KR20060042288A - A metallic yarn film coated uv-curing resin - Google Patents
A metallic yarn film coated uv-curing resin Download PDFInfo
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Abstract
본 발명은 폴리에틸렌 테레프탈레이트와 같은 박막의 필름의 상하부에 자외선 경화형 수지가 코팅된 금은사 필름에 관한 것으로, 장식용으로 사용되는 얇은 박막의 필름층(10); 및 상기 필름층(10)의 상하부에는, 올리고머 40~70 중량부, 반응성 모노머 20~60 중량부, 광개시제 0.1~10 중량부, 기타 첨가제 0~5 중량부를 포함하는 자외선경화형 수지조성물로 코팅된 코팅층(20);으로 구성되는 것을 특징으로 한다. 본 발명에 따른 금은사 필름은 내열성, 내 알카리성, 부착성, 내 약품성이 우수하여 열경화성 수지에 비하여 우수한 물성 효과를 기대할 수 있으며 휘발성 유기 화합물의 사용량이 적고 포름알데히드를 전혀 사용하지 않아 환경친화적인 장점이 있다.The present invention relates to a gold and silver yarn film coated with an ultraviolet curable resin on the upper and lower portions of a thin film of polyethylene terephthalate, such as a thin film layer (10) used for decoration; And coating layers coated with an ultraviolet curable resin composition including 40 to 70 parts by weight of oligomer, 20 to 60 parts by weight of reactive monomer, 0.1 to 10 parts by weight of photoinitiator, and 0 to 5 parts by weight of other additives on the upper and lower parts of the film layer 10. 20, characterized in that consisting of. Gold and silver yarn film according to the present invention is excellent in heat resistance, alkali resistance, adhesiveness, chemical resistance can be expected excellent physical properties compared to the thermosetting resin, and the amount of volatile organic compounds used less formaldehyde is not used at all environmentally friendly advantages There is this.
자외선, 경화, 금은사, 내후성, UV, 장식UV, hardening, gold silver yarn, weather resistance, UV, decoration
Description
도 1은 본 발명의 일 실시예에 따른 자외선 경화형 수지가 코팅된 금은사 필름의 구성도이다.1 is a block diagram of a gold silver yarn film coated with an ultraviolet curable resin according to an embodiment of the present invention.
* 도면의 주요 부분에 대한 부호 설명* Explanation of symbols on the main parts of the drawing
10 : 필름층10: film layer
20 : 코팅층20: coating layer
본 발명은 금은사 필름에 관한 것으로, 보다 상세하게는 폴리에틸렌 테레프탈레이트와 같은 박막의 필름의 상하부에 자외선 경화형 수지가 코팅된 금은사 필름에 관한 것이다.The present invention relates to a gold silver yarn film, and more particularly to a gold silver yarn film coated with an ultraviolet curable resin on the upper and lower portions of a thin film such as polyethylene terephthalate.
일반적인 금은사 제품은 폴리에틸렌 테레프탈레이트, 폴리에틸렌 등과 같은 필름에, 적절한 광택과 색깔, 내후성, 내화학성 및 기타 원하는 물성을 나타낼 수 있는 코팅재를 이용하여 필름에 코팅을 하여 제조되는 바, 이것을 가늘게 절사하여 반짝이는 색사를 제조하기도 하고 섬유와 함께 사용하여 원하는 색깔과 물성을 지닌 제품을 제조하기도 한다. Common gold and silver products are manufactured by coating a film such as polyethylene terephthalate, polyethylene, etc. using a coating material that can exhibit appropriate gloss and color, weather resistance, chemical resistance and other desired physical properties. Some companies produce color yarns or use them with fibers to produce products with the desired color and properties.
금은사 필름의 코팅재로 사용되는 열경화성수지를 일정온도에 노출시켜 경화시키는 기존의 방식과 달리, 본 발명은 자외선 경화형 도료 조성물을 이용하여 높은 온도를 요하지 않고도 원하는 물성의 제품을 얻을 수 있다.Unlike conventional methods of curing a thermosetting resin used as a coating material for gold and silver yarns at a predetermined temperature, the present invention can obtain a product having a desired physical property without requiring a high temperature by using an ultraviolet curable coating composition.
종래의 코팅 방법은 에폭시, 우레탄, 멜라민 등의 수지를 이용하여 다량의 휘발성 유기 화합물이 들어 있는 용제를 사용하여 180℃ 이상의 고온에서 수초간 노출시켜 경화시키는 방식을 사용하였다.In the conventional coating method, a resin containing epoxy, urethane, melamine or the like is used to harden by exposing for several seconds at a high temperature of 180 ° C. or more using a solvent containing a large amount of volatile organic compounds.
이와 같이 코팅한 제품을 가늘게 절사하여 색사 또는 금은사를 제조함으로써 이들은 각종 장식품 또는 반짝이는 효과를 내는 제품에 사용되기도 하며 섬유와 함께 가공하여 의류, 화장품, 장식용 등의 여러 가지 생활 용품에 사용되기도 한다.By finely cutting the coated products to manufacture colored yarn or gold and silver yarn, they are used for various ornaments or products that produce glittering effects. They can also be processed with textiles and used in various household goods such as clothing, cosmetics, and decorative products. .
상기와 같은 종래의 방법에 의하여 제조된 금은사 제품은 열에 의해 수축 및 변형이 일어나 필름의 두께가 12㎛ 미만이 되는 얇은 필름은 사용할 수 없으므로 생산 효율이 떨어지는 문제점이 있었다. 그리고, 다량의 포름알데히드와 휘발성 유기화합물을 사용함으로써 제조 과정과 도장 과정에서 환경호르몬이나 발암물질을 유출시키는 문제점을 안고 있었다.The gold and silver product manufactured by the conventional method as described above has a problem in that production efficiency is lowered because a thin film having a thickness of less than 12 μm due to shrinkage and deformation due to heat cannot be used. In addition, by using a large amount of formaldehyde and volatile organic compounds, there was a problem of spilling environmental hormones or carcinogens during the manufacturing process and coating process.
본 발명은 상기와 같은 문제점을 해결하기 위하여 창작된 것으로서, 본 발명의 목적은 금은사용 필름코팅을 하는데 있어 자외선 경화형 수지 조성물을 이용하여 기존의 열경화성 코팅재의 코팅 작업시 문제점을 해결하고 다량의 열을 발생하지 않으면서도 휘발성 유기화합물의 사용을 최소화시킬 수 있는 금은사 필름을 제공하는 것이다.The present invention was created to solve the above problems, an object of the present invention is to solve the problem of coating work of the conventional thermosetting coating material using a UV-curable resin composition in the film coating using gold and silver and a large amount of heat It is to provide a gold and silver yarn film that can minimize the use of volatile organic compounds without generating.
상기와 같은 본 발명의 목적은 장식용으로 사용되는 얇은 박막의 필름층(10); 및 상기 필름층(10)의 상하부에는, 올리고머 40~70 중량부, 반응성 모노머 20~60 중량부, 광개시제 0.1~10 중량부, 기타 첨가제 0~5 중량부를 포함하는 자외선경화형 수지조성물로 코팅된 코팅층(20);으로 구성되는 것을 특징으로 하는 자외선 경화형 수지가 코팅된 금은사 필름에 의하여 달성된다.An object of the present invention as described above is a
본 발명의 그 밖의 목적, 특정한 장점 및 신규한 특징들은 첨부된 도면들과 연관되어지는 이하의 발명의 상세한 설명과 바람직한 실시예로부터 더욱 분명해질 것이다.
Other objects, specific advantages, and novel features of the present invention will become more apparent from the following detailed description of the invention and the preferred embodiments in connection with the accompanying drawings.
이하에서는 본 발명에 따른 자외선 경화형 수지가 코팅된 금은사 필름의 구성에 대하여 설명하기로 한다. Hereinafter, the configuration of the gold-silver yarn film coated with an ultraviolet curable resin according to the present invention will be described.
도 1은 본 발명의 일 실시예에 따른 자외선 경화형 수지가 코팅된 금은사 필름의 구성도이다. 도 1에 도시된 바와 같이, 금은사 필름은 필름층(10)과 상기 필름층(10)의 상부와 하부에 코팅된 코팅층(20)으로 구성된다.1 is a block diagram of a gold silver yarn film coated with an ultraviolet curable resin according to an embodiment of the present invention. As shown in FIG. 1, the gold and silver yarn film includes a
상기 필름층(10)은 폴리에틸렌 테레프탈레이트, 나일론, 폴리프로필렌, 폴리에틸렌, 폴리비닐 클로라이드 필름 등을 사용한다.The
상기 코팅층(20)은 올리고머 40~70 중량부, 반응성 모노머 20~60 중량부, 광개시제 0.1~10 중량부 및 기타 첨가제 0~5 중량부로 구성된다.The
상기 올리고머는 우레탄 아크릴레이트, 에폭시 아크릴레이트, 아크릴릭 아크릴레이트, 멜라민 아크릴레이트, 폴리 에스터 아크릴레이트, 실리콘 아크릴 레이트, 폴리이서 아크릴레이트, 수계 올리고머로 이루어진 군으로부터 하나 이상을 사용한다.The oligomer uses at least one from the group consisting of urethane acrylate, epoxy acrylate, acrylic acrylate, melamine acrylate, polyester acrylate, silicone acrylate, polyacer acrylate, aqueous oligomer.
올리고머의 중량부가 40 미만에서는 내후성 및 내용제성이 약해지고 70 초과시에는 증착면과 필름과의 접합력을 약하게 만들어서 도막이 증착면과 함께 떨어지는 현상이 발생하게 된다.If the weight part of the oligomer is less than 40, weather resistance and solvent resistance are weak, and if it is more than 70, the adhesion between the deposition surface and the film is weakened, so that the coating film falls with the deposition surface.
상기 반응성 모노머는 2-에틸 헥실 아크릴레이트, 트릴데실메타크릴레이트, 노닐페놀에톡시레이트 모노아크릴레이트, 베타-카르복시에틸 아크릴레이트, 이소보닐 아크릴레이트, 테트라하이드로퍼푸릴 아크릴레이트, 테트라하이드로퍼푸릴 메타크릴레이트, 4-부틸싸이크로 헥실 아크릴레이트, 다싸이크로 펜테닐 아크릴레이트, 디싸이크로 펜테닐 옥시 에틸 아크릴레이트, 에톡시에톡시 에틸 아크릴레이트, 에 톡시레이티드모노아크릴레이트로 이루어진 단관능 모노머 군으로부터 하나 이상 선택된 것을 사용할 수 있다.The reactive monomers are 2-ethyl hexyl acrylate, trilydecyl methacrylate, nonylphenolethoxylate monoacrylate, beta-carboxyethyl acrylate, isobornyl acrylate, tetrahydroperfuryl acrylate, tetrahydrofurfuryl meta Monofunctional monomers consisting of acrylate, 4-butylcyclohexyl acrylate, dacyclopentenyl acrylate, dicyclopentenyl oxy ethyl acrylate, ethoxyethoxy ethyl acrylate, ethoxylated monoacrylate One or more selected from the group can be used.
또한, 상기 반응성 모노머는 1,6-헥산디올 디아크릴레이트, 트리페닐 글리콜 디아크릴레이트, 부탄디올디아크릴레이트, 1,3-부틸렌글리콜 디메타크릴레이트, 1,6-헥산디올 디메타크릴레이트, 네오펜틸 글리콜 디아크릴레이트, 에틸렌글리콜, 디트리메틸 올프로판 테트라아크릴레이트, 알콕시레이티드 테트라 아크릴레이트로 이루어진 다관능 모노머 군으로부터 하나 이상 선택된 것을 사용할 수 있다.In addition, the reactive monomer is 1,6-hexanediol diacrylate, triphenyl glycol diacrylate, butanediol diacrylate, 1,3-butylene glycol dimethacrylate, 1,6-hexanediol dimethacrylate And at least one selected from the group of polyfunctional monomers consisting of neopentyl glycol diacrylate, ethylene glycol, ditrimethyl allpropane tetraacrylate, and alkoxylated tetra acrylate.
반응성 모너머는 20 미만의 중량부에서는 증착면을 약하게 만들면서 경화 시간이 길어지고, 60 초과시에는 수축현상이 일어나 부착력이 감소하게 된다. In the reactive monomer, the curing time is long while weakening the deposition surface at less than 20 parts by weight, and when it is more than 60, shrinkage occurs to decrease the adhesion.
상기 광개시제는 벤조페논계, 벤질 디메틸 케탈계, 아세토페논계, 아드라퀴논계, 벤질 케탈계 등의 2-하이드록시 1,2-디퍼페닐 에타논, 2-에톡시 1,2 디페닐 에타논, 이소프로필 1,2-페닐에타논, 2-부톡시 1,2-디페닐 에타논, 2-이소부톡시 1,2-디페닐 에타논, 2,2-디메톡시 1,2-디페닐에타논, 비스(2,4,6-트리메틸 벤조일)-페닐포스핀옥사이드로 이루어진 군으로부터 하나 이상 선택된 것을 사용할 수 있다.The photoinitiator is 2-hydroxy 1,2-diperphenyl ethanone, 2-ethoxy 1,2 diphenyl ethanone such as benzophenone series, benzyl dimethyl ketal series, acetophenone series, adraquinone series, benzyl ketal series, etc. To isopropyl 1,2-phenylethanone, 2-butoxy 1,2-diphenyl ethanone, 2-isobutoxy 1,2-diphenyl ethanone, 2,2-dimethoxy 1,2-diphenyl One or more selected from the group consisting of tanone, bis (2,4,6-trimethyl benzoyl) -phenylphosphine oxide can be used.
광개시제는 0.1 미만의 중량부에서는 경화가 이루어지지 않으며 10 초과시에는 도막을 구성하는 고분자 사슬의 길이가 짧아지고 분자량이 낮아지며 미반응 개시제가 남아 물성을 저하시킨다.The photoinitiator is not cured at less than 0.1 part by weight, and when it is more than 10, the length of the polymer chain constituting the coating film is shortened, the molecular weight is low, and the unreacted initiator remains to deteriorate the physical properties.
첨가제는 레벨링제나 소광제, 슬립제 등의 일반 코팅에서 사용하는 첨가제를 사용한다.As the additive, additives used in general coatings such as leveling agents, matting agents and slip agents are used.
표 1에서는 종래에 사용하고 있는 열경화성 금은사필름과 본 발명에 따른 UV경화형 금은사필름을 비교하였는 바, 본 실시예에서는 포름알데히드는 사용되지 않았으며 비교예에 비하여 유기용제도 소량만을 사용하였다. 비교예에 따른 금은사필름은 필름의 두께가 12㎛ 미만일 경우 열에 수축 변형되어 제품을 사용할 수 없었으나, 본 발명에 따른 실시예에서는 필름의 두께가 6㎛ 이하인 경우에도 내열성 및 내후성이 강한 특징이 있었다.In Table 1, a conventional thermosetting gold silver yarn film and a UV-curable gold silver yarn film according to the present invention were compared. In this embodiment, no formaldehyde was used and only a small amount of an organic solvent was used as compared to the comparative example. The gold and silver yarn film according to the comparative example was not deformable due to heat shrinkage when the film thickness is less than 12㎛, but in the embodiment according to the present invention, even when the thickness of the film is 6㎛ or less is characterized by strong heat resistance and weather resistance there was.
상기 언급한 바와 같은 본 발명에 따른 자외선 경화형 수지가 코팅된 금은사 필름은 내열성, 내 알카리성, 부착성, 내 약품성이 우수하여 열경화성 수지에 비하여 우수한 물성 효과를 기대할 수 있으며 휘발성 유기 화합물의 사용량이 적고 포름알데히드를 전혀 사용하지 않아 환경친화적인 장점이 있다.As mentioned above, the gold-silver yarn film coated with the ultraviolet curable resin according to the present invention is excellent in heat resistance, alkali resistance, adhesiveness, and chemical resistance, and thus, excellent physical properties can be expected compared to thermosetting resins, and the amount of volatile organic compounds used is small. It does not use formaldehyde at all and has an environmentally friendly advantage.
비록 본 발명에 상기 언급된 바람직한 실시예와 관련하여 설명되어졌지만, 발명의 요지와 범위로부터 벗어남이 없이 다양한 수정이나 변형을 하는 것이 가능하다. 따라서 첨부된 특허청구범위는 본 발명의 요지에 속하는 이러한 수정이나 변형을 포함한다.Although described in connection with the preferred embodiments mentioned above in the present invention, it is possible to make various modifications or variations without departing from the spirit and scope of the invention. Accordingly, the appended claims include such modifications and variations as fall within the spirit of the invention.
Claims (6)
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| KR1020040090884A KR20060042288A (en) | 2004-11-09 | 2004-11-09 | A metallic yarn film coated uv-curing resin |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100731209B1 (en) * | 2006-04-14 | 2007-06-22 | 주식회사 유니테크 | Coating composition for ultraviolet curing and accessory ornaments using the same |
| CN101382727B (en) * | 2007-09-04 | 2011-06-08 | 四川大学 | Optical heat sensitive material, method for making same and optical device composed thereby |
| WO2016043496A1 (en) * | 2014-09-18 | 2016-03-24 | 주식회사 소포스 | Method for high fastness dyeing of fibrous yarn employing uv curing |
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2004
- 2004-11-09 KR KR1020040090884A patent/KR20060042288A/en not_active Application Discontinuation
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100731209B1 (en) * | 2006-04-14 | 2007-06-22 | 주식회사 유니테크 | Coating composition for ultraviolet curing and accessory ornaments using the same |
| CN101382727B (en) * | 2007-09-04 | 2011-06-08 | 四川大学 | Optical heat sensitive material, method for making same and optical device composed thereby |
| WO2016043496A1 (en) * | 2014-09-18 | 2016-03-24 | 주식회사 소포스 | Method for high fastness dyeing of fibrous yarn employing uv curing |
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