KR20090115326A - Functional fabrics made of korean paper (hanji) - Google Patents

Functional fabrics made of korean paper (hanji) Download PDF

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Publication number
KR20090115326A
KR20090115326A KR1020080041118A KR20080041118A KR20090115326A KR 20090115326 A KR20090115326 A KR 20090115326A KR 1020080041118 A KR1020080041118 A KR 1020080041118A KR 20080041118 A KR20080041118 A KR 20080041118A KR 20090115326 A KR20090115326 A KR 20090115326A
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South Korea
Prior art keywords
hanji
korean paper
resin
water
fiber
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KR1020080041118A
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Korean (ko)
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이병수
김숙현
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이병수
김숙현
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Priority to KR1020080041118A priority Critical patent/KR20090115326A/en
Publication of KR20090115326A publication Critical patent/KR20090115326A/en

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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/10Organic non-cellulose fibres
    • D21H13/12Organic non-cellulose fibres from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/16Sizing or water-repelling agents
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/22Agents rendering paper porous, absorbent or bulky

Abstract

PURPOSE: Functional fabrics made of Korean paper(HanJi) is provided to prevent permeation of water/liquid into the fiber perfectly, and to restrict deformation of the fabric due to water while increasing tensile strength. CONSTITUTION: Functional fabrics made of Korean paper(HanJi) is formed by applying polymer such as acryl resin, urethane resin, fluorine-based resin or poly ester resin etc, and includes a Korean paper fiber layer(30) and a thin film layer(40). The functional fabric includes a function of preventing permeation of water drops and a function of permeating liquid vapor(60). The Korean paper fiber is made of the paper mulberry. The Korean paper fiber layer and the thin film layer are bonded with an adhesive.

Description

한지를 사용한 기능성 섬유 소재{Functional Fabrics made of Korean Paper (HanJi)}Functional fabrics made of Korean paper {Functional Fabrics made of Korean Paper (HanJi)}

본 발명은 닥나무 껍질을 주원료로 하여 제조되는 한지 또는 한지로 제직한 한지 섬유 (이하 한지섬유) 표면에 아크릴계 수지나 우레탄계 수지, 불소계 수지, 폴리에스테르계 수지 등의 고분자 폴리머를 이용하여 균일한 피막을 견고하게 형성시켜 한지 또는 한지 섬유 단독으로는 얻기 힘든 기능, 즉 외부로부터 물의 침투를 막고 내부(안쪽)로부터 발생하는 액체 수증기를 투과시키는 기능을 동시에 갖는 한지를 사용한 섬유 소재의 제조 방법에 관한 것이다.According to the present invention, a uniform film is formed on the surface of Hanji or Hanji fibers (hereinafter, Hanji fiber) manufactured by using a bark of bark as a main raw material by using a polymer such as acrylic resin, urethane resin, fluorine resin, or polyester resin. The present invention relates to a method for producing a fiber material using Hanji, which is formed firmly and simultaneously has a function that is difficult to obtain by Hanji or Hanji fiber alone, that is, a function of preventing the penetration of water from the outside and permeating liquid vapor generated from the inside (the inside).

한지는 지피(닥나무 껍질) 자체로 제작되어 질기고 촉감이 부드럽고 섬유사이에 적당한 공간을 가지고 있어 습도를 조절하고 습기에 강하며 통기성과 보온성이 좋아 천연 소재로서 의류, 포장지, 창호지 등 여러 가지 산업분야에서 본래의 기능을 근본으로 하여 다양하게 사용되어 왔다. 최근에 와서 웰빙 산업의 비약으로 천연 소재에 대한 요구가 더욱 구체화되고 다양화됨에 따라 더욱 많은 산업 분야나 응용 분야에 사용되어져야 하나 근본적으로 종이 소재가 갖는 취약점 즉, 인장 강도가 약하거나 물(액체)에 의하여 그 형태가 틀어지어 사용 목적을 이루기 어렵거 나, 또는 물(액체)의 일정한 압력 이상이 되면 내부로 스며들게 되는 등 그의 사용의 한계를 갖게 되어 그러한 요구를 수용 할 수 없게 되었다.Hanji is made of paper (bark) itself, which is durable, soft to the touch, and has a suitable space between fibers. It controls humidity, resists moisture, and has good breathability and warmth.It is a natural material in various industries such as clothing, wrapping paper and window paper. It has been used in various ways based on the original function. In recent years, as the need for natural materials has become more specific and diversified as a leap of the well-being industry, it has to be used in more industrial fields or applications, but the weakness of paper materials, that is, weak tensile strength or water (liquid) It is difficult to achieve the purpose of use because of its shape, or it becomes permeable to the inside when it exceeds the constant pressure of water (liquid).

한지 또는 한지 섬유의 표면에 우레탄계 수지 등 고분자 폴리머를 이용하여 피막을 형성하며, 이를 통하여 한지 섬유의 인장강도가 강화되고 또한 물에 대한 저항력 즉 물에 의한 형태 변경이 억제되고, 물/액체가 내부로 스며드는 것을 완벽하게 방지하는데 목적이 있다The film is formed on the surface of Hanji or Hanji fiber by using a polymer such as urethane resin, which strengthens the tensile strength of the Hanji fiber, and also suppresses the change of shape by water, and the water / liquid inside. The purpose is to completely prevent seepage into

상기의 목적을 달성하기 위하여 닥나무 껍질을 주 원료로 하는 한지 또는 한지 섬유의 표면에 아크릴계 수지, 우레탄계 수지, 불소계 수지 또는 폴리에스테르계 수지 등의 폴리머를 이용하여 두 가지 이상의 층을 이루어, 하나의 층은 한지 또는 한지 섬유이며 또 다른 하나의 층은 연속적인 폴리머 물질로 피막을 형성하여 그 층들을 접착제 또는 접착 물질로 서로의 층들을 접합한다.In order to achieve the above object, two or more layers are formed on the surface of Hanji or Hanji fiber, which are mainly made of bark, using polymers such as acrylic resins, urethane resins, fluorine resins, or polyester resins. Silver is Hanji or Hanji fiber and another layer forms a film of continuous polymeric material to join the layers to each other with an adhesive or adhesive material.

본 발명에 의한 한지 또는 한지 섬유에 방수, 투습 코팅제조 방법에 의하여 한지 본래의 기능에 추가로 물의 일정한 압력에도 견디는 방수성(waterproofness)을 가짐과 동시에 내부의 수증기를 바깥으로 배출시키는 투습(water vapor transmission)효과를 누리게 되어 종이 섬유 본래의 물에 취약하고 형태가 변형되는 점을 차단하여, 또한 이면의 수지층(피막)이 강하게 한지를 붙잡고 있어 종이의 취약점인 인장강도를 보강하여 다양한 산업 분야에 접목이 가능하게 한다.Water vapor transmission to the Hanji or Hanji fiber according to the present invention in addition to the original function of the Hanji by the method of manufacturing a waterproof, moisture-permeable coating in addition to the water resistance (waterproofness) to withstand a constant pressure of water and to discharge the water vapor inside the outside (water vapor transmission) It is vulnerable to the original water of paper fiber and prevents the deformation of shape, and also holds the resin layer on the back side strongly to strengthen the tensile strength, which is a weakness of paper, to be applied to various industrial fields. Makes this possible.

상기의 목적을 달성하기 위하여 도 1에서 보듯이 한지 또는 한지 섬유(10)의 표면에 아크릴계 수지, 우레탄계 수지, 불소계 수지 또는 폴리에스테르계 수지 등의 고분자 폴리머(20)를 이용하여 아래의 실시 예에서 볼 수 있듯이 필름 라미네이트 또는 코팅 방식으로 제조하여 한지 또는 한지 섬유 층(30) 과 연속적인 고분자 물질로 이루어진 피막층 (40)의 두 가지 층 이상으로 구성한다. 도 2에서 보듯이 외부로부터 물의 침투를 막고(50) 내부(안쪽)로부터 발생하는 액체 수증기를 투과시키는 기능(60)을 동시에 가진다.In order to achieve the above object as shown in Figure 1 using the polymer polymer 20, such as acrylic resin, urethane resin, fluorine resin or polyester resin on the surface of the Hanji or Hanji fiber 10 in the following embodiment As can be seen, it is made of film lamination or coating method and consists of two or more layers of Hanji or Hanji fiber layer 30 and the coating layer 40 made of a continuous polymer material. As shown in FIG. 2, it simultaneously has a function 60 to prevent infiltration of water from the outside 50 and to permeate liquid vapor generated from the inside (inside).

실시 예를 통하여 본 발명을 구체적으로 살펴보지만, 하기 예에 본 발명의 범주가 한정되는 것은 아니다.Although the present invention will be described in detail through examples, the scope of the present invention is not limited to the following examples.

실시 예 1Example 1

유기용제와 물로써 용해 분산한 수지, 에멀젼, 분산제 등을 한지 또는 한지 섬유 기재에 도포하여, 열. 바람에 의하여 용매를 기화시키거나, 연속 고형피막에 의하여 한지 또는 한지 섬유의 표면을 코팅하는 방법으로 한다. 미리 가열에 의하여 가소화 유동화된 고분자 폴리머를 냉각하여 성막을 형성하는 방법으로도 한다. 이 방법은 얇은 피막을 형성 할 수 있으며, 안료와 각종 첨가물의 혼합이 용이하기 때문에 추가 기능성의 부여와 표면변화가 있는 제품을 얻을 수 있다.Resin, emulsion, dispersing agent, etc. which were dissolved and dispersed with an organic solvent and water were applied to Hanji or Hanji fiber base material, and heated. The solvent may be vaporized by wind, or the surface of Hanji or Hanji fibers may be coated by a continuous solid film. It is also a method of forming a film by cooling the plasticized fluidized polymer polymer by heating in advance. This method can form a thin film, and since the mixing of pigments and various additives is easy, it is possible to obtain a product having additional functionality and surface change.

실시 예 2Example 2

물과 친화성이 있으며 완전히 용해 할 수 있는 알코올과 DMF (Dimethyl Formaldehyde)등의 유기용제에 용해한 코팅 액을 사용하여 가공하는 방법으로 이 코팅 액을 한지 또는 한지 섬유 표면에 코팅한 후에 다량의 물에 침지함으로써 용제를 용출시켜 균일한 다공질 피막을 형성시키는 방법으로 물에의 침지에 의해 수지을 용해하고 용제의 용해성을 변화하여 수지를 응고시키는 방법이다.Processed using a coating solution dissolved in an organic solvent such as alcohol and DMF (Dimethyl Formaldehyde), which is compatible with water and is completely soluble. It is a method of eluting a solvent and forming a uniform porous film by dipping, and dissolving resin by immersion in water, and changing the solubility of a solvent, and coagulating resin.

실시 예 3Example 3

이형지 위에 수지를 코팅하여 친수무공형(hydrophillic, non-porous type) 혹은 다공질(microporous type) 필름을 제조한 후, 이를 접착제로 한지 또는 한지 섬유와 접합시켜서(라미네이팅) 투습방수포를 제조하는 방법이다.Resin is coated on a release paper to produce a hydrophillic (non-porous type) or porous (microporous type) film, and then bonded with a paper or adhesive paper (laminating) with an adhesive (laminating) to prepare a moisture-permeable waterproof foam.

실시 예 4Example 4

전기 방사 기술 (electrospinning) 을 이용하여 한지 또는 한지 표면에 우레탄 등의 소수성 수지 (hydrophobic)를 방사하여 나노 단위의 웹 형태의 피막을 형성하는 방법을 제공한다.The present invention provides a method of forming a nano-shaped web-like coating by spinning hydrophobic resins such as urethane on the surface of Hanji or Korean paper using electrospinning.

도 1은 한지 도는 한지 섬유와 고분자 폴리머를 접합하는 방식을 나타낸 것임1 is a diagram showing a method of bonding Hanji or Hanji fiber and a polymer polymer

도 2는 한지 또는 한지 섬유와 피막의 접착 단면을 나타낸 것으로 이 기능성 섬유의 방수, 투습 기능 원리를 표시한 것임Figure 2 shows the adhesive cross section of the Hanji or Hanji fiber and the film showing the waterproof, moisture-permeable functional principle of this functional fiber

Claims (1)

닥나무 껍질을 주 원료로 하여 제조된 한지 또는 한지를 사용하여 만든 한지 섬유와 아크릴계 수지, 우레탄계 수지, 불소계 수지 및 폴리에틸렌계 수지 등의 고분자 폴리머를 이용하여 균일한 피막을 견고하게 형성시켜 천연한지 또는 한지 섬유 단독으로는 얻기 힘든 외관, 물성 및 성능 등을 부여하여, 물/액체의 일정한 압력에 따른 내부로의 침투를 차단하며(방수성: waterproofness) 동시에 내부에 있는 수증기 형태를 바깥으로 배출하도록(투습성: water vapor transmission) 하는 제조 방법.It is made of natural paper or Korean paper by forming a uniform film firmly by using Hanji fiber made from Korean bark as the main raw material, or high-molecular polymer such as acrylic resin, urethane resin, fluorine resin and polyethylene resin. The fiber alone imparts appearance, properties and performance, which is difficult to obtain by itself, preventing the penetration of water / liquid into the interior under constant pressure (waterproofness) and simultaneously discharging the water vapor form inside (outdoor). water vapor transmission).
KR1020080041118A 2008-05-02 2008-05-02 Functional fabrics made of korean paper (hanji) KR20090115326A (en)

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