KR20100014087A - Antibacterial functional resin (PE, PP) film composed of node pores - Google Patents

Antibacterial functional resin (PE, PP) film composed of node pores Download PDF

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KR20100014087A
KR20100014087A KR1020090000034A KR20090000034A KR20100014087A KR 20100014087 A KR20100014087 A KR 20100014087A KR 1020090000034 A KR1020090000034 A KR 1020090000034A KR 20090000034 A KR20090000034 A KR 20090000034A KR 20100014087 A KR20100014087 A KR 20100014087A
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film
resin
silica
tourmaline
pores
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이규주
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/02Wrappers or flexible covers
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/02Ingredients treated with inorganic substances
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/16Applications used for films

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  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
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Abstract

PURPOSE: An antibacterial functional resin film containing node pores is provided to suppress alive bacteria and to prevent the generation of bacteria in packed food when packaging vegetables and food. CONSTITUTION: An antibacterial functional resin film containing node pores comprises the steps of: removing harmfulness heavy metal and foreign materials from tourmaline and then supporting silica with micropores in the tourmaline to prepare silica-coated tourmaline; coating 4-10 nm nano silver metal to 3-4 nm uniform silica film with micropores to prepare silica coated silver; mixing the silica coated tourmaline and/or silica coated silver with resin(PE,PP)(7) to prepare an antibacterial functional resin film; and forming node pores(8) on the surface of the antibacterial functional resin film.

Description

절점기공이 구성된 항균기능수지(PE,PP) 필름{omitted}Antibacterial functional resin (PE, PP) film composed of node pores {omitted}

음이온 원적외선을 방출시키고 항균, 탈취, 살균력이 있는 천연 광물질 Tourmaline에 함유되어 있는 유해중금속, 이물질을 특수 공법(Tourmaline - ① 조분쇄(Pin mill) - ② 미분쇄(disc mill) - ③ 950℃ 소성(중금속제거) ④ 산세정(중금속제거) - ⑤ 미분쇄 - ⑥ Tourmaline 분말 - ⑦ 물유리(K2SiO4) - ⑧ 유화공정 - ⑨ 중합반응(중탄산 암모늄) - ⑩ 물세정 - ⑪ 건조 - ⑫ 미분쇄 - ⑬ 완제품)으로 제거시키고 micro Pore를 갖는 Silica(SiO2)에 담지시켜 백색도를 높이고 비중을 줄이고 부피를 늘려 기능과 사용의 효율성을 높이도록 도 1과 같이 Silica Coated Tourmaline(1)으로 구성시키고, 한편The natural heavy substance that emits negative ion far infrared rays and has antibacterial, deodorant, and sterilizing power. Special heavy-duty method for the harmful heavy metals and foreign substances contained in Tourmaline (Tourmaline-① Pin mill-② Disc mill-③ 950 ℃ firing ( Heavy metal removal) ④ Acid cleaning (heavy metal removal)-⑤ Fine grinding-⑥ Tourmaline powder-⑦ Water glass (K 2 SiO 4 )-⑧ Emulsification process-⑨ Polymerization (ammonium bicarbonate)-⑩ Water washing-⑪ Drying-⑫ Fine grinding -It is composed of Silica Coated Tourmaline (1) as shown in Fig. 1 to remove the finished product) and to be loaded on Silica (SiO 2 ) with micro pores to increase whiteness, reduce specific gravity and increase volume to increase function and efficiency of use. Meanwhile

무기물을 지지체로 사용한 4-10 nm 크기의 nano Silver metal을 흡착력이 우수하여 오염원을 효율적으로 흡착할 수 있는 micro Pore를 갖는 3∼4nm의 균일한 Silica(SiO2) 막으로 Coating 시켜 Silver에 의한 항균 작용을 향상시킬 수 있도록 도 2와 같이 Silica Coated Silver(5)로 구성시킨 다음 이들 중 한가지 이상을 수지(PE,PP)(7)에 혼합시켜 통상적인 수지(PE,PP) 필름 제조 공정으로 항균기능 수지(PE,PP) 필름으로 제조시키고 제조된 수지(PE,PP) 필름에 공기가 유통되면서 이물 질과 세균을 막을 수 있는 절점기공(찢어진 선이 모인 점)(8)을 구성시켜 절점기공이 구성된 항균기능 수지(PE,PP) 필름으로 구성 제조시킨다.4-10 nm nano silver metal using inorganic material as a support has excellent adsorptivity and is coated with 3 ~ 4 nm uniform silica (SiO 2 ) film with micro pores that can adsorb pollutants efficiently. To improve the action, as shown in Figure 2 composed of Silica Coated Silver (5) and then mixed at least one of them to the resin (PE, PP) (7) to antibacterial in the conventional resin (PE, PP) film manufacturing process Nodal pores made of functional resin (PE, PP) film and made of pores (points where tear lines are gathered) (8) to prevent foreign substances and bacteria as air flows through the produced resin (PE, PP) film The composition is made of antimicrobial resin (PE, PP) film.

이때 절점기공의 찢어지는 부분은 포장내,외 공기압에 의해 미미하게 움직여저서 포장내,외 공기압에 의해 절점이 미미하게 열렸다가 닫히는 기능을 하게 되어 내장시킨 내용물의 호흡을 돕게되는 한편 필름의 항균기능에 의해 세균 유입을 막을 수 있는 장점이 있게 된다At this time, the tearing part of the nostril pore is moved slightly by the air pressure inside and outside the package so that the node opens and closes slightly due to the air pressure inside and outside the package, helping to breathe the internal contents while preventing the antibacterial function of the film. There is an advantage that can prevent the influx of bacteria

일반적으로 식품포장 용으로 사용되는 수지(PE,PP) 필름은 습기, 세균, 이물질 등 환경에 민감한 식자재 및 식품을 안전하게 포장시키기 위해 널리 채용되는 포장재로서 용기를 만들고 식품을 내장시킨 후 밀봉시키는 방법으로 사용하고 있다. 그러나 종래의 수지(PE,PP) 필름에는 항균기능이 없는 결점이 있어 수지(PE,PP) 필름을 제조하는 과정 또는 내장시킬 식품제조 과정 및 포장작업 과정에서 세균에 감열될 수도 있으므로 세균에 감염된 상태의 식품을 포장시켰을 때는 식품과 세균을 함께 포장시키는 결과가 되고, 필름에 내장된 내용물이 호흡을 필요로 하는 경우에는 수지(PE,PP) 필름에 도 8과 같이 기공을 타공(뜯어내는 공간) 방법으로 구성시켜 사용하는 경우가 있으나 이러한 방법은 기공을 통해 이물질, 세균 등이 유입될 수 있는 결점이 있다. 그러나 본 발명의 절점기공은 도 5와 같이 찢어진 선이 모인 절점으로 구성시킴으로 포장시킨 봉투내,외 공기 압력에 의해 찢어진 부분이 도 7과 같이 미미하게 열렸다 닫히는 운동을 하게 되므로 이물질 유입을 막을 수 있고 항균기능으로 세균 유입을 막을 수 있는 효과가 있게 된다.Generally, resin (PE, PP) film used for food packaging is a widely used packaging material to safely package food and foods sensitive to environment such as moisture, bacteria, and foreign substances. I use it. However, the conventional resin (PE, PP) film has a defect that does not have an antibacterial function, so it may be heat-sensitive to bacteria in the process of manufacturing the resin (PE, PP) film or food manufacturing process and packaging work to be embedded, so that the state is infected with bacteria When the food is packaged, the result is to pack the food and bacteria together. If the contents contained in the film require breathing, the resin (PE, PP) film perforates pores as shown in FIG. It may be used in a way that is configured, but this method has a drawback that foreign substances, bacteria, etc. can be introduced through the pores. However, the nostril pores of the present invention can prevent the inflow of foreign substances because the torn portion is opened and closed slightly as shown in FIG. The antibacterial function is effective in preventing bacterial influx.

본 발명은 절점이 구성된 항균기능 수지(PE,PP) 필름에 관한 것으로 음이온 원적외선이 방출되며 항균 살균력 탈취력을 갖으며 휘발성 유기화합물을 분해하는 우수한 기능을 갖고 있는 천연광물질 Tourmaline 원석에 석여있는 있는 유해중금속, 이물질을 제거시키고 micro Pore를 갖는 Silica(SiO2)에 담지시켜 백색도를 높이고 비중을 줄이고 부피를 늘려 사용의 효율성을 높이도록 Silica Coated Tourmaline으로 도 1과 같이 구성시키며,The present invention relates to an antibacterial resin (PE, PP) film composed of a node, anion far infrared ray is emitted, harmful anti-metals that are present in the natural mineral Tourmaline gemstone that has an antibacterial germicidal deodorizing power and has an excellent function of decomposing volatile organic compounds. Silica Coated Tourmaline is composed of Silica Coated Tourmaline to remove white matter and to be loaded on Silica (SiO 2 ) with micro pore to increase whiteness, reduce specific gravity and increase volume.

흡착력이 우수하여 오염원을 효율적으로 흡착할 수 있는 micro Pore를 갖는 3∼4nm의 균일한 Silica(SiO2) 막으로 무기물을 지지체로 사용하여 4∼10nm 크기의 nano Silver metal을 Coating시켜 Silver에 의한 항균작용을 향상시킬 수 있고 균일한 Silica 막으로 인해 피부에 자극이 없고 금속 산화 작용이 없고 색상변화가 없도록 Silica Coated Silver(Ag)로 도 2와 같이 구성시킨 다음 이들 중 한가지 이상을 수지(PE,PP)에 혼합시켜 통상적인 수지(PE,PP) 필름 제조 방법으로 항균기능 수지(PE,PP) 필름으로 구성 제조 시킨 다음 항균기능 수지(PE,PP) 필름에 공기를 유통시키면서 세균과 이물질을 막을 수 있는 절점기공(찢어진 선이 모인점)을 구성시킨다.It is a 3 ~ 4nm uniform Silica (SiO 2 ) membrane with micro pores that can adsorb contaminants efficiently because of its excellent adsorption power. Silica Coated Silver (Ag) is composed as shown in FIG. 2 so that the action can be improved and there is no irritation to the skin due to the uniform Silica film, no metal oxidation, and no color change, and at least one of them is made of resin (PE, PP). ), Which is composed of antimicrobial resin (PE, PP) film using conventional resin (PE, PP) film manufacturing method, and then prevents bacteria and foreign substances while circulating air in antibacterial resin (PE, PP) film. It consists of a nodal pore (a point where the torn line is collected).

이때 도 5와 같이 절점기공을 구성시킨 찢어진 선 부분은 포장 봉투 내,외 공기압에 의해 미미하게 움직이게 되어 공기유통으로 내용물이 호흡을 할 수 있게 되며, 이물질 유입은 방지되고 세균 유입은 항균기능 수지(PE,PP) 필름 항균기능에 의해 막을 수 있게 한다.At this time, the torn line portion constituting the nodal pores as shown in FIG. 5 is slightly moved by the air pressure inside and outside the packaging bag, so that the contents can breathe through the air distribution, foreign matters are prevented and bacteria inflow is antibacterial function resin ( PE, PP) film can be prevented by antibacterial function.

본 발명은 절점이 구성된 항균기능 수지(PE,PP)필름에 관한 것으로 천연 광물질로서 음이온 원적외선이 방출되고 항균, 살균력이 있고 휘발성 유기화합물을 분해하는 특징이 있는 Tourmaline 원석에 함유되어 있는 유해 중금속, 이물질을 특수공법 공정(① Tourmaline 조분쇄(Pin mill) - ② 미분쇄(disc mill) - ③ 950℃ 소성(중금속제거) - ④ 산세정(중금속제거) - ⑤ 미분쇄 - ⑥ Tourmaline 분말 - ⑦ 물유리(K2SiO4) - ⑧ 유화공정 - ⑨ 중합반응(중탄산 암모늄) - ⑩ 물세정 - ⑪ 건조 - ⑫ 미분쇄 - ⑬ 완제품)으로 제거시키고 Micro Pore를 갖는 Silica(SiO2)에 담지시켜 백색도를 높이고 비중을 줄이고 부피를 늘려 기능과 사용의 효율성을 높이도록 도 1과 같이 Silica Coated Tourmaline으로 구성시키고 한편으로The present invention relates to an antibacterial resin (PE, PP) film composed of nodes, harmful heavy metals, foreign substances contained in Tourmaline gemstones, which are characterized by the release of negative ion far infrared rays as natural minerals, antibacterial, bactericidal and decomposing volatile organic compounds. Special process (① Tourmaline coarse grinding (Pin mill)-② Disc milling-③ 950 ℃ firing (heavy metal removal)-④ Pickling (heavy metal removal)-⑤ Fine grinding-⑥ Tourmaline powder-⑦ Water glass ( K 2 SiO 4 )-⑧ emulsification process-⑨ Polymerization reaction (ammonium bicarbonate)-⑩ water washing-⑪ drying-⑫ fine pulverization-⑬ finished product) and added to Silica (SiO 2 ) with micro pores to increase whiteness Silica Coated Tourmaline as shown in Figure 1 to reduce the specific gravity and increase the volume to increase the function and efficiency of use, while

무기물을 지지체로 사용한 4-10nm 크기의 nano Silver metal을 흡착력이 우수하여 오염원을 효율적으로 흡착할 수 있는 micre Pore를 갖는 3∼4nm의 균일한 Silica막으로 Coating시켜 Silver(Ag)에 의한 항균작용을 향상시킬 수 있는 균일한 Silica(SiO2)막으로 인해 피부에 자극이 없고 금속산화에 따른 색상변화가 없도록 Silica Coated Silver(Ag)로 도 2와 같이 구성시킨 다음, 이들 중 한가지 이상을 도 3과 같은 수지(PE,PP)에 혼합시켜 통상적인 수지(PE,PP) 필름제조방법으로 항균기능 수지(PE,PP) 필림으로 구성 제조시킨 다음 절선으로 구성된 절점기공(찢어진 선이 모인점)을 수지(PE,PP) 필름 표면에 구성시켜 이물질과 세균은 차단되면서 공기압에 의해 절점 기공이 미미하게 열렸다 닫치면서 미미한 공기(산소)가 유통되도록 하여 포장된 내용물이 숨을 쉴 수 있도록 하여 절점 기공이 구성된 항균기능 수지(PE,PP) 필름으로 구성시킨다.4-10nm size nano silver metal using inorganic material as a support has excellent adsorption power and it is coated with 3 ~ 4nm uniform silica film with micre pore that can adsorb pollutants efficiently. Silica Coated Silver (Ag) is composed as shown in FIG. 2 so that there is no irritation to the skin and no color change due to metal oxidation due to the uniform Silica (SiO 2 ) film which can be improved. It is mixed with the same resin (PE, PP) and manufactured with antimicrobial resin (PE, PP) film using a conventional resin (PE, PP) film manufacturing method, and then the nodal pores composed of cutting lines It consists of (PE, PP) on the surface of the film so that foreign matter and bacteria are blocked, and the pore of the node is opened slightly by air pressure.The closed contents allow the air (oxygen) to flow and allow the packaged contents to breathe. The ball consists of antimicrobial resin (PE, PP) film.

식품의 안전성을 높이기 위해 식품 포장재로 많이 사용하는 수지(PE,PP) 필름은 식품자재 채소 및 가공식품을 포장시킬 때 외부에서 유입되는 습기, 세균, 이물질 등을 막을 수 있고 유통 및 보관 과정에서 경고하고 내용물을 눈으로 볼 수 있는 이점이 있다. 그러나 수지(PE,PP) 필름 제조과정, 용기를 만드는 과정, 식품을 만드는 과정, 식품을 포장시키는 과정에서 세균이 침투할 수도 있으며 포장된 상태에서 세균이 발생할 수도 있는 결점이 있으며 공기가 통하지 않게 밀봉시키는 관계로 숨을 쉬는 내용물은 질식하는 결점이 있다. 그러나 본 발명 절점이 구성된 항균기능 수지(PE,PP) 필름으로 식자재 채소 및 식품을 포장시킬 경우 세균이 침투하여 생존할 수 없는 장점이 있고 포장된 식품에서 세균발생을 억제시킬 수 있는 항균력이 있고, 절점기공으로 포장된 내용물이 숨을 쉴 수 있는 장점이 있어 내용물은 신선도가 유지되고 보관시간이 연장될 수 있는 효과가 있게 된다Resin (PE, PP) film, which is widely used as food packaging material to increase the safety of food, can prevent moisture, bacteria, foreign substances, etc. coming from outside when packing food materials, vegetables and processed foods, and warn during distribution and storage There is an advantage that you can see the contents. However, there is a defect that germs can penetrate in the manufacturing process of resin (PE, PP) film, container making, food making, and food packaging, and bacteria can be generated in the packaged state, and airtight sealing Breathing content is a choking defect. However, when packaging food materials vegetables and food with antimicrobial functional resin (PE, PP) film composed of the present invention, there is an advantage that bacteria can not penetrate and survive, and there is an antimicrobial activity that can suppress the occurrence of bacteria in the packaged food, The contents packed with node pores have the advantage of breathing, so the contents are kept fresh and the storage time can be extended.

본 발명은 절점기공이 구성된 항균기능 수지(PE,PP) 필름에 관한 것으로,The present invention relates to an antimicrobial resin (PE, PP) film composed of node pores,

첨부시킨 도면을 참조하여 설명하면 다음과 같다.When described with reference to the accompanying drawings as follows.

천연 광물질 Tourmaline에 함유되어 있는 유해중금속, 이물질을 도 9와 같은 특수공법공정(① Tourmaline 조분쇄 - ② 미분쇄 - ③ 950℃ 소성(중금속제거) - ④ 산세정(중금속제거) - ⑤ 미분쇄 - ⑥ Tourmaline 분말 - ⑦ 물유리(K2SiO4) - ⑧ 유화공정 - ⑨ 중합반응(중탄산 암모늄) - ⑩ 물세정 - ⑪ 건조 - ⑫ 미분쇄 - ⑬ 완제품)으로 제거시키고 micro Pore를 갖는 Silica(SiO2)에 담지시켜 백색도를 높이고, 비중을 줄이고, 부피를 늘려 기능과 사용의 효율성을 높이도록 도 1과 같이 Silica Coated Tourmaline으로 구성시키며,Natural minerals Toxic heavy metals and foreign substances contained in Tourmaline special process (① tourmaline coarse grinding-② fine grinding-③ 950 ℃ firing (heavy metal removal)-④ pickling (heavy metal removal)-⑤ fine grinding- ⑥ Tourmaline powder-⑦ Water glass (K 2 SiO 4 )-⑧ Emulsification process-⑨ Polymerization reaction (ammonium bicarbonate)-⑩ Water washing-⑪ Drying-⑫ Fine grinding-⑬ Finished product) Silica (SiO 2) ), Which is composed of Silica Coated Tourmaline as shown in FIG. 1 to increase the whiteness, reduce specific gravity, increase volume, and increase efficiency of use and function.

무기물을 지지체로 사용한 4-10nm 크기의 nano Silver metal을 흡착력이 우수하여 오염원을 효율적으로 흡착할 수 있는 micro Pore를 갖는 3-4nm의 균일한 Silica(SiO2)막으로 Coating시켜 Silver에 의한 항균 작용을 향상시킬 수 있도록 도 2와 같이 Silica Coated Silver로 구성시킨 다음 이들 중 한가지 이상을 도 3과 같은 수지(PE,PP)에 혼합시켜 통상적인 수지(PE,PP) 필름제조 공정으로 항균기능 수지(PE,PP) 필름으로 제조시키고, 제조된 수지(PE,PP) 필름에 찢어진 선이 도 5와 같이 구멍이 없는 점으로 구성되어 이물질과 세균을 막을 수 있고 공기압에 따라 찢어진 선이 모인 점 부분이 도 7과 같이 미미하게 움직이면서 미미한 공기를 유통시키게 하여 절점이 구성된 항균기능 수지(PE, PP)필름을 도 5와 같이 만들게 된다.Antimicrobial effect of silver by coating 4-10nm size nano silver metal using inorganic material as a support with 3-4nm uniform Silica (SiO 2 ) film with micro pores that can adsorb pollutants with excellent adsorptive power 2 to at least one of them mixed with a resin (PE, PP) as shown in Figure 3 to improve the antimicrobial functional resin (PE, PP) film manufacturing process PE, PP) film, and the torn lines in the resin (PE, PP) film is composed of points without holes as shown in FIG. 5 to prevent foreign substances and bacteria, and the points where the torn lines are gathered according to air pressure 7 makes the antimicrobial function resin (PE, PP) film composed of nodes by circulating the minute air while moving slightly as shown in FIG.

도 1 - Silica Coated Tourmaline 구성도Figure 1-Silica Coated Tourmaline Configuration

도 2 - Silica Coated Silver 구성Figure 2-Silica Coated Silver Configuration

도 3 - 수지(PE,PP) 도Figure 3-Resin (PE, PP)

도 4 - 항균 수지(PE,PP) 필름 단면도Figure 4-Antibacterial resin (PE, PP) film cross section

도 5 - 절점기공 구성 평면도Figure 5-Node pore composition plan

도 6 - 절점기공 제작도Figure 6-Node Pore Fabrication

도 7 - 절점기공 공기 흐름도Figure 7-Node Pore Air Flow

도 8 - 종래 타공 제작도Figure 8-conventional perforated drawing

도 9 - Tourmaline 분말 정제 공정도Figure 9-Tourmaline powder purification process diagram

도 10 - 항균 시험 성적서Figure 10-Antimicrobial Test Report

도 11 - 음이온 방출 시험 성적서11-Anion Release Test Report

도 12 - 원적외선 방사 시험 성적서Figure 12-Far infrared radiation test report

(도면의 주요 부분에 대한 기호 설명)(Symbol description for main part of drawing)

1. Silica Coated TourmalineSilica Coated Tourmaline

2. Tourmaline2. Tourmaline

3. Silica3.silica

4. Pore4. Pore

5. Silica Coated Silver5.Silica Coated Silver

6. Silver(Ag)6. Silver (Ag)

7. 수지(PE,PP)7. Resin (PE, PP)

8. 절점기공8. Node porosity

9. 수지(PE,PP) 필름9. Resin (PE, PP) Film

10. 절점기공 제조기구10. Node pore manufacturing apparatus

11. 공기 흐름 방향11. Air flow direction

12. 타공제조기구12. Other manufacturing organization

13. 타공(기공)13. Perforation (pore)

14. 타공(기공) 평면14. Perforation (pore) plane

Claims (1)

절점기공이 구성된 항균기능 수지(PE,PP) 필름에 있어 음이온 원적외선을 방출시키고 항균, 살균력, 탈취력이 있는 천연 광물질 Tourmaline 원석에 함유되어 있는 유해 중금속, 이물질을 특수공법가공(Tourmaline - ① 조분쇄 - ② 미분쇄 - ③ 950℃ 소성(중금속제거) - ④ 산세정(중금속제거) - ⑤ 미분쇄 - ⑥ Tourmaline 분말 - ⑦ 물유리(K2SiO4) - ⑧ 유화공정(suspension) - ⑨ 중합반응 - ⑩ 물세정 - ⑪ 건조 - ⑫ 미분쇄 ⑬ 완제품)으로 제거시킨 다음 micro Pore를 갖는 Silica(SiO2)에 담지시켜 백색도를 높이고, 비중을 줄이고, 부피를 늘려 기능성, 사용효율성을 높이도록 Silica Coated Tourmaline으로 구성시키며,In the antibacterial resin (PE, PP) film composed of node pores, it emits anion far infrared rays, and it is a special processing method for the harmful heavy metals and foreign substances contained in the tourmaline gemstones with antibacterial, bactericidal and deodorizing properties. ② Fine grinding-③ 950 ℃ firing (heavy metal removal)-④ pickling (heavy metal removal)-⑤ fine grinding-⑥ Tourmaline powder-⑦ water glass (K 2 SiO 4 )-⑧ emulsion-⑨ polymerization reaction- After washing with water-⑪ drying-⑫ fine pulverizing ⑬ finished product, it is loaded on Silica (SiO 2 ) with micro pores to increase whiteness, reduce specific gravity, increase volume, and increase functionality and efficiency with Silica Coated Tourmaline. Make up, 무기물을 지지체로 사용 조성시킨 4-10nm 크기의 nano Silver metal을 흡착력이 우수하여 오염원을 효율적으로 흡수할 수 있는 micro Pore를 갖는 3-4nm의 균일한 Silica 막으로 Coating 시켜 Silver(Ag)에 의한 항균작용을 향상시킬 수 있고 균일한 Silica 막으로 인해 피부에 자극이 없고 금속산화에 따른 색상변화가 없도록 Silica Coated Silver로 구성시키며 Silica Coated Tourmaline과 Silica Coated Silver 중 한가지 이상을 수지(PE,PP)에 혼합시켜 통상적인 수지(PE,PP) 필름 제조 방법으로 항균기능 수지(PE,PP) 필름으로 구성제조시킨 다음 항균기능 수지(PE,PP) 필름 표면에 미미하게 찢어진 선이 모여 구성된 절점기공을 구성시켜 미미한 공기압에 의해 절점기공(찢어진 선이 모인 점)이 미미한 여닫이 기능으로 미미한 공기 유통이 이루어 지도록 함을 특징으로 하는Antimicrobial by silver (Ag) by coating 4-10nm nano silver metal with inorganic material as a support and coating with 3-4nm uniform silica membrane with micro pores that can absorb pollutants efficiently with excellent adsorptive power It is composed of Silica Coated Silver so that it can improve the action and have no skin irritation due to the uniform Silica film and there is no color change due to metal oxidation. At least one of Silica Coated Tourmaline and Silica Coated Silver is mixed with resin (PE, PP) By using a conventional resin (PE, PP) film manufacturing method made of antimicrobial resin (PE, PP) film and then composed of finely torn lines on the surface of the antimicrobial resin (PE, PP) film It is characterized by the fact that the air gap (the point where the torn lines are gathered) is made by the slight air pressure and the airflow function is made by the slight opening function. "절점기공이 구성된 항균기능 수지(PE,PP) 필름""Anti-microbial resin (PE, PP) film composed of node pores"
KR1020090000034A 2008-07-31 2009-01-02 Antibacterial functional resin (PE, PP) film composed of node pores KR20100014087A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110479052A (en) * 2019-08-27 2019-11-22 徐玲军 A kind of anion removes the air cleaning decorative adhesive film and preparation method of formaldehyde

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110479052A (en) * 2019-08-27 2019-11-22 徐玲军 A kind of anion removes the air cleaning decorative adhesive film and preparation method of formaldehyde
CN110479052B (en) * 2019-08-27 2021-01-26 北京优氧朗芬莱环保科技有限公司 Air purification decoration film capable of removing formaldehyde through negative ions and preparation method

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