KR20100068580A - Composite for electrode of polymer battery, composite for separator of polymer battery, polymer batter and manufacturing method of polymer battery using the same - Google Patents

Abstract

PURPOSE: A polymer battery is provided to prevent electrical loss and explosiveness due to heat generation, to obtain excellent stability of the battery, and to enable a user to use the polymer battery for a long term without generating electron noise. CONSTITUTION: An electrode composition for a polymer battery; a polymer for offering a basic framework of a chain structure; a soft polymer for offering flexibility to the polymer by being combined with the polymer; a polymer inflating agent; carbon nanotube powder acting as an electrode activator offering conductivity; and an activated charcoal powder which acts the electrode activator offering conductivity while inducing covalent bonds of materials within the electrode.

Description

Composite for electrode of polymer battery, composite for separator of polymer battery, polymer batter and manufacturing method of polymer battery using the same }

The present invention relates to a composition for an electrode of a polymer battery, a composition for a separator of a polymer battery, a polymer battery and a method for producing a polymer battery using the same, and more particularly, a polymer battery having excellent stability without electrical loss and explosion due to heat generation The composition for electrodes, the composition for separators of a polymer battery, the polymer battery using this, and the manufacturing method of a polymer battery.

As a secondary battery for audio / video (A / V) such as a personal computer (PC), a video tape recorder (VTR), a memory backup of an information apparatus, or a driving power supply thereof, a nickel-cadmium battery Has become mainstream. In recent years, non-aqueous electrolyte secondary batteries that can replace nickel-cadmium batteries have been attracting considerable attention because they have the advantages of high voltage and high energy density and exhibit excellent self-discharge characteristics. It is.

For example, more than half of notebook PCs, cellular phones, and the like are driven by nonaqueous electrolyte secondary batteries. In these nonaqueous electrolyte secondary batteries, carbon is frequently used as a material for forming a negative electrode. Various organic solvents have been used as electrolytes for the purpose of reducing the risk of lithium formation, high driving, and voltage reduction. In addition, as a nonaqueous electrolyte secondary battery for cameras, since alkali metal (especially lithium metal or lithium alloy) etc. are used as a negative electrode material, the aprotic organic solvent, such as ester type organic solvent, is used normally as the electrolyte solution.

However, these nonaqueous electrolyte secondary batteries have high performance, but have the following problems in terms of safety.

First, when alkali metals (particularly lithium metals or lithium alloys, etc.) are used as the negative electrode material of the nonaqueous electrolyte secondary battery, since the alkali metals are very highly active against moisture, for example, the battery is incompletely sealed and moisture When this invasion occurs, there is a problem that there is a high risk of hydrogen generation or ignition due to reaction between the negative electrode material and water.

In addition, since lithium metal has a low melting point (about 170 ° C.), when a large amount of current flows rapidly during a short circuit or the like, there is a problem that the battery generates abnormally heat and causes a very dangerous situation such as melting of the battery. In addition, due to the heat generation of the battery, the above-mentioned organic solvent-based electrolyte is vaporized and decomposed to generate gas, or the battery is ruptured or ignited by the generated gas.

On the other hand, the interest in energy harvesting (Energy Harvesting) that can obtain energy from the scattered environment around the sun, vibration, temperature change, noise, etc. in recent years. For example, solar cells using the sun, piezoelectrics using vibration or pressure, thermoelectrics due to temperature differences, acoustic noises due to noise, and the like.

In particular, piezoelectric devices (piezoelectric device) is a device using the phenomenon that the electrical polarization occurs when a force is applied to a solid. In general, when a mechanical force is applied to a material such as ceramics such as Pb, Nb, Zr, Ga, Ti, stress is generated inside, and electric polarization occurs in the material. Piezoelectric phenomenon is called. This occurs and can contract and expand. The direction in which piezoelectric phenomena occur can be divided into contraction or relaxation in the same direction as in the electrical polarization and in the transverse direction. Such piezoelectric elements are used in pressure gauges, oscillators and the like, and also in load cells, actuators, printers, and the like.

The piezoelectric element, which is an energy conversion element that converts mechanical energy into electrical energy, is a pressure caused by unused vibration or pressure (eg, walking, typing, etc., which is a daily operation of a human being). It is possible to obtain the required power from the power supply, the electronic noise is not generated, and the use of the battery for a long time has been studied.

On the other hand, in relation to polymer batteries, Korean Patent Registration No. 10-0836202 (Patent Application No. 10-2006-0137748), which is the applicant's patent right, refers to 'nano polymer clay battery material, a battery and a method of manufacturing the battery using the same'. Is disclosed.

SUMMARY OF THE INVENTION The present invention has been made in an effort to provide an electrode composition of a polymer battery, a composition for a separator of a polymer battery, a polymer battery, and a method for manufacturing a polymer battery using the same.

The present invention relates to a composition for electrodes forming an electrode of a polymer battery, comprising: a polymer for providing a framework of a chain structure, a softened polymer which binds to the polymer to give flexibility to the polymer, and Induces electrical conductivity while inducing covalent bonding between a polymer or a polymer swelling agent for expanding the compound of the polymer and the softened polymer, carbon nanotube (CNT) powder acting as an electrode active material to impart electrical conductivity, and materials in the electrode Provided is a composition for electrodes of a polymer battery containing activated carbon powder that acts as an electrode active material.

The electrode composition of the polymer battery is an electrode composition constituting the positive electrode, the polymer is contained 25.0 to 75.0% by weight, the soft polymer is contained 4.0 to 40.0% by weight, the polymer swelling agent is contained 0.5 to 15.0% by weight 0.5 to 15.0% by weight of the carbon nanotube powder may be contained, and 0.2 to 8.0% by weight of the activated carbon powder may be contained.

The electrode composition of the polymer battery is an electrode composition constituting the negative electrode, the polymer is contained 25.0 to 75.0% by weight, the soft polymer is contained 4.0 to 40.0% by weight, the polymer swelling agent is contained 0.5 to 15.0% by weight 0.2 to 8.0% by weight of the carbon nanotube powder, the activated carbon powder may be contained 0.5 to 15.0% by weight.

The polymer may be polyamide, modified polyphenylene ether, polyphenylene sulfide, polyarylate, polyimide, polyetherimide, polyamideimide, polybenzoimidazole, polybenzookizazole, polyether ether ketone, polycyclo Hexanedimethylene terephthalate, polycarbonate, polymethyl methacrylate, methyl styrene, polystyrene, acrylonitrile-butadiene-styrene, styrene-butadiene copolymer, polyvinyl chloride, polymethylpentene, cyclic polyolefin, fluorene polyolefin It may be made of at least one material selected from esters, polyethylene naphtharate, polylactic acid, thermoplastic polyimide, thermoplastic polystyrene, thermoplastic polyvinyl chloride, thermoplastic polyamide, thermoplastic polyurethane, thermoplastic olefin elastomer and thermoplastic polyester elastomer. .

In addition, the polymer is polythiophene, polyaniline, polyacetylene, polypyrrole, polyphenylene, polyphenylenevinylene, polyfluorene, polyisocyanaphthalene, polyethylene dioxythiophene, poly (2,5-dialkoxy) para At least one conductive polymer selected from phenylenevinylene, polyparaphenylene and polyheptadiene.

The softening polymer may be made of at least one material selected from benzocyclobutane, polyvinylphenol, polyvinyl alcohol, parylene, polyvinylidene fluoride, cyanoethyl pullulan, and novolak resin.

The electrode composition of the polymer battery may further include a thickener for viscosity control, and the thickener may be 0.5 to 15.0% by weight and be made of polystearate.

The polymer expanding agent may be made of at least one material selected from lecithin, fluoromethane, chlorofluoromethane, fluoroethane, fluoroethane, fluoropropane and fluorobutane.

In addition, the present invention relates to a composition for a separator, which is inserted between electrodes of a polymer battery to form a separator, comprising: a polymer clay for providing a framework of a chain structure, calcium chloride powder bonded to the polymer clay, and a separator Provided is a composition for a separator of a polymer battery comprising a carbon nanotube (CNT) powder acting as a conductive agent, an activated carbon powder acting as a conductive agent, and carrageenan used as a gelling stabilizer while inducing covalent bonds between materials in the composition for the separator. .

The composition for the separator is a material forming a negative separator, the polymer clay is contained in 25.0 to 75.0% by weight, the calcium chloride powder is contained in 5.0 to 40.0% by weight, the carbon nanotube powder is 0.1 to 5.0% by weight It is contained, the activated carbon powder is contained 1.0 to 25.0% by weight, the carrageenan may be contained 0.5 to 15.0% by weight.

The composition for the separator is a material forming a positive separator, the polymer clay is contained in 25.0 to 75.0% by weight, the calcium chloride powder is contained in 5.0 to 40.0% by weight, the carbon nanotube powder is 1.0 to 25.0% by weight It is contained, the activated carbon powder is contained 1.0 to 5.0% by weight, the carrageenan may be contained 0.5 to 15.0% by weight.

The composition for the separator of the polymer battery may further include a thickener for viscosity control, and the thickener may be 0.5 to 15.0% by weight and be made of polystearate.

In addition, the present invention is a polymer battery comprising a positive electrode and a negative electrode provided opposite the positive electrode, wherein the positive electrode and the negative electrode, a polymer for providing a framework of the chain structure, in combination with the polymer and the polymer A soft polymer which provides flexibility to the polymer, a polymer swelling agent for expanding the polymer, the soft polymer or a compound of the polymer and the soft polymer, a carbon nanotube (CNT) powder acting as an electrode active material to impart electrical conductivity, and It includes activated carbon powder acting as an electrode active material to impart electrical conductivity while inducing covalent bonds between the materials in the electrode, the content of the carbon nanotube powder contained in the positive electrode is based on the content of the carbon nanotube powder contained in the negative electrode The amount of activated carbon powder contained in the negative electrode is higher than that of the positive electrode. Many polymer cells are provided relative to the amount of activated carbon powder present.

The present invention also provides a polymer battery having a structure in which a positive electrode, a negative separator, a positive separator, and a negative electrode are sequentially stacked, wherein the positive electrode and the negative electrode comprise a polymer for providing a basic structure of a chain structure, and A soft polymer combined with a polymer to impart flexibility to the polymer, a polymer swelling agent for expanding the polymer, the soft polymer or a compound of the polymer and the soft polymer, and carbon nano acting as an electrode active material for imparting electrical conductivity CNT powder and activated carbon powder, which acts as an electrode active material to impart electrical conductivity while inducing covalent bonding between materials in the electrode, the negative separator and the positive separator provide a framework of chain structure. Polymer clay for bonding, and calcium chloride powder bonded to the polymer clay And carbon nanotube (CNT) powder acting as a conducting agent in the separator, and activated carbon powder acting as a conducting agent and carrageenan used as a gelling stabilizer while inducing covalent bonding between materials in the composition for the separator. The amount of the carbon nanotube powder is higher than the content of the carbon nanotube powder contained in the negative electrode, the amount of activated carbon powder contained in the negative electrode is higher than the content of the activated carbon powder contained in the positive electrode, the positive separator The amount of carbon nanotubes contained in is higher than the content of carbon nanotubes contained in the negative separator, and the amount of activated carbon powder contained in the negative separator is higher than that of the activated carbon powder contained in the positive separator. Many polymer cells are provided.

The amount of carbon nanotubes contained in the positive electrode is higher than that of the carbon nanotubes contained in the negative separator, and the amount of activated carbon powder contained in the negative separator is higher than that of the activated carbon powder contained in the positive electrode. Many are preferred.

The amount of carbon nanotubes contained in the positive separator is higher than that of the carbon nanotubes contained in the negative electrode, and the amount of activated carbon powder contained in the negative electrode is higher than that of the activated carbon powder contained in the positive separator. Many are preferred.

0.5 to 15.0 wt% of the carbon nanotube powder is contained in the positive electrode, 0.2 to 8.0 wt% of the activated carbon powder is contained in the positive electrode, 0.2 to 8.0 wt% of the carbon nanotube powder is contained in the negative electrode and 0.5 to 5.0 wt% of the activated carbon powder. It is preferable that 15.0 weight% is contained.

Preferably, the positive electrode and the negative electrode contain 25.0 to 75.0 wt% of the polymer, 4.0 to 40.0 wt% of the soft polymer, and 0.5 to 15.0 wt% of the polymer expanding agent.

The negative separator contains 0.1 to 5.0% by weight of the carbon nanotube powder and the activated carbon powder to 1.0 to 25.0% by weight, and the positive separator contains 1.0 to 25.0% by weight of the carbon nanotube powder and the activated carbon The powder is preferably contained 1.0 to 5.0% by weight.

The positive electrode and the negative electrode may further include a thickener for viscosity control, the thickener may be 0.5 to 15.0% by weight contained in the positive electrode and the negative electrode and made of polystearate.

The negative separator and the positive separator may further include a thickener for viscosity control, and the thickener may be 0.5 to 15.0 wt% in the positive electrode and the negative electrode, and may be made of polystearate.

The polymer may be polyamide, modified polyphenylene ether, polyphenylene sulfide, polyarylate, polyimide, polyetherimide, polyamideimide, polybenzoimidazole, polybenzookizazole, polyether ether ketone, polycyclo Hexanedimethylene terephthalate, polycarbonate, polymethyl methacrylate, methyl styrene, polystyrene, acrylonitrile-butadiene-styrene, styrene-butadiene copolymer, polyvinyl chloride, polymethylpentene, cyclic polyolefin, fluorene polyolefin It may be made of at least one material selected from esters, polyethylene naphtharate, polylactic acid, thermoplastic polyimide, thermoplastic polystyrene, thermoplastic polyvinyl chloride, thermoplastic polyamide, thermoplastic polyurethane, thermoplastic olefin elastomer and thermoplastic polyester elastomer. .

The polymer is polythiophene, polyaniline, polyacetylene, polypyrrole, polyphenylene, polyphenylenevinylene, polyfluorene, polyisocyanaphthalene, polyethylene dioxythiophene, poly (2,5-dialkoxy) paraphenylene At least one conductive polymer selected from vinylene, polyparaphenylene and polyheptadiene.

The softening polymer may be made of at least one material selected from benzocyclobutane, polyvinylphenol, polyvinyl alcohol, parylene, polyvinylidene fluoride, cyanoethyl pullulan, and novolac resin.

In the present invention, a polymer and a soft polymer are added to a solvent, and a polymer swelling agent is added to the blended composition, followed by mixing to expand the polymer, the soft polymer, or the compound of the polymer and the soft polymer, and expand the carbon nano. Preparing a composition for a positive electrode by mixing a tube (CNT) powder and an activated carbon powder; blending a polymer and a soft polymer into a solvent, and adding a polymer swelling agent to the blended composition to mix the polymer and the soft polymer. Or expanding the polymer and the compound of the softened polymer, and mixing carbon nanotube (CNT) powder and activated carbon powder to prepare a negative electrode composition, and the positive electrode composition and the negative electrode composition having a predetermined size and thickness. Molding to have and the opposite composition for the positive electrode composition and the negative electrode composition facing each other Preparing a thin film or a film by laminating by using a roller press, followed by drying to obtain a polymer battery, wherein the carbon nanotube powder contained in the positive electrode has a carbon nanotube powder contained in the negative electrode. The present invention provides a method for manufacturing a polymer battery in which the compound is blended more than the amount, and the amount of activated carbon powder contained in the negative electrode is higher than that of the activated carbon powder contained in the positive electrode.

In the present invention, a polymer and a soft polymer are added to a solvent, and a polymer swelling agent is added to the blended composition, followed by mixing to expand the polymer, the soft polymer, or the compound of the polymer and the soft polymer, and expand the carbon nano. Preparing a composition for a positive electrode by mixing a tube (CNT) powder and an activated carbon powder; blending polymer clay and calcium chloride powder; adding carbon nanotube (CNT) powder and activated carbon powder to the blended composition, and mixing and mixing carrageenan. Preparing a composition for a negative separator by mixing the mixture, polymer clay and calcium chloride powder were mixed, carbon nanotube (CNT) powder and activated carbon powder were added to the blended composition, mixed, and carrageenan to mix the positive separator. Preparing a solvent composition, blending a polymer and a soft polymer to a solvent, and blending the composition. Adding a polymer swelling agent to the mixture to expand the polymer, the softened polymer or the compound of the polymer and the softened polymer, and mixing carbon nanotube (CNT) powder and activated carbon powder to prepare a composition for a negative electrode; Molding the composition for the positive electrode, the composition for the negative separator, the composition for the positive separator, and the composition for the negative electrode to have a predetermined size and thickness, and the molded composition for the positive electrode, the composition for the negative separator, and the positive separator. And stacking the composition for the negative electrode and the composition for the negative electrode sequentially and bonding them using a roller press to form a thin film or a film, followed by drying to obtain a polymer battery, the content of the carbon nanotube powder contained in the positive electrode. The content of the carbon nanotube powder contained in the negative electrode The amount of activated carbon powder contained in the negative electrode is higher than that of the activated carbon powder contained in the positive electrode, and the amount of carbon nanotubes contained in the positive separator is contained in the negative separator. The present invention provides a method for producing a polymer battery, wherein the amount of the activated carbon powder contained in the negative separator is higher than that of the carbon nanotubes, and the amount of the activated carbon powder contained in the negative separator increases.

0.5 to 15.0 wt% of the carbon nanotube powder is contained in the positive electrode, 0.2 to 8.0 wt% of the activated carbon powder is contained in the positive electrode, 0.2 to 8.0 wt% of the carbon nanotube powder is contained in the negative electrode and 0.5 to 5.0 wt% of the activated carbon powder. It is preferable to mix | blend so that 15.0 weight% is contained.

Preferably, the positive electrode and the negative electrode contain 25.0 to 75.0 wt% of the polymer, 4.0 to 40.0 wt% of the soft polymer, and 0.5 to 15.0 wt% of the polymer swelling agent.

The negative separator contains 0.1 to 5.0% by weight of the carbon nanotube powder and the activated carbon powder to 1.0 to 25.0% by weight, and the positive separator contains 1.0 to 25.0% by weight of the carbon nanotube powder and the activated carbon It is preferable to mix | blend powder so that 1.0-5.0 weight% may be contained.

In preparing the composition for the positive electrode and the composition for the negative electrode, further comprising the step of adding a thickener for viscosity control to the blended composition, wherein the thickener contains 0.5 to 15.0% by weight in the positive electrode and the negative electrode And may be made of polystearate.

In preparing the negative separator composition and the positive separator composition, the method further includes adding a thickener for viscosity control to the blended composition, wherein the thickener is 0.5 to 15.0 in the positive electrode and the negative electrode. It may be contained by weight percent and made of polystearate.

As said polymer, polyamide, modified polyphenylene ether, polyphenylene sulfide, polyarylate, polyimide, polyetherimide, polyamideimide, polybenzoimidazole, polybenzookizazole, polyether ether ketone, poly Cyclohexanedimethylene terephthalate, polycarbonate, polymethyl methacrylate, methyl styrene, polystyrene, acrylonitrile-butadiene-styrene, styrene-butadiene copolymer, polyvinyl chloride, polymethylpentene, cyclic polyolefin, fluorene At least one material selected from polyester, polyethylene naphrate, polylactic acid, thermoplastic polyimide, thermoplastic polystyrene, thermoplastic polyvinyl chloride, thermoplastic polyamide, thermoplastic polyurethane, thermoplastic olefin elastomer and thermoplastic polyester elastomer can be used. .

Moreover, as said polymer, polythiophene, polyaniline, polyacetylene, polypyrrole, polyphenylene, polyphenylene vinylene, polyfluorene, polyisocyanaphthalene, polyethylene dioxythiophene, poly (2, 5- dialkoxy) At least one conductive polymer selected from paraphenylenevinylene, polyparaphenylene, and polyheptadiene may be used.

As the softening polymer, it is preferable to use at least one material selected from benzocyclobutane, polyvinylphenol, polyvinyl alcohol, parylene, polyvinylidene fluoride, cyanoethyl pullulan and novolak resin.

According to the polymer battery according to the present invention, unlike the battery by the conventional chemical method, there is no electrical loss and explosion due to heat generation, and the stability of the battery is very excellent.

In addition, the polymer battery of the present invention can be used as a piezoelectric element in which electrical polarization occurs inside the battery when vibration or pressure is applied. When a mechanical force is applied to the polymer battery of the present invention, a piezoelectric phenomenon occurs in which stress is generated inside and electric polarization occurs in the material. Accordingly, the polymer battery of the present invention is a piezoelectric element that is an energy conversion element that converts mechanical energy into electrical energy, thereby obtaining necessary electric power from vibration or pressure, and not only generating electronic noise but also using it for a long time. It is expected that secondary cells or fuel cells can be replaced or supplemented.

Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings. However, the following embodiments are provided to those skilled in the art to fully understand the present invention, and may be modified in various forms, and the scope of the present invention is limited to the embodiments described below. It doesn't happen. Like numbers refer to like elements in the figures.

The polymer battery according to an exemplary embodiment of the present invention includes a positive electrode and a negative electrode provided to face the positive electrode, as shown in FIG. 3.

The positive electrode and the negative electrode may include a polymer for providing a framework of a chain structure, a softened polymer which combines with the polymer to give flexibility to the polymer, and the polymer, the soft polymer, or a compound of the polymer and the soft polymer. A polymer swelling agent to expand the carbon dioxide, a carbon nanotube (CNT) powder acting as an electrode active material to impart electrical conductivity, and an activated carbon powder to act as an electrode active material to impart electrical conductivity while inducing covalent bonds between materials in the electrode. do. The positive electrode and the negative electrode may further include a thickener for viscosity control. The potential difference appears between the positive electrode and the negative electrode according to the solid solution content of carbon nanotubes (CNT) and activated carbon powder contained in the positive electrode and the negative electrode. The amount of carbon nanotubes contained in the positive electrode is higher than that of the carbon nanotubes contained in the negative electrode, and the amount of activated carbon powder contained in the negative electrode is preferably higher than that of the activated carbon powder contained in the positive electrode.

In addition, the polymer battery according to another preferred embodiment of the present invention has a structure in which the positive electrode, the negative separator, the positive separator and the negative electrode are sequentially stacked as shown in FIG. The positive electrode and the negative electrode may include a polymer for providing a framework of a chain structure, a softened polymer which combines with the polymer to give flexibility to the polymer, and the polymer, the soft polymer, or a compound of the polymer and the soft polymer. A polymer swelling agent to expand the carbon dioxide, a carbon nanotube (CNT) powder acting as an electrode active material to impart electrical conductivity, and an activated carbon powder to act as an electrode active material to impart electrical conductivity while inducing covalent bonds between materials in the electrode. do. The positive electrode and the negative electrode may further include a thickener for viscosity control. The negative separator and the positive separator include polymer clay for providing a framework of chain structure, calcium chloride powder bonded to the polymer clay, carbon nanotube (CNT) powder serving as a conductive agent in the separator, Activated carbon powder which acts as a conducting agent while inducing covalent bonds between materials in the composition for the separator and carrageenan used as a gelling stabilizer. The negative separator and the positive separator may further include a thickener for viscosity control.

The potential difference appears between the positive electrode and the negative electrode according to the solid solution content of carbon nanotubes (CNT) and activated carbon powder contained in the positive electrode and the negative electrode. The amount of carbon nanotubes contained in the positive electrode is higher than that of the carbon nanotubes contained in the negative electrode, and the amount of activated carbon powder contained in the negative electrode is preferably higher than that of the activated carbon powder contained in the positive electrode.

In addition, a potential difference appears between the positive separator and the negative separator according to the content of solid solution of carbon nanotubes (CNT) and activated carbon powder contained in the positive separator and the negative separator. The amount of carbon nanotubes contained in the positive separator is higher than that of the carbon nanotubes contained in the negative separator, and the amount of activated carbon powder contained in the negative separator is higher than that of the activated carbon powder contained in the positive separator. It is desirable to increase it.

On the other hand, between the positive electrode and the negative separator according to the solid solution content of carbon nanotube (CNT) and activated carbon powder contained in the positive electrode having an electrical positive polarity and the negative separator having an electrical negative polarity The potential difference will appear. The amount of carbon nanotubes contained in the positive electrode is higher than that of the carbon nanotubes contained in the negative separator, and the amount of activated carbon powder contained in the negative separator is higher than that of the activated carbon powder contained in the positive electrode. Do.

In addition, between the negative electrode and the positive separator according to the solid solution content of carbon nanotubes (CNT) and activated carbon powder contained in the positive electrode having a negative polarity and the positive positive polarity The potential difference will appear. The amount of carbon nanotubes contained in the positive separator is higher than that of the carbon nanotubes contained in the negative electrode, and the amount of activated carbon powder contained in the negative electrode is higher than that of the activated carbon powder contained in the positive separator. desirable.

Hereinafter, each constituent material used for the positive electrode of the polymer battery of the present invention will be described.

The positive electrode composition constituting the positive electrode includes a polymer for providing a basic framework of a chain structure, a softened polymer which combines with the polymer to impart flexibility to the polymer, and the polymer, the softened polymer or the polymer and the softened polymer A polymer swelling agent for expanding a compound, a carbon nanotube (CNT) powder acting as an electrode active material for imparting electrical conductivity, and an activated carbon powder acting as an electrode active material for imparting electrical conductivity while inducing covalent bonding between materials in the electrode. Include. The electrode composition forming the positive electrode may further include a thickener for viscosity control.

The polymer is used as a main raw material of an electrode material forming an unstable chain structure in which carriers and vacancy are formed by expansion or the like. Here, the carrier means electrons, holes, ions, and the like. The polymer is polyamide (PA), modified polyphenylene ether (PPE), polyphenylene sulfide (PPS), polyacrylate (PAR), polyimide (PI) , Polyetherimide (PEI), polyamideimide (PAI), polybenzimidazole (PBI), polybenzookazole (polybenzobisoxazole (PBO), polyether ether ketone (PEEK) ), Polycyclohexane-dimethylene-terephthalate (PCT), polycarbonate (PC), polymethylmethacrylate (PMMA), methylstryrene (MS), polystyrene (polystyrene); PS), acrylonitrile-butadiene-styrene (ABS), styrene-butadiene copolymer (SBC), polyvinyl chloride (PVC), polymer Pentene (polymethylpentene; PMP), cyclic polyolefin, fluorene polyester, polyethylene naphthalate (PEN), poly lactic acid (PLA), thermoplastic polyimide (TPI), Thermoplastic polystyrene (TPS), thermoplastic polyvinyl chloride (TPVC), thermoplastic polyamide (TPA), thermoplastic polyurethane; TPU), thermoplastic olefinic elastomers (TPO), thermoplastic polyester elastomers (TPEE), or mixtures thereof. In addition, the polymer is a polythiophene, polyaniline (polyaniline), polyacetylene (polyacetylene), polypyrrole (polypyrrole), polyphenylene (polyphenylene), polyphenylene vinylene (polyphenylene vinylene), polyfluorene, poly It may also be a conductive polymer that is used alone or in combination of two or more of socianaphthalene, polyethylene dioxythiophene, poly (2,5-dialkoxy) paraphenylenevinylene, polyparaphenylene, polyheptadiene and derivatives thereof. In addition, the present invention is not limited thereto, and other polymers not mentioned within the scope of not impairing the object of the present invention may be used.

If the content of the polymer for the positive electrode composition is less than 25.0% by weight it is difficult to expect sufficient electrode stability, when the content of more than 75.0% by weight adversely affects the electrical conductivity in the electrode is not efficient. Therefore, it is preferable that the said polymer is contained 25.0-75.0 weight% with respect to the composition for positive electrodes.

The softening polymer is benzocyclobutane (BCB), polyvinyl phenol (Polyvinylphenol), polyvinyl alcohol (Polyvinyalcohol), parylene (parylene), polyvinylidene fluoride (PVF), cyanoethyl pullulan, novolac The resin may be used alone or in combination of two or more thereof, and other softening polymers may be used, which are not necessarily limited thereto and are not mentioned within the scope of not impairing the object of the present invention. The softening polymer is combined with a polymer in the electrode composition to provide flexibility to the electrode composition and serves to synthesize and maintain the structure of the electrode composition.

If the content of the softening polymer in the positive electrode composition is less than 4.0% by weight, it is difficult to expect the effect of imparting sufficient flexibility of the electrode composition. If the content is more than 40.0% by weight, the electrical conductivity in the electrode is adversely affected, which is not efficient. . Therefore, it is preferable that the said soft polymer is contained 4.0 to 40.0 weight% with respect to the composition for positive electrodes.

The thickener is to be added when the viscosity is adjusted to improve the workability by increasing the viscosity of the electrode composition. When the thickener is less than 0.5% by weight of the composition for the positive electrode, the viscosity becomes weak, and when it exceeds 15.0% by weight, the workability is not easy due to excessive viscosity, so that the content is 0.5 to 15.0% by weight It is preferable.

Polymer expanding agent refers to a material that expands a polymer by changing physical or chemical conditions such as occupying a larger volume when applied to expansion conditions such as heating, changes in pressure or application of mechanical forces. Polymeric expanders may be expanded by mixing with one or more other components, such as finely divided particulate matter, viscous fluids, plasticizers, extenders, or mixtures thereof. Lecithin may be used as the polymer swelling agent, and in addition, fluoromethane, chlorofluoromethane, fluoroethane, fluoroethane, fluoropropane, fluorobutane and the like may be used, and the base polymer may be polyborondimethylsiloxane. Boronated siloxane-based material (PBDMS) (Dow Corning, catalogue 3179) and the like may also be used, and the present invention is not limited thereto, and the polymer-expandable material may not be mentioned within the scope of not impairing the object of the present invention. Can also be used. The polymer expanding agent plays an important role in expanding the polymer, the soft polymer or the compound of the polymer and the soft polymer in the electrode composition. When the content of the polymer expanding agent is less than 0.5% by weight of the positive electrode composition, sufficient polymer material is not expanded, and when the content of the polymer expanding agent is greater than 15.0% by weight, the electrical conductivity in the electrode is adversely affected. It is preferable to set it as.

Carbon nanotubes (CNTs) have a long, thin tube-like structure with a diameter of several nm. Carbon nanotubes have been spotlighted for their unique electrical properties, which can be conductors and semiconductors, depending on their unique shape and dried structure. Carbon nanotubes can be divided into two types, single walled nanotubes and multiwall nanotubes. Single-walled nanotubes consist of only one wall, and multi-walled nanotubes consist of multiple walls. Single-walled carbon nanotubes are more flexible than multi-walled carbon nanotubes, so they tend to stick together in a rope. This is called a bundle of carbon nanotubes (Nanotube Rope). The carbon nanotubes (CNTs) are dispersed and mixed in the nanoparticle size in the composition for the electrode, so that the electrode has an electrical polarity and can emit electrons. Carbon nano tube (CNT) powder (Powder) is not fixed but refers to a single-walled, multi-walled or bundle type of all carbon nanotube (CNT) powder.

According to the solid solution content of the carbon nanotubes (CNT), the electrode has a positive polarity, which is a potential difference between a positive electrode having an electrical polarity and a negative electrode having an electrical polarity. It is to give. The carbon nanotubes (CNT) may be nanoparticles of carbon nanotubes modified with various intercalants in order to improve secondary processability of the electrode composition having electrical polarity. Here, the nanoparticles mean particles having a size in nanometer (nm) units of 1 nm or more and less than 1 μm.

When the content of the carbon nanotube (CNT) powder is less than 0.5% by weight with respect to the positive electrode composition, it is difficult to expect sufficient electrical conductivity, and the electrical polarity and electron emission characteristics of the electrode are insufficient. Since the dispersibility and the texture of the composition for degradation are reduced, the content thereof is preferably 0.5 to 15.0% by weight.

Active carbon powders are highly adsorptive and most of the components are carbonaceous materials. Activated carbon powder is intended to bring the atoms, molecules, or ions into a high energy state due to absorption of radiation, impact of a high-speed particle beam, external pressure, etc. in a composition for an electrode, to make a chain structure state. Easily and stably bonds with the compounds in the electrode composition to improve the carbonaceous function, carbon can easily form covalent bonds with hydrogen, oxygen or nitrogen, single bond, double bond, triple bond is possible and chain type To form a structure.

According to the solid solution content of the activated carbon powder, it has a positive polarity, which is intended to give a potential difference between a positive electrode having an electrical positive polarity and a negative electrode having an electrical negative polarity. The activated carbon powder may be modified with various intercalants such as nanoparticles of activated carbon powder in order to improve secondary processability of the electrode composition having electrical polarity.

When the activated carbon powder is less than 0.2% by weight, it is not sufficient to make the electrode composition into a chain structure state, and when the content of the activated carbon powder exceeds 8.0% by weight, the dispersibility of the electrode composition is lowered. It is preferable to set it as%.

Hereinafter, each constituent material used for the negative electrode of the polymer battery of the present invention will be described.

The negative electrode composition constituting the negative electrode includes a polymer for providing a framework of a chain structure, a softened polymer which binds to the polymer to give flexibility to the polymer, the polymer, the soft polymer, or the polymer and the soft polymer A polymer swelling agent for expanding a compound of the present invention, a carbon nanotube (CNT) powder acting as an electrode active material for imparting electrical conductivity, and an activated carbon powder acting as an electrode active material for imparting electrical conductivity while inducing covalent bonding between materials in the electrode It includes. The composition for electrodes forming the negative electrode may further include a thickener for viscosity control.

The polymer is used as a main raw material of the composition for electrodes forming an unstable chain structure in which a carrier is formed by expansion or the like. The polymer is polyamide (PA), modified polyphenylene ether (PPE), polyphenylene sulfide (PPS), polyacrylate (PAR), polyimide (PI) , Polyetherimide (PEI), polyamideimide (PAI), polybenzimidazole (PBI), polybenzookazole (polybenzobisoxazole (PBO), polyether ether ketone (PEEK) ), Polycyclohexane-dimethylene-terephthalate (PCT), polycarbonate (PC), polymethylmethacrylate (PMMA), methyl styrene (MS), polystyrene (polystyrene); PS), acrylonitrile-butadiene-styrene (ABS), styrene-butadiene copolymer (SBC), polyvinyl chloride (PVC), polymer Pentene (polymethylpentene; PMP), cyclic polyolefin, fluorene-based polyester, polyethylene naphthalate (PEN), poly lactic acid (PLA), thermoplastic polyimide (TPI) Thermoplastic polystyrene (TPS), thermoplastic polyvinyl chloride (TPVC), thermoplastic polyamide (TPA), thermoplastic polyurethane; TPU), thermoplastic olefinic elastomers (TPO), thermoplastic polyester elastomers (TPEE), or mixtures thereof. In addition, the polymer is a polythiophene, polyaniline (polyaniline), polyacetylene (polyacetylene), polypyrrole (polypyrrole), polyphenylene (polyphenylene), polyphenylene vinylene (polyphenylene vinylene), polyfluorene, poly It may also be a conductive polymer that is used alone or in combination of two or more of socianaphthalene, polyethylene dioxythiophene, poly (2,5-dialkoxy) paraphenylenevinylene, polyparaphenylene, polyheptadiene and derivatives thereof. In addition, the present invention is not limited thereto, and other polymers not mentioned within the scope of not impairing the object of the present invention may be used.

If the content of the polymer for the negative electrode composition is less than 25.0% by weight it is difficult to expect sufficient electrode stability, when the content of more than 75.0% by weight adversely affects the electrical conductivity in the electrode is not efficient. Therefore, it is preferable that the said polymer is contained 25.0-75.0 weight% with respect to the composition for negative electrodes.

The softening polymer is benzocyclobutane (BCB), polyvinyl phenol (Polyvinylphenol), polyvinyl alcohol (Polyvinyalcohol), parylene (parylene), polyvinylidene fluoride (PVF), cyanoethyl pullulan, no Volac resins may be used alone or in combination of two or more, and are not necessarily limited thereto, and other softened polymers may be used, which are not mentioned within the scope of not impairing the object of the present invention. The softening polymer is combined with a polymer in the electrode composition to provide flexibility to the electrode composition and serves to synthesize and maintain the structure of the electrode composition.

When the content of the softening polymer in the negative electrode composition is less than 4.0% by weight, it is difficult to expect a sufficient effect of imparting flexibility of the electrode composition, and when it exceeds 40.0% by weight, there is a problem that it is not efficient because it adversely affects the electrical conductivity in the electrode. . Therefore, it is preferable that the said soft polymer contains 4.0 to 40.0 weight% with respect to the composition for negative electrodes.

The thickener is to be added when the viscosity is adjusted to improve the workability by increasing the viscosity of the electrode composition. When the thickener is less than 0.5% by weight of the composition for the negative electrode, the viscosity becomes weak, and when it exceeds 15.0% by weight, the workability is not easy due to excessive viscosity, so that the content is 0.5 to 15.0% by weight It is preferable.

Polymer expanding agent refers to a material that expands a polymer by changing physical or chemical conditions such as occupying a larger volume when applied to expansion conditions such as heating, changes in pressure or application of mechanical forces. Polymeric expanders may be expanded by mixing with one or more other components, such as finely divided particulate matter, viscous fluids, plasticizers, extenders or mixtures thereof. Lecithin may be used as the polymer swelling agent, and in addition, fluoromethane, chlorofluoromethane, fluoroethane, fluoroethane, fluoropropane, fluorobutane and the like may be used, and the base polymer may be polyborondimethylsiloxane. Boronated siloxane-based material (PBDMS) (Dow Corning, catalogue 3179) and the like may also be used, and the present invention is not limited thereto, and the polymer-expandable material may not be mentioned within the scope of not impairing the object of the present invention. Can also be used. The polymer expanding agent plays an important role in expanding the polymer, the soft polymer or the compound of the polymer and the soft polymer in the electrode composition. When the content of the polymer expanding agent is less than 0.5% by weight of the positive electrode composition, sufficient polymer material is not expanded, and when the content of the polymer expanding agent is greater than 15.0% by weight, the electrical conductivity in the electrode is adversely affected. It is preferable to set it as.

The carbon nanotubes (CNTs) are dispersed and mixed in the nanoparticle size in the composition for the electrode, so that the electrode has an electrical polarity and can emit electrons. According to the solid solution content of the carbon nanotube (CNT), the electrode has a negative polarity, which is a potential difference between a positive electrode having an electrical polarity and a negative electrode having an electrical polarity. It is to give. The carbon nanotubes (CNT) may be nanoparticles of carbon nanotubes modified with various intercalants in order to improve secondary processability of the electrode composition having electrical polarity. Here, the nanoparticles mean particles having a size in nanometer (nm) units of 1 nm or more and less than 1 μm.

When the content of the carbon nanotube (CNT) powder is less than 0.2% by weight relative to the composition for the negative electrode, it is difficult to expect sufficient electrical conductivity, and the electrical polarity and electron emission characteristics of the electrode are insufficient. Since the dispersibility and binding property of the composition for inferiority fall, it is preferable to make the content into 0.2 to 8.0 weight%.

Active carbon powders are highly adsorptive and most of the components are carbonaceous materials. Activated carbon powder is intended to bring the atoms, molecules, or ions into a high energy state due to absorption of radiation, impact of a high-speed particle beam, external pressure, etc. in a composition for an electrode, to make a chain structure state. Easily and stably bonds with the compounds in the electrode composition to improve the carbonaceous function, carbon can easily form covalent bonds with hydrogen, oxygen or nitrogen, single bond, double bond, triple bond is possible and chain type To form a structure.

According to the solid solution content of the activated carbon powder has a negative polarity, which is to give a potential difference between the positive electrode having an electrical positive polarity and the negative electrode having an electrical negative polarity. The activated carbon powder may be a nanoparticles of the activated carbon powder may be modified with various intercalants in order to improve secondary processability of materials having electrical polarity.

When the activated carbon powder is less than 0.5% by weight, it is not enough to make the electrode composition into a chain structure state, and when the content is greater than 15.0% by weight, the dispersibility of the electrode composition is lowered, so that the content is 0.5 to 15.0% by weight. It is preferable to set it as%.

Electrodes composed of the above materials are to be excellent in physical and chemical stability and to minimize the risk of exothermic phenomenon and explosion.

In addition, each component used in the composition for negative (-) separator of this invention is demonstrated as follows.

The negative separator composition is composed of a polymer clay or a polymer clay to provide a basic structure of the chain structure, and the atom or molecule or the like due to absorption of radiation, impact of high-speed particle beams, external pressure, etc. in the composition for the separator. Calcium chloride powder, gelling stabilizer, carbon nanotube (CNT) powder acting as a conducting agent in the separator and the material in the composition for separator acting as a conducting agent while ions and the like easily change to a high energy state Activated carbon powder. The negative separator composition may further include a thickener for viscosity control.

The polymer clay is a compound produced by mixing an additive such as a plasticizer to make the polymer such as polyvinyl chloride and polyester soft. Polymer-clay is a water-soluble resin wheeler, and one of a series of high-density compounds is an aromatic-aliphatic polyester resin. The polymer clay is in the form of clay, which is free to express, hardens when applied to heat, and does not deform, and is soft to the touch. Since these polymer clays contain pigments, they are frequently used in interior props, accessories, characters, and clay animation props.

The polymer clay is used as a main raw material of the composition for separators forming an unstable chain structure in which carriers are formed by expansion or the like. In consideration of dispersibility, electrical properties and the like, it is preferable to use polymer clay having nano-sized particles (particles having a size in nanometer (nm) units of 1 nm or more and less than 1 μm). If the content of the polymer clay with respect to the composition for the negative separator is less than 25.0% by weight, it is difficult to expect sufficient separator stability. When the content of the polymer clay is greater than 75.0% by weight, the separator is adversely affected and the efficiency of the separator is not efficient. Therefore, it is preferable that the said polymer clay is contained 25.0-75.0 weight% with respect to the composition for negative separators.

Calcium chloride Powder is a formula of CaCl ₂ . Calcium chloride is a double salt, produced as minerals such as tachyhydrite, and is contained 0.15% in seawater. Anhydrides of calcium chloride are slightly twisted rutile structure with white crystals of deliquescent tetragonal system. It is known that the formula weight of calcium chloride is 111.0, the melting point is 772 ° C, the boiling point is 1,600 ° C or more, and the specific gravity is about 2.15. Solubility in water, ie, the number of grams of calcium chloride that is soluble in 100 g of water, is very high at 74.5 g (20 ° C), and is very soluble in alcohol and acetone. In addition, dihydrates and anhydrides of calcium chloride are widely used as a drying agent during the rainy season because they are strongly deliquescent and absorb moisture well. Calcium chloride can absorb as much as 14 times its own weight. In addition, calcium chloride is combined with ammonia (NH ₃ ) and alcohol (eg, ethanol: C ₂ H ₅ OH) to form molecular compounds such as CaCl ₂ · 8NH ₃ and CaCl 2 · 4C ₂ H ₅ OH.

The calcium chloride powder combines with the polymer clay and serves to easily change atoms, molecules, or ions into a high energy state due to absorption of radiation, impact of high-speed particle beams, and external pressure in the material. When the content of the calcium chloride powder is less than 5.0% by weight with respect to the composition for the negative separator, it is difficult to change the atoms, molecules, or ions inside the negative separator into a high energy state. There is a problem that it is not efficient because it adversely affects sex. Therefore, the calcium chloride powder is preferably 5.0 to 40.0% by weight.

The carbon nanotubes (CNTs) are dispersed and mixed in the composition for the separator in nanoparticle size, so that the separator has polarity with electrical polarity to emit or store electrons. According to the solid solution content of the carbon nanotubes (CNT), the separator has a negative polarity, which is a positive separator having an electrical positive polarity and a negative separator having an electrical negative polarity. It is to give a potential difference between.

When the content of the carbon nanotube (CNT) powder is less than 0.1% by weight with respect to the composition for the negative separator, the electrical polarity and electron emission characteristics of the separator are insufficient. When the content of the carbon nanotube (CNT) exceeds 5.0% by weight, the dispersibility of the composition for the separator And since the bond falls, it is preferable to make the content into 0.1 to 5.0 weight%.

Active carbon powders are highly adsorptive and most of the materials are carbonaceous materials. Activated carbon powder is intended to bring the atoms, molecules, or ions into a high energy state due to absorption of radiation, impact of a high-speed particle beam, external pressure, etc. in a composition for an electrode, to make a chain structure state. Easily and stably bonds with the compounds in the composition for the separator to improve the carbonaceous function, carbon can easily form covalent bonds with hydrogen, oxygen or nitrogen, single bond, double bond, triple bond is possible and chain type To form a structure.

According to the solid solution content of the activated carbon powder has a negative polarity, which is intended to give a potential difference in the positive polarity material and the electrically negative material. The activated carbon powder may be a nanoparticles of the activated carbon powder may be modified with various intercalants in order to improve secondary processability of materials having electrical polarity.

When the activated carbon powder is less than 1.0% by weight, it is not sufficient to make the electrode composition into a chain structure state, and when the content of the activated carbon powder exceeds 25.0% by weight, the dispersibility of the electrode composition is lowered, so that the content is 1.0 to 25.0%. It is preferable to set it as%.

The thickener is to be added when the viscosity is adjusted to improve the workability by increasing the viscosity of the electrode composition. The thickener has a weak viscosity when the content is less than 0.5% by weight based on the amount of the composition for the separator, and when the content exceeds 15.0% by weight, the workability is not easy due to excessive viscosity, so that the content is 0.5-15.0% by weight. It is preferable to set it as. It is preferable to use poly stearate as the thickener.

Preference is given to using Carrageenan as the gelling stabilizer. Carrageenan is an additive for increasing adhesion and viscosity, enhancing emulsion stability, and improving physical properties and feel. Carrageenan is used as a thickener, gelling agent, stabilizer and the like. Carrageenan's water retention is very good and its viscosity does not change over time. In addition, carrageenan reacts with casein to form a uniform gel. The gel strength varies depending on the cation concentration and fat content of Ca ⁺ and K ⁺ in milk, and the whey separation prevention effect is excellent. The viscosity of carrageenan rises rapidly at 1 to 2%, but gradually decreases due to temperature rise and agitation. In addition, in the Ca ⁺ and acidic ranges, the viscosity decreases, but becomes more stable toward the alkali, and does not change over time. Carrageenan has a pH of 8 to 11 and a viscosity of at least 5 cps (7.5 ° C., 1.5% solution).

The carrageenan is less viscous and safety when the content is less than 0.5% by weight with respect to the composition for the negative separator, and when it exceeds 15.0% by weight, the workability is not easy due to excessive viscosity of the polymer clay bond, It is preferable to set it as 0.5 to 15.0 weight%.

The negative separator composition having an electrical negative polarity may include a polymer clay, calcium chloride powder, carbon nanotube (CNT) powder, activated carbon powder, a thickener, and a gelling stabilizer. According to the solid solution content of carbon nanotubes (CNT) and activated carbon powder contained in the separator of the potential difference between the positive and negative separators.

Referring to each component used in the composition for the positive (+) separator of the present invention is as follows.

The amount of the composition for the separator is combined with the polymer clay, the polymer clay to provide a framework of the chain structure, in the separator composition due to the absorption of radiation, impact of high-speed particle beams, external pressure, etc. Calcium chloride powder, gelling stabilizer, carbon nanotube (CNT) powder acting as a conducting agent in the separator and the material in the composition for separator acting as a conducting agent while ions and the like easily change to a high energy state Activated carbon powder. The amount of the composition for the separator may further include a thickener for viscosity control.

The polymer clay is used as a main raw material of the composition for separators forming an unstable chain structure in which carriers are formed by expansion or the like. If the content of the polymer clay in the amount of the composition for the separator is less than 25.0% by weight, it is difficult to expect sufficient separator stability. When the amount of the polymer clay is greater than 75.0% by weight, the separator is adversely affected and thus inefficient. Therefore, it is preferable that the said polymer clay is contained 25.0-75.0 weight% with respect to the composition for separators.

The calcium chloride powder combines with the polymer clay and serves to easily change atoms, molecules, or ions into a high energy state due to absorption of radiation, impact of high-speed particle beams, and external pressure in the material. When the content of the calcium chloride powder is less than 5.0 wt% with respect to the composition for the positive separator, it is difficult to change the atoms, molecules, or ions, etc., inside the positive separator into a high energy state. There is a problem that it is not efficient because it adversely affects sex. Therefore, the calcium chloride powder is preferably 5.0 to 40.0% by weight.

The carbon nanotubes (CNT) are dispersed and mixed in the composition for the separator in nanoparticle size, so that the separator has an electrical polarity and emits or accumulates electrons. According to the solid solution content of the carbon nanotubes (CNT), the separator has a positive polarity, which is a positive separator having a positive polarity and a negative polarity having a negative polarity. This is to give a potential difference between the separators.

When the content of the carbon nanotube (CNT) powder is less than 1.0 wt% with respect to the positive electrode composition, the electrical polarity and electron emission characteristics of the separator are insufficient, and when the content of the carbon nanotube (CNT) exceeds 25.0 wt%, the dispersibility of the composition for the separator And since the bond falls, it is preferable to make the content into 1.0 to 25.0 weight%.

Active carbon powders are highly adsorptive and most of the components are carbonaceous materials. Activated carbon powder is intended to bring the atoms, molecules, or ions into a high energy state due to absorption of radiation, impact of a high-speed particle beam, external pressure, etc. in a composition for an electrode, to make a chain structure state. Easily and stably bonds with the compounds in the composition for the separator to improve the carbonaceous function, carbon can easily form covalent bonds with hydrogen, oxygen or nitrogen, single bond, double bond, triple bond is possible and chain type To form a structure.

It has a positive polarity according to the solid solution content of the activated carbon powder, which is intended to give a potential difference between a positive separator having an electrical positive polarity and a negative separator having an electrical negative polarity. will be. The activated carbon powder may be a nanoparticles of the activated carbon powder may be modified with various intercalants in order to improve secondary processability of materials having electrical polarity.

When the activated carbon powder is less than 1.0% by weight, it is not sufficient to make the electrode composition into a chain structure state, and when the content of the activated carbon powder exceeds 5.0% by weight, the dispersibility of the electrode composition is lowered, so that the content is 1.0 to 5.0% by weight. It is preferable to set it as%.

The thickener is to be added when the viscosity is adjusted to improve the workability by increasing the viscosity of the electrode composition. The thickener has a weak viscosity when the content is less than 0.5% by weight based on the amount of the composition for the separator, and when the content exceeds 15.0% by weight, the workability is not easy due to excessive viscosity, so that the content is 0.5-15.0% by weight. It is preferable to set it as. It is preferable to use poly stearate as the thickener.

Preference is given to using Carrageenan as the gelling stabilizer. Carrageenan is an additive for increasing adhesion and viscosity, enhancing emulsion stability, and improving physical properties and feel. Carrageenan is less viscous and safety when the content is less than 0.5% by weight with respect to the composition for the negative separator, and when it exceeds 10.0% by weight, the workability is not easy due to excessive viscosity of the polymer clay bond, the compounding ratio It is preferable to make 0.5-15.0 weight%.

The positive separator composition having an electrical positive polarity may include polymer clay, calcium chloride powder, carbon nanotube (CNT) powder, activated carbon powder, thickener and gelling stabilizer, and negative separator and positive According to the solid solution content of carbon nanotubes (CNT) and activated carbon powder contained in the separator of the potential difference between the positive separator and the negative separator.

The separator composed of the above materials is to be excellent in physical and chemical stability and to minimize the risk of exothermic phenomenon and explosion.

Hereinafter, the method of manufacturing the composition for positive electrodes, the composition for negative electrodes, the composition for negative separators, and the composition for positive separators is demonstrated, and the method of manufacturing a polymer battery using these is demonstrated. In the following description of the preparation method, the compounding ratio of each material has already been described sufficiently in describing the material, and thus the detailed description thereof will be omitted.

In a preferred embodiment of the present invention, the composition for the electrode having an electrical positive polarity and the composition for the electrode having an electrical negative polarity, and the composition for a negative separator having an electrical negative polarity and electrical To prepare a composition for a positive separator having a positive polarity, respectively, first, a method for preparing a composition for an electrode having a positive polarity and an electrical negative polarity will be described. However, in the present invention, the composition for an electrode having an electrical positive polarity and a negative polarity and the composition for a negative separator having an electrical negative polarity and the polarity of an electrical positive The order of preparation of the composition for positive separators is not limited.

A method of producing a composition for a positive electrode having an electrical positive polarity will be described.

First, the polymer and the soft polymer are blended into the solvent. The first reason for blending the polymer is because it is used as a main raw material of the electrode composition having an unstable chain structure in which a carrier is formed. Because it is easy to synthesize a constant, but is not limited to this. It is preferable that the said mixing is made at the temperature of about normal temperature (15 degreeC)-about 60 degreeC, and it is preferable to mix | blend while stirring at a speed of about 10-300 rpm.

The solvent is necessary for controlling the viscosity and fluidity appropriate for the electrode composition. As the solvent, an alcohol solvent, an ether solvent, an aromatic solvent, an acetate solvent, a ketone solvent, or a mixture thereof may be used. The alcohol solvent may be ethanol, methanol, isopropyl alcohol, normal butanol and the like. The ether solvent is propylene glycol monopropyl ether, propylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monopropyl ether, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, di Ethylene glycol monopropyl ether, diethylene glycol monobutyl ether, diethylene glycol-2-ethylhexyl ether and the like. The aromatic solvent may be toluene, xylene or the like. The acetate solvent may be butyl acetate, ethyl acetate, or the like. The ketone solvent may be acetone, methyl ethyl ketone, methyl isobutyl ketone, or the like. The content of the solvent is preferably 3 to 30% by weight relative to the electrode composition. The solvent is removed in a drying step described later.

When the blending is completed, a polymer swelling agent is added and mixed to expand the polymer, the softened polymer, or the compound of the polymer and the softened polymer. When the polymer swelling agent is added to the composition in which the polymer and the soft polymer are mixed, mixed with stirring, and left at a constant temperature (for example, room temperature) for a predetermined time, the polymer, the soft polymer, or the compound of the polymer and the soft polymer is expanded.

A thickener may be added to and mixed with the composition in which the polymer and the soft polymer are blended. The thickener is intended to make the blended composition have a certain viscosity or more.

Carbon nanotube (CNT) powder and activated carbon powder are mixed to prepare a composition for a positive electrode having a positive polarity (+). The carbon nanotube (CNT) powder and the activated carbon powder may be mixed at a temperature of about 15 ° C. to about 60 ° C., and the mixing may be performed while stirring at a speed of about 10 to 300 rpm.

The negative electrode composition having an electrical negative polarity may be prepared in the same manner as the method for preparing a positive electrode composition having an electrical positive polarity, when the carbon nanotube (CNT) powder and the activated carbon powder are mixed. The potential difference is generated between the positive electrode and the negative electrode by changing the solid solution content of the positive electrode composition having positive polarity and the carbon nanotube (CNT) powder and the activated carbon powder.

Hereinafter, a method of preparing a composition for negative separators having a negative polarity and a composition for positive separators having a positive polarity will be described.

First, the manufacturing method of the composition for negative separators having an electrical negative polarity is demonstrated.

Polymer clay and calcium chloride powder are blended. The first reason for mixing them is that the polymer clay and calcium chloride powder are used in the composition for separators due to absorption of radiation, impact of high-speed particle beams, external pressure, etc. This is because it is used as a main raw material of the composition for the separator, which serves to change to a state that tends to become a high energy state, but it is easy to synthesize the structure of the material uniformly when pre-mixed, but is not limited thereto. It is preferable that the said mixing is made at the temperature of about normal temperature (15 degreeC)-about 60 degreeC, and it is preferable to mix | blend while stirring at a speed of about 10-300 rpm.

When the blending is completed, the carbon nanotube (CNT) powder and activated carbon powder is added to the blended composition and mixed. The carbon nanotube (CNT) powder and the activated carbon powder may be mixed at a temperature of about 15 ° C. to about 60 ° C., and the mixing may be performed while stirring at a speed of about 10 to 300 rpm.

When the mixing of the carbon nanotube (CNT) powder and the activated carbon powder is completed, in order to increase the adhesiveness and viscosity and to improve the emulsion stability by mixing a gelling stabilizer to form a negative separator composition having a negative polarity (-) Manufacture. The gelling stabilizer is preferably mixed at a temperature of about 15 ° C. to about 60 ° C., and is preferably mixed while stirring at a rate of about 10 to 300 rpm.

A thickening agent may be added to the composition to be blended with the gelling stabilizer, and the thickening agent is used to make the blended composition have a certain viscosity or more.

A positive separator composition having an electrical positive polarity may be prepared in the same manner as a method for preparing a negative separator composition having an electrical polarity, and carbon nanotubes (CNT). When the powder and the activated carbon powder are mixed, the potential difference between the positive separator and the negative separator is changed by varying the content of the solid separator having a negative polarity, the carbon nanotube (CNT) powder and the activated carbon powder. Make it happen.

The positive electrode composition having a positive polarity and the negative electrode composition having a negative polarity are molded to have a predetermined size and thickness, respectively. The molded composition for the positive electrode and the composition for the negative electrode are bonded to each other to prepare a thin film or film form. In this case, the bonding may use a pressurization method using a device such as a roller press, and the pressure of the roller press is preferably about 1 to 300 ton / m 2 in consideration of the thickness of the polymer battery to be formed. When the pressure of the roller press is less than 1 ton / ㎡ may be weak adhesiveness between the bonded material, if it exceeds 300 ton / ㎡ may cause deterioration in the material due to excessive pressure can be a reliable polymer battery You may not get it. Finally, a drying process is performed to complete the polymer cell. The drying process is preferably carried out at a temperature of 15 ~ 80 ℃. The solvent contained in the composition for electrodes is removed by the drying process. In the polymer battery configured as described above, a potential difference appears between the positive electrode and the negative electrode according to the solid solution content of the carbon nanotubes (CNT) and activated carbon powder contained in the positive electrode and the negative electrode.

In addition, the composition for positive electrode having an electrical positive polarity, the composition for negative separators having an electrical negative polarity, the composition for positive separators having an electrical positive polarity, and the electrical negative (-) The negative electrode composition having a polarity of each is molded to have a predetermined size and thickness. The molded composition for the positive electrode, the composition for the negative separator, the composition for the positive separator and the composition for the negative electrode are sequentially stacked, and then bonded to prepare a thin film or film. In this case, the bonding may use a pressurization method using a device such as a roller press, and the pressure of the roller press is preferably about 1 to 300 ton / m 2 in consideration of the thickness of the polymer battery to be formed. When the pressure of the roller press is less than 1 ton / ㎡ may be weak adhesiveness between the bonded material, if it exceeds 300 ton / ㎡ may cause deterioration in the material due to excessive pressure can be a reliable polymer battery You may not get it. Finally, a drying process is performed to complete the polymer cell. The drying process is preferably carried out at a temperature of 15 ~ 80 ℃. The solvent contained in the electrode composition is removed by the drying process. In the polymer battery configured as described above, a potential difference appears between the positive electrode and the negative electrode according to the solid solution content of the carbon nanotubes (CNT) and activated carbon powder contained in the positive electrode and the negative electrode, and the carbon nanoparticles contained in the positive separator and the negative separator. Depending on the solid solution content of the tube (CNT) and activated carbon powder, a potential difference appears between the positive separator and the negative separator.

One or both surfaces of the manufactured polymer battery may be further coated with an insulator as shown in FIGS. 4 and 6, and as the insulator, for example, silicon oxide (SiO ₂ ), teflon, polyurethane, or the like may be used. .

When the insulator is coated on one side or both sides of the polymer battery in order to use the device using the tunneling phenomenon of the former, the coating thickness of each insulator is preferably about 6 to 10 kPa. If the thickness of the insulator is less than 6 kPa, the production of the thickness is not easy, so the productivity is lowered. If the thickness of the insulator is more than 10 kPa, the electron migration due to the tunneling phenomenon of the electrons is not easy.

When an electric wave is generated in an oscillator such as an AP (Accss Point), or an absorption of radiation, impact of a high-speed particle beam, or an external pressure is applied to the polymer battery of the present invention, a polymer battery or a positive electrode, which is composed of a positive electrode and a negative electrode, negative Energy is generated by the activation of electrons, holes, or ions in the polymer battery consisting of a separator, a positive separator, and a negative electrode.

The polymer battery of the present invention is applicable to almost all products requiring a power source, for example, a mobile phone, a wireless mouse, a keyboard, an MP3 player, a camera, a notebook, a PDA, a robot, an electronic tag (Active RFID). ) It can be used in a battery or the like, its use is not limited.

Hereinafter, a polymer battery according to a preferred embodiment of the present invention will be described with reference to the accompanying drawings.

1 and 2, the general polymer generally has a stable molecular chain structure, and the expanded polymer has an unstable molecular chain structure and a carrier like a hole as compared to the general polymer. The polymer battery of the present invention is caused by the pressure at the time of bonding between an unstable molecular chain structure and an electrode composition or bonding between an electrode composition and a separator composition due to bonding and expansion of the polymer constituting the electrode composition or the separator composition. It has a spin hole chain structure.

Atomic bonds or molecular orbitals in a polymer cell according to the present invention are atoms, molecules, electrons or ions due to expansion of polymers, soft polymers or compounds of polymers and soft polymers, structural distortion of molecules, pressure, etc. The back energy becomes a high energy state, thereby causing mutual attraction and repulsion between atoms, electrons, holes, or ions, and carriers (electrons, holes, or ions) released from the bond are dependent on the attraction force and repulsive force acting. Will move. On the other hand, due to the potential difference between the positive electrode and the negative electrode, the potential difference between the positive electrode and the negative separator, the potential difference between the negative separator and the positive separator or the potential difference between the positive separator and the negative electrode, The repulsive force acts, and there is a constant carrier movement between the positive electrode and the negative electrode.

The lamination structure of the polymer battery composed of the positive electrode and the negative electrode is shown in FIG. 3, and the lamination structure of the polymer battery composed of the positive electrode, the negative separator, the positive separator and the negative electrode is shown in FIG. 4.

On the other hand, in the polymer battery of the present invention as shown in Figs. 4 and 6 when the insulator is coated on both sides and the metal plate is coupled again, when the pressure is applied up and down as shown in Fig. 7, the potential difference and the electron transfer phenomenon appears to induce a current May be

When a mechanical force is applied to the polymer battery of the present invention, a piezoelectric phenomenon occurs in which stress is generated inside and electric polarization occurs in the material. The polymer battery of the present invention is a piezoelectric element, which is an energy conversion element for converting mechanical energy into electrical energy, and may obtain necessary power from pressure.

The invention is described in more detail with reference to the following examples, which are not intended to limit the invention.

First, a composition for a positive electrode according to a preferred embodiment of the present invention will be described.

In a preferred embodiment of the present invention, water-soluble polyvinyl chloride is used as the polymer of the electrode composition. Polyvinyl chloride (PVC) is a representative material of plastics. It is originally a hard material, and it is flexible and elastic by using a phthalic acid (phthalates, DEHP, DINP, DBP, etc.) plasticizer or adipic acid (adipates, DHEA, etc.) plasticizer. It is then commercialized.

Polyvinyl chloride (PVC) used in the present invention is a series of high-density compounds using a plasticizer, the polyvinyl chloride (PVC) is used as the main raw material of the composition for the electrode to expand the carrier (carrier) and have an unstable chain structure do. Polyvinyl chloride (PVC) is contained 60.0% by weight based on the positive electrode.

As the softening polymer of the electrode composition, polyvinyl phenol (poly vinyl phenol) is used. Polyvinyl phenol (polyvinyl phenol) is combined with polyvinyl chloride (PVC) and the like in the composition for the electrode to give flexibility to the composition for the electrode and serves to maintain a constant synthesis of the structure of the composition for the electrode. The polyvinylphenol is contained 20.0% by weight based on the positive electrode.

Ethanol is used as a solvent for the electrode composition. Ethanol is a colorless liquid with a chemical formula of C ₂ H ₅ OH and a characteristic smell and taste. It has a molecular weight of 46.07, a melting point of -114.3 ° C, a boiling point of 78.4 ° C and a specific gravity of 0.7893.

Poly stearate is used as a thickener of the electrode composition. Poly stearate improves workability by increasing the viscosity of the electrode composition. The poly stearate is 6.0 wt% based on the positive electrode.

Lecithin is used as a polymer swelling agent for the electrode composition. The lecithin is derived from Greek yolkis (lecithos). It is soluble in alcohol or ether and creates an emulsion with water, and plays an important role in expanding the polyvinyl chloride (PVC), polyvinylphenol or a compound of polyvinyl chloride and polyvinylphenol in the electrode composition. The lecithin is 6.0% by weight based on the positive electrode.

Carbon nanotubes (CNTs) are dispersed and mixed in the composition for electrodes in nanoparticle size, so that the electrodes can emit electrical polarity and electrons. The carbon nanotube powder is contained 5.5 wt% based on the positive electrode.

The activated carbon powder is contained 2.5% by weight based on the positive electrode.

A composition for a negative electrode according to a preferred embodiment of the present invention will be described.

In a preferred embodiment of the present invention, water-soluble polyvinyl chloride is used as the polymer of the electrode composition. Polyvinyl chloride (PVC) is a representative material of plastic, and it is originally a hard material, and it is flexible and elasticity by using a phthalic acid plasticizer (phthalates, DEHP, DINP, DBP, etc.) or adipic acid plasticizer (adipates, DHEA, etc.). After it is raised, it is commercialized.

Polyvinyl chloride (PVC) used in the present invention is a series of high-density compounds using a plasticizer, the polyvinyl chloride (PVC) is used as the main raw material of the composition for the electrode to expand the carrier (carrier) and have an unstable chain structure do. The polyvinyl chloride (PVC) is contained 60.0% by weight based on the negative electrode.

As the softening polymer of the electrode composition, polyvinyl phenol (poly vinyl phenol) is used. Polyvinyl phenol (polyvinyl phenol) is combined with polyvinyl chloride (PVC) and the like in the composition for the electrode to give flexibility to the composition for the electrode and serves to maintain a constant synthesis of the structure of the composition for the electrode. The polyvinylphenol is contained 20.0% by weight based on the negative electrode.

Ethanol is used as a solvent for the electrode composition. Ethanol is a colorless liquid with a chemical formula of C ₂ H ₅ OH and a characteristic smell and taste. It has a molecular weight of 46.07, a melting point of -114.3 ° C, a boiling point of 78.4 ° C and a specific gravity of 0.7893.

Poly stearate is used as a thickener of the electrode composition. Poly stearate improves workability by increasing the viscosity of the electrode composition. The poly stearate is 6.0 wt% based on the negative electrode.

Lecithin is used as a polymer swelling agent for the electrode composition. The lecithin is derived from Greek yolkis (lecithos). It is soluble in alcohol or ether and creates an emulsion with water, and plays an important role in expanding the polyvinyl chloride (PVC), polyvinylphenol or a compound of polyvinyl chloride and polyvinylphenol in the electrode composition. The lecithin is 6.0% by weight based on the negative electrode.

Carbon nanotubes (CNTs) are dispersed and mixed in the composition for electrodes in nanoparticle size, so that the electrodes can emit electrical polarity and electrons. The carbon nanotube powder is contained 2.5% by weight based on the negative electrode.

The activated carbon powder is contained 5.5 wt% based on the negative electrode.

The potential difference appears between the positive electrode and the negative electrode according to the solid solution content of carbon nanotubes (CNT) and activated carbon powder contained in the positive electrode having an electrical positive polarity and the negative electrode having an electrical negative polarity. The amount of carbon nanotubes contained in the positive electrode is higher than that of the carbon nanotubes contained in the negative electrode (preferably at least two times), and the amount of activated carbon powder contained in the negative electrode is determined by the amount of activated carbon powder contained in the positive electrode. It is preferable to make it larger (preferably at least 2 times or more).

A composition for negative separators according to a preferred embodiment of the present invention will be described.

The polymer clay is an aromatic-aliphatic polyester resin-based polymer clay, which is contained 53.0% by weight based on the composition for the negative separator. Polymer clay uses polymer clay having nano-sized particles (particles having a size in nanometer (nm) units of 1 nm or more and less than 1 μm) in consideration of dispersibility, electrical properties, and the like.

The calcium chloride powder is to be contained 30.0% by weight based on the composition for the negative separator.

The carbon nanotube (CNT) powder may be contained in an amount of 1.0 wt% based on the composition of the negative separator with respect to the composition of the negative separator.

The activated carbon powder is to be contained 8.0% by weight relative to the negative separator composition.

Poly stearate is used as a thickener of the negative separator composition. Poly stearate improves workability by increasing the viscosity of the composition for separators. The poly stearate is 4.0 wt% based on the composition for the negative separator.

Purified Carrageenan is used as a negative separator gelling stabilizer. The purified carrageenan is to be contained 4.0% by weight based on the composition for the negative separator.

A composition for a separator of a quantity according to a preferred embodiment of the present invention will be described.

The polymer clay is an aromatic-aliphatic polyester resin-based polymer clay, which contains 53.0% by weight of the composition for the separator.

The calcium chloride powder is to be contained 30.0% by weight based on the amount of the composition for the separator.

The carbon nanotube (CNT) powder is contained in an amount of 8.0% by weight based on the amount of the composition for the separator.

The activated carbon powder is contained in an amount of 1.0% by weight based on the amount of the composition for the separator.

Poly stearate is used as a thickener in the composition for positive separators. Poly stearate improves workability by increasing the viscosity of the composition for separators. The poly stearate is contained in an amount of 4.0% by weight based on the amount of the composition for the separator.

Purified Carrageenan is used as a gelling stabilizer of the composition for positive separators. The purified carrageenan is contained in an amount of 4.0% by weight based on the amount of the composition for separator.

Positive and negative separators according to the solid solution content of carbon nanotubes (CNT) and activated carbon powder contained in the positive and negative separators having an electrical polarity A potential difference will appear between the negative separators. The amount of carbon nanotubes contained in the positive separator is higher than the content of carbon nanotubes contained in the negative separator (preferably at least 4 times higher), and the amount of activated carbon powder contained in the negative separator is positive. It is preferable to increase the amount (preferably at least 4 times or more) relative to the content of the activated carbon powder contained in the.

On the other hand, between the positive electrode and the negative separator according to the solid solution content of carbon nanotube (CNT) and activated carbon powder contained in the positive electrode having an electrical positive polarity and the negative separator having an electrical negative polarity The potential difference will appear. The amount of carbon nanotubes contained in the positive electrode is higher than the content of carbon nanotubes contained in the negative separator (preferably at least two times), and the amount of activated carbon powder contained in the negative separator is higher than that of the activated carbon contained in the positive electrode. It is preferable to make it large (preferably at least 2 times or more) with respect to powder content.

In addition, between the negative electrode and the positive separator according to the solid solution content of carbon nanotube (CNT) and activated carbon powder contained in the negative electrode having an electrical negative polarity and the positive positive polarity The potential difference will appear. The amount of carbon nanotubes contained in the positive separator is higher than the content of carbon nanotubes contained in the negative electrode (preferably at least two times), and the amount of activated carbon powder contained in the positive separator is higher than that of the activated carbon contained in the positive separator. It is preferable to make it large (preferably at least 2 times or more) with respect to powder content.

Composition for positive electrode having electrical positive polarity, composition for negative separator having electrical negative polarity, composition for positive separator having electrical positive polarity and polarity of electrical negative The composition for negative electrodes having a shape was molded to have a predetermined size (20 mm x 20 mm) and a thickness (2 mm), respectively. Composition for positive electrode having positive polarity, composition for negative separator having electrical negative polarity, composition for positive separator having electrical positive polarity, and electrical negative The negative electrode composition having the polarity was sequentially laminated, and then bonded to prepare a film. At this time, the bonding was used a roller press, the pressure of the roller press was about 100ton / ㎡. The drying process was performed for 2 hours at a temperature of 60 ℃ to complete the polymer battery.

As a result of measuring the voltage and current of the manufactured polymer battery (the value of the voltage and current of the battery is proportional to the unit area), the voltage was 1.09 V and the current was 5.95 mA, and the polymer battery was As a result of confirming whether the power is applied by applying it was confirmed that the power is turned on (see Fig. 8).

The polymer battery manufactured as described above may be used as a piezoelectric element in which electrical polarization occurs in the battery when vibration or pressure is applied. When a mechanical force is applied to the polymer battery of the present invention, a piezoelectric phenomenon occurs in which stress is generated inside and electric polarization occurs in the material. Accordingly, the polymer battery of the present invention is a piezoelectric element that is an energy conversion element that converts mechanical energy into electrical energy, thereby obtaining necessary power from vibration, pressure, and the like. It is expected to be able to replace or supplement secondary cells or fuel cells.

As mentioned above, although preferred embodiment of this invention was described in detail, this invention is not limited to the said embodiment, A various deformation | transformation by a person of ordinary skill in the art within the scope of the technical idea of this invention is carried out. This is possible.

1 is a view showing a chain structure of a general polymer and an expanded polymer molecule.

2 is a view schematically showing a chain structure of the electrode composition according to the present invention.

3 is a view showing a laminated structure of a polymer battery according to an embodiment of the present invention.

4 is a view illustrating a device structure in which insulating layers are formed on both electrodes of a polymer battery according to an exemplary embodiment of the present invention.

5 is a view showing a laminated structure of a polymer battery according to another embodiment of the present invention.

6 is a diagram illustrating a device structure in which insulating layers are formed on both surfaces of an electrode of a polymer battery according to another exemplary embodiment of the present invention.

7 is a view showing the potential difference and the electron transfer phenomenon of the polymer battery according to the present invention.

8 is a photograph showing a state in which the power of the electronic calculator is turned on using the polymer battery of the present invention including a positive electrode, a negative separator, a positive separator, and a negative electrode.

Claims (34)

In the composition for electrodes which form the electrode of a polymer battery, Polymers to provide a framework for the chain structure; A softened polymer which is combined with the polymer to impart flexibility to the polymer; A polymer swelling agent for expanding the polymer, the soft polymer or a compound of the polymer and the soft polymer; Carbon nanotube powder serving as an electrode active material for imparting electrical conductivity; And A composition for an electrode of a polymer battery comprising activated carbon powder that acts as an electrode active material to impart electrical conductivity while inducing covalent bonds between materials in the electrode. According to claim 1, wherein the electrode composition of the polymer battery is a composition for the electrode constituting a positive electrode, the polymer is contained 25.0 to 75.0% by weight, the soft polymer is contained 4.0 to 40.0% by weight, the polymer expanding agent is 0.5 It is contained -15.0% by weight, 0.5-15.0% by weight of the carbon nanotube powder is contained, 0.2 to 8.0% by weight of the activated carbon powder is a composition for electrodes of a polymer battery. According to claim 1, wherein the electrode composition of the polymer battery is a composition for the electrode constituting a negative electrode, the polymer is contained 25.0 to 75.0% by weight, the soft polymer is contained 4.0 to 40.0% by weight, the polymer expanding agent is 0.5 It is contained -15.0 weight%, 0.2-8.0 weight% of the said carbon nanotube powders, The said activated carbon powder contains 0.5-15.0 weight%, The composition for electrodes of a polymer battery. The polymer according to any one of claims 1 to 3, wherein the polymer is Polyamide, modified polyphenylene ether, polyphenylene sulfide, polyarylate, polyimide, polyetherimide, polyamideimide, polybenzoimidazole, polybenzookizazole, polyether ether ketone, polycyclohexanedimethylene tere Phthalates, polycarbonates, polymethylmethacrylates, methylstyrenes, polystyrenes, acrylonitrile-butadiene-styrenes, styrene-butadiene copolymers, polyvinyl chloride, polymethylpentene, cyclic polyolefins, fluorine-based polyesters, polyethylene naphthas A polymer battery comprising at least one material selected from the group consisting of latex, polylactic acid, thermoplastic polyimide, thermoplastic polystyrene, thermoplastic polyvinyl chloride, thermoplastic polyamide, thermoplastic polyurethane, thermoplastic olefin elastomer and thermoplastic polyester elastomer The composition for electrode. The polymer according to any one of claims 1 to 3, wherein the polymer is Polythiophene, polyaniline, polyacetylene, polypyrrole, polyphenylene, polyphenylenevinylene, polyfluorene, polyisocyanaphthalene, polyethylene dioxythiophene, poly (2,5-dialkoxy) paraphenylenevinylene, poly The composition for electrodes of a polymer battery, characterized in that at least one conductive polymer selected from paraphenylene and polyheptadiene. The soft polymer according to any one of claims 1 to 3, wherein A composition for an electrode of a polymer battery, comprising at least one material selected from benzocyclobutane, polyvinylphenol, polyvinyl alcohol, parylene, polyvinylidene fluoride, cyanoethyl pullulan, and novolak resin. The polymer battery electrode according to any one of claims 1 to 3, further comprising a thickener for viscosity control, wherein the thickener is 0.5 to 15.0 wt% and is made of polystearate. Composition. The method according to any one of claims 1 to 3, wherein the polymer expanding agent, A composition for an electrode of a polymer battery, comprising at least one material selected from lecithin, fluoromethane, chlorofluoromethane, fluoroethane, fluoroethane, fluoropropane and fluorobutane. In the composition for a separator which is inserted between the electrodes of a polymer battery, and forms a separator, Polymer clay to provide a framework of chain structure; Calcium chloride powder bonded to the polymer clay; Carbon nanotube powder serving as a conductive agent in the separator; Activated carbon powder which acts as a conductive agent while inducing covalent bonds between materials in the composition for the separator; And The composition for separators of polymer batteries containing carrageenan used as a gelling stabilizer. The method of claim 9, wherein the separator composition is a material for forming a negative separator having an electrical negative polarity, the polymer clay is contained in 25.0 to 75.0% by weight, the calcium chloride powder is contained in 5.0 to 40.0% by weight And 0.1 to 5.0% by weight of the carbon nanotube powder, 1.0 to 25.0% by weight of the activated carbon powder, and 0.5 to 15.0% by weight of the carrageenan. 10. The method of claim 9, wherein the separator composition is a material for forming a positive separator having an electrical polarity, the polymer clay is contained in 25.0 to 75.0% by weight, the calcium chloride powder is contained in 5.0 to 40.0% by weight And 1.0 to 25.0% by weight of the carbon nanotube powder, 1.0 to 5.0% by weight of the activated carbon powder, and 0.5 to 15.0% by weight of the carrageenan. The polymer battery separator according to any one of claims 9 to 11, further comprising a thickener for viscosity control, wherein the thickener is 0.5 to 15.0 wt% and is made of polystearate. Composition. In the polymer battery comprising a positive electrode and a negative electrode provided to face the positive electrode, The positive electrode and the negative electrode may include a polymer for providing a framework of a chain structure, a softened polymer which combines with the polymer to give flexibility to the polymer, and the polymer, the soft polymer, or a compound of the polymer and the soft polymer. A polymer swelling agent for swelling the carbon dioxide, a carbon nanotube powder acting as an electrode active material for imparting electrical conductivity, and an activated carbon powder for acting as an electrode active material for imparting electrical conductivity while inducing covalent bonding between materials in the electrode, The amount of carbon nanotube powder contained in the positive electrode is higher than that of the carbon nanotube powder contained in the negative electrode, and the amount of activated carbon powder contained in the negative electrode is higher than that of the activated carbon powder contained in the positive electrode. A polymer battery characterized by the above-mentioned. In a polymer battery having a structure in which a positive electrode, a negative separator, a positive separator and a negative electrode are sequentially stacked, The positive electrode and the negative electrode may include a polymer for providing a framework of a chain structure, a softened polymer which combines with the polymer to give flexibility to the polymer, and the polymer, the soft polymer, or a compound of the polymer and the soft polymer. A polymer swelling agent for swelling, a carbon nanotube powder serving as an electrode active material for imparting electrical conductivity, and an activated carbon powder for acting as an electrode active material for imparting electrical conductivity while inducing covalent bonding between materials in the electrode, The negative separator and the positive separator include a polymer clay for providing a framework of a chain structure, calcium chloride powder bonded to the polymer clay, a carbon nanotube powder serving as a conductive agent in the separator, and a composition for a separator. It contains activated carbon powder and carrageenan used as a gelling stabilizer to act as a conducting agent while inducing covalent bonds between the substances in the The content of the carbon nanotube powder contained in the positive electrode is higher than that of the carbon nanotube powder contained in the negative electrode, and the content of the activated carbon powder contained in the negative electrode is higher than that of the activated carbon powder contained in the positive electrode, The amount of carbon nanotubes contained in the positive separator is higher than that of the carbon nanotubes contained in the negative separator, and the amount of activated carbon powder contained in the negative separator is activated carbon powder contained in the positive separator. Polymer battery, characterized in that more than the amount of. 15. The method of claim 14, wherein the amount of carbon nanotubes contained in the positive electrode is higher than the amount of carbon nanotubes contained in the negative separator, and the amount of activated carbon powder contained in the negative separator is contained in the positive electrode. A polymer battery, characterized in that more than the amount of activated carbon powder. 15. The method of claim 14, wherein the amount of carbon nanotubes contained in the positive separator is higher than the content of carbon nanotubes contained in the negative electrode, and the amount of activated carbon powder contained in the negative electrode is contained in the positive separator. A polymer battery, characterized in that more than the amount of activated carbon powder. 15. The method according to claim 13 or 14, wherein the positive electrode contains 0.5 to 15.0 wt% of the carbon nanotube powder, the activated carbon powder contains 0.2 to 8.0 wt%, and the carbon nanotube powder is 0.2 to 8.0 on the negative electrode The polymer battery, characterized in that contained by weight to 0.5% by weight to 0.5% by weight. The method according to claim 13 or 14, wherein the positive electrode and the negative electrode, the polymer is contained 25.0 to 75.0% by weight, the softening polymer is contained 4.0 to 40.0% by weight and the polymer swelling agent is contained 0.5 to 15.0% by weight A polymer battery characterized by the above-mentioned. 15. The method according to claim 14, wherein the negative separator contains 0.1 to 5.0% by weight of the carbon nanotube powder, the activated carbon powder contains 1.0 to 25.0% by weight, and the positive separator contains 1.0 to 25.0. A polymer battery, characterized in that contained by weight 1.0% to 5.0% by weight of the activated carbon powder. 15. The method of claim 13 or 14, wherein the positive electrode and the negative electrode further comprises a thickening agent for viscosity control, the thickener is contained in the positive electrode and the negative electrode 0.5 to 15.0% by weight, characterized in that made of polystearate Polymer battery. 15. The method of claim 14, wherein the negative separator and the positive separator further comprises a thickener for viscosity adjustment, the thickener is contained in the positive electrode and the negative electrode 0.5 to 15.0% by weight and is made of polystearate Polymer battery. The method of claim 13 or 14, wherein the polymer, Polyamide, modified polyphenylene ether, polyphenylene sulfide, polyarylate, polyimide, polyetherimide, polyamideimide, polybenzoimidazole, polybenzookizazole, polyether ether ketone, polycyclohexanedimethylene tere Phthalates, polycarbonates, polymethylmethacrylates, methylstyrenes, polystyrenes, acrylonitrile-butadiene-styrenes, styrene-butadiene copolymers, polyvinyl chloride, polymethylpentene, cyclic polyolefins, fluorine-based polyesters, polyethylene naphthas A polymer battery comprising at least one material selected from the group consisting of latex, polylactic acid, thermoplastic polyimide, thermoplastic polystyrene, thermoplastic polyvinyl chloride, thermoplastic polyamide, thermoplastic polyurethane, thermoplastic olefin elastomer and thermoplastic polyester elastomer . The method of claim 13 or 14, wherein the polymer, Polythiophene, polyaniline, polyacetylene, polypyrrole, polyphenylene, polyphenylenevinylene, polyfluorene, polyisocyanaphthalene, polyethylene dioxythiophene, poly (2,5-dialkoxy) paraphenylenevinylene, poly At least one conductive polymer selected from paraphenylene and polyheptadiene. The method according to claim 13 or 14, wherein the soft polymer, A polymer battery comprising at least one material selected from benzocyclobutane, polyvinylphenol, polyvinyl alcohol, parylene, polyvinylidene fluoride, cyanoethyl pullulan, and novolak resin. A polymer and a softened polymer are added to a solvent, and a polymer expanding agent is added to the blended composition, followed by mixing to expand the polymer, the softened polymer, or the compound of the polymer and the softened polymer, and carbon nanotube powder and activated carbon powder. Preparing a composition for a positive electrode by mixing; A polymer and a softened polymer are added to a solvent, and a polymer expanding agent is added to the blended composition, followed by mixing to expand the polymer, the softened polymer, or the compound of the polymer and the softened polymer, and carbon nanotube powder and activated carbon powder. Preparing a composition for a negative electrode by mixing; Molding the positive electrode composition and the negative electrode composition to have a predetermined size and thickness; And Comprising the molded composition for the positive electrode and the composition for the negative electrode facing each other and bonded using a roller press to form a thin film or film, and then dried to obtain a polymer battery, The amount of carbon nanotube powder contained in the positive electrode is blended more than that of the carbon nanotube powder contained in the negative electrode, and the amount of activated carbon powder contained in the negative electrode is higher than that of the activated carbon powder contained in the positive electrode. A method for producing a polymer battery, characterized by blending a lot. A polymer and a softened polymer are added to a solvent, and a polymer expanding agent is added to the blended composition, followed by mixing to expand the polymer, the softened polymer, or the compound of the polymer and the softened polymer, and carbon nanotube powder and activated carbon powder. Preparing a composition for a positive electrode by mixing; Blending polymer clay and calcium chloride powder, adding carbon nanotube powder and activated carbon powder to the blended composition, and mixing carrageenan to prepare a composition for a negative separator; Mixing the polymer clay and the calcium chloride powder, adding carbon nanotube powder and activated carbon powder to the blended composition, and mixing carrageenan to prepare a composition for a positive separator; A polymer and a softened polymer are added to a solvent, and a polymer expanding agent is added to the blended composition, followed by mixing to expand the polymer, the softened polymer, or the compound of the polymer and the softened polymer, and carbon nanotube powder and activated carbon powder. Preparing a composition for a negative electrode by mixing; Forming the positive electrode composition, the negative separator composition, the positive separator composition, and the negative electrode composition to have a predetermined size and thickness; And The molded positive electrode composition, the negative separator composition, the positive separator composition, and the negative electrode composition were sequentially laminated and bonded using a roller press to be manufactured in the form of a thin film or a film, and then dried to form a polymer battery. Including obtaining The amount of carbon nanotube powder contained in the positive electrode is blended more than that of the carbon nanotube powder contained in the negative electrode, and the amount of activated carbon powder contained in the negative electrode is higher than that of the activated carbon powder contained in the positive electrode. Mixes a lot, The amount of carbon nanotubes contained in the positive separator is higher than that of the carbon nanotubes contained in the negative separator, and the amount of activated carbon powder contained in the negative separator is contained in the positive separator. A method for producing a polymer battery, characterized in that blended more than the content of activated carbon powder. 27. The method according to claim 25 or 26, wherein the positive electrode contains 0.5 to 15.0 wt% of the carbon nanotube powder, the activated carbon powder contains 0.2 to 8.0 wt%, and the carbon nanotube powder contains 0.2 to 8.0 A method for producing a polymer battery, characterized in that the mixture is contained in an amount of 0.5% by weight to 15.0% by weight. 27. The method according to claim 25 or 26, wherein the positive electrode and the negative electrode contain 25.0 to 75.0 wt% of the polymer, 4.0 to 40.0 wt% of the softening polymer, and 0.5 to 15.0 wt% of the polymer swelling agent. Method for producing a polymer battery, characterized in that. 27. The carbon nanotube of claim 25 or 26, wherein the negative separator contains 0.1 to 5.0% by weight of the carbon nanotube powder, and the activated carbon powder contains 1.0 to 25.0% by weight. A method for producing a polymer battery, characterized in that the powder is contained in an amount of 1.0 to 25.0% by weight and the activated carbon powder is contained in an amount of 1.0 to 5.0% by weight. 27. The method of claim 25 or 26, wherein in the step of preparing the composition for the positive electrode and the composition for the negative electrode, further comprising the step of adding a thickening agent for viscosity control to the blended composition, wherein the thickener is A method for producing a polymer battery, comprising 0.5 to 15.0% by weight of a positive electrode and a negative electrode and made of polystearate. 27. The method of claim 26, further comprising adding a thickening agent for viscosity control to the blended composition in the step of preparing the negative separator composition and the positive separator composition, wherein the thickener is the positive electrode And 0.5 to 15.0 wt% in the negative electrode and made of polystearate. The method of claim 25 or 26, wherein as the polymer, Polyamide, modified polyphenylene ether, polyphenylene sulfide, polyarylate, polyimide, polyetherimide, polyamideimide, polybenzoimidazole, polybenzookizazole, polyether ether ketone, polycyclohexanedimethylene tere Phthalates, polycarbonates, polymethylmethacrylates, methylstyrenes, polystyrenes, acrylonitrile-butadiene-styrenes, styrene-butadiene copolymers, polyvinyl chloride, polymethylpentene, cyclic polyolefins, fluorine-based polyesters, polyethylene naphthas At least one material selected from the group consisting of latex, polylactic acid, thermoplastic polyimide, thermoplastic polystyrene, thermoplastic polyvinyl chloride, thermoplastic polyamide, thermoplastic polyurethane, thermoplastic olefin elastomer, and thermoplastic polyester elastomer Method. The method of claim 25 or 26, wherein as the polymer, Polythiophene, polyaniline, polyacetylene, polypyrrole, polyphenylene, polyphenylenevinylene, polyfluorene, polyisocyanaphthalene, polyethylene dioxythiophene, poly (2,5-dialkoxy) paraphenylenevinylene, poly A method for producing a polymer battery, comprising using at least one conductive polymer selected from paraphenylene and polyheptadiene. The method of claim 25 or 26, wherein the softening polymer, A method for producing a polymer battery, comprising using at least one material selected from benzocyclobutane, polyvinylphenol, polyvinyl alcohol, parylene, polyvinylidene fluoride, cyanoethyl pullulan, and novolak resin.

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