KR20060111984A - Polaris paper and manufacturing method thereof - Google Patents
Polaris paper and manufacturing method thereof Download PDFInfo
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- KR20060111984A KR20060111984A KR1020050034303A KR20050034303A KR20060111984A KR 20060111984 A KR20060111984 A KR 20060111984A KR 1020050034303 A KR1020050034303 A KR 1020050034303A KR 20050034303 A KR20050034303 A KR 20050034303A KR 20060111984 A KR20060111984 A KR 20060111984A
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F9/00—Complete machines for making continuous webs of paper
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
- D21H17/28—Starch
- D21H17/29—Starch cationic
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/54—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
- D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
- D21H23/04—Addition to the pulp; After-treatment of added substances in the pulp
- D21H23/06—Controlling the addition
- D21H23/08—Controlling the addition by measuring pulp properties, e.g. zeta potential, pH
- D21H23/10—Controlling the addition by measuring pulp properties, e.g. zeta potential, pH at least two kinds of compounds being added
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Abstract
Description
도1은 종래의 제지를 제조하는 공정을 도시한 흐름도,1 is a flowchart illustrating a process of manufacturing a conventional papermaking machine;
도2는 본 발명에 의한 폴라리스지를 제조하는 공정을 도시한 흐름도,2 is a flowchart illustrating a process of manufacturing polaris paper according to the present invention;
도3은 본 발명에 의한 폴라리스지를 도시한 일부 평면도이다.3 is a partial plan view of the polarisage according to the present invention.
본 발명은 펄 특유의 고급스러움과 독특한 광택이 인쇄물을 더욱 돋보이게 하는 펄(pearl) 안료로 코팅된 양면 펄지를 재활용하여 제조한 폴라리스지 및 그 제조 방법에 관한 것이다.The present invention relates to a polaris paper produced by recycling double-sided pulp coated with a pearl pigment, the pearl's unique luxury and unique luster makes the printed material stand out more.
일반적으로, 펄 안료가 코팅된 양면 펄지를 제조하는 과정을 도1에 도시하고 있다.In general, the process for producing a double-sided pulp coated with a pearl pigment is shown in FIG.
먼저, 양면 펄지는 일반적인 종이 제조 공정에 코팅하는 공정을 더해 제조된다. 즉, 양면 펄지를 제조하는 공정은 크게, 종이를 생산하기 위한 최적의 원료를 준비하는 조성공정과, 상기 공정에서 준비된 원료를 리파이너를 통해 물과 혼합하여 알맞게 절단 섬유화하는 고해공정과, 초지기를 통해 종이를 생산하는 초지 (paper making)공정과, 코터를 통해 종이의 양면에 펄 안료로 코팅하는 코팅공정과, 이 종이에 인쇄적성을 향상시키는 슈퍼캘린더링 공정과, 고객이 원하는 크기와 형태로 재단 및 포장하여 최종적으로 완성된 제품을 유통하는 완정 및 물류 공정으로 이루어진다.First, double-sided pulp is prepared by adding a coating process to a general paper manufacturing process. That is, the process of manufacturing double-sided pulp is largely composed of a composition process for preparing an optimal raw material for producing paper, a beating process for mixing the raw material prepared in the above process with water through a refiner, and appropriately cutting and fiberizing the paper. Paper making process to produce paper, coating process to coat pearl pigment on both sides of paper through coater, super calendering process to improve printability on this paper, cutting to the size and shape that customer wants And packaging and distribution processes for distributing the finished product by packaging.
도1의 흐름도를 보면서 상기한 공정을 자세히 설명하면, 종이를 생산하기 위한 최적의 원료 즉, 펄프를 종이 제조에 적당한 조건으로 물과 혼합하여 개별 섬유로 분리하는 펄핑단계와, 상기 단계에서 물과 혼합된 원료를 리파이너(Refiner)로 알맞게 절단, 섬유화하는 고해 단계와, 상기한 주원료에 사이즈제 및 충전제와 같은 약품을 일정한 비율로 혼합하는 배합 단계와, 섬유 크기를 고르게 하거나 이물질을 최종적으로 걸러주는 정선(Screen & Cleaner) 단계와, 상기 정선 단계에서 다수의 압력 스크린을 거쳐 나온 종이가 헤드 박스에서 와이어 전폭에 걸쳐 종이를 균일하게 사출 배분하는 단계와, 상기 헤드 박스에서 와이어로 된 틈으로 사출된 종이를 탈수하는 단계와, 상기에서 탈수된 종이가 프레스를 통과하면서 기계적으로 압축 및 탈수가 이루어지는 단계와, 상기와 같이 탈수된 종이를 스팀을 이용하여 건조하는 전건조 단계와, 이 종이에 품질을 향상시키기 위해 기능성 약품을 첨가하는 사이즈 프레스 단계와, 재습윤된 종이를 다시 한 번 건조하고 적정 수분 균형을 유지하도록 건조하는 후건조 단계와, 상기 단계가 완성된 종이를 코터를 통해 코팅하기 위하여 상기한 종이를 다시 풀어 주는 언와인더 단계와, 상기 언와인딩된 종이에 펄 안료나 바인더 등의 코팅 칼라를 발라 광택을 부여하는 코팅 단계와, 상기 단계에서 코팅된 종이를 열풍과 스팀을 이용하여 종이를 건조하는 건조 단계와, 코팅이 완료된 종이를 다시 감는 리와인딩 단계와, 롤에 상기한 종이를 통과시켜 평활도와 광택도 등의 인쇄 적성을 더욱 좋게 하는 슈퍼 캘린더링 단계와, 고객이 원하는 크기와 형태로 재단 및 포장하여 최종적으로 완성된 제품을 유통하는 완정 및 물류 단계로 이루어진다.Referring to the process described in detail with reference to the flow chart of Figure 1, the optimum raw material for producing paper, that is, a pulping step of separating the individual fibers by mixing the pulp with water in a condition suitable for paper production, and the water and A beating step of appropriately cutting and fiberizing the mixed raw materials with a refiner, a blending step of mixing a chemical such as a sizing agent and a filler in a predetermined ratio to the main raw materials, and evenly filtering the fibers or finally filtering out foreign substances. Screen & Cleaner step, the paper passed through a plurality of pressure screens in the step of the step of uniformly distribute the paper across the wire width in the head box, and injected into the gap of the wire in the head box Dewatering the paper and mechanically compressing and dewatering the dewatered paper as it passes through the press. The system, a predrying step of drying the dewatered paper using steam, a size press step of adding functional chemicals to the paper to improve the quality, and drying and titrating the rewet paper again. A post-drying step of drying to maintain moisture balance, an unwinder step of releasing the paper again to coat the finished paper through a coater, and a pearl pigment or binder on the unwinded paper. A coating step of applying a coating color to give gloss, a drying step of drying the paper using hot air and steam from the paper coated in the step, a rewinding step of rewinding the coated paper, and a roll of paper as described above. Super calendering step to improve printing aptitude such as smoothness and glossiness through cutting, and cutting and packing to the size and shape desired by customers. It consists wanjeong and logistics step of distributing the finished product in the longitudinal.
상기한 바와 같은 공정으로 제조된 양면 펄지는 불량품으로 폐지 처리시 종이의 양면에 펄 안료로 코팅되어 있어 전량 폐기하여 재활용이 되지 않아 폐기시 자연 상태로 분해되는 데, 200 내지 300년이 소요되는 것으로 나타났다. The double-sided pulps produced by the process as described above is a defective product is coated with a pearl pigment on both sides of the paper when the waste paper is treated, so that the entire amount of waste is not recycled, so that it takes 200 to 300 years to decompose into a natural state at the time of disposal. appear.
본 발명은 상기와 같은 문제점을 해결하기 위한 것으로써, 본 발명의 목적은 양면에 펄 안료로 코팅된 양면 펄지와 일반 종이를 혼합한 것을 원료로 하여 제조된 폴라리스지 및 그 제조 방법을 제공하는 데 있다. The present invention is to solve the above problems, an object of the present invention is to provide a polaris paper produced by mixing a double-sided pulp coated with a pearl pigment on both sides and a plain paper as a raw material and a method for producing the same have.
따라서 상기와 같은 목적을 실현하기 위하여 본 발명에 따른 폴라리스지는, 펄 안료가 함유된 폐기용 양면 펄지 60~75wt%와, 일반 파지 25~40wt%와, 수분 4.5 wt%를 주원료로 한 펄프와;Therefore, in order to achieve the above object, the polaris paper according to the present invention is a pulp containing 60 to 75 wt% of waste double-sided pulp containing pearl pigment, 25 to 40 wt% of general phage, and 4.5 wt% of water;
사이즈제 1~2g과, 알미늄 설페이트(AL2(SO4)3) 1.5~2.5g과, 양성 전분 0.6g과, 아크릴아마이드와 캐이셔닉 아크릴레이트의 코폴리머인 보류제 0.03g과, 일반 전분 3~4g과, 표면 사이즈제 0.3~0.4g과, 전분경화제 0.01g을 부원료로 하여 상기 펄프에 첨가되는 것을 특징으로 한다.1-2 g of size agent, 1.5-2.5 g of aluminum sulfate (AL 2 (SO 4 ) 3 ), 0.6 g of positive starch, 0.03 g of preservative, which is a copolymer of acrylamide and cationic acrylate, and general starch It is added to the said pulp using 3-4 g, surface size agents 0.3-0.4 g, and starch hardening | curing agent as a subsidiary material.
상기한 바와 같은 폴라리스지의 제조 방법은 종이를 생산하기 위한 최적의 원료인 펄프를 종이 제조에 적당한 조건으로 물과 혼합하여 개별 섬유로 분리하는 펄핑단계와, 펄 입자를 적절한 크기 분포를 가지도록 조절 및 해리시켜 주는 디플레이크(deflaker) 단계와, 상기한 주원료에 사이즈제 및 충전제와 같은 약품을 일정한 비율로 혼합하는 배합 단계와, 상기 배합된 주원료 및 부원료가 헤드 박스에서 와이어 전폭에 걸쳐 종이를 균일하게 사출 배분하는 단계와, 상기 헤드 박스에서 와이어로 된 틈으로 사출된 종이를 탈수하는 단계와, 상기에서 탈수된 종이가 프레스를 통과하면서 기계적으로 압축 및 탈수가 이루어지는 단계와, 상기와 같이 탈수된 종이를 스팀을 이용하여 건조하는 전건조 단계와, 이 종이에 품질을 향상시키기 위해 기능성 약품을 첨가하는 사이즈 프레스 단계와, 재습윤된 종이를 다시 한 번 건조하고 적정 수분 균형을 유지하도록 건조하는 후건조 단계와, 롤에 상기한 종이를 통과시켜 평활도와 광택도 등의 인쇄 적성을 더욱 좋게 하는 캘린더링 단계와, 고객이 원하는 크기와 형태로 재단 및 포장하여 최종적으로 완성된 제품을 유통하는 완정 및 물류 단계로 이루어진 것을 특징으로 한다.Polaris paper production method as described above is a pulp step of mixing the pulp, which is the best raw material for producing paper with water under conditions suitable for paper production, separated into individual fibers, and control the pearl particles to have an appropriate size distribution and A deflaker step of dissociation, a mixing step of mixing a drug such as a sizing agent and a filler into the main raw material at a constant ratio, and the blended main raw material and the sub raw material uniformly distribute the paper over the wire width in the head box. Injection distribution, dewatering the paper injected into the gap of the wire in the head box, mechanically compressing and dehydrating the dewatered paper while passing through the press, and dewatering paper as described above Predrying step of drying with steam, and the functional drugs are applied to the paper to improve the quality. A size press step to add, a post-drying step to dry the re-wetted paper once again and to maintain an appropriate moisture balance, and to pass the paper through a roll to improve printing aptitude such as smoothness and glossiness. It is characterized in that consisting of a calendaring step, and the final and distribution stage for circulating the finished product by cutting and packaging in the size and shape desired by the customer.
이하, 본 발명의 실시예를 첨부된 도면을 참조하면서 상세히 설명한다.Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings.
도2는 본 발명에 의한 폴라리스지의 제조 공정을 도시한 플로우챠트이다.Fig. 2 is a flowchart showing a manufacturing process of polarisage according to the present invention.
도2에 도시된 바와 같이, 본 발명에 따른 폴라리스지는, 펄 안료가 함유된 폐기용 양면 펄지 60~75wt%와, 일반 파지 25~40wt%와, 수분 4.5 wt%를 주원료로 한 펄프와; 사이즈제 1~2g과, 알미늄 설페이트(AL2(SO4)3) 1.5~2.5g과, 양성 전분 0.6g 과, 아크릴라마이드와 캐이셔닉 아크릴레이트의 코폴리머인 보류제 0.03g과, 일반 전분 3~4g과, 표면 사이즈제 0.3~0.4g과, 전분경화제 0.01g을 부원료로 하여 상기 펄프에 첨가되어 구성된다.As shown in Fig. 2, the polaris paper according to the present invention includes pulp containing 60 to 75 wt% of waste double-sided pulp containing pearl pigment, 25 to 40 wt% of general waste paper, and 4.5 wt% of water; 1 to 2 g of size agent, 1.5 to 2.5 g of aluminum sulfate (AL 2 (SO 4 ) 3 ), 0.6 g of positive starch, 0.03 g of preservative, which is a copolymer of acrylamide and cationic acrylate, and general It is comprised by adding 3-4 g of starch, 0.3-0.4 g of surface size agents, and 0.01 g of starch hardening | curing agents as a subsidiary material to the said pulp.
상기한 바와 같은 폴라리스지의 제조 방법은 종이를 생산하기 위한 최적의 원료인 펄프를 종이 제조에 적당한 조건으로 물과 혼합하여 개별 섬유로 분리하는 펄핑단계와, 펄 입자를 적절한 크기 분포를 가지도록 조절 및 해리시켜 주는 디플레이크(deflaker) 단계와, 상기한 주원료에 사이즈제 및 충전제와 같은 약품을 일정한 비율로 혼합하는 배합 단계와, 상기 배합된 주원료 및 부원료가 헤드 박스에서 와이어 전폭에 걸쳐 종이를 균일하게 사출 배분하는 단계와, 상기 헤드 박스에서 와이어로 된 틈으로 사출된 종이를 탈수하는 단계와, 상기에서 탈수된 종이가 프레스를 통과하면서 기계적으로 압축 및 탈수가 이루어지는 단계와, 상기와 같이 탈수된 종이를 스팀을 이용하여 건조하는 전건조 단계와, 이 종이에 품질을 향상시키기 위해 기능성 약품을 첨가하는 사이즈 프레스 단계와, 재습윤된 종이를 다시 한 번 건조하고 적정 수분 균형을 유지하도록 건조하는 후건조 단계와, 롤에 상기한 종이를 통과시켜 평활도와 광택도 등의 인쇄 적성을 더욱 좋게 하는 캘린더링 단계와, 고객이 원하는 크기와 형태로 재단 및 포장하여 최종적으로 완성된 제품을 유통하는 완정 및 물류 단계로 이루어진다.Polaris paper production method as described above is a pulp step of mixing the pulp, which is the best raw material for producing paper with water under conditions suitable for paper production, separated into individual fibers, and control the pearl particles to have an appropriate size distribution and A deflaker step of dissociation, a mixing step of mixing a drug such as a sizing agent and a filler into the main raw material at a constant ratio, and the blended main raw material and the sub raw material uniformly distribute the paper over the wire width in the head box. Injection distribution, dewatering the paper injected into the gap of the wire in the head box, mechanically compressing and dehydrating the dewatered paper while passing through the press, and dewatering paper as described above Predrying step of drying with steam, and the functional drugs are applied to the paper to improve the quality. A size press step to add, a post-drying step to dry the re-wetted paper once again and to maintain an appropriate moisture balance, and to pass the paper through a roll to improve printing aptitude such as smoothness and glossiness. It consists of a calendaring step and a finalization and logistics step of circulating the finished product by cutting and packing to the size and shape desired by the customer.
그리고, 또한, 상기한 폴라리스지를 코팅 처리할 경우, 상기 단계가 완성된 종이를 코터를 통해 코팅하기 위하여 슈퍼 캘린더링 단계 전에 이루어지는 공정으로, 상기한 종이를 다시 풀어 주는 언와인더 단계와, 상기 언와인딩된 종이에 펄 안료나 바인더 등의 코팅 칼라를 발라 광택을 부여하는 코팅 단계와, 상기 단계에서 코팅된 종이를 열풍과 스팀을 이용하여 종이를 건조하는 건조 단계와, 코팅이 완료된 종이를 다시 감는 리와인딩 단계를 더 포함하여 구성된다.Further, when the polaris paper is coated, the step is performed before the super calendering step to coat the finished paper through a coater, the unwinder step of releasing the paper again; A coating step of applying a coating color such as a pearl pigment or binder to the wound paper to give gloss, a drying step of drying the paper using hot air and steam on the coated paper in the step, and rewinding the coated paper. It further comprises a rewinding step.
상기한 바와 같이, 구성된 본 발명은, 전량 폐지로 사용되던 펄 안료가 코팅된 양면 펄지를 주원료로 하여 폴라리스지를 제조함으로써, 주원료에 포함된 양면펄지를 절단 파쇄하는 고해 단계나 클리너에 의한 정선단계를 삭제하여 공정을 단축할 뿐만 아니라 인쇄시 표면의 펄 안료 입자들로 인해 은은하면서 반짝임이 나타나 고급스러운 전통 한지의 이미지를 연출할 수 있으며, 일반지종 대비 두께가 두꺼우면서도, 부드러운 이미지를 부여하는 지종이다. 도3에 도시된 바와 같은 폴라리스지는 연하카드, 청첩장, 카다로그 등과 같은 팬시지로서 자연스러운 표면 특성 및 고급 이미지를 갖는다.As described above, according to the present invention, the polarizing paper coated with the pearl pigment used as waste paper as a main raw material is produced as a main raw material, and the crushing step for cutting and crushing the double-sided pulp contained in the main raw material or the selection step by the cleaner By not only shortening the process, but also by the pearl pigment particles on the surface of the printing, it is soft and shiny, so that it can produce an image of the traditional Korean paper, which is thicker than the general paper, and gives a soft image. Polaris paper, as shown in Figure 3, is a fan of greeting cards, wedding invitations, catalogs, and the like, with natural surface properties and high-quality images.
다음은 본 발명에 의한 폴라리스지의 품질 성능을 시험한 결과를 하기 표에 기술하고 있다.Next, the results of testing the quality performance of the Polaris paper according to the present invention are described in the following table.
[표][table]
이러한 폴라리스지는 상기한 바와 같은 시험 데이터에서 보는 바와 같이, 일반 지종에 비해 두께 및 고시(stiffness) 특성을 지닌다.This polaris paper has a thickness and stiffness characteristics as compared to the general paper, as shown in the test data as described above.
상기한 바와 같은 본 발명에 의한 폴라리스지 및 그 제조 방법에 의하면, 전량 폐지로 사용되던 펄 안료가 코팅된 양면 펄지를 주원료로 하여 폴라리스지를 제조함으로써, 주원료에 포함된 양면펄지를 절단 파쇄하는 고해 단계나 클리너에 의한 정선단계를 삭제하여 공정을 단축할 뿐만 아니라 펄 안료 입자크기를 디플레이크를 통해 필요한 크기로 조절하므로써 인쇄시 표면의 다양한 크기로 분산된 펄 안료 입자들로 인해 은은하면서 반짝임이 나타나 고급스러운 전통 한지의 이미지를 연출할 수 있으며, 일반지종 대비 두께가 두꺼우면서도, 부드러운 이미지를 부여하는 지종으로, 고가의 펄 안료인 순수 원료를 사용하지 않고 펄 안료가 코팅된 양면 펄지를 재회수, 이를 주원료로 사용하여 폴라리스지를 제조함으로써, 폐기에 따른 환경오염을 방지할 수 있으며, 자원을 절약하는 효과가 있다. According to the polaris paper according to the present invention and the manufacturing method as described above, the beating step of cutting and crushing the double-sided pulp contained in the main raw material by producing a polaris paper with the double-sided pulp coated with the pearl pigment used as a total waste paper as the main raw material In addition to shortening the process by eliminating the selection process by the cleaner, the pearl pigment particle size is adjusted to the required size through the de-flake, so that the pearl pigment particles dispersed in various sizes on the surface during printing are soft and shiny. It can produce the image of traditional Korean paper, and it is thicker than general paper and gives a soft image.It reclaims the double-sided pulp coated with pearl pigment without using pure raw material, which is an expensive pearl pigment. Polaris paper is used to prevent environmental pollution Can, and has the effect of saving resources.
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