KR20090042130A - Low temperature sealing heat constriction film having gas barrier disposition - Google Patents

Low temperature sealing heat constriction film having gas barrier disposition Download PDF

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Publication number
KR20090042130A
KR20090042130A KR1020080030411A KR20080030411A KR20090042130A KR 20090042130 A KR20090042130 A KR 20090042130A KR 1020080030411 A KR1020080030411 A KR 1020080030411A KR 20080030411 A KR20080030411 A KR 20080030411A KR 20090042130 A KR20090042130 A KR 20090042130A
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South Korea
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resin layer
layer
gas barrier
low temperature
nylon
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KR1020080030411A
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Korean (ko)
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구미경
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구미경
주식회사 에스케이지플라스텍
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Priority to PCT/KR2008/003534 priority Critical patent/WO2009054590A1/en
Publication of KR20090042130A publication Critical patent/KR20090042130A/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/28Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties

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  • Wrappers (AREA)

Abstract

A heating constriction film having gas barrier property at low temperature is provided to improve visual beauty after package and to prevent deformation of shapes of wrapped dairy products. A heating constriction film having gas barrier property at low temperature comprises the followings: a tepidity sealing resin layer(10) located in an inner side; a first nylon layer(20) welded by a glue layer(30) in an outer side of the tepidity sealing resin layer; a gas intercepting resin layer(40) having gas barrier property and formed to an outside of the first nylon layer; a second nylon layer(50) laminated to outer side of the gas intercepting resin layer; and a finishing resin layer(70) using the glue layer. The tepidity sealing resin layer is made of ethylene vinyl acetate can be contracted at low temperature easily.

Description

가스차단성 저온 씰링 열수축필름{low temperature sealing heat constriction film having gas barrier disposition}Low temperature sealing heat constriction film having gas barrier disposition}

본 발명은 가스차단성 저온 씰링 열수축필름에 관한 것으로, 더 상세하게는 가스 차단율과 차단 시간을 연장하고, 열수축 포장시 찢어지는 현상에 대한 내충격성을 향상시킬 수 있도록 발명된 것이다.The present invention relates to a gas barrier low temperature sealing heat shrink film, and more particularly, to extend gas blocking rate and breaking time, and to improve impact resistance against tearing during heat shrink packaging.

일반적으로, 식품포장에 사용되는 포장재는 피포장물의 변패를 방지하고 선도저하를 최소화하기 위하여 가스 및 수분 차단성이 우수해야한다.In general, packaging materials used for food packaging should have excellent gas and moisture barrier properties in order to prevent deterioration of the package and to minimize freshness.

특히 육류 제품과 육류로 가공된 육가공식품의 경우에는 다량의 수분을 함유하고 주변 온도에 의해 쉽게 변질되는 문제점이 있어 냉장보관을 요하고, 유동 과정 중에 신선도가 쉽게 저하되는 폐단이 있는 것이다.In particular, meat products and processed meat processed meat is a problem that contains a large amount of moisture and easily deteriorated by the ambient temperature requires refrigeration storage, there is a closed end that freshness is easily reduced during the flow process.

따라서 근래에는 육가공 제품을 포장하는 포장재로써 열에 의해 수축되는 열 수축필름을 사용하고 있는 실정이다.Therefore, in recent years, the use of heat shrinkable film shrinkage by heat as a packaging material for packaging meat products.

즉, 열 수축 필름에 육가공 제품을 넣은 다음 열을 가하면 제조 시 설정된 수축율로 그 폭 방향과 길이방향으로 수축하면서 내부의 공기를 외부로 배출하면서 내부를 진공상태로 간편히 밀폐시키고 포장할 수 있게 되는 것이다.In other words, if the meat product is placed in a heat shrinkable film and then heat is applied, the shrinkage in the width direction and the lengthwise direction at the shrinkage rate set at the time of manufacture allows the inside to be easily sealed and packed in a vacuum while the air is discharged to the outside. .

이러한 육가공 제품 포장용 열 수축 필름은 미열의 온도에서도 쉽게 수축되도록 에틸렌 비닐 아세테이트(이후 EVA로 칭함 ; Ethylene Vinyl Acetate)와 같은 미온실링수지로 제조되어 이 열 수축 필름을 수축시키기 위해 가해지는 열에 의한 육가공 제품의 손상을 방지한다.The heat shrinkable film for packaging meat products is made of luke-sealing resins such as ethylene vinyl acetate (hereinafter referred to as EVA; Ethylene Vinyl Acetate) so that the shrinkable film shrinks easily even at a low temperature, and the heat processed meat product is applied to shrink the heat shrinkable film. To prevent damage.

또한, 육가공 제품 포장용 열 수축 필름은 통상의 열 수축 필름의 제조장치와 동일하게 합성수지 원료를 용융시켜 압출하는 압출기와, 이 압출기에서 압출된 원료를 두겹의 필름형상으로 형성하면서 미연신 상태의 필름을 필요로 하는 수축률을 가지도록 연신시키는 연신기와, 이 연신기를 통해서 제조된 필름을 이송하여 권취하는 이송권취기로 구성된다.In addition, the heat shrink film for packaging meat products is an extruder that melts and extrudes a synthetic resin raw material in the same manner as a conventional apparatus for producing a heat shrink film, and forms an unstretched film while forming the raw material extruded by the extruder in a double film form. It consists of the drawer which draws | stretches so that it has a required shrinkage | contraction rate, and the transfer winder which conveys and winds up the film manufactured through this drawer.

한편 근래에는 열 수축필름이 내부에 육가공제품을 삽입한 후 수축되어 밀폐된 상태에서 외부의 공기 및 물의 침입을 방지하여 육가공제품의 신선도를 장기간 유지할 수 있도록 다층 구조로 제조되고 있는 실정이다.On the other hand, in recent years, the heat shrink film is manufactured in a multi-layer structure so as to maintain the freshness of the processed meat products by inserting the processed meat products therein to prevent the intrusion of outside air and water in a sealed state.

종래 육가공 제품 포장용 열 수축 필름은 제조된 후 두 겹의 필름이 밀착되어 있어, 그 마찰력에 의해 두 겹의 사이를 벌려 포장하고자 하는 육가공 제품을 삽입하기 어려운 문제점이 있었던 것이다.The heat shrink film for packaging conventional meat products has been a problem that it is difficult to insert the meat products to be packaged to open the two layers by the friction force after the two-layer film is in close contact with each other.

따라서 육가공 제품이 포장 시 외부에서 노출되는 시간이 길어지고, 이로 인해 신선도가 저하되는 폐단이 있으며, 포장작업의 작업효율이 저하되는 문제점이 있었던 것이다.Therefore, the time is exposed to the outside during the packaging of the processed meat products, there is a closed end is reduced due to the freshness, there was a problem that the work efficiency of the packaging operation is reduced.

또한, 육가공 제품 포장용 열 수축 필름 내부에 육가공 제품을 삽입한 후 수축할 경우 필름과 육가공 제품이 밀착되어 소비자가 포장된 육가공 제품을 조리하기 위하여 포장을 벗길 경우 필름 내측면에 육가공 제품이 들러붙어 떨어지게 되는 문제점이 있었으며, 과도하게 수축될 경우 그 수축에 의해 육가공 제품이 가압되어 그 형상이 변해 외관미를 저하시키는 폐단이 있었던 것이다.In addition, when the meat product is inserted into the heat shrink film for packaging the meat product and then contracted, the film and the meat product are in close contact with each other, so that the meat product sticks to the inner side of the film when the consumer peels off the package to cook the packaged meat product. There was a problem that, when excessively contracted, the meat products are pressed by the contraction, the shape is changed, there was a closed end to reduce the appearance beauty.

본 고안의 목적은 미열의 온도로 열 수축되는 필름의 내측면에 파우더층이 구비되어 이 파우더층에 의해 두 겹의 필름이 달라붙는 마찰력을 최소화하여 포장 시 두 겹의 필름이 잘 떨어지게 함으로써 포장이 용이하고, 포장 시 외관미와 포장을 쉽게 벗겨 낼 수 있는 포장용 열 수축 필름을 제공하는 데 있다 The purpose of the present invention is to provide a powder layer on the inner surface of the film heat-shrinked at a sub-heat temperature, thereby minimizing the frictional force of the two layers of film adhered by the powder layer so that the two layers of the film fall off during packaging. To provide a heat shrink film for packaging that is easy and can easily peel off appearance and packaging during packaging.

이러한 본 발명의 목적은, 가장 내측에 위치되는 미온실링수지층(10)과,An object of the present invention, the lukewarm sealing resin layer 10 is located on the innermost side,

미온실링수지층(10)의 외측에 접착제층(3)으로 접합되는 제1나이론층(20)과,A first nylon layer 20 bonded to the outer side of the mesosealing resin layer 10 by an adhesive layer 3,

제1나이론층(20)의 외부로 형성되며 가스 차단기능을 갖는 가스차단수지층(40),The gas barrier resin layer 40 is formed outside the first nylon layer 20 and has a gas blocking function.

이 가스차단수지층(40)의 외측으로 적층되는 제2나이론층(50)과,A second nylon layer 50 stacked outside the gas barrier resin layer 40,

상기 제2나이론층(50)의 외부로 접착제층(60)을 이용해 적층되는 마감수지 층(70)으로 구성되는 것에 의해 달성된다.It is achieved by being composed of a finish resin layer 70 laminated using the adhesive layer 60 to the outside of the second nylon layer 50.

상기한 본 발명의 구성에 의하면, 포장 시 열 수축 필름이 과도하게 수축되어 포장되는 유가공 제품의 형상을 변형시키는 것을 방지하고 포장 후 외관미를 증대시킬 수 있다.According to the configuration of the present invention described above, it is possible to prevent the heat-shrinkable film from being excessively deformed during packaging to deform the shape of the packaged dairy product and increase the appearance after packaging.

또 나이론수지가 2중으로 형성되어 가스 차단율을 향상시킴과 아울러 가스 차단 시간을 연장할 수 있다.In addition, the nylon resin is doubled to improve the gas blocking rate and to extend the gas blocking time.

그리고, 방수 기능 및 강도가 향상되어 포장중 열수축 포장시 찢어지는 현상에 대한 내충격성을 향상시킬 수 있다.In addition, the waterproof function and the strength is improved to improve the impact resistance against tearing during the heat shrink packaging during packaging.

또, 마감수지층에 의해 내충격과 인장력에 대해서도 우수한 강도를 유지하여 제품의 신뢰도와 품질이 향상되는 등의 매우 유용한 고안인 것이다.In addition, the finish resin layer is a very useful design, such as maintaining the excellent strength against impact and tensile strength to improve the reliability and quality of the product.

이하, 본 발명의 바람직한 실시예를 첨부된 도면에 의거하여 상세히 설명하면 다음과 같다.Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings.

도 1은 본 발명의 단면구조를 보인 단면도이다.1 is a cross-sectional view showing a cross-sectional structure of the present invention.

도 2는 도 1의 일부 확대 단면도이다.2 is a partially enlarged cross-sectional view of FIG. 1.

본 발명의 목적은 미열의 가열에도 열 수축되는 재질로 다중겹의 튜브형상으로 제조된다.An object of the present invention is made of a multi-ply tube shape made of a material that is heat-shrinkable even under mild heating.

즉, 도 1에서 도시한 바와 같이 열 수축필름은 다중겹으로 성형되면서도 전체 두께가 얇은 필름부재가 두 겹으로 겹쳐져 양 측단이 각각 길이 방향으로 이어져 두 겹의 필름을 벌여 그 사이로 육가공 제품을 삽입하여 포장할 수 있고, 삽입되어 포장되는 육가공 제품의 크기에 맞게 그 길이를 절단하여 사용할 수 있도록 제조된다.That is, as shown in Figure 1, the heat shrinkable film is molded in multiple layers, but the entire thickness of the thin film member is overlapped in two layers, so that both ends are extended in the longitudinal direction, thereby earning two layers of film and inserting the processed meat product therebetween. It can be packaged and manufactured so that its length can be cut to fit the size of the meat product to be inserted and packaged.

본 발명의 가장 내측에는 미열의 가열에도 열 수축되도록 연신처리되어 가열 시 수축되어 그 내부를 실링시키는 미온실링수지층(10)이 위치된다.At the innermost side of the present invention, the lukewarm sealing resin layer 10 is stretched so as to heat shrink even when heated under heat, and shrinks when heated to seal the inside thereof.

상기 미온실링수지층(10)은 미열의 온도에도 열 수축이 용이한 에틸렌 비닐 아세테이트(이후 EVA로 칭함 ; Ethylene Vinyl Acetate)로 형성되며, 이 EVA수지는 열 수축 필름 제조장치(미도시)의 압출기에서 압출된 후 연신기에서 미열의 온도에도 제품의 포장을 위한 수축율로 수축되도록 연신 처리되어 제조된다.The mil sealing resin layer 10 is formed of ethylene vinyl acetate (hereinafter referred to as EVA; Ethylene Vinyl Acetate) which is easy to heat shrink even at a low temperature, the EVA resin is an extruder of a heat shrink film manufacturing apparatus (not shown) After being extruded in the drawing machine is drawn and drawn to shrink at a shrinkage rate for the packaging of the product even at the temperature of the mild heat.

또 미온실링수지층(10)은 두께가 얇은 원통형의 튜브형상으로 제조된 후 롤러에 의해 양 측단이 접혀지면서 두겹으로 겹쳐져 형성되는 것이다.In addition, the lukewarm sealing resin layer 10 is formed in a thin cylindrical tube shape and then formed by overlapping two sides while being folded at both sides by a roller.

이때, 두 겹으로 겹쳐진 미온실링수지층(10)의 내부에 미세한 인체에 무해한 파우더를 전면에 걸쳐 고르게 뿌려져 롤러에 의해 압착되어 맞붙는 미온실링수지층(10) 간의 접촉을 방지할 수도 있다.At this time, evenly spread the powder harmless to the human body finely in the inside of the two layers of the luke-sealing resin layer 10 overlapped by the roller may be prevented contact between the luke-sealing resin layer (10).

여기서 미온실링수지층(10)은 미열의 온도를 가열해도 필요한 수축율을 얻을 수 있는 EVA수지로 형성되어 포장 시 필름부재를 수축시키기 위해 가열되는 온도에 의해 육가공 제품의 변질을 방지하고 신선도를 유지할 수 있게 되는 것이다.The lukewarm sealing resin layer 10 is formed of an EVA resin that can obtain the required shrinkage rate even when the temperature of the heat is heated to prevent deterioration of the processed meat product and maintain freshness by the temperature heated to shrink the film member during packaging. Will be.

한편, 상기 미온실링수지층(10)은 미열의 고온에도 필요한 수축율을 얻을 수 있는 장점이 있으나, 가스 투과율이 높아 포장 후 장기간 보관 시 미세한 틈으로 외부의 공기가 유입되어 포장된 육가공 제품의 선도를 저하시키는 문제점이 있는 것이다.On the other hand, the lukewarm sealing resin layer 10 has the advantage of obtaining the required shrinkage even at high temperatures of the low heat, but the gas permeability is high, the long-term storage after packaging, the outside air flows into the fine gap to lead the packaged meat products There is a problem to degrade.

이러한 문제점을 해결하기 위하여 상기 미온실링수지층(10)의 외측에 접착성이 있는 접착제로 형성되는 접착제층(3)으로 제1나이론층(20)과 가스 차단성이 우수한 가스차단수지층(40) 및 이 가스차단수지층(40)의 외측으로 물에 강하고, 방수성이 우수한 제2나이론층(50)이 순차적으로 적층하게 된다.In order to solve this problem, the first nylon layer 20 and the gas barrier resin layer 40 having excellent gas barrier properties as an adhesive layer 3 formed of an adhesive with an adhesive on the outside of the meso sealing resin layer 10. And the second nylon layer 50 which is resistant to water and excellent in water resistance to the outside of the gas barrier resin layer 40 are sequentially stacked.

그리고, 제2나이론층(50)의 외부로 접착제층(60)을 이용해 마감수지층(70)을 더 형성하게 된다.Then, the finishing resin layer 70 is further formed by using the adhesive layer 60 to the outside of the second nylon layer 50.

상기 가스차단수지층(40)이 미온실링수지층(10)에 쉽게 접착되지 못하므로 접작체층(30)을 이용해 미온실링수지층(10)과 가스차단수지층(40) 사이에 제1나이론층(20)을 개재하여 미온실링수지층(10)의 외측에서 완전히 접착되어 고정되도록 하는 것이다.Since the gas barrier resin layer 40 is not easily adhered to the lukewarm sealing resin layer 10, the first nylon layer is formed between the lukewarm sealing resin layer 10 and the gas barrier resin layer 40 using the graft layer 30. It is to be completely adhered to and fixed to the outside of the lukewarm sealing resin layer 10 through the (20).

제1나이론층(20)은 상기 가스차단수지층(40)이 가스를 차단성은 우수하나 물에 약해 쉽게 물을 투과시키고, 물에 의해 그 가스 차단성이 저하되는 문제점이 발생되므로 물로부터 상기 가스차단수지층(40)과 미온실링수지층(10)을 보호하는 역할을 하는 것이다.The first nylon layer 20 has a problem that the gas barrier resin layer 40 is excellent in blocking gas, but weak in water, so that water is easily penetrated and the gas barrier property is deteriorated by water. It will serve to protect the blocking resin layer 40 and the lukewarm sealing resin layer (10).

즉, 상기 미온실링수지층(10)의 외측에 가스 차단성은 우수한 반면 물에 약한 가스차단수지층(40)을 제1나이론층(20)에 의해 육가공 제품의 포장 후 장기간 보관 할 경우 외부의 공기와 습기가 미온실링수지층(10) 내부로 유입되는 것을 방 지하게 되는 것이다.That is, when the gas barrier resin layer 40 having excellent gas barrier property on the outside of the lukewarm sealing resin layer 10 is stored for a long time after packaging the processed meat product by the first nylon layer 20 by external air, And it is to prevent the moisture from entering the inside of the lukewarm sealing resin layer (10).

따라서 포장된 육가공 제품의 신선도를 유지할 수 있는 것이다.Therefore, it is possible to maintain the freshness of the packaged meat products.

한편, 상기 가스차단수지층(40)은 가스차단성이 우수한 에틸렌 비닐알코올(EVOH; Ethylene Vinyl Alcohol) 또는 염화 비닐덴 수지(PVDC:Poly Vinyl Dene Chloride) 중에 어느 하나의 성분을 선택하여 제조하게 된다.On the other hand, the gas barrier resin layer 40 is prepared by selecting any one component of ethylene vinyl alcohol (EVOH; Ethylene Vinyl Alcohol) excellent gas barrier properties (PVDC: Poly Vinyl Dene Chloride).

또, 제1나이론층(20)과 제2나이론층(50)은 방수성이 우수하고 강도를 증가시켜 가스차단 효과와 아울러 물에 대해 강한 나일론수지로 제조된다.In addition, the first nylon layer 20 and the second nylon layer 50 are excellent in water resistance and increase in strength, and are made of a nylon resin resistant to water as well as a gas barrier effect.

그리고, 제2나이론층(50)의 외부에서 접착제층(60)에 의해 일체로 접착되는 마감수지층(70)은 가스차단성 저온 씰링 열수축필름 전체를 충격과 인장으로 인해 변형되는 것을 보호하게 된다.In addition, the finishing resin layer 70 which is integrally bonded by the adhesive layer 60 on the outside of the second nylon layer 50 protects the entire gas barrier low temperature sealing heat shrink film from being deformed due to impact and tension.

마감수지층(70)은 폴리프로필렌(PP: Poly Propylene)이 적합하다.The finishing resin layer 70 is suitable for polypropylene (PP).

상기 접착제층(30)(60)은 나이론이나 폴리플로필렌과 같은 타 수지필름을 일체로 접합시킬 수 있는 수지계 접착 성분이면 만족한다.The adhesive layers 30 and 60 are satisfactory as long as they are a resin adhesive component capable of integrally bonding other resin films such as nylon and polyflofilene.

도 1은 본 발명의 단면구조를 보인 단면도.1 is a cross-sectional view showing a cross-sectional structure of the present invention.

도 2는 도 1의 일부 확대 단면도.2 is a partially enlarged cross-sectional view of FIG. 1.

*도면 중 주요 부호에 대한 설명** Description of the major symbols in the drawings *

10 - 미온실링수지층 20 - 제1나이론층10-Mild sealing resin layer 20-1st nylon layer

30 - 접착제층 40 - 가스차단수지층30-Adhesive layer 40-Gas barrier resin layer

50 - 제2나이론층 60 - 접착제충50-2nd Nylon Layer 60-Glue

70 - 마감수지층70-Finishing Floor

Claims (2)

가장 내측에 위치되는 미온실링수지층(10)과,The lukewarm sealing resin layer 10 which is located in the innermost part, 미온실링수지층(10)의 외측에 접착제층(30)으로 접합되는 제1나이론층(20)과,The first nylon layer 20 bonded to the outer side of the meso sealing resin layer 10 by the adhesive layer 30, 제1나이론층(20)의 외부로 형성되며 가스 차단기능을 갖는 가스차단수지층(40),The gas barrier resin layer 40 is formed outside the first nylon layer 20 and has a gas blocking function. 이 가스차단수지층(40)의 외측으로 적층되는 제2나이론층(50)과,A second nylon layer 50 stacked outside the gas barrier resin layer 40, 상기 제2나이론층(50)의 외부로 접착제층(60)을 이용해 적층되는 마감수지층(70)으로 구성되는 것을 특징으로 하는 가스차단성 저온 씰링 열수축필름.Gas-blocking low temperature sealing heat shrink film, characterized in that consisting of a finish resin layer 70 is laminated to the outside of the second nylon layer 50 using an adhesive layer 60. 청구항 1에 있어서, 상기 가스차단수지층(40)은 가스차단성능을 갖는 염화 비닐덴 수지(PVDC:Poly Vinyl Dene Chloride) 또는 에틸렌 비닐알코올(EVOH; Ethylene Vinyl Alcohol)중 어느 하나로 선택되며, The method of claim 1, wherein the gas barrier resin layer 40 is selected from any one of polyvinyl chloride resin (PVDC) or ethylene vinyl alcohol (EVOH) having a gas barrier performance, 상기 마감수지층(70)은 폴리프로필렌(PP: Poly Propylene)으로 이루어지는 것을 특징으로 하는 가스차단성 저온 씰링 열수축필름.The finishing resin layer 70 is a gas barrier low temperature sealing heat shrink film, characterized in that made of polypropylene (PP: Poly Propylene).
KR1020080030411A 2007-10-25 2008-04-01 Low temperature sealing heat constriction film having gas barrier disposition KR20090042130A (en)

Priority Applications (1)

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PCT/KR2008/003534 WO2009054590A1 (en) 2007-10-25 2008-06-20 Heat shrinkable film for low temperature sealing and gas blocking

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KR1020070107866 2007-10-25
KR20070107866 2007-10-25

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20200049229A (en) * 2018-10-31 2020-05-08 (주)태우그린푸드 Vacuum Shrink Packaging Film and Manufacturing Method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20200049229A (en) * 2018-10-31 2020-05-08 (주)태우그린푸드 Vacuum Shrink Packaging Film and Manufacturing Method thereof

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