KR20100057182A - Acrylic copolymer, method for preparing the same and vinyl chloride resin composition containing the same - Google Patents

Abstract

PURPOSE: A method for manufacturing an acrylic copolymer is provided to obtain excellent reactivity, latex stability, and polymerization conversion rate and to manufacture the acrylic copolymer having high molecular weight and superior dispersibility. CONSTITUTION: A method for manufacturing an acrylic copolymer includes an emulsion polymerization step polymerizing monomer mixture 100.0 parts by weight and dispersing agent 0.05-0.5 parts by weight. The monomer mixture comprises methyl methacrylate 60-95 weight% and a compound 5-40 weight% which is selected from a group of alkyl acrylate and alkyl methacrylate having 2-18 carbons of alkyl group.

Description

ACRYLIC COPOLYMER, METHOD FOR PREPARING THE SAME AND VINYL CHLORIDE RESIN COMPOSITION CONTAINING THE SAME}

The present invention relates to an acrylic copolymer, a method for preparing the same, and a vinyl chloride resin composition including the same. More specifically, the reactivity, latex stability, and polymerization conversion are excellent, and the acrylic copolymer prepared has excellent molecular weight and dispersibility. The present invention relates to a method for producing an acrylic copolymer having excellent processability, appearance characteristics and foaming characteristics when applied to a vinyl chloride resin as a processing aid.

Vinyl chloride-based resin is a polymer containing 50% or more vinyl chloride units, economical, easy to control the hardness, can be processed under a variety of conditions are widely used in many fields.

Foaming molding can reduce the manufacturing cost and lighten the plastic product, but the foamed molded article of the vinyl chloride-based resin is poor in appearance due to the generation of undispersed molten melt during processing, the foaming cell is small and uneven, the foaming problem is low. have.

U.S. Patent No. 4,052,482 discloses a method of blending a copolymer in which methyl methacrylate monomer is the main component of vinyl chloride resin, but there is a problem that the effect of suppressing the generation of undispersed melt during processing is not sufficient.

U.S. Patent No. 5,541,256 discloses a method of incorporating a modifier prepared by including a crosslinkable monomer in a vinyl chloride resin, but the effect of suppressing the generation of undispersed molten melt during processing is insufficient, elongation and tensile properties are reduced. There is a problem.

U.S. Patent No. 6,140,417 discloses a method of blending a butyl acrylate-methyl methacrylate copolymer with vinyl chloride resin, but the uniformity of the foaming cells is somewhat insufficient, and there is a problem of undispersed melt during processing. .

Therefore, there is a need to develop a processing aid that can suppress the generation of undispersed molten melt and express excellent foaming characteristics during the molding processing of vinyl chloride resin.

In order to solve the problems of the prior art as described above, the present invention is excellent in reactivity, latex stability and polymerization conversion, the acrylic copolymer produced is excellent in molecular weight and dispersibility, and processability, appearance when applied as a processing aid to vinyl chloride resin An object of the present invention is to provide a method for producing an acrylic copolymer having excellent properties and foaming properties, an acrylic copolymer produced therefrom, and a vinyl chloride resin composition comprising the acrylic copolymer as a processing aid.

The above and other objects of the present invention can be achieved by the present invention described below.

In order to achieve the above object, the present invention provides a method for producing an acrylic copolymer, a) i) 60 to 95% by weight of methyl methacrylate and ii) alkyl methacrylate having 2 to 18 carbon atoms of alkyl acrylate and alkyl group. 100 parts by weight of a monomer mixture consisting of 5 to 40% by weight of at least one selected from the group consisting of acrylates; And b) at least one dispersant selected from the group consisting of cellulose dispersants, partially saponified EVA resins, gelatin, acrylates, acrylate copolymers, polyethylene glycols, polyvinyl pyrrolidones and maleic anhydride-styrene copolymers. Parts by weight; It provides a vinyl chloride-based resin composition comprising a method for producing an acrylic copolymer, an acrylic copolymer prepared therefrom and the acrylic copolymer as a processing aid, comprising the step of emulsion polymerization.

As described above, according to the present invention, the reactivity, the latex stability and the polymerization conversion rate are excellent, and the prepared acrylic copolymer has excellent molecular weight and dispersibility, and when applied to the vinyl chloride resin as a processing aid, processability, appearance characteristics and foaming There exists an effect which provides the manufacturing method of an acryl-type copolymer excellent in the characteristic, etc.

Hereinafter, the present invention will be described in detail.

The method for producing an acrylic copolymer of the present invention is a method for producing an acrylic copolymer, which comprises a) i) 60 to 95 wt% of methyl methacrylate and ii) alkyl methacrylate having 2 to 18 carbon atoms of the alkyl acrylate and the alkyl group. 100 parts by weight of a monomer mixture consisting of 5 to 40% by weight of at least one selected from the group consisting of late rates; And b) at least one dispersant selected from the group consisting of cellulose dispersants, partially saponified EVA resins, gelatin, acrylates, acrylate copolymers, polyethylene glycols, polyvinyl pyrrolidones and maleic anhydride-styrene copolymers. Parts by weight; Emulsification polymerization, including; characterized in that comprises a.

The methyl methacrylate is preferably included in 60 to 95% by weight based on the total weight of the monomer mixture, the acrylic copolymer prepared within this range is excellent compatibility with the vinyl chloride-based resin to improve processability, Excellent acidity has the effect of reducing the occurrence of undispersed melt.

The alkyl acrylate may be an alkyl group having 1 to 18 carbon atoms, preferably methyl acrylate, ethyl acrylate, n-butyl acrylate, lauryl acrylate, stearyl acrylate, 2-ethylhexyl acrylic It may be at least one selected from the group consisting of a rate and cyclohexyl acrylate.

The alkyl methacrylate is n-butyl methacrylate, lauryl methacrylate, stearyl methacrylate, tridecyl methacrylate, i-butyl methacrylate, t-butyl methacrylate, 2-ethylhexyl meta It may be preferred to be at least one selected from the group consisting of acrylates and cyclohexyl methacrylates.

The dispersant may be preferably 0.05 to 0.5 parts by weight based on 100 parts by weight of the total monomer mixture. The dispersing agent may have a role of maintaining a constant emulsion state during polymerization. Rather, the reactivity, latex stability and polymerization conversion rate are lowered when the amount is more than that, and the polyvinyl chloride-based resin composition including the prepared acrylic copolymer has a problem in that a plurality of undispersed melts are generated and foaming properties are deteriorated.

The cellulose dispersant may be prepared in a 2% cellulose dispersant aqueous solution and added to the emulsion polymerization, and the 2% cellulose dispersant aqueous solution may have a viscosity of 10 to 10,000 cps at room temperature (25 ° C.), 2 cps If less than the reactivity, latex stability and polymerization conversion rate is not improved, the effect of improving the physical properties of the acrylic copolymer and the vinyl chloride-based resin composition produced is insignificant, if it exceeds 10,000 cps polymerization conversion rate is lowered by excessive viscosity, The polyvinyl chloride resin composition including the prepared acrylic copolymer has a problem in that a large number of undispersed melts are generated and foaming properties are deteriorated.

The emulsion polymerization is not particularly limited in the case of the emulsion polymerization method that can be usually used in the production of an acrylic copolymer.

The method of preparing the acrylic copolymer may further include preparing an acrylic copolymer powder by agglomerating, dehydrating, and drying the reaction product in a latex state after the emulsion polymerization is completed.

The acrylic copolymer powder may be applied to calendering molding, extrusion molding, brow molding, injection molding, etc. as a processing aid, and expresses excellent transparency, high temperature elongation, etc. during secondary processing, and foam cells are uniform and stable during foaming. It is effective to make low density foam.

Acrylic copolymer of the present invention is characterized in that it is produced by the method for producing the acrylic copolymer.

The vinyl chloride-based resin composition of the present invention is characterized by comprising 1 to 20 parts by weight of the acrylic copolymer as 100 parts by weight of the vinyl chloride-based resin and processing aid.

The acrylic copolymer is preferably included in an amount of 1 to 20 parts by weight based on 100 parts by weight of the vinyl chloride resin, and within this range, secondary processability such as transparency and high temperature elongation without affecting the intrinsic properties of the vinyl chloride resin. It is excellent in improving the gelation in the melting process and reducing the occurrence of undispersed melt and flow traces, and at the same time, it is effective in satisfying the foaming characteristics such as foaming ratio and stability of the foaming cell in extrusion foaming.

The vinyl chloride resin composition may further include at least one selected from the group consisting of a heat stabilizer, a lubricant, a processing aid, an impact modifier, a plasticizer, a UV stabilizer, a flame retardant, a colorant, a filler, and the like.

Hereinafter, preferred examples are provided to aid the understanding of the present invention, but the following examples are merely for exemplifying the present invention, and it will be apparent to those skilled in the art that various changes and modifications can be made within the scope and spirit of the present invention. It is natural that such variations and modifications fall within the scope of the appended claims.

EXAMPLE

Example 1

<Production of Acrylic Copolymer>

In a 3-liter four-necked flask reactor equipped with a stirrer, thermometer, nitrogen inlet, and circulation condenser, 232 g of ion-exchanged water, 37.5 g of 8% aqueous potassium salt solution, and 2% aqueous hydroxy propyl methyl cellulose solution having a viscosity of 1000 cps 10 g and 200 g of a monomer mixture of methyl methacrylate and butyl acrylate in a ratio of 85:15 were added to prepare an emulsion.Then, the reactor was maintained at 45 ° C. and replaced with a nitrogen atmosphere. The first batch reaction was carried out by adding 0.07 g of t-butyl hydroperoxide (10% diluent) solution and 6.5 g of 4% activator.

The activation solution is 0.017 g of dixodium ehtylenediaminetetraacetate (EDTA), 0.04 g of formaldehyde sodium sulfoxylate (SFS), 0.001 g of ferrous sulfate, and 1.392 g of ion-exchanged water. It is made up of a ratio of.

After completion of the first batch reaction, the mixture was stirred at the same temperature (45 ° C.) for 1 hour, and then the internal temperature of the reactor was adjusted to 45 ° C., where 232 g of ion-exchanged water and an aqueous solution of 8% fatty acid potassium salt were added. g, 10 g of hydroxy propyl methyl cellulose 2% aqueous solution having a viscosity of 1000 cps, and 200 g of a monomer mixture of methyl methacrylate and butyl acrylate in a ratio of 85:15 were added to prepare an emulsion, followed by The internal temperature was maintained at 45 ° C. and replaced with a nitrogen atmosphere, followed by addition of 0.07 g of t-butyl hydroperoxide (10% diluent) and 6.5 g of the same activation solution as used in the first batch reaction to carry out the second batch reaction. It was.

After completion of the second batch reaction, the mixture was further stirred for 1.5 hours, and then the internal temperature of the reactor was adjusted to 45 ° C., where 232 g of ion-exchanged water, 37.5 g of an aqueous 8% fatty acid potassium salt solution, and a viscosity of 1000 cps were used. An emulsion was prepared by adding 10 g of hydroxypropyl methyl cellulose 2% aqueous solution and 200 g of a monomer mixture of methyl methacrylate and butyl acrylate in a ratio of 85:15, and then maintaining the internal temperature of the reactor at 45 ° C After substitution with nitrogen atmosphere, tertiary batch reaction was performed by adding 0.07 g of t-butyl hydroperoxide (10% diluent) and 6.5 g of the same activating solution as used in the first batch reaction.

After completion of the third batch reaction, the prepared acrylic copolymer latex was further stirred for 1 hour, and then spray dried to prepare a powdery acrylic copolymer.

<Production of Vinyl Chloride-Based Resin Composition>

100 g of vinyl chloride-based resin (LS080, manufactured by LG Chemical) 6.4 g of composite stabilizer KD-105 (compound thermal stabilizer and foam stabilizer, which is a uniform mixture of thermal stabilizer and lubricant), filler (CaCO ₃ ) 14 g, 5 g of the powdery acrylic copolymer and 0.8 g of azodicarbonamide were mixed and kneaded while heating up to 115 ° C. using a Henschel mixer to prepare a vinyl chloride resin composition.

Example 2

In Example 1, the same procedure as in Example 1 was performed except that 5 g of hydroxy propyl methyl cellulose 2% aqueous solution having a viscosity of 1000 cps was used during the first to third batch reactions.

Example 3

In Example 1, the same procedure as in Example 1 was performed except that 50 g of hydroxypropyl methyl cellulose 2% aqueous solution having a viscosity of 1000 cps was used in the first to third batch reactions.

Example 4

Example 1 was carried out in the same manner as in Example 1 except that the monomer mixture of methyl methacrylate and butyl acrylate in a ratio of 80:20 was used in the first to third batch reactions.

Example 5

In Example 4, the same procedure as in Example 4 was performed except that 5 g of hydroxypropyl methyl cellulose 2% aqueous solution having a viscosity of 1000 cps was used in the first to third batch reactions.

Example 6

In Example 4, 50 g of hydroxy propyl methyl cellulose 2% aqueous solution having a viscosity of 1000 cps was used in the first to third batch reactions in the same manner as in Example 4.

Example 7

Except for adjusting the reaction temperature to 40 ℃ in the first to third batch reaction in Example 4 was carried out in the same manner as in Example 4.

Example 8

The same procedure as in Example 4 was conducted except that 25 g of an aqueous 8% fatty acid potassium salt solution was used in the first to third batch reactions in Example 4.

Example 9

In Example 4, the same procedure as in Example 4 was performed except that a 2% aqueous solution of hydroxy propyl methyl cellulose having a viscosity of 10 cps was used in the first to third batch reactions.

Example 10

In Example 4, the same procedure as in Example 4 was performed except that a 2% aqueous solution of hydroxy propyl methyl cellulose having a viscosity of 10000 cps was used during the first to third batch reactions.

Comparative Example 1

In Example 1, the same procedure as in Example 1 was performed except that 2% aqueous solution of hydroxypropyl methyl cellulose was not used in the first to third batch reactions.

Comparative Example 2

In Example 4, except that 2% aqueous hydroxypropyl methyl cellulose solution was not used in the first to third batch reactions, the same procedure as in Example 4 was performed.

Comparative Example 3

In Example 4, the same procedure as in Example 4 was performed except that 4 g of hydroxypropyl methyl cellulose 2% aqueous solution having a viscosity of 1000 cps was used in the first to third batch reactions.

Comparative Example 4

In Example 4, the same procedure as in Example 4 was performed except that 55 g of hydroxy propyl methyl cellulose 2% aqueous solution having a viscosity of 1000 cps was used in the first to third batch reactions.

Comparative Example 5

In Example 4, the reaction was carried out in the same manner as in Example 4, except that the reaction temperature was adjusted to 40 ° C. without using the first to third batch reaction hydroxy propyl methyl cellulose 2% aqueous solution.

Comparative Example 6

Except for using the first to third batch reaction hydroxy propyl methyl cellulose 2% aqueous solution in Example 4, it was carried out in the same manner as in Example 4 except that 25 g of 8% fatty acid potassium salt aqueous solution was used.

Comparative Example 7

In Example 4, the same procedure as in Example 4 was performed except that a 2% aqueous solution of hydroxy propyl methyl cellulose having a viscosity of 5 cps was used in the first to third batch reactions.

Comparative Example 8

In Example 4, the same procedure as in Example 4 was performed except that a 2% aqueous solution of hydroxy propyl methyl cellulose having a viscosity of 11000 cps was used in the first to third batch reactions.

[Test Example]

The properties of the acrylic copolymer and the vinyl chloride resin composition prepared in Examples 1 to 10 and Comparative Examples 1 to 8 were measured by the following method, and the results are shown in Table 1 below.

(1) Stability of Acrylic Copolymer Latex

200 g of the prepared acrylic copolymer latex was measured using a stability meter (homomixer) to maintain the mechanical stability at 10000 rpm.

(2) Polymerization Conversion Rate of Acrylic Copolymer

The amount of the prepared powdery acrylic copolymer relative to the total monomers used in the polymerization was measured and expressed as a percentage.

(3) Weight average molecular weight of acrylic copolymer

0.03 g of the prepared powdery acrylic copolymer was dissolved in 10 ml of tetrahydrofuran (THF) for 24 hours, and then the weight average molecular weight was measured by gel permeation chromatography (Gel Permeation Cheromatography, GPC).

(4) Melting time of vinyl chloride resin composition

64 g of the prepared vinyl chloride resin composition was measured using a Brabender at a temperature of 180 ° C. and a rotational speed of 40 rpm, and the time taken from the minimum load to the maximum load was expressed as a melting time.

(5) Degree of occurrence of undispersed melt of vinyl chloride resin composition

After preparing the vinyl chloride-based resin composition without adding a filler (CaCO ₃ ) in the preparation of the vinyl chloride-based resin composition, a 20 mm single spindle extruder equipped with a T-die was used at a temperature of 180 ° C. After extracting 0.2 mm thick film at cylinder temperature and screw speed of 30 rpm, visually observe the number of undispersed melts present in the defined area of the film surface. It was evaluated as 3 points when slightly produced, 1 point when a large amount of undispersed melt was produced.

(6) Foam density of vinyl chloride resin composition

The prepared vinyl chloride resin composition was 5 mm (thickness) at a cylinder temperature of 180 ° C. and a screw speed of 30 rpm using a 30 mm single spindle extruder equipped with a rectangular slit die. The foam density of the foamed molded article obtained by cutting out a rectangular rod of 30 mm (width) and cutting it into a length of 5 mm was measured using a specific gravity measuring instrument. In this case, the higher the foaming density, the lower the foaming magnification, and the lower the foaming characteristics.

(7) Uniformity of Foam Cell of Vinyl Chloride Resin Composition

The cross section of the foamed molded article was observed with an optical microscope and evaluated as 5 points when the foaming cell was uniform, 3 points when the foaming cell was slightly uneven, and 1 point when most of the foaming cells were not uniform.

As shown in Table 1, the acrylic copolymer (Examples 1 to 10) of the present invention, which contains 0.05 to 0.5 parts by weight of hydroxy propyl methyl cellulose during polymerization, is an acrylic copolymer containing no hydroxy propyl methyl cellulose. Compared with (Comparative Examples 1, 2, 5, and 6), it was confirmed that the latex stability, polymerization conversion rate and the like were excellent.

In addition, the vinyl chloride resin composition (Examples 1 to 10) containing the acrylic copolymer of the present invention is compared with the vinyl chloride resin composition (Comparative Examples 1 to 8) containing the acrylic copolymer according to the present invention. As a result, almost no dispersed melt was found, and it was confirmed that the foaming properties (density of the foam and uniformity of the foaming cell) were excellent.

In addition, the polymerization method of the acrylic copolymer of the present invention proceeds smoothly even when the polymerization is carried out at a somewhat low polymerization temperature (Example 7) and when a small amount of fatty acid potassium salt is used (Example 8). It was confirmed that the vinyl chloride resin composition having high stability, polymerization conversion rate and molecular weight, and including the prepared acrylic copolymer, had almost no undispersed melt, and was excellent in foaming properties.

Claims (8)

A method for producing an acrylic copolymer, comprising: a) i) 60 to 95 wt% of methyl methacrylate and ii) alkyl acrylate and alkyl methacrylate having 2 to 18 carbon atoms in the alkyl group. 100 parts by weight of the monomer mixture consisting of 40% by weight; And b) at least one dispersant selected from the group consisting of cellulose dispersants, partially saponified EVA resins, gelatin, acrylates, acrylate copolymers, polyethylene glycols, polyvinyl pyrrolidones and maleic anhydride-styrene copolymers. Parts by weight; Emulsification polymerization including; Method for producing an acrylic copolymer. The method of claim 1, The alkyl acrylate is characterized in that the alkyl group has 1 to 18 carbon atoms Method for producing an acrylic copolymer. 3. The method of claim 2, The alkyl acrylate is at least one member selected from the group consisting of methyl acrylate, ethyl acrylate, n-butyl acrylate, lauryl acrylate, stearyl acrylate, 2-ethylhexyl acrylate and cyclohexyl acrylate. Characterized by Method for producing an acrylic copolymer. The method of claim 1, The alkyl methacrylate is n-butyl methacrylate, lauryl methacrylate, stearyl methacrylate, tridecyl methacrylate, i-butyl methacrylate, t-butyl methacrylate, 2-ethylhexyl At least one member selected from the group consisting of methacrylate and cyclohexyl methacrylate Method for producing an acrylic copolymer. The method of claim 1, The cellulose-based dispersant is prepared as a 2% aqueous solution of cellulose-based dispersant and added to the emulsion polymerization, wherein the aqueous 2% cellulose-based dispersant solution has a viscosity of 10 to 10,000 cps at room temperature. Method for producing an acrylic copolymer. An acrylic copolymer prepared according to any one of claims 1 to 5. 100 parts by weight of the vinyl chloride resin and a processing aid comprising 1 to 20 parts by weight of the acrylic copolymer of claim 6 Vinyl chloride-based resin composition. The method of claim 7, wherein The vinyl chloride resin composition further comprises at least one selected from the group consisting of a heat stabilizer, a lubricant, a processing aid, an impact modifier, a plasticizer, a UV stabilizer, a flame retardant, a colorant, and a filler. Vinyl chloride-based resin composition.