KR20090095721A - Boots's manufacturing methods - Google Patents

Boots's manufacturing methods Download PDF

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Publication number
KR20090095721A
KR20090095721A KR1020080020830A KR20080020830A KR20090095721A KR 20090095721 A KR20090095721 A KR 20090095721A KR 1020080020830 A KR1020080020830 A KR 1020080020830A KR 20080020830 A KR20080020830 A KR 20080020830A KR 20090095721 A KR20090095721 A KR 20090095721A
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Prior art keywords
weight
rubber
boots
mixture
mold
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KR1020080020830A
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Korean (ko)
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인 선 정
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인 선 정
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Priority to KR1020080020830A priority Critical patent/KR20090095721A/en
Publication of KR20090095721A publication Critical patent/KR20090095721A/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D35/00Producing footwear
    • B29D35/0009Producing footwear by injection moulding; Apparatus therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/80Component parts, details or accessories; Auxiliary operations
    • B29B7/82Heating or cooling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/80Component parts, details or accessories; Auxiliary operations
    • B29B7/88Adding charges, i.e. additives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C71/00After-treatment of articles without altering their shape; Apparatus therefor
    • B29C71/02Thermal after-treatment

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Heating, Cooling, Or Curing Plastics Or The Like In General (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)

Abstract

A method for manufacturing boots is provided to prevent deformation of the shape by performing one foaming within an injection mold through foaming particles for production of rubber boots. A method for manufacturing boots comprises the steps of: airtight mixing a natural rubber and a synthetic rubber in a mixer of 125°C; adding carbon, light calcium carbonate, and vulcanizing agent and heating and mixing them; adding zinc oxide, depilation wax, promoter, softening oil, zinc stearic acid, antiaging agent, and antioxidant and heating and mixing them; passing a mixture for rubber boots through a roller of 2 mm interval and dropping the mixture in a roll type; transferring the mixture to a machine for manufacturing rubber particles of 80°C ~ 105°C, and cutting it in diameter 2 mm; cooling the mixture and preparing foam particles; injecting the mixture in a foam injector of 75°C ~ 95°C and a mold of 170°C; passing a molding box of 85°C ~ 65°C through a foot shape mold(LAST) after vulcanization for 15 minutes and cooling it.

Description

장화의 제조방법 {Boots's manufacturing methods}Boots's manufacturing methods

본 발명은 장화의 제조방법에 관한 것으로 좀더 상세하게는 천연고무와 합성고무(SBR)를 혼합하고 카본, 경질탄산칼슘, 가류제 등을 첨가하여 고무장화 생산용발포 입자로 제조하여 사출성형과 탈모를 완성하므로써 가볍고 촉감이 부드러운 장화를 제조할 수 있게 한 것이다.The present invention relates to a method of manufacturing rain boots, and more specifically, natural rubber and synthetic rubber (SBR) are mixed, and carbon, hard calcium carbonate, and a vulcanizing agent are added to prepare rubber foam production foam particles for injection molding and hair loss. By completing this, it is possible to manufacture a light and soft boots.

종래에 사용되고 있는 장화는 대부분 합성수지나 유화 회사에서 생산된 EVA 입자를 소재로 하여 발포사출기에서 발포기로 유입해서 공기와 함께 압축 발포시켜 성형을 하고 변형을 방지하기 위해 발 모양의 금형(LAST)에 넣어 냉각장치를 경유하는 과정에 냉각시켜 완제품을 제조하여 착용하였으나 하절기에 기온이 상승하면 장화에 함유된 공기가 증발하는 과정에 장화가 축소되어 변형이 되는 단점이 있었으며 착용하고 보행시에 구부러지는 경우 원상태로 잘 복원이 되지 않았고 경질이기 때문에 착용감이 좋지 않았으며 무거운 등의 폐단이 있었다.Most of the boots used in the past are made of synthetic resin or EVA particles produced by an emulsifying company, and flowed into the foaming machine from the foam injection molding machine, followed by compression and foaming together with air, and then put into a foot-shaped mold (LAST) to prevent deformation. The finished product was manufactured by wearing the product by cooling it through a cooling system, but when the temperature increased in the summer, the boots contained therein were deformed and deformed during the evaporation of the air contained in the boots. Because it was not restored well and was hard, it was not comfortable to wear and had a heavy back.

본 발명은 상기와 같은 문제점을 해소할 수 있는 장화의 제조방법을 발명한 것으로 천연고무와 합성고무를 고온의 혼합기에서 일차로 혼합하고 카본, 경질탄산칼슘, 가류제등의 첨가물을 혼합하는 과정을 거처 오픈롤러 에서 내리기를 하고 고무입자 제조기에 넣어 직경 2 mm 크기로 절단함과 동시에 급냉하여 사출이 가능한 고무장화 생산용 발포입자를 만든 후 75℃ ~ 95℃의 발포사출기에서 사출하고 7분 ~ 8분간 가류한 다음 탈모하여 변형이 되지 않고 충격흡수 및 완충작용을 하는 착용감이 좋은 연질의 친환경적인 고무장화를 제공할 수 있게 한 것이다.The present invention has been invented a method of manufacturing rain boots that can solve the above problems, the process of mixing the natural rubber and synthetic rubber in a high-temperature mixer and mixing additives such as carbon, hard calcium carbonate, vulcanizing agent Get off at the open roller and cut into 2mm in diameter into the rubber particle maker, and at the same time, make foamed particles for rubber boots production by quenching and inject them in the foam injection molding machine at 75 ℃ ~ 95 ℃. After vulcanizing for a minute, it is possible to provide a comfortable, soft, eco-friendly rubber boots that do not deform and deform without impacting.

이와같은 본 발명은 천연고무와 합성고무를 혼합하고 카본, 경질탄산칼슘, 가류제 등을 각각 첨가, 가열, 혼합하여 고무장화 생산용 발포입자를 제조해 사출몰드 내에서 한차례 발포를 거처 중량이 가볍고 변형이 되지 않는 촉감이 부드러워 착용감이 좋은 장화를 재료의 낭비나 환경의 오염이 없이 능률적으로 생산할 수 있는 효과가 있다.In the present invention, natural rubber and synthetic rubber are mixed, and carbon, hard calcium carbonate, and vulcanizing agent are added, heated, and mixed to prepare foamed particles for producing rubber boots, and foamed once in an injection mold. The soft, non-deformable touch can effectively produce boots that are comfortable to wear without waste of material or pollution of the environment.

천연고무 (Natural Rubber) 42.81 중량 %Natural Rubber 42.81 Weight%

합성고무 (Styrene butadiene rubber) 14.26 "Synthetic rubber (Styrene butadiene rubber) 14.26 "

카본 (carbon) 28.53 "Carbon 28.53 "

경질(輕質)탄산칼슘 (CaCo3) 11.4 "Hard Calcium Carbonate (CaCo3) 11.4 "

가류제(유황)(Vulcanzing Agent) 0.31 "Vulcanzing Agent 0.31 "

산화아연 (zn0) 0.35 "Zinc Oxide (zn0) 0.35 "

발포제(發泡劑)(Blowing Agent) 0.9 "Blowing Agent 0.9 "

탈모왁스 (STE) 0.21 "Hair Loss Wax (STE) 0.21 "

촉진제(DCP) 0.03 "Accelerator (DCP) 0.03 "

연화오일(process oil) 0.56 "Process oil 0.56 "

징크스타아린산 (ENST) 0.19 "Zinc Stearic Acid (ENST) 0.19 "

노화방지제 (SPP) 0.37 "Anti Aging Agent (SPP) 0.37 "

방산화제 (AT-76) 0.08 " Fire Retardant (AT-76) 0.08 "

계 100 "        Total 100 "

<제 1 공정><1st process>

천연고무 42.81 중량 % 와 합성고무 14.26 중량 % 를 배합비로 125℃가 유지되는 혼합기에서 20분간 밀봉 믹싱을 한다.Seal mix for 42.81% by weight of natural rubber and 14.26% by weight of synthetic rubber in a mixer maintained at 125 ° C for 20 minutes.

<제 2 공정><Second process>

제 1 공정을 거친 혼합물에 카본 28.53 중량 % , 경질 탄산칼슘 11.4 중량 % , 가류제 0.31 중량 % 를 각각 첨가하여 125℃의 혼합기에서 20분간 가열 혼합한다.28.53% by weight of carbon, 11.4% by weight of hard calcium carbonate, and 0.31% by weight of vulcanizing agent were added to the mixture which passed through the first step, and the mixture was heated and mixed for 20 minutes in a mixer at 125 ° C.

<제 3 공정><Third process>

제 2 공정을 거친 혼합물에 산화아연 0.35 중량 % , 발포제 0.9 중량 % , 탈모왁스 0.21 중량 % , 촉진제 0.03 중량 % , 연화오일 0.56 중량 % , 징크스타아린산 0.19 중량 % , 노화방지제 0.37 중량 % , 방산화제 0.08 중량 % 를 각각 배합비로 첨가하여 125℃의 혼합기에서 20분간 가열 혼합하여 고무장화 생산용 혼합물을 만든다.0.35 wt% zinc oxide, 0.9 wt% blowing agent, 0.21 wt% hair loss wax, 0.03 wt% accelerator, 0.56 wt% softening oil, 0.19 wt% zinc stararic acid, 0.37 wt% antioxidant, Add 0.08% by weight of each agent in the blending ratio and heat-mix for 20 minutes in a mixer at 125 ° C to produce a rubber boot mixture.

<제 4 공정><4th process>

제 3 공정을 거친 고무장화 생산용 혼합물을 꺼내어 2 mm 간격으로 롤러를 통과시켜 두루말이 형태로 내리기를 한다.The mixture for the production of rubber boots after the third process is taken out and passed through the rollers at intervals of 2 mm to lower the roll into a form.

<제 5 공정><5th process>

제 4 공정을 거친 두루말이를 80℃ ~ 105℃가 유지되는 고무입자 제조기에 넣어 직경 2 mm 크기로 절단함과 동시에 급냉시켜 즉시 사출이 가능한 고무장화 생산용 발포입자를 제조한다.The rolled through the fourth process is put into a rubber particle maker maintained at 80 ℃ ~ 105 ℃ cut to a size of 2 mm in diameter and quenched at the same time to produce a foamed foam for producing rubber boots can be injected immediately.

<제 6 공정><6th process>

제 5 공정을 거친 직경 2 mm 크기의 고무장화 생산용 발포입자를 75℃ ~ 95℃가 유지되는 발포사출기와 170℃ 가 유지되는 몰드에서 사출하고 7분 ~ 8분간 가류 후 탈모한다.The foamed particles for rubber boots production having a diameter of 2 mm passed through the fifth process are injected from a foam injection molding machine maintained at 75 ° C. to 95 ° C. and a mold maintained at 170 ° C., and dehydrated after 7 minutes to 8 minutes.

<제 7 공정><7th process>

제 6 공정을 거처 탈모한 발모양금형(LAST)을 85℃ ~ 65℃의 성형상자를 15분 동안 통과시킨 후 냉각하여 완제품을 제조하는 것이다.After passing through the sixth step of the hair loss mold (LAST) through a molding box of 85 ℃ ~ 65 ℃ for 15 minutes to cool to manufacture the finished product.

이와같이 된 본 발명은 천연고무 42.81 중량 % 와 합성고무 14.26 중량 % 를 배합비로 하여 125℃가 유지되는 혼합기에서 20분간 밀봉 혼합을 하고 카본 28.53 중량 % ,경질탄산칼슘 11.4 중량 % , 가류제 0.31 중량 % 를 2차로 각각 첨가하여 가열혼합 한 후 나머지 첨가물인 산화아연 0.35 중량 % , 발포제 0.9 중량 % , 탈모왁스 0.21 중량 % , 촉진제 0.03 중량 % , 연화오일 0.56 중량 % , 징크스타아린산 0.19 중량 % , 노화방지제 0.37 중량 % , 방산화제 0.08 중량 % 를 각각 배합비 로 혼합기에 첨가하여 계속해 가열 혼합한 고무장화 생산용 혼합물을 꺼내어 롤러의 간격을 2 mm 로 조정하고 2 mm 간격의 롤러를 통과시켜 두루말이 형태로 내리기를 하고 80℃ ~ 105℃가 유지되는 고무입자 제조기에 이송하여 직경 2 mm 크기로 절단함과 동시에 급냉시켜 즉시 사출이 가능한 고무장화 생산용 발포입자를 제조하여 75℃ ~ 95℃ 가 유지되는 발포 사출기와 170℃ 가 유지되는 몰드에서 사출한 후 7분 ~ 8분간 가류하고 탈모한 발모양금형(LAST)을 85℃ ~ 65℃의 성형상자를 15분간 통과 시킨 후 냉각하여 완제품을 제조하게 되는 것이다.Thus, the present invention is a mixture of 42.81% by weight of natural rubber and 14.26% by weight of synthetic rubber in a mixer maintained at 125 ℃ for 20 minutes, 28.53% by weight carbon, 11.4% by weight calcium carbonate, 0.31% by weight vulcanizing agent After the second mixture, the mixture was heated and mixed, followed by 0.35% by weight of zinc oxide, 0.9% by weight of blowing agent, 0.21% by weight of hair loss wax, 0.03% by weight of accelerator, 0.56% by weight of softened oil, 0.19% by weight of zinc stearic acid, and aging. 0.37% by weight of inhibitor and 0.08% by weight of flame retardant were added to the mixer at the mixing ratio, and then the mixture for production of the rubber boots produced by heat mixing was taken out, the rollers were adjusted to 2 mm, and the rollers were passed through the rollers having a gap of 2 mm to form a roll. The rubber boots are transported to the rubber particle maker, which is maintained at 80 ℃ ~ 105 ℃, cut into 2mm diameter and quenched at the same time to produce rubber boots that can be injected immediately. After forming foam particles for injection molding and injection molding in the mold maintained at 75 ℃ ~ 95 ℃ and the mold maintained at 170 ℃, vulcanized for 7 minutes to 8 minutes, and the deformed hair mold (LAST) of 85 ℃ ~ 65 ℃ After passing through the box for 15 minutes, the product is cooled and manufactured.

Claims (1)

천연고무 42.81 중량 % , 합성고무 14.26 중량 % 를 배합비로 125℃ 가 유지되는 혼합기에 넣어 20분간 밀봉 믹싱을 하고 카본 28.53 중량 % , 경질탄산칼슘 11.4 중량 % , 가류제 0.31 중량 % , 를 첨가하여 가열 혼합한 후 나머지 첨가물인 산화아연 0.35 중량 % , 발포제 0.9 중량 % , 탈모왁스 0.21 중량 % , 촉진제 0.03 중량 % , 연화오일 0.56 중량 % , 징크스타아린산 0.19 중량 % , 노화방지제 0.37 중량 % , 방산화제 0.08 중량 % 를 각각 배합비로 첨가하여 계속 가열 혼합한 고무장화 생산용 혼합물을 꺼내어 2 mm 간격의 롤러를 통과시켜 두루말이 형태로 내리기를 하고 80℃ ~ 105℃ 가 유지되는 고무입자 제조기에 이송하여 직경 2 mm 크기로 절단함과 동시에 급냉시켜 즉시 사출이 가능한 고무장화 생산용 발포입자를 제조하여 75℃ ~ 95℃ 가 유지되는 발포사출기와 170℃ 가 유지되는 몰드에서 사출한 후 7분 ~ 8분간 가류후 탈모한 발모양 금형(LAST)을 85℃ ~ 65℃ 의 성형상자를 15분간 통과시킨 후 냉각하여 완제품을 제조함을 특징으로 하는 고무장화의 제조방법Add 42.81% by weight of natural rubber and 14.26% by weight of synthetic rubber to a mixer maintained at 125 ° C in a mixing ratio for 20 minutes to seal-mix and heat by adding 28.53% by weight of carbon, 11.4% by weight of hard calcium carbonate and 0.31% by weight of vulcanizing agent. After mixing, the remaining additives were zinc oxide 0.35% by weight, blowing agent 0.9% by weight, hair loss wax 0.21% by weight, accelerator 0.03% by weight, softening oil 0.56% by weight, zinc stararic acid 0.19% by weight, antioxidant 0.37% by weight, fire retardant Take out the mixture for the production of rubber boots which are continuously heated and mix by adding 0.08% by weight of each, and pass through the roller of 2 mm intervals to roll down the form and transfer it to the rubber particle maker maintained at 80 ℃ ~ 105 ℃. Manufactured foam particles for the production of rubber boots that can be immediately injected by quenching and cutting at the size of mm, and 170 ℃ and foam injection molding machines are maintained at 75 ℃ ~ 95 ℃. After injection in the mold after vulcanization 7-8 minutes process for producing a rubber boots, characterized in that to the foot-shaped mold hair loss (LAST) cooling after passing through the forming box of 85 ℃ ~ 65 ℃ 15 bungan manufacture the finished product
KR1020080020830A 2008-03-06 2008-03-06 Boots's manufacturing methods KR20090095721A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101527393B1 (en) * 2014-03-10 2015-06-09 문소수 Boots manufacturing method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101527393B1 (en) * 2014-03-10 2015-06-09 문소수 Boots manufacturing method

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