KR20060046896A - Detergent composition for toilet-stool - Google Patents
Detergent composition for toilet-stool Download PDFInfo
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- KR20060046896A KR20060046896A KR1020040092406A KR20040092406A KR20060046896A KR 20060046896 A KR20060046896 A KR 20060046896A KR 1020040092406 A KR1020040092406 A KR 1020040092406A KR 20040092406 A KR20040092406 A KR 20040092406A KR 20060046896 A KR20060046896 A KR 20060046896A
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- sodium
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
본 발명은 변기세정액 조성물에 관한 것으로, 더욱 상세하게는 높은 전도도가 높은 물질을 포함하여 전극식 센서에 보다 용이하게 탐지되는 것을 특징으로 하는 변기 세정액 조성물에 관한 발명이다.The present invention relates to a toilet cleaning liquid composition, and more particularly, to a toilet cleaning liquid composition comprising a substance having a high conductivity is more easily detected by the electrode sensor.
본 발명의 변기세정액은 전도도가 높은 물질 포함하는 것을 특징으로 하는 것으로서, 통상적으로 사용되는 액체 비누에 비하여 세정액 자동 공급장치의 센서에서 보다 용이하게 검출된다. 따라서 본 발명의 변기세정액은 저수조 내부의 수위변화를 전극형 센서로 탐지하여 자동적으로 세정액을 공급하는 장치에 사용되었을 경우, 통상적인 액체 비누에 비하여 그 장치의 동작을 확실히 할 수 있는 효과가 있다.Toilet bowl cleaning liquid of the present invention is characterized in that it contains a high conductivity material, it is more easily detected by the sensor of the automatic cleaning liquid supply device than the liquid soap used in general. Therefore, when the toilet cleaning liquid of the present invention is used in a device that detects the water level change in the reservoir with an electrode type sensor and automatically supplies the cleaning liquid, the toilet cleaning liquid has an effect of ensuring the operation of the apparatus as compared to a conventional liquid soap.
세정제, 변기, 전도도, 자동, 공급장치Cleaner, Toilet, Conductivity, Automatic, Feeder
Description
도 1은 한국공개특허 제2003-0045201호에서 개시하고 있는 세척액 공급장치를 나타낸 그림1 is a view showing a cleaning solution supply device disclosed in Korea Patent Publication No. 2003-0045201
<*도면에 사용된 부호에 대한 설명*><* Description of the symbols used in the drawings *>
1: 변기 2: 변기물탱크 10-1: 제1전극봉 10-2: 제2전극봉DESCRIPTION OF
20: 제어회로부 40: 세척액통 41: 공급펌프 42: 세척액공급관20: control circuit 40: washing liquid container 41: supply pump 42: washing liquid supply pipe
43: 분사노즐팁43: spray nozzle tip
본 발명은 변기세정액 조성물에 관한 것으로, 더욱 상세하게는 높은 전도도가 높은 물질을 포함하여 전극식 센서에 보다 용이하게 탐지되는 것을 특징으로 하는 변기 세정액 조성물에 관한 발명이다.The present invention relates to a toilet cleaning liquid composition, and more particularly, to a toilet cleaning liquid composition comprising a substance having a high conductivity is more easily detected by the electrode sensor.
일반적으로 수세식변기에 사용되는 세정제는 고체상태의 덩어리로서 저수조 내부에 설치되는 것이 가장 흔하게 사용되며, 저수조 내부에서 물에 용해된 상태로 변기에 공급되어 각종 오염 물질과 냄새 등을 제거하는 작용을 수행한다.In general, the cleaning agent used in the flush toilet is a solid mass, which is installed inside the reservoir, and is most commonly used. The detergent is supplied to the toilet in a state dissolved in water to remove various pollutants and odors. do.
그러나 이러한 방식의 변기세정제는 저수조 내부에서 물에 포화될 때까지 용해되기 때문에 소모가 심하여 그 수명이 매우 짧은 것이 단점이며, 또한 변기를 연속적으로 2회 이상 사용할 경우에는 세정 성분이 충분히 용해되지 않은 상태에서 변기로 공급되므로 세정 효과가 충분하지 못한 문제점이 있다.However, this type of toilet cleaner dissolves until it saturates in water in the water tank, so it is consumed so much that its life is very short. Also, when two or more toilet bowls are used continuously, the cleaning component is not sufficiently dissolved. There is a problem that the cleaning effect is not sufficient because it is supplied to the toilet.
상기한 문제점을 해결하는 방안으로서 한국공개특허 제2003-0045201호에서는 액체상태의 변기세척액을 자동으로 공급하는 장치에 관한기술을 개시하고 있다. 상기 발명은 도 1에 나타낸 구성을 가지는 것으로서, 전극봉(10-1, 10-2)으로 변기 저수조 내부의 수위 변화를 탐지하여 세척액통(40)에 저장된 세척액을 공급펌프(41)과 세척액 공급관(42)를 통하여 자동적으로 일정량씩 공급함을 특징으로 하고 있다.As a solution to the above problems, Korean Laid-Open Patent Publication No. 2003-0045201 discloses a technique related to an apparatus for automatically supplying a liquid toilet flushing liquid. The present invention has the configuration shown in Figure 1, by detecting the change in the water level inside the toilet reservoir with the electrode rods (10-1, 10-2) to supply the washing liquid stored in the washing
따라서, 상기한 한국공개특허 제2003-0045201호의 기술에 의하면 세정액을 낭비 없이 일정량씩 변기에 공급하는 것이 가능한 효과가 있다.Therefore, according to the above-described technique of Korean Patent Laid-Open Publication No. 2003-0045201, it is possible to supply the cleaning liquid to the toilet bowl by a predetermined amount without waste.
그러나 상기 특허에서는 전극봉(10-1, 10-2)를 이용하여 저수조 내부의 수위 변화를 탐지하는 방법을 사용하고 있기 때문에, 정확한 출력 신호의 검출이 어려웠고, 따라서 세척액 공급장치가 오작동 하는 경우가 많이 나타나는 것이 문제점이었다.However, since the patent uses a method of detecting the water level change inside the reservoir using the electrodes 10-1 and 10-2, it is difficult to accurately detect the output signal, and thus, the cleaning solution supply device often malfunctions. It was a problem that appeared.
상기한 문제점은 전극봉(10-1, 10-2)대신에 다른 형태의 레벨센서 즉, 광센서나 초음파센서, 정전용량형 레벨센서를 사용하면 해결 가능하지만, 이런 종류의 센서들은 그 가격이 매우 비싸 일상 생활용품으로 사용하기는 매우 어렵다.The above problems can be solved by using other types of level sensors instead of electrodes 10-1 and 10-2, that is, optical sensors, ultrasonic sensors, and capacitive level sensors. However, these types of sensors are very expensive. It is expensive and very difficult to use as daily necessities.
본 발명은 상기한 한국공개특허 제2003-0045201호의 문제점을 해결하기 위하여 제시되는 것으로서, 상기 발명에 사용되는 세정액에 전도도가 높은 물질을 포함시켜 전극봉에서 보다 용이한 검출이 가능하도록 하였다.
The present invention has been made to solve the problems of the above-described Korean Patent Publication No. 2003-0045201, by including a high conductivity material in the cleaning liquid used in the invention to enable easier detection in the electrode.
본 발명에 따른 변기세정액 조성물은 세제, 살균소독제, 향료, 색소, 전도도 증진제를 포함하는 것을 기술적 특징으로 한다.The toilet bowl cleaning composition according to the present invention is characterized in that it comprises a detergent, a disinfectant, a perfume, a pigment, and a conductivity enhancer.
이하 본 발명의 기술적 구성을 보다 상세히 설명한다.Hereinafter, the technical configuration of the present invention in more detail.
본 발명에서 제공하는 변기세정액 조성물에서 사용하는 세제는 통상적으로 세정의 목적으로 사용되는 것으로서 계면활성제를 뜻한다. 따라서 본 발명의 세제는 음이온계 계면활성제, 양이온계 계면활성제, 비이온계 계면활성제, 양성 계면활성제 중에서 선택된 어느 1종 이상의 물질이다.Detergent used in the toilet bowl cleaning composition provided in the present invention is usually used for the purpose of cleaning means a surfactant. Therefore, the detergent of the present invention is any one or more substances selected from anionic surfactants, cationic surfactants, nonionic surfactants, and amphoteric surfactants.
본 발명에서 음이온계 계면활성제로는 직쇄 알킬벤젠설폰산염(LAS), 알파올레핀설폰산염(AOS), 알킬황산에스테르염(AS), 폴리옥시에칠렌 알킬에스테르황산염(AES), 2급 알칸설폰산염(SAS), 비누(soap), 알파설포지방산에스테르염(MES)를 사용한다.In the present invention, the anionic surfactant is a linear alkylbenzene sulfonate (LAS), alpha olefin sulfonate (AOS), alkyl sulfate ester salt (AS), polyoxyethylene alkyl ester sulfate (AES), secondary alkane sulfonate ( SAS), soap, alpha sulfo fatty acid ester salt (MES) is used.
본 발명에서 양이온계 계면활성제로는 디알킬이메틸 암모늄 클로라이드(DDAC), 이미다졸륨염(imidazolium salt), 에스테르를 포함하는 4급 암모늄염(ester-containing quaternary ammonium salt(EQ))을 사용한다.As the cationic surfactant in the present invention, dialkyl dimethyl ammonium chloride (DDAC), imidazolium salt (imidazolium salt), and an ester-containing quaternary ammonium salt (EQ) containing an ester are used.
본 발명에서 비이온계 계면활성제로는 폴리옥시에틸렌알킬에테르(AE), 알킬디메틸아민옥사이드(AO), 지방산 알카놀아마이드(FAA), 알킬폴리글루코사이드(APG), 폴리옥시에틸렌알킬페닐에테르(APEO)를 사용한다.In the present invention, the nonionic surfactant is polyoxyethylene alkyl ether (AE), alkyldimethylamine oxide (AO), fatty acid alkanolamide (FAA), alkyl polyglucoside (APG), polyoxyethylene alkylphenyl ether (APEO ).
본 발명에서 양쪽성 계면활성제로는 알킬베타인(AB), 알킬설포베타인(ASB)을 사용한다.In the present invention, the amphoteric surfactant is alkylbetaine (AB) or alkylsulfobetaine (ASB).
본 발명의 변기세정제에 포함되는 살균소독제는 변기에 기생하는 미생물을 제거하고 그 생장을 방지하는 목적으로 사용한다. 살균소독제는 살균제(biocide)와 소독제(disinfectant)의 기능을 함께하는 것으로, 본 발명에서는 과망간산칼륨, 과산화수소, 과산화옥탄산, 과산화초산, 구연산, D-글루콘산나트륨, 나프탈렌설폰산나트륨, 네오데칸산, 노나논산, 데칸산, 도데실벤젠설폰산, 도데실벤젠설폰산 나트륨, 도데실펜옥시벤젠 디설폰산, 디도데실펜옥시벤젠 디설폰산나트륨, 디메틸나프탈렌설폰산나트륨, 디메틸벤젠설폰산 나트륨, n,n-디메틸-1-옥탄아민, 4-(1,1-디메틸프로필)페놀, 디옥틸설포석신산 나트륨, α-라우로일-ω-하이드록시폴리옥시에틸렌, 메틸나프탈렌설폰산나트륨, 메틸렌블루(C.I.basic blue P), 2-메틸-2,4-펜탄디올, 모노도데실에스테르 황산나트륨, 모노도데실펜옥시벤젠 디설폰산나트륨, 벤잘코늄, 2-부톡시-에탄올, 붕산나트륨, 브롬화나트륨, 브롬화칼륨, 브롬화칼슘, 산화마그네슘, 삼염화이소시아뉼산, 삼염화이소시아뉼산 나트륨, 삼염화이소시아뉼산 칼륨, 설포-1,4-디옥틸부탄산나트륨, 설포옥타데센산, 설포옥타데센산 나트륨, 설포지방산, 설포지방산나트륨, 2-설피노-1-옥탄설폰산, 2-[시클로헥실(1-옥소헥사데실)아미노]-에탄설폰산 나트륨, 수산화나트륨, 아염소산염, 알킬나프탈렌설폰산나 트륨, 알킬디메틸나프탈렌 설폰산나트륨, 알킬메틸나프탈렌설폰산 나트륨, 알킬트리메틸나프탈렌설폰산 나트륨, 에탄올, 2-(2-에톡시에톡시)에탄올, 에틸렌디아민 테트라아세트산 사나트륨, 에틸렌디아민 테트라아세트산 이나트륨, 폴리알킬렌글리콜, (에틸렌-프로필렌)폴리알킬렌글리콜부톡시모노에테르, 염소산염, 염화멜라민, 염화암모늄, 옥시비스도데실벤젠설폰산, 옥시에틸렌옥시프로필렌 공중합체, 옥시에틸렌옥시프로필렌 공중합체, 옥시에틸렌옥시프로필렌 공중합체, 옥시클로로계 물질, 옥타데칸산칼슘, 1,2-옥탄디설폰산, 옥탄산, 1-옥탄설폰산, 1-옥탄설폰산나트륨, 옥테닐부탄디오익산, 요오드, 요오드나트륨, 요오드칼륨, 요오드화수소산, 은, 이산화염소, 이염화이소시아뉼산, 이염화이소시아뉼산 나트륨, 이염화이소시아뉼산 나트륨이수화물, 이염화이소시아뉼산 칼륨, 인산, 인산나트륨, 인산삼나트륨, 일염화요오드, 젖산, 질산, 차아염소산, 차아염소산나트륨, 차아염소산리튬, 차아염소산칼륨, 차아염소산칼슘, 초산, n-카르복실산, 코코지방산칼륨, n-클로로-4-메틸 벤젠설폰아미드나트륨, 클로로아세트산나트륨, 클로라민 T, 클로로헥사딘, 4,5-디하이드로-2-언데실-1H-이미다졸-1-에탄올과 수산화 나트륨의 반응물, 4-클로로-2-(페닐메틸)-페놀, 트리메틸나프탈렌, 설폰산나트륨, α,α-트리메틸-3-시클로헥산-1-메탄올, 페놀, 페닐페놀, 메틸페놀(크레졸), 폴리알킬렌글리콜, (에틸렌-프로필렌)부톡시모노에테르, 폴리에틸렌글리콜 모노라우레이트, 폴리에틸렌 글리콜, 폴리프로필렌글리콜 모노부틸에테르, 폴리에틸렌 글리콜, 폴리프로필렌 글리콜 n-알킬 에테르, 황산으로 구성되는 군에서 선택되는 어느 1종 이상을 사용한다.Disinfectant disinfectant included in the toilet bowl cleaner of the present invention is used to remove microorganisms parasitic in the toilet bowl and to prevent its growth. Bactericidal disinfectants combine the functions of biocide and disinfectant. In the present invention, potassium permanganate, hydrogen peroxide, octanoic acid peracetic acid, acetic acid, citric acid, sodium D-gluconate, sodium naphthalene sulfonate, neodecanoic acid, Nonanoic acid, decanoic acid, dodecylbenzenesulfonic acid, sodium dodecylbenzenesulfonic acid, dodecylphenoxybenzene disulfonic acid, sodium didodecylphenoxybenzene disulfonic acid, sodium dimethylnaphthalenesulfonate, sodium dimethylbenzenesulfonate, n, n -Dimethyl-1-octanamine, 4- (1,1-dimethylpropyl) phenol, sodium dioctylsulfosuccinate, α-lauroyl-ω-hydroxypolyoxyethylene, sodium methylnaphthalenesulfonate, methylene blue (CI basic blue P), 2-methyl-2,4-pentanediol, sodium monododecyl ester sodium sulfate, sodium monododecylphenoxybenzene disulfonate, benzalkonium, 2-butoxy-ethanol, sodium borate, sodium bromide, potassium bromide, Calcium bromide, Magnesium sulfide, isocyanate trichloride, sodium isocyanate trichloride, potassium isocyanate trichloride, sodium sulfo-1,4-dioctylbutanate, sulfooctadecenoic acid, sodium sulfooctadecenoic acid, sulfofatty acid, sodium sulfofatty acid, 2-sulfino- 1-octane sulfonic acid, 2- [cyclohexyl (1-oxohexadecyl) amino] -ethanesulfonic acid sodium, sodium hydroxide, chlorite, alkylnaphthalenesulfonic acid sodium, alkyldimethylnaphthalene sodium sulfonate, alkylmethylnaphthalenesulfonic acid Sodium, alkyltrimethylnaphthalenesulfonic acid sodium, ethanol, 2- (2-ethoxyethoxy) ethanol, ethylenediamine tetraacetic acid tetrasodium, ethylenediamine disodium tetraacetate, polyalkylene glycol, (ethylene-propylene) polyalkylene Glycolbutoxy monoether, chlorate, melamine chloride, ammonium chloride, oxybisdodecylbenzenesulfonic acid, oxyethyleneoxypropylene copolymer, oxyethylene jade Propylene copolymer, oxyethylene oxypropylene copolymer, oxychloro-based material, calcium octadecanoate, 1,2-octane disulfonic acid, octanoic acid, 1-octane sulfonic acid, sodium 1-octane sulfonic acid, octenylbutanedioic acid , Iodine, sodium iodine, potassium iodide, hydrous iodide, silver, chlorine dioxide, isocyanate dichloride, sodium isocyanate dichloride, sodium diocyanate dichloride, potassium diisocyanide dichloride, phosphoric acid, sodium phosphate, trisodium phosphate , Iodine, lactic acid, nitric acid, hypochlorous acid, sodium hypochlorite, lithium hypochlorite, potassium hypochlorite, calcium hypochlorite, acetic acid, n-carboxylic acid, coco fatty acid potassium, n-chloro-4-methyl benzenesulfonamide Sodium, sodium chloroacetate, chloramine T, chlorohexadine, 4,5-dihydro-2-undecyl-1H-imidazole-1-ethanol and sodium hydroxide, 4-chloro-2- (phenylmethyl)- Phenolic, Trimethylna Talylene, sodium sulfonate, α, α-trimethyl-3-cyclohexane-1-methanol, phenol, phenylphenol, methylphenol (cresol), polyalkylene glycol, (ethylene-propylene) butoxy monoether, polyethylene glycol mono Any one or more selected from the group consisting of laurate, polyethylene glycol, polypropylene glycol monobutyl ether, polyethylene glycol, polypropylene glycol n-alkyl ether, sulfuric acid is used.
상기한 살균소독제 중에서는 차아염소산나트륨, 차아염소산칼슘 등의 무기 염소계 화합물, 이염화이소시아눌산 나트륨과 같은 유기염소계 화합물 및 아염소산염, 이산화염소 등이 보다 편리하게 사용될 수 있다. 이외에 과산화수소, 과산화옥탄산, 과산화초산 등의 과산화물이나 페놀, 크레졸과 같은 페놀계 화합물, 알코올계 등의 화합물 등도 편리하게 사용된다.Among the disinfectant disinfectants, inorganic chlorine compounds such as sodium hypochlorite and calcium hypochlorite, organic chlorine compounds such as sodium isocyanate dichloride, chlorite, chlorine dioxide and the like can be used more conveniently. In addition, peroxides such as hydrogen peroxide, octanoic acid and acetic acid peroxide, phenolic compounds such as phenol and cresol, and compounds such as alcohols are also conveniently used.
보통 시판되는 살균소독제는 위에 열거한 살균소독제 중의 어느 한 성분으로 구성되기도 하지만, 대부분의 경우 보다 나은 살균소독 효과를 나타내기 위하여 여러 성분을 조합한 것이 많다. 따라서, 본 발명에서도 이러한 혼합 성분의 살균소독제를 이용하여도 무방하다. Commercially available disinfectant disinfectants may be composed of any one of the above-described disinfectant disinfectants, but in many cases, many components are combined to give a better disinfectant effect. Therefore, in this invention, you may use the disinfectant of these mixed components.
본 발명에서 향료는 화장실에서 발생하기 쉬운 냄새를 제거하고 향기를 발생시키는 용도로 사용되므로 일정한 향기를 가지는 물질은 대부분 사용가능하지만 변기세정액을 구성하는 나머지 물질과 상분리 현상을 일으키지 말아야 한다. 따라서 바람직하게는 수용성 향을 사용하는 것이 좋다.In the present invention, the fragrance is used to remove the odor that is likely to occur in the toilet and to generate a fragrance, so the substance having a certain fragrance can be used in most cases, but should not cause phase separation with the rest of the toilet constituent. Therefore, it is preferable to use water-soluble fragrance.
그러나, 오일 형태를 가지는 향이더라도 본 발명에서 사용한 계면활성제와 에멀전을 이룰수 있으므로 그 사용이 제한되는 것은 아니다. 따라서, 본 발명에서는 화장실에서 발생하는 악취를 제어할 수 있는 향료라면 제한 없이 사용 가능하다.However, even if the fragrance in the oil form can be an emulsion with the surfactant used in the present invention, its use is not limited. Therefore, the present invention can be used without limitation as long as the perfume can control the odor generated in the toilet.
아울러 본 발명에서는 변기세정액에 색소를 포함시키는데 이는 변기세정액이 충분히 공급되고 있음을 지시하는 역할을 할 뿐만 아니라 보다 청결한 느낌을 부여하는데 매우 유용하기 때문이다.In addition, the present invention includes a pigment in the toilet cleaning liquid, because it not only serves to indicate that the toilet cleaning liquid is sufficiently supplied, it is very useful to give a more clean feeling.
본 발명에서 사용하는 색소는 주로 식용색소로서 대한민국식품 공전에 규정 되어 있는 것이다. 여기에는 3-[Ｎ-에틸-Ｎ-[4-[[4-[Ｎ-에틸-Ｎ-(3-설포네이트벤질)아미노]페닐](4-히드록시-2-설포네이트페닐)메틸렌]-2,5-시클로헥사디에니리덴]암모니오메틸]벤젠설폰산이나트륨(식용색소 녹색 제3호), 3-[Ｎ-에틸-Ｎ-[4-[[4-[Ｎ-에틸-Ｎ-(3-설포벤질)아미노]페닐](4-히드록시-2-설포페닐)메틸렌]-2,5-시클로헥산디에닐리덴]암모니오메틸]벤젠설폰산(식용색소 녹색제3호 알루미늄레이크), 2-히드록시아조나프탈렌-3,4',6-트리설폰산삼나트륨(식용색소 적색 제2호), 2-히드록시아조나프탈렌-3,4',6-트리설폰산(식용색소 적색 제2호 알루미늄레이크), 2',4',5',7'-테트라요오드풀루오레세인이나트륨수화물(식용색소 적색 제3호), 6-히드록시-5[(2-메톡시-5-메틸-4-설포페닐)아조]-2-나프탈렌설폰산이나트륨(식용색소 적색 제40호), 6-히드록시-5-(2-메톡시-5-메틸-4-설포페닐아조)-2-나프탈렌설폰산(식용색소 적색 제40호 알루미늄레이크), 3-[Ｎ-에틸-Ｎ-[4-[[4-[Ｎ 에틸-Ｎ-(3-설포네이트벤질)아미노]페닐](2-설포네이트페닐)메틸렌]-2,5-클로헥사디에닐리덴]암모니오메틸]벤젠설폰산이나트륨(식용색소 청색 제1호), 3-[Ｎ-에틸-Ｎ-[4-[[4-[Ｎ-에틸-Ｎ-(3-설포벤질)아미노]페닐](2-설포페닐)메틸렌]-2,5-시클로헥사디에닐리덴]암모니오메틸]벤젠설폰산(식용색소 청색 제1호 알루미늄레이크), 3,3'-디옥소-2,2'-비인돌리덴-5,5'-디설폰산이나트륨(식용색소 청색 제2호), 3,3'-디옥소-2,2'-비인돌리덴-5,5'-디설폰산(식용색소 청색 제2호 알루미늄레이크), 3-카르보네이트-5-히드록시-1-(4-설포네이트페닐)-1H-피라졸-4-아조-4'-(벤젠설폰산)삼나트륨(식용색소 황색 제4호), 3-카르복시-5-히드록시-1-(4-설포페닐)1H-피라졸-4-아조-(4'-벤젠설폰산)(식용색소 황색 제4호 알루미늄레이크), 2-(히드록시-6-설포네이트나프탈 렌)-1-아조-(4'-벤젠설폰산)이나트륨(식용색소 황색 제5호), 2-히드록시-6-설포나프탈렌-1-아조-(4'-벤젠설폰산)(식용색소 황색 제5호 알루미늄레이크)가 있으며, 이들 군에서 선택되는 색소를 1종 이상을 사용한다.The pigments used in the present invention are mainly prescribed as food coloring in the Republic of Korea Food Code. These include 3- [N-ethyl-N- [4-[[4- [N-ethyl-N- (3-sulfonatebenzyl) amino] phenyl] (4-hydroxy-2-sulfonatephenyl) methylene] -2,5-cyclohexadieniidene] ammoniomethyl] benzenesulfonate disodium (edible colorant No. 3), 3- [N-ethyl-N- [4-[[4- [N-ethyl-N -(3-sulfobenzyl) amino] phenyl] (4-hydroxy-2-sulfophenyl) methylene] -2,5-cyclohexanedienylidene] ammoniomethyl] benzenesulfonic acid (edible colorant Green No. 3 Aluminum Lake), 2-hydroxyazonaphthalene-3,4 ', 6-trisulfonic acid trisodium (food coloring red No. 2), 2-hydroxyazonaphthalene-3,4', 6-trisulfonic acid (food coloring Red No. 2 Aluminum Lake), 2 ', 4', 5 ', 7'-tetraiod pullolesane disodium hydrate (edible pigment red No. 3), 6-hydroxy-5 [(2-methoxy- 5-methyl-4-sulfophenyl) azo] -2-naphthalenesulfonic acid disodium (food coloring red No. 40), 6-hydroxy-5- (2-methoxy-5-methyl-4-sulfophenylazo) 2-nap Talenesulfonic acid (edible color red No. 40 Aluminum Lake), 3- [N-ethyl-N- [4-[[4- [N ethyl-N- (3-sulfonatebenzyl) amino] phenyl] (2- Sulfonatephenyl) methylene] -2,5-chlorohexadienylidene] ammoniomethyl] benzenesulfonate disodium (edible color blue No. 1), 3- [N-ethyl-N- [4-[[4- [N-ethyl-N- (3-sulfobenzyl) amino] phenyl] (2-sulfophenyl) methylene] -2,5-cyclohexadienylidene] ammoniomethyl] benzenesulfonic acid (edible color blue No. 1 Aluminum lake), 3,3'-dioxo-2,2'-biindolene-5,5'-disulfonic acid disodium (food coloring blue No. 2), 3,3'-dioxo-2,2 '-Biindoleden-5,5'-disulfonic acid (edible blue No. 2 aluminum lake), 3-carbonate-5-hydroxy-1- (4-sulfonatephenyl) -1H-pyrazole- 4-Azo-4 '-(benzenesulfonic acid) trisodium (edible color yellow No. 4), 3-carboxy-5-hydroxy-1- (4-sulfophenyl) 1H-pyrazole-4-azo- ( 4'-benzenesulfonic acid) (edible color yellow No. 4 aluminium Lake), 2- (hydroxy-6-sulfonatenaphthalene) -1-azo- (4'-benzenesulfonate) disodium (edible color yellow No. 5), 2-hydroxy-6-sulfonaphthalene -1-azo- (4'-benzenesulfonic acid) (edible yellow yellow No. 5 aluminum lake), and at least one pigment selected from these groups is used.
본 발명의 변기세정액 조성물에는 높은 전도도를 가지는 물질을 포함시킴으로써 도 1에 도시한 형태의 전극형 센서(전극봉)가 변기 저수조의 수위 변화를 보다 용이하게 탐지하도록 한다.The toilet cleaning liquid composition of the present invention includes a substance having a high conductivity so that the electrode type sensor (electrode) of the type shown in FIG. 1 makes it easier to detect a change in the water level of the toilet bowl.
즉, 변기세정액 조성물에 높은 전도도를 가지는 물질로 소금(NaCl), 염화칼륨(KCl), 염화리튬(LiCl), 브롬화나트륨(NaBr), 브롬화칼륨(KBr), 브롬화리튬(LiBr), 염화칼슘(CaCl2), 황산나트륨(Na2SO4), 황산칼륨(K2SO 4), 황산칼슘(CaSO4), 황산마그네슘(MgSO4), 탄산나트륨(Na2CO3), 탄산수소나트륨(NaHCO3 ), 수산화암모늄, 수산화나트륨, 수산화칼슘, 수산화칼륨, 질산나트륨, 질산칼륨, 염산, 인산나트륨, 인산칼륨, 염소산나트륨, 차아염소산나트륨으로 구성되는 군에서 선택되는 어느 1종 이상을 전도도 증진제로 포함한다.That is, the material having high conductivity in the toilet cleaning composition is salt (NaCl), potassium chloride (KCl), lithium chloride (LiCl), sodium bromide (NaBr), potassium bromide (KBr), lithium bromide (LiBr), calcium chloride (CaCl 2 ), Sodium sulfate (Na 2 SO 4 ), potassium sulfate (K 2 SO 4 ), calcium sulfate (CaSO 4 ), magnesium sulfate (MgSO 4 ), sodium carbonate (Na 2 CO 3 ), sodium bicarbonate (NaHCO 3 ), hydroxide Any one or more selected from the group consisting of ammonium, sodium hydroxide, calcium hydroxide, potassium hydroxide, sodium nitrate, potassium nitrate, hydrochloric acid, sodium phosphate, potassium phosphate, sodium chlorate and sodium hypochlorite are included as conductivity enhancers.
본 발명의 변기세정액 조성물은 상기한 세제(계면활성제), 살균소독제, 향료, 색소, 전도도 증진제를 물에 용해시켜 제조하며, 이때 각 구성 성분의 조성 비율은 다음 표 1과 같다.Toilet bowl cleaning composition of the present invention is prepared by dissolving the detergent (surfactant), disinfectant disinfectant, fragrance, pigment, conductivity enhancer in water, wherein the composition ratio of each component is shown in Table 1.
상기 표 1에 나타낸 조성물은 액상으로서 도 1에 나타낸 세척액 통에 보관되며, 수세식 변기의 물을 1회 내릴 때마다 저수조내로 자동적으로 투입된다. 저수조 내로 유입된 상기 세정제는 전도도 증진제를 함유하고 있어 저수조 내부에 저장되는 물의 전도도를 높게 유지하는 역할을 한다.The composition shown in Table 1 is stored in the washing liquid container shown in Figure 1 as a liquid, it is automatically introduced into the reservoir every time the water of the flush toilet is lowered. The cleaning agent introduced into the reservoir contains a conductivity enhancer, thereby maintaining a high conductivity of the water stored in the reservoir.
사용자가 변기의 물을 내리면 전극봉(10-1, 10-2)은 저수조 내부에 수위 변화가 있음을 탐지하게 되는데, 이때 전극봉에 접하는 저수조 내부의 물이 높은 전도도를 가질수록 그 탐지가 용이하다.When the user flushes the toilet, the electrodes 10-1 and 10-2 detect that there is a water level change in the reservoir, where the water inside the reservoir in contact with the electrode has a high conductivity, so that the detection is easier.
본 발명의 변기세정액 조성물에는 증점제를 선택적으로 사용할 수 있다. 상기 증점제로는 카르복시메틸셀룰로오스(CMC, sodium carboxy methyl cellulose), 히드록시메틸셀룰로오스(HPMC, hydroxypropyl methyl cellulose), 히드록시에틸셀룰로오스(HEC, hydroxyethylcellulose), 히드록시프로필셀룰로오스(HPC, hydroxy propyl cellulose)과 같은 셀룰로오스 유도체 계통의 증점제, 구아검, 타피오카검, 알긴산, 카라기난(carrageenan) 등의 천연물 소재의 증점제가 가장 바람직하며, 폴리비닐알콜, 폴리비닐아크릴아마이드와 같은 수용성 고분자도 사용 가능하다.Thickeners may be optionally used in the toilet bowl cleaning composition of the present invention. The thickener includes carboxymethyl cellulose (CMC, sodium carboxy methyl cellulose), hydroxymethyl cellulose (HPMC, hydroxypropyl methyl cellulose), hydroxyethyl cellulose (HEC, hydroxyethylcellulose), hydroxypropyl cellulose (HPC, hydroxy propyl cellulose) and The thickeners of the same cellulose derivatives, such as guar gum, tapioca gum, alginic acid, carrageenan, and the like, are most preferred, and water-soluble polymers such as polyvinyl alcohol and polyvinyl acrylamide may be used.
상기한 증점제는 표 1에 나타낸 변기세정액 조성물 90 ∼ 99.95 중량%에 대하여 0.05 ∼ 10 중량%의 비율로 사용하며, 바람직하게는 0.1 ∼ 5 중량%의 범위에 서 사용한다.The thickener is used in a proportion of 0.05 to 10% by weight relative to 90 to 99.95% by weight of the toilet bowl cleaning composition shown in Table 1, preferably in the range of 0.1 to 5% by weight.
이하 다음 실시예를 통하여 본 발명을 보다 상세히 설명한다.Hereinafter, the present invention will be described in more detail with reference to the following examples.
[실시예 1] 변기세정액 조성물의 제조Example 1 Preparation of Toilet Bowl Cleaning Composition
다음 표 1과 같은 조성을 가지는 수용액을 제조하였다. 제조시 각 성분을 100L의 용량을 가지는 교반기에서 20분간 300rpm의 속도로 충분하게 교반하여 청색의 투명한 색상을 가지는 변기세정액 조성물을 제조하였다.Next, an aqueous solution having the composition shown in Table 1 was prepared. At the time of preparation, each component was sufficiently stirred at a speed of 300 rpm for 20 minutes in a stirrer having a capacity of 100 L to prepare a toilet cleaning composition having a blue transparent color.
[실시예 2] 점도가 증가된 변기세정액 조성물의 제조Example 2 Preparation of Toilet Bowl Liquid Composition with Increased Viscosity
실시예1에서 제조한 변기 세정액 조성물 95kg에 CMC 5kg을 혼합하여 매우 높은 점도(2000 CP)를 가지도록 하였다. 점도를 높인 변기세정액을 도 1에 나타낸 세척액 공급장치에 충전하고 실험한 결과, 점도를 높이지 않은 변기세정액과 점도를 높인 변기세정액 모두 일정량씩 공급되는데 아무런 문제점이 없었다.5 kg of CMC was mixed with 95 kg of the toilet bowl cleaning composition prepared in Example 1 to have a very high viscosity (2000 CP). As a result of filling and experimenting the toilet washing liquid with increased viscosity in the washing liquid supply device shown in Figure 1, there was no problem in supplying both the toilet washing liquid without increasing the viscosity and the toilet washing liquid with increasing viscosity by a predetermined amount.
[실시예 3] 전도도 증진제가 포함된 변기세정액 조성물과 일반 세정액의 비교 평가Example 3 Comparative Evaluation of Toilet Bowl Cleaning Composition Containing Conductivity Enhancer and General Cleaning Solution
전도도 증진제가 포함된 실시예1의 변기세정액과 통상적으로 시판되는 액체 비누를 도 1의 세척액 공급장치에 충전하고 작동 성능을 비교하였다. 그 결과 전도도 증진제가 포함된 변기세정액을 사용했을 경우에는 세척액 공급장치의 오동작이 없었으나, 일반 액체 비누는 평균 10회당 5회의 오동작을 발생시켰다.The toilet bowl cleaning liquid of Example 1 including a conductivity enhancer and a commercially available liquid soap were charged to the washing liquid supply device of FIG. 1 and the operating performance was compared. As a result, there was no malfunction of the cleaning liquid supply device when the toilet cleaning solution containing the conductivity enhancer was used. However, the average liquid soap generated five malfunctions every 10 times.
본 발명의 변기세정액은 전도도가 높은 물질 포함하는 것을 특징으로 하는 것으로서, 통상적으로 사용되는 액체 비누에 비하여 세정액 자동 공급장치의 센서에서 보다 용이하게 검출된다. Toilet bowl cleaning liquid of the present invention is characterized in that it contains a high conductivity material, it is more easily detected by the sensor of the automatic cleaning liquid supply device than the liquid soap used in general.
따라서 본 발명의 변기세정액은 저수조 내부의 수위변화를 전극형 센서로 탐지하여 자동적으로 세정액을 공급하는 장치에 사용되었을 경우, 통상적인 액체 비누에 비하여 그 장치의 동작을 확실히 할 수 있는 효과가 있다.Therefore, when the toilet cleaning liquid of the present invention is used in a device that detects the water level change in the reservoir with an electrode type sensor and automatically supplies the cleaning liquid, the toilet cleaning liquid has an effect of ensuring the operation of the apparatus as compared to a conventional liquid soap.
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| KR100865979B1 (en) * | 2007-08-08 | 2008-10-29 | 강경종 | Disinfectant lime composition and its preparing method |
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| KR100865979B1 (en) * | 2007-08-08 | 2008-10-29 | 강경종 | Disinfectant lime composition and its preparing method |
| CN102449132B (en) * | 2009-05-26 | 2015-01-07 | 德乐福控股公司 | Chlorinated alkaline pipeline cleaner with methane sulfonic acid |
| WO2010138518A3 (en) * | 2009-05-26 | 2011-02-24 | Delaval Holding Ab | Chlorinated alkaline pipeline cleaner with methane sulfonic acid |
| CN102449132A (en) * | 2009-05-26 | 2012-05-09 | 德乐福控股公司 | Chlorinated alkaline pipeline cleaner with methane sulfonic acid |
| US9994799B2 (en) | 2012-09-13 | 2018-06-12 | Ecolab Usa Inc. | Hard surface cleaning compositions comprising phosphinosuccinic acid adducts and methods of use |
| US9670434B2 (en) | 2012-09-13 | 2017-06-06 | Ecolab Usa Inc. | Detergent composition comprising phosphinosuccinic acid adducts and methods of use |
| US9752105B2 (en) | 2012-09-13 | 2017-09-05 | Ecolab Usa Inc. | Two step method of cleaning, sanitizing, and rinsing a surface |
| US10358622B2 (en) | 2012-09-13 | 2019-07-23 | Ecolab Usa Inc. | Two step method of cleaning, sanitizing, and rinsing a surface |
| US10377971B2 (en) | 2012-09-13 | 2019-08-13 | Ecolab Usa Inc. | Detergent composition comprising phosphinosuccinic acid adducts and methods of use |
| US11001784B2 (en) | 2012-09-13 | 2021-05-11 | Ecolab Usa Inc. | Detergent composition comprising phosphinosuccinic acid adducts and methods of use |
| US11053458B2 (en) | 2012-09-13 | 2021-07-06 | Ecolab Usa Inc. | Hard surface cleaning compositions comprising phosphinosuccinic acid adducts and methods of use |
| US11859155B2 (en) | 2012-09-13 | 2024-01-02 | Ecolab Usa Inc. | Hard surface cleaning compositions comprising phosphinosuccinic acid adducts and methods of use |
| US11952556B2 (en) | 2012-09-13 | 2024-04-09 | Ecolab Usa Inc. | Detergent composition comprising phosphinosuccinic acid adducts and methods of use |
| KR101440375B1 (en) * | 2012-12-05 | 2014-09-17 | 주식회사 우성양행 | Disinfectant with synergistic effect and method for manufacturing thereof |
| US11865219B2 (en) | 2013-04-15 | 2024-01-09 | Ecolab Usa Inc. | Peroxycarboxylic acid based sanitizing rinse additives for use in ware washing |
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