KR20110064293A - Antibiosis with fixed thermal conductivity and coating method thereof - Google Patents
Antibiosis with fixed thermal conductivity and coating method thereof Download PDFInfo
- Publication number
- KR20110064293A KR20110064293A KR1020090120811A KR20090120811A KR20110064293A KR 20110064293 A KR20110064293 A KR 20110064293A KR 1020090120811 A KR1020090120811 A KR 1020090120811A KR 20090120811 A KR20090120811 A KR 20090120811A KR 20110064293 A KR20110064293 A KR 20110064293A
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- coat
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47J—KITCHEN EQUIPMENT; COFFEE MILLS; SPICE MILLS; APPARATUS FOR MAKING BEVERAGES
- A47J36/00—Parts, details or accessories of cooking-vessels
- A47J36/02—Selection of specific materials, e.g. heavy bottoms with copper inlay or with insulating inlay
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
- B05D7/56—Three layers or more
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2350/00—Pretreatment of the substrate
- B05D2350/30—Change of the surface
- B05D2350/33—Roughening
- B05D2350/38—Roughening by mechanical means
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- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Food Science & Technology (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
Apparatus having an antimicrobial performance of the present invention and a method for forming a coating layer thereof is a mechanism in which a primer coat, a mid coat, and a top coat are sequentially stacked on a surface to form a three coating layer, wherein the coating liquid of the primer coat in the three coating layer is nmp of polyamide. The composition and composition ratio of the dissolution mixture, water, PTFE dispersion, carbon black dispersion and silica dispersion, and the coating of the mid coat is PTFE dispersion, water, aromatic hydrocarbon, triethylamine, oleic acid, surfactant, carbon black dispersion, It is composed of mica composition and composition ratio, and the coating liquid of the top coat is composed of PTFE dispersion, water, aromatic hydrocarbon, triethylamine, oleic acid, surfactant, mica composition and composition ratio, and antibacterial to each coat surface The antibacterial powder is added to the selected coat surface by spraying with a sprayer by adding powder or mixing antibacterial powder with ink pigment. The heat treatment and, after that word applied.
Description
The present invention relates to a device having an antimicrobial performance and a method for forming a coating layer thereof, and more particularly, by adding a powder having an antibacterial property to the coating layer boundary of the device and coating it selectively with heat treatment, thereby preventing the antibacterial and deodorizing of the device. The present invention relates to a device having an antimicrobial performance and a coating layer composition method thereof to improve the performance.
Of the common appliances that need to be coated on the surface, all instruments are generally made of metal, such as aluminum. Initially, the appliance itself has been used even with the metal itself. In order to prevent the problem such as scratching the surface of the device when cooking the same thing or in other cases, after the development of a mechanism for applying a coating liquid to the surface to form a coating layer on the surface has been developed In addition to various types of coating liquids, various types of coating layers were formed on the surface.
Among them, a primer coat, a mid coat, and a top coat are sequentially laminated on the surface of the apparatus, so-called three coatings forming a coating layer are commonly applied to the apparatus. Doing.
That is, as shown in Figure 1, the triple coating layer applied to the surface of the instrument is subjected to a primer coat 12 (undercoat) on the
And it is manufactured by performing the top coat 15 (top coat) on the
In addition, on the
By the way, in order to explain the coating layer, the coating layer of the kitchen appliance of the type described above was representatively selected, but in the end, all the coating layers of the surface of the apparatus remain only to protect the surface of the apparatus or express the aesthetic sense. Since the composition constituting the coating layer itself does not have a specific property to exert a special effect on the human body, in order to cook the food that a human ingests, the raw material of the food must be coated with the coating layer formed on the surface of the kitchen utensil. In view of the contact, it may not be overlooked that the coating component of the kitchen utensils necessarily affects the raw material of the food to some extent.
However, since cooking utensils are foods for human consumption, physical properties to satisfy wear resistance are important, but above all, it is more important to have antimicrobial and sterilization properties that have a beneficial effect on cooked foods. The conventional coating layer is limited only to improvement of physical properties such as abrasion resistance, there is a problem that the beneficial properties to the human body does not exist at all in the component itself to form the coating layer.
These cooking utensils are coated with a fluorine resin on the inner surface of the preservative container made of aluminum, stainless steel, etc., and exhibits heat resistance to prevent the food from burning in a high temperature state when cooking the food and non-sticking property to prevent the food from sticking to the inner surface thereof.
When internal treatment with only fluorine resin through this, there was a lack of antimicrobial properties, there was an unsanitary problem in which various bacteria propagate due to black discoloration, odor and mucus generation of the food caused by molds after a certain time.
The present invention has been made to solve the above problems, and an object of the present invention is to coat the three coat layer with an antimicrobial composition having antibacterial, bactericidal and deodorizing functions, so that each coat has a bactericidal and deodorizing performance. .
In addition, an object of the present invention is to maintain the antibacterial, deodorizing function by coating and coating the antimicrobial composition that selectively acts antibacterial and deodorizing function to the primer, mead, top coating layer boundary forming three coatings .
In addition, it is an object of the present invention to further maximize the antibacterial, deodorizing function through the far-infrared emission from the apparatus exposed to heat during food cooking by using the characteristics of the antimicrobial composition that the far-infrared emission is original as the heat is applied.
In order to achieve this object, the apparatus having the antimicrobial performance of the present invention is a mechanism in which a primer coat, a mid coat, and a top coat are sequentially stacked on a surface to form a three coating layer, wherein the coating liquid of the primer coat in the three coating layer is formed of polyamide. The composition and composition ratio of nmp soluble mixture, water, PTFE dispersion, carbon black dispersion, and silica dispersion, and the coating of the mid coat are PTFE dispersion, water, aromatic hydrocarbon, triethylamine, oleic acid, surfactant, and carbon black dispersion. , The composition and composition ratio of the mica, the coating liquid of the top coat is made of PTFE dispersion, water, aromatic hydrocarbon, triethylamine, oleic acid, surfactant, mica composition and composition ratio, the primer coat, mead Selected coat by selectively adding antibacterial powder among coating solution of coat and top coat and then heat-treating Such that the antimicrobial coating is formed.
The apparatus having an antimicrobial performance of the present invention is a mechanism in which a primer coat, a mid coat, and a top coat are sequentially stacked on a surface to form a three coating layer, wherein the coating liquid of the primer coat in the three coating layer is a nmp soluble mixture of polyamide, water, The composition and composition ratio of PTFE dispersion, carbon black dispersion, and silica dispersion, and the coating of the mid coat are composed of PTFE dispersion, water, aromatic hydrocarbon, triethylamine, oleic acid, surfactant, carbon black dispersion, and mica. The coating liquid of the top coat is composed of PTFE dispersion, water, aromatic hydrocarbon, triethylamine, oleic acid, surfactant, and mica, and the composition ratio is selected. Mix with pigment and spray with a sprayer to apply the antimicrobial powder on the surface of the selected coat, and then heat It will be such that the antimicrobial coating of the pigment ink formed between the selected coat.
According to the present invention, the coating solution of the primer coat in the three coating layer is a composition of 16.8% by weight nmp dissolved mixture of polyamide, 4.1% by weight of water, 67.2% by weight of PTFE dispersion, 3.5% by weight of carbon black dispersion, 8.4% by weight of silica dispersion. And the composition ratio of the mid coat, and the coating liquid of the mid coat is 81.5 wt% of PTFE dispersion, 9.22 wt% of water, 3.14 wt% of aromatic hydrocarbon, 0.46 wt% of triethylamine, 0.46 wt% of oleic acid, 0.33 wt% of surfactant, carbon The composition and composition ratio of 3.35% by weight of the black dispersion, 1.54% by weight of mica, and the coating of the top coat is 89.25% by weight of PTFE dispersion, 6.53% by weight of water, 1.09% by weight of aromatic hydrocarbons, 0.32% by weight of triethylamine, It consists of 0.32% by weight of oleic acid, 0.25% by weight of surfactant and 2.24% by weight of mica.
According to the present invention, the antibacterial powder is composed of granite diorite rock having adsorptivity by fine pores formed on the surface.
According to the present invention, the antimicrobial powder is composed of granules and granules tourmaline powder, which is a polar crystal having electric polarization, and granules and granules powder and tourmaline powder in a 7: 3 ratio.
According to the present invention, the antimicrobial powder is contained in an amount of 0.5 to 5 parts by weight based on 100 parts by weight of the coating liquid of each of the primer coat or the mid coat or the top coat.
According to the present invention, the antimicrobial powder has a size of 0.05μ ~ 5μ.
According to the present invention, an antimicrobial powder is added directly to the coating liquid on the mid coat without the top coat, or an ink pigment containing the antimicrobial powder is applied to form an antimicrobial coating layer.
According to the present invention, the antimicrobial powder is added directly to the coating liquid on the primer coat except for the mid coat, or the antimicrobial powder contains an ink pigment to form an antimicrobial coating layer.
According to the present invention, the coating liquid of the ink pigment consists of a composition of PTFE dispersion, water, aromatic hydrocarbon, triethylamine, oleic acid, surfactant, inorganic pigment dispersion.
The coating layer composition method of the device having the antimicrobial performance of the present invention comprises the steps of increasing the surface area by sand blasting on the surface of the device to be coated; Cleaning the surface of the instrument; Applying a primer coating liquid to the surface of the apparatus with a thickness of 10 to 12 μm to form a primer coat, and then heat-treating at 200 ° C. for 15 minutes; After the antimicrobial powder is added to the coating liquid on the primer coat or the ink pigment containing the antimicrobial powder is sprayed, heat treatment is performed at 405 to 415 ° C. for 20 minutes to form an antimicrobial coating layer.
The coating layer composition method of the device having the antimicrobial performance of the present invention comprises the steps of increasing the surface area by sand blasting on the surface of the device to be coated; Cleaning the surface of the instrument; Applying a primer coating liquid to the surface of the apparatus with a thickness of 10 to 12 μm to form a primer coat, and then heat-treating at 200 ° C. for 15 minutes; After applying a mid coat liquid on the primer coat to a thickness of 10 ~ 12㎛ to form a wet mid coat, by adding an antibacterial powder to the coating liquid on the mid coat or by spraying an ink pigment containing an antibacterial powder After the antimicrobial coating layer is formed, the step of heat treatment for 20 minutes at 405 ~ 415 ℃.
The coating layer composition method of the device having the antimicrobial performance of the present invention comprises the steps of increasing the surface area by sand blasting on the surface of the device to be coated; Cleaning the surface of the instrument; Applying a primer coating liquid to the surface of the apparatus to a thickness of 10 to 12 μm to form a primer coat, and then drying at 200 ° C. for 15 minutes; After the mid coat liquid was applied on the primer coat with a thickness of 10 to 12 μm to form a wet mid coat, the top coat liquid was applied onto the mid coat with a thickness of 8 to 12 μm on the mid coat. Forming a top coat and drying for 15 minutes at 200 ~ 300 ℃; Adding an antimicrobial powder to the coating solution on the dried top coat or spraying an ink pigment containing an antimicrobial powder to form an antimicrobial coating layer having irregular shapes, and then heat-treating at 405 to 415 ° C. for 20 minutes. .
According to the present invention, a transparent discontinuous coating layer may be further included on top of the antimicrobial coating layer selectively applied in the primer coat, the mid coat, and the top coat.
As described above, the apparatus having an antimicrobial performance of the present invention and its coating method are coated with an antimicrobial powder composed of granular chlorophyllum rock having adsorption and tourmaline powder, which is a polar crystal having electrical polarization, by the micropores formed on the surface thereof. The bacterium eradication and deodorization performance of the coat can be guaranteed, and the bactericidal function can be quickly performed within 2 hours after the instrument cleaning.
In addition, the apparatus having an antimicrobial performance of the present invention and a coating method thereof may be coated by coating and then selectively coating an antimicrobial composition having a selective antibacterial and deodorizing function at a boundary of a primer, a mead, and a top coating layer forming three coatings. It is effective to maintain the deodorizing function continuously.
In addition, the apparatus having an antimicrobial performance of the present invention and its coating method further increase the antibacterial and deodorizing function through the far-infrared emission from the apparatus exposed to heat during food cooking by using the characteristics of the antimicrobial composition that the far-infrared emission becomes more raw as heat is applied. It has the effect of maximizing.
Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the accompanying drawings.
First, in the drawings, the same components or parts are to be noted that the same reference numerals as possible. In describing the present invention, detailed descriptions of related well-known functions or configurations are omitted in order not to obscure the subject matter of the present invention.
As used herein, the terms "about", "substantially", and the like, are used at, or in proximity to, the numerical values of the preparations and material tolerances inherent in the meanings indicated, and an understanding of the invention Numerical, accurate or absolute figures, are used to assist in the prevention of unfair use by unscrupulous infringers.
Figure 2 is a block diagram showing the coating step of the device according to the invention, Figure 3 is a perspective view showing the device according to the invention, Figure 4 is a partially enlarged cross-sectional view showing a coating layer of the device according to the invention, Figure 5 Is a partially enlarged cross sectional view showing another embodiment of a coating layer of an appliance according to the invention.
First, as shown in Figures 2 to 5, the apparatus having an antimicrobial performance of the present invention and its coating layer composition method is as follows.
A
That is, the coating solution of the primer coat in the three coating layer is made of the composition and composition ratio of nmp soluble mixture of polyamide, water, PTFE dispersion, carbon black dispersion, silica dispersion.
The coating solution of the mid coat is composed of the composition and proportion of PTFE dispersion, water, aromatic hydrocarbon, triethylamine, oleic acid, surfactant, carbon black dispersion, mica.
The coating solution of the top coat is composed of PTFE dispersion, water, aromatic hydrocarbon, triethylamine, oleic acid, surfactant, and mica.
When each coat is made of the composition as described above, the antimicrobial powder is selectively added to the primer coat, the mid coat, and the top coat coating solution, followed by heat treatment to form an antimicrobial coating layer on the selected coat.
In other words, the antimicrobial powder is added to the coating liquid of each coat, and may be selectively added to each coat.
Alternatively, the antimicrobial powder may be selectively mixed with the ink pigment on the surface of each coat and sprayed with an atomizer to apply the antimicrobial powder to the selected coat surface, and then heat-treated to form an antimicrobial coating layer of the ink pigment between the selected coats.
As described above, the antimicrobial powder may be directly added to the coating solution of the primer coat, the mid coat, and the top coat, or the antimicrobial powder may be added to each coat and then sprayed selectively on each coat to form an antimicrobial coating layer. have.
Here, 0.5 to 5 parts by weight of the antimicrobial powder is included with respect to 100 parts by weight of the coating liquid of each of the primer coat or the mid coat or the top coat.
Subsequently, the antimicrobial coating layer is selectively formed on the coat by curing through heat treatment.
Here, the antimicrobial powder is applied to granite diorite rock having adsorption by micropores formed on the surface, and powdered into a powder form.
Alternatively, the antimicrobial powder may be composed of tourmaline powder, which is a polar crystal having granulocylenite powder and electrical polarization.
At this time, the antibacterial powder is granulated diorite rock powder and tourmaline powder is added in a ratio of 7: 3.
The components of granite diorite rock applied to the antibacterial powder in the present invention are shown in Table 1 below.
SiO2
67.42
AL2O3
12.30
FeO2
1.07
TiO2
0.06
CaO
0.82
MgO
0.13
Na2O
3.36
K2O
4.55
Ig.loss
0.49
The granite diorite rock refers to igneous rocks rich in silicon oxide in chemical composition, and mineral composition is almost the same as granite. Peel-like tissue consisting of semifinished tablets of granules and stone of fine or neutral.
Mineral composition is almost the same as granite, but it is semi-structured and composed of semi-crystal of granulation and fine or neutral stone. Semi-crystal contains many crystals of quartz or potassium feldspar and contains a small amount of mica. Like granite, the stoneware itself is crystalline and granular, but much smaller. Granite rock is produced at the periphery of a fairly large granite body or as an independent rock.
Since granite diorite is the main component is silicic anhydride and aluminum oxide. Yellowish white is used as filter, anti-inflammatory and so on. It is called weak stone. It emits far infrared rays and is applied to jjimjilbang, tableware and medical equipment.
Particularly, granulocythemia is also called as a medicinal stone. In the past, it was used as an anti-inflammatory agent for treating skin diseases such as swelling or boils.
The granulophyllite is composed of 3 to 150,000 holes per cubic centimeter, which is highly adsorptive and contains about 25,000 inorganic salts.
Moreover, it acts as a toxic metal remover because it functions to exchange ions with heavy metals, and heat is emitted to the rock to emit far infrared rays.
The apparatus of the present invention, which is applied to the cooking of foods by using the properties of granite chlorophyll, has a strong adsorption effect, so it adsorbs heavy metals such as Cd and Hg, residual chlorine, E. coli, and radioactive substances, and thus, bacteria generated in kitchen equipment. Removal can be done quickly.
In addition, far-infrared emission may proceed more easily because it is directly exposed to heat when used for food cooking.
Such, the antibacterial device of the present invention by selectively coating the antimicrobial powder having antibacterial, sterilization and deodorizing function on each coat layer boundary, to ensure the eradication of bacteria, deodorizing performance of each coat, after cleaning the instrument It can perform antibacterial and deodorizing function within 2 hours.
In order to prove such an effect, the apparatus having the antimicrobial performance of the present invention was commissioned by the Korea Institute of Construction Materials, and the results of the antimicrobial performance after incubation with E. coli strains are shown in Table 2 below.
Test Items
Test result
Test Methods
Initial concentration
(CFU / 70p)
Concentration after 2 hours
(CFU / 70a)
Bacterial reduction rate
(%)
E. coli
by
Antibacterial test
BLANK
839
839
-
Requester
suggest
Silver metalic clean fry pan
839
One
99.9
As shown in [Table 2], after the culture of Escherichia coli Escherichia coli ATCC 25922 in the initial concentration of 839 CFU / 70p on the surface of the apparatus and anti-bacterial bacterium having a bactericidal performance of the present invention at the initial concentration of 839 CFU / 70p As a result of testing by the method (KICM-FIR-1003), after 2 hours, the same result as the initial concentration was measured in the normal sample (BLANK).
On the contrary, it can be seen that the apparatus having the antimicrobial performance of the present invention reduced the concentration of the used strain to 1CFU / 70p after 2 hours at the initial initial concentration of 839 (CFU / 70p).
As a result, in the general sample, while the bacterial reduction rate was 0%, the apparatus having the antimicrobial performance of the present invention showed a 99.9% bacterial reduction rate by the antibacterial powder.
In addition, the antimicrobial powder applied to the apparatus having antimicrobial performance can further maximize the antibacterial and deodorizing performance by adding tourmaline.
Here, tourmaline is a borosilicate having a hexagonal columnar crystal and refers to a natural mineral belonging to a hexagonal system.
The tourmaline is also known as tourmaline because the crystal itself generates electricity, and has only permanent electrical properties among the minerals present on Earth.
This is also called a polar crystal, and this ore generates negative ions and weak currents and far infrared rays generated by itself. For this reason, the tourmaline crystals have positive and negative electrodes at both ends of the crystals, no matter how small they are crushed, and they have electrodes that do not decay permanently unless heated near 1000 ° C. to be.
Here, when the positive and negative poles of the tourmaline crystal are connected, a weak current of 0.06 mA flows.
Such tourmaline generates negative ions and far infrared rays of 4 to 14 (μm) growth rays due to adsorption and repulsion, so that even if the smell of food to be cooked is adsorbed on the surface of the appliance to generate odors, dl cations and anions are combined. As a result of the electrical odor, the odorless odorless (odorless) phenomenon occurs, it is possible to more effectively exhibit the deodorizing function of the antibacterial powder.
In addition, the tourmaline has the effect of removing not only the smell soaked on the surface of the device but also the smell of floating in the room.
Moreover, the tourmaline increases the radiation amount to the far infrared rays by applying heat from the outside. This is the same as the properties of granite calculocarcinoma has the effect of increasing the far-infrared emission by heat even in the cooking process through the apparatus having antibacterial performance.
Finally, the present invention by selectively coating the antimicrobial powder having antibacterial, bactericidal and deodorizing function on each coat layer boundary by using granite diorite rock and tourmaline ore having antibacterial and deodorizing function, the bacterial eradication and deodorizing performance of each coat is improved. It can be ensured, and within two hours after the cleaning of the instrument to perform the bactericidal function quickly, there is an effect that can deodorize the surface of the appliance or deodorant of the food to be cooked.
Here, the antibacterial powder is usually made in the form of a powder and the size is made of a size of 0.05μ ~ 5μ.
This, while diversifying the shape of the powder to add the aesthetic effect of the antimicrobial coating layer coated on the surface of the instrument, and through the antimicrobial powder of the thin film having a wider to ensure more improved antibacterial and deodorizing effect.
The composition and composition ratio of the three coating layer are as follows.
The composition ratio of the coating solution of the
The coating solution of the
The composition ratio of the
In addition, the coating liquid of the
The coating liquid composition ratio of the
As described above, the antimicrobial powder contains 2 to 3 parts by weight based on 100 parts by weight of the coating liquid of each of the
In addition, the
That is, the
Alternatively, the
Alternatively, the
In this way, the surface of the
The thickness of the
Here, the
In addition, the above three coating is only one embodiment, it can be applied to apply the antimicrobial powder to water-based fluorine resin 1 coating, fluorine resin 2 coating, fluorine resin 3 coating and multi-layer coating, such as various coatings The antimicrobial coating layer to be applied is added one of the composition constituting all the paint products for forming the coating layer, that is, silicone oil paint, oily fluorocarbon resin paint, ceramic paint and the like.
In addition, the thickness of the three
Since this leads to a problem of lowering the productivity, when the ink pigment is applied on the top coat of the three
In addition, the antimicrobial powder having an antimicrobial function contained in the ink pigment is included, so that bacteria generated before and after washing can be quickly extinguished within 2 hours.
In addition, the ink pigment dispersed on the
A method of forming a coating layer on the surface of the
Firstly, the surface area is increased by a sand blasting process in which a number of fine embossings are formed on the surface of the
The second step is to clean the surface of the sandblasted
In the third step, the primer coating solution is applied to the surface of the sandblasted and washed
In a fourth step, the mid coat liquid is applied to the
In the fifth step, the top coat liquid is coated with a thickness of 8 to 12 μm while the
After the dried
Here, the application of the antimicrobial powder is the
Alternatively, before the heat treatment may be applied by coating an ink pigment containing an antimicrobial powder or an antimicrobial powder on the top coat in a wet state and heat treatment at 405 ~ 415 ℃ for 20 minutes.
In particular, by including a transparent discontinuous coating layer on top of the antimicrobial powder applied on the
In the
Alternatively, the
In addition, in the coating layer composition method, the
When the method is applied, the size of the
By the way, although the
In addition, when the coating layer is formed by the method as described above, by selectively forming the
1 is a perspective view showing a state of coating of the apparatus according to the prior art.
2 is a block diagram showing the coating step of the device according to the invention.
3 is a perspective view of a mechanism according to the present invention;
4 is a partially enlarged cross-sectional view showing a coating layer of the appliance according to the invention.
5 is a partially enlarged cross-sectional view showing another embodiment of a coating layer of an appliance according to the invention.
Explanation of symbols on the main parts of the drawings
10: apparatus 100: three coating layer
110: primer coat 120: mid coat
130: top coat 140: antimicrobial coating layer
Claims (14)
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KR1020090120811A KR20110064293A (en) | 2009-12-07 | 2009-12-07 | Antibiosis with fixed thermal conductivity and coating method thereof |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103431770A (en) * | 2013-08-03 | 2013-12-11 | 刘广进 | Cast iron stone electric cooker inner pot and production method thereof |
WO2017018776A1 (en) * | 2015-07-28 | 2017-02-02 | (주)더몰론코리아 | Ceramic printing ink composition having antibacterial function |
-
2009
- 2009-12-07 KR KR1020090120811A patent/KR20110064293A/en not_active Application Discontinuation
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103431770A (en) * | 2013-08-03 | 2013-12-11 | 刘广进 | Cast iron stone electric cooker inner pot and production method thereof |
WO2017018776A1 (en) * | 2015-07-28 | 2017-02-02 | (주)더몰론코리아 | Ceramic printing ink composition having antibacterial function |
US10640663B2 (en) | 2015-07-28 | 2020-05-05 | Thermolon Korea Co., Ltd. | Ceramic printing ink composition having antibacterial function |
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