KR20110050841A - Magnetic material and method for fabricating the same - Google Patents
Magnetic material and method for fabricating the same Download PDFInfo
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- KR20110050841A KR20110050841A KR1020090107386A KR20090107386A KR20110050841A KR 20110050841 A KR20110050841 A KR 20110050841A KR 1020090107386 A KR1020090107386 A KR 1020090107386A KR 20090107386 A KR20090107386 A KR 20090107386A KR 20110050841 A KR20110050841 A KR 20110050841A
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Abstract
Description
본 발명의 실시예들은 고 주파수 대역에서도 높은 투자율을 유지할 수 있는 자성체 기술에 관한 것이다.Embodiments of the present invention are directed to a magnetic material technology that can maintain a high permeability even in a high frequency band.
일반적으로 자성체는 소정의 유전율과 투자율을 가지고 있다. 이러한 자성체의 유전율과 투자율은 주파수에 따라 가변되는 특성을 보인다. 구체적으로, 상기 자성체의 투자율은 낮은 주파수 대역에서는 높은 투자율을 가지나, 주파수가 높아질수록 투자율이 점차 감소하고 투자 손실이 높아지는 경향이 있으며, 이를 스넉스 한계(Snoek's Limit)라고 한다.In general, magnetic materials have a predetermined permittivity and permeability. The permittivity and permeability of these magnetic materials vary with frequency. Specifically, the magnetic permeability of the magnetic material has a high permeability in a low frequency band, but as the frequency increases, the permeability gradually decreases and the investment loss tends to be high, which is called a Snoek's Limit.
도 1은 W형 자성체(BaMxFe16O27)에서 x 값의 변화에 따른 각 자성체의 스넉스 한계(Snoek's Limit)를 나타낸 그래프로서, 도 1a는 W형 자성체의 투자율 중 실수부 값(μ')을 나타낸 그래프이고, 도 1b는 W형 자성체의 투자율 중 허수부 값(μ '')을 나타낸 그래프이다.1 is a graph showing the Snoek's Limit of each magnetic material according to the change of x value in the W-type magnetic material (BaM x Fe 16 O 27 ), Figure 1a is a real part value of the permeability of the W-type magnetic material (μ ') Is a graph showing the imaginary part value (μ') of the magnetic permeability of the W-type magnetic material.
도 1을 참조하면, W형 자성체가 100 MHz까지는 일정한 투자율을 가지다가 100 MHz를 벗어나 주파수가 증가할수록 투자율이 급격히 감소하는 것을 볼 수 있으며, 특히 주파수가 1GHz를 넘어가는 경우 투자율이 거의 1에 근접하는 것을 볼 수 있다. 이때, 낮은 주파수 대역에서 높은 투자율을 가진 자성체일수록, 주파수가 높아질 때 더욱 급한 경사를 가지고 투자율이 낮아지는 것을 볼 수 있다.Referring to FIG. 1, it can be seen that the W-type magnetic material has a constant permeability up to 100 MHz, but the permeability rapidly decreases as the frequency increases beyond 100 MHz, especially when the frequency exceeds 1 GHz, the permeability is nearly 1. I can see that. At this time, the magnetic material having a high permeability in the low frequency band, it can be seen that the magnetic permeability has a steep slope and the permeability is lower when the frequency is higher.
또한, 투자 손실은 투자율의 허수부 값/투자율의 실수부 값(즉, μ''/μ')으로서, 낮은 주파수에서는 높은 투자 손실을 갖다가 주파수가 높아질수록 낮은 투자 손실을 갖는 것을 볼 수 있다.In addition, the investment loss is the imaginary part of the permeability / the real part value of the permeability (that is, μ '' / μ '), it can be seen that a high investment loss at a low frequency, but a low investment loss at higher frequencies .
이러한 스넉스 한계를 뛰어 넘어 고주파 대역에서도 높은 투자율을 가지도록 헥사 타입(Hexa Type)의 자성체에 대한 연구가 이루어지고 있으나, 헥사 타입의 자성체도 1GHz를 넘어가는 고 주파수 대역에서는 투자율이 급격히 감소하고, 2GHz 이후의 주파수 대역에서는 대부분 2 이하의 투자율 값을 가진다.Hexa type magnetic material has been studied to have high permeability even in high frequency bands beyond the snooze limit, but the magnetic permeability of hexa type magnetic material is also rapidly reduced in high frequency bands exceeding 1 GHz. In the frequency band after 2GHz, most have permeability values of 2 or less.
따라서, 고주파수 대역에서도 높은 투자율 및 낮은 투자 손실을 유지할 수 있는 자성체 및 그 제조 방법이 요구된다.Therefore, there is a need for a magnetic material capable of maintaining a high permeability and a low permeability even in a high frequency band and a method of manufacturing the same.
본 발명의 실시예들은 주파수가 높아질수록 투자율이 급격히 저하되어 낮은 투자율을 갖게 되는 스넉스 한계(Snoek's Limit)를 극복함으로써, 자성체가 고 주파수 대역에서도 높은 투자율을 유지할 수 있도록 한다.Embodiments of the present invention by overcoming the Snoek's Limit that the magnetic permeability is rapidly lowered to have a lower permeability as the frequency increases, the magnetic material can maintain a high permeability even in the high frequency band.
본 발명의 실시예들에 의한 다른 기술적 해결 과제는 하기의 설명에 의해 이해될 수 있으며, 이는 특허청구범위에 나타낸 수단 및 그 조합에 의해 실현될 수 있다.Other technical problems by the embodiments of the present invention can be understood by the following description, which can be realized by the means and combinations thereof shown in the claims.
본 발명의 일 실시예에 따른 자성체는, 조성이 BaAMBFeCOD 인 W형 자성체에 있어서, 상기 메탈 사이트(MB)는 Mn, Zn, Cu, 및 Co 중 하나 이상의 원소를 포함하며, 상기 A, C, D는 0.5 ≤ A ≤ 1.5, 14 ≤ C ≤ 18, 24 ≤ D ≤ 30의 범위를 갖는다.In a magnetic material according to an embodiment of the present invention, in the W-type magnetic material whose composition is Ba A M B Fe C O D , the metal site (M B ) includes one or more elements of Mn, Zn, Cu, and Co. And A, C, and D have a range of 0.5 ≦ A ≦ 1.5, 14 ≦ C ≦ 18, and 24 ≦ D ≦ 30.
또한, 본 발명의 일 실시예에 따른 자성체 제조방법은, 조성이 BaAMBFeCOD (여기서, 0.5 ≤ A ≤ 1.5, 14 ≤ C ≤ 18, 24 ≤ D ≤ 30)인 W형 자성체의 제조방법에 있어서, (A) Ba 산화물, Fe 산화물, 및 상기 메탈 사이트(MB)인 Mn, Zn, Cu, Co 산화물 중에서 선택된 하나 이상의 산화물을 소정의 조성이 되도록 혼합하는 단계; 및 (B) 상기 혼합한 산화물을 가공 처리하여 자성체를 형성하는 단계를 포함한다.In addition, the magnetic material manufacturing method according to an embodiment of the present invention, the composition is a W A magnetic material Ba A M B Fe C O D (where 0.5 ≦ A ≦ 1.5, 14 ≦ C ≦ 18, 24 ≦ D ≦ 30) In the manufacturing method of (A) Ba oxide, Fe oxide, and the metal site (M B ) Mn, Zn, Cu, Co oxides of the oxide selected from Co oxides mixed to a predetermined composition; And (B) processing the mixed oxides to form a magnetic body.
본 발명의 실시예들에 의하면, 주파수가 높아질수록 투자율이 급격히 저하되어 낮은 투자율을 갖게 되는 스넉스 한계(Snoek's Limit)를 극복함으로써, 자성체가 고 주파수 대역에서도 높은 투자율 및 낮은 투자 손실을 유지할 수 있게 된다.According to embodiments of the present invention, the magnetic permeability can be maintained even at high frequency bands by overcoming the Snoek's Limit in which the permeability decreases rapidly as the frequency increases to have a low permeability. do.
이하, 도 2 내지 도 4를 참조하여 본 발명의 자성체 및 그 제조 방법의 구체적인 실시예를 설명하기로 한다. 그러나 이는 예시적 실시예에 불과하며 본 발명은 이에 제한되지 않는다.Hereinafter, with reference to Figures 2 to 4 will be described a specific embodiment of the magnetic material of the present invention and its manufacturing method. However, this is only an exemplary embodiment and the present invention is not limited thereto.
본 발명을 설명함에 있어서, 본 발명과 관련된 공지기술에 대한 구체적인 설명이 본 발명의 요지를 불필요하게 흐릴 수 있다고 판단되는 경우에는 그 상세한 설명을 생략하기로 한다. 그리고, 후술되는 용어들은 본 발명에서의 기능을 고려하여 정의된 용어들로서 이는 사용자, 운용자의 의도 또는 관례 등에 따라 달라질 수 있다. 그러므로 그 정의는 본 명세서 전반에 걸친 내용을 토대로 내려져야 할 것이다. In describing the present invention, when it is determined that the detailed description of the known technology related to the present invention may unnecessarily obscure the subject matter of the present invention, the detailed description thereof will be omitted. The following terms are defined in consideration of the functions of the present invention, and may be changed according to the intention or custom of the user, the operator, and the like. Therefore, the definition should be based on the contents throughout this specification.
또한, 본 발명의 기술적 사상은 청구범위에 의해 결정되며, 이하 실시예는 진보적인 본 발명의 기술적 사상을 본 발명이 속하는 기술분야에서 통상의 지식을 가진자에게 효율적으로 설명하기 위한 일 수단일 뿐이다.In addition, the technical spirit of the present invention is determined by the claims, the following embodiments are merely one means for efficiently explaining the technical spirit of the present invention to those skilled in the art to which the present invention belongs. .
본 발명의 실시예들은 W형 자성체 물질 즉, 조성이 BaAMBFeCOD 인 물질에서 메탈 사이트(MB)에 들어갈 원소들의 조성비를 조절하여, 고 주파수 대역(예를 들어, 1GHz 이상)에서도 높은 투자율 및 낮은 투자 손실을 유지하는 자성체를 제공하고자 한다. 여기서, A, C, D는 0.5 ≤ A ≤ 1.5, 14 ≤ C ≤ 18, 24 ≤ D ≤ 30 의 범위를 갖는다.Embodiments of the present invention by adjusting the composition ratio of the elements to enter the metal site (M B ) in the W-type magnetic material, that is, the composition is Ba A M B Fe C O D , the high frequency band (for example, 1GHz or more ) Also provides a magnetic material that maintains a high investment rate and a low investment loss. Here, A, C, and D have a range of 0.5 ≦ A ≦ 1.5, 14 ≦ C ≦ 18, and 24 ≦ D ≦ 30.
즉, 조성이 BaAMBFeCOD 인 W형 자성체 물질을 주상으로 하여 메탈 사이트(MB)에 들어갈 원소들의 조성비를 조절함으로써, 상기 W형 자성체가 고 주파수 대역에서도 높은 투자율 및 낮은 투자 손실을 가지도록 한다.That is, by adjusting the composition ratio of the elements to enter the metal site (M B ) with a W-type magnetic material having a composition of Ba A M B Fe C O D as a main phase, the W-type magnetic material has a high permeability and a low investment even in a high frequency band Have a loss.
상기 메탈 사이트(MB)에 들어가는 원소로는 Mn, Zn, Cu, 및 Co 중 하나 이상의 원소를 포함하는 것으로 한다. 여기서, 상기 메탈 사이트(MB)에 들어가는 원소들의 조성 비율은 다음과 같다. As the element entering the metal site M B , one or more elements of Mn, Zn, Cu, and Co shall be included. Here, the composition ratio of the elements entering the metal site (M B ) is as follows.
예를 들어, MB = MnxZnyCuzCov 으로 이루어질때, 상기 메탈 사이트(MB)에 들어가는 원소들의 조성 비율이 1.9 ≤ x+y+z+v ≤ 2.1 이 되도록 하며, 특히 v ≥ 1.0 이 되도록 한다.For example, when M B = Mn x Zn y Cu z Co v , the composition ratio of elements entering the metal site M B is 1.9 ≦ x + y + z + v ≦ 2.1, in particular v ≥ 1.0
도 2는 본 발명의 일 실시예에 따른 W형 자성체 물질에서 메탈 사이트(MB)에 들어갈 원소들의 조성 비율에 따른 자성체의 투자율을 나타낸 도면이다. 여기서, 조성이 BaMBFe16O27인 W형 자성체 물질을 주상으로 하였고, 주파수 200 MHz, 1GHz, 2.4 GHz 대역에서 각 조성체 물질의 투자율(μr) 및 투자 손실을 나타내었다.FIG. 2 is a diagram illustrating magnetic permeability of a magnetic material according to a composition ratio of elements to enter metal sites (M B ) in a W-type magnetic material according to an embodiment of the present invention. Here, the W-type magnetic material having a composition of BaM B Fe 16 O 27 was used as a main phase, and the magnetic permeability (μ r ) and the investment loss of each composition material were shown in the
도 2를 참조하면, 표본 WMZO1 내지 WMZ03은 메탈 사이트(MB)에 Mn 및 Zn이 들어간 자성체로서, 구체적으로 표본 WMZO1은 BaMn0.5Zn1.5Fe16O27의 조성을 갖고, 표본 WMZ02는 BaMn1.0Zn1.0Fe16O27의 조성을 갖으며, 표본 WMZ03은 BaMn1.5Zn0.5Fe16O27의 조성을 갖는다. 상기 표본 WMZO1 내지 WMZ03은 200 MHz에서 투자율이 각각 1.9, 1.8, 1.7이고, 1GHz 및 2.4 GHz에서는 투자율이 거의 1에 근접하는 것을 볼 수 있다. Referring to FIG. 2, samples WMZO1 to WMZ03 are magnetic materials containing Mn and Zn in a metal site (M B ), and specifically, sample WMZO1 has a composition of BaMn 0.5 Zn 1.5 Fe 16 O 27 , and sample WMZ02 is BaMn 1.0 Zn 1.0 Fe 16 O 27 has a composition, sample WMZ03 has a composition of BaMn 1.5 Zn 0.5 Fe 16 O 27 . It can be seen that the samples WMZO1 to WMZ03 have permeability of 1.9, 1.8, and 1.7 at 200 MHz, respectively, and the permeability is close to 1 at 1 GHz and 2.4 GHz.
상기 표본 WMZO1 내지 WMZ03은 상기 메탈 사이트(MB)에 들어가는 원소들의 조성 비율이 1.9 ≤ x+y+z+v ≤ 2.1 의 범위를 만족하며, 주파수가 높아질수록 투자율이 저감되는 정도가 낮은 것을 볼 수 있다. 즉, 상기 표본 WMZO1 내지 WMZ03은 주파수가 높아질수록 투자율이 완만한 경사를 가지고 감소하는 것을 볼 수 있다.The samples WMZO1 to WMZ03 satisfy a composition ratio of 1.9 ≦ x + y + z + v ≦ 2.1 of elements entering the metal site (M B ), and as the frequency increases, the degree of permeability decreases. Can be. That is, it can be seen that the samples WMZO1 to WMZ03 decrease with a gentle slope as the frequency increases.
표본 WMC01 및 WMC02는 메탈 사이트(MB)에 Mn 및 Cu가 들어간 자성체로서, 구체적으로 표본 WMC01은 BaMn0.5Cu1.5Fe16O27의 조성을 갖고, 표본 WMC02는 BaMn1.0Cu1.0Fe16O27의 조성을 갖는다. 상기 표본 WMC01 및 WMC02는 200 MHz에서 투자율이 4 이상(각각 4.9, 4.1)으로 투자율이 높으나, 1GHz에서는 투자율이 각각 1.9, 1.8로 낮아지고, 2.4 GHz에서는 투자율이 각각 1.4, 1.5로 낮아지는 것을 볼 수 있다. Samples WMC01 and WMC02 are magnetic materials containing Mn and Cu in metal sites (M B ), specifically, sample WMC01 has a composition of BaMn 0.5 Cu 1.5 Fe 16 O 27 , and sample WMC02 has a composition of BaMn 1.0 Cu 1.0 Fe 16 O 27 . Have The samples WMC01 and WMC02 have a high permeability of 4 or more (4.9 and 4.1, respectively) at 200 MHz, but low permeability of 1.9 and 1.8 at 1 GHz and 1.4 and 1.5 at 2.4 GHz, respectively. Can be.
상기 표본 WMC01 및 WMC02는 상기 메탈 사이트(MB)에 들어가는 원소들의 조 성 비율이 1.9 ≤ x+y+z+v ≤ 2.1 의 범위를 만족하며, 주파수가 높아질수록 투자율이 저감되는 정도가 낮은 것을 볼 수 있다. 즉, 도 1의 W형 자성체는 100 MHz에서 1GHz로 갈수록 자성체의 투자율이 매우 급격한 경사를 가지고 감소하나, 상기 표본 WMC01 및 WMC02는 주파수가 증가할수록 투자율이 보다 완만한 경사를 가지고 감소한다.The samples WMC01 and WMC02 have a composition ratio of elements entering the metal site M B in a range of 1.9 ≦ x + y + z + v ≦ 2.1, and the higher the frequency, the lower the degree of permeability decreases. can see. That is, the magnetic permeability of the W-type magnetic body of FIG. 1 decreases with a very steep slope from 100 MHz to 1 GHz, but the samples WMC01 and WMC02 decrease with a gentler slope as the frequency increases.
표본 WCZ01 내지 WCZ03은 메탈 사이트(MB)에 Cu 및 Zn이 들어간 자성체로서, 구체적으로 표본 WCZO1은 BaCu0.5Zn1.5Fe16O27의 조성을 갖고, 표본 WCZ02는 BaCu1.0Zn1.0Fe16O27의 조성을 갖으며, 표본 WCZ03은 BaCu1.5Zn0.5Fe16O27의 조성을 갖는다. 상기 표본 WCZ01 내지 WCZ03은 200 MHz에서 투자율이 각각 2.0, 2.5, 2.7이나, 1GHz 및 2.4 GHz에서는 투자율이 거의 1에 근접하는 것을 볼 수 있다. Samples WCZ01 to WCZ03 are magnetic materials containing Cu and Zn in metal sites (M B ), specifically, sample WCZO1 has a composition of BaCu 0.5 Zn 1.5 Fe 16 O 27 , and sample WCZ02 has a composition of BaCu 1.0 Zn 1.0 Fe 16 O 27 . The sample WCZ03 has a composition of BaCu 1.5 Zn 0.5 Fe 16 O 27 . The samples WCZ01 to WCZ03 have a permeability of 2.0, 2.5, and 2.7 at 200 MHz, respectively, but the permeability is close to 1 at 1 GHz and 2.4 GHz.
상기 표본 WCZ01 내지 WCZ03은 상기 메탈 사이트(MB)에 들어가는 원소들의 조성 비율이 1.9 ≤ x+y+z+v ≤ 2.1 의 범위를 만족하며, 주파수가 높아질수록 투자율이 저감되는 정도가 낮아진 것을 볼 수 있다. The samples WCZ01 to WCZ03 satisfy a range of 1.9 ≦ x + y + z + v ≦ 2.1 of the elements entering the metal site (M B ), and as the frequency increases, the degree of permeability decreases. Can be.
표본 WMCZ01 내지 WMCZ03은 메탈 사이트(MB)에 Mn, Cu 및 Zn이 들어간 자성체로서, 구체적으로 표본 WMCZO1은 BaMn0.7Cu0.8Zn0.5Fe16O27의 조성을 갖고, 표본 WMCZ02는 BaMn0.5Cu1.0Zn0.5Fe16O27의 조성을 갖으며, 표본 WMCZ03은 BaMn0.3Cu1.2Zn0.5Fe16O27의 조성을 갖는다. 상기 표본 WMCZ01 내지 WMCZ03은 200 MHz에서 투자율이 각각 3.6, 3.7. 3.5로 투자율이 높으나, 1GHz에서는 투자율이 각각 1.5, 1.7, 1.6으로 낮아지고, 2.4 GHz에서는 투자율이 각각 1.4로 낮아지는 것을 볼 수 있다. Samples WMCZ01 to WMCZ03 are magnetic materials containing Mn, Cu, and Zn in metal sites (M B ), specifically, sample WMCZO1 has a composition of BaMn 0.7 Cu 0.8 Zn 0.5 Fe 16 O 27 , and sample WMCZ02 is BaMn 0.5 Cu 1.0 Zn 0.5 Fe 16 O 27 has a composition, and the sample WMCZ03 has a composition of BaMn 0.3 Cu 1.2 Zn 0.5 Fe 16 O 27 . The samples WMCZ01 to WMCZ03 have permeability rates of 3.6 and 3.7 at 200 MHz, respectively. Although the permeability is high at 3.5, the permeability is lowered to 1.5, 1.7 and 1.6 at 1 GHz, and the permeability is lowered to 1.4 at 2.4 GHz, respectively.
상기 표본 WMCZ01 내지 WMCZ03은 상기 메탈 사이트(MB)에 들어가는 원소들의 조성 비율이 1.9 ≤ x+y+z+v ≤ 2.1 의 범위를 만족하며, 주파수가 높아질수록 투자율이 저감되는 정도가 낮은 것을 볼 수 있다.The samples WMCZ01 to WMCZ03 satisfy a composition ratio of 1.9 ≦ x + y + z + v ≦ 2.1 of elements entering the metal site (M B ), and as the frequency increases, the degree of permeability decreases. Can be.
표본 WMOCZ01 내지 WMOCZ06은 메탈 사이트(MB)에 Co를 기본으로 포함하는 자성체로서, 표본 WMOCZ01는 메탈 사이트(MB)에 Co만 포함하나, 표본 WMOCZ02 내지 WMOCZ06은 메탈 사이트(MB)에 Mn, Co, Cu 및 Zn을 포함한다.Sample WMOCZ01 to WMOCZ06 is a magnetic body including Co as a base to the metal site (M B), the sample WMOCZ01 is the metal site (M B) one only contain Co, the sample WMOCZ02 to WMOCZ06 the metal site (M B) Mn, Co, Cu and Zn.
구체적으로, 표본 WMOCZ01은 BaCo2Fe16O27의 조성을 갖고, 표본 WMOCZ02는 BaMn0.25Co1.0Cu0.5Zn0.25Fe16O27의 조성을 갖으며, 표본 WMOCZ03은 BaMn0.5Co1.0Cu0.25Zn0.25Fe16O27의 조성을 갖고, 표본 WMOCZ04는 BaMn1.0Co0.5Cu0.25Zn0.25Fe16O27의 조성을 갖으며, 표본 WMOCZ06은 BaMn1.2Co0.3Cu0.25Zn0.25Fe16O27의 조성을 갖는다.Specifically, the sample WMOCZ01 has a composition of BaCo 2 Fe 16 O 27 , the sample WMOCZ02 has a composition of BaMn 0.25 Co 1.0 Cu 0.5 Zn 0.25 Fe 16 O 27 , the sample WMOCZ03 is BaMn 0.5 Co 1.0 Cu 0.25 Zn 0.25 Fe 16 O 27 , the sample WMOCZ04 has a composition of BaMn 1.0 Co 0.5 Cu 0.25 Zn 0.25 Fe 16 O 27 , and the sample WMOCZ06 has a composition of BaMn 1.2 Co 0.3 Cu 0.25 Zn 0.25 Fe 16 O 27 .
여기서, 표본 WMOCZ01은 상기 메탈 사이트(MB)에 들어가는 원소들의 조성 비율이 1.9 ≤ x+y+z+v ≤ 2.1 의 범위를 만족하며, 200 MHz, 1GHz, 2.4 GHz에서 투자율이 각각 1.6, 1.6, 1.5로, 주파수에 따라 투자율에 큰 차이가 없는 것을 볼 수 있다. Here, the sample WMOCZ01 has a composition ratio of 1.9 ≦ x + y + z + v ≦ 2.1 of elements entering the metal site (M B ), and the magnetic permeability is 1.6, 1.6 at 200 MHz, 1 GHz, and 2.4 GHz, respectively. , 1.5, shows no significant difference in permeability with frequency.
그리고, 표본 WMOCZ04 및 표본 WMOCZ06은 투자율이 200 MHz에서 각각 2.1, 2.0, 1GHz에서 1.5, 1.3, 2.4 GHz에서 1.3, 1.2임을 볼 수 있다. 즉, 주파수가 높아질수록 투자율이 저감되는 정도가 낮아진 것을 볼 수 있다.The sample WMOCZ04 and sample WMOCZ06 have permeability rates of 2.1, 2.0 and 1 GHz at 200 MHz, 1.5, 1.3 and 1.3 and 1.2 at 2.4 GHz, respectively. In other words, the higher the frequency, the lower the permeability decreases.
상기 표본 WMOCZ04 및 표본 WMOCZ06은 상기 메탈 사이트(MB)에 들어가는 원소들의 조성 비율이 1.9 ≤ x+y+z+v ≤ 2.1 의 범위를 만족하며, 또한 Co의 조성이 각각 0.5 및 0.3으로 1이하의 조성을 갖는다.The sample WMOCZ04 and the sample WMOCZ06 have a composition ratio of elements entering the metal site M B in the range of 1.9 ≦ x + y + z + v ≦ 2.1, and the composition of Co is 0.5 and 0.3, respectively, which is less than 1 Has a composition.
한편, 표본 WMOCZ02 및 WMOCZ03 200 MHz에서 투자율이 각각 6.7, 7.8 로 높은 투자율을 갖으며, 1GHz에서는 투자율이 각각 3.7, 4.2 로 투자율이 줄어들었으나 여전히 높은 투자율을 가지는 것을 볼 수 있다. 그리고, 2.4 GHz에서는 투자율이 각각 3.1, 2.8 로 투자율이 줄어들었으나 3에 근접하는 높은 투자율을 유지하는 것을 볼 수 있다. On the other hand, in the sample WMOCZ02 and WMOCZ03 200 MHz, the permeability was 6.7 and 7.8 respectively, and the permeability was reduced to 3.7 and 4.2 at 1 GHz, but the permeability was still high. At 2.4 GHz, the permeability decreased to 3.1 and 2.8, respectively, but the high permeability remained close to three.
상기 표본 WMOCZ02 및 WMOCZ03은 상기 메탈 사이트(MB)에 들어가는 원소들의 조성 비율이 1.9 ≤ x+y+z+v ≤ 2.1 의 범위를 만족하며, 또한 Co의 조성이 모두 1 이상의 조성을 갖는다. In the samples WMOCZ02 and WMOCZ03, the composition ratio of the elements entering the metal site M B satisfies the range of 1.9 ≦ x + y + z + v ≦ 2.1, and all of the compositions of Co have one or more compositions.
이에 의하면, 상기 메탈 사이트(MB)에 들어가는 원소들의 조성 비율이 1.9 ≤ x+y+z+v ≤ 2.1 및 v ≥ 1.0 의 범위를 모두 만족할 때, 200 MHz에서 높은 투자율을 가지고, 1GHz 이상의 고 주파수 대역에서도 여전히 3에 근접하는 투자율을 유지하며, 또한 주파수가 증가함에 따라 투자율의 줄어드는 저감 정도도 낮은 것을 볼 수 있다.According to this, when the composition ratio of elements entering the metal site (M B ) satisfies the range of 1.9 ≦ x + y + z + v ≦ 2.1 and v ≧ 1.0, it has a high permeability at 200 MHz, and has a high permeability of 1 GHz or more. We can see that the permeability is still close to 3 in the frequency band, and the decrease in permeability decreases with increasing frequency.
정리하면, 위에서 언급한 모든 표본들은 메탈 사이트(MB)가 MB = MnxZnyCuzCov 로 이루어지며, 이때 상기 메탈 사이트(MB)에 들어가는 원소들의 조성 비율이 1.9 ≤ x+y+z+v ≤ 2.1 의 범위를 만족한다. 이 경우, 주파수가 높아질수록 완만한 경사를 가지고 투자율이 줄어들게 된다. 특히, 상기 표본들 중 표본 WMOCZ02 및 WMOCZ03 1GHz 이상의 고 주파수 대역에서도 3에 근접하는 높은 투자율을 유지한다. In short, all the samples mentioned above are made of a metal site (M B) is M B = Mn x Zn y Cu z Co v, wherein the composition ratio of the metal sites into the (M B) element 1.9 ≤ x + It satisfies the range of y + z + v ≦ 2.1. In this case, the higher the frequency, the slower the slope and the lower the permeability. In particular, the high permeability close to 3 is maintained even in the high frequency bands of the specimens WMOCZ02 and WMOCZ03 1GHz and above.
여기서, 상기 표본 WMOCZ02 및 WMOCZ03을 살펴보면, 상기 메탈 사이트(MB)에 들어가는 원소들의 조성 비율이 1.9 ≤ x+y+z+v ≤ 2.1 의 범위를 만족하며, 특히 Co의 조성인 v가 v ≥ 1.0 을 만족한다.Here, looking at the samples WMOCZ02 and WMOCZ03, the composition ratio of elements entering the metal site (M B ) satisfies the range of 1.9 ≦ x + y + z + v ≦ 2.1, in particular, the composition of Co is v ≥ Satisfies 1.0
한편, 도 2에 도시된 표본들은 상기 메탈 사이트(MB)에 들어가는 원소들의 조성 비율을 일정한 값으로 특정한 하나의 실시예일 뿐이며, 상기 메탈 사이트(MB)에 들어가는 원소들의 조성 비율이 1.9 ≤ x+y+z+v ≤ 2.1 의 범위를 만족하는 한도에서, x, y, z, v 값을 각각 적절히 조절하여 스넉스 한계(Snoek's Limit)를 극복하는 자성체를 구현할 수 있다.On the other hand, also the samples are the mole fraction of the metal sites into the (M B) only carried one particular constant value for the mole fraction of the elements to enter the example, and the metal site (M B) element as shown in 2 1.9 ≤ x As long as it satisfies the range of + y + z + v ≦ 2.1, a magnetic material that overcomes the Snoek's Limit may be implemented by appropriately adjusting the x, y, z, and v values, respectively.
도 3은 본 발명의 일 실시예에 의한 자성체의 주파수에 따른 투자율 변화를 나타낸 그래프이다. 여기서, 자성체의 투자율 중 실수부(μ')는 실선으로 표시하였고, 자성체의 투자율 중 허수부(μ'')는 점선으로 표시하였으며, 표본 WMOCZ01 내 지 WMOCZ06의 주파수에 따른 투자율 변화를 나타내었다.3 is a graph showing a change in permeability according to the frequency of the magnetic material according to an embodiment of the present invention. Here, the real part (μ ') of magnetic permeability is represented by a solid line, the imaginary part (μ' ') of magnetic permeability is shown by a dotted line, and the permeability change according to the frequency of samples WMOCZ01 to WMOCZ06 is shown.
도 3을 참조하면, 표본 WMOCZ01은 주파수가 증가하여도 투자율이 거의 일정한 값을 유지하는 것을 볼 수 있고, 표본 WMOCZ04 및 표본 WMOCZ06은 주파수가 증가할수록 투자율이 서서히 낮아지다가 일정한 값을 유지하는 것을 볼 수 있다. 즉, 상기 표본 WMOCZ04 및 표본 WMOCZ06은 주파수가 높아질수록 투자율이 급속하게 감소하지 않고 완만한 경사를 가지고 감소하는 것을 볼 수 있다.Referring to FIG. 3, the sample WMOCZ01 shows that the permeability is maintained at a constant value even when the frequency is increased, and the sample WMOCZ04 and the sample WMOCZ06 are gradually decreased and the constant value is maintained as the frequency is increased. have. That is, it can be seen that the sample WMOCZ04 and the sample WMOCZ06 decrease with a gentle slope rather than rapidly decreasing as the frequency increases.
한편, 표본 WMOCZ02 및 표본 WMOCZ03은 주파수가 증가할수록 투자율이 낮아지나, 1GHz 이상의 고 주파수 대역에서도 투자율이 3에 근접하는 높은 투자율을 유지하는 것을 볼 수 있다. 특히, 표본 WMOCZ02는 2.8GHz 까지 투자율이 3 이상의 값을 유지하면서도 낮은 투자 손실을 갖는 것을 볼 수 있다.On the other hand, sample WMOCZ02 and sample WMOCZ03 have lower permeability as frequency increases, but the high permeability close to 3 can be seen even in high frequency band above 1GHz. In particular, the sample WMOCZ02 can be seen to have a low investment loss while maintaining a permeability of up to 2.8 GHz or more.
도 4는 본 발명의 일 실시예에 따른 자성체 제조방법을 나타낸 순서도이다.4 is a flowchart illustrating a method of manufacturing a magnetic material according to an embodiment of the present invention.
도 4를 참조하면, Ba 산화물, Fe 산화물, 및 메탈 산화물(예를 들어, Mn, Zn, Cu, Co의 산화물)을 소정의 조성이 되도록 칭량한 후 혼합한다(S 100).Referring to FIG. 4, Ba oxide, Fe oxide, and metal oxide (for example, oxides of Mn, Zn, Cu, Co) are weighed to a predetermined composition and mixed (S 100).
여기서, 상기 산화물들을 통해 조성이 BaAMBFeCOD 인 자성체를 제조하게 되는데, 이때 A, C, D는 0.5 ≤ A ≤ 1.5, 14 ≤ C ≤ 18, 24 ≤ D ≤ 30 의 범위가 되도록 상기 Ba 산화물, Fe 산화물, 및 메탈 산화물을 칭량한다.In this case, a magnetic substance having a composition of Ba A M B Fe C O D is prepared through the oxides, wherein A, C, and D are 0.5 ≦ A ≦ 1.5, 14 ≦ C ≦ 18, and 24 ≦ D ≦ 30. The Ba oxide, Fe oxide, and metal oxide are weighed as much as possible.
그리고, MB = MnxZnyCuzCov 으로 이루어질때, 상기 메탈 산화물들을 1.9 ≤ x+y+z+v ≤ 2.1 이 되도록 칭량하며, 또한 v ≥ 1.0 이 되도록 칭량한다. 그 후, 상기 산화물들을 볼 밀(Ball Mill) 등과 같은 장비를 이용하여 혼합한다.And, when M B = Mn x Zn y Cu z Co v , the metal oxides are weighed to be 1.9 ≦ x + y + z + v ≦ 2.1 and also weighed to be ≧ 1.0. Thereafter, the oxides are mixed using equipment such as a ball mill.
상기 혼합한 산화물들을 건조시킨 후(S 110), 상기 소정의 온도에서 일정 시간 하소(Calcination)하여 하소체를 얻는다(S 120).After drying the mixed oxides (S 110), calcining (calcination) for a predetermined time at the predetermined temperature to obtain a calcined body (S 120).
상기 하소체를 일정 직경(예를 들어, 0.5 ~ 10 ㎛)이 될 때까지 분쇄하여 분체를 얻는다(S 130). 상기 하소체는 일반적으로 과립상이기 때문에 진동 밀, 제트 밀, 볼 밀 등의 장치를 이용하여 일정 직경이 될 때까지 분쇄한다.The calcined powder is pulverized until it has a predetermined diameter (for example, 0.5 to 10 µm) to obtain powder (S 130). Since the calcined body is generally granular, it is pulverized until it reaches a certain diameter using a device such as a vibration mill, a jet mill, a ball mill, or the like.
상기 분체에 일정한 성형 압력(예를 들어, 100 ~ 2000kg/cm2)을 가하여 일정한 형상의 성형체를 얻은 후(S 140), 소정의 온도에서 일정 시간 소결(Sintering)하여 자성체를 얻는다(S 150).After applying a constant molding pressure (for example, 100 ~ 2000kg / cm 2 ) to the powder to obtain a molded body of a predetermined shape (S 140), by sintering at a predetermined temperature for a predetermined time to obtain a magnetic body (S 150) .
이상에서 대표적인 실시예를 통하여 본 발명에 대하여 상세하게 설명하였으나, 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자는 상술한 실시예에 대하여 본 발명의 범주에서 벗어나지 않는 한도 내에서 다양한 변형이 가능함을 이해할 것이다. Although the present invention has been described in detail with reference to exemplary embodiments above, those skilled in the art to which the present invention pertains can make various modifications to the above-described embodiments without departing from the scope of the present invention. Will understand.
그러므로 본 발명의 권리범위는 설명된 실시예에 국한되어 정해져서는 안 되며, 후술하는 특허청구범위뿐만 아니라 이 특허청구범위와 균등한 것들에 의해 정해져야 한다. Therefore, the scope of the present invention should not be limited to the described embodiments, but should be defined by the claims below and equivalents thereof.
도 1은 W형 자성체(BaMxFe16O27)에서 x 값의 변화에 따른 각 자성체의 스넉스 한계(Snoek's Limit)를 나타낸 그래프.1 is a graph showing the Snoek's Limit of each magnetic material according to the change of x value in the W-type magnetic material (BaM x Fe 16 O 27 ).
도 2는 W형 자성체 물질에서 메탈 사이트(MB)에 들어갈 원소들의 조성 비율에 따른 자성체의 투자율 및 유전율을 나타낸 도면.FIG. 2 is a diagram illustrating magnetic permeability and permittivity of magnetic material according to the composition ratio of elements to enter the metal site (M B ) in the W-type magnetic material.
도 3은 본 발명의 일 실시예에 의한 자성체의 주파수에 따른 투자율 변화를 나타낸 그래프.Figure 3 is a graph showing the permeability change according to the frequency of the magnetic material according to an embodiment of the present invention.
도 4는 본 발명의 일 실시예에 따른 자성체 제조방법을 나타낸 순서도.Figure 4 is a flow chart showing a method of manufacturing a magnetic material according to an embodiment of the present invention.
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| WO2014209067A1 (en) * | 2013-06-27 | 2014-12-31 | 주식회사 제이엠씨 | Composition of soft-magnetic nano-amorphous composite material and method for preparing same |
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| JP4158081B2 (en) * | 2001-04-09 | 2008-10-01 | 戸田工業株式会社 | Soft magnetic hexagonal ferrite composite particle powder, green sheet using the soft magnetic hexagonal ferrite composite particle powder, and soft magnetic hexagonal ferrite sintered body |
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| WO2014209067A1 (en) * | 2013-06-27 | 2014-12-31 | 주식회사 제이엠씨 | Composition of soft-magnetic nano-amorphous composite material and method for preparing same |
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