KR20100101232A - The plastic form - Google Patents

The plastic form Download PDF

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Publication number
KR20100101232A
KR20100101232A KR1020090019610A KR20090019610A KR20100101232A KR 20100101232 A KR20100101232 A KR 20100101232A KR 1020090019610 A KR1020090019610 A KR 1020090019610A KR 20090019610 A KR20090019610 A KR 20090019610A KR 20100101232 A KR20100101232 A KR 20100101232A
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KR
South Korea
Prior art keywords
synthetic resin
foam beads
resin foam
binder
resistance
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KR1020090019610A
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Korean (ko)
Inventor
오은영
오정훈
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오은영
오정훈
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Priority to KR1020090019610A priority Critical patent/KR20100101232A/en
Publication of KR20100101232A publication Critical patent/KR20100101232A/en

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/16Making expandable particles
    • C08J9/18Making expandable particles by impregnating polymer particles with the blowing agent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C67/00Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
    • B29C67/20Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00 for porous or cellular articles, e.g. of foam plastics, coarse-pored
    • B29C67/205Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00 for porous or cellular articles, e.g. of foam plastics, coarse-pored comprising surface fusion, and bonding of particles to form voids, e.g. sintering
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02Homopolymers or copolymers of hydrocarbons
    • C08L25/04Homopolymers or copolymers of styrene
    • C08L25/06Polystyrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02Homopolymers or copolymers of hydrocarbons
    • C08J2325/04Homopolymers or copolymers of styrene
    • C08J2325/06Polystyrene

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

PURPOSE: A molded product of a synthetic resin foam bead, and a manufacturing method thereof are provided to protect the surface of a bead particle by coating the surface with a binder, and to improve the coherence force between bead particles. CONSTITUTION: A manufacturing method of a molded product of a synthetic resin foam bead comprises the following steps; forming a mixed material by mixing a synthetic resin foamed bead and more than one binder selected form the group of organic binders; filling the mixed material to a mold, and sealing; and heat-molding the material.

Description

고강도 합성수지발포비즈 성형물{THE PLASTIC FORM }High strength synthetic resin foam beads moldings {TH PLASTIC FORM}

본 발명은 합성수지발포비즈성형물에 관한 것으로서, 보다 상세하게는 입자형(BEAD STYLE)의 합성수지발포체인 합성수지발포비즈를 몰드에 투입 및 가열하여 입자를 팽창 및 융착시켜 일체화시키므로써 제조된 합성수지발포비즈 성형물에 관한 것이다.The present invention relates to a synthetic resin foam beads molded article, more specifically, a synthetic resin foam beads molded article prepared by injecting and heating the synthetic resin foam beads, which is a synthetic resin foam body of a particle shape (BEAD STYLE) into a mold to expand and fuse the particles to integrate. It is about.

종래의 합성수지발포비즈를 이용한 성형물의 제조방법으로는As a manufacturing method of a molded article using a conventional synthetic resin foam beads

제조된 합성수지발포비즈를 단독원료로 하고 상기를 제조하고자 하는 형상의 성형물에 충진 및 가열하므로써 상기 몰드에 충진된 합성수지발포비즈를 팽창 및 표면을 융해시키므로써 팽창된 합성수지발포비즈들 간에 융착을 일으켜 일체화시키므로써 원하는 형상의 성형물로 제조하는 방법이 사용되어 왔다. By using the prepared synthetic resin foam beads as a sole raw material and filling and heating the molded article of the shape to be prepared, the synthetic resin foam beads filled in the mold are expanded and the surface is melted to cause fusion between the expanded synthetic resin foam beads. Thus, a method for producing a molded article of a desired shape has been used.

그러나 통상의 합성수지발포비즈는 10~60배 내외의 고발포형 발포체로서 고발포로 인한 원가절감, 초경량성, 내충격성, 방음성, 단열성 등은 우수하나 입자의 강도가 매우 취약하여 종래의 제조방법을 통해 제조된 성형물의 경우 성형 후 입자간의 결합력이 떨어지고 표면이 마찰에 의해 쉽게 부서지는 등 물성이 매우 취약한 단점을 나타내고 있다.However, ordinary synthetic resin foam beads are 10 to 60 times higher foaming foams, which are excellent in cost reduction, ultra-light weight, impact resistance, soundproofing, and thermal insulation due to high foaming, but are manufactured through the conventional manufacturing method because the strength of the particles is very weak. In the case of the molded article, the bonding strength between the particles is reduced after molding and the surface is easily broken by friction.

이에 본 발명은 상기의 단점이 해소하고자 종래 합성수지발포비즈 단독원료에 물성강화를 위한 유기 또는 무기의 원료를 추가의 원료로 투입하고 이를 통해 제조된 혼합원료를 사용하여 합성수지발포비즈성형물을 제조하므로써 성형물의 내구성을 향상시키고자 한다.In order to solve the above disadvantages, the present invention is made by adding a synthetic resin foam beads beads to the raw material of the conventional synthetic resin foam beads alone as an additional raw material and by using the mixed raw materials prepared through the molding material To improve the durability of the.

이에, 상기 과제의 달성을 위한 본 발명은Accordingly, the present invention for achieving the above object

합성수지발포비즈에 유기 바인더의 군으로부터 선택된 일 종 이상의 바인더를 투입하므로써 합성수지발포비즈와 바인더의 혼합원료를 제조하고 상기 제조된 혼합원료를 제조하고자 하는 형상의 몰드에 충진 및 이를 가열성형하므로써 제조된 고강도합성수지발포비즈성형물을 제공한다.A high strength produced by preparing a mixed raw material of the synthetic resin foam beads and a binder by filling the mold of the shape to be prepared by mixing the resin and foamed by heating it by putting at least one binder selected from the group of the organic binder into the synthetic resin foam beads It provides a synthetic resin foam beads moldings.

본 발명에 따라 제조된 고강도합성수지발포비즈성형물은 혼합원료인 바인더가 비즈 입자의 표면에 코팅되어 입자의 표면을 보호하고 입자간 융착시 입자간의 결합력을 높이므로써 향상된 내구성을 갖는 고강도 합성수지발포비즈 성형물을 제공하는 효 과가 있다.The high-strength synthetic resin foam beads molded article prepared according to the present invention is a high-strength synthetic resin foam beads molded article having improved durability by coating the binder as a mixed raw material on the surface of the beads particles to protect the surface of the particles and increase the bonding strength between the particles when fusion between the particles There is an effect to provide.

본 발명은 합성수지발포비즈와 유기 바인더의 군으로부터 선택된 일 종 이상의 바인더를 혼합한 합성수지발포비즈와 바인더의 혼합원료를 제조하고 상기 제조된 혼합원료를 제조하고자 하는 형상의 몰드에 충진 및 이를 가열 성형하므로써 제조된 고강도 합성수지발포비즈성형물을 제공한다.The present invention is prepared by preparing a mixed raw material of the synthetic resin foam beads and the binder mixed with at least one binder selected from the group of synthetic resin foam beads and organic binder and filling the mold of the shape to prepare the mixed raw material and heat-molding it It provides a high-strength synthetic resin foam beads molding prepared.

본 발명에 따라 제조된 고강도합성수지발포비즈성형물은 본 발명을 통한 추가의 혼합원료인 바인더가 비즈 입자의 표면에 코팅되어 입자의 표면을 보호하고 입자간 융착시 입자간의 결합력을 높이므로써 향상된 내구성을 갖는 고강도 합성수지발포비즈 성형물을 제공할 수 있게 된다.The high strength synthetic resin foam beads molded according to the present invention has an improved durability by coating a binder, which is an additional raw material of the present invention, on the surface of the bead particles to protect the surface of the particles and to increase the bonding strength between the particles when the particles are fused. It is possible to provide a high strength synthetic resin foam beads moldings.

이하, Below,

본 발명의 구성의 이해를 돕기 위하여 통상의 합성수지발포비즈의 제조방법 중 범용의 제조방법인 중합식과 뺏지식의 제조방법에 대해 간단히 설명하고 이를 본 발명과 연관하여 간단히 설명하고자 한다.In order to help the understanding of the configuration of the present invention will be described briefly in connection with the present invention will be briefly described in the general method of manufacturing the general formula of the synthetic resin foam beads and the polymerization method.

그러나 이하 기술될 합성수지발포비즈의 제조방법과 구성은 본 발명의 구성을 보다 이해하기 쉽도록 설명하기 위해 게시되는 것으로서 본 발명이 합성수지발포비즈를 제조하는 방법에 관련한 기술의 개시를 목적으로 하지 않는다는 것은 주지의 사실임과 아울러, 본 발명의 원료로 사용되는 합성수지발포비즈는 이하 게시되지 않은 다양한 제조방법을 통해서도 제조될 수 있으며, 그러한 미게시의 다양한 제조방법을 통해 제조된 합성수지발포비즈 역시도 본 발명의 고강도 합성수지발포비즈성형물의 제조원료가 될 수 있음을 미리 밝혀두고자 한다.However, the method and configuration of the synthetic resin foam beads to be described below are posted to explain the configuration of the present invention more easily understood that the present invention is not intended to disclose the technology related to the method for producing the synthetic resin foam beads. In addition to the well-known facts, synthetic resin foam beads used as a raw material of the present invention can be prepared through a variety of manufacturing methods that are not published below, synthetic resin foam beads prepared through a variety of such unpublished manufacturing method is also high strength of the present invention It will be appreciated that it can be a raw material for the production of synthetic resin foam beads moldings.

중합식 제조방법에 의한 합성수지발포비즈에는 대표적으로 eps비즈가 포함되며,Synthetic resin foam beads by the polymerized production method typically includes eps beads,

이는 단위체인 스티렌(styrene)을 폴리스티렌(PS:polystyrene)로 중합 제조하는 과정에 PS에 발포용개스를 주입 및 수중 중합한 뒤 이를 회수 건조하여 발포 반응기(Autoclave)에 투입 및 발포하는 방법을 통해 제조된 것이다.This is produced by injecting foaming gas into PS and polymerizing it in water in the process of polymerizing styrene as polystyrene (PS), and then collecting and drying it in a foaming reactor (Autoclave). It is.

이러한 eps비즈는 체적의 98%가 공기이고, 나머지 2%가 수지인 자원 절약형 소재이나 부스러지는 단점과 비내용제성(톨루엔, MEK등) 등의 취약한 물성을 나타내므로 그 자체로서 본 발명의 합성수지발포비즈성형물의 원료로 사용하기에는 무리가 있으며 그러한 취약한 물성의 개선을 통하여 사용됨이 보다 바람직하다 할 것이다.These eps beads are synthetic resin foams of the present invention as they exhibit poor physical properties such as resource-saving materials, which have 98% of the volume, and the remaining 2% of the resin, and the disadvantages of brittleness and non-solvent resistance (toluene, MEK, etc.). It is unreasonable to use as a raw material for bead molding, and it is more preferable to be used through improvement of such weak physical properties.

뱃지식의 제조방법에 의한 합성수지발포비즈에는 대표적으로 epp비즈가 포함되며, Synthetic resin foam beads by a badge manufacturing method typically includes epp beads,

이는 우선 최종 발포체의 크기를 고려하여 PP(polypropylene)수지를 압출기에 투입 및 선상압출시켜 이를 미니 입자로 절단하고, 상기 절단된 입자를 발포반응기First of all, in consideration of the size of the final foam, PP (polypropylene) resin is introduced into the extruder and linearly extruded to cut it into mini particles, and the cut particles are blown into a foaming reactor.

(Autoclave)에 투입 및 발포제(부탄, CO2 개스 등)를 주입하여 발포시키는 방법을 통해 제조된 것이다.(Autoclave) was prepared by the method of foaming by injection and blowing agent (butane, CO2 gas, etc.).

이 때, 발포 온도, 개스, 압력을 조절하여 목적하는 발포 배율을 얻을 수 있으며At this time, the desired foaming ratio can be obtained by adjusting the foaming temperature, gas, and pressure.

이러한 발포배율을 조정으로 사용환경과 용도에 적합하도록 탄성을 증감시켜 제조될 수 있다.By adjusting the foaming ratio can be prepared by increasing the elasticity to suit the environment and use.

상기 제조된 EPP비즈는 EPS, EPE에 비해 내열성 및 내한성이 우수하고, 온도에 따른 변형이 적으며, 강한 융착성, 우수한 강성, 뛰어난 (반복)충격 흡수 및 우수한 복원력을 가지며, 내유, 내약품성이 우수하고, UL 난연규격 수준 난연처리 가능하며, The produced EPP beads have better heat resistance and cold resistance than EPS and EPE, less deformation due to temperature, strong adhesion, excellent rigidity, excellent (repeated) impact absorption and excellent restoring force, oil resistance and chemical resistance. Excellent flame retardant level of UL flame retardant standard,

특히, 소각시 유독가스(다이옥신 등) 발생이 없으며, 화학적으로 안정되어 있어 식품의 포장용기로 사용할 수 있으며, EPS와 같은 부스러짐이 없으므로 청결을 유지 할 수 있는 등 인체와 환경에 대한 안정성이 확보되므로 본 발명이 제공하고자 하는 충격흡수재 및 인테리어재의 사용에 매우 바람직한 소재가 될 수 있다.In particular, it does not generate toxic gas (dioxin, etc.) when incinerated, and it is chemically stable, so it can be used as a packaging container for food, and since there is no crumb like EPS, it can maintain cleanliness. Therefore, it can be a very desirable material for use of the shock absorbing material and interior material to be provided by the present invention.

이상, 본 발명의 이해를 돕기 위하여 범용의 합성수지발포비즈의 제조방법과 물성에 관해 설명하였다.In the above, the manufacturing method and the physical properties of the general purpose synthetic resin foam beads in order to help the understanding of the present invention has been described.

이하, 본 발명의 상세한 구성을 프로어챠트로 나타내면 다음과 같다.Hereinafter, the detailed structure of this invention is shown as a pro chart.

<고강도 합성수지발포비즈성형물 제조공정><Manufacturing process of high strength synthetic resin foam beads>


가) 혼합원료 제조(합성수지발포비즈와 바인더 혼합)

A) Preparation of mixed raw materials (mixing synthetic resin foam beads and binder)

                           ↓


나) 혼합원료를 몰드에 충진

B) Filling the mixed raw material into the mold

                           ↓


다) 가열성형

C) heating molding

                           ↓


라) 탈형

D) demolding

                           ↓

마)

고강도 합성수지발포비즈성형물 제조완료

hemp)

Completed manufacturing high strength synthetic resin foam beads

상기 공정을 단계별로 상세히 설명한다.The process will be described in detail step by step.

가) 혼합원료 제조(합성수지발포비즈와 바인더 혼합)A) Preparation of mixed raw materials (mixing synthetic resin foam beads and binder)

제조된 합성수지발포비즈와 바인더를 혼합하는 공정으로서 As a process of mixing the prepared synthetic resin foam beads and a binder

합성수지발포비즈와 유기 바인더의 군으로부터 선택된 일 종 이상의 바인더를 혼합 하므로써 합성수지발포비즈의 표면에 바인더 코팅층이 형성된 혼합물을 제조하는 단계이다.It is a step of preparing a mixture in which the binder coating layer is formed on the surface of the synthetic resin foam beads by mixing at least one binder selected from the group of synthetic resin foam beads and organic binder.

이 때, 사용되는 바인더는 상기한 바대로 유기 또는 무기의 바인더의 군으로부터 선택된 단일 원료의 바인더이거나 또는 둘 이상의 원료를 혼합하므로써 제조된 혼합형의 바인더 중 선택 사용될 수 있으며, 보다 바람직하게는 성형물을 신속한 건조를 위하여서는 용제나 물의 건조 없이도 스스로 건조되는 특성을 갖는 자경성 속경성의 바인더 중 선택 및 이를 혼합원료로 사용하여 제조될 수 있으며 그 예로는 우레탄바인더, 에폭시바인더 및 기타 속경성의 바인더를 포함하는 스팀, 수분, 열에 신속히 경화되는 속경성바인더를 포함한다. At this time, the binder to be used may be a binder of a single raw material selected from the group of organic or inorganic binders as described above, or may be selected from a binder of a mixed type prepared by mixing two or more raw materials, and more preferably For drying, it can be manufactured by using a self-hardening fast binder having the property of drying itself without solvent or water and using it as a mixed raw material. Examples include urethane binder, epoxy binder and other fast hard binder. It includes a fast-hard binder that is quickly cured by steam, moisture, heat.

특히, 최종 결과물인 고강도 합성수지발포비즈성형물의 탄성을 증대시키기 위한 제조방법으로서 선택된 단일 또는 혼합원료의 바인더에 추가의 혼합원료로서 고무를 포함하는 탄성원료인 엘라스토머형 수지 바인더를 추가의 원료로 혼합하므로써 제조된 혼합바인더를 사용하여 제조될 수도 있다.In particular, by mixing an elastomeric resin binder, an elastic raw material containing rubber as an additional raw material, as an additional raw material to a single or mixed raw material binder selected as a manufacturing method for increasing the elasticity of the high-strength synthetic resin foam beads molding as a final result. It may also be prepared using the prepared mixing binder.

나)혼합원료를 몰드에 충진B) Filling the mixture with mold

상기 단계를 통해 제조된 혼합원료를 제조하고자 하는 형상의 몰드에 충진 및 밀폐한다.Filling and sealing in the mold of the shape to be prepared to prepare the mixed raw material prepared through the above steps.

다)가열성형C) Heating Molding

상기 충진된 몰드에 140~150도씨 내외의 스팀을 가하므로써 합성수지발포비즈가 몰드 내에서 추가로 팽창되고 혼합된 바인더에 의해 입자들 간이 결합을 이루므로써 일체형의 성형체를 형성시킨다.By applying steam of about 140 to 150 degrees Celsius to the filled mold, the synthetic resin foam beads are further expanded in the mold to form a unitary molded body by bonding between the particles by the mixed binder.

라)탈형D) demolding

상기 일체화 성형된 고강도합성수지발포비즈성형물을 성형몰드로 부터 탈형한다.The integrally molded high strength synthetic resin foam beads molded product is demolded from the molding mold.

이상 본 발명의 공정을 설명하였다.The process of the present invention has been described above.

한편,Meanwhile,

본 발명의 고강도 합성수지발포비즈성형물의 물리적 또는 화학적인 물성과 다양한 기능성의 향상을 위하여,In order to improve the physical or chemical properties and various functionalities of the high-strength synthetic resin foam beads molding of the present invention,

제조공정 상에 일 종 이상의 화학적 첨가제를 첨가 제조하므로써 탄성, 복원력,내후성, 내마모성, 인장강도, 내열강도, 내한성, 내유성, 내약품성, 항산화성, 난연성, 대전방지 등을 포함하는 기타의 화학적 물성이 강화된 고강도합성수지발포비즈성형물로 제조되거나By adding one or more chemical additives to the manufacturing process, other chemical properties including elasticity, restoring force, weather resistance, abrasion resistance, tensile strength, heat resistance, cold resistance, oil resistance, chemical resistance, antioxidant resistance, flame resistance, antistatic, etc. Made of reinforced high strength synthetic resin foam beads

또, 합성수지발포비즈에 일 종 이상의 물리적 혼화재인 고무칩, 우레탄칩, EPDM칩, 합성수지칩, 스폰지칩, 폐타이어분쇄칩, 각종 기능성 필라 및 기타의 유, 무기의 원료를 1종 이상 추가 혼합 제조하므로써 물리적인 물성과 기능성이 향상된 고강도합성수지발포비즈성형물로 제조할 수 있다. In addition, at least one additional raw material of rubber chips, urethane chips, EPDM chips, synthetic resin chips, sponge chips, waste tire grinding chips, various functional pillars, and other oil and inorganic materials may be mixed with synthetic resin foam beads. As a result, it is possible to produce a high-strength synthetic resin foam beads molded with improved physical properties and functionality.

또, 제조하고자 하는 색상의 안료를 추가 투입 제조하므로써 보다 향상된 심미감을 갖는 고강도 합성수지발포비즈성형물이 제조될 수 있다.In addition, a high-strength synthetic resin foam beads molded article having improved aesthetics can be prepared by additionally preparing a pigment of a color to be prepared.

실시예1)Example 1

EPP발포비즈(20배 발포) 1KGEPP Foamed Beads (20x Foam) 1KG

스팀경화형 우레탄바인더 2KG 을 혼합하므로써 제조된 혼합물을 가로 1M 세로 1M 두께 3CM의 판상의 성형몰드에 투입하고 약140도씨의 스팀을 주입 및 2~3분 가열하므로써 발포비즈를 팽창과 동시에 우레탄바인더를 경화시키므로써 판상의 고강도 합성수지발포비즈성형물을 제조하였다.The mixture prepared by mixing 2kg of steam-curable urethane binder is poured into a plate-shaped mold having a width of 1M length and 1M thickness 3CM, and the urethane binder is expanded at the same time as the foam beads are expanded by injecting steam of about 140 ° C and heating for 2-3 minutes. By hardening, a plate-like high strength synthetic resin foam beads molded product was prepared.

실시예2)Example 2

EPP발포비즈(20배 발포) 1KGEPP Foamed Beads (20x Foam) 1KG

스팀경화형 우레탄바인더 2KGSteam Curing Type Urethane Binder 2KG

삼산안티몬(난연제) 600G 을 혼합하므로써 제조된 혼합물을 가로 1M 세로 1M 두께 3CM의 판상의 성형몰드에 투입하고 약140도씨의 스팀을 주입 및 2~3분 가열하므로써 발포비즈를 팽창과 동시에 우레탄바인더를 경화시키므로써 난연성을 갖는 판상의 고강도합성수지발포비즈성형물을 제조하였다.The mixture prepared by mixing 600G Samsan antimony (flame retardant) is poured into a plate-shaped mold having a width of 1M length and 1M thickness 3CM, injecting about 140 ° C steam and heating for 2-3 minutes to expand the foam beads and urethane binder By hardening, a plate-shaped high strength synthetic resin foam beads molded product having flame retardancy was prepared.

실시예3)Example 3

EPP, EPS 발포비즈 (20~30배 발포) 1KGEPP, EPS Foam Beads (20 ~ 30x Foam) 1KG

스팀경화형 우레탄바인더 또는 수분경화형 우레탄바인더 2KGSteam Curing Urethane Binder or Water Curing Urethane Binder 2KG

을 원료로 하고, 상기 발포비즈에 수분을 흡착시킨 직 후 바인더와 믹싱하여 혼합물을 제조하고, 상기 제조된 혼합물을 25~30도씨 내외의 상온 상압의 성형몰드에 충진 및 이를 30분~1시간 내외의 시간을 두어 경화시키므로써 합성수지발포비즈성형물을 제조하였다. It was prepared as a raw material, admixed with a binder immediately after adsorbing moisture to the foam beads, to prepare a mixture, and filled the prepared mixture in a molding mold at room temperature and atmospheric pressure of about 25 ~ 30 ° C and 30 minutes to 1 hour Synthetic resin foamed beads molded product was prepared by curing the mixture with time.

이상, 본 발명의 구성을 상세히 설명하였다.In the above, the structure of this invention was demonstrated in detail.

Claims (4)

합성수지발포비즈와 유기 바인더의 군으로부터 선택된 일 종 이상의 바인더를 혼합하므로써 혼합원료를 제조하고 상기 제조된 혼합원료를 제조하고자 하는 형상의 몰드에 충진 밀폐 및 이를 가열성형하므로써 제조된 고강도합성수지발포비즈성형물.A high-strength synthetic resin foam beads molded by manufacturing a mixed raw material by mixing at least one binder selected from the group of synthetic resin foam beads and an organic binder and filling and sealing the mold of the shape to prepare the mixed raw material prepared by heating and molding them. EPP발포비즈와 스팀경화형 우레탄바인더를 혼합하므로써 제조된 혼합원료를 성형몰드에 충진 밀폐하고 상기 몰드 내에 약140도씨 내외의 스팀을 주입 및 가열하므로써 성형제조된 것을 특징으로 하는 고강도합성수지발포비즈성형물.A high-strength synthetic resin foam beads molding, characterized in that the mixed material produced by mixing the EPP foam beads and steam-curable urethane binder is filled and sealed in a molding mold and molded by injecting and heating steam of about 140 degrees Celsius into the mold. 상기 1항 또는 2항의 고강도합성수지발포비즈성형물의 물성 개선을 위하여 비즈발포용칩 제조공정 상에 일 종 이상의 물리적 혼화재 또는 화학적 첨가제가 추가로 더 투입 제조되어진 발포비즈를 성형하므로써 제조된 것을 특징으로 하는 고강도합성수지발포비즈성형물.In order to improve the physical properties of the high-strength synthetic resin foam beads molded article of claim 1 or 2 characterized in that the high-strength, characterized in that by manufacturing the foam beads in which at least one physical admixture or chemical additive is further added to the beads manufacturing chip manufacturing process Synthetic resin foam beads moldings. 상기 3항에 있어서The method of claim 3 물리적 혼화재 또는 화학적 첨가제는 고무칩, 우레탄칩, EPDM칩, 합성수지칩, 스폰 지칩, 폐타이어칩, 각종 기능성필라 및 기타 혼화재 및 탄성, 복원력, 내후성, 내마모성, 인장강도, 내열강도, 내한성, 내유성, 내약품성, 항산화성, 난연성, 대전방지 및 기타 화학적인 물성의 개선을 위한 증강제 및 안료를 포함하는 것으로 상기 중 선택된 하나 이상의 원료를 추가의 원료로 투입 및 성형 제조된 것을 특징으로 하는 고강도합성수지발포비즈성형물. Physical admixtures or chemical additives include rubber chips, urethane chips, EPDM chips, synthetic resin chips, sponge chips, waste tire chips, various functional fillers and other admixtures and elasticity, restoring force, weather resistance, wear resistance, tensile strength, heat resistance, cold resistance, oil resistance, High strength synthetic resin foam beads, characterized in that the addition and molding of one or more of the raw materials selected from the above as an additional raw material including pigments and enhancers for improving chemical resistance, antioxidant resistance, flame retardancy, antistatic and other chemical properties Moldings.
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