R0011-1에 명시된 근적외선 영역별 반사율을 만족하도록 위장 날염된 원단(A);
(ⅱ) 상기 원단(A)상에 습식코팅방식으로 형성되어, 폴리우레탄 수지 100 중량부를 기준으로 수분산성 TiO2 10~14중량부를 함유하는 폴리우레탄 접착층(B);
(ⅲ) 상기 폴리우레탄 접착층(B) 상에 습식코팅 방식으로 형성되어, 폴리우레탄 수지 100중량부 기준으로 쿠퍼 프탈로시안 피그멘트(Copper phthalocyanine pigment) 4~6중량부를 함유하는 제1폴리우레탄 코팅층(C); 및
(ⅳ) 상기 제1폴리우레탄 코팅층(C) 상에 건식코팅 방식으로 형성되어 폴리우레탄 수지 100중량부를 기준으로 용제형 TiO2 15~25중량부를 함유하는 제2폴리우레탄 코팅층(D)으로 구성됨을 특징으로 하는 방수성이 우수한 위장날염 천막덮개 원단.
(i) camouflage-printed fabric (A) to satisfy the near-infrared reflectivity specified in Defense Specification KDC 8305-R0011-1;
(Ii) a polyurethane adhesive layer (B) formed on the fabric (A) by a wet coating method and containing 10-14 parts by weight of water dispersible TiO 2 based on 100 parts by weight of polyurethane resin;
(Iii) a first polyurethane coating layer formed on the polyurethane adhesive layer (B) by a wet coating method and containing 4 to 6 parts by weight of copper phthalocyanine pigment based on 100 parts by weight of the polyurethane resin. (C); And
(Iii) a second polyurethane coating layer (D) formed on the first polyurethane coating layer (C) by a dry coating method and containing 15 to 25 parts by weight of a solvent-based TiO 2 based on 100 parts by weight of a polyurethane resin. Camouflage tent cover fabric with excellent waterproofing.
제1항에 있어서, 위장 날염된 원단(A)은 천연섬유사, 합성섬유사 및 천연섬유사와 합성섬유의 혼방사 중에서 선택된 1종 또는 2종 이상의 원사로 제직된 것을 특징으로 하는 방수성이 우수한 위장날염 천막덮개 원단.The method of claim 1, wherein the camouflage printed fabric (A) is a waterproof camouflage printing, characterized in that the woven fabric of one or two or more selected from natural fibers, synthetic fibers and blended yarns of natural fibers and synthetic fibers Tent cover fabric. 제1항에 있어서, 폴리우레탄 접착층(B)의 단위면적당 중량은 3~5g/㎡이고, 제1폴리우레탄 코팅층(C)의 단위면적당 중량은 20~25g/㎡이고, 제2폴리우레탄 코팅층(D)의 단위면적당 중량은 25~30g/㎡인 것을 특징으로 하는 방수성이 우수한 위장날염 천막덮개 원단.According to claim 1, wherein the weight per unit area of the polyurethane adhesive layer (B) is 3 ~ 5g / ㎡, the weight per unit area of the first polyurethane coating layer (C) is 20 ~ 25g / ㎡, and the second polyurethane coating layer ( D) The camouflage tent cover fabric excellent in water resistance, characterized in that the weight per unit area of 25 ~ 30g / ㎡. (i) 국방규격서 KDC 8305-R0011-1에 명시된 근적외선 영역별 반사율을 만족하도록 위장 날염된 원단(A);
(ⅱ) 상기 원단(A)상에 습식코팅방식으로 형성되어, 폴리우레탄 수지 100 중량부를 기준으로 수분산성 TiO2 10~14중량부를 함유하는 폴리우레탄 접착층(B);
(ⅲ) 상기 폴리우레탄 접착층(B) 상에 습식코팅 방식으로 형성되어, 폴리우레탄 수지 100중량부 기준으로 쿠퍼 프탈로시안 피그멘트(Copper phthalocyanine pigment) 4~6중량부를 함유하는 제1폴리우레탄 코팅층(C); 및
(ⅳ) 상기 제1폴리우레탄 코팅층(C) 상에 건식코팅 방식으로 형성되어 폴리우레탄 수지 100중량부를 기준으로 용제형 TiO2 15~25중량부를 함유하는 제2폴리우레탄 코팅층(D)으로 구성되어,
KS K 0590 방법으로 측정한 초기발수도가 5급이고,
KS K ISO 6330(B2) 방법으로 5회 세탁후 KS K 0590 방법으로 측정한 발수도가 3급 이상이고,
KS K 0535 방법으로 측정한 경사방향의 인열강도가 1,700cN 이상이고, 위사방향의 인열강도가 1,600cN 이상이고,
KS K 0591의 저수압법으로 측정한 내수도가 10,000㎜H2O 이상이고,
KS M 6893(-20℃에서 40,000회) 방법으로 측정한 내한굴곡성이 5,000㎜H2O 이상이고,
KS K ISO 5077 방법으로 측정한 치수변화율은 경사방향 및 위사방향 모두 ±2% 이내 이고,
KS K 0760 방법으로 측정한 블로킹성이 4급 이상인 것을 특징으로 하는 방수성이 우수한 위장날염 천막덮개 원단.
(i) camouflage-printed fabric (A) to satisfy the near-infrared reflectivity specified in Defense Specification KDC 8305-R0011-1;
(Ii) a polyurethane adhesive layer (B) formed on the fabric (A) by a wet coating method and containing 10-14 parts by weight of water dispersible TiO 2 based on 100 parts by weight of polyurethane resin;
(Iii) a first polyurethane coating layer formed on the polyurethane adhesive layer (B) by a wet coating method and containing 4 to 6 parts by weight of copper phthalocyanine pigment based on 100 parts by weight of the polyurethane resin. (C); And
(Iii) a second polyurethane coating layer (D) formed on the first polyurethane coating layer (C) by a dry coating method and containing 15 to 25 parts by weight of a solvent-based TiO 2 based on 100 parts by weight of a polyurethane resin. ,
Initial water repellency measured by KS K 0590 method is 5th grade,
After washing 5 times with KS K ISO 6330 (B2) method, the water repellency measured by KS K 0590 method is more than 3 grade,
The tear strength in the inclined direction measured by the KS K 0535 method is 1,700 cN or more, the tear strength in the weft direction is 1,600 cN or more,
The water resistance measured by the low water pressure method of KS K 0591 is 10,000 mmH 2 O or more,
Cold resistance bend measured by KS M 6893 (40,000 times at -20 ℃) is more than 5,000mmH 2 O,
The rate of dimensional change measured by KS K ISO 5077 method is within ± 2% in both the warp direction and the weft direction.
A waterproof camouflage tent cover fabric, characterized in that the blocking property measured by the method of KS K 0760.
제4항에 있어서, 위장 날염된 원단(A)의 경사 및 위사가 고강력 원사인 것을 특징으로 하는 방수성이 우수한 위장날염 천막덮개 원단.The waterproof camouflage tent cover fabric of claim 4, wherein the warp and weft of the camouflage printed fabric (A) is a high strength yarn. 제4항 또는 제5항에 있어서, KS K 0700 방법으로 측정한 일광견뢰도, KS K 0430 방법으로 측정한 세탁견뢰도, KS K 0715 방법으로 측정한 땀 견뢰도 및 KS K 0650 방법으로 측정한 마찰견뢰도 모두가 각각 4.5급 이상인 것을 특징으로 하는 방수성이 우수한 위장날염 천막덮개 원단.The light fastness measured by the KS K 0700 method, the laundry fastness measured by the KS K 0430 method, the sweat fastness measured by the KS K 0715 method, and the friction fastness measured by the KS K 0650 method. The camouflage tent cover fabric is excellent waterproof, characterized in that each of the 4.5 grade or more.
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101347192B1 (en) * 2012-05-12 2014-01-03 (주)원영티앤비 the printed cloth for camouflage with high waterproof and the manufacturing method thereof
KR20210052682A (en) * 2019-10-30 2021-05-11 장완건설 주식회사 High thermal shield, durability, thermal durability urethane waterproof coating containing carbon fiber composition
WO2023163993A1 (en) * 2022-02-22 2023-08-31 Live Watersports, LLC Cosmetically altered fiberglass piece and related methods

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101347192B1 (en) * 2012-05-12 2014-01-03 (주)원영티앤비 the printed cloth for camouflage with high waterproof and the manufacturing method thereof
KR20210052682A (en) * 2019-10-30 2021-05-11 장완건설 주식회사 High thermal shield, durability, thermal durability urethane waterproof coating containing carbon fiber composition
WO2023163993A1 (en) * 2022-02-22 2023-08-31 Live Watersports, LLC Cosmetically altered fiberglass piece and related methods
US11969982B2 (en) 2022-02-22 2024-04-30 Live Watersports, LLC Cosmetically altered fiberglass piece

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