KR20050079205A - Manufacture of gac composite non-woven filter with three dimensional structure - Google Patents
Manufacture of gac composite non-woven filter with three dimensional structure Download PDFInfo
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- KR20050079205A KR20050079205A KR1020040007387A KR20040007387A KR20050079205A KR 20050079205 A KR20050079205 A KR 20050079205A KR 1020040007387 A KR1020040007387 A KR 1020040007387A KR 20040007387 A KR20040007387 A KR 20040007387A KR 20050079205 A KR20050079205 A KR 20050079205A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/02—Loose filtering material, e.g. loose fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/14—Other self-supporting filtering material ; Other filtering material
- B01D39/16—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres
- B01D39/1607—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous
- B01D39/1623—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous of synthetic origin
- B01D39/163—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous of synthetic origin sintered or bonded
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H13/00—Other non-woven fabrics
- D04H13/001—Making non-woven fabrics from staple fibres, filaments or yarns, bonded to at least one web-like material, e.g. woven, knitted non-woven fabric, paper, leather, during consolidation
- D04H13/007—Making non-woven fabrics from staple fibres, filaments or yarns, bonded to at least one web-like material, e.g. woven, knitted non-woven fabric, paper, leather, during consolidation strengthened or consolidated by welding together the various components
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
- D04H3/16—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B1/00—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating
- D06B1/02—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating by spraying or projecting
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
- B01D2239/04—Additives and treatments of the filtering material
- B01D2239/045—Deodorising additives
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
- B01D2239/06—Filter cloth, e.g. knitted, woven non-woven; self-supported material
- B01D2239/0604—Arrangement of the fibres in the filtering material
- B01D2239/0618—Non-woven
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
- B01D2239/06—Filter cloth, e.g. knitted, woven non-woven; self-supported material
- B01D2239/0604—Arrangement of the fibres in the filtering material
- B01D2239/0622—Melt-blown
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
- B01D2239/06—Filter cloth, e.g. knitted, woven non-woven; self-supported material
- B01D2239/0604—Arrangement of the fibres in the filtering material
- B01D2239/0627—Spun-bonded
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
- B01D2239/06—Filter cloth, e.g. knitted, woven non-woven; self-supported material
- B01D2239/0604—Arrangement of the fibres in the filtering material
- B01D2239/0631—Electro-spun
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2505/00—Industrial
- D10B2505/04—Filters
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Nonwoven Fabrics (AREA)
- Filtering Materials (AREA)
Abstract
본 발명은 고성능 입상활성탄(Granular activated carbon : GAC)의 악취 및 유해가스 흡착 효율특성과 방사원리에 의해 형성되는 섬유 집합체인 부직포의 고효율의 여과특성을 동시에 갖도록 구성된 GAC부착 복합 부직포 필터 제품의 제조공정과 GAC 공급장치에 관한 것이다.The present invention is a manufacturing process of a composite nonwoven filter product with a GAC configured to have both high-efficiency odor and harmful gas adsorption efficiency characteristics of granular activated carbon (GAC) and high-efficiency filtration characteristics of the nonwoven fabric, which is a fiber assembly formed by the radiation principle. And a GAC supply.
이러한 발명은 방사원리를 이용한 부직포 제조공정에서 노즐을 통해 방사되는 섬유에 GAC의 투입과정이 동시에 이루어지며 GAC를 열적 결합 방법을 이용하여 웹 형성시 균일한 분포의 점접착 결합방식에 의한 3차원구조의 특성을 갖도록 하고, 또한 GAC 복합 부직포 필터 제품의 제조공정에서 부직포 제조공정과 GAC 공급장치를 동시에 구비시킨 것을 특징으로 한다.In the invention, the process of injecting GAC into the fiber spun through the nozzle is made at the same time in the nonwoven fabric manufacturing process using spinning principle. In the manufacturing process of the GAC composite nonwoven filter product, and characterized in that the non-woven fabric manufacturing process and the GAC supply device at the same time.
Description
대기중의 미세 먼지나 악취, 유독성 가스 등의 제거 및 포집을 위한 여과재는 다양하게 제작되고 있으며, 성능향상을 위하여 새로운 제조방법의 연구가 계속되고 있다.Filter media for removing and collecting fine dust, odors, and toxic gases in the air have been produced in various ways, and researches on new manufacturing methods have been conducted to improve performance.
최근에는 미세다공질의 활성탄(Activated carbon)에 의한 흡착특성, 악취제거특성 등을 이용한 복합 건식필터가 많이 제조되고 있다. 활성탄의 종류에는 분말카본(Carbon powder), 입상활성탄(Granular activated carbon : GAC), ACF(Activated carbon fiber) 등이 있으며, 필터용으로 가장 좋은 특성을 갖는 GAC가 주로 사용되고 있다.Recently, many composite dry filters using adsorption characteristics, odor removal characteristics, and the like by microporous activated carbon have been manufactured. Types of activated carbon include carbon powder, granular activated carbon (GAC), and activated carbon fiber (ACF), and GAC having the best characteristics for filters is mainly used.
필터용 부직포의 제조공정은 니들펀칭 제조법, 스펀본드 제조법, 멜트블론 제조법 등이 있다. 현재까지는 제조방법이 비교적 간단하며 국내 생산 대수가 가장 많은 니들펀칭 제조법이 증가하고 있는 추세이다. 이러한 건식 부직포 필터는 제품의 형태에 따라 그림 1∼3과 같이 구분될 수 있다. 그림 1은 서로 다른 특성을 갖는 부직포의 적층에 의한 건식필터로써 차압이 높고 여과효율이 낮은 단점이 있다. 그림 2는 기능성 부직포들과 활성탄 입자 등과의 적층 형태로서 활성탄 층의 형태유지를 위해 접착제(그림에서 검은점으로 표시)가 사용되고 있다. 사용된 접착제는 일부 활성탄의 미세다공을 막게되어 그 효율이 급격히 감소하며, 장기간 보관시 접착제의 변성에 의해 특유의 악취가 발생하는 단점이 있다.The manufacturing process of the filter nonwoven fabric includes a needle punching manufacturing method, a spunbond manufacturing method, a meltblown manufacturing method, and the like. To date, the manufacturing method is relatively simple and the needle punching manufacturing method with the largest domestic production is increasing. Such dry nonwoven filters can be classified as shown in Figs. Figure 1 is a dry filter by laminating nonwoven fabrics with different characteristics, which has the disadvantage of high differential pressure and low filtration efficiency. Figure 2 is a stack of functional nonwoven fabrics and activated carbon particles, and adhesives (indicated by black dots in the figure) are used to maintain the shape of the activated carbon layer. The adhesive used has the disadvantage of blocking the micropores of some activated carbons, the efficiency of which is dramatically reduced, and a characteristic odor due to the modification of the adhesive during long term storage.
그림 3은 접착제를 사용하지 않고 부직포의 해면체 입체구조에 의해 활성탄을 고정한 것으로서 높은 효율과 낮은 차압을 갖으며, 취급의 용이성과 다양한 기능성 GAC 사용이 가능하고, 여과면적을 최대로 하기 위한 절곡필터(pleated filter media)의 생산이 용이하다.Figure 3 shows the activated carbon fixed by the spongy structure of the nonwoven fabric without using the adhesive. It has high efficiency and low differential pressure. It is easy to handle and can use various functional GACs, and it is a bending filter for maximizing the filtration area. The production of pleated filter media is easy.
기존의 이러한 3차원 구조의 부직포 필터 제조방법은 그림 4 및 5와 같다. 그림 4는 국내와 중국, 대만 등에서 생산되는 제조방법으로 소면(carding)공정 후에 웹(web) 상태에서 GAC를 도포한 후 니들펀칭하여 생산하는 방식으로 부직포의 구조상 기공도가 커서 GAC의 위치안정성이 극히 적어 취급상의 어려움이 많고, GAC의 최대 충진밀도가 낮아 높은 효율의 제품생산이 어렵다.The conventional nonwoven filter manufacturing method of the three-dimensional structure is shown in Figures 4 and 5. Figure 4 is a manufacturing method produced in Korea, China, Taiwan, etc. It is produced by applying needle punching after applying GAC in web state after carding process. Due to the extremely small handling difficulty, and the maximum filling density of the GAC is low, it is difficult to produce high efficiency products.
그림 5는 최근에 미국에서 개발된 제조방식으로 저융점의 표면(sheath) 구조와 고융점의 심부(core) 구조를 갖는 이중구조 섬유(biocomponent fiber)와 GAC의 도포후에 열과 압력을 가해 섬유-섬유간, 섬유-GAC간의 열접착(thermal bondig)에 의해 필터여재를 제조하는 방법이다. 이는 사용원료의 가격이 매우 높아 가격경쟁력이 매우 낮고, 단섬유를 사용하므로 열과 압력을 가해 접착하여야하며 이로인해 필터의 유연성과 굽힘특성이 낮아진다. 또한 GAC에 의한 포집효율이 크게 작용하고 부직포의 분리효율이 거의 없어 전체적인 필터효율이 낮아진다.Figure 5 shows a recently developed manufacturing method in the United States, in which a bicomponent fiber having a low melting point sheath structure and a high melting point core structure and heat-pressure are applied after application of a GAC. It is a method of manufacturing a filter medium by thermal bonding between fibers and fiber-GAC. This is because the price of raw material is very high, the price competitiveness is very low, and short fiber is used, so it must be bonded by applying heat and pressure, which lowers the flexibility and bending characteristics of the filter. In addition, the collection efficiency by GAC acts greatly, and the separation efficiency of the nonwoven fabric is virtually low, resulting in low overall filter efficiency.
GAC를 포함한 3차원 구조의 복합 부직포 필터 제조에는 다음과 같은 문제점이 있다. ① 대부분의 부직포의 제조공정과 GAC의 도포공정을 동시에 한 공정에서 처리할 수가 없고, ② GAC의 외관이 둥글고 크기분포가 다양해서 일반적인 부직포 내에서는 위치안정성이 없어 취급이 어렵고, ③ 이를 보정하기 위해 접착제를 사용하면 필터효율이 급격히 떨어지게 된다.The manufacturing of a composite nonwoven filter having a three-dimensional structure including a GAC has the following problems. ① Most nonwoven fabric manufacturing process and GAC coating process cannot be processed at the same time. ② GAC's round appearance and various size distribution make it difficult to handle in general nonwoven fabrics. The use of adhesives can drastically reduce the filter efficiency.
따라서 본 발명의 목적은 방사원리를 이용한 부직포 제조공정에서 웹 형성시 GAC의 투입방법에 의해 상기의 문제점이 해결될 수 있으며, 다양한 GAC 충진밀도와 초극세섬유의 조합에 의해서 효율이 높고, 취급성과 절곡성이 용이한 기능성 부직포 필터 제품의 생산이 가능하도록 새로운 제조공정에 관한 기술을 제공하는 것이다.Therefore, the object of the present invention can be solved by the method of adding the GAC when forming the web in the nonwoven fabric manufacturing process using the spinning principle, high efficiency by the combination of various GAC filling density and ultra-fine fibers, handling and cutting It is to provide a technology for a new manufacturing process to enable the production of functional nonwoven filter products with easy bending.
도 3은 방사원리를 이용한 부직포 제조와 GAC의 투입과정이 동시에 이루어지며 3차원 구조를 갖는 필터제품의 제조공정을 도식화 한 것으로, 주요공정은 방사구간(16), 연신 및 냉각구간(17), 웹 적층구간(18)과 GAC 공급장치(10)에 의한 투입구간으로 구성된다.3 is a diagram illustrating a manufacturing process of a nonwoven fabric using a spinning principle and a GAC input process at the same time, and a filter product having a three-dimensional structure. The main processes include a spinning section 16, a drawing section and a cooling section 17, It consists of a web lamination section 18 and the input section by the GAC supply device 10.
그리고 본 발명에서 가장 중요한 섬유의 나선형 운동(spiral action)은 연신/냉각 구간(17)과 웹 적층구간(18)의 경계에서 가장 높게 발생된다. 각 구간별 제조기술은 다음과 같다.And the most important spiral action of the fiber in the present invention occurs at the boundary between the stretching / cooling section 17 and the web stacking section 18. The manufacturing technology for each section is as follows.
1. 방사구간(16) : 스핀팩에 도달된 용융수지(20)는 필터를 통과하여 노즐(4)에서 고압으로 방사되며, 에어플레이트(5)를 통해 고온·고압의 에어(6)는 필터제조에 중요한 인자가 된다.1. Spinning section 16: The molten resin 20 reaches the spin pack is passed through the filter is radiated at a high pressure from the nozzle (4), the high temperature and high pressure air (6) through the air plate (5) is a filter It is an important factor in manufacturing.
2. 연신 및 냉각구간(17) : 방사된 수지는 고속기류(air-jet)에 의해 길이방향으로 급격히 연신되고, 일정구간 이후에는 속도의 감소로 나선운동(21)을 하게된다. 나선운동(21)은 부직포로 적층시에 3차원 구조를 갖게 하며, 이 구간에서 온도조절된 GAC가 균일한 분포로 분사되어 부직포에 투입된다. 즉, 섬유상에 분사된 GAC는 순간적으로 열접착이 발생되어 3차원 구조의 안정된 복합 필터가 제조된다.2. Stretching and Cooling Section 17: The spun resin is drawn rapidly in the longitudinal direction by a high-speed air-jet, and after a certain period, the spiral motion 21 is made with a decrease in speed. The spiral motion 21 has a three-dimensional structure when laminated with a nonwoven fabric, and the temperature-controlled GAC is injected into the nonwoven fabric with a uniform distribution in this section. That is, the GAC sprayed on the fiber is instantaneously thermally bonded to produce a stable composite filter having a three-dimensional structure.
3. 웹 적층구간(18) : 최적의 필터생산을 위해서 적층구간에서 부직포의 잠재적 열에너지 분포조절이 필요하며, 나선운동(21)의 크기조절을 위해 방사시 온도, 압력관계와 수집체(7)와 노즐(4)간의 거리인 DCD(15)의 설정이 중요하다.3. Web lamination section 18: It is necessary to control the distribution of potential heat energy of the nonwoven fabric in the lamination section for optimal filter production, and the temperature, pressure relation and the collector (7) during spinning to control the size of the spiral motion (21). The setting of the DCD 15, which is the distance between the nozzle and the nozzle 4, is important.
결론적으로 본 발명의 구성은 기존의 방사원리를 이용한 부직포 제조공정의 시스템에서 각 구간별 온도와 압력, 구간별 거리 등의 최적조건 설정과 GAC 투입에 적합한 수집체(7)와 GAC 공급장치(10)의 설계로 요약될 수 있다.In conclusion, in the system of the nonwoven fabric manufacturing process using the conventional radiation principle, the collector (7) and the GAC supply device (10) suitable for setting the optimum conditions such as temperature and pressure for each section, distance for each section, and GAC input (10). Can be summarized as a design.
<실시예 1><Example 1>
필터형태 : GAC 복합 부직포 필터Filter Type: GAC Composite Nonwoven Filter
방사기 DIE 온도 : 250℃Spinner DIE Temperature: 250 ℃
Hot-air 온도 : 150 m/secHot-air temperature: 150 m / sec
DCD : 20cmDCD: 20cm
분리물질 : Paraffin oil, NaClSeparation material: Paraffin oil, NaCl
유량 : 95LPMFlow rate: 95LPM
분리효율 : 94.0% 이상Separation efficiency: 94.0% or more
흡기저항 : 24.0mm H2O 이하Intake resistance: 24.0mm H 2 O or less
본 발명의 제조방법에 의해 기존의 GAC 복합 부직포 필터가 갖는 단점인 화학적 접착제의 사용, 구조적 결합에 의한 유연성 상실로 롤링(rolling) 작업 및 절곡처리(pleat process)의 어려움, 결합력 부족에 의한 GAC의 유출로 인한 취급의 불편함 등을 해소할 수 있으며, 공정의 생략화와 생략화에 의한 생산성향상 및 원가절감의 효과가 매우 크다.According to the manufacturing method of the present invention, the use of a chemical adhesive, which is a disadvantage of the conventional GAC composite nonwoven filter, the loss of flexibility due to structural coupling, the difficulty of rolling and bending processes, and the lack of bonding strength of the GAC. The inconvenience of handling due to spillage can be eliminated, and the effect of productivity improvement and cost reduction by omission and omission of process is very large.
도1은 본 발명의 GAC 복합 부직포 필터제품의 일부 절취 평면도 상세도1 is a detailed cut-away plan view of a GAC composite nonwoven filter product of the present invention
도2는 도1의 C-C'선을 따라 잘라진 부분 측단면도 상세도Figure 2 is a partial side cross-sectional view cut along the line CC 'of FIG.
도3은 본 발명의 3차원 구조의 GAC 복합 부직포 필터 제조공정 상세도Figure 3 is a detailed view of the manufacturing process GAC composite nonwoven filter of the three-dimensional structure of the present invention
도4는 본 발명의 온도조절 GAC 공급장치 상세도Figure 4 is a detailed view of the temperature control GAC supply apparatus of the present invention
<도면의 주요부분에 대한 부호의 설명><Description of the code | symbol about the principal part of drawing>
1 : 부직포 2 : 입상활성탄1: nonwoven fabric 2: granular activated carbon
5 : 에어플레이트 6 : 고온·고압에어5: air plate 6: high temperature / high pressure air
7 : 수집체 8 : 웹스크린7: Collector 8: Web Screen
9 : 석션장치 10 : 온도조절 GAC 공급장치9: suction device 10: temperature control GAC supply device
13 : 부직포필터 권취 14 : 다이스웰 현상13: winding of the nonwoven fabric filter 14: dieswell development
15 : 수집체와 노즐간거리(DCD) 16 : 방사구간15: Distance between collector and nozzle (DCD) 16: Spinning section
17 : 연신/냉각구간 18 : 웹 적층구간17: stretched / cooled section 18: web laminated section
19 : GAC 공급장치 가열부 20 : 용융수지19: GAC supply unit heating part 20: molten resin
21 : 나선형 운동21: spiral movement
Claims (4)
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KR1020040007387A KR20050079205A (en) | 2004-02-04 | 2004-02-04 | Manufacture of gac composite non-woven filter with three dimensional structure |
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KR1020040007387A KR20050079205A (en) | 2004-02-04 | 2004-02-04 | Manufacture of gac composite non-woven filter with three dimensional structure |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100801325B1 (en) * | 2005-12-23 | 2008-02-11 | 한양대학교 산학협력단 | Method of preparation chemical filter for air cleaning by reaction injection molding process |
KR101494387B1 (en) * | 2013-06-04 | 2015-02-23 | 주식회사 선진인더스트리 | Non-woven fabric having activated carbon and device for manufacturing the same |
KR102645082B1 (en) * | 2023-01-31 | 2024-03-06 | 건양대학교 산학협력단 | Manufacturing method of composite nonwoven fabric with excellent absorbency and processability |
KR102655447B1 (en) * | 2023-01-31 | 2024-04-08 | 건양대학교 산학협력단 | Manufacturing method of multi-purpose composite filter with excellent flexibility and adsorption |
-
2004
- 2004-02-04 KR KR1020040007387A patent/KR20050079205A/en not_active Application Discontinuation
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100801325B1 (en) * | 2005-12-23 | 2008-02-11 | 한양대학교 산학협력단 | Method of preparation chemical filter for air cleaning by reaction injection molding process |
KR101494387B1 (en) * | 2013-06-04 | 2015-02-23 | 주식회사 선진인더스트리 | Non-woven fabric having activated carbon and device for manufacturing the same |
KR102645082B1 (en) * | 2023-01-31 | 2024-03-06 | 건양대학교 산학협력단 | Manufacturing method of composite nonwoven fabric with excellent absorbency and processability |
KR102655447B1 (en) * | 2023-01-31 | 2024-04-08 | 건양대학교 산학협력단 | Manufacturing method of multi-purpose composite filter with excellent flexibility and adsorption |
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