KR20070006048A - Functional aqueous adhesives - Google Patents

Functional aqueous adhesives Download PDF

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KR20070006048A
KR20070006048A KR1020050061032A KR20050061032A KR20070006048A KR 20070006048 A KR20070006048 A KR 20070006048A KR 1020050061032 A KR1020050061032 A KR 1020050061032A KR 20050061032 A KR20050061032 A KR 20050061032A KR 20070006048 A KR20070006048 A KR 20070006048A
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effect
water
adhesive
mixing
deodorizing
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Korean (ko)
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고상남
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고상남
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04Homopolymers or copolymers of esters
    • C09J133/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09J133/08Homopolymers or copolymers of acrylic acid esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J9/00Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

Provided is a functional aqueous adhesive for use in interior building materials or wallpapering materials, which has electron wave-shielding effect, deodorizing effect and anion-emitting effect. The functional aqueous adhesive comprises: 9.8% of a conventional aqueous adhesive prepared by mixing an acrylate resin, a surfactant and water; 0.2% of titanium oxide having electron wave-shielding effect; 82% of sodium silicate having deodorizing effect and electron wave-shielding effect; 3% of white carbon for maintaining a white color; and 5% of monazite used as a natural mineral substance for generating anions.

Description

기능성의 수용성 접착제{Functional aqueous adhesives}Functional aqueous adhesives

본 발명은 내장재, 초배지, 도배지, 벽지 등의 접착에 이용되는 다기능을 갖는 수용성 접착제에 관한 것으로, 좀 더 구체적으로는 특정의 기능성 성분을 혼합하여 전자파 차단효과와 탈취효과, 음이온 발생효과를 부여할 수 있도록 함으로써 품질의 고급화와 사용효과의 향상을 기할 수 있도록 한 것이다. The present invention relates to a water-soluble adhesive having a multi-function used for the adhesion of interior materials, super medium, paper, wallpaper, etc. More specifically, by mixing a specific functional component to give the electromagnetic wave blocking effect, deodorizing effect, anion generating effect In this way, the quality can be improved and the use effect can be improved.

통상적으로 음이온이란 공기 중에 음(-)의 전기를 띠고 있는 이온을 말하는데 순수한 공기가 안정된 상태에 있을 때 음이온과 양이온의 비율은 약 1 : 1.2인 것으로 알려져 있다. Generally, negative ions are negative ions in the air. When pure air is in a stable state, the ratio of anions and cations is about 1: 1.2.

하지만 인간 문명의 발달로 산업이 고도로 발달하면서 자연적인 환경에서 점점 멀어지고 있으며, 고도화된 산업화의 사회로의 변화는 합성 고분자, 시멘트, 전자파, 환경오염 등에 의하여 정상 상태의 이온 구성비가 파괴되어 양이온이 우세한 조건으로 변하며, 이렇게 되면 공기의 이온들은 브라운 운동에 의해 빠른 속도로 부딪혀서 생물학적으로 아무런 활성을 갖지 못하는 큰 입자 덩어리로 되며 이때의 큰 입자 덩어리로 된 이온 수는 현저히 감소하게 되며, 두통, 긴장 등을 더욱 악화시키게 된다.However, due to the development of human civilization, the industrial development is becoming more and more distant from the natural environment, and the change of the advanced industrialization society is due to the destruction of the ion composition ratio in the normal state by synthetic polymers, cement, electromagnetic waves, and environmental pollution. It changes to prevailing conditions, which causes air ions to collide at high speed by Brownian motion, resulting in large particle masses that have no biological activity, and greatly reduce the number of ions in the large particle masses. Will make it even worse.

보통 도시 생활자들은 약 200개/cc(max.)의 음이온을 마시는데 이 수치는 점점 감소하는 추세이다. 1000개/cc의 음이온을 마시면 뇌에서 α파의 활동을 증가 시키고 serotonin과 free histamine을 억제하여 긴장완화에 따른 건강에 도움을 준다. 음이온은 건강유지의 3가지 원칙인 혈액의 정화, 세포의 활성화, 신경의 조절 등을 조화 있게 유지시켜 전신의 기능을 원활하게 촉진시켜 준다. 음이온이 많은 숲 속이나 계곡, 폭포 주변에 오랫동안 있으면 기분이 상쾌해지고 싱그러움을 느끼며 몸의 컨디션도 좋아지는 것을 느낄 수 있다. 그래서 음이온을 '공기의 비타민'이라고 부르기도 한다.Normally, city dwellers drink about 200 anions / cc (max.) Of negative ions, which is decreasing. Drinking 1000 / cc negative ions increases the activity of α waves in the brain and inhibits serotonin and free histamine, which is beneficial to the health of relaxation. Negative ions promote the functioning of the whole body by keeping the three principles of health maintenance, such as blood purification, cell activation, and nerve regulation in harmony. If you stay in forests, valleys or waterfalls with a lot of negative ions for a long time, you can feel refreshed, refreshed, and feel better. Therefore, negative ions are also called 'air vitamins'.

이와 같은 음이온의 기능으로는 탈취, 방균, 탈습, 연수화작용(물), 공기청정 등을 들 수 있다. Functions of such anions include deodorization, antibacterial, dehumidification, softening (water), air cleaning, and the like.

한편 최근 컴퓨터와 전자레인지, 각종 사무기기 등이 널리 보급되면서 외부로 누출되는 전자파가 심각한 사회 문제를 일으킴에 따라 미연방통신위원회(F.C.C)등에서는 이에 대한 규제에 나섰으며, 근래에 와서는 그 규정이 더욱 강화되고 있는 추세인 바, 각 업계에서는 전자파를 효율적으로 차단할 수 있는 새로운 소재개발에 몰두하고 있는 실정이다.Meanwhile, as computers, microwave ovens, and various office equipment have become widespread, the leakage of external electromagnetic waves has caused serious social problems, and the Federal Communications Commission (FCC) has regulated them. As the trend is getting stronger, each industry is devoted to developing new materials that can effectively block electromagnetic waves.

또한 내장재, 초배지, 도배지, 벽지 등의 접착에 이용되는 기존의 수용성 접착제는 곡분이나 화학성 성분을 단독 또는 혼합한 형태의 접착제로서 도포 시 화학약품의 냄새가 발생하여 인체에 좋지 않은 영향을 미침과 동시에 사용에 거부감을 초래하였으며, 곡분으로 인해 습기의 발생 시 곰팡이의 발생을 유도하여 표면의 오염과 악취의 발생을 초래하는 등의 문제가 있었다. In addition, the existing water-soluble adhesives used for adhesion of interior materials, super medium, paper, wallpaper, etc. are adhesives in the form of single or mixed grains or chemical components, and when applied, they cause odors of chemicals and adversely affect the human body. It caused a rejection of the use, there was a problem such as induces the occurrence of mold when the moisture generated due to grains, contamination of the surface and the generation of odor.

또한 접착제의 조성물 자체가 접착 외에 별도의 기능성 효과를 발휘할 수 없는 것이어서 사용효과가 단순하고 획일적이며 부가가치가 낮고 건물이나 생활하면서 방출되는 유독성 물질의 흡수 제거가 불가능하고 각종 세균의 서식을 억제할 수 없어 제품의 사용효과와 신뢰성이 저하되었으며, 품질의 고급화를 추구할 수 없게 되는 문제가 있었던 것이다.In addition, the composition of the adhesive itself is not able to exert a separate functional effect other than adhesion, the use effect is simple, uniform, low added value, it is impossible to absorb and remove the toxic substances released during the building or life, and to suppress the growth of various bacteria The effectiveness and reliability of the product was degraded, and there was a problem that the quality of the product could not be pursued.

기존에도 화학물질 과민증, 시크하우스증후군(빌딩증후군)에 대응하기 위하여 기능성을 추가하기 위하여 전기석을 함유시킨 접착제가 일본공개특허 제1999-343473호, 일본공개특허 제2002-80800호. 한국공개특허 제2001-77173호에는 숯, 맥섬석, 옥, 맥반석 등의 음 이온성 무기물질이 함유시킨 음이온 접착제 및 그의 제조방법이 공개되어 있다.Conventionally, adhesives containing tourmaline to add functionality to cope with chemical hypersensitivity and seek house syndrome (building syndrome) are disclosed in Japanese Patent Laid-Open No. 1999-343473 and Japanese Patent Laid-Open No. 2002-80800. Korean Laid-Open Patent Publication No. 2001-77173 discloses an anionic adhesive contained in anionic inorganic materials such as charcoal, macsumite, jade, and macbanrite, and a method of manufacturing the same.

하지만 상기 접착제는 전기석 자체만으로는 음이온의 발생이 충분하지 않고 전자파 차단이나 탈취효과 등을 발휘할 수 없으며, 숯이나 맥반석 등 첨가 성분의 고유 색상으로 인해 접착제의 색상이 회색이나 검은 색을 띄게 되어 도배용 접착제로 사용되는 경우 도배지의 고유색상을 변질시켜 미관을 저해시킴으로써 사용에 적합지 않게 되는 문제가 있었다.However, the adhesive is not enough to generate negative ions by the tourmaline itself, and cannot exhibit electromagnetic wave blocking or deodorizing effects. The color of the adhesive is gray or black due to the intrinsic color of additives such as charcoal or elvan. When used as, there was a problem that it is not suitable for use by inhibiting the aesthetics by altering the intrinsic color of the paper.

본 발명은 상기와 같은 제반 문제점을 해결하기 위한 것으로The present invention is to solve the above problems

본 발명의 목적은 전자파 차단효과와 탈취효과 및 음이온 발생효과를 부여할 수 있도록 함으로써 품질의 고급화와 사용효과의 향상을 기할 수 있는 접착제를 제공함에 그 목적이 있는 것이며, An object of the present invention is to provide an adhesive capable of improving the quality and the improvement of the use effect by providing an electromagnetic wave blocking effect, deodorizing effect and anion generating effect,

상기와 같은 목적을 달성하기 위하여 본 발명은 아크릴산 에스테르수지와 계면활성제 및 적정량의 물을 혼합하여 구성되는 공지의 접착제에 전자파를 차단하고 탈취효과를 갖는 티타늄옥사이드와 규산염소다 그리고 음이온을 발생할 수 있는 천연의 모네자이트 및 접착제의 색상을 백색으로 유지시키기 위한 백색카본을 적정량 혼합하여 수용성 접착제를 제조하는 것을 특징으로 하는 것이다. In order to achieve the above object, the present invention is a natural adhesive which blocks the electromagnetic waves and has a deodorizing effect of titanium oxide, sodium silicate, and anion, which are formed by mixing acrylic ester resin, a surfactant, and an appropriate amount of water. To prepare a water-soluble adhesive by mixing a proper amount of white carbon to maintain the color of the monetite and the adhesive of white.

상기와 같은 목적을 달성하기 위한 본 발명은;The present invention for achieving the above object;

아크릴산 에스테르수지와 계면활성제 및 물을 혼합하여 제조되는 공지의 수용성 접착제:9.8%에 전자파를 차단하는 기능을 하는 티타늄옥사이드:0.2% 탈취기능과 전자판 차단기능을 갖는 규산염소다:82% 그리고 접착제의 색상을 백색으로 유지시키기 위한 백색카본: 3% 그리고 음이온을 발생시키기 위한 천연 광물인 모네자이트:5%를 혼합하여 전자파 차단과 탈취효과 음이온 발생기능을 갖는 수용성 접착제를 제조하였다.Known water-soluble adhesive made by mixing acrylic ester resin with surfactant and water: Titanium oxide with a function of blocking the electromagnetic waves in 9.8%: 0.2% Sodium silicate with deodorizing function and electromagnetic shielding function: 82% A water-soluble adhesive having an electromagnetic wave blocking and deodorizing effect anion generating function was prepared by mixing white carbon: 3% to maintain color as white and monesite: 5% as a natural mineral to generate anions.

이하, 본 발명의 구체적인 작용을 설명하면 다음과 같다.Hereinafter, the specific operation of the present invention will be described.

상기와 같이 제조된 수용성 접착제는 전자파를 차단할 수 있는 물질인 티타늄옥사이드와 규산염소다를 첨가함으로서 일반 가정 및 사업장 등지에서 사용하는 전기/전자제품이나 기기 등지에서 발생하는 전자파 중 자기장 성분을 흡수하여 조성된 전자파의 노출환경으로부터 전자파를 차단하여 전자파 비노출환경으로 이루어 질 수 있도록 해주며, The water-soluble adhesive prepared as described above is formed by absorbing the magnetic field component of the electromagnetic wave generated in the electrical / electronic products or devices used in homes and businesses, etc. by adding titanium oxide and sodium silicate, which can block the electromagnetic waves. It shields the electromagnetic waves from the exposure environment of the electromagnetic waves, so that the electromagnetic waves can be exposed to the non-exposure environment.

규산염소다의 주 기능인 탈취기능으로 인하여 접착 부위나 접착제 자체에서 발생될 수 있는 제반 악취와 냄새를 제거하여 실내 공기의 오염을 방지하여 쾌적한 상태를 유지할 수 있게 된다.Due to the deodorizing function, which is the main function of sodium silicate, it is possible to remove the odors and odors that may be generated at the adhesive site or the adhesive itself, thereby preventing the contamination of indoor air and maintaining a pleasant state.

한편 음이온 발생 물질인 천연의 모나자이드를 첨가함으로써 탈취, 방균, 탈습, 연수화작용(물), 공기청정 등의 다양한 기능을 발휘하게 된다.On the other hand, by adding natural monazide, an anion generating material, it exhibits various functions such as deodorization, antibacterial, dehumidification, water softening (water), and air cleaning.

그리고 백색카본을 첨가함으로써 접착제의 색상을 백색으로 유지할 수 있게 됨으로써 도배용 접착제로 사용되는 경우 밝은 색상이 주류를 이루는 도배지의 고유색상을 변질시키지 않게 되어 폭넓은 활용도를 유지할 수 있게 된다.By adding white carbon, the color of the adhesive can be maintained as white, so that when used as a paper-based adhesive, bright colors do not alter the intrinsic color of the paper, which forms the mainstream, thereby maintaining a wide range of applications.

본 발명은 상기에서 수용성의 도배용 접착제를 기초로 설명하였지만 이에 한정되지 않고 다른 용도의 접착제 즉 문방구용 풀이나 점착제, 공업용 접착제 등에도 상기 기능성 물질을 혼합시켜 전자파를 차단하고 탈취효과와 음이온을 발생할 수 있는 접착제를 구성할 수 있음은 물론이다.Although the present invention has been described above based on a water-soluble papering adhesive, the present invention is not limited thereto, but the above-mentioned functional materials may also be mixed with adhesives of other uses, such as stationery glue, adhesives, industrial adhesives, etc. to block electromagnetic waves and generate deodorizing effects and anions. Of course, the adhesive can be configured.

이상에서는, 본 발명의 실시 예를 설명하였지만, 본 발명이 속하는 기술 분야에서 통상의 지식을 가진 자가 본 발명의 기술적 사상을 벗어나지 않는 범위 내에서 변경 및 변형한 것도 본 발명의 권리범위에 속함은 당연하다.In the above, the embodiments of the present invention have been described, but it is obvious that those skilled in the art belong to the scope of the present invention changes and modifications without departing from the technical spirit of the present invention. Do.

이상과 같은 본 발명은 공지의 접착제에 전자파 차단효과와 탈취효과 및 음이온 발생효과를 부여할 수 있는 기능성 물질들을 혼합함으로써 품질의 고급화와 사용효과의 향상을 기할 수 있는 효과를 추구할 수 있게 된다. The present invention as described above can achieve the effect of improving the quality and the improvement of the use effect by mixing functional materials that can impart the electromagnetic wave blocking effect, deodorizing effect and anion generating effect to the known adhesive.

Claims (1)

아크릴산 에스테르수지와 계면활성제 및 물을 혼합하여 제조되는 공지의 수용성 접착제:9.8%와;Known water-soluble adhesive prepared by mixing acrylic acid ester resin with surfactant and water: 9.8%; 전자파를 차단하는 기능을 하는 티타늄옥사이드:0.2%와;Titanium oxide having a function of blocking electromagnetic waves: 0.2%; 탈취기능과 전자판 차단기능을 갖는 규산염소다:82%와;Sodium silicate having a deodorizing function and an electron blocking function: 82%; 접착제의 색상을 백색으로 유지시키기 위한 백색 카본:3%와;3% white carbon to keep the color of the adhesive white; 음이온을 발생시키기 위한 천연 광물인 모네자이트:5%를 각각 혼합하여 구성함을 특징으로 하는 기능성의 수용성 접착제.A functional water-soluble adhesive, characterized by mixing each of the natural mineral monetite: 5% for generating anions.
KR1020050061032A 2005-07-07 2005-07-07 Functional aqueous adhesives KR20070006048A (en)

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