KR20060112746A - Cap assembly and lithium ion secondary battery with the same - Google Patents

Abstract

Provided are a cap assembly which allows the gas of inside to be discharged by internal pressure or temperature increase by separating a stopper for finishing a safety vent hole and improves the safety and reliance of a battery, and a lithium ion secondary battery using the cap assembly. The cap assembly comprises a cap assembly provided with a cap plate(310) here at least safety vent hole(380), wherein the safety vent hole is combined with a stopper(390). The stopper is located at the stopper upper part and is fixed by a solder(400) molten at a certain temperature. Preferably the solder has a melting point of 90-110 deg.C, and is an alloy of tin, zinc and bismuth or an alloy of tin, lead and bismuth. Preferably the stopper is made of a metal foil such as aluminum or aluminum alloy or a soft resin.

Description

Cap assembly and Lithium-ion secondary battery having the same {Cap Assembly and Lithium Ion Secondary Battery with the same}

1A and 1B illustrate a conventional cap assembly.

2 is a cross-sectional view of a lithium ion secondary battery according to a first embodiment of the present invention.

3 is an enlarged view showing an area of FIG. 2 according to the present invention;

Figure 4 is an enlarged cross-sectional view showing a safety vent area according to a second embodiment of the present invention.

5 is an enlarged cross-sectional view of a safety vent area according to a third exemplary embodiment of the present invention.

Figure 6 is an enlarged cross-sectional view showing a safety vent area according to a fourth embodiment of the present invention.

<Brief description of symbols for the main parts of the drawings>

Lithium-ion rechargeable battery 31 Case

32. Electrode assembly 34 ... First electrode plate

35 ... Separator 36 ... Second electrode plate

37 ... first electrode tab 38 ... second electrode tab

300. Cap assembly 310 ... Cap plate

311 ... Terminal through hole 312 ... Electrolyte inlet

320 ... electrode terminal 380 ... safety vent hole

390, 390a, 390b, 390c ... plug 400 ... solder

410 ... notch

The present invention relates to a cap assembly and a lithium ion secondary battery having the same, and to a cap assembly and a lithium ion secondary battery including the improved reliability and safety operating in response to temperature.

In general, a secondary battery refers to a battery that can be charged and discharged and has a small size and a large capacity, unlike a primary battery that cannot be charged. Typically, a secondary battery is a nickel-cadmium (Ni-Cd) battery and a nickel hydrogen (Ni-MH) battery. Batteries, lithium (Li) batteries and lithium ion (Li-ion) batteries are used. Recently developed lithium ion secondary batteries are widely used in the field of advanced electronic devices such as cellular phones, notebook computers.

In particular, the lithium ion secondary battery has an operating voltage of 3.6 V, which is three times higher than that of a nickel-cadmium battery or a nickel-hydrogen battery, which is widely used as a power source for portable electronic equipment, and is rapidly expanding in terms of high energy density per unit weight. It is a trend.

Such lithium ion secondary batteries use lithium-based oxides as positive electrode active materials and carbon materials as negative electrode active materials. Lithium ion secondary batteries are classified into a liquid electrolyte battery and a polymer electrolyte battery according to the type of electrolyte. A battery using a liquid electrolyte is called a lithium ion battery, and a battery using a polymer electrolyte is called a lithium polymer battery. Moreover, although a lithium secondary battery is manufactured in various shapes, typical shapes include cylindrical shape, square shape, and pouch type.

The lithium ion secondary battery is positioned between the positive electrode plate coated with a positive electrode active material, the negative electrode plate coated with a negative electrode active material, and between the positive electrode plate and the negative electrode plate to prevent a short and to move only lithium ions (Li-ion). The separator is formed of an electrode assembly which is wound up, a lithium ion secondary battery case accommodating the electrode assembly, and an electrolyte solution injected into the case to allow lithium ions to move.

The lithium ion secondary battery is coated with the positive electrode active material and the positive electrode tab is connected to the positive electrode tab, the negative electrode active material is coated and the negative electrode tab is connected to the negative electrode plate and the separator is wound to manufacture an electrode assembly. The electrode assembly is accommodated in the case for the lithium secondary battery, and the cap assembly is assembled on the top of the case for the lithium secondary battery to prevent separation of the electrode assembly. The electrolyte is injected into and sealed in the case for the lithium ion secondary battery assembled with the cap assembly to complete the battery.

In general, when the battery is normally charged, reactions such as melting of an organic solvent, pyrolysis of the SEI film of the negative electrode, reaction of the negative electrode active material and the electrolyte, reaction of the oxygen and the electrolyte decomposed in the positive electrode active material, and decomposition of lithium are sequentially performed. Occurs. However, when the battery is overcharged, the above reactions proceed simultaneously to exothermic reactions, which causes the battery to expand and become unstable at the same time due to the ejected gas. The generation of gas continues until the battery ruptures, so the gas must be released outside the cell at a predetermined pressure for the safety of the battery.

Safety measures against such a phenomenon include a built-in positive temperature coefficient thermistor, a separator with a shutdown function, and a safety vent operated by gas generation. The safety vent generally refers to a thin region formed in the cap assembly. When the battery is swelled due to gas generation, the safety vent is broken to discharge gas to maintain safety of the battery.

1A and 1B show a view for explaining a conventional cap assembly.

1A and 1B, the cap assembly includes a cap plate 100 having a safety vent 190 formed thereon to release a gas generated by the simultaneous multiple exothermic reactions. The safety vent 190 is broken when the internal pressure of the battery rises, so that the internal gas and the like is discharged to the outside to improve the safety of the battery.

In general, however, when the battery is overcharged, the temperature increases as well as the internal pressure of the battery. However, the safety vent is operated only by the internal pressure of the battery and does not respond to a temperature increase. There is a problem.

The present invention relates to a cap assembly and a lithium ion secondary battery having the same, and an object thereof is to provide a cap assembly and a lithium ion secondary battery having the improved reliability and safety operating in response to temperature.

In order to achieve the above object, the present invention provides a cap assembly having a cap plate having at least a safety vent hole, wherein the safety vent hole formed in the cap plate is closed by a stopper, and the stopper is disposed on the top of the stopper. The cap assembly is positioned and secured by solder that is melted at a predetermined temperature.

In addition, the present invention provides a wound electrode assembly including a first electrode plate, a second electrode plate, a separator interposed between the first electrode plate and the second electrode plate; A case having a space for accommodating the electrode assembly; At least a safety vent hole is formed and the safety vent hole is closed with a stopper, and the stopper is positioned on top of the stopper and has a cap plate having a cap plate fixed by solder melted at a predetermined temperature; It provides a lithium ion secondary battery characterized in that.

Hereinafter, a lithium ion secondary battery according to a preferred embodiment of the present invention will be described in detail with reference to the accompanying drawings.

FIG. 2 is a sectional view of a lithium ion secondary battery according to a first embodiment of the present invention, and FIG. 3 is an enlarged view showing an area of FIG. 2 of the present invention.

2 and 3, the lithium ion secondary battery 30 according to the embodiment of the present invention includes a case 31, an electrode assembly 32 accommodated in the case 31, and the case 31. It includes a cap assembly 300 coupled to the top of the).

The case 31 is a metal container having an open top shape, and generally, aluminum or an aluminum alloy is used that is light and easy to cope with corrosion. It is also possible to itself serve as a terminal.

The electrode assembly 32 is interposed between the first electrode plate 34, the second electrode plate 36, and the first electrode plate 34 and the second electrode plate 36 to insulate them from each other. It contains (35).

The electrode assembly 32 includes a first electrode plate and a second electrode plate 34 and 36 and a separator 35 each consisting of one strip, and the first electrode plate 34, the separator 35, and the first electrode plate 32. It arrange | positions in order of the 2 electrode plate 36 and the separator 35, and is wound in the jelly-roll type.

The first electrode tab 37 is welded to the first electrode plate 34, and the second electrode tab 38 is welded to the second electrode plate 36, and the first electrode tab 37 and the second electrode tab ( One end of 38 protrudes above the electrode assembly 32. The first electrode tab 37 and the second electrode tab 38 are wrapped with an insulating tape 39 to prevent a short circuit between the positive electrode plates. The first electrode plate 34 and the second electrode plate 36 may act as a positive electrode plate or a negative electrode plate.

For example, the first electrode plate 34, which is used as a negative electrode plate, is coated with a negative electrode current collector made of a conductive metal plate, such as a copper foil, and a slurry composed mainly of a carbon material on both surfaces thereof.

For example, the second electrode plate 36, which is used as the positive electrode plate, is coated with a positive electrode current collector made of a metal thin plate having excellent conductivity, such as aluminum foil, and a slurry containing lithium-based oxide as a main component on both surfaces thereof.

The separator 35 may be made of polyethylene, polypropylene, or a copolymer of polyethylene and polypropylene. However, the separator 35 is not limited to the above materials. The separator 35 may be formed to be wider than the first electrode plate 34 and the second electrode plate 36 to prevent short circuit between the electrode plates 34 and 36.

The cap assembly 300 is provided with a flat cap plate 310 having a size and shape corresponding to the opening of the case 31. A terminal through hole 311 is formed at the center of the cap plate 310, and an electrolyte injection hole 312 and a safety vent hole 380 are formed at one side to inject the electrolyte.

An electrode terminal 320, for example, a negative electrode terminal, may be inserted into the terminal through hole 311 provided in the cap plate 310. The outer surface of the electrode terminal 320 is provided with a tube-shaped gasket 330 for electrical insulation with the cap plate 310. An insulating plate 340 is disposed on a lower surface of the cap plate 310 near the terminal hole 311 of the cap plate 310, and a terminal plate 350 is installed on a lower surface of the insulating plate 340. have.

The electrode terminal 320 is inserted through the terminal through hole 311 in a state in which the gasket 330 surrounds the outer circumferential surface. A lower surface portion of the electrode terminal 320 is electrically connected to the terminal plate 350 in a state where the insulating plate 340 is opened.

An insulating case 370 is provided on the upper surface of the electrode assembly 32 to electrically insulate the electrode assembly 32 from the cap assembly 300 and at the same time to cover the upper end of the electrode assembly 32. It is. The insulating case 370 is an insulating polymer resin, preferably made of polypropylene, but the material is not limited in the embodiment of the present invention.

The electrolyte injection hole 312 formed in the cap plate 310 is sealed with a ball 360, and the ball 360 is pressed against the electrolyte injection hole 312 by pressing means, such as a press, which moves up and down. It is possible. The electrolyte injection hole 312 is compressed by the ball 360, the weld portion (not shown) is formed through the laser welding along the boundary portion that is compressed between the ball 360 and the cap plate 310 is closed It is possible.

The safety vent hole 380 formed at one side of the cap plate 310 may be closed by a stopper 390 which is broken at a predetermined internal pressure. The stopper 390 may be formed of a flexible resin as well as a thin metal plate such as aluminum or an aluminum alloy. It may also be formed, but is not limited to the above material in the present invention.

The stopper 390 is coupled to the safety vent hole 380 to close the safety vent hole 380 and is fixed by solder 400 that is melted at a predetermined temperature. The stopper 390 is formed in a 'ㅁ' shape, the inside is empty and the outer surface is thinner than the thickness of the cap plate 310 so as to release the gas when the internal pressure increases above a certain pressure Is formed.

The melting point of the solder 400 which is positioned above the safety vent hole 380 and the stopper 390 and fixes the stopper 390 is preferably 90 to 110 ° C. If the melting point of the solder 400 is less than 90 ℃ there is a problem that can be melted in the aging process of the battery manufacturing process, if the melting point exceeds 110 ℃ it will not be sensitive to the internal temperature rise of the secondary battery. As a result, the solder 400 may not be melted or the stopper 390 may be easily broken due to overheating of the battery and an increase in internal pressure, such that there is a risk of explosion of the battery.

The solder 400 may be an alloy of tin (Sn), zinc (Zn), and lead (Pb), an alloy of tin (Sn), lead (Pb), bismuth (Bi), or an equivalent thereof, where the material It is not intended to limit. Since the melting point increases when the content of the tin (Sn) is lowered, the content of the tin (Sn) may be included in an amount of 20 to 90%.

In the lithium ion secondary battery 30 according to the present invention, when the temperature inside the battery increases due to overcharging or the like, the solder 400 is melted, and thus the plug 390 coupled to the safety vent hole 380. It can be easily released even by a small pressure inside the gas can discharge the gas inside the battery, it is possible to prevent the explosion, fire of the battery.

4 is an enlarged cross-sectional view of a safety vent area according to a second exemplary embodiment of the present invention.

Referring to FIG. 4, as shown, a safety vent hole 380 is formed in the cap plate 310, and the safety vent hole 380 is sealed by combining a stopper 390a having a '∩' shape. . The stopper 390a may be formed of a thin metal sheet such as aluminum or an aluminum alloy, and a flexible resin, preferably rubber, but is not limited to the above material in the present invention. The stopper 390a is fixed to the cap plate 310 by solder 400.

The stopper 390a has a groove formed at a lower side thereof, so that the stopper 390a may be easily broken due to an increase in the internal pressure of the battery, thereby improving safety of the battery. The solder 400 is melted when the internal temperature of the battery rises so that the stopper 390a coupled to the safety vent hole 380 can be easily detached and operated by the temperature as well as the pressure inside the battery. The safety of the battery can be improved.

5 is an enlarged cross-sectional view of a safety vent area according to a third exemplary embodiment of the present invention, and FIG. 6 is an enlarged cross-sectional view of a safety vent area according to a fourth exemplary embodiment of the present invention.

Referring to FIGS. 5 and 6, the stoppers 390b and 390a have notches formed in the inner or outer direction of the cap plate 310 so that the caps 390b and 390a are easily broken when the internal pressure due to gas generation becomes higher than a predetermined level. Can be. The notch may be formed in a V or U shape. The stoppers 390b and 390a are fixed by the solder 400, and the solder 400 is melted at 90 to 110 ° C. so that the stoppers 390b and 390a can be easily detached when the internal temperature of the battery increases. .

Herein, the shape of the stopper 390 has been described as an example of being formed in a 'ㅁ' and '자' shape, but the shape of the stopper 390 according to the present invention is not limited to the above examples. For example, various shapes, such as "'" and "H", are possible.

As described above, according to the present invention, the stopper for closing the safety vent hole can be easily detached in response to the internal temperature increase, thereby releasing the internal gas not only by the internal pressure but also by the temperature increase, thereby increasing the reliability and reliability of the battery. It can improve safety.

As described above, the present invention is not limited to the specific preferred embodiments described above, and any person having ordinary knowledge in the technical field to which the present invention belongs without departing from the gist of the present invention claimed in the claims. Various modifications are possible, of course, and such changes are within the scope of the claims.

Claims (18)

A cap assembly comprising a cap plate with at least a safety vent hole formed therein, The safety vent hole formed in the cap plate is closed with a stopper, the stopper is positioned on the top of the cap, characterized in that the cap assembly is fixed by a solder that is melted at a predetermined temperature. The method of claim 1, Cap assembly, characterized in that the melting point of the solder is 90 to 110 ℃. The method of claim 1, Wherein said solder is an alloy of tin (Sn), zinc (Zn) and bismuth (Bi). The method of claim 1, And wherein the solder is an alloy of tin (Sn), lead (Pb) and bismuth (Bi). The method of claim 1, Cap is characterized in that the cap is formed of a thin metal or flexible resin, such as aluminum or aluminum alloy fracture at a certain internal pressure. The method of claim 1, Cap is characterized in that the cap is formed in a 'ㅁ' shape. The method of claim 1, Cap is characterized in that the cap is formed in a '∩' shape. The method of claim 1, A cap assembly, characterized in that the notch is formed inside the stopper. The method of claim 1, The cap assembly is characterized in that the notch is formed on the outside. The method according to claim 8 or 9, The notch is a cap assembly, characterized in that formed in a V or U shape. A wound electrode assembly having a first electrode plate, a second electrode plate, a separator interposed between the first electrode plate and the second electrode plate; A case having a space for accommodating the electrode assembly; At least a safety vent hole is formed and the safety vent hole is closed with a stopper, and the stopper is positioned on top of the stopper and has a cap plate having a cap plate fixed by solder melted at a predetermined temperature; Lithium-ion secondary battery, characterized in that. The method of claim 11, Melting point of the solder is a lithium ion secondary battery, characterized in that 90 to 110 ℃. The method of claim 11, The solder is a lithium ion secondary battery, characterized in that the alloy of tin (Sn), zinc (Zn) and bismuth (Bi). The method of claim 11, The solder is a lithium ion secondary battery, characterized in that the alloy of tin (Sn), lead (Pb) and bismuth (Bi). The method of claim 11, The stopper is a lithium ion secondary battery, characterized in that formed of a thin metal or flexible resin, such as aluminum or aluminum alloy fracture at a certain breakdown pressure. The method of claim 11, The stopper is a lithium ion secondary battery, characterized in that formed in the 'ㅁ' or '∩' shape. The method of claim 11, A notch is formed inside or outside the stopper, wherein the lithium ion secondary battery. The method of claim 17, The notch is a lithium ion secondary battery, characterized in that formed in a V or U shape.

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