KR20100001575A - Multi-layered module of amorphous thin film solar cell - Google Patents
Multi-layered module of amorphous thin film solar cell Download PDFInfo
- Publication number
- KR20100001575A KR20100001575A KR1020080061533A KR20080061533A KR20100001575A KR 20100001575 A KR20100001575 A KR 20100001575A KR 1020080061533 A KR1020080061533 A KR 1020080061533A KR 20080061533 A KR20080061533 A KR 20080061533A KR 20100001575 A KR20100001575 A KR 20100001575A
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- South Korea
- Prior art keywords
- solar cell
- film
- thin film
- amorphous thin
- transparent plastic
- Prior art date
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- 239000010409 thin film Substances 0.000 title claims abstract description 51
- 229920003023 plastic Polymers 0.000 claims abstract description 28
- 239000002985 plastic film Substances 0.000 claims abstract description 28
- 239000005329 float glass Substances 0.000 claims abstract description 14
- 239000010408 film Substances 0.000 claims description 13
- 229910052782 aluminium Inorganic materials 0.000 claims description 12
- 229920006267 polyester film Polymers 0.000 claims description 12
- 239000011521 glass Substances 0.000 claims description 11
- 238000002834 transmittance Methods 0.000 claims description 8
- -1 polyethylene terephthalate Polymers 0.000 claims description 5
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 3
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 3
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 2
- 229920006290 polyethylene naphthalate film Polymers 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 8
- 238000012546 transfer Methods 0.000 abstract description 5
- 238000010276 construction Methods 0.000 abstract description 4
- 210000004027 cell Anatomy 0.000 description 42
- 238000000034 method Methods 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- BFMKFCLXZSUVPI-UHFFFAOYSA-N ethyl but-3-enoate Chemical compound CCOC(=O)CC=C BFMKFCLXZSUVPI-UHFFFAOYSA-N 0.000 description 2
- 210000004692 intercellular junction Anatomy 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000010248 power generation Methods 0.000 description 2
- 238000005464 sample preparation method Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000012356 Product development Methods 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/0248—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies
- H01L31/036—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by their crystalline structure or particular orientation of the crystalline planes
- H01L31/0376—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by their crystalline structure or particular orientation of the crystalline planes including amorphous semiconductors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/0445—PV modules or arrays of single PV cells including thin film solar cells, e.g. single thin film a-Si, CIS or CdTe solar cells
- H01L31/046—PV modules composed of a plurality of thin film solar cells deposited on the same substrate
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/048—Encapsulation of modules
- H01L31/0481—Encapsulation of modules characterised by the composition of the encapsulation material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Landscapes
- Engineering & Computer Science (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Electromagnetism (AREA)
- General Physics & Mathematics (AREA)
- Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Sustainable Energy (AREA)
- Laminated Bodies (AREA)
- Photovoltaic Devices (AREA)
Abstract
The present invention relates to a transmissive amorphous thin-film solar cell multilayer module, and in particular, by providing a transmissive amorphous thin-film solar cell multilayer module in which the front float glass is replaced with a transparent plastic film, the weight of the module becomes lighter, thereby facilitating handling and construction. In addition, the temperature transfer by the transparent plastic film may be faster, thereby speeding up the curing reaction of the EVA sheet, thereby improving manufacturing process efficiency.
Description
The present invention relates to an amorphous thin film solar cell module, and more particularly, to a transmissive amorphous thin film solar cell multilayer module.
Recently, research and product development for the application of the photovoltaic power generation system in the field of construction have been actively conducted.
If the solar cell module used as a building material is installed in the building in the form of a junction module without multilayering, condensation occurs due to temperature difference inside and outside. In order to prevent this, the solar cell junction module is made of a double layer module by adding an air layer (6 mm or 12 mm) to the solar cell bonding module so that the heat transmission rate is usually 2.6 to 2.7 W / ㎡ ℃ value.
An example of a conventional transmissive amorphous thin film solar cell multilayer module has a structure as shown in FIG. 1, and a method of manufacturing the transmissive thin film amorphous solar cell including a transparent conductive film glass (TCO glass) and an amorphous thin film deposited on glass ( 11), the EVA sheet (Ethyl Vinyl Acetate sheet) 12 and the front float glass (13) are sequentially bonded (laminated) to form a transmissive amorphous solar
At this time, the transfer rate of the temperature applied to the
In addition, the
The present invention is excellent in bonding to the EVA sheet, the heat transfer rate applied to the transmissive amorphous thin film solar cell bonding module is fast, the curing reaction rate of the EVA sheet is a transmissive amorphous thin film that can improve the production efficiency Provides a solar cell multilayer module.
The present invention also provides a transmissive amorphous thin film solar cell multilayer module that is lighter than a conventional transmissive amorphous thin film solar cell multilayer module and is easy to install and install.
A transmissive amorphous thin film solar cell multilayer module according to an embodiment of the present invention is a transmissive thin film solar cell including a transparent conductive film glass and an amorphous thin film deposited on the transparent conductive film glass, an EVA sheet bonded to the amorphous thin film And a front transparent plastic film bonded to the EVA sheet, an aluminum spacer bonded to the transparent plastic film and having an air layer, and a rear transparent plastic film or rear float glass bonded to the aluminum spacer.
That is, the present invention is a form of a multi-layered structure including a transmissive amorphous thin-film solar cell bonding module consisting of a transmissive thin film solar cell, an EVA sheet, and a front transparent plastic film, an aluminum spacer having an air layer, and a rear transparent plastic film or a rear float glass. The multi-layer module can be configured.
Accordingly, the present invention can significantly reduce the weight of the entire transmissive amorphous thin film solar cell multilayer module by replacing the conventional front float glass with a transparent plastic film having a lower density than glass. The amorphous thin-film solar cell multilayer module of the present invention having such a structure can reduce the weight of the module itself by about 35%, thereby improving the workability when handling the module and installing it in a building, and as the overall thickness of the multilayer module becomes thinner. It is advantageous to design aluminum frame for installation in building and has the advantage that existing general purpose aluminum frame can be used as it is.
In the transmissive amorphous thin-film solar cell multilayer module according to the exemplary embodiment of the present invention, the heat shrinkage rate of the front transparent plastic film or the rear transparent plastic film for 20 minutes in a 150 ° C. hot air is 3% or less.
That is, the transparent plastic film of the present invention needs to be excellent in dimensional stability even at high temperature, but when the heat shrinkage is 3% or less, or preferably 1% or less when left in a hot air at 150 ° C. for 20 minutes, it is a transmissive amorphous solar cell. The bonding module may not be affected by shrinkage in the process of bonding the transparent plastic film to the EVA sheet carried out below 150 ℃ during the manufacturing process. In addition, when the transmissive amorphous thin film solar cell multilayer module of the present invention is constructed and used, it can be prevented from being deformed even under a high temperature environment.
In addition, according to the present invention it is possible to facilitate the temperature transfer to the EVA sheet, it is possible to speed up the curing reaction of the EVA sheet in the manufacture of the transmission-type amorphous thin-film solar cell multilayer module of the present invention.
In addition, since the transparent plastic film in the present invention is provided on the back side of the transmissive thin film solar cell, the influence of power generation performance by the transmittance of the transparent plastic film itself is not affected. In addition, when the visible light transmittance of 80% or more, the sunlight transmitted through the transmission type thin film battery cell can be transmitted through the room well. In particular, it is preferable that visible light transmittance is 90% or more.
In the transmissive amorphous thin film solar cell multilayer module according to the exemplary embodiment of the present invention, the front transparent plastic film or the rear transparent plastic film may be a polyester film, and the polyester film may have a thickness of 200 μm or more.
That is, it is preferable that the transparent plastic film in this invention is a polyester film. Polyester film is a representative transparent plastic film excellent in various basic physical properties, has a particularly strong strength and moderate elongation, in particular, has excellent optical properties. In particular, it is preferable that the thickness of the polyester film in this invention is 200-350 micrometers. That is, in order to ensure further excellent mechanical strength, it is preferable that it is 200 micrometers or more, and in order to make heat transfer to EVA film smooth, it is preferable that it is 350 micrometers or less.
The polyester film in the present invention may be a polyethylene terephthalate film, a polybutylene terephthalate film, a polyethylene naphthalate film, or the like.
As a result, the present invention provides a transmissive amorphous thin-film solar cell multilayer module that can increase the ease of a bonding operation process for manufacturing a transmissive amorphous thin-film solar cell bonding module and easily control the reaction rate of the EVA sheet.
In addition, as the weight of the transmissive amorphous thin-film solar cell multilayer module is reduced and the thickness is also thin, the constructability can be improved in the design of the frame or the application of the building.
The following examples are examples of the transmissive amorphous thin film solar cell multilayer module according to the present invention, but the scope of the present invention is not limited thereto.
Experimental evaluation method of the polyester film in the embodiment of the present invention was carried out as follows.
<Heat shrinkage rate>
Sample preparation method; The film was cut into the length of 20 mm (width) x 200 mm (length) in a longitudinal direction (MD; Machinery Direction) and a transverse direction (TD; Tenter Direction), and the sample was prepared.
How to measure ; After leaving for 20 minutes in a hot air circulation furnace (STI Co., Ltd.) set at 150 ° C, the mixture was cooled at room temperature for 10 minutes, and then the longitudinal length (Ls) after heat treatment was measured to obtain a heat shrinkage ratio by the following equation.
Thermal Shrinkage (%) = [(200-Ls) / 200] × 100
<Visible light transmittance>
Measuring method: KS M ISO13468-1 "Measuring light transmittance of plastic-transparent material"
Sample preparation method; 50mm width x 50mm square specimen
Other ambient conditions; * Set general conditions such as temperature and pressure and special conditions for measurement. Specimens requiring condition conditions are subjected to condition control under conditions of temperature 23 ± 2 ° C and condition humidity (50 ± 5)%, based on KS M ISO 291, prior to testing. If the thickness of the sample is thinner than 0.025 mm, 16 hours is sufficient; if thick, 40 hours is recommended.
Method of calculating measurement results; The visible light transmittance τ t % is calculated by the following equation.
τ t % = (τ 2 / τ 1 )
τ 2 : incident light, τ 1 : total light passing through the test piece
Example
As an exemplary embodiment of the present invention, the transmissive amorphous thin film solar cell multilayer module includes a transmissive thin film amorphous
Here, the front transparent plastic film is a polyethylene terephthalate film having a heat shrinkage rate of 0.9% in the longitudinal direction (MD; Machinery Direction) when left for 20 minutes in a 150 ° C hot air, and 0.2% in the transverse direction (TD; Tenter Direction). The thickness is 250 µm and the visible light transmittance is 91.3%.
Comparative example
The comparative example is a conventional product having the same structure as the embodiment except that the front polyester film is made of the
The transmissive amorphous thin-film solar cell multilayer module according to the present embodiment had a weight per unit area of about 23 kg / m 2 and reduced about 35% of the weight of the comparative example about 35 kg / m 2. When installed, it was possible to increase workability, and the overall thickness of the multilayer module (based on 6 mm of air layer) was also about 16 mm, which was considerably thinner than 21 mm of the comparative example.
1 is a block diagram of a conventional transmissive amorphous thin film solar cell multilayer module.
2 is a block diagram of a transmissive amorphous thin film solar cell multilayer module according to an embodiment of the present invention.
10: Transmissive amorphous thin film solar cell junction module
11: Transmissive Thin Film Amorphous Solar Cell
12: EVA sheet
13: front float glass
21: aluminum spacer
21a: air layer
22: rear float glass
101: front transparent plastic film
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020080061533A KR20100001575A (en) | 2008-06-27 | 2008-06-27 | Multi-layered module of amorphous thin film solar cell |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020080061533A KR20100001575A (en) | 2008-06-27 | 2008-06-27 | Multi-layered module of amorphous thin film solar cell |
Publications (1)
Publication Number | Publication Date |
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KR20100001575A true KR20100001575A (en) | 2010-01-06 |
Family
ID=41811863
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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KR1020080061533A KR20100001575A (en) | 2008-06-27 | 2008-06-27 | Multi-layered module of amorphous thin film solar cell |
Country Status (1)
Country | Link |
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KR (1) | KR20100001575A (en) |
-
2008
- 2008-06-27 KR KR1020080061533A patent/KR20100001575A/en not_active Application Discontinuation
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