KR20090121967A - Metal nano composite material manufacture method using for turbulent in-situ melting mixing process - Google Patents

Abstract

PURPOSE: A metal nano-composite material manufacturing method is provided, which can produce nano-composite material in a simple process by applying a casting method. CONSTITUTION: A metal nano-composite material manufacturing method comprises a step for preparing alloy by making Cu-B alloy into ingot; a step of inserting the ingot into a quartz tube having a nozzle and melting the ingot within the chamber; a step for forming the chamber into vacuum; a step for injecting the argon gas into the chamber; a step for transferring the molten solution; a step for performing in-situ reaction in the mixing chamber; a step for spraying the molten solution passed in-situ reaction using a nozzle; and a step for cooling the molten solution passed the spraying step.

Description

Metal nano composite material manufacture method using for turbulent in-situ melting mixing process}

The present invention relates to a method for manufacturing a metal nanocomposite, and more particularly, to a method for manufacturing a metal nanocomposite using a turbulent molten in-situ synthesis method.

In general, nanocomposite materials can be used in almost all fields such as information and electronic parts, automotive parts, aerospace parts, defense parts, and medical parts.The development technology of nanocomposite materials is developed in advanced countries in the 21st century. It is a technique that will enable the leap forward.

Nanocomposite materials can replace not only existing metal materials but also various metal-based composite materials with micron structure, which are being applied to automobile parts, aerospace parts, defense parts, information electronic parts, etc.

According to the 21st Century Technology Prospective Report, created by the Swedish Swedish Academy of Engineering Sciences with 130 scientific brains, the future of technology is one of three technologies: IT, genetic engineering and chemical materials science. The development of the sector is expected to lead to explosive growth in the field of molecular biology (food and medicine, computers, biosensors, new materials, energy, etc.). Among the three technical fields pointed out in this report, the material technology field will break away from the current material engineering technology for analyzing and simply synthesizing various materials, and in the future, there will be a technology for producing various materials having the characteristics and structures required by the researcher. It predicts and refers to nanotechnology as one of these technologies.

Nanotechnology is a comprehensive description of the technology of fabricating and utilizing materials, devices, and systems in the nanometer-sized (one-billionth) area, ie atoms, molecules, and macromolecular structures. Among them, in the field of nanomaterials, with recent advances in peripheral technology, the material synthesis technology has been rapidly developed, and it is possible to synthesize nanomaterials (nanostructure materials) in various ways. As a result of the discovery of various unusual phenomena that cannot be inferred from the characteristics of existing materials, that is, an extension of the properties of existing materials, the possibility of the birth of materials exhibiting new physical properties became widely recognized. Due to these characteristics, since the 1990s, scientists from all fields such as physics, chemistry, and materials have been focused on the synthesis and characterization of nanomaterials.

Among them, the nanocomposite material is a combination of the dispersed phase of the second phase on a matrix, and is designed to give strength, toughness, heat resistance, and functionality to the original characteristics of the matrix, and to obtain a material characteristic that cannot be obtained with the matrix on a matrix. At least one of the phases has a size in the nanometer range (generally 1-100 nm). Nanocomposites have nanometer ranges of constituent size, which greatly increases constituent interactions and interface interactions at the atomic or molecular level, which does not obey the laws of physics applied to traditional micron-sized composites. In addition, the effect on macroscopic properties is significantly greater than that of micron composites, and new and special properties are expected to emerge.

Therefore, the nanocomposite material is reported not only in the expression of simple specific properties (improved mechanical properties, catalytic properties, changes in electromagnetic states, optical properties, etc.) pursued in single-phase nano (bulk) materials having a grain size of 100 nm or less. Attention is being drawn to the "second generation nanostructure material" from the viewpoint of complexing the specific properties to be made to artificially create the required properties.

However, the existing material synthesis technology is still limited in particle size control, and in the case of advanced foreign countries, the development of nanocomposite-related technology is limited in some cases, targeting polymer matrix materials and ceramic matrix materials, which are easy to control in size. In progress, full-scale R & D on metal matrix materials has not been carried out systematically.

In general, as a method of manufacturing a nanocomposite material, a method of mixing the compositional phases having nanoparticle sizes with each other is currently used the most, but this method is the final nanocomposite material due to the surface contamination occurs during the manufacturing process The interface property of the deterioration of not only can not sufficiently express the characteristics of the nanometer size, but also has the disadvantage that the composition is not uniformly dispersed. Therefore, it is necessary to develop an in-situ process technology capable of uniformly dispersing a thermodynamically stable dispersed phase having a clean surface capable of expressing nanometer-sized characteristics on a matrix. In particular, there is an urgent need to develop a new material processing technology for metal base materials, which is relatively difficult to control the particle size compared to polymer base materials and ceramic base materials.

Microstructure control of metal materials has been used for a long time to improve the strength and toughness of metals and to improve functionality such as magnetic properties. Compared to semiconductors or electronic ceramics, the traditional research theme of improving microstructure by improving microstructure in metallic materials can give a lasting impression. In recent years, however, it has become possible to refine such a range of tissue control by more than one dimension size 101 by using various means, and as a result, nanostructured material having high characteristics that cannot be obtained in conventional micron-based materials is available. Is being realized. However, the Orowan strengthening theory showing the relationship between the particle spacing and the strength, the continuum model considering the effect of particle size, the shear-lag theory for equiaxed particles Although it is explained by the interphase barrier-strengthening mechanism, etc., the development of a new technique for predicting / explaining the characteristics of the nanostructured material is required.

The present invention has been proposed to solve the above-mentioned problems, the object of which is to produce a metal nanocomposite material in a simple process by applying the casting method, it can also be mass-produced inexpensive molten metal phosphorus- It is an object of the present invention to provide a method for producing a metal nanocomposite material using in-situ synthesis.

The turbulent melt in-situ synthesis method controls the reactivity of the molten metal to control the reaction between the molten metal, the molten metal, the solid, the molten metal and the gas, and simultaneously controls the flow of the molten metal and the solidification rate of the molten metal. It is a new material processing technology that can synthesize nanometer-sized dispersed phases in-situ.

This technique forcibly forms turbulent turbulence in the molten metal in which the components are dissolved in an atomic state to induce homogeneous nucleation of the in-situ reaction product and rapidly solidifies the mixed melt while simultaneously reacting the in-situ reaction product. It is characterized by suppressing growth. In addition, by applying conventional mold casting, atomizing method or melt spinning method during rapid solidification, nano-composites of various shapes such as bulk, powder, and ribbon can be manufactured, and other in-situ by applying the conventional casting process. Compared to the nanocomposite manufacturing process technology, it has the advantage of easy mass production at low cost.

Method for producing a metal nanocomposite material using the turbulent molten metal in-situ synthesis method according to the present invention for achieving the above object (a) a copper-boron (Cu-B) alloy ingot (ingot) (B) a melting step of inserting the ingot into a quartz tube having a nozzle in the chamber and melting the ingot in the chamber; and (c) forming a vacuum in the chamber. A vacuum forming step, (d) an injection step of injecting argon (Ar) gas into the chamber, (e) a transfer step of transferring the molten liquid melted in the melting step, and (f) a transfer step of the transfer step. A reaction step of allowing the melt to pass through the mixing chamber to perform in-situ reaction in the mixing chamber, and (g) spraying the in-situ reacted melt in the reaction step to a nozzle through the outside of the chamber; Spraying step, and (h) phase It characterized in that it comprises a; a cooling step for cooling the melt passed through the spraying step.

In addition, the cooling step of the method for producing a metal nanocomposite material using the turbulent melt in-situ synthesis method according to the present invention is characterized by forming a ribbon-shaped specimen by rotating the cooling wheel.

The cooling wheel is characterized in that it is rotated to 3400 Alp (RPM) to 3800 Alp (RPM).

In addition, the cooling wheel of the method for producing a metal nanocomposite material using the turbulent melt in-situ synthesis method according to the present invention is characterized in that the surface is polished and then rotated.

In addition, the vacuum forming step of the method for producing a metal nanocomposite material using the turbulent melt in-situ synthesis method according to the present invention, 1 × 10 ^-4 to Characterized in that it is formed by a vacuum of 1 × 10 ^-6 Torr.

In addition, the transfer of the melt of the method for producing a metal nanocomposite material using the turbulent melt in-situ synthesis method according to the present invention is made while passing through a heater, the heater is 1100 to 1300 ℃, Its lower portion is characterized in that it is heated to 1000 to 1200 ℃ respectively.

In addition, the melting step of the method for producing a metal nanocomposite using the turbulent melt in-situ synthesis method according to the present invention is characterized in that it is made using a high frequency heater.

In addition, the conveying step of the method for producing a metal nanocomposite material using the turbulent melt in-situ synthesis method according to the present invention is characterized in that the conveying at a pressure of 0.1MPa.

In addition, argon gas injection in the chamber of the method for producing a metal nanocomposite material using the turbulent molten metal in-situ synthesis method according to the present invention is characterized in that it is performed under a pressure of 1 atm.

In addition, a separate resistance heating unit is further provided around the quartz tube nozzle in the method of manufacturing the metal nanocomposite material using the turbulent melt in-situ synthesis method according to the present invention to transfer the solution inside the quartz tube. It is characterized in that to facilitate.

In addition, the quartz tube nozzle of the method for producing a metal nanocomposite material using the turbulent melt in-situ synthesis method according to the present invention is characterized in that it has a diameter of 0.8 mm.

In addition, the alloy of copper-boron (Cu-B) of the method for producing a metal nanocomposite material using the turbulent melt in-situ synthesis method according to the present invention, the temperature and fluidity at the time of melting the alloy In order to ensure the composition has a composition of Cu-2.5wt% B which is a theoretical process point on the state diagram.

In addition, the method of manufacturing a metal nanocomposite using the turbulent molten metal in-situ synthesis method according to the present invention (a) to prepare an alloy by ingoting a copper-titanium (Cu-Ti) alloy An alloy preparation step, (b) a melting step of inserting the ingot into a quartz tube having a nozzle in the chamber and melting the ingot in the chamber, and (c) forming a vacuum in the chamber; (d) an injection step of injecting argon (Ar) gas into the chamber, (e) a transfer step of transferring the molten liquid melted in the melting step, and (f) a melt transferred in the transfer step of the mixing chamber. A reaction step of in-situ reacting in the mixing chamber, (g) an injection step of injecting the melt liquid in-situ reacted in the reaction step into a nozzle passing out of the chamber, and (h ) The melt that passed through the spraying step Characterized in that it comprises a cooling step of cooling.

In addition, the specimen of the method for producing a metal nanocomposite using the turbulent molten metal in-situ synthesis method according to the present invention is obtained a composite material in which TiB ₂ is dispersed in a copper (Cu) base, in-situ TiB ₂ formed by the reaction is characterized by exhibiting a size of 100 ~ 300nm.

According to the manufacturing method of the metal nanocomposite material using the turbulent melt in-situ synthesis method according to the present invention, by applying the casting method, the metal nanocomposite material can be manufactured in a simple process, and also mass production at low cost. It can work.

The present invention will be described with reference to the embodiments shown in the accompanying drawings, which are exemplary and will be understood by those skilled in the art that various modifications and equivalent embodiments are possible. Therefore, the true scope of protection of the present invention should be defined only by the appended claims.

Hereinafter, a method of manufacturing a metal nanocomposite material using a turbulent molten metal in-situ synthesis method according to a preferred embodiment of the present invention will be described in detail with reference to the accompanying drawings.

Method for producing a metal nanocomposite material using the turbulent melt in-situ synthesis method according to an embodiment of the present invention is an alloy preparation step, a melting step, a vacuum forming step, an injection step, a transfer step, It includes a response step, an injection step, and a cooling step.

The alloy preparation step is a process of preparing an alloy by ingoting a copper-boron (Cu-B) alloy.

The melting step is a process of inserting the ingot into a quartz tube having a nozzle in the chamber and accommodating the ingot in the chamber.

The vacuum forming step is a process of forming a vacuum in the chamber.

The injection step is a step of injecting argon (Ar) gas into the chamber.

The transfer step is a process for transferring the molten liquid melted in the melting step.

The reaction step is a process for in-situ reaction in the mixing chamber by allowing the melt transferred in the transferring step to pass through the mixing chamber.

The spraying step is a step of injecting the melt liquid reacted in-drilling in the reaction step to a nozzle passing outside the chamber.

The cooling step is a step of cooling the molten liquid that has passed through the injection step.

The cooling step is characterized in that to form a specimen on the ribbon by rotating the cooling wheel, the cooling wheel is rotated to 3400 Alp (RPM) to 3800 Alp (RPM), the cooling wheel is rotated after the surface is polished Will be.

The vacuum forming step, 1 × 10 ^-4 to It is formed by a vacuum of 1 × 10 ^-6 Torr, the transfer of the molten liquid is made while passing through the heater, the heater is heated to the upper portion of 1100 to 1300 ℃, the lower portion of 1000 to 1200 ℃, respectively.

In addition, the melting step is performed using a high-frequency heater, the transfer step is transferred at a pressure of 0.1MPa, argon gas in the chamber is carried out under a pressure of 1 atm.

In addition, by providing a separate resistance heating unit around the quartz tube nozzle to facilitate the transfer of the solution inside the quartz tube, the quartz tube nozzle has a diameter of 0.8 mm.

In addition, the alloy of copper-boron (Cu-B) has a composition of Cu-2.5wt% B, which is a theoretical process point on the state diagram in order to ensure the temperature and fluidity when dissolving the alloy.

In addition, the specimen obtained by the method of manufacturing a metal nanocomposite material using the turbulent molten metal in-situ synthesis method according to the present invention is obtained a composite material in which TiB ₂ is dispersed in a copper (Cu) matrix, TiB ₂ formed by the -situ reaction is characterized by exhibiting a size of 100 ~ 300nm.

An embodiment of a method for producing a metal nanocomposite using the turbulent melt in-situ synthesis method according to an embodiment of the present invention having the above configuration is described.

▶ Target Material

-Cu-based nanocomposites (Cu / TiB ₂ )

            Room temperature strength: 700MPa class, electrical conductivity: 55% IACS or more

-Al-based nanocomposites (AlN / Al, Al ₂ O ₃ / Al)

            Room temperature strength: 1GPa class, high temperature strength: 350MPa (300 ℃)

▶ Particle size of dispersed phase: 100nm or less

Figure 1 shows the expected mechanical and electrical properties of Cu-based nanocomposites.

In the case of the Cu-based composite material, a ribbon phase of nanoparticles having an average size of 100 nm could be prepared. As a result of analyzing the characteristic values, we approached the expected characteristic values of Cu-based nanocomposites in Figure 1. Figure 2 shows the hardness values according to the particle size as a result of nano indentation. The hardness value of the particle size of 50 nm (5 wt% TiB 2, wheel speed 4000 rpm) was found to be at least 1.0 GPa from 2.4 GPa to 200 nm (1 wt% TiB 2, wheel speed 2000 rpm). The average hardness of the melt spun ribbon having an average particle size of about 100 nm was about 1.2 GPa. As a result of plotting the hardness value, it can be seen that the particle tends to increase as the particle becomes finer. In particular, it can be seen that the increase rapidly increases in the case of 200 nm or less. Figure 3 shows the change of electrical conductivity according to the TiB2 content. In the case of 1wt% TiB2, the maximum was 79% IACS and decreased with increasing content.

Figure 4 shows the correlation between particle size and characteristic values for each manufacturing process. It can be seen that the characteristic values obtained in this study show superior characteristics compared to other manufacturing processes.

In the embodiment of the present invention it was confirmed that it is possible to manufacture a composite material of better properties by controlling the size and content of the particles. Therefore, we believe it will be possible to apply the bulking technology to be pursued in the future.

In order to establish the optimum conditions of the present invention, the following experiment was conducted.

 ▶ Changes in process equipment design

 ○ In order to increase the adjustment range of RPM in the design drawing, the diameter of the cooling wheel is changed from 20φ to 22φ (without difficulty in loading) in the construction of turbulent melt in-situ process equipment (see Fig. 5). , Produced.

 ○ Designed for smooth transfer of the molten metal in the quartz tube, in addition to the heating device inside the mixing chamber, a resistance heater (see Figs. 5 and 6) is installed around the nozzle of the quartz tube, so that the entire process isothermalized before spraying the gm of the molten metal. It could be maintained.

            Figure 5. Inside process equipment chamber

           Figure 6. Process Equipment Nozzle Heating Part

Influence of in-situ reactions by alloys of base metals in the manufacture of master alloys

  In the preparation of the master alloy, the experiment was carried out using the composition of Cu-2.5wt% B (see Fig. 7), which is the theoretical process point on the state diagram, to secure the temperature and fluidity during the dissolution of Cu-B. In the case of Cu-Ti, the ribbon phase of Cu-4wt% TiB2 (Cu-7.7vol% TiB2) was selected by selecting the composition of Cu-5.57wt% Ti (see Fig. 8) which can be theoretically reacted by the process point of Cu-B. Got.

 Influence of in-situ response with temperature

  In order to control the flow of each Cu-Ti and Cu-B molten metal to prevent solidification in the flow chart, the temperature of the heating part of the process equipment is maintained at 1200 ° C in the upper part and 1100 ° C in the lower part (to prevent solidification following the temperature just before spraying). To keep the flow of the molten metal smoothly. As a result, it was possible to confirm the flow of the molten metal in the quartz tube.

 Influence of in-situ response on the position of the diaphragm of the induction heating part of the quartz tube and the diameter of the nozzle

  The molten metal of the master alloy solidifies to the tip of the diaphragm due to the position of the diaphragm in the downwind tube of the induction heating unit inside the turbulent melt in-situ process equipment. The phenomenon (see Figure 9) occurred. In order to compensate for this, fabrication and experiments were carried out by adjusting the diaphragm of the quartz tube upwards (see Fig. 10) to prevent solidification and to ensure a smooth flow of the molten metal.

Figure 9. Breakage of quartz tube diaphragm Figure 10. Upgraded quartz tube aperture

In addition, specimens obtained from experiments on quartz tubes with a nozzle diameter of 1φ were wide and broken (see Figs. 11 and 12). In order to solve this problem, the nozzle diameter was changed from 1φ to 0.8φ, and the quartz tube was manufactured and tested. A more uniform specimen (see Figs. 13 and 14) was obtained.

 Figure 11. Nozzle diameter 1φ quartz tube Figure 12. Specimen at 1φ Nozzle Diameter

Fig.13 Nozzle diameter 0.8φ quartz tube Fig.14. Specimen at 0.8φ Nozzle Diameter

Influence of in-situ reaction with gas pressure

Experimental results show that gas pressure affects the in-situ reaction. When the gas pressure was 0.08 MPa or less, the melted block was clogged at the nozzle part of the quartz tube and the nozzle part was broken (see Figs. 15 and 16) .In the case of 0.10 MPa, the melt flows smoothly and the quartz is clean. Tubes and uniform ribbons (see Figures 17 and 18) were obtained.

Figure 15. Melt blockage of nozzle part Figure 16. Nozzle Damage

On the other hand, in case of 0.12MPa or more, cracks in the holder part of the quartz tube and cracks in the mixing part (see Figs. 19 and 20) were found to cause damage to the equipment. Experiments under each condition confirmed that 0.10MPa was the optimal condition.

    Figure 17. Clean quartz tube picture 18. Specimen obtained at 0.10 MPa

Figure 19. Breakage of quartz tube holder part Figure 20. Breakage phenomenon of the mixing part of quartz tube

 Influence of in-situ response on wheel surface

 In the operation of the process equipment, after the experiment, a phenomenon in which the molten metal was entangled around the nozzle heating part occurred. This entangled melt caused scratches on the wheels (see Figures 21 and 22), which affected subsequent experiments. If the surface of the wheel is smooth (see Figure 23), the specimen obtained has a good shape, but if there are even minor scratches on the wheel, the surface of the wheel will melt and the specimen will not enter the collector and fall to the bottom of the chamber (see Figure 24). This occurred. In order to prevent this phenomenon, the wheel surface was evenly ground and tested, which solved the problem.

Figure 21. Melt tangle phenomenon of nozzle heating part Figure 22. Scratch generating wheel

Figure 23. Smooth surface wheel Fig. 24 Specimen entangled in chamber bottom

In order to confirm the final optimum condition, the arc dissolution was performed as shown in the conditions of the above state diagrams of Cu-B and Cu-Ti, and the experiments were performed by inserting 10g of alloyed ingots on both sides of the quartz tube.

First, the chamber was vacuumed at 1 × 10 −5 Torr, and the Ar gas in the chamber was adjusted to 1 atm, and the heaters were heated to 1200 ° C. and 1100 ° C., respectively, for smooth flow of the molten metal in the quartz tube. Then, the high frequency heating unit was operated to dissolve each ingot, and transferred to a pressure of 0.1 MPa. The molten metal reacted in-situ in the mixing chamber was sprayed through a nozzle to rotate a cooling wheel at 3600 RPM to prepare a ribbon specimen. The prepared specimens (see Figure 29) were analyzed using SEM and XRD (see Figures 30 and 31). A composite material containing TiB2 dispersed in Cu matrix was obtained, and TiB2 formed by in-situ reaction was 100 ~ 300. The size of nm is shown.

Figure 25. TiB ₂ / Cu nanocomposite ribbon image 26. TiB ₂ / Cu nanocomposite SEM

Claims (25)

(a) an alloy preparation step of preparing an alloy by ingoting a copper-boron (Cu-B) alloy; (b) a melting step of inserting and receiving the ingot into a quartz tube having a nozzle in the chamber and melting the ingot in the chamber; (c) forming a vacuum in the chamber; (d) injecting argon (Ar) gas into the chamber; (e) a transfer step of transferring the molten liquid melted in the melting step; (f) a reaction step of allowing in-situ reaction in the mixing chamber by allowing the melt conveyed in the transferring step to pass through the mixing chamber; (g) a spraying step of injecting the in-situ reacted melt in the reaction step into a nozzle through the outside of the chamber; (h) a cooling step of cooling the molten liquid after the injection step; a method of manufacturing a metal nanocomposite material using a turbulent melt in-situ synthesis method comprising a. The method of claim 1, The cooling step is a method for producing a metal nanocomposite material using a turbulent melt in-situ synthesis method, characterized in that the cooling wheel is rotated to form a specimen on the ribbon. The method of claim 2, The cooling wheel is a method of manufacturing a metal nanocomposite material using a turbulent molten metal in-situ synthesis method, characterized in that the rotating to 3400 Alp (RPM) to 3800 Alp (RPM). The method of claim 3, wherein The cooling wheel is a method of manufacturing a metal nanocomposite material using a turbulent melt in-situ synthesis method, characterized in that the surface is rotated after grinding. The method of claim 1, The vacuum forming step, 1 × 10 ^-4 to A method for producing a metal nanocomposite material using a turbulent melt in-situ synthesis method, characterized in that formed by a vacuum of 1 × 10 ^-6 Torr. The method of claim 1, The transfer of the melt is made while passing through the heater, The heater is a method of manufacturing a metal nanocomposite material using a turbulent melt in-situ synthesis method, characterized in that the upper portion is heated to 1100 to 1300 ℃, the lower portion to 1000 to 1200 ℃, respectively. The method of claim 1, The melting step is a method for producing a metal nanocomposite material using a turbulent melt in-situ synthesis method, characterized in that using a high-frequency heater. The method of claim 1, The transfer step is a method for producing a metal nanocomposite material using a turbulent melt in-situ synthesis method, characterized in that the transfer to a pressure of 0.1MPa. The method of claim 1, Argon gas injection in the chamber is a method of producing a metal nanocomposite material using a turbulent molten in-situ synthesis method, characterized in that under a pressure of 1 atm. The method of claim 1, Preparation of a metal nanocomposite material using a turbulent melt in-situ synthesis method characterized by further providing a separate resistance heating unit around the quartz tube nozzle to facilitate the transfer of the solution inside the quartz tube. Way. The method of claim 1, The quartz tube nozzle is a method of manufacturing a metal nanocomposite material using a turbulent melt in-situ synthesis method, characterized in that having a diameter of 0.8 mm. The method of claim 1, The alloy of copper-boron (Cu-B) has a composition of the turbulent molten metal phosphorus, characterized in that it has a composition of Cu-2.5wt% B, which is a theoretical process point on the state diagram in order to secure the temperature and fluidity upon dissolution of the alloy Method for producing a metal nanocomposite material using the (in-situ) synthesis method. (a) an alloy preparation step of preparing an alloy by ingoting a copper-titanium (Cu-Ti) alloy; (b) a melting step of inserting and receiving the ingot into a quartz tube having a nozzle in the chamber and melting the ingot in the chamber; (c) forming a vacuum in the chamber; (d) injecting argon (Ar) gas into the chamber; (e) a transfer step of transferring the molten liquid melted in the melting step; (f) a reaction step of allowing in-situ reaction in the mixing chamber by allowing the melt conveyed in the transferring step to pass through the mixing chamber; (g) a spraying step of injecting the in-situ reacted melt in the reaction step into a nozzle through the outside of the chamber; (h) a cooling step of cooling the molten liquid after the injection step; a method of manufacturing a metal nanocomposite material using a turbulent melt in-situ synthesis method comprising a. The method of claim 13, The cooling step is a method for producing a metal nanocomposite material using a turbulent melt in-situ synthesis method, characterized in that the cooling wheel is rotated to form a specimen on the ribbon. The method of claim 14, The cooling wheel is a method of manufacturing a metal nanocomposite material using a turbulent molten metal in-situ synthesis method, characterized in that the rotating to 3400 Alp (RPM) to 3800 Alp (RPM). The method of claim 15, The cooling wheel is a method of manufacturing a metal nanocomposite material using a turbulent melt in-situ synthesis method, characterized in that the surface is rotated after grinding. The method of claim 13, The vacuum forming step, 1 × 10 ^-4 to A method for producing a metal nanocomposite material using a turbulent melt in-situ synthesis method, characterized in that formed by a vacuum of 1 × 10 ^-6 Torr. The method of claim 13, The transfer of the melt is made while passing through the heater, The heater is a method of manufacturing a metal nanocomposite material using a turbulent melt in-situ synthesis method, characterized in that the upper portion is heated to 1100 to 1300 ℃, the lower portion to 1000 to 1200 ℃, respectively. The method of claim 13, The melting step is a method for producing a metal nanocomposite material using a turbulent melt in-situ synthesis method, characterized in that using a high-frequency heater. The method of claim 13, The transfer step is a method for producing a metal nanocomposite material using a turbulent melt in-situ synthesis method, characterized in that the transfer to a pressure of 0.1MPa. The method of claim 13, Argon gas injection in the chamber is a method of producing a metal nanocomposite material using a turbulent molten in-situ synthesis method, characterized in that under a pressure of 1 atm. The method of claim 13, Preparation of a metal nanocomposite material using a turbulent melt in-situ synthesis method characterized by further providing a separate resistance heating unit around the quartz tube nozzle to facilitate the transfer of the solution inside the quartz tube. Way. The method of claim 14, The quartz tube nozzle is a method of manufacturing a metal nanocomposite material using a turbulent melt in-situ synthesis method, characterized in that having a diameter of 0.8 mm. The method of claim 13, The alloy of copper-titanium (Cu-Ti) has a composition of Cu-5.57 wt% Ti, which is a theoretical process point on the state diagram in order to ensure temperature and fluidity upon dissolution of the alloy. Method for producing a metal nanocomposite using the (in-situ) synthesis method. The method according to claim 2 or 14, The specimens were copper (Cu) is obtained a composite material in the base TiB ₂ is dispersed, formed by the in-situ reaction TiB ₂ is a bath for turbulent flow, characterized in that indicating the size of 100 ~ 300㎚ - drilling (in- situ) A method for producing a metal nanocomposite material using a synthesis method.