KR20070035566A - Wettable Polyester Fibers and Fabrics - Google Patents

Wettable Polyester Fibers and Fabrics Download PDF

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KR20070035566A
KR20070035566A KR1020077000825A KR20077000825A KR20070035566A KR 20070035566 A KR20070035566 A KR 20070035566A KR 1020077000825 A KR1020077000825 A KR 1020077000825A KR 20077000825 A KR20077000825 A KR 20077000825A KR 20070035566 A KR20070035566 A KR 20070035566A
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polyester
article
fibers
bis
tert
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콜린 모톤
토마스 프렌드 톰프슨
아슈토쉬 에이취. 샤마
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시바 스폐셜티 케미칼스 홀딩 인코포레이티드
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/20—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons containing organic materials
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/62—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Epidemiology (AREA)
  • Materials Engineering (AREA)
  • Hematology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Manufacturing & Machinery (AREA)
  • Artificial Filaments (AREA)

Abstract

본 발명은 폴리에스테르 섬유나 필라멘트, 그로부터 제조된 직조 또는 부직 직물 및 그로부터 제조된 물품에 습윤성을 제공하는 방법을 목적으로 한다. 이 방법은 폴리에스테르와 1 이상의 알킬 금속 술포네이트(여기서 금속은 Na, K 또는 Li이고, 알킬이 직쇄 또는 측쇄 C12-C15 알킬이거나 또는 직쇄 또는 측쇄 C12-C18 알케닐임)를 포함하는 혼합물을 용융 압출하는 단계를 포함한다. 상기 알킬 금속 술포네이트는 폴리에스테르의 중량 기준으로 2∼5 중량%의 양으로 존재한다. 알칼리 처리 단계와 같은 후처리 단계는 포함되지 않는다. 용융 압출 혼합물은 폴리옥시알킬렌 화합물, 알킬모노에탄올아미드 화합물, 알킬디에탄올아민 화합물 및 폴리에테르아미드 화합물과 같은 특정 첨가제를 포함하지 않는다.The present invention aims at providing wettability to polyester fibers or filaments, woven or nonwoven fabrics made therefrom, and articles made therefrom. The method comprises a polyester and at least one alkyl metal sulfonate, wherein the metal is Na, K or Li, wherein the alkyl is straight or branched C 12 -C 15 alkyl or straight or branched C 12 -C 18 alkenyl Melt extruding the mixture. The alkyl metal sulfonate is present in an amount of 2 to 5% by weight, based on the weight of the polyester. Post-treatment steps such as alkali treatment steps are not included. The melt extrusion mixture does not include specific additives such as polyoxyalkylene compounds, alkylmonoethanolamide compounds, alkyldieethanolamine compounds and polyetheramide compounds.

습윤성 폴리에스테르 섬유 직물Wettable polyester fiber fabric

Description

습윤성 폴리에스테르 섬유 및 직물{Wettable Polyester Fibers and Fabrics}Wetable Polyester Fibers and Fabrics

본 발명은 항구적으로 습윤성을 갖는 폴리에스테르 니트, 직조 및 부직 직물을 제조하는 방법 및 이들로부터 제조된 물품에 관한 것이다.FIELD OF THE INVENTION The present invention relates to methods of making permanently wettable polyester knits, wovens and nonwoven fabrics and articles made from them.

미국특허 제4,357,390호는 대전방지성을 갖는 중공 폴리에스테르 섬유에 대해서 기재하고 있다.U. S. Patent No. 4,357, 390 describes hollow polyester fibers having antistatic properties.

미국특허 제4,351,738호는 고속 마찰 드로우-폴스(draw-false) 트위스트 직조(texturing)를 위한 폴리에스테르 필라멘트 야안에 대해 기재하고 있다.U.S. Patent No. 4,351,738 describes polyester filament yarns for high speed friction draw-false twist texturing.

미국특허 제4,666,764호는 발수성을 갖는 대전방지성 폴리에스테르 직물에 대해서 기재하고 있다.U.S. Patent No. 4,666,764 describes an antistatic polyester fabric having water repellency.

JP-A-08060488, JP-A-08260343, JP-A-08260344, JP-A-08260349, JP-A-09077963, JP-A-10025623 및 JP-A-58081616에서는 바람직한 특정 성질을 갖는 폴리에스테르 섬유 및 직물에 대해서 기재하고 있다.JP-A-08060488, JP-A-08260343, JP-A-08260344, JP-A-08260349, JP-A-09077963, JP-A-10025623 and JP-A-58081616, polyester fibers having specific properties desirable And woven fabrics.

놀랍게도, 폴리에스테르를 알킬 금속 술포네이트와 용융 혼합하고, 상기 혼합물을 압출하여 섬유로 만들면, 항구적인 습윤성과 우수한 수분 조절 특성을 갖는 폴리에스테르 섬유나 필라멘트를 제공하게 된다는 사실을 알아냈다. Surprisingly, it has been found that melt blending polyester with alkyl metal sulfonates and extruding the mixture into fibers provides polyester fibers or filaments with permanent wettability and good moisture control properties.

본 발명은 습윤성 폴리에스테르 직물을 포함하는 물품에 관한 것으로, 상기 직물은 섬유나 필라멘트를 포함하고, 상기 섬유나 필라멘트는 용융 블렌드를 포함하고,상기 용융 블렌드는 폴리에스테르 및 화학식 RSO3M의 알킬 금속 술포네이트 1 이상을 포함하고; 여기서 M은 Na, K 또는 Li이고, R은 직쇄 또는 측쇄 C12-C15 알킬이거나 또는 직쇄 또는 측쇄 C12-C18 알케닐이고, 상기 알킬 금속 술포네이트의 양은 폴리에스테르의 중량 기준으로 2∼5 중량%이며, 상기 섬유나 필라멘트는 후처리되며, 그리고 상기 용융 블렌드는 폴리옥시알킬렌 부가 화합물, 알킬모노에탄올아미드 부가 화합물, 알킬디에탄올아민 부가 화합물 및 폴리에테르아미드 부가 화합물로 이루어진 군으로부터 선택된 계면 활성 화합물을 함유하지 않는, 습윤성 폴리에스테르 직물을 포함하는 물품에 관한 것이다.The present invention relates to an article comprising a wettable polyester fabric, the fabric comprising fibers or filaments, the fibers or filaments comprising a melt blend, the melt blend being a polyester and an alkyl metal of formula RSO 3 M At least one sulfonate; Wherein M is Na, K or Li, R is straight or branched C 12 -C 15 alkyl or straight or branched C 12 -C 18 alkenyl and the amount of alkyl metal sulfonate is from 2 to based on the weight of the polyester 5% by weight, the fibers or filaments are post-treated and the melt blend is selected from the group consisting of polyoxyalkylene addition compounds, alkylmonoethanolamide addition compounds, alkyldiethanolamine addition compounds and polyetheramide addition compounds An article comprising a wettable polyester fabric that does not contain a surfactant compound.

또한 본 발명은 1 이상의 습윤성 직물 층들로부터 물품을 형성하는 물품의 제조방법에 관한 것으로, 상기 직물 층이 폴리에스테르 및 화학식 RSO3M의 알킬 금속 술포네이트 1 이상을 포함하는 혼합물을 용융 압출하여 다수의 섬유나 필라멘트를 만든 후, 상기 섬유나 필라멘트를 냉각하는 공정에 의해 제조되고; 여기서 M이 Na, K 또는 Li이고, R이 직쇄 또는 측쇄 C12-C15 알킬이거나 또는 직쇄 또는 측쇄 C12-C18 알케닐이고, 상기 알킬 금속 술포네이트가 폴리에스테르의 중량 기준으로 2∼5 중량%의 양으로 존재하고, 상기 섬유나 필라멘트의 후처리 단계가 포함되지 않으며, 그리고 상기 혼합물이 폴리옥시알킬렌 부가 화합물, 알킬모노에탄올아미드 부가 화합물, 알킬디에탄올아민 부가 화합물 및 폴리에테르아미드 부가 화합물로 이루어진 군으로부터 선택된 계면 활성 화합물을 함유하지 않는, 물품의 제조방법에 관한 것이다.The present invention also relates to a method of making an article from which the article is formed from one or more wettable fabric layers, wherein the fabric layer comprises melt extrusion of a mixture comprising polyester and at least one alkyl metal sulfonate of formula RSO 3 M Produced by a process of cooling the fibers or filaments after making the fibers or filaments; Wherein M is Na, K or Li, R is straight or branched C 12 -C 15 alkyl or straight or branched C 12 -C 18 alkenyl and the alkyl metal sulfonate is 2 to 5 by weight of the polyester Present in an amount by weight, does not include post-treatment of the fibers or filaments, and the mixture is a polyoxyalkylene addition compound, an alkylmonoethanolamide addition compound, an alkyldiethanolamine addition compound and a polyetheramide addition A method of making an article that does not contain a surfactant compound selected from the group consisting of compounds.

바람직하게는, 제조 물품은 폴리에스테르 섬유나 필라멘트이다.Preferably, the article of manufacture is a polyester fiber or a filament.

후처리 단계는 화학적 단계, 가스, 플라즈마 방전, 코로나 및 알칼리 처리 단계를 포함한다. 알칼리 처리 단계는 이를테면 "Textile Progess, Vol. 20, No. 2, Surface Modification of Polyester by Alkaline Treatments, pp. 13-14"에 기재되어 있다. 이 문헌에서는 이를테면 미국특허 2,590,402; 2,828,528 및 3,135,577를 참고로 하고 있다. 알칼리 처리 단계는 공지되어 있다.Post-treatment steps include chemical steps, gas, plasma discharge, corona and alkali treatment steps. Alkali treatment steps are described, for example, in "Textile Progess, Vol. 20, No. 2, Surface Modification of Polyester by Alkaline Treatments, pp. 13-14". This document describes, for example, US Pat. No. 2,590,402; 2,828,528 and 3,135,577. Alkali treatment steps are known.

기타 부가적인 계면활성제는 본 물품의 제조에 요구되지 않는다.Other additional surfactants are not required for the manufacture of this article.

본 발명의 용융 압출 공정은 폴리옥시알킬렌 부가 화합물 또는 폴리옥시알킬렌 함유 화합물을 포함하지 않는다. 예를 들면, 본 발명의 조성물은 폴리에틸렌 글리콜(PEG), 폴리프로필렌 글리콜, 또는 기타 폴리옥시알킬렌 화합물(폴리알콕실레이트 및 폴리알킬렌 글리콜)을 포함하지 않는다. 폴리옥시알킬렌-함유 화합물은 이를테면 스테아릴 폴리에틸렌 글리콜과 같은 알킬 폴리알콕실레이트이다.The melt extrusion process of the present invention does not include polyoxyalkylene addition compounds or polyoxyalkylene containing compounds. For example, the composition of the present invention does not include polyethylene glycol (PEG), polypropylene glycol, or other polyoxyalkylene compounds (polyalkoxylates and polyalkylene glycols). Polyoxyalkylene-containing compounds are alkyl polyalkoxylates such as stearyl polyethylene glycols.

본 발명의 용융 압출 공정은 알킬모노에탄올아미드 또는 알킬디에탄올아민 부가 화합물을 사용하지 않는다.The melt extrusion process of the present invention does not use alkylmonoethanolamide or alkyldiethanolamine addition compounds.

본 발명의 용융 압출 공정은 폴리에테르아미드 부가 화합물을 사용하지 않는다. 폴리에테르아미드 화합물의 예는 폴리에테르에스테르아미드 부가 화합물 및 폴리에테르폴리아미드 부가 화합물이다.The melt extrusion process of the present invention does not use polyetheramide addition compounds. Examples of the polyetheramide compound are polyetheresteramide addition compounds and polyetherpolyamide addition compounds.

폴리에테르폴리아미드는 이를테면 미국특허 제5,140,065호 및 제4,356,300호에 기재되어 있다. 폴리에테르폴리아미드는 폴리에테르디아민, 디카르복시산, 이합체 산의 중축합반응과 락탐, 이를테면 카프로락탐으로부터 형성된 생성물이다. 폴리에테르폴리아미드는 이를테면 블록 공중합체이다. 예를 들면, 폴리에테르폴리아미드는 카프로락탐, 이합체 산 및 폴리에테르디아민 이를테면 Jeffanime D-2000의 중축합반응으로부터 형성된다.Polyetherpolyamides are described, for example, in US Pat. Nos. 5,140,065 and 4,356,300. Polyetherpolyamides are products formed from polycondensation reactions of polyetherdiamines, dicarboxylic acids, dimeric acids and lactams, such as caprolactam. Polyetherpolyamides are such block copolymers. For example, polyetherpolyamides are formed from polycondensation of caprolactam, dimer acids and polyetherdiamines such as Jeffanime D-2000.

일반적으로, 본 발명의 기술 분야에서 알려진 폴리에테르에스테르아미드는 에스테르 기와 함께 연결된 폴리아미드 및 폴리에테르 세그먼트를 포함한다. 이들은 이를테면 폴리아민, 다염기성 카르복시산 및 폴리옥시알킬렌 글리콜로부터 제조된다. 가장 간단한 방법으로, 이들은 카르복시 말단기를 갖는 폴리아미드(디카르복시산 폴리아미드)와 폴리옥시알킬렌 글리콜의 공중합체이다.In general, polyetheresteramides known in the art include polyamide and polyether segments linked with ester groups. They are prepared from polyamines, polybasic carboxylic acids and polyoxyalkylene glycols, for example. In the simplest way, they are copolymers of polyamides (dicarboxylic acid polyamides) with polycarboxyl end groups and polyoxyalkylene glycols.

포함되지 않는 기타 계면 활성 화합물의 예는 미국특허 제5,882,780호에 기재된 것들이다. Examples of other surfactant compounds not included are those described in US Pat. No. 5,882,780.

예를 들면, 기타 모든 계면활성제는 배제된다.For example, all other surfactants are excluded.

본 발명의 방법에서는 니트, 직조 및 부직 직물로 각각 니트, 직조 또는 결합되는 섬유나 필라멘트를 생성한다.The process of the present invention produces fibers or filaments that are knit, woven, or joined with knit, woven, and nonwoven fabrics, respectively.

본 발명의 용융 압출법은 섬유나 필라멘트를 형성한다. 야안 또는 스테이플 섬유에 대한 연속 필라멘트 스피닝 및 스펀본드 생성 및 용융취입 생성과 같은 부직 공정과 같은 공지 기술에 따라서, 섬유나 필라멘트는 작은 오리피스를 통한 용융 중합체의 압출에 의해 형성된다. 일반적으로, 이와 같이 형성된 섬유나 필라멘트는 연신되어 분자 배향을 유도하고 결정성에 영향을 미쳐 직경을 감소시키고 물리적 성질을 개선시킨다. 스펀본딩 및 용융취입과 같은 부직 공정에서, 섬유나 필라멘트는 이동 플랫 콘베이어와 같은 포라미너스(foraminous) 표면에 직접 퇴적되고, 여러 가지 접합 수단에 의해 적어도 부분적으로 결합(consolidate)된다. 소망하는 특성을 갖는 복합 직물을 제조하기 위해서 서로 다른 공정으로부터 공정들이나 직물을 조합하는 기술은 본 분야의 숙련자에게 공지되어 있다. 그 예는 라미네이트 직물을 제조하기 위해서 방사결합(spunbond) 및 용융취입(meltblown)을 조합하는 것이다. 마찬가지로 이들 공정의 어느 하나 또는 모두는 스테이플 섬유 카딩 공정 또는 부직 스테이플 섬유 카딩 공정으로부터 얻어지는 결합된 직물과의 어떠한 배열로도 조합될 수 있다. 상기 라미네이트 직물에서, 층들은 통상 적어도 부분적으로 결합된다.The melt extrusion method of the present invention forms fibers and filaments. According to known techniques such as continuous filament spinning and spunbond formation and melt blown formation on yarn or staple fibers, fibers or filaments are formed by extrusion of the molten polymer through small orifices. In general, the fibers or filaments thus formed are stretched to induce molecular orientation and affect crystallinity, reducing diameter and improving physical properties. In nonwoven processes such as spunbonding and meltblowing, fibers or filaments are deposited directly on foraminous surfaces, such as mobile flat conveyors, and are at least partially consolidated by various joining means. Techniques for combining processes or fabrics from different processes to produce composite fabrics with desired properties are known to those skilled in the art. An example is the combination of spunbond and meltblown to make laminate fabrics. Either or both of these processes can likewise be combined in any arrangement with the bonded fabric obtained from the staple fiber carding process or the nonwoven staple fiber carding process. In the laminate fabric, the layers are usually at least partially joined.

본 발명은 용융 압출된 2성분 섬유에 이용할 수 있으며, 여기서 성분들 중 하나는 본 발명에 따른 폴리에스테르이다.The invention can be used for melt extruded bicomponent fibers, where one of the components is a polyester according to the invention.

폴리에스테르의 부직 직물은 카딩된 섬유 구조를 갖거나, 또는 섬유나 필라멘트가 임의의 배열로 분포되는 매트를 포함할 수 있다. 직물로부터 만들어지는 물품의 최종 용도에 따라, 직물은 하이드로인탱글먼트(hydroentanglement) 및 스펀-레이스(spun-lace) 기술을 포함하는 수많은 공정중 어느 하나 또는 에어 레잉(air laying) 및 용융-취입 필라멘트, 배트 드로잉(batt drawing), 스티치본딩(stitchbonding) 등에 의해 형성될 수 있다. The nonwoven fabric of polyester may have a carded fiber structure or may comprise a mat in which fibers or filaments are distributed in any arrangement. Depending on the end use of the article made from the fabric, the fabric can be in any of a number of processes including air entanglement and spun-lace techniques or air laying and melt-blown filaments, It may be formed by bat drawing, stitchbonding, or the like.

열가소성 폴리에스테르 섬유는 통상 285∼300℃에서 압출된다.Thermoplastic polyester fibers are usually extruded at 285 to 300 ° C.

본 발명에 따라서, 특정 알킬 금속 술포네이트는 열가소성 폴리에스테르, 이를테면 폴리에틸렌 테레프탈레이트의 용융물에 혼입되고, 폴리에스테르와 함께 섬유나 필라멘트 형태로 압출되고, 상기 섬유와 필라멘트는 후속 또는 동반 공정 단계에서 다시 급냉된 후, 약화되어(attenuate)되어 직물을 형성하게 된다.According to the invention, certain alkyl metal sulfonates are incorporated into melts of thermoplastic polyester, such as polyethylene terephthalate, extruded together with polyester in the form of fibers or filaments, the fibers and filaments being quenched again in subsequent or accompanying process steps And then attenuated to form a fabric.

알킬 금속 술포네이트는 용융 압출되는 중합체 펠릿과 함께 혼합될 수 있다. 공정을 개선하기 위해서, 화합물은 충전제, 이를테면 활석, 그리고 기타 공지의 안정화제를 함유하는 폴리에스테르에 미리 배합되거나 혼합될 수 있다.The alkyl metal sulfonate can be mixed with the polymer pellets that are melt extruded. In order to improve the process, the compounds may be premixed or mixed with polyesters containing fillers, such as talc, and other known stabilizers.

알킬 금속 술포네이트의 혼합은 롤-밀링과 같은 공지 기술에 의해 용융 중합체에 혼합하거나, 밴부리(Banbury) 형 혼합기에서 혼합하거나, 및 압출기 배럴에서 혼합함으로써 실시된다. 열 이력(승온에서 유지되는 시간)은 알킬 금속 술포네이트를 비가열 중합체 입자와 혼합하여 중합체 물질에 상기 술포네이트를 사실상 균일하게 분산시킴으로써 짧아질 수 있으며, 이에 따라 용융 온도에서 강도높은 혼합을 위해 필요한 시간을 줄일 수 있게 된다.Mixing of the alkyl metal sulfonate is carried out by mixing into the molten polymer by known techniques such as roll-milling, mixing in a Banbury type mixer, or mixing in an extruder barrel. The thermal history (time held at elevated temperature) can be shortened by mixing the alkyl metal sulfonate with the non-heated polymer particles to substantially uniformly disperse the sulfonate in the polymeric material, thus making it necessary for intensive mixing at the melting temperature. You can save time.

편리하게는, 알킬 금속 술포네이트는 어떤 경우에 요구될 수 있는 기타 첨가제와 사실상 동시에 또는 연속적으로 첨가될 수 있다. 알킬 금속 술포네이트는 또한 기타 첨가제와 미리 혼련될 수 있으며, 그 블렌드는 다시 중합체에 첨가된다. 어떤 경우에 알킬 금속 술포네이트는 기타 첨가제가 폴리에스테르에 더욱 쉽고 균일하게 분산 또는 용해되도록 하는 추가 장점을 가질 수 있다. 품질을 뱃치-뱃치(batch-to-batch) 식으로 더 쉽게 조절하기 위해서, 소망하는 최종 배합물을 얻도록 중합체의 추가량에 후속적으로 소량씩 혼련되는 중합체/첨가제 블렌드의 농축된 마스터뱃치를 이용하는 것이 바람직할 수 있다. 마스터뱃치나 순수 첨가제는 중합체가 용융되어 있는 상태에서 그리고 중합반응 용기나 트레인을 떠난 후에 새롭게 제조된 중합체에 주입될 수 있으며, 용융된 중합체가 냉각되어 고체로 되거나 추가 공정에 도입되기 전에 그와 함께 혼련될 수 있다.Conveniently, the alkyl metal sulfonate may be added substantially simultaneously or sequentially with other additives that may be required in some cases. The alkyl metal sulfonate can also be premixed with other additives, the blend being added back to the polymer. In some cases, alkyl metal sulfonates may have the added advantage of making other additives more easily and uniformly dispersed or dissolved in the polyester. In order to more easily control the quality in a batch-to-batch fashion, using a concentrated masterbatch of polymer / additive blend which is subsequently kneaded in small amounts in addition to the additional amount of polymer to obtain the desired final blend. It may be desirable. The masterbatch or pure additive can be injected into the newly prepared polymer in the molten state and after leaving the polymerization vessel or train, with the molten polymer before it is cooled to solid or introduced into further processing. Can be kneaded.

따라서, 본 발명의 방법에서는 1 이상의 알킬 금속 술포네이트 및 제1 폴리에스테르를 포함하는 마스터뱃치를 제조하는 단계 및 상기 마스터뱃치 및 제2 폴리에스테르를 포함하는 혼합물을 압출하여 다수의 섬유나 필라멘트를 제조하는 단계, 및 섬유나 필라멘트를 냉각하는 단계를 포함한다.Accordingly, the process of the present invention produces a plurality of fibers or filaments by preparing a masterbatch comprising at least one alkyl metal sulfonate and a first polyester and extruding a mixture comprising the masterbatch and a second polyester. And cooling the fibers or filaments.

본 발명의 마스터뱃치 또는 농축물은, 이를테면 폴리에스테르에 혼입된 1∼75 중량%, 2∼50 중량%, 5∼40 중량%의 농도로 알킬 금속 술포네이트를 함유한다.Masterbatches or concentrates of the present invention contain alkyl metal sulfonates at concentrations of, for example, 1 to 75%, 2 to 50%, 5 to 40% by weight incorporated into polyester.

본 발명의 방법에서, 알킬 금속 술포네이트는 폴리에스테르의 총 중량 기준으로, 2∼5 중량%의 양으로 존재한다. 예를 들면, 알킬 금속 술포네이트는 폴리에스테르의 총 중량 기준으로, 2.5∼4.5 중량%, 2.5∼5 중량%, 2.5∼4 중량%, 3∼4 중량%, 3∼5 중량%, 및 3∼4.5 중량%의 양으로 존재한다. 예를 들면, 본 발명의 알킬 금속 술포네이트는 폴리에스테르의 총 중량 기준으로, 2 중량%, 2.5 중량%, 3 중량%, 3.5 중량%, 4 중량%, 4.5 중량% 및 5 중량%의 양으로 존재한다.In the process of the invention, the alkyl metal sulfonate is present in an amount of from 2 to 5% by weight, based on the total weight of the polyester. For example, the alkyl metal sulfonate may be 2.5 to 4.5 wt%, 2.5 to 5 wt%, 2.5 to 4 wt%, 3 to 4 wt%, 3 to 5 wt%, and 3 to 5 wt%, based on the total weight of the polyester Present in an amount of 4.5% by weight. For example, the alkyl metal sulfonates of the present invention may be present in amounts of 2%, 2.5%, 3%, 3.5%, 4%, 4.5% and 5% by weight based on the total weight of the polyester. exist.

알킬 금속 술포네이트를 본 발명에 따른 폴리에스테르 섬유나 필라멘트에 혼입하면, 이들 물질의 습윤성을 개선시킨다. 이러한 변성은 또한 항구적인 데, 그 이유는 섬유나 필라멘트 및 그로부터 제조된 직물이 에이징 또는 취급 시 그들의 습윤성을 잃지 않기 때문이다. 개선된 습윤성은 오랜 기간 동안 사용한 우에도 성능이 손실되지 않고 반복된 가혹한 조건에 안정하다.Incorporation of alkyl metal sulfonates into the polyester fibers or filaments according to the present invention improves the wettability of these materials. Such denaturation is also permanent because the fibers or filaments and fabrics made therefrom do not lose their wettability upon aging or handling. The improved wettability is stable even in repeated harsh conditions without loss of performance even after long periods of use.

본 발명은 부직 직물, 이를테면 폴리에스테르 직물을 제공하는 것을 목적으로 한다. 본 발명은 또한 종래의 텍스타일 공정에서 위빙(weaving)이나 니팅(kniting)을 위한 실이나 야안을 제공하는 것을 목적으로 한다.The present invention aims to provide a nonwoven fabric, such as a polyester fabric. The present invention also aims to provide yarns or yarns for weaving or knitting in conventional textile processes.

본 발명의 알킬 금속 술포네이트는 부직 직물의 성질, 예를 들면, 기본 중량, 섬유 직경, 섬유의 결합 정도 및 형태, 상승 효과 및 복합 구조물에 영향을 미치는 기타 요소와 무관하게 효과적이다.The alkyl metal sulfonates of the present invention are effective regardless of the nature of the nonwoven fabric, such as basis weight, fiber diameter, degree and form of bonding of the fibers, synergistic effects and other factors affecting the composite structure.

본 발명은 단일 성분 섬유에 한정되지 않는다. 폴리에스테르 2성분 섬유, 특히 사이드-바이-사이드(side-by-sied) 또는 시스-코어(sheath-core) 섬유는 단일 성분 섬유와 동일한 실용상의 장점을 갖는 것으로 예상된다. 단일 폴리에스테르 성분에만 용융 첨가제를 포함하는 것이 특히 효과적일 수 있다.The present invention is not limited to single component fibers. Polyester bicomponent fibers, in particular side-by-sied or sheath-core fibers, are expected to have the same practical advantages as single component fibers. It may be particularly effective to include melt additives only in a single polyester component.

본 발명의 방법은 이를테면 미국특허 4,357,390; 4,666,764 및 4,351,738에 기재된 중공 폴리에스테르 섬유에 이용될 수 있다.The method of the present invention is described, for example, in US Pat. No. 4,357,390; And hollow polyester fibers described in 4,666,764 and 4,351,738.

본 발명의 직물은 0.5∼10 메가라드의 감마선에 조사함으로써 멸균될 수 있다. 감마선 조사에 의한 멸균은 병원복 등에 이용된다. The fabric of the present invention can be sterilized by irradiating gamma rays of 0.5-10 megarad. Sterilization by gamma irradiation is used for hospital clothes and the like.

본 발명에 따라 제조된 폴리에스테르 직조 섬유, 부직 섬유 및 직물은 매우 우수한 인쇄성을 갖는다.Polyester woven fibers, nonwoven fibers and fabrics made according to the invention have very good printability.

본 발명의 섬유 및 직물은 우수한 연성(softness)을 갖는다.The fibers and fabrics of the present invention have good softness.

폴리에스테르는 C8-C14 방향족 디카르복시산, C4-C12 지방족 디카르복시산, C8-C12 시클로지방족 디카르복시산 및 이들의 혼합물로 이루어진 군으로부터 선택된 디카르복시산 반복 단위를 갖는다.The polyester has dicarboxylic acid repeat units selected from the group consisting of C 8 -C 14 aromatic dicarboxylic acids, C 4 -C 12 aliphatic dicarboxylic acids, C 8 -C 12 cycloaliphatic dicarboxylic acids and mixtures thereof.

이러한 이산(diacids)의 예로는 테레프탈산, 이소프탈산, o-프탈산, 나프탈렌 디카르복시산, 시클로헥산 디카르복시산, 시클로헥산디아세트산, 디페닐-4,4'-디카르복시산, 숙신산, 말레산, 글루타르산, 아디프산, 세바스산 및 이들의 혼합물이 있다.Examples of such diacids include terephthalic acid, isophthalic acid, o-phthalic acid, naphthalene dicarboxylic acid, cyclohexane dicarboxylic acid, cyclohexanediacetic acid, diphenyl-4,4'-dicarboxylic acid, succinic acid, maleic acid, glutaric acid , Adipic acid, sebacic acid and mixtures thereof.

예를 들면, 이산은 테레프탈산, 이소프탈산 및 2,6-나프탈렌 디카르복시산이다.For example, diacids are terephthalic acid, isophthalic acid and 2,6-naphthalene dicarboxylic acid.

폴리에스테르의 디올 및 글리콜 부분은 화학식 HO-G-OH(G는 C2-C18 지방족, 시클로지방족 및 방향족 잔기임)로부터 유도된다.The diol and glycol portions of the polyester are derived from the formula HO-G-OH, where G is a C 2 -C 18 aliphatic, cycloaliphatic and aromatic moiety.

이러한 디올 및 글리콜의 예는 에틸렌 글리콜, 디에틸렌 글리콜, 트리에틸렌 글리콜, 프로판-1,3-디올, 프로판-1,2-디올, 부탄-1,4-디올, 펜탄-1,5-디올, 헥산-1,6-디올, 1,4-시클로헥산디메탄올, 3-메틸펜탄-2,4-디올, 2-메틸펜탄-1,4-디올, 2,2-디에틸프로판-1,3-디올, 1,4-디-(히드록시에톡시)벤젠, 2,2-비스(4-히드록시시클로헥실)-프로판, 2,4-디히드록시-1,1,3,3-테트라메틸시클로부탄, 2,2-비스-(3-히드록시에톡시페닐)프로판, 2,2-비스-(4-히드록시프로폭시페닐)에탄 및 이들의 혼합물이다.Examples of such diols and glycols are ethylene glycol, diethylene glycol, triethylene glycol, propane-1,3-diol, propane-1,2-diol, butane-1,4-diol, pentane-1,5-diol, Hexane-1,6-diol, 1,4-cyclohexanedimethanol, 3-methylpentane-2,4-diol, 2-methylpentane-1,4-diol, 2,2-diethylpropane-1,3 -Diol, 1,4-di- (hydroxyethoxy) benzene, 2,2-bis (4-hydroxycyclohexyl) -propane, 2,4-dihydroxy-1,1,3,3-tetra Methylcyclobutane, 2,2-bis- (3-hydroxyethoxyphenyl) propane, 2,2-bis- (4-hydroxypropoxyphenyl) ethane and mixtures thereof.

디올의 예는 에틸렌 글리콜 및 1,4-시클로헥산디메탄올이다.Examples of diols are ethylene glycol and 1,4-cyclohexanedimethanol.

폴리에스테르의 예는 폴리(에틸렌 테레프탈레이트)PET 및 폴리(에틸렌 2,6-나프탈렌-2,6-디카르복실레이트)PEN, 바람직하게는 폴리(에틸렌 테레프탈레이트) PET이다.Examples of polyesters are poly (ethylene terephthalate) PET and poly (ethylene 2,6-naphthalene-2,6-dicarboxylate) PEN, preferably poly (ethylene terephthalate) PET.

또한, 폴리에스테르는 상기 성분들을 포함하는 폴리에스테르 및 코폴리에스테르의 블렌드로 할 것을 고려할 수 있다.It is also contemplated that the polyester be a blend of polyester and copolyesters comprising the above components.

본 발명에 따른 알킬 금속 술포네이트의 예로는 화학식 RSO3Na(R은 직쇄 또는 측쇄 C12-C15 알킬이거나, 또는 직쇄 또는 측쇄 C12-C18 알케닐임)으로 나타내진다.Examples of alkyl metal sulfonates according to the invention are represented by the formula RSO 3 Na, wherein R is straight or branched C 12 -C 15 alkyl or straight or branched C 12 -C 18 alkenyl.

관심있는 것은 M이 Na, K 또는 Li이고, 그리고 R이 측쇄 C12-C15 알킬이거나 또는 직쇄 또는 측쇄 C12-C18 알케닐인 RSO3M이다.Of interest are RSO 3 M, wherein M is Na, K or Li, and R is branched C 12 -C 15 alkyl or straight or branched C 12 -C 18 alkenyl.

C12-C18 알케닐의 예는 올레일이다.An example of C 12 -C 18 alkenyl is oleyl.

알킬 기는 특히 측쇄기이다. 측쇄란 2급 또는 3급 탄소 기를 갖는 것을 의미한다.Alkyl groups are in particular branched groups. By side chain is meant having a secondary or tertiary carbon group.

본 발명의 방법에 의해 제조된 조성물은 하기에서 열거한 바와 같은 여러 공지의 안정화제 공통 첨가제 또는 이들의 혼합물을 0.01∼10 중량%, 바람직하게는 0.025∼5 중량%, 특히 바람직하게는 0.1∼3 중량%의 양으로 임의로 함유할 수 있다.The composition prepared by the process of the invention comprises from 0.01 to 10% by weight, preferably from 0.025 to 5% by weight, particularly preferably from 0.1 to 3, of various known stabilizer common additives or mixtures thereof as listed below. It may optionally contain in an amount of weight percent.

1. 산화방지제1. Antioxidant

1.1. 알킬화 모노페놀, 예를들어 2,6-디-삼차 부틸-4-메틸페놀, 2-삼차 부틸-4,6-디메틸페놀, 2,6-디-삼차 부틸-4-에틸페놀, 2,6-디-삼차 부틸-4-n-부틸페놀, 2,6-디-삼차 부틸-4-이소부틸페놀, 2,6-디시클로펜틸-4-메틸페놀, 2-(α-메틸시클로헥실)-4,6-디메틸페놀, 2,6-디옥타데실-4-메틸페놀, 2,4,6-트리시클로헥실페놀, 2,6-디-삼차 부틸-4-메톡시메틸페놀, 직쇄 또는 측쇄에서 분지된 노닐페놀 예컨대, 2,6-디노닐-4-메틸페놀, 2,4-디메틸-6-(1-메틸-운데스-1-일)-페놀, 2,4-디메틸-6-(1-메틸-헵타데스-1-일)-페놀, 2,4-디메틸-6-(1-메틸트리데스-1-일)-페놀 및 이들의 혼합물. 1.1. Alkylated monophenols such as 2,6-di-tert butyl-4-methylphenol, 2-tert butyl-4,6-dimethylphenol, 2,6-di-tert butyl-4-ethylphenol, 2,6 -Di-tertiary butyl-4-n-butylphenol, 2,6-di-tertiary butyl-4-isobutylphenol, 2,6-dicyclopentyl-4-methylphenol, 2- (α-methylcyclohexyl) -4,6-dimethylphenol, 2,6-dioctadecyl-4-methylphenol, 2,4,6-tricyclohexylphenol, 2,6-di-tert butyl-4-methoxymethylphenol, straight chain or Nonylphenol branched in the side chain such as 2,6-dinononyl-4-methylphenol, 2,4-dimethyl-6- (1-methyl-undes-1-yl) -phenol, 2,4-dimethyl-6 -(1-methyl-heptades-1-yl) -phenol, 2,4-dimethyl-6- (1-methyltrides-1-yl) -phenol and mixtures thereof.

1.2. 알킬티오메틸페놀, 예를들어 2,4-디옥틸티오메틸-6-삼차 부틸페놀, 2,4-디옥틸티오메틸-6-메틸페놀, 2,4-디옥틸티오메틸-6-에틸페놀, 2,6-디도데실티오메틸-4-노닐페놀. 1.2. Alkylthiomethylphenols such as 2,4-dioctylthiomethyl-6-tertiary butylphenol, 2,4-dioctylthiomethyl-6-methylphenol, 2,4-dioctylthiomethyl-6-ethylphenol , 2,6-didodecylthiomethyl-4-nonylphenol.

1.3. 히드로퀴논 및 알킬화 히드로퀴논, 예를들어 2,6-디-삼차 부틸-4-메톡시페놀, 2,5-디-삼차 부틸-히드로퀴논, 2,5-디-삼차 아밀히드로퀴논, 2,6-디페닐-4-옥타데실옥시페놀, 2,6-디-삼차 부틸히드로퀴논, 2,5-디-삼차 부틸-4-히드록시아니솔, 3,5-디-삼차 부틸-4-히드록시아니솔, 3,5-디-삼차 부틸-4-히드록시페닐 스테아레이트, 비스(3,5-디-삼차 부틸-4-히드록시페닐)아디페이트. 1.3. Hydroquinones and alkylated hydroquinones , for example 2,6-di-tert butyl-4-methoxyphenol, 2,5-di-tert butyl-hydroquinone, 2,5-di-tert amylhydroquinone, 2,6-diphenyl -4-octadecyloxyphenol, 2,6-di-tertiary butylhydroquinone, 2,5-di-tertiary butyl-4-hydroxyanisole, 3,5-di-tertiary butyl-4-hydroxyanisole, 3,5-di-tert butyl-4-hydroxyphenyl stearate, bis (3,5-di-tert butyl-4-hydroxyphenyl) adipate.

1.4. 토코페롤, 예를 들어 α-, β-, γ-, δ-토코페롤 및 이들의 혼합물 (비타민E) 1.4. Tocopherols , for example α-, β-, γ-, δ-tocopherol and mixtures thereof (vitamin E)

1.5. 히드록시화 티오디페닐 에테르, 예를들어 2,2'-티오비스(6-삼차 부틸-4-메틸페놀), 2,2'-티오비스(4-옥틸페놀), 4,4'-티오비스(6-삼차 부틸-3-메틸페놀), 4,4'-티오비스(6-삼차 부틸-2-메틸페놀), 4,4'-티오비스(3,6-디-이차 아밀페놀), 4,4'-비스 (2,6-디메틸-4-히드록시페닐)디술피드. 1.5. Hydroxylation Thiodiphenyl ethers such as 2,2'-thiobis (6-tert-butyl-4-methylphenol), 2,2'-thiobis (4-octylphenol), 4,4'-thiobis (6 Tertiary butyl-3-methylphenol), 4,4'-thiobis (6-tertiary butyl-2-methylphenol), 4,4'-thiobis (3,6-di-secondary amylphenol), 4, 4'-bis (2,6-dimethyl-4-hydroxyphenyl) disulfide.

1.6. 알킬리덴비스페놀, 예를들어 2,2'-메틸렌비스(6-삼차 부틸-4-메틸페놀), 2,2'-메틸렌비스(6-삼차 부틸-4-에틸페놀), 2,2'-메틸렌비스[4-메틸-6-(α-메틸시클로헥실)-페놀], 2,2'-메틸렌비스(4-메틸-6-시클로헥실페놀), 2,2'-메틸렌비스(6-노닐-4-메틸페놀), 2,2'-메틸렌비스(4,6-디-삼차 부틸페놀), 2,2'-에틸리덴비스(4,6-디-삼차 부틸페놀), 2,2'-에틸리덴비스(6-삼차 부틸-4-이소부틸페놀), 2,2'-메틸렌비스[6-(α-메틸벤질)-4-노닐페놀], 2,2'-메틸렌비스[6-(α,α-디메틸벤질)-4-노닐페놀], 4,4'-메틸렌비스(2,6-디-삼차 부틸페놀), 4,4'-메틸렌비스(6-삼차 부틸-2-메틸페놀), 1,1-비스(5-삼차 부틸-4-히드록시-2-메틸페닐)부탄, 2,6-비스(3-삼차 부틸-5-메틸-2-히드록시벤질)-4-메틸페놀, 1,1,3-트리스(5-삼차 부틸-4-히드록시-2-메틸페닐)부탄, 1,1-비스(5-삼차 부틸-4-히드록시-2-메틸-페닐)-3-n-도데실머캅토부탄, 에틸렌 글리콜 비스[3,3-비스(3-삼차 부틸-4-히드록시페닐)부티레이트], 비스(3-삼차 부틸-4-히드록시-5-메틸-페닐)디시클로펜타디엔, 비스[2-(3'-삼차 부틸-2-히드록시-5-메틸벤질)-6-삼차 부틸-4-메틸페닐]테레프탈레이트, 1,1-비스-(3,5-디메틸-2-히드록시페닐)부탄, 2,2-비스(3,5-디-삼차 부틸-4-히드록시페닐)-프로판, 2,2-비스-(5-삼차 부틸-4-히드록시-2-메틸페닐)-4-n-도데실머캅토부탄, 1,1,5,5-테트라(5-삼차 부틸-4-히드록시-2-메틸페닐)펜탄. 1.6. Alkylidenebisphenols such as 2,2'-methylenebis (6-tertiary butyl-4-methylphenol), 2,2'-methylenebis (6-tert-butylbutylethylethylphenol), 2,2'- Methylenebis [4-methyl-6- (α-methylcyclohexyl) -phenol], 2,2'-methylenebis (4-methyl-6-cyclohexylphenol), 2,2'-methylenebis (6-nonyl -4-methylphenol), 2,2'-methylenebis (4,6-di-tertiary butylphenol), 2,2'-ethylidenebis (4,6-di-tertiary butylphenol), 2,2 ' -Ethylidenebis (6-tert-butyl-4-isobutylphenol), 2,2'-methylenebis [6- (α-methylbenzyl) -4-nonylphenol], 2,2'-methylenebis [6- (α, α-dimethylbenzyl) -4-nonylphenol], 4,4'-methylenebis (2,6-di-tertiary butylphenol), 4,4'-methylenebis (6-tert-butylbutyl-2-methyl Phenol), 1,1-bis (5-tert-butyl-4-hydroxy-2-methylphenyl) butane, 2,6-bis (3-tert-butyl-5-methyl-2-hydroxybenzyl) -4-methyl Phenol, 1,1,3-tris (5-tertiary butyl-4-hydroxy-2-methylphenyl) butane, 1,1-bis (5-tertiary butyl-4-hydroxy-2-methyl-phenyl) -3 -n-dodecylmer Tobutane, ethylene glycol bis [3,3-bis (3-tert-butyl-4-hydroxyphenyl) butyrate], bis (3-tert-butyl-4-hydroxy-5-methyl-phenyl) dicyclopentadiene, Bis [2- (3'-tert-butyl-2-hydroxy-5-methylbenzyl) -6-tert-butyl-4-methylphenyl] terephthalate, 1,1-bis- (3,5-dimethyl-2-hydride Hydroxyphenyl) butane, 2,2-bis (3,5-di-tertiary butyl-4-hydroxyphenyl) -propane, 2,2-bis- (5-tertiary butyl-4-hydroxy-2-methylphenyl) 4-n-dodecylmercaptobutane, 1,1,5,5-tetra (5-tertiary butyl-4-hydroxy-2-methylphenyl) pentane.

1.7. 벤질 화합물, 예를들어 3,5,3',5'-테트라-삼차-부틸-4,4'-디히드록시디벤질 에테르, 옥타데실-4-히드록시-3,5-디메틸벤질머캅토아세테이트, 트리데실-4-히드록시-3,5-디-삼차-부틸벤질머캅토아세테이트, 트리스(3,5-디-삼차-부틸-4-히드록시벤질)아민, 1,3,5-트리-(3,5-디-삼차-부틸-4-히드록시벤질)-2,4,6-트리메틸벤젠, 디-(3,5-디-삼차-부틸-4-히드록시벤질)설파이드, 3,5-디-삼차-부틸-4-히드록시벤질-머캅토-아세트산 이소옥틸 에스테르, 비스(4-삼차-부틸-3-히드록시-2,6-디메틸벤질)디티올 테레프탈레이트, 1,3,5-트리스-(3,5-디-삼차-부틸-4-히드록시벤질)이소시아누레이트, 1,3,5-트리스-(4-삼차-부틸-3-히드록시-2,6-디메틸벤질)이소시아누레이트, 3,5-디-삼차-부틸-4-히드록시벤질-인산 디옥타데실 에스테르 및 3,5-디-삼차-부틸-4-히드록시벤질-인산 모노에틸 에스테르, 칼슘염. 1.7. Benzyl compounds such as 3,5,3 ', 5'-tetra-tert-butyl-4,4'-dihydroxydibenzyl ether, octadecyl-4-hydroxy-3,5-dimethylbenzyl mercapto Acetate, tridecyl-4-hydroxy-3,5-di-tert-butylbenzylmercaptoacetate, tris (3,5-di-tert-butyl-4-hydroxybenzyl) amine, 1,3,5- Tri- (3,5-di-tert-butyl-4-hydroxybenzyl) -2,4,6-trimethylbenzene, di- (3,5-di-tert-butyl-4-hydroxybenzyl) sulfide, 3,5-di-tert-butyl-4-hydroxybenzyl-mercapto-acetic acid isooctyl ester, bis (4-tert-butyl-3-hydroxy-2,6-dimethylbenzyl) dithiol terephthalate, 1 , 3,5-tris- (3,5-di-tert-butyl-4-hydroxybenzyl) isocyanurate, 1,3,5-tris- (4-tert-butyl-3-hydroxy-2 , 6-dimethylbenzyl) isocyanurate, 3,5-di-tert-butyl-4-hydroxybenzyl-phosphate dioctadecyl ester and 3,5-di-tert-butyl-4-hydroxybenzyl-phosphate Monoethyl ester, calcium .

1.8. 히드록시벤질화 말로네이트, 예를들어 디옥타데실-2,2-비스(3,5-디-삼차 부틸-2-히드록시벤질)말로네이트, 디-옥타데실-2-(3-삼차 부틸-4-히드록시-5-메틸벤질)-말로네이트, 디-도데실머캅토에틸-2,2-비스(3,5-디-삼차 부틸-4-히드록시벤질)말로네이트, 비스-[4-(1,1,3,3-테트라메틸부틸)페닐]-2,2-비스(3,5-디-삼차 부틸-4-히드록시벤질)말로네이트. 1.8. Hydroxybenzylation Malonates , for example dioctadecyl-2,2-bis (3,5-di-tert-butyl-2-hydroxybenzyl) malonate, di-octadecyl-2- (3-tert butyl-4-hydride Hydroxy-5-methylbenzyl) -malonate, di-dodecylmercaptoethyl-2,2-bis (3,5-di-tert butyl-4-hydroxybenzyl) malonate, bis- [4- (1, 1,3,3-tetramethylbutyl) phenyl] -2,2-bis (3,5-di-tert butyl-4-hydroxybenzyl) malonate.

1.9. 방향족 히드록시벤질 화합물, 예를들어 1,3,5-트리스(3,5-디-삼차 부틸-4-히드록시벤질)-2,4,6-트리메틸벤젠, 1,4-비스(3,5-디-삼차 부틸-4-히드록시벤질)-2,3, 5, 6-테트라메틸벤젠, 2,4,6-트리스(3,5-디-삼차 부틸-4-히드록시벤질)페놀. 1.9. Aromatic hydroxybenzyl compounds such as 1,3,5-tris (3,5-di-tert-butyl-4-hydroxybenzyl) -2,4,6-trimethylbenzene, 1,4-bis (3, 5-di-tertiary butyl-4-hydroxybenzyl) -2,3,5,6-tetramethylbenzene, 2,4,6-tris (3,5-di-tert butyl-4-hydroxybenzyl) phenol .

1.10. 트리아진 화합물, 예를들어 2,4-비스(옥틸머캅토)-6-(3,5-디-삼차 부틸-4-히드록시아닐리노)-1,3,5-트리아진, 2-옥틸머캅토-4,6-비스(3,5-디-삼차 부틸-4-히드록시아닐리노)-1,3,5-트리아진, 2-옥틸머캅토-4,6-비스(3,5-디-삼차 부틸-4-히드록시페녹시)-1,3,5-트리아진, 2,4,6-트리스(3,5-디-삼차 부틸-4-히드록시페녹시)-1,2,3-트리아진, 1,3,5-트리스(3,5-디-삼차 부틸-4-히드록시벤질)이소시아누레이트, 1, 3,5-트리스(4-삼차 부틸-3-히드록시-2,6-디메틸벤질)이소시아누레이트, 2,4,6-트리스(3,5-디-삼차 부틸-4-히드록시페닐에틸)-1,3,5-트리아진, 1,3,5-트리스(3,5-디-삼차 부틸-4-히드록시페닐프로피오닐)헥사히드로-1,3,5-트리아진, 1,3,5-트리스 (3,5-디시클로헥실-4-히드록시벤질)이소시아누레이트. 1.10. Triazine compounds such as 2,4-bis (octylmercapto) -6- (3,5-di-tert butyl-4-hydroxyanilino) -1,3,5-triazine, 2-jade Tylmercapto-4,6-bis (3,5-di-tertiary butyl-4-hydroxyanilino) -1,3,5-triazine, 2-octylmercapto-4,6-bis (3,5 -Di-tertiary butyl-4-hydroxyphenoxy) -1,3,5-triazine, 2,4,6-tris (3,5-di-tertiary butyl-4-hydroxyphenoxy) -1, 2,3-triazine, 1,3,5-tris (3,5-di-tert-butyl-4-hydroxybenzyl) isocyanurate, 1,3,5-tris (4-tert-butyl-3- Hydroxy-2,6-dimethylbenzyl) isocyanurate, 2,4,6-tris (3,5-di-tert butyl-4-hydroxyphenylethyl) -1,3,5-triazine, 1 , 3,5-tris (3,5-di-tert-butyl-4-hydroxyphenylpropionyl) hexahydro-1,3,5-triazine, 1,3,5-tris (3,5-dicyclo Hexyl-4-hydroxybenzyl) isocyanurate.

1.11. 벤질포스포네이트, 예를들어 디메틸-2,5-디-삼차 부틸-4-히드록시벤질 포스포네이트, 디에틸-3,5-디-삼차 부틸-4-히드록시벤질포스포네이트, 디옥타데실-3,5-디-삼차 부틸-4-히드록시벤질포스포네이트, 디옥타데실-5-삼차 부틸-4-히드록시-3-메틸벤질 포스포네이트, 3,5-디-삼차 부틸-4-히드록시벤질-포스폰산 모노에틸 에스테르의 칼슘 염. 1.11. Benzylphosphonates , for example dimethyl-2,5-di-tertiary butyl-4-hydroxybenzyl phosphonate, diethyl-3,5-di-tertiary butyl-4-hydroxybenzylphosphonate, di Octadecyl-3,5-di-tertiary butyl-4-hydroxybenzylphosphonate, dioctadecyl-5-tertiary butyl-4-hydroxy-3-methylbenzyl phosphonate, 3,5-di-tertiary Calcium salt of butyl-4-hydroxybenzyl-phosphonic acid monoethyl ester.

1.12. 아실아미노페놀, 예를들어 4-히드록시-라우르산 아닐리드, 4-히드록시-스테아르산 아닐리드, 2,4-비스-옥틸머캅토-6-(3,5-삼차 부틸-4-히드록시아닐리노)-s-트리아진 및 옥틸 N-(3,5-디-삼차 부틸-4-히드록시페닐)카바메이트. 1.12. Acylaminophenols such as 4-hydroxy-lauric acid anilide, 4-hydroxy-stearic acid anilide, 2,4-bis-octylmercapto-6- (3,5-tertiary butyl-4-hydroxy Anilino) -s-triazine and octyl N- (3,5-di-tert butyl-4-hydroxyphenyl) carbamate.

1.13. 1가 또는 다가 알코올, 예컨대 메탄올, 에탄올, n-옥탄올, i-옥탄올, 옥타데칸올, 1,6-헥산디올, 1,9-노난디올, 에틸렌 글리콜, 1,2-프로판디올, 네오펜틸 글리콜, 티오디에틸렌 글리콜, 디에틸렌 글리콜, 트리에틸렌 글리콜, 펜타에리트리톨, 트리스(히드록시에틸)이소시아누레이트, N,N'-비스(히드록시에틸)옥사미드, 3-티아운데칸올, 3-티아펜타데칸올, 트리메틸헥산디올, 트리메틸올프로판, 4-히드록시메틸-1-포스파-2,6,7-트리옥사비시클로[2.2.2]옥탄과 β-(3,5-디-삼차 부틸-4- 히드록시페닐 )-프로피온산의 에스테르. 1.13. Monohydric or polyhydric alcohols such as methanol, ethanol, n-octanol, i-octanol, octadecanol, 1,6-hexanediol, 1,9-nonanediol, ethylene glycol, 1,2-propanediol, neo Pentyl glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol, pentaerythritol, tris (hydroxyethyl) isocyanurate, N, N'-bis (hydroxyethyl) oxamide, 3-thiaundanol , 3-thiapentadecanol, trimethylhexanediol, trimethylolpropane, 4-hydroxymethyl-1-phospha-2,6,7-trioxabicyclo [2.2.2] octane and β- (3,5 Ester of di-tert-butyl-4 -hydroxyphenyl ) -propionic acid .

1.14. 1가 또는 다가 알코올, 예를들어 메탄올, 에탄올, n-옥탄올, i-옥탄올, 옥타데칸올, 1,6-헥산디올, 1,9-노난디올, 에틸렌 글리콜, 1,2-프로판디올, 네오펜틸 글리콜, 티오디에틸렌 글리콜, 디에틸렌 글리콜, 트리에틸렌 글리콜, 펜타에리트리톨, 트리스(히드록시에틸)이소시아누레이트, N,N'-비스(히드록시에틸)옥사미드, 3-티아운데칸올, 3-티아펜타데칸올, 트리메틸헥산디올, 트리메틸올프로판, 4-히드록시메틸-1-포스파-2,6,7-트리옥사비시클로-[2.2.2]옥탄과 β-(5-삼차 부틸-4-히드록시-3- 메틸페닐 )-프로피온산의 에스테르. 1.14. Monohydric or polyhydric alcohols such as methanol, ethanol, n-octanol, i-octanol, octadecanol, 1,6-hexanediol, 1,9-nonanediol, ethylene glycol, 1,2-propanediol , Neopentyl glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol, pentaerythritol, tris (hydroxyethyl) isocyanurate, N, N'-bis (hydroxyethyl) oxamide, 3-thia Undecanol, 3-thiapentadecanol, trimethylhexanediol, trimethylolpropane, 4-hydroxymethyl-1-phospha-2,6,7-trioxabicyclo- [2.2.2] octane and β- ( Esters of 5-tert-butyl-4-hydroxy-3- methylphenyl ) -propionic acid .

1.15. 1가 또는 다가 알코올, 예를들어 메탄올, 에탄올, 옥탄올, 옥타데칸올, 1,6-헥산디올, 1,9-노난디올, 에틸렌 글리콜, 1,2-프로판디올, 네오펜틸 글리콜, 티오디에틸렌 글리콜, 디에틸렌 글리콜, 트리에틸렌 글리콜, 펜타에리트리톨, 트리스(히드록시에틸)이소시아누레이트, N,N'-비스(히드록시에틸)옥사미드, 3-티아운데칸올, 3-티아펜타데칸올, 트리메틸헥산디올, 트리메틸올프로판, 4-히드록시메틸-1-포스파-2,6,7-트리옥사비시클로-[2.2.2]옥탄과 β-(3,5- 디시클로헥실 -4- 히드록시페닐 )-프로피온산의 에스테르. 1.15. Monohydric or polyhydric alcohols such as methanol, ethanol, octanol, octadecanol, 1,6-hexanediol, 1,9-nonanediol, ethylene glycol, 1,2-propanediol, neopentyl glycol, thiodi Ethylene glycol, diethylene glycol, triethylene glycol, pentaerythritol, tris (hydroxyethyl) isocyanurate, N, N'-bis (hydroxyethyl) oxamide, 3-thiaundanol, 3-thiapenta Decanol, trimethylhexanediol, trimethylolpropane, 4-hydroxymethyl-1-phospha-2,6,7-trioxabicyclo- [2.2.2] octane and β- (3,5 -dicyclohexyl 4 - Ester of hydroxyphenyl ) -propionic acid .

1.16. 1가 또는 다가 알코올, 예를들어 메탄올, 에탄올, 옥탄올, 옥타데칸올, 1,6-헥산디올, 1,9-노난디올, 에틸렌 글리콜, 1,2-프로판디올, 네오펜틸 글리콜, 티오디에틸렌 글리콜, 디에틸렌 글리콜, 트리에틸렌 글리콜, 펜타에리트리톨, 트리스(히드록시에틸)이소시아누레이트, N,N'-비스(히드록시에틸)옥사미드, 3-티아운데칸올, 3-티아펜타데칸올, 트리메틸헥산디올, 트리메틸올프로판, 4-히드록시메틸-1-포스파-2,6,7-트리옥사비시클로-[2.2.2]옥탄과 3,5-디-삼차 부틸-4- 히드록시페닐 아세트산의 에스테르. 1.16. Monohydric or polyhydric alcohols such as methanol, ethanol, octanol, octadecanol, 1,6-hexanediol, 1,9-nonanediol, ethylene glycol, 1,2-propanediol, neopentyl glycol, thiodi Ethylene glycol, diethylene glycol, triethylene glycol, pentaerythritol, tris (hydroxyethyl) isocyanurate, N, N'-bis (hydroxyethyl) oxamide, 3-thiaundanol, 3-thiapenta Decanol, trimethylhexanediol, trimethylolpropane, 4-hydroxymethyl-1-phospha-2,6,7-trioxabicyclo- [2.2.2] octane and 3,5-di-tertiary butyl-4 -hydroxy esters of phenylacetic acid.

1.17. β-(3,5-디-삼차 부틸-4- 히드록시페닐 )프로피온산의 아미드, 예를들어 N,N'-비스(3,5-디-삼차 부틸-4-히드록시페닐프로피오닐)헥사메틸렌디아미드, N,N'-비스(3,5-디-삼차 부틸-4-히드록시페닐피로피오닐)트리메틸렌디아미드, N,N'-비스(3,5-디-삼차 부틸-4-히드록시-페닐프오피오닐)히드라지드, N,N'-비스[2-(3-[3,5-디-삼차 부틸-4-히드록시페닐]프로피오닐옥시)에틸]옥사미드 (Naugard® XL-1, 유니로얄사 제). 1.17. Amides of β- (3,5-di-tert-butyl-4 -hydroxyphenyl ) propionic acid, for example N, N'-bis (3,5-di-tert-butyl-4-hydroxyphenylpropionyl) hexa Methylenediamide, N, N'-bis (3,5-di-tertiary butyl-4-hydroxyphenylpyrropiionyl) trimethylenediamide, N, N'-bis (3,5-di-tertiary butyl- 4-hydroxy-phenylpropionyl) hydrazide, N, N'-bis [2- (3- [3,5-di-tert butyl-4-hydroxyphenyl] propionyloxy) ethyl] oxamide ( Naugard ® XL-1, manufactured by UniRoyal).

1.18. 아스코르브산 (비타민 C)1.18. Ascorbic acid (vitamin C)

1.19. 아민 산화방지제, 예컨대 N,N'-디-이소프로필-p-페닐렌디아민, N,N'-디-이차부틸-p-페닐렌디아민, N,N'-비스(1,4-디메틸펜틸)-p-페닐렌디아민, N,N'-비스(1-에틸-3-메틸펜틸)-p-페닐렌디아민, N,N'-비스(1-메틸헵틸)-p-페닐렌디아민, N,N'- 디시클로헥실-p-페닐렌디아민, N,N'-디페닐-p-페닐렌디아민, N,N'-비스(2-나프틸)-p-페닐렌디아민, N-이소프로필-N'-페닐-p-페닐렌디아민, N-(1,3-디메틸부틸)-N'-페닐-p-페닐렌디아민, N-(1-메틸헵틸)-N'-페닐-p-페닐렌디아민, N-시클로헥실-N'-페닐-p-페닐렌디아민, 4-(p-톨루엔술파모일)-디페닐아민, N,N'-디메틸-N,N'-디-이차부틸-p-페닐렌디아민, 디페닐아민, N-알릴디페닐아민, 4-이소프로폭시디페닐아민, N-페닐-1-나프틸아민, N-(4-삼차 옥틸페닐)-1-나프틸아민, N-페닐-2-나프틸아민, 옥틸화 디페닐아민, 예컨대, p,p'-디-삼차 옥틸디페닐아민, 4-n-부틸아미노페놀, 4-부티릴아미노페놀, 4-노난오일아미노-페놀, 4-도데칸오일아미노페놀, 4-옥타데칸오일아미노페놀, 비스(4-메톡시페닐)아민, 2,6-디-삼차 부틸-4-디메틸아미노메틸페놀, 2,4'-디-아미노디페닐메탄, 4,4'-디아미노디페닐메탄, N,N,N',N'-테트라메틸-4,4'-디-아미노디페닐메탄, 1,2-비스[(2-메틸페닐)아미노]에탄, 1,2-비스(페닐아미노)프로판, (o-톨릴)비구아니드, 비스[4-(1',3'-디메틸부틸)페닐]아민, 삼차 옥틸화 N-페닐-1-나프틸아민, 모노- 및 디알킬화 삼차 부틸/삼차 옥틸디페닐아민의 혼합물, 모노- 및 디알킬화 노닐디페닐아민의 혼합물, 모노- 및 디알킬화 노닐디페닐아민의 혼합물, 모노- 및 디알킬화 도데실디페닐아민의 혼합물, 모노- 및 디알킬화 이소프로필/이소헥실페닐아민의 혼합물, 모노- 및 디알킬화 삼차 부틸디페닐아민의 혼합물, 2,3-디-히드로-3,3-디메틸-4H-1,4-벤조티아진, 페노티아진, 모노 및 디알킬화 삼차 부틸/삼차 옥틸페노타이진의 혼합물, 모노- 및 디알킬화 삼차 옥틸-페노티아진의 혼합물, N-알릴페노티아진, N,N,N',N'-테트라페닐-1,4-디아미노부트-2-엔. 1.19. Amine antioxidants such as N, N'-di-isopropyl-p-phenylenediamine, N, N'-di-secondarybutyl-p-phenylenediamine, N, N'-bis (1,4-dimethylpentyl ) -p-phenylenediamine, N, N'-bis (1-ethyl-3-methylpentyl) -p-phenylenediamine, N, N'-bis (1-methylheptyl) -p-phenylenediamine, N, N'-dicyclohexyl-p-phenylenediamine, N, N'-diphenyl-p-phenylenediamine, N, N'-bis (2-naphthyl) -p-phenylenediamine, N- Isopropyl-N'-phenyl-p-phenylenediamine, N- (1,3-dimethylbutyl) -N'-phenyl-p-phenylenediamine, N- (1-methylheptyl) -N'-phenyl- p-phenylenediamine, N-cyclohexyl-N'-phenyl-p-phenylenediamine, 4- (p-toluenesulfamoyl) -diphenylamine, N, N'-dimethyl-N, N'-di- Secondary butyl-p-phenylenediamine, diphenylamine, N-allyldiphenylamine, 4-isopropoxydiphenylamine, N-phenyl-1-naphthylamine, N- (4-tertiary octylphenyl) -1 -Naphthylamine, N-phenyl-2-naphthylamine, octylated diphenylamines such as p, p'-di-tertiary octyldiphenylamine, 4-n-butyl Minophenol, 4-butyrylaminophenol, 4-nonanylamino-phenol, 4-dodecane oilaminophenol, 4-octadecane oilaminophenol, bis (4-methoxyphenyl) amine, 2,6-di- Tertiary butyl-4-dimethylaminomethylphenol, 2,4'-di-aminodiphenylmethane, 4,4'-diaminodiphenylmethane, N, N, N ', N'-tetramethyl-4,4' -Di-aminodiphenylmethane, 1,2-bis [(2-methylphenyl) amino] ethane, 1,2-bis (phenylamino) propane, (o-tolyl) biguanide, bis [4- (1 ' , 3'-dimethylbutyl) phenyl] amine, tertiary octylated N-phenyl-1-naphthylamine, mixture of mono- and dialkylated tertiary butyl / tertiary octyldiphenylamine, mono- and dialkylated nonyldiphenylamine Mixtures, mixtures of mono- and dialkylated nonyldiphenylamines, mixtures of mono- and dialkylated dodecyldiphenylamines, mixtures of mono- and dialkylated isopropyl / isohexylphenylamines, mono- and dialkylated tertiary butyldiphenyl Mixture of amines, 2,3-di-hydride -3,3-dimethyl-4H-1,4-benzothiazine, phenothiazine, mixture of mono and dialkylated tertiary butyl / tertiary octylphenothiazine, mixture of mono- and dialkylated tertiary octyl-phenothiazine, N Allylphenothiazine, N, N, N ', N'-tetraphenyl-1,4-diaminobut-2-ene.

2. 2. UVUV 흡수제 및  Absorbent and 광안정화제Light stabilizer

2.1. 2-(2- 히드록시페닐 )-2H- 벤조트리아졸, 미국특허 3,004,896; 3,055,896; 3,072,585; 3,074,910; 3,189,615; 3,218,332; 3,230,194; 4,127,586; 4,226,763; 4,275,004; 4,278,589; 4,315,848; 4,347,180; 4,383,863; 4,675,352; 4,681,905, 4,853,471; 5,268,450; 5,278,314; 5,280,124; 5,319,091; 5,410,071; 5,436,349; 5,516,914; 5,554,760; 5,563,242; 5,574,166; 5,607,987, 및 5,977,219에 기재된 공지의 히드록시페닐-2H-벤조트리아졸 및 벤조트리아졸, 예를 들어 2-(2-히드록시-5-메틸페닐)-2H-벤조트리아졸, 2-(3,5-디-삼차 부틸-2-히드록시페닐)-2H-벤조트리아졸, 2-(2-히드록시-5-삼차 부틸페닐)-2H-벤조트리아졸, 2-(2-히드록시-5-삼차-옥틸페닐)-2H-벤조트리아졸, 5-클로로-2-(3,5-디-삼차-부틸-2-히드록시페닐)-2H-벤조트리아졸, 5-클로로-2-(3-삼차-부틸-2-히드록시-5-메틸페닐)-2H-벤조트리아졸, 2-(3-이차-부틸-5-삼차-부틸-2-히드록시페닐)-2H-벤조트리아졸, 2-(2-히드록시-4-옥틸옥시페닐)-2H-벤조트리아졸, 2-(3,5-디-삼차-아밀-2-히드록시페닐)-2H-벤조트리아졸, 2-(3,5-비스-α-쿠밀-2-히드록시페닐)-2H-벤조트리아졸, 2-(3-삼차-부틸-2-히드록시-5-(2-(ω-히드록시-옥타(에틸렌옥시)카르보닐-에틸)-,페닐)-2H-벤조트리아졸, 2-(3-도데실-2-히드록시-5-메틸페닐)-2H-벤조트리아졸, 2-(3-삼차-부틸-2-히드록시-5-(2-옥틸옥시카르보닐)에틸페닐)-2H-벤조트리아졸, 도데실화 2-(2-히드록시-5-메틸페닐)-2H-벤조트리아졸, 2-(3-삼차-부틸-2-히드록시-5-(2-옥틸옥시카르보닐에틸)페닐)-5-클로로-2H-벤조트리아졸, 2-(3-삼차-부틸-5-(2-(2-에틸헥실옥시)-카르보닐에틸)-2-히드록시페닐)-5-클로로-2H-벤조트리아졸, 2-(3-삼차-부틸-2-히드록시-5-(2-메톡시카르보닐에틸)페닐)-5-클로로-2H-벤조트리아졸, 2-(3-삼차-부틸-2-히드록시-5-(2-메톡시카르보닐에틸)페닐)-2H-벤조트리아졸, 2-(3-삼차-부틸-5-(2-(2-에틸헥실옥시)카르보닐에틸)-2-히드록시페닐)-2H-벤조트리아졸, 2-(3-삼차-부틸-2-히드록시-5-(2-이소옥틸옥시카르보닐에틸)페닐)-2H-벤조트리아졸, 2,2'-메틸렌-비스(4-삼차-옥틸-(6-2H-벤조트리아졸-2-일)페놀), 2-(2-히드록시-3-α-쿠밀-5-삼차-옥틸페닐)-2H-벤조트리아졸, 2-(2-히드록시-3-삼차-옥틸-5-α-쿠밀페닐)-2H-벤조트리아졸, 5-플루오로-2-(2-히드록시-3,5-디-α-쿠밀페닐)-2H-벤조트리아졸, 5-클로로-2-(2-히드록시-3,5-디-α-쿠밀페닐)-2H-벤조트리아졸, 5-클로로-2-(2-히드록시-3-α-쿠밀-5-삼차-옥틸페닐)-2H-벤조트리아졸, 2-(3-삼차-부틸-2-히드록시-5-(2-이소옥틸옥시카르보닐에틸)페닐)-5-클로로-2H-벤조트리아졸, 5-트리플루오로메틸-2-(2-히드록시-3-α-쿠밀-5-삼차-옥틸페닐)-2H-벤조트리아졸, 5-트리플루오로메틸-2-(2-히드록시-5-삼차-옥틸페닐)-2H-벤조트리아졸, 5-트리플루오로메틸-2-(2-히드록시-3,5-디-삼차-옥틸페닐)-2H-벤조트리아졸, 메틸-3-(5-트리플루오로메틸-2H-벤조트리아졸-2-일)-5-3차-부틸-4-히드록시히드로신남메이트, 5-부틸술포닐-2-(2-히드록시-3-α-쿠밀-5-삼차-옥틸페닐)-2H-벤조트리아졸, 5-트리플루오로메틸-2-(2-히드록시-3-α-쿠밀-5-삼차-부틸페닐)-2H-벤조트리아졸, 5-트리플루오로메틸-2-(2-히드록시-3,5-디-삼차-부틸페닐)-2H-벤조트리아졸, 5-트리플루오로메틸-2-(2-히드록시-3,5-디-α-쿠밀페닐)-2H-벤조트리아졸, 5-부틸술포닐-2-(2-히드록시-3,5-디-삼차-부틸페닐)-2H-벤조트리아졸 및 5-페닐술포닐-2-(2-히드록시-3,5-디-삼차-부틸페닐)-2H-벤조트리아졸. 2.1. 2- (2 -hydroxyphenyl ) -2H- benzotriazole , US Patent 3,004,896; 3,055,896; 3,072,585; 3,074,910; 3,189,615; 3,218,332; 3,230,194; 4,127,586; 4,226,763; 4,275,004; 4,278,589; 4,315,848; 4,347,180; 4,383,863; 4,675,352; 4,681,905, 4,853,471; 5,268,450; 5,278,314; 5,280,124; 5,319,091; 5,410,071; 5,436,349; 5,516,914; 5,554,760; 5,563,242; 5,574,166; Known hydroxyphenyl-2H-benzotriazoles and benzotriazoles described in 5,607,987, and 5,977,219, for example 2- (2-hydroxy-5-methylphenyl) -2H-benzotriazole, 2- (3,5 -Di-tertiary butyl-2-hydroxyphenyl) -2H-benzotriazole, 2- (2-hydroxy-5-tertiary butylphenyl) -2H-benzotriazole, 2- (2-hydroxy-5- Tert-octylphenyl) -2H-benzotriazole, 5-chloro-2- (3,5-di-tert-butyl-2-hydroxyphenyl) -2H-benzotriazole, 5-chloro-2- (3 Tert-butyl-2-hydroxy-5-methylphenyl) -2H-benzotriazole, 2- (3-secondary-butyl-5-tert-butyl-2-hydroxyphenyl) -2H-benzotriazole, 2 -(2-hydroxy-4-octyloxyphenyl) -2H-benzotriazole, 2- (3,5-di-tert-amyl-2-hydroxyphenyl) -2H-benzotriazole, 2- (3 , 5-bis-α-cumyl-2-hydroxyphenyl) -2H-benzotriazole, 2- (3-tert-butyl-2-hydroxy-5- (2- (ω-hydroxy-octa (ethylene Oxy) carbonyl-ethyl)-, phenyl) -2H-benzotriazole, 2- (3-dodecyl-2-hydroxy-5-meth Phenyl) -2H-benzotriazole, 2- (3-tert-butyl-2-hydroxy-5- (2-octyloxycarbonyl) ethylphenyl) -2H-benzotriazole, dodecylated 2- (2- Hydroxy-5-methylphenyl) -2H-benzotriazole, 2- (3-tert-butyl-2-hydroxy-5- (2-octyloxycarbonylethyl) phenyl) -5-chloro-2H-benzotria Sol, 2- (3-tert-butyl-5- (2- (2-ethylhexyloxy) -carbonylethyl) -2-hydroxyphenyl) -5-chloro-2H-benzotriazole, 2- ( 3-tert-butyl-2-hydroxy-5- (2-methoxycarbonylethyl) phenyl) -5-chloro-2H-benzotriazole, 2- (3-tert-butyl-2-hydroxy-5 -(2-methoxycarbonylethyl) phenyl) -2H-benzotriazole, 2- (3-tert-butyl-5- (2- (2-ethylhexyloxy) carbonylethyl) -2-hydroxy Phenyl) -2H-benzotriazole, 2- (3-tert-butyl-2-hydroxy-5- (2-isooctyloxycarbonylethyl) phenyl) -2H-benzotriazole, 2,2'-methylene -Bis (4-tert-octyl- (6-2H-benzotriazol-2-yl) phenol), 2- (2-hydroxy-3-α-cumyl-5-tert-octylphenyl) -2H- Benzotriazole, 2- (2-hydroxy-3-tert-octyl-5-α-cumylphenyl) -2H-benzotriazole, 5-fluoro-2- (2-hydroxy-3,5-di -α-cumylphenyl) -2H-benzotriazole, 5-chloro-2- (2-hydroxy-3,5-di-α-cumylphenyl) -2H-benzotriazole, 5-chloro-2- ( 2-hydroxy-3-α-cumyl-5-tert-octylphenyl) -2H-benzotriazole, 2- (3-tert-butyl-2-hydroxy-5- (2-isooctyloxycarbonylethyl ) Phenyl) -5-chloro-2H-benzotriazole, 5-trifluoromethyl-2- (2-hydroxy-3-α-cumyl-5-tert-octylphenyl) -2H-benzotriazole, 5 -Trifluoromethyl-2- (2-hydroxy-5-tert-octylphenyl) -2H-benzotriazole, 5-trifluoromethyl-2- (2-hydroxy-3,5-di-tert -Octylphenyl) -2H-benzotriazole, methyl-3- (5-trifluoromethyl-2H-benzotriazol-2-yl) -5-tert-butyl-4-hydroxyhydrocinnamate, 5 -Butylsulfonyl-2- (2-hydroxy-3-α-cumyl-5-tert-octylphenyl) -2H-benzotriazole, 5-trifluoromethyl-2- (2- Hydroxy-3-α-cumyl-5-tert-butylphenyl) -2H-benzotriazole, 5-trifluoromethyl-2- (2-hydroxy-3,5-di-tert-butylphenyl)- 2H-benzotriazole, 5-trifluoromethyl-2- (2-hydroxy-3,5-di-α-cumylphenyl) -2H-benzotriazole, 5-butylsulfonyl-2- (2- Hydroxy-3,5-di-tert-butylphenyl) -2H-benzotriazole and 5-phenylsulfonyl-2- (2-hydroxy-3,5-di-tert-butylphenyl) -2H-benzo Triazole.

2.2. 2- 히드록시벤조페논, 예를들어 4-히드록시, 4-메톡시, 4-옥틸옥시, 4-데실옥시, 4-도데실옥시, 4-벤질옥시, 4,2',4'-트리히드록시 및 2'-히드록시-4,4'-디메톡시 유도체. 2.2. 2 -hydroxybenzophenones such as 4-hydroxy, 4-methoxy, 4-octyloxy, 4-decyloxy, 4-dodecyloxy, 4-benzyloxy, 4,2 ', 4'- Trihydroxy and 2'-hydroxy-4,4'-dimethoxy derivatives.

2.3. 치환 및 비치환된 벤조산의 에스테르, 예를들어 4-삼차 부틸-페닐 살리실레이트, 페닐 살리실레이트, 옥틸페닐 살리실레이트, 디벤조일 레조르시놀, 비스(4-삼차 부틸-벤조일)레조르시놀, 벤조일 레조르시놀, 2,4-디-삼차 부틸페닐 3,5-디-삼차 부틸-4-히드록시벤조에이트, 헥사데실 3,5-디-삼차 부틸-4-히드록시벤조에이트, 옥타데실 3,5-디-삼차 부틸-4-히드록시벤조에이트, 2-메틸-4,6-디-삼차 부틸페닐 3,5-디-삼차 부틸-4-히드록시벤조에이트. 2.3. Esters of substituted and unsubstituted benzoic acids , for example 4-tert-butyl phenyl salicylate, phenyl salicylate, octylphenyl salicylate, dibenzoyl resorcinol, bis (4-tert-butyl benzoyl) resorci Nol, Benzoyl Resorcinol, 2,4-Di-tert-Butylphenyl 3,5-di-tert-Butyl-4-hydroxybenzoate, Hexadecyl 3,5-di-tert-Butyl-4-hydroxybenzoate, Octadecyl 3,5-di-tert butyl-4-hydroxybenzoate, 2-methyl-4,6-di-tert butylphenyl 3,5-di-tert butyl-4-hydroxybenzoate.

2.4. 아크릴레이트 및 말로네이트, 예를들어 α-시아노-β,β-디페닐아크릴산 에틸 에스테르 또는 이소옥틸 에스테르, α-카르보메톡시-신남산 메틸 에스테르, α-시아노-β-메틸-p-메톡시-신남산 메틸 에스테르 또는 부틸 에스테르, α-카르보메톡시-p-메톡시-신남산 메틸 에스테르, N-(β-카르보메톡시-β-시아노비닐)-2-메틸인돌린, Sanduvor® PR25, 디메틸 p-메톡시벤질리덴말로네이트 (CAS#7443-25-6) 및 Sanduvor® PR31, 디-(1,2,2,6,6-펜타메틸피페리딘-4-일)-p-메톡시벤질리덴말로네이트 (CAS#147783-69-5). 2.4. Acrylates and malonates , for example α-cyano-β, β-diphenylacrylic acid ethyl ester or isooctyl ester, α-carbomethoxy-cinnamic acid methyl ester, α-cyano-β-methyl-p- Methoxy-cinnamic acid methyl ester or butyl ester, α-carbomethoxy-p-methoxy-cinnamic acid methyl ester, N- (β-carbomethoxy-β-cyanovinyl) -2-methylindolin, Sanduvor ® PR25, dimethyl p-methoxybenzylidenemalonate (CAS # 7443-25-6) and Sanduvor ® PR31, di- (1,2,2,6,6-pentamethylpiperidin-4-yl)- p-methoxybenzylidenemalonate (CAS # 147783-69-5).

2.5. 니켈 화합물, 2.5. Nickel compound ,

예를 들어 적절한 경우 부가적인 리간드(예: n-부틸아민, 트리에탄올아민 또는 N-시클로헥실디에탄올아민)가 있는 2,2'-티오-비스[4-(1,1,3,3-테트라메틸부틸)페놀]의 니켈 착물(예컨대 1:1 또는 1:2 착물), 니켈 디부틸 디티오카바메이트, 4-히드록시-3,5-디-삼차 부틸벤질 포스폰산 모노알킬 에스테르(예: 메틸 에스테르 또는 에틸 에스테르)의 니켈 염, 케톡심(예: 2-히드록시-4-메틸페닐 운데실케톡심)의 니켈 착물, 적절한 경우 부가적인 리간드가 있는 1-페닐-4-라우로일-5-히드록시 피라졸의 니켈 착물.For example, 2,2'-thio-bis [4- (1,1,3,3-tetra), where appropriate, with additional ligands such as n-butylamine, triethanolamine or N-cyclohexyl diethanolamine Methylbutyl) phenol] (such as 1: 1 or 1: 2 complex), nickel dibutyl dithiocarbamate, 4-hydroxy-3,5-di-tertiary butylbenzyl phosphonic acid monoalkyl ester (e.g. Nickel salts of methyl esters or ethyl esters), nickel complexes of ketoximes (eg 2-hydroxy-4-methylphenyl undecylketoxime), 1-phenyl-4-lauroyl-5- with additional ligands, where appropriate Nickel complex of hydroxypyrazole.

2.6. 입체장애 아민 안정화제, 예를들어 4-히드록시-2,2,6,6-테트라메틸피페리딘, 1-알릴-4-히드록시-2,2,6,6-테트라메틸피페리딘, 1-벤질-4-히드록시-2,2,6,6-테트라메틸피페리딘, 비스(2,2,6,6-테트라메틸-4-피페리딜)세바케이트, 비스(2,2,6,6-테트라메틸-4-피페리딜)숙시네이트, 비스(1,2,2,6,6-펜타메틸-4-피페리딜)세바케이트, 비스(1-옥틸옥시-2,2,6,6-테트라메틸-4-피페리딜)세바케이트, 비스 (1,2,2,6,6-펜타메틸-4-피페리딜) n-부틸-3,5-디-삼차부틸-4-히드록시벤질말로네이트, 1-(2-히드록시에틸)-2,2,6,6-테트라메틸-4-히드록시피페리딘과 숙신산의 축합생성물, N,N'-비스(2,2,6,6-테트라메틸-4-피페리딜)헥사메틸렌디아민과 4-삼차옥틸아미노-2,6-디클로로-1,3,5-트리아진의 선형 또는 고리상 축합생성물, 트리스 (2,2,6,6-테트라메틸-4-피페리딜)니트릴로트리아세테이트, 테트라키스(2,2,6,6-테트라메틸-4-피페리딜)-1,2,3,4-부탄테트라카르복실레이트, 1,1'-(1,2-에탄디일)비스(3,3,5,5-테트라메틸피페라지논), 4-벤조일-2,2,6,6-테트라메틸피페리딘, 4-스테아릴옥시-2,2,6,6-테트라메틸피페리딘, 비스(1,2,2,6,6-펜타메틸피페리딜)-2-n-부틸-2-(2-히드록시-3,5-디-삼차부틸벤질)말로네이트, 3-n-옥틸-7,7,9,9-테트라메틸-1,3,8-트리아자스피로[4.5]데칸-2,4-디온, 비스(1-옥틸옥시 -2,2,6,6-테트라메틸피페리딜)세바케이트, 비스(1-옥틸옥시-2,2,6,6-테트라메틸피페리딜)숙시네이트, N, N'-비스(2,2,6,6-테트라메틸-4-피페리딜)헥사메틸렌디아민과 4-모르폴리노-2,6-디클로로-1,3,5-트리아진의 선형 또는 고리상 축합생성물, 2-클로로-4,6-비스(4-n-부틸아미노-2,2,6,6-테트라메틸피페리딜)-1,3,5-트리아진과 1,2-비스(3-아미노프로필아미노)에탄의 축합생성물, 2-클로로-4,6-디-(4-n-부틸아미노-1,2,2,6,6-펜타메틸피페리딜)-1,3,5-트리아진과 1,2-비스(3-아미노프로필아미노)에탄의 축합생성물, 8-아세틸-3-도데실-7,7,9,9-테트라메틸-1,3,8-트리아자스피로[4.5]데칸-2,4-디온, 3-도데실-1-(2,2,6,6-테트라메틸-4-피페리딜)피롤리딘-2,5-디온, 3-도데실-1-(1, 2,2,6,6-펜타메틸-4-피페리딜)피롤리딘-2,5-디온, 4-헥사데실옥시- 및 4-스테아릴옥시-2,2,6,6-테트라메틸피페리딘의 혼합물, N,N'-비스-(2,2,6,6-테트라메틸-4-피페리딜)헥사메티렌디아민 및 4-시클로헥실아민-2,6-디-클로로-1,3,5-트리아진의 축합생성물, 1,2-비스(3-아미노프로필아미노)에탄 및 2,4,6-트리클로로-1,3,5-트리아진 뿐만 아니라 4-부틸아미노-2,2,6,6-테트라메틸피페리딘의 축합생성물(CAS Reg.No.[136504-96-6]); N-(2,2,6,6-테트라메틸-4-피페리딜)-n-도데실숙신이미드, N-(1,2,2,6,6-펜타메틸-4-피페리딜)-n-도데실숙신이미드, 2-운데실-7,7,9,9-테트라메틸-1-옥사-3,8-디아자-4-옥소-스피로[4,5]데칸, 7,7,9,9-테트라메틸-2-시클로운데실-1-옥사-3,8-디아자-4-옥소스피로[4,5]데칸 및 에피클로로히드린의 반응생성물, 1,1-비스(1,2,2,6,6-펜타메틸-4-피페리딜옥시카르보닐)-2-(4-메톡시페닐)에텐, N,N'-비스포르밀-N,N'-비스(2,2,6,6-테트라메틸-4-피페리딜)헥사메틸렌디아민, 4-메톡시메틸렌말론산과 1,2,2,6,6-펜타메틸-4-히드록시피페리딘의 디에스테르, 폴리 -[메틸프로필-3-옥시-4-2,2,6,6-테트라메틸-4-피페리딜)]실옥산, 말레산무수물-α -올레핀 공중합체와 2,2,6,6-테트라메틸-4-아미노피페리딘 또는 1,2,2,6,6-펜타메틸-4-아미노피페리딘의 반응생성물. 2.6. Sterically hindered amine stabilizers such as 4-hydroxy-2,2,6,6-tetramethylpiperidine, 1-allyl-4-hydroxy-2,2,6,6-tetramethylpiperidine , 1-benzyl-4-hydroxy-2,2,6,6-tetramethylpiperidine, bis (2,2,6,6-tetramethyl-4-piperidyl) sebacate, bis (2, 2,6,6-tetramethyl-4-piperidyl) succinate, bis (1,2,2,6,6-pentamethyl-4-piperidyl) sebacate, bis (1-octyloxy-2 , 2,6,6-tetramethyl-4-piperidyl) sebacate, bis (1,2,2,6,6-pentamethyl-4-piperidyl) n-butyl-3,5-di- Tert-butyl-4-hydroxybenzylmalonate, condensation product of 1- (2-hydroxyethyl) -2,2,6,6-tetramethyl-4-hydroxypiperidine with succinic acid, N, N'- Linear or cyclic condensation products of bis (2,2,6,6-tetramethyl-4-piperidyl) hexamethylenediamine with 4-tert-octylamino-2,6-dichloro-1,3,5-triazine , Tris (2,2,6,6-tetramethyl-4-piperidyl) nitrilotriacetate, tetrakis (2,2,6 , 6-tetramethyl-4-piperidyl) -1,2,3,4-butanetetracarboxylate, 1,1 '-(1,2-ethanediyl) bis (3,3,5,5- Tetramethylpiperazinone), 4-benzoyl-2,2,6,6-tetramethylpiperidine, 4-stearyloxy-2,2,6,6-tetramethylpiperidine, bis (1,2 , 2,6,6-pentamethylpiperidyl) -2-n-butyl-2- (2-hydroxy-3,5-di-tert-butylbenzyl) malonate, 3-n-octyl-7,7 , 9,9-tetramethyl-1,3,8-triazaspiro [4.5] decane-2,4-dione, bis (1-octyloxy-2,2,6,6-tetramethylpiperidyl) seva Kate, bis (1-octyloxy-2,2,6,6-tetramethylpiperidyl) succinate, N, N'-bis (2,2,6,6-tetramethyl-4-piperidyl) Linear or cyclic condensation products of hexamethylenediamine with 4-morpholino-2,6-dichloro-1,3,5-triazine, 2-chloro-4,6-bis (4-n-butylamino-2 Condensation product of 2,6,6-tetramethylpiperidyl) -1,3,5-triazine with 1,2-bis (3-aminopropylamino) ethane, 2-chloro-4,6-di- ( 4-n-butylamino Condensation product of -1,2,2,6,6-pentamethylpiperidyl) -1,3,5-triazine with 1,2-bis (3-aminopropylamino) ethane, 8-acetyl-3-dode Sil-7,7,9,9-tetramethyl-1,3,8-triazaspiro [4.5] decane-2,4-dione, 3-dodecyl-1- (2,2,6,6-tetra Methyl-4-piperidyl) pyrrolidine-2,5-dione, 3-dodecyl-1- (1, 2,2,6,6-pentamethyl-4-piperidyl) pyrrolidine-2 A mixture of, 5-dione, 4-hexadecyloxy- and 4-stearyloxy-2,2,6,6-tetramethylpiperidine, N, N'-bis- (2,2,6,6 Condensation products of -tetramethyl-4-piperidyl) hexamethylenediamine and 4-cyclohexylamine-2,6-di-chloro-1,3,5-triazine, 1,2-bis (3-amino Condensation products of 4-butylamino-2,2,6,6-tetramethylpiperidine as well as propylamino) ethane and 2,4,6-trichloro-1,3,5-triazine (CAS Reg.No. . [136504-96-6]); N- (2,2,6,6-tetramethyl-4-piperidyl) -n-dodecylsuccinimide, N- (1,2,2,6,6-pentamethyl-4-piperidyl ) -n-dodecylsuccinimide, 2-undecyl-7,7,9,9-tetramethyl-1-oxa-3,8-diaza-4-oxo-spiro [4,5] decane, 7 Reaction product of 7,7,9,9-tetramethyl-2-cycloundecyl-1-oxa-3,8-diaza-4-oxospyro [4,5] decane and epichlorohydrin, 1,1- Bis (1,2,2,6,6-pentamethyl-4-piperidyloxycarbonyl) -2- (4-methoxyphenyl) ethene, N, N'-bisporyl-N, N'- Bis (2,2,6,6-tetramethyl-4-piperidyl) hexamethylenediamine, 4-methoxymethylenemalonic acid and 1,2,2,6,6-pentamethyl-4-hydroxypiperidine Diester, poly- [methylpropyl-3-oxy-4-2,2,6,6-tetramethyl-4-piperidyl)] siloxane, maleic anhydride-α-olefin copolymer and 2,2 Reaction product of 6,6-tetramethyl-4-aminopiperidine or 1,2,2,6,6-pentamethyl-4-aminopiperidine.

입체장애 아민은 본 발명에서 참고로 하는 미국특허 5,980,783호에 기재된 화합물중의 하나, 즉 미국특허 5,980,783호의 칼럼 64-72에 수록된 화합물 I-a), I-b), I-c), I-d), I-e), I-f), I-g), I-h), I-i), I-j), I-k) 또는 I-l), 특히 광안정화제 1-a-1, 1-a-2, 1-b-1, 1-c-1, 1-c-2, 1-d-1, 1-d-2, 1-d-3, 1-e-1, 1-f-1, 1-g-1, 1-g-2 또는 1-k-1이다. The hindered amine is one of the compounds described in US Pat. No. 5,980,783, to which the compounds Ia), Ib), Ic), Id), Ie), If) are listed in column 64-72 of US Pat. No. 5,980,783. , Ig), Ih), Ii), Ij), Ik) or Il), in particular light stabilizers 1-a-1, 1-a-2, 1-b-1, 1-c-1, 1-c- 2, 1-d-1, 1-d-2, 1-d-3, 1-e-1, 1-f-1, 1-g-1, 1-g-2 or 1-k-1 .

입체장애 아민은 또한 본 발명에서 참고로 하는 미국 특허 6,046,304호 및 6,297,299호에 기재된 화합물중의 하나, 예컨대 청구항 10 또는 38 또는 실시예 1-12 또는 D-1 내지 D-5에 기재된 화합물일 수 있다. The hindered amines may also be one of the compounds described in US Pat. Nos. 6,046,304 and 6,297,299, which are incorporated herein by reference, such as those described in claims 10 or 38 or Examples 1-12 or D-1 to D-5. .

2.7. 히드록시-치환된 알콕시 기에 의해 N- 원자상에서 치환된 입체장애 아민, 예컨대 1-(2-히드록시-2-메틸-프로폭시)-4-옥타데카노일옥시-2,2,6,6-테트라메틸피페리딘, 1-(2-히드록시-2-메틸프로폭시)-4-헥사데카노일옥시-2,2,6,6-테트라메틸피페리딘, 1-옥실-4-히드록시-2,2,6,6-테트라메틸피페리딘과 삼차-아밀알코올로부터의 탄소 라디칼과의 반응 생성물, 1-(2-히드록시-2-메틸프로폭시)-4-히드록시-2,2,6,6-테트라메틸피페리딘, 1-(2-히드록시-2-메틸프로폭시)-4-옥소-2,2,6,6-테트라메틸피페리딘, 비스(1-(2-히드록시-2-메틸프로폭시)-2,2,6,6-테트라메틸피페리딘-4-일)아디페이트, 비스(1-(2-히드록시-2-메틸프로폭시)-2,2,6,6-테트라메틸피페리딘-4-일)숙시네이트, 비스(1-(2-히드록시-2-메틸프로폭시)-2,2,6,6-테트라메틸피페리딘-4-일)글루타레이트 또는 2,4-비스{N-[1-(2-히드록시-2-메틸프로폭시)-2,2,6,6-테트라메틸피페리딘-4-일]-N-부틸아미노}-6-(2-히드록시에틸아미노)-s-트리아진. 2.7. Hindered amines substituted on the N- atom by hydroxy-substituted alkoxy groups such as 1- (2-hydroxy-2-methyl-propoxy) -4-octadecanoyloxy-2,2,6,6- Tetramethylpiperidine, 1- (2-hydroxy-2-methylpropoxy) -4-hexadecanoyloxy-2,2,6,6-tetramethylpiperidine, 1-oxyl-4-hydroxy Reaction product of -2,2,6,6-tetramethylpiperidine with carbon radicals from tert-amyl alcohol, 1- (2-hydroxy-2-methylpropoxy) -4-hydroxy-2, 2,6,6-tetramethylpiperidine, 1- (2-hydroxy-2-methylpropoxy) -4-oxo-2,2,6,6-tetramethylpiperidine, bis (1- ( 2-hydroxy-2-methylpropoxy) -2,2,6,6-tetramethylpiperidin-4-yl) adipate, bis (1- (2-hydroxy-2-methylpropoxy)- 2,2,6,6-tetramethylpiperidin-4-yl) succinate, bis (1- (2-hydroxy-2-methylpropoxy) -2,2,6,6-tetramethylpiperi Din-4-yl) glutarate or 2,4-bis {N- [1- (2-hydroxy-2-meth Propoxy) 2,2,6,6-tetramethyl-4-yl] -N- butylamino} -6- (2-hydroxy-ethylamino) -s- triazine.

2.8. 옥사미드, 예를들어 4,4'-디옥틸옥시옥사닐리드, 2,2'-디에톡시옥사닐리드, 2,2'-디옥틸옥시-5,5'-디-삼차 부톡사아닐리드, 2,2'-디도데실옥시-5,5'-디-삼차 부톡사아닐리드, 2-에톡시-2'-에톡사닐리드, N,N'-비스(3-디메틸아미노프로필)옥사미드, 2-에톡시-5-삼차 부틸-2'-에톡사닐리드 및 그와 2-에톡시-2'-에틸-5,4'-디-삼차 부톡사닐리드와의 혼합물, o- 및 p-메톡시-이중 치환된 옥사닐리드의 혼합물 및 o- 및 p-에톡시-이중치환된 옥사닐리드의 혼합물. 2.8. Oxamides , for example 4,4'-dioctyloxyoxanilide, 2,2'-diethoxyoxanilide, 2,2'-dioctyloxy-5,5'-di-tert-butoxananilide, 2,2'-didodecyloxy-5,5'-di-tertiary butoxananilide, 2-ethoxy-2'-ethoxanilide, N, N'-bis (3-dimethylaminopropyl) oxamide, 2-ethoxy-5-tertiary butyl-2'-ethoxanilide and mixtures thereof with 2-ethoxy-2'-ethyl-5,4'-di-tertiary butoxanilide, o- and p-meth A mixture of oxy-disubstituted oxanilides and a mixture of o- and p-ethoxy-disubstituted oxanilides.

2.9. 트리스 -아릴-o- 히드록시페닐 -s- 트리아진, 예를 들어 WO-A-96/28431, EP 434608, EP 941989, GB 2,317,893, 미국특허 3,843,371호; 4,619,956호; 4,740,542호; 5,096,489호; 5,106,891호; 5,298,067호; 5,300,414호; 5,354,794호; 5,461,151호; 5,476,937호; 5,489,503호; 5,543,518호; 5,556,973호; 5,597,854호; 5,681,955호; 5,726,309호; 5,736,597호; 5,942,626호; 5,959,008호; 5,998,116호; 및 6,013,704호에 기재된 공지의 트리스-아릴-o-히드록시페닐-s-트리아진 및 트리아진류, 예컨대 4,6-비스(2,4-디메틸페닐)-2-(2-히드록시-4-옥틸옥시페닐)-s-트리아진, Cyasorb® 1164, Cyte Corp, 4,6-비스-(2,4-디메틸페닐)-2-(2,4-디히드록시페닐)-s-트리아진, 2,4-비스(2,4-디히드록시페닐)-6-(4-클로로페닐)-s-트리아진, 2,4-비스[2-히드록시-4-(2-히드록시에톡시)페닐]-6-(4-클로로페닐)-s-트리아진, 2,4-비스[2-히드록시-4-(4-히드록시에톡시)페닐]-6-(4-브로모페닐)-s-트리아진, 2,4-비스[2-히드록시-4-(2-아세톡시에톡시)페닐]-6-(4-클로로페닐)-s-트리아진, 2,4-비스(2,4-디히드록시페닐)-6-(2,4-디메틸페닐)-s-트리아진, 2,4-비스(4-비페닐릴)-6-(2-히드록시-4-옥틸옥시카르보닐에틸리덴옥시페닐)-s-트리아진, 2-페닐-4-[2-히드록시-4-(3-이차-부틸옥시-2-히드록시프로필옥시)페닐]-6-[2-히드록시-4-(3-이차-아밀옥시-2-히드록시프로필옥시)페닐]-s-트리아진, 2,4-비스(2-히드록시-4-n-부틸옥시페닐)-6-(2,4-디-n-부틸옥시페닐)-s-트리아진, 2,4-비스-(2,4-디메틸페닐)-6-[2-히드록시-4-(3-노닐옥시*-2-히드록시프로필옥시)-5-α-큐밀페닐]-s-트리아진(*는 옥틸옥시, 노닐옥시 및 데실옥시 기의 혼합물을 의미함), 메틸렌비스-{2,4-비스(2,4-디메틸페닐)-6-[2-히드록시-4-(3-부틸옥시-2-히드록시프로폭시)페닐]-s-트리아진}, 3:5', 5:5' 및 3:3' 위치에서 5:4:1 비로 브릿지된 메틸렌 브릿지된 이합체 혼합물, 2,4,6-트리스(2-히드록시-4-이소옥틸옥시카르보닐이소프로필리덴옥시페닐)-s-트리아진, 2,4-비스(2,4-디메틸페닐)-6-(2-히드록시-4-헥실옥시-5-α-큐밀페닐)-s-트리아진, 2-(2,4,6-트리메틸페닐)-4,6-비스[2-히드록시-4-(3-부틸옥시-2-히드록시프로필옥시)페닐]-s-트리아진, 2,4,6-트리스[2-히드록시-4-(3-이차-부틸옥시-2-히드록시프로필옥시)페닐]-s-트리아진, 4,6-비스-(2,4-디메틸페닐)-2-(2-히드록시-4-(3-도데실옥시-2-히드록시프로폭시)-페닐)-s-트리아진과 4,6-비스-(2,4-디메틸페닐)-2-(2-히드록시-4-(3-트리데실옥시-2-히드록시프로폭시)-s-트리아진의 혼합물, Tinuvin®400, 시바 스폐셜티 케미컬스 코포레이션 제조, 4,6-비스-(2,4-디메틸페닐)-2-(2-히드록시-4-(3-(2-에틸헥실옥시)-2-히드록시프로폭시)-페닐)-s-트리아진 및 4,6-디페닐-2-(4-헥실옥시-2-히드록시페닐)-s-트리아진. 2.9. Tris -aryl-o -hydroxyphenyl- s -triazine , for example WO-A-96 / 28431, EP 434608, EP 941989, GB 2,317,893, US Pat. No. 3,843,371; 4,619,956; 4,740,542; 5,096,489; 5,106,891; 5,298,067; 5,300,414; 5,354,794; 5,461,151; 5,476,937; 5,489,503; 5,543,518; 5,556,973; 5,597,854; 5,681,955; 5,726,309; 5,736,597; 5,942,626; 5,959,008; 5,998,116; And the known tris-aryl-o-hydroxyphenyl-s-triazines and triazines described in 6,013,704, such as 4,6-bis (2,4-dimethylphenyl) -2- (2-hydroxy-4- Octyloxyphenyl) -s-triazine, Cyasorb ® 1164, Cyte Corp, 4,6-bis- (2,4-dimethylphenyl) -2- (2,4-dihydroxyphenyl) -s-triazine, 2,4-bis (2,4-dihydroxyphenyl) -6- (4-chlorophenyl) -s-triazine, 2,4-bis [2-hydroxy-4- (2-hydroxyethoxy ) Phenyl] -6- (4-chlorophenyl) -s-triazine, 2,4-bis [2-hydroxy-4- (4-hydroxyethoxy) phenyl] -6- (4-bromophenyl ) -s-triazine, 2,4-bis [2-hydroxy-4- (2-acetoxyethoxy) phenyl] -6- (4-chlorophenyl) -s-triazine, 2,4-bis (2,4-dihydroxyphenyl) -6- (2,4-dimethylphenyl) -s-triazine, 2,4-bis (4-biphenylyl) -6- (2-hydroxy-4- Octyloxycarbonylethylideneoxyphenyl) -s-triazine, 2-phenyl-4- [2-hydroxy-4- (3-secondary-butyloxy-2-hydroxypropyloxy) phenyl] -6- [2-hydroxy-4- (3-di -Amyloxy-2-hydroxypropyloxy) phenyl] -s-triazine, 2,4-bis (2-hydroxy-4-n-butyloxyphenyl) -6- (2,4-di-n- Butyloxyphenyl) -s-triazine, 2,4-bis- (2,4-dimethylphenyl) -6- [2-hydroxy-4- (3-nonyloxy * -2-hydroxypropyloxy)- 5-α-cumylphenyl] -s-triazine (* means a mixture of octyloxy, nonyloxy and decyloxy groups), methylenebis- {2,4-bis (2,4-dimethylphenyl)- 6- [2-hydroxy-4- (3-butyloxy-2-hydroxypropoxy) phenyl] -s-triazine}, 5: at 5 ', 5: 5' and 3: 3 'positions Methylene bridged dimer mixture bridged in 4: 1 ratio, 2,4,6-tris (2-hydroxy-4-isooctyloxycarbonylisopropylideneoxyphenyl) -s-triazine, 2,4-bis ( 2,4-dimethylphenyl) -6- (2-hydroxy-4-hexyloxy-5-α-cumylphenyl) -s-triazine, 2- (2,4,6-trimethylphenyl) -4, 6-bis [2-hydroxy-4- (3-butyloxy-2-hydroxypropyloxy) phenyl] -s-triazine, 2,4,6-tris [2-hydroxy-4 -(3-secondary-butyloxy-2-hydroxypropyloxy) phenyl] -s-triazine, 4,6-bis- (2,4-dimethylphenyl) -2- (2-hydroxy-4- ( 3-dodecyloxy-2-hydroxypropoxy) -phenyl) -s-triazine and 4,6-bis- (2,4-dimethylphenyl) -2- (2-hydroxy-4- (3-tri Mixture of decyloxy-2-hydroxypropoxy) -s-triazine, Tinuvin ® 400, manufactured by Ciba Specialty Chemicals Corporation, 4,6-bis- (2,4-dimethylphenyl) -2- (2 -Hydroxy-4- (3- (2-ethylhexyloxy) -2-hydroxypropoxy) -phenyl) -s-triazine and 4,6-diphenyl-2- (4-hexyloxy- 2-hydroxyphenyl) -s-triazine.

3. 금속 탈활성화제, 예를들어 N,N'-디페닐옥사아미드, N-살리실알-N'-살리실로일히드라진, N,N'-비스(살리실로일)히드라진, N,N'-비스(3,5-디-삼차 부틸-4-히드록시페닐프로피오닐)히드라진, 3-살리실로일아미노-1,2,4-트리아졸, 비스(벤질리덴)옥살릴 디히드라지드, 옥사닐리드, 이소프탈오일 디히드라지드, 세바코일 비스페닐히드라지드, N,N'-디아세틸아디포일 디히드라지드, N,N'-비스(살리실오일)옥살릴 디히드라지드, N,N'-비스(살리실오일)티오프로피오닐 디히드라지드. 3. Metal deactivators such as N, N'-diphenyloxaamide, N-salicyl-N'-salicyloylhydrazine, N, N'-bis (salicyloyl) hydrazine, N, N ' -Bis (3,5-di-tertiary butyl-4-hydroxyphenylpropionyl) hydrazine, 3-salicyloylamino-1,2,4-triazole, bis (benzylidene) oxalyl dihydrazide, oxa Nilide, isophthaloyl dihydrazide, sebacoyl bisphenylhydrazide, N, N'-diacetyladifoyl dihydrazide, N, N'-bis (salicyl) oxalyl dihydrazide, N, N '-Bis (salicylic oil) thiopropionyl dihydrazide.

4. 포스파이트 및 포스포나이트, 예를들어 트리페닐 포스파이트, 디페닐알킬 포스파이트, 페닐디알킬 포스파이트, 트리스(노닐페닐)포스파이트, 트리라우릴 포스파이트, 트리옥타데실 포스파이트, 디스테아릴 펜타에리트리톨 디포스파이트, 트리스(2,4-디-삼차 부틸페닐)포스파이트, 디이소데실 펜타에리트리톨 디포스파이트, 비스(2,4-디-삼차 부틸페닐)펜타에리트리톨 디포스파이트, 비스(2,4-디큐밀페닐)펜타에리트리톨 디포스파이트, 비스(2,6-디-삼차 부틸-4-메틸페닐)펜타에리트리톨 디포스파이트, 디이소데실옥시펜타에리트리톨 디포스파이트, 비스(2,4-디-삼차 부틸-6-메틸페닐)펜타에리트리톨 디포스파이트, 비스(2,4,6-트리스-삼차 부틸페닐)펜타에리트리톨 디포스파이트, 트리스테아릴 소르비톨 트리포스파이트, 테트라키스(2,4-디-삼차 부틸페닐)4,4'-비페닐렌 디포스포나이트, 6-이소옥틸옥시-2,4,8,10-테트라-삼차 부틸-12H-디벤즈[d,g]-1,3,2-디옥사포스포신, 비스(2,4-디-삼차 부틸-6-메틸페닐)메틸 포스파이트, 비스(2,4-디-삼차 부틸-6-메틸페닐)에틸 포스파이트, 6-플루오로-2,4,8,10-테트라-삼차 부틸-12-메틸-디벤즈[d,g]-1,3,2-디옥사포스포신, 2,2',2"-니트릴로-[트리에틸트리스(3,3',5,5'-테트라-삼차 부틸-1,1'-비페닐-2,2'-디일)포스파이트], 2-에틸헥실(3,3',5,5'-테트라-삼차 부틸-1,1'-비페닐-2,2'-디일)포스파이트. 4. Phosphites and phosphonites such as triphenyl phosphite, diphenylalkyl phosphite, phenyldialkyl phosphite, tris (nonylphenyl) phosphite, trilauryl phosphite, trioctadecyl phosphite, disdis Tearyl pentaerythritol diphosphite, tris (2,4-di-tertiary butylphenyl) phosphite, diisodecyl pentaerythritol diphosphite, bis (2,4-di-tertiary butylphenyl) pentaerythritol diphosphite, Bis (2,4-dicumylphenyl) pentaerythritol diphosphite, bis (2,6-di-tertiary butyl-4-methylphenyl) pentaerythritol diphosphite, diisodecyloxypentaerythritol diphosphite, bis (2 , 4-di-tert-butyl-6-methylphenyl) pentaerythritol diphosphite, bis (2,4,6-tris-tert-butylphenyl) pentaerythritol diphosphite, tristearyl sorbitol triphosphite, tetrakis (2 , 4-di-tert butylphenyl) 4, 4'-biphenylene diphosphonite, 6-isooctyloxy-2,4,8,10-tetra-tertiary butyl-12H-dibenz [d, g] -1,3,2-dioxaphosphosine, Bis (2,4-di-tert butyl-6-methylphenyl) methyl phosphite, bis (2,4-di-tert butyl-6-methylphenyl) ethyl phosphite, 6-fluoro-2,4,8,10 Tetra-tertiary butyl-12-methyl-dibenz [d, g] -1,3,2-dioxaphosphosine, 2,2 ', 2 "-nitrilo- [triethyltris (3,3', 5,5'-tetra-tertiary butyl-1,1'-biphenyl-2,2'-diyl) phosphite], 2-ethylhexyl (3,3 ', 5,5'-tetra-tertiary butyl-1 , 1'-biphenyl-2,2'-diyl) phosphite.

이하의 포스파이트가 특히 바람직하다: Particular preference is given to the following phosphites:

트리스(2,4-디-삼차 부틸페닐)포스파이트(Irgafos® 168, 시바 스페셜티 케미칼스사 제품), 트리스(노닐페닐)포스파이트 및 하기 화학식(A), (B), (C), (D), (E), (F) 및 (G)를 포함하는 군으로부터 선택되는 포스파이트:Tris (2,4-di-tert-butylphenyl) phosphite (Irgafos ® 168, from Ciba Specialty Chemicals), tris (nonylphenyl) phosphite and the following formulas (A), (B), (C), (D ), (E), (F) and (G) phosphite selected from the group comprising:

Figure 112007003298238-PCT00001
Figure 112007003298238-PCT00001

Figure 112007003298238-PCT00002
Figure 112007003298238-PCT00002

Figure 112007003298238-PCT00003
Figure 112007003298238-PCT00003

Figure 112007003298238-PCT00004
Figure 112007003298238-PCT00004

Figure 112007003298238-PCT00005
Figure 112007003298238-PCT00005

5. 히드록실아민, 예를들어 N,N-디벤질히드록실아민, N,N-디에틸히드록실아민, N,N-디옥틸히드록실아민, N,N-디라우릴히드록실아민, N,N-디테트라데실히드록실아민, N,N-디헥사데실히드록실아민, N,N-디옥타데실히드록실아민, N-헥사데실-N-옥타데실히드록실아민, N-헵타데실-N-옥타데실히드록실아민, 수소화 수지 아민으로부터 유도된 N,N-디알킬히드록실아민. 5. Hydroxylamines such as N, N-dibenzylhydroxylamine, N, N-diethylhydroxylamine, N, N-dioctylhydroxylamine, N, N-dilaurylhydroxylamine, N , N-ditetedecylhydroxylamine, N, N-dihexadecylhydroxylamine, N, N-dioctadecylhydroxylamine, N-hexadecyl-N-octadecylhydroxylamine, N-heptadecyl- N-octadecylhydroxylamine, N, N-dialkylhydroxylamine derived from hydrogenated resin amine.

6. 니트론, 예를들어 N-벤질-α-페닐-니트론, N-에틸-α-메틸-니트론, N-옥틸-α-헵틸-니트론, N-라우릴-α-운데실-니트론, N-테트라데실-α-트리데실-니트론, N-헥사데실-α-펜타데실-니트론, N-옥타데실-α-헵타데실-니트론, N-헥사데실-α-헵타데실-니트론, N-옥타데실-α-페타데실-니트론, N-헵타데실-α-헵타데실-니트론, N-옥타데실-α-헥사데실-니트론, 수소화 수지 아민으로부터 유도된 N,N-디알킬히드록실아민으로부터 유도된 니트론. 6. Nitrons , eg N-benzyl-α-phenyl-nitron, N-ethyl-α-methyl-nitron, N-octyl-α-heptyl-nitron, N-lauryl-α-undecyl Nitron, N-tetradecyl-α-tridecyl-nitron, N-hexadecyl-α-pentadecyl-nitron, N-octadecyl-α-heptadecyl-nitron, N-hexadecyl-α- Derived from heptadecyl-nitron, N-octadecyl-α-fetadecyl-nitron, N-heptadecyl-α-heptadecyl-nitron, N-octadecyl-α-hexadecyl-nitron, hydrogenated resin amine Nitron derived from N, N-dialkylhydroxylamine.

7. 아민 옥사이드, 예를 들어 미국특허 5,844,029호 및 5,880,191호에 기재된 바와 같은 아민 옥사이드 유도체, 디데실 메틸 아민 옥사이드, 트리데실 아민 옥사이드, 트리도데실 아민 옥사이드 및 트리헥사데실 아민 옥사이드. 7. Amine oxides such as amine oxide derivatives, such as didecyl methyl amine oxide, tridecyl amine oxide, tridodecyl amine oxide and trihexadecyl amine oxide, as described, for example, in US Pat. Nos. 5,844,029 and 5,880,191.

8. 벤조푸라논 및 인돌리논 , 예를들어 미국특허 4 325 863호, 4 338 244호, 5 175 312호, 5 216 052호, 5 252 643호, DE-A-4 316 611호, DE-A-4 316 622호, DE-A-4 316 876호, EP-A-0 589 839호, EP-A-0 591 102호, EP-A-1 291 364호에 개시된 것 또는 3-[4-(2-아세톡시에톡시)페닐]-5,7-디-삼차 부틸-벤조푸란-2-온, 5,7-디-삼차 부틸-3-[4-(2-스테아로일옥시에톡시)페닐]벤조푸란-2-온, 3,3'-비스[5,7-디-삼차 부틸-3-(4-[2-히드록시에톡시]-페닐)벤조푸란-2-온], 5,7-디-삼차 부틸-3-(4-에톡시페닐)벤조푸란-2-온, 3-(4-아세톡시-3,5-디메틸페닐)-5,7-디-삼차 부틸-벤조푸란-2-온, 3-(3,5-디메틸-4-피발로일옥시페닐)-5,7-디-삼차 부틸-벤조푸란-2-온, 3-(3,4-디메틸페닐)-5,7-디-삼차 부틸벤조푸란-2-온, 3-(2,3-디메틸페닐)-5,7-디-삼차 부틸벤조푸란-2-온, 3-(2-아세틸-5-이소옥틸페닐)-5-이소옥틸벤조푸란-2-온. 8. Benzofuranone and indolinones , for example US Pat. Nos. 4 325 863, 4 338 244, 5 175 312, 5 216 052, 5 252 643, DE-A-4 316 611, DE- A-4 316 622, DE-A-4 316 876, EP-A-0 589 839, EP-A-0 591 102, EP-A-1 291 364 or 3- [4 -(2-acetoxyethoxy) phenyl] -5,7-di-tertiary butyl-benzofuran-2-one, 5,7-di-tertiary butyl-3- [4- (2-stearoyloxye Methoxy) phenyl] benzofuran-2-one, 3,3'-bis [5,7-di-tertiary butyl-3- (4- [2-hydroxyethoxy] -phenyl) benzofuran-2-one] , 5,7-di-tert butyl-3- (4-ethoxyphenyl) benzofuran-2-one, 3- (4-acetoxy-3,5-dimethylphenyl) -5,7-di-tert butyl -Benzofuran-2-one, 3- (3,5-dimethyl-4-pivaloyloxyphenyl) -5,7-di-tertiary butyl-benzofuran-2-one, 3- (3,4-dimethyl Phenyl) -5,7-di-tertiary butylbenzofuran-2-one, 3- (2,3-dimethylphenyl) -5,7-di-tertiary butylbenzofuran-2-one, 3- (2-acetyl -5-isooctylphenyl) -5-isooctylbenzofuran-2-one.

9. 티오상승제, 예를 들어 디라우릴 티오디프로피오네이트 또는 디스테아릴 티오디프로피오네이트. 9. Thio synergists , for example dilauryl thiodipropionate or distearyl thiodipropionate.

10. 과산화물 제거제, 예를들어 β-티오디프로핀산의 에스테르, 예컨대 라우릴, 스테아릴, 미리스틸 또는 트리데실 에스테르, 머캅토벤즈이미다졸 또는 2-머캅토벤즈이미다졸의 아연염, 디부틸디티오카밤산 아연, 디옥타데실 디술피드, 펜타에리트리톨 테트라키스(β-도데실메르캅토)프로피오네이트. 10. Peroxide scavengers , for example esters of β-thiodipropinic acid such as lauryl, stearyl, myristyl or tridecyl esters, zinc salts of mercaptobenzimidazole or 2-mercaptobenzimidazole, dibutyl Zinc dithiocarbamate, dioctadecyl disulfide, pentaerythritol tetrakis (β-dodecyl mercapto) propionate.

11. 폴리아미드 안정화제, 예를들어 요오드 및/또는 인 화합물과 병합된 구리 염 및 2가 망간의 염. 11. Polyamide stabilizers , for example copper salts in combination with iodine and / or phosphorus compounds and salts of divalent manganese.

12. 염기성 공안정화제, 예를들어 멜라민, 폴리비닐피롤리돈, 디시안디아미드, 트리알릴 시아누레이트, 우레아 유도체, 히드라진 유도체, 아민, 폴리아미드, 폴리우레탄, 고급 지방산의 알칼리금속 및 알칼리토금속 염, 예컨대 스테아르산 칼슘, 스테아르산 아연, 베헨산 마그네슘, 스테아르산 마그네슘, 리시놀레산 나트륨, 팔미트산 칼륨, 피로카테콜산 안티몬 또는 피로카테콜산 아연. 12. Basic co-stabilizers , for example melamine, polyvinylpyrrolidone, dicyandiamide, triallyl cyanurate, urea derivatives, hydrazine derivatives, amines, polyamides, polyurethanes, alkali and alkaline earth metal salts of higher fatty acids. Such as calcium stearate, zinc stearate, magnesium behenate, magnesium stearate, sodium ricinoleate, potassium palmitate, antimony pyrocatecholate or zinc pyrocatecholate.

13. 핵생성제, 예를들어 무기물질(예;활석), 금속 산화물(예; 이산화 티탄 또는 산화마그네슘), 바람직하게는 알칼리 토금속의 인산염, 탄산염 또는 황산염; 유기 화합물(모노- 또는 폴리카르복시산) 및 이들의 염, 예컨대 4-삼차 부틸벤조산, 아디프산, 디페닐아세트산, 숙신산 나트륨 또는 벤조산 나트륨; 중합체 화합물, 예컨대 이온성 공중합체("이오노머"). 13. Nucleating agents , for example inorganic substances (eg talc), metal oxides (eg titanium dioxide or magnesium oxide), preferably phosphates, carbonates or sulfates of alkaline earth metals; Organic compounds (mono- or polycarboxylic acids) and salts thereof such as 4-tertiary butylbenzoic acid, adipic acid, diphenylacetic acid, sodium succinate or sodium benzoate; Polymeric compounds such as ionic copolymers (“ionomers”).

14. 충전제 및 보강제, 예를 들어 탄산칼슘, 규산염, 유리 섬유, 유리 벌브, 석면, 활석, 카올린, 운모, 황산바륨, 금속 산화물 및 수산화물, 카본블랙, 흑연, 목재 가루 또는 기타 천연물의 가루 또는 섬유, 합성 섬유. 14. Fillers and reinforcing agents , for example calcium carbonate, silicates, glass fibers, glass bulbs, asbestos, talc, kaolin, mica, barium sulfate, metal oxides and hydroxides, carbon black, graphite, wood flour or other natural powders or fibers , Synthetic fiber.

15. 분산제, 예를 들어 폴리에틸렌 산화물 왁스 또는 광유. 15. Dispersants , for example polyethylene oxide waxes or mineral oils.

16. 기타 첨가제, 예를들어 가소제, 윤활제, 유화제, 안료, 유동 보조제, 촉매, 유동조절제, 광학 광택제(brighteners), 미끄럼제, 가교제, 가교 부스터(boosters), 할로겐 제거제, 매연 억제제, 난연제, 대전방지제, 치환 및 비치환 비스벤질리덴 소르비톨과 같은 청정제(clarifiers), 2,2'-p-페닐렌-비스(3,1-벤조옥사진-4-온)과 같은 벤조옥사지논 UV 흡수제, Cyasorb® 3638(CAS# 18600-59-4) 및 발포제. 16. Other additives , for example plasticizers, lubricants, emulsifiers, pigments, flow aids, catalysts, flow regulators, optical brighteners, slippers, crosslinkers, crosslinker boosters, halogen removers, soot suppressors, flame retardants, charging Clarifiers such as inhibitors, substituted and unsubstituted bisbenzylidene sorbitol, benzooxazinone UV absorbers such as 2,2'-p-phenylene-bis (3,1-benzooxazin-4-one), Cyasorb ® 3638 (CAS # 18600-59-4) and blowing agents.

본 발명의 섬유나 필라멘트로부터 제조된 습윤성 직물은 이를테면 위생 물품, 특히 일회용 기저귀, 운동복, 여성 위생 제품 또는 요실금 보호 제품의 피부 접촉 내부 라이닝 직물로서 특히 유용하다. 직물은 또한 젖은 걸래, 마른 걸래, 권취된 드레싱, 수술 망토, 여과 메디알, 배터리 분리기 등과 같은 물품에 유용하다.Wettable fabrics made from the fibers or filaments of the present invention are particularly useful as skin contact inner lining fabrics, such as in hygiene articles, in particular disposable diapers, sportswear, feminine hygiene products or incontinence protection products. Fabrics are also useful for articles such as wet rags, dry rags, wound dressings, surgical capes, filtration media, battery separators, and the like.

기저귀의 구조는 이를테면 미국특허 5,149,576; 5,961,504; 6,031,147 및 6,110,849에 기재되어 있다.The structure of the diaper is described, for example, in US Pat. No. 5,149,576; 5,961,504; 6,031,147 and 6,110,849.

또한, 용융 압출된 폴리올레핀 필름에 습윤성을 부여하는 것이 종종 바람직하다. 천공된 형태의 이러한 필름은 위생 물품의 커버 시트로서 널리 사용된다.In addition, it is often desirable to impart wettability to melt extruded polyolefin films. Such films in perforated form are widely used as cover sheets for sanitary articles.

위생 물품의 커버스톡(coverstock)에 있어서, 함께 결합된 2층 이상의 직물을 사용함으로써 역습윤(wetback) 성질을 개선할 수 있다. 그 예는, 용융취입 층에 화학식(I)의 첨가제가 전혀 없는 SMS 직물이나 2개의 방사결합 층을 포함한다.In the coverstock of hygiene articles, the use of two or more layers of fabrics bonded together can improve the wetback properties. Examples include SMS fabrics or two spin-bonding layers in which the meltblown layer is free of additives of formula (I).

본 발명의 직물은 약 0.5∼10 메가라드의 감마선의 조사에 의해 멸균될 수 있다. 감마선 조사에 의한 멸균은 병원복 등에 이용된다.The fabric of the present invention can be sterilized by irradiation of gamma rays of about 0.5-10 megarad. Sterilization by gamma irradiation is used for hospital clothes and the like.

다음 실시예에서는 본 발명을 더욱 상세히 설명한다. 별도 언급이 없는 한, 양은 중량%이다.The following examples illustrate the invention in more detail. Unless stated otherwise, amounts are in weight percent.

폴리에틸렌 테레프탈레이트(섬유 급, Wellman PERMACLEAR Lot 61458) 195부와 1급 및 2급 나트륨 알킬 술폰산 염 RSO3Na [R=C14 (64%), C15 (31%) 및 C16 (5%)임]의 혼합물 5 부로 이루어진 혼합물은 "TURBULA Mixer Type T10B"를 사용하여 제조된다.Of polyethylene terephthalate (fiber grade, Wellman PERMACLEAR Lot 61458) and 195 parts of primary and secondary sodium alkyl sulfonic acid salts RSO 3 Na [R = C14 (64%), C15 (31%) and C16 (5%)] A mixture of 5 parts of the mixture is prepared using "TURBULA Mixer Type T10B".

그 다음, "Coperion Corporation Werner" 및 "Pfleiderer ZSK 25 mm" 이중 스크루 압출기를 사용하여 혼합물을 용융 혼합한다. 압출기 가열 영역은 220∼230℃, 스크루 속도 300 rpm, 및 공급기 속도 40 lbs/시이다. 용융 중합체 및 첨가제는 4개의 오리피스 둥근 다이를 통해 배출된다. 용융 물질은 냉각수 통에서 즉시 냉각 및 고화된 다음, CONAIR/JETRO 304 펠릿화기로 공급된다. 펠릿은 BLUE M 강제 대류 오븐에서 16 시간 동안 100 ℃에서 예비 결정화되고, 펠릿을 체질한 다음, 100℃에서 16 시간 동안 진공 건조한다.The mixture is then melt mixed using a "Coperion Corporation Werner" and "Pfleiderer ZSK 25 mm" double screw extruder. The extruder heating zone is 220-230 ° C., screw speed 300 rpm, and feeder speed 40 lbs / hour. The molten polymer and additives are discharged through four orifice round dies. The molten material is immediately cooled and solidified in the coolant canister and then fed to the CONAIR / JETRO 304 pelletizer. The pellets are precrystallized at 100 ° C. for 16 hours in a BLUE M forced convection oven, sieved pellets and then vacuum dried at 100 ° C. for 16 hours.

부직 방사결합 섬유 샘플은 다음 조건 하에서 NORDSON FIBER SYSTEM/HILL INC. 2성분 방사결합 시스템 상의 2.5% 첨가제-PET 펠릿으로부터 제조된다: 압출 온도 290∼300℃; 스크린 변화기 온도 300℃; 스핀 헤드 온도 300℃; 559 구멍 스피너렛; 카렌다 압력 800 PSI, 상부 롤 온도 150℃, 하부 롤 온도 140℃. 수집 속도는 50 gm-2의 기본 중량을 갖는 부직물을 생성하도록 조절된다.Nonwoven spunbond fiber samples were prepared under NORDSON FIBER SYSTEM / HILL INC. Prepared from 2.5% additive-PET pellets on a bicomponent spin-bond system: extrusion temperature 290-300 ° C .; Screen changer temperature 300 ° C .; Spin head temperature 300 ° C .; 559 hole spinneret; Calendar pressure 800 PSI, upper roll temperature 150 ° C, lower roll temperature 140 ° C. The collection rate is adjusted to produce a nonwoven fabric having a basis weight of 50 gm −2 .

그 결과 얻어진 부직 샘플에 대해서, Lenzing Lister 1997 모델 장치 상에서 EDANA(European Disposables and Nonwovens Association) 150.4-99 표준 시험법에 따라, 액체 통과(strikethrough) 시간을 측정함으로써 투과성 및 내구성의 평가를 한다. 이는 일정 부피의 가상 오줌(9.0 g NaCl/리터)이 부직물을 통과하는 시간이다. 샘플에 대해 동일한 장치에서 연속적인 통과에 대해 평가한다.The resulting nonwoven samples are evaluated for permeability and durability by measuring the liquid through time according to the European Disposables and Nonwovens Association (EDANA) 150.4-99 standard test method on a Lenzing Lister 1997 model device. This is the time for a volume of virtual urine (9.0 g NaCl / liter) to pass through the nonwoven. Samples are evaluated for successive passes in the same device.

EDANA 액체 통과 시간: 시험법 150.4-99, 그 결과를 가혹한 조건에 대해 3회 측정한 것을 초로 나타낸다.EDANA Liquid Pass Time: Test Method 150.4-99, the results of which are measured three times for harsh conditions in seconds.

블랭크 Blank PETPET (첨가제 없음) (No additives) RSORSO 33 NaNa 첨가제 2.5%  Additive 2.5%

100 초 2.40 초    100 sec 2.40 sec

100 초 2.74 초    100 seconds 2.74 seconds

100 초 3.03 초    100 sec 3.03 sec

통과 데이타로부터, 첨가제-PET 조성물이 부직물 폴리에틸렌 테레프탈레이트 직물에 우수한 습윤성을 제공한다는 것을 나타낸다.Passing data indicate that the additive-PET composition provides excellent wettability to nonwoven polyethylene terephthalate fabrics.

EDANA 연속 통과 시험: 시험법 150.4-99, 그 결과를 가혹한 조건에 대해 3회 측정한 것을 초로 나타낸다. 통과 시간 최대 30 초, 동일한 부직 샘플 상에서 시험. 그 결과를 초로 나타낸다.EDANA Continuous Pass Test: Test Method 150.4-99, the results of which are measured three times against harsh conditions in seconds. Pass time up to 30 seconds, tested on the same nonwoven sample. The results are expressed in seconds.

블랭크 PET (첨가제 없음)Blank PET (no additives) 첨가제 2.5 %Additive 2.5% 통과 1Pass 1 >100, >100, >100> 100,> 100,> 100 2.40, 2.74, 3.032.40, 2.74, 3.03 통과 2Pass 2 >100, >100, >100> 100,> 100,> 100 3.04, 3.90, 3.623.04, 3.90, 3.62 통과 3Pass 3 >100, >100, >100> 100,> 100,> 100 3.03, 2.80, 3.093.03, 2.80, 3.09 통과 4Pass 4 >100, >100, >100> 100,> 100,> 100 3.31, 2.92, 2.933.31, 2.92, 2.93 통과 5Pass 5 >100, >100, >100> 100,> 100,> 100 3.00, 2.87, 2.753.00, 2.87, 2.75 통과 6Pass 6 >100, >100, >100> 100,> 100,> 100 2.74, 2.91, 2.602.74, 2.91, 2.60 통과 7Pass 7 >100, >100, >100> 100,> 100,> 100 3.60, 3.16, 3.203.60, 3.16, 3.20 통과 8Pass 8 >100, >100, >100> 100,> 100,> 100 2.64, 3.08, 2.592.64, 3.08, 2.59

연속 통과 시험 결과, 본 발명의 조성물은 단기간에 반복된 액체 통과 조건을 통과하는 데 효과적이라는 것이 증명된다. 이는 첨가제의 내구성을 입증하는 것이다.Continuous pass test results demonstrate that the compositions of the present invention are effective in passing repeated liquid pass conditions in a short time. This proves the durability of the additive.

Claims (13)

습윤성 폴리에스테르 직물을 포함하는 물품에 관한 것으로, 상기 직물은 섬유나 필라멘트를 포함하고, 상기 섬유나 필라멘트는 용융 블렌드를 포함하고,상기 용융 블렌드는 폴리에스테르 및 화학식 RSO3M의 알킬 금속 술포네이트 1 이상을 포함하고; 여기서 M은 Na, K 또는 Li이고, R은 직쇄 또는 측쇄 C12-C15 알킬이거나 또는 직쇄 또는 측쇄 C12-C18 알케닐이고, 상기 알킬 금속 술포네이트의 양은 폴리에스테르의 중량 기준으로 2∼5 중량%이며, 상기 섬유나 필라멘트는 후처리되며, 그리고 상기 용융 블렌드는 폴리옥시알킬렌 부가 화합물, 알킬모노에탄올아미드 부가 화합물, 알킬디에탄올아민 부가 화합물 및 폴리에테르아미드 부가 화합물로 이루어진 군으로부터 선택된 계면 활성 화합물을 함유하지 않는, 습윤성 폴리에스테르 직물을 포함하는 물품.An article comprising a wettable polyester fabric, the fabric comprising fibers or filaments, the fibers or filaments comprising a melt blend, wherein the melt blend is polyester and an alkyl metal sulfonate of formula RSO 3 M 1 Including the above; Wherein M is Na, K or Li, R is straight or branched C 12 -C 15 alkyl or straight or branched C 12 -C 18 alkenyl and the amount of alkyl metal sulfonate is from 2 to based on the weight of the polyester 5% by weight, the fibers or filaments are post-treated and the melt blend is selected from the group consisting of polyoxyalkylene addition compounds, alkylmonoethanolamide addition compounds, alkyldiethanolamine addition compounds and polyetheramide addition compounds An article comprising a wettable polyester fabric that does not contain a surfactant compound. 제 1항에 있어서, 폴리에스테르가 폴리(에틸렌 테레프탈레이트) 또는 폴리(에틸렌 2,6-나프탈렌-2,6-디카르복실레이트)인 물품.The article of claim 1 wherein the polyester is poly (ethylene terephthalate) or poly (ethylene 2,6-naphthalene-2,6-dicarboxylate). 제 1항에 있어서, 폴리에스테르가 폴리(에틸렌 테레프탈레이트)인 물품.The article of claim 1 wherein the polyester is poly (ethylene terephthalate). 제 1항에 있어서, 알킬 금속 술포네이트가 RSO3M이고, 여기서 R은 직쇄 또는 측쇄 C12-C15 알킬이거나 또는 직쇄 또는 측쇄 C12-C18 알케닐인 물품.The article of claim 1, wherein the alkyl metal sulfonate is RSO 3 M, wherein R is straight or branched C 12 -C 15 alkyl or straight or branched C 12 -C 18 alkenyl. 제 1항에 있어서, R이 직쇄 또는 측쇄 C12-C15 알킬이거나 또는 직쇄 또는 측쇄 C12-C18 알케닐인 물품.The article of claim 1, wherein R is straight or branched C 12 -C 15 alkyl or straight or branched C 12 -C 18 alkenyl. 제 1항에 있어서, R이 올레일인 물품.The article of claim 1, wherein R is oleyl. 제 1항에 있어서, 알킬 금속 술포네이트가 폴리에스테르의 중량 기준으로 약 2.5∼4.5 중량%의 양으로 존재하는 물품.The article of claim 1, wherein the alkyl metal sulfonate is present in an amount of about 2.5 to 4.5 weight percent based on the weight of the polyester. 제 1항에 있어서, 기저귀, 운동복, 여성 위생 제품, 요실금 보호 제품, 젖은 걸래, 마른 걸래, 권취된 드레싱, 수술 망토, 여과 메디알 및 배터리 분리기로 이루어진 군으로부터 선택되는 물품.The article of claim 1 selected from the group consisting of diapers, sportswear, feminine hygiene products, incontinence protection products, wet rags, dry rags, wound dressings, surgical cloaks, filtration media, and battery separators. 제 1항에 있어서, 종래의 안정화제 공통 첨가제를 더 포함하는 물품.The article of claim 1 further comprising a conventional stabilizer common additive. 1 이상의 습윤성 직물 층들로부터 물품을 형성하는 물품의 제조방법에 관한 것으로, 상기 직물 층이 폴리에스테르 및 화학식 RSO3M의 알킬 금속 술포네이트 1 이상을 포함하는 혼합물을 용융 압출하여 다수의 섬유나 필라멘트를 만든 후, 상기 섬유나 필라멘트를 냉각하는 공정에 의해 제조되고; 여기서 M이 Na, K 또는 Li이고, R이 직쇄 또는 측쇄 C12-C15 알킬이거나 또는 직쇄 또는 측쇄 C12-C18 알케닐이고, 상기 알킬 금속 술포네이트가 폴리에스테르의 중량 기준으로 2∼5 중량%의 양으로 존재하고, 상기 섬유나 필라멘트의 후처리 단계가 포함되지 않으며, 그리고 상기 혼합물이 폴리옥시알킬렌 부가 화합물, 알킬모노에탄올아미드 부가 화합물, 알킬디에탄올아민 부가 화합물 및 폴리에테르아미드 부가 화합물로 이루어진 군으로부터 선택된 계면 활성 화합물을 함유하지 않는, 물품의 제조방법.A method of making an article from which the article is formed from one or more wettable fabric layers, wherein the fabric layer melt-extrudes a mixture comprising polyester and at least one alkyl metal sulfonate of formula RSO 3 M to form a plurality of fibers or filaments. After making, by the process of cooling the fiber or filament; Wherein M is Na, K or Li, R is straight or branched C 12 -C 15 alkyl or straight or branched C 12 -C 18 alkenyl and the alkyl metal sulfonate is 2 to 5 by weight of the polyester Present in an amount by weight, does not include post-treatment of the fibers or filaments, and the mixture is a polyoxyalkylene addition compound, an alkylmonoethanolamide addition compound, an alkyldiethanolamine addition compound and a polyetheramide addition A method of making an article that does not contain a surfactant compound selected from the group consisting of compounds. 제 10항에 있어서, 제조 물품이 폴리에스테르 섬유 또는 필라멘트인 방법.The method of claim 10 wherein the article of manufacture is a polyester fiber or a filament. 제 10항에 있어서, 섬유나 필라멘트를 결합하여 부직 직물을 제조하는 단계를 더 포함하는 방법.The method of claim 10 further comprising the step of combining the fibers or filaments to produce a nonwoven fabric. 제 10항에 있어서, 1 이상의 알킬 금속 술포네이트 및 제1 폴리에스테르를 포함하는 마스터뱃치를 제조하는 단계, 상기 마스터뱃치 및 제2 폴리에스테르를 포함하는 혼합물을 용융 압출하여 다수의 섬유나 필라멘트를 제조하는 단계, 및 섬유나 필라멘트를 냉각하는 단계를 포함하는 방법.The method of claim 10, further comprising: preparing a masterbatch comprising at least one alkyl metal sulfonate and a first polyester, melt extruding the mixture comprising the masterbatch and the second polyester to produce a plurality of fibers or filaments. And cooling the fibers or filaments.
KR1020077000825A 2004-07-23 2005-07-13 Wettable Polyester Fibers and Fabrics KR20070035566A (en)

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