KR20060117005A - Concrete substitute of new material using a natual soil and producing method thereof - Google Patents
Concrete substitute of new material using a natual soil and producing method thereof Download PDFInfo
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- KR20060117005A KR20060117005A KR1020050039698A KR20050039698A KR20060117005A KR 20060117005 A KR20060117005 A KR 20060117005A KR 1020050039698 A KR1020050039698 A KR 1020050039698A KR 20050039698 A KR20050039698 A KR 20050039698A KR 20060117005 A KR20060117005 A KR 20060117005A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/10—Clay
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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Abstract
Description
도 1은 본 발명에 따라 제조된 신소재 콘크리트의 사진이다.1 is a photograph of a new material concrete produced according to the present invention.
본 발명은 자연흙을 이용한 친환경 신소재 콘크리트 및 그 제조방법에 관한 것으로, 보다 자세하게는 일정 사이즈 이하의 통상적인 자연 상태의 흙과 접착제 및 계면활성제와 일정비율로 혼합하여 접착성, 응결 속도 및 압축강도가 우수한 자연친화적인 경량 콘크리트의 제조방법에 관한 것이다.The present invention relates to a new environment-friendly concrete material using natural soil, and a method for manufacturing the same, and more specifically, the adhesiveness, the setting speed and the compressive strength by mixing in a certain ratio with the soil and the adhesive and the surfactant in a normal natural state of a certain size or less The present invention relates to a method for producing excellent natural friendly lightweight concrete.
일반적으로, 건설용 콘크리트의 대표적인 주접착제는 세멘트(CEMENT)와 아스팔트(AP)를 들 수 있으며, 이들을 모래 및 자갈과 일정 비율로 혼합된 것을 시멘트 콘크리트 및 아스팔트 콘크리트라 칭하며, 토목ㆍ건축용 콘크리트로 제조ㆍ생산되고 시공되고 있다.In general, the main adhesives for construction concrete include cement and asphalt (AP), and these mixed with sand and gravel in a certain ratio are called cement concrete and asphalt concrete, and manufactured from civil and building concrete. ㆍ It is produced and constructed.
상기와 같이 통상적으로 사용되는 이들 콘크리트에 공통적으로 사용되는 재료는 1차 가공된 모래와 자갈이 대부분인 골재로써 모래 이하의 흙, 점토질 및 실트질 성분은 콘크리트 내구성, 내화학성 등을 저해시키는 주요 요인이 되어 구조물의 중요 부위에는 거의 사용되지 못하고 있는 실정이다.The materials commonly used for these concretes, which are commonly used as described above, are aggregates mainly composed of sand and gravel that are primarily processed. Soil, clay, and silt components below sand are major factors that impair concrete durability and chemical resistance. As a result, it is rarely used in important areas of the structure.
더욱이, 세계 건설시장에서 시멘트와 아스팔트를 이용한 콘크리트는 아주 오랫동안 제조ㆍ생산되어 사용되어 왔지만, 상온에서 흙을 이용한 친환경적인 콘크리트는 아직 연구 개발 단계를 벗어나지 못하고 있는 실정이며, 특히 구조용으로서 흙 콘크리트를 실용화하기 위해선 보다 많은 연구 개발이 더 진행되어야 할 것으로 생각한다.Moreover, although concrete using cement and asphalt has been manufactured and produced for a long time in the global construction market, eco-friendly concrete using soil at room temperature has not yet escaped from the R & D stage. In order to do that, more research and development will be needed.
또한, 상기한 종래의 콘크리트의 주접착제인 시멘트와 아스팔트는 제조설비 및 생산과정이 매우 복잡할 뿐 아니라, 많은 시간을 요구하며, 또한 건설 개발로 인해 발생하는 폐콘크리트로 인한 환경파괴 영향은 산술적으로 평가하기가 어려울 만큼 큰 폐해를 가져오고 있다.In addition, cement and asphalt, which are the main adhesives of the conventional concrete, are not only complicated in manufacturing facilities and production processes, but also require a lot of time, and also have an arithmetic effect on environmental destruction due to waste concrete generated by construction development. The damage is so great that it is difficult to evaluate.
따라서 본 발명자는 상기와 같은 종래의 콘크리트에 있어서의 문제점을 감안하여 일반 시멘트 콘크리트가 지니고 있는 소요 강도를 유지하면서도, 친환경적인 흙을 콘크리트의 주성분으로 이용할 수 있는 방법에 대해 예의 연구한 결과 본 발명을 완성하게 되었다.Accordingly, the present inventors have made a thorough study on the method of using environmentally friendly soil as the main component of concrete while maintaining the required strength of general cement concrete in view of the problems in the conventional concrete as described above. It was completed.
따라서, 본 발명은 친환경적인 흙을 콘크리트의 주성분으로 하면서도, 종래의 일반 시멘트 콘크리트가 지니고 있는 소정의 압축강도를 유지하고 응결속도가 빠른 새로운 환경친화적인 경량의 신소재 콘크리트의 제조방법을 제공하기 위한 것이다.Accordingly, the present invention is to provide a new environmentally friendly lightweight new material concrete manufacturing method that maintains the predetermined compressive strength of the conventional cement concrete, while the environmentally friendly soil as the main component of the concrete, and fasten the setting speed .
상기 본 발명의 목적을 달성하기 위한 자연흙을 이용한 경량의 신소재 콘크리트의 제조방법은;Method for producing a lightweight new material concrete using natural soil for achieving the object of the present invention;
접착성과 결합성이 우수한 폴리비닐 아세테이트(Polyvinyl acetate; PVAC), 통상의 자연흙, 물 및 계면활성제를 일정 비율로 혼합하여 상온에서 경화하여 구성됨을 특징으로 한다.Polyvinyl acetate (PVAC), excellent adhesion and bonding properties, characterized in that it is configured by curing at room temperature by mixing a certain ratio of natural natural soil, water and surfactant.
본 발명의 다른 구성에 따르면, 상기 폴리비닐 아세테이트(Polyvinyl acetate; PVAC), 통상의 자연흙, 물 및 계면활성제의 비율은 중량비로 5 내지 30 : 70 내지 95 : 10 내지 20 : 0.5 내지 5로 됨을 특징으로 한다.According to another configuration of the invention, the ratio of the polyvinyl acetate (PVAC), conventional natural soil, water and surfactant is 5 to 30: 70 to 95: 10 to 20: 0.5 to 5 by weight. It features.
상기 본 발명에 따른 조성비율에 있어서, 폴리비닐 아세테이트의 비율이 5중량부 이하로 되면 콘크리트의 접합력이 떨어져 바람직하지 않고, 10중량부 이상이 되면 접착강도나 응결속도는 빠르지만 경제성 측면이나 환경적인 측면에서 바람직하지 않다. In the composition ratio according to the present invention, when the ratio of polyvinyl acetate is 5 parts by weight or less, the bonding strength of the concrete is not preferable, and when more than 10 parts by weight, the adhesive strength and the setting speed is fast, but economical and environmental Not preferable in terms of.
본 발명의 다른 구성에 따르면, 상기 본 발명에 따른 자연흙은 바람직하기로는 황토, 마사토를 포함한 점토질, 실트질, 모래, 자갈 등이다.According to another configuration of the present invention, the natural soil according to the present invention is preferably clay, including silt, masato, silt, sand, gravel and the like.
또한, 본 발명에서 사용될 수 있는 계면활성제는 특정한 것에 한정되지 않으며, 상업적으로 시판되어 용이하게 이용할 수 있는 PKW2005를 사용할 수 있다.In addition, the surfactant that may be used in the present invention is not limited to a specific one, and PKW2005, which is commercially available and easily available, may be used.
또한, 본 발명에 따른 상기 재료의 혼합은 상온에서 혼합하여 콘크리트를 제조할 수 있다.In addition, the mixing of the material according to the present invention can be prepared at room temperature by mixing concrete.
이하, 상기한 바와 같은 본 발명에 따라 사용되는 재료의 특성을 설명하면 다음과 같다.Hereinafter, the characteristics of the material used according to the present invention as described above are as follows.
(1)폴리비닐 아세테이트(POLYVINYL ACETATE)(1) POLYVINYL ACETATE
본 발명에 따른 친환경 콘크리트를 제조하기 위해서 일 구성성분으로 사용되어 접착제 역활을 하는 폴리비닐 아세테이트는 접착성과 결합성이 좋은 수지계 접착제이다.Polyvinyl acetate, which is used as one component to prepare an eco-friendly concrete according to the present invention and serves as an adhesive, is a resin adhesive having good adhesiveness and bonding property.
또한, 상기 본 발명의 일 구성성분인 폴리비닐 아세테이트는 자연흙 고유의 미를 유지할 수 있는 투명성, 응결ㆍ경화성 및 부착성이 우수하여, 종래의 시멘트를 사용한 콘크리트와 본 발명의 PVAC를 사용한 콘크리트를 비교하여 그 물리적 성질을 다음 표 1에 나타냈다.In addition, the polyvinyl acetate as one component of the present invention is excellent in transparency, condensation, hardenability and adhesion to maintain the beauty of natural soil inherent, and the conventional concrete and concrete using the PVAC of the present invention In comparison, the physical properties are shown in Table 1 below.
(2)자연흙(2) natural soil
상기 본 발명에 따라 사용된 자연흙은 마사토, 황토를 포함한 점토질, 실트질 및 모래, 자갈 등으로 본 발명에 따른 친환경 콘크리트의 경우 종래의 시멘트 콘크리트 및 아스팔트 콘크리트에서 사용하지 않았던 흙을 주재료로 사용하는 것으로 건설 현장 어디에서든 쉽게 구할 수 있는 양질의 자연흙을 대표적인 시료로 적용하여 사용할 수 있다.The natural soil used in accordance with the present invention is masato, clay including clay, silt and sand, gravel, etc. In the case of eco-friendly concrete according to the present invention using the soil which was not used in conventional cement concrete and asphalt concrete as the main material It can be used as a representative sample of high quality natural soil which can be easily obtained anywhere in the construction site.
하기의 본 발명에 따른 실시예에서 사용된 자연흙은 경기도 여주군 능서면 백석리 토취장의 흙을 사용하였으며, 사용 전 표토 제거 후 깨끗한 토층에서 채굴한 흙을 40mm 스크린으로 걸러 간단히 불순물을 제거 후 사용하였다.The natural soil used in the examples according to the present invention used was the soil of Baekseok-ri, Seokri-ri, Yeongju-myeon, Yeoju-gun, Gyeonggi-do, and after removing the topsoil, the soil mined from a clean soil layer was filtered and then used to simply remove impurities.
상기 자연흙의 물리적 특성시험의 결과는 다음 표 2와 같다.The results of the physical properties of the natural soil are shown in Table 2 below.
*산지:경기도 여주군 능서면 백석리 토취장 * Country of origin: Baekseok-ri, Neungseo-myeon, Yeoju-gun, Gyeonggi-do
상기와 같이 구성되는 본 발명은 통상의 자연흙을 주재로 사용함으로 흙의 자연미를 유지할 뿐 아니라, 폴리비닐 아세테이트와 자연흙을 일정 비율로 혼합하여 사용함으로 제조된 콘크리트의 내구성, 내화성, 내화학성, 경제성 및 시공성 등을 만족시키는 친환경 소재의 콘크리트로, 통상적인 토목ㆍ건축용 내ㆍ외 장식재, 벽돌, 각종 블록, 타일, 대ㆍ소구조물, 다이크, 방호벽, 포장용 콘크리트 및 보수ㆍ보강재외 기타 다양한 용도로 사용될 수 있다.The present invention constituted as described above is not only to maintain the natural beauty of the soil by using a normal natural soil as a main material, but also durable, fire resistance, chemical resistance, It is eco-friendly concrete that satisfies the economic feasibility and constructability.It is used for interior and exterior decoration materials, bricks, various blocks, tiles, large and small structures, dikes, firewalls, paving concrete, repair and reinforcement materials, etc. Can be used.
이하, 본 발명을 실시예에 의해 보다 자세히 설명하지만, 본 발명의 범위에 여기에 한정되는 것이 아님은 물론이다. Hereinafter, although an Example demonstrates this invention in detail, of course, it is not limited to the scope of the present invention.
실시예 1Example 1
본 발명에 따른 친환경 콘크리트를 다음 표 3에 나타난 특성을 갖는 각 조성을 표 3의 조성비로 하여 다음과 같이 제조하였다.Eco-friendly concrete according to the present invention was prepared as follows by each composition having the characteristics shown in Table 3 as the composition ratio of Table 3.
상기 표 3과 같은 배합비로 각 재료를 배합ㆍ믹싱하는 방법은 먼저 믹서기에 계량된 흙을 투입한다.In the method of compounding and mixing the ingredients at the mixing ratios as shown in Table 3, first, the weighed soil is put into the blender.
그 다음 준비된 물통에 계량된 물을 채우고 폴리비닐 아세테이트와 계면활성제가 혼합된 PP(mixed by polyvinyl acetate and PKW2005)를 준비된 물통속에 넣어 약30초간 희석ㆍ혼합하였다.Then, the water tank was filled with the metered water, and mixed with polyvinyl acetate and PKW2005 (PP) mixed with polyvinyl acetate and a surfactant were put in the water tank and diluted and mixed for about 30 seconds.
물통속에서 충분히 희석ㆍ혼합된 물을 최종적으로 흙과 함께 3분간 믹서기 내에서 균일한 콘크리트가 될 때까지 혼합하여 콘크리트를 제조하였다. Water was sufficiently diluted and mixed in the water bottle was finally mixed with the soil for 3 minutes in a mixer until a uniform concrete to prepare a concrete.
실시예 2Example 2
본 발명에 따른 조성비를 다음 표 4와 같이 하는 외에는 상기 실시예 1과 동일하게 하여 콘크리트를 제조하였다.Concrete was prepared in the same manner as in Example 1 except that the composition ratio according to the present invention is as shown in Table 4 below.
실시예 3Example 3
본 발명에 따른 조성비를 다음 표 5와 같이 하는 외에는 상기 실시예 1과 동일하게 하여 콘크리트를 제조하였다.Concrete was prepared in the same manner as in Example 1 except that the composition ratio according to the present invention is as shown in Table 5 below.
실험예Experimental Example
상기 각 실시예에 따라 제조된 친환경 콘크리트의 생콘크리트를 KSF2406에 따라 10*20㎝몰드를 사용하여 콘크리트 압축강도 시험용 공시체를 제작하고 수분증발을 막아 24시간 후에 탈형하여 수중양생을 한 다음 압축강도를 시험하여 그 결과를 다음 표 6에 나타냈다.The raw concrete of eco-friendly concrete manufactured according to the above examples was prepared using a 10 * 20 cm mold according to KSF2406 to prepare a test specimen for concrete compressive strength, and prevented water evaporation to demould after 24 hours to cure in water and then to compressive strength. The test results are shown in Table 6 below.
상기 실시예 및 실험예에서 알 수 있는 바와 같이 본 발명에 따라 PVAC, 자연흙(마사토, 황토를 포함한 점토질, 실트질, 모래, 자갈 등), 물 및 계면활성제(PKW2005)를 일정비율로 상온에서 혼합ㆍ사용하여 얻은 콘크리트는 양호한 압축강도를 나타냄을 알 수 있다.As can be seen in the above examples and experimental examples, according to the present invention, PVAC, natural soil (mass clay, clay including clay, silt, sand, gravel, etc.), water and surfactant (PKW2005) at a constant ratio at room temperature. Concrete obtained by mixing and using shows good compressive strength.
또한, 본 발명에서는 사용되는 자연흙을 특별히 흙속에 섞여있는 자갈 덩이를 골라내지 않아도 되며, 단지 40mm 스크린으로만 걸러 통과하는 재료를 사용할 수 있으므로 시공 절차가 간단하고 경제적이다.In addition, in the present invention, it is not necessary to pick out a gravel lump in which the natural soil used is specifically mixed in the soil, and the construction procedure is simple and economical because only a 40 mm screen can be used to pass through the material.
상기의 실시예에서 알 수 있는 바와 같이 본 발명에서 주재료로 사용되는 마사토, 황토를 포함한 점토질, 실트질, 모래, 자갈 등으로 구성된 자연흙은 재료를 구하기도 간단하며, 특별한 가공ㆍ생산 절차를 거치지 않고 일반 건설 현장 주변에서 손쉽게 채취가 용이하고, 사용하기가 편리하면서도, 구조물에 사용할 수 있는 소요 압축강도를 얻는데 필요한 시험결과 현재 시공되고 있는 일반 구조물의 소요 압축강도(210 ~ 240㎏/㎠)이상의 강도를 만족하고 있음을 알 수 있다. 또한, 현장 특성상 구조물에 따라 요구하는 소요 압축강도가 특히 높은 경우에는 필요에 따라 자연흙에 배합되는 PP의 배합비 조정함으로 특정의 강도를 갖는 콘크리트를 창출할 수 있어, 경제성, 내구성, 시공성을 만족하는 친환경 신소재의 콘크리트를 제조하여 현장에 시공할 수 있게 한다. As can be seen in the above embodiment, natural soil composed of masato, clay including clay, silt, sand, gravel, etc. used as the main material in the present invention is easy to obtain the material, and does not undergo special processing and production procedures. It is easy to collect around the general construction site, and it is convenient to use, but the test result necessary to obtain the required compressive strength to be used for the structure is greater than the required compressive strength (210 ~ 240㎏ / ㎠) of the general structure currently being constructed. It can be seen that the strength is satisfied. In addition, if the required compressive strength required by the structure is particularly high due to the characteristics of the site, concrete having a specific strength can be created by adjusting the mixing ratio of PP blended with natural soil as needed, which satisfies economic efficiency, durability, and workability. It is possible to manufacture concrete of eco-friendly new material and construct it on site.
또한, 도 1은 본 발명에 따라 제조되어 경화된 콘크리트의 사진으로, 본 도면에서 알 수 있는 바와 같이 일반적인 자연흙을 주재료로 사용함으로 시공된 면에 흙의 자연미를 유지할 수 있다. In addition, Figure 1 is a picture of the concrete is made and cured according to the present invention, as can be seen in this figure can maintain the natural beauty of the soil on the surface constructed by using the general natural soil as the main material.
특히, 본 발명에 따른 자연흙을 이용한 친환경 신소재 콘크리트는 상기 표 1에 나타난 바와 같이 압축강도가 350kg/cm2 수준을 유지하는데 7일의 단기간에서 90% 이상의 강도를 유지할 수 있으며, 균열이 없음이 확인되었다(도 1참고). 또한, 종래의 세멘트 콘크리트의 비중이 3.15인데 반하여 본 발명의 신소재 콘크리트의 비중은 1.2로서 경량임을 알 수 있으며 더욱이 건설 공사 전후에 폐기물로서도 재활용할 수 있다는 큰이점이 있다.In particular, the new eco-friendly concrete material using natural soil according to the present invention can maintain a strength of more than 90% in a short period of 7 days to maintain the compressive strength 350kg / cm 2 level, as shown in Table 1, there is no crack It was confirmed (see Fig. 1). In addition, while the specific gravity of the conventional cement concrete is 3.15, it can be seen that the specific gravity of the new material concrete of the present invention is lightweight as 1.2, and furthermore, it can be recycled as waste before and after construction work.
상기와 같이 구성되는 본 발명의 자연흙을 이용한 콘크리트의 제조방법은 통상의 자연흙을 주재료로 사용함으로 흙의 자연미를 유지할 뿐 아니라, 폴리비닐 아세테이트와 자연흙을 일정 비율로 혼합하여 사용함으로 제조된 친환경 콘크리트의 내구성, 내화성, 내화학성, 경제성, 시공성 및 친환경성, 경량성 등을 모두 만족시키는 친환경 신소재 소재의 콘크리트로, 통상적인 토목ㆍ건축용 내ㆍ외 장식재, 벽돌, 각종 블록, 타일, 대ㆍ소구조물, 다이크, 방호벽, 포장용 콘크리트 및 보수ㆍ보강재외 기타 다양한 용도로 종래의 세멘트 콘크리트 대신 사용될 수 있는 유용한 발명이다.The production method of concrete using natural soil of the present invention configured as described above is prepared by using a mixture of polyvinyl acetate and natural soil as well as maintaining natural beauty of the soil by using ordinary natural soil as a main material. Eco-friendly concrete material that satisfies the durability, fire resistance, chemical resistance, economical efficiency, workability, eco-friendliness, and light weight of eco-friendly concrete. It is a useful invention that can be used in place of conventional cement concrete for various structures such as small structures, dykes, barriers, paving concrete, and repair and reinforcement materials.
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