KR20050071277A - Lanthanide-chelated porphyrins with porphyrin-linked dendrons having light-harvesting effect - Google Patents

Lanthanide-chelated porphyrins with porphyrin-linked dendrons having light-harvesting effect Download PDF

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KR20050071277A
KR20050071277A KR1020030102340A KR20030102340A KR20050071277A KR 20050071277 A KR20050071277 A KR 20050071277A KR 1020030102340 A KR1020030102340 A KR 1020030102340A KR 20030102340 A KR20030102340 A KR 20030102340A KR 20050071277 A KR20050071277 A KR 20050071277A
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pyrrole
dendrimer
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porphyrin
ethyne
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김환규
가재원
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
    • C07F3/06—Zinc compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0086—Platinum compounds
    • C07F15/0093—Platinum compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
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    • C08G83/00—Macromolecular compounds not provided for in groups C08G2/00 - C08G81/00
    • C08G83/002—Dendritic macromolecules
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Abstract

본 발명은 하기 화학식1의 구조를 갖는 에너지 전달 현상을 이용한 덴드리머형 금속폴피린 희토류 이온 착화합물 및 그 제조방법에 관한 것이다The present invention relates to a dendrimer-type metalpolpyrin rare earth ion complex compound using an energy transfer phenomenon having a structure of Formula 1, and a method for preparing the same.

[화학식 1][Formula 1]

Description

에너지 전달 현상을 이용한 덴드리머형 금속폴피린 희토류 이온 착화합물 및 그 제조방법{Lanthanide-chelated porphyrins with porphyrin-linked dendrons having light-harvesting effect}Dendrimer-type metal porphyrin rare earth ion complex using energy transfer phenomenon and its manufacturing method {Lanthanide-chelated porphyrins with porphyrin-linked dendrons having light-harvesting effect}

본 발명은 희토류 금속 이온을 포함하는 덴드리머의 합성에 관한 것으로, 분자 구조의 설계를 통하여 고분자 매질 하에서 용해도를 향상시켜 고분자 매질에 보다 효율적으로 도핑하고, 광자 에너지(또는 빛)를 흡수하여 복합체 중심계로 에너지를 전달하여 집광 효과(light harvesting effect)를 나타내는 자연계에 존재하는 광합성 안테나 복합체들의 원리를 이용하여 아릴에테르계 및 폴피린계의 광안테나를 이용하여 인공적인 빛을 포집하고 전달하는 과정에 의해 광물리적 특성을 극대화시킨 새로운 평면도파로형 광증폭 소재 개발에 관한 기술로서,BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to the synthesis of dendrimers containing rare earth metal ions. The design of the molecular structure improves the solubility under a polymer medium to more efficiently dope the polymer medium, and absorbs photon energy (or light) into the composite core. Light is collected by the process of capturing and transmitting artificial light using optical antennas of arylether and polypyrine based on the principle of photosynthetic antenna complexes in nature that transmits energy and shows the light harvesting effect. As a technology for developing a new planar waveguide optical amplification material that maximizes physical properties,

특히 하기의 화학식에서 표현되는 화합물과 그의 제조 방법에 관한 것이다. 이 화합물들은 덴드리머를 도입하여 집광 기능을 부여하며, 또한 희토류 금속간의 상호작용을 방지하기 위해 희토류 금속 이온을 효율적으로 폴피린 유도체로 캡슐화한 구조이다.In particular, it is related with the compound represented by the following formula, and its manufacturing method. These compounds are condensed by introducing a dendrimer, condensing function, and effectively encapsulating rare earth metal ions with a polypyrrole derivative in order to prevent interaction between rare earth metals.

상기와 같은 문제점을 해결하기 위하여, 본 발명은 용해도와 에너지 전달 능력이 향상된 새로운 평면도파로형 광증폭용 물질에 관한 것이다. 이는 광정보 고분자 소재가 지니고 있는 근본적인 문제점인 광세기 감소를 보상하기 위한 것이다. 기존의 광섬유 실리카에 도핑 되는 Er+3 농도는 100-1000 ppm 정도이며, 그 이상이 되면 Er+3 이온간의 상호작용에 의해 비발광 프로세스가 주로 일어나서 광증폭 효율이 급격히 떨어지게 된다. 이러한 이유로 실리카 광섬유에 Er+3을 도핑 시키는 방법으로는 고이득 광증폭이 불가능하고 따라서 평면도파로형 광집적 회로 형태로 30 dB 정도의 광증폭을 기대하기가 어렵다. 이와 같은 문제를 해결하고 평면도파로형 광증폭 소자를 구현하기 위한 새로운 물질로서 고분자에 희토류 이온을 도핑 시킨 물질이 주목을 받고 있다. 광증폭 고분자 소재는 현재 일본, 미국, 유럽 등의 선진 각국에서 고분자 소재에 희토류 이온 착화합물을 고분자 매질에 도핑시킨 평면도파로형 광증폭 소재를 연구를 하고 있다. 고분자 증폭 소자는 1993년에 일본 Keio 대학에 의해 처음으로 발표된 PMMA계 고분자 광섬유 코아 매질에 유기 염료를 1ppm 정도의 농도로 도핑한 광섬유 증폭 소자이며, 광소자의 길이는 50 ㎝로 비교적 길며, 30 dB 정도로 아주 우수한 증폭 특성을 보였다. 그러나 이는 발광 과정이 자발적인 발광에 의한 것이어서 광증폭 시간이 짧기 때문에 평면도파로형 광증폭 소자에는 활용할 수 없다. 이를 극복하기 위해, 이 연구팀은 PMMA계 고분자 광섬유에 증폭 효과가 있는 희토류 금속을 도핑하여 광증폭 고분자 소자를 발표하였다.In order to solve the above problems, the present invention relates to a new planar waveguide optical amplification material with improved solubility and energy transfer capability. This is to compensate for the decrease in light intensity, which is a fundamental problem of the optical information polymer material. The concentration of Er +3 doped in the conventional optical silica is about 100-1000 ppm, and if it is higher than that, the non-luminescence process mainly occurs due to the interaction between the Er +3 ions, thereby rapidly decreasing the optical amplification efficiency. For this reason, high gain optical amplification is not possible by doping Er +3 to silica optical fiber, and thus it is difficult to expect about 30 dB of optical amplification in the form of a planar waveguide integrated circuit. As a new material for solving such a problem and implementing a planar waveguide optical amplification device, a material having a rare earth ion doped into a polymer has attracted attention. Optically amplified polymer materials are currently being studied in top countries, such as Japan, the United States, and Europe, in planar waveguide optical amplification materials in which a rare earth ion complex compound is doped into a polymer medium. The polymer amplification device is an optical fiber amplification device doped with organic dye at a concentration of about 1 ppm in a PMMA polymer fiber core medium, first published by Keio University in 1993. The optical device is 50 cm in length and is relatively long, 30 dB. It showed very good amplification characteristics. However, since the light emission process is caused by spontaneous light emission, and the light amplification time is short, it cannot be used in the planar waveguide optical amplification device. To overcome this problem, the team presented a photo-amplified polymer device by doping rare earth metal with amplification effect to PMMA polymer fiber.

최근에 미국의 Texas (Austin) 대학의 Kuzyk 연구팀은 수용성 고분자인 photolime gel에 Nd+3을 도핑하여 스핀 코팅 법으로 2.2 ㎝의 매우 짧은 광증폭 소자를 제작 발표하였으며, 증폭 파장은 1.06 ㎛이며, 증폭 이득은 8.5 dB로 비교적 우수하였다. 네덜란드 Philips 사에서는 테프론 모세관에 MA 계통인 라울릴 메타크릴레이트 단량체를 채우고 난 다음, 여기에 희토류 금속인 Eu+3을 도핑한 후 중합하여 1.5 ㎝ 정도의 매우 짧은 고분자 광섬유 형태의 광증폭 소자를 개발하였는데, 증폭 이득은 4.1 dB로 보고하였다.Recently, Kuzyk and colleagues at the University of Texas (Austin) in the United States announced the fabrication of a very short optical amplification device of 2.2 cm by spin coating method by doping Nd +3 on a water-soluble polymer, photolime gel, with an amplification wavelength of 1.06 µm. The gain was relatively good at 8.5 dB. Philips, the Netherlands, filled a Teflon capillary with a MA-based lauryl methacrylate monomer, and then doped the rare earth metal Eu +3 and polymerized it to develop an optical amplification device in the form of a very short polymer optical fiber of about 1.5 cm. The amplification gain was reported as 4.1 dB.

최근 들어 일본의 NTT 광전자연구팀, 미국의 여러 대학(Colorado대학, Arizona대학) 및 기업연구소 (Bellcore, Corning), 및 캐나다의 McGill대학 등에서 저온 졸-겔 화학을 이용해서 희토류 금속을 균일하게 무기 고분자 매질 (SiO2)에 주입한 손님-주인 계의 광증폭 재료에 대한 연구가 활발히 이루어지고 있다. 특히, 1996년도에는 이 방법으로 평면도파로형 광증폭 소자와 WDM과의 집적화된 광증폭 소자 개발이 보고되었다. 그러나 이 계의 문제로는 희토류 금속들의 용해도가 낮아서 도핑 농도가 제한되어 광증폭 효과가 낮다는 점과 희토류 이온-실리카 간의 상 분리 문제점으로 광증폭 효과가 아주 낮다는 단점이 있다.In recent years, NTT optoelectronic research teams in Japan, universities in the US (Colorado University, Arizona University) and corporate research institutes (Bellcore, Corning), and McGill University in Canada have used low-temperature sol-gel chemistry to uniformly distribute rare earth metals with inorganic polymer media. Research into the light-amplifying material of the guest-host system injected into (SiO 2 ) is being actively conducted. In particular, in 1996, the development of a planar waveguide optical amplification device and WDM integrated optical amplification device was reported by this method. However, the problem of this system is that the rare earth metals have low solubility so that the doping concentration is limited, resulting in low optical amplification effect, and the rare earth ion-silica phase separation problem is very low optical amplification effect.

고분자에 희토류 이온을 도핑 시키는 기존의 연구 방법과는 달리, 분자공학을 이용하여 자연광합성의 원리인 집광 효과를 나타내고, 고분자 매질에 우수한 용해도를 가지며, 희토류 금속의 뭉침이 없어서 이온-이온간의 상호작용이 없는 덴드리머형 폴피린 희토류 이온 착화합물 구조인 에너지 전달 현상을 이용하고, 다양한 희토류 금속을 이용하여 그림 1과 같이 광물리적 특성을 제어할 수 있는 (특히 발광) 덴드리머형 금속폴피린 희토류 이온 착화합물 및 그 제조방법을 제공하는 것이 본 발명이 이루고자 하는 기술적 과제인 것이다. Unlike the existing research method of doping rare earth ions to a polymer, molecular engineering is used to show the condensing effect, which is the principle of photosynthesis of nature, has excellent solubility in the polymer medium, and there is no agglomeration of rare earth metals. Dendrimer-type polypyrroline rare earth ion complex which can control the photophysical properties (especially luminescence) by using the energy transfer phenomenon which is a dendrimer type porphyrin rare earth ion complex structure which is free of charge and various rare earth metals It is a technical object of the present invention to provide a manufacturing method .

상기와 같은 목적을 달성하기 위하여 본 발명은 덴드리머형 금속폴피린 희토류 이온 착화합물과 그의 제조 방법에 관한 것이다. In order to achieve the above object, the present invention relates to a dendrimer type metalpolpyrin rare earth ion complex compound and a method for producing the same.

구체적으로는 본 발명은 하기의 화학식 1의 구조를 가지는 신규한 덴드리머형 금속폴피린 희토류 이온 착화합물과 그의 제조 방법에 관한 것이다.Specifically, the present invention relates to a novel dendrimer type metalpolpyrin rare earth ion complex having a structure represented by the following formula (1) and a method for producing the same.

[화학식 1][Formula 1]

본 발명의 화합물을 합성하기 위해 사용하는 시약중 헥산, 디클로로메탄, 메틸알콜, 에틸알콜, THF, 트리에틸아민, K2CO3, KOH, 무수마그네슘설페이트, 암모늄클로아이드는 시약급을 사용하였다. 그리고 피롤(pyrrole), 4-(트리메틸실릴에테닐)벤즈알데히드, 4-이오도벤즈알데히드, TFA(trifluoroacetic acid), BF3·OEt2, 아세토니트릴, BBr3, ZnCl2, 18-crown-6, 징크아세테이트디하이드레이트(zinc acetate dihydrate), 플라티늄디클로리드(platinum dichloride), 어븀클로리드헥사하이드레이트(erbium chloride hexahydrate), 이터비윰클로리드헥사하이드레이트(ytterbium chloride hexahydrate), 네오디미움클로리드 헥사하이드레이트(neodymium chloride hexahydrate), 트리스(디벤질리덴아세톤)디팔리디움(0)( tris(dibenzylideneacetone)dipalladium(0)), 트리-o-톨릴포스핀(tri-o-tolylphosphine), 테트라키스-(트리페닐포스핀)팔라디움(0)(tetrakis- (triphenylphosphine)palladium(0)), n-BuLi, 구리(copper), 디이소프로필에틸아민 (DIEA), 디에틸포름아미드, 톨루엔, 2,3-디클로로-5,6-디시아노-1,4-벤조퀴논(DDQ)은 Aldrich사 제품을 구입하여 사용하였고, 별다른 정제과정 없이 사용하였다.Among the reagents used to synthesize the compound of the present invention, hexane, dichloromethane, methyl alcohol, ethyl alcohol, THF, triethylamine, K 2 CO 3, KOH, anhydrous magnesium sulfate, and ammonium chloride were used. And pyrrole, 4- (trimethylsilylethenyl) benzaldehyde, 4-iodobenzaldehyde, trifluoroacetic acid (TFA), BF 3 · OEt 2 , acetonitrile, BBr3, ZnCl 2, 18-crown-6, zinc acetate di Hydrate (zinc acetate dihydrate), platinum dichloride, erbium chloride hexahydrate, ytterbium chloride hexahydrate, neodymium chloride hexahydrate ), tris (dibenzylideneacetone) di-Farley Stadium (0) (tris (dibenzylideneacetone) dipalladium (0)), the tree -o- tolyl phosphine (tri- o -tolylphosphine), tetrakis- (triphenylphosphine) Palladium (0) (tetrakis- (triphenylphosphine) palladium (0)), n-BuLi, copper, diisopropylethylamine (DIEA), diethylformamide, toluene, 2,3-dichloro-5,6 -Dicyano-1,4-benzoquinone (DDQ) is purchased from Aldrich It was was used without any purification.

본 발명에서 제조한 화합물은 모두 1H NMR과 13C NMR 그리고 FT-IR로 구조를 확인하였다. 1H-NMR은 Varian 300 분광기를 사용하여 기록하였고, 모든 화학적 이동도는 내부 표준물질인 테트라메틸 실란에 대해 ppm단위로 기록하였다. IR 스펙트럼은 Perkin-Elmer Spectrometer를 사용하여 KBr 펠렛으로 측정하였다.The compounds prepared in the present invention were all confirmed by 1 H NMR, 13 C NMR and FT-IR. 1 H-NMR was recorded using a Varian 300 spectrometer and all chemical mobility was reported in ppm relative to tetramethyl silane, an internal standard. IR spectra were measured on KBr pellets using a Perkin-Elmer Spectrometer.

본 발명에서 상기의 화학식 1의 화합물을 제조하기 위한 전구체를 제조하는 방법은 하기에 기재한 바와 같은 반응을 통하여 제조하였다.In the present invention, the method for preparing a precursor for preparing the compound of Formula 1 was prepared through the reaction as described below.

Zn-폴피린의 제조방법How to prepare Zn-polpyrin

둥근 바닥 플라스크에 폴피린(porphyrin) (1.3 mmol)과 아세테이트아연(zinc acetate) (52.0 mmol, 40 equiv.)를 넣고 DMF 50 mL를 넣어 녹인 후 질소하에서 5시간동안 환류시킨다. 용매를 모두 증발시키고 CH2Cl2-메탄올로 재결정한다.Porphyrin (1.3 mmol) and zinc acetate (52.0 mmol, 40 equiv.) Were added to a round bottom flask. Dissolve 50 mL and reflux under nitrogen for 5 hours. All solvents are evaporated and recrystallized with CH 2 Cl 2 -methanol.

Pt-폴피린의 제조방법Method for preparing Pt-polpyrin

둥근 바닥 플라스크에 폴피린 (1.5 mmol)과 PCl2 (4.5 mmol, 3 equiv.)를 넣고 벤조나이트릴 50mL를 넣어 녹인 후 질소하에서 48시간동안 환류시킨다. 용매를 모두 증발시키고 관 크로마토그래피(Silica, CH2Cl2)로 분리한다.Polpyrin (1.5 mmol) and PCl 2 (4.5 mmol, 3 equiv.) Were added to a round bottom flask, and 50 mL of benzonitrile was dissolved. The mixture was refluxed under nitrogen for 48 hours. Solvents are all evaporated and separated by column chromatography (Silica, CH 2 Cl 2 ).

에타인 연결된 폴피린 이량체(Ethyne linked porphyrin dimer)의 제조 방법Method for preparing ethine linked porphyrin dimer

둥근 바닥 플라스크에 에티닐폴피린(ethynylphenyl porphyrin) (1.0 mmol)과 이오도페닐폴피린(iodophenylporphyrin) (1.0 mmol.), 트리-o-톨릴포스핀(P(o-tol)3)(2.0 mmol, 2 equiv.)을 넣고 돌루엔/DIEA 5:1 혼합용매 100 mL에 녹인다. 반응용기에 Pd2(dba)3 (0.15 mmol, 0.15 equiv.)를 넣고 실온에서 4시간동안 교반한다. 유기용매를 모두 증발시키고 CH2Cl2-헥산으로 재결정한다.Ethynylphenyl porphyrin (1.0 mmol) and iodophenylporphyrin (1.0 mmol.), Tri-o-tolylphosphine (P ( o -tol) 3 ) (2.0 mmol, 2 equiv.) And dissolve in 100 mL of toluene / DIEA 5: 1 mixed solvent. Pd 2 (dba) 3 (0.15 mmol, 0.15 equiv.) Was added to the reaction vessel and stirred at room temperature for 4 hours. All organic solvents are evaporated and recrystallized with CH 2 Cl 2 -hexane.

탄소-탄소연결된 덴드리머(C-C Direct linked dendrimer)의 제조 방법Process for producing carbon-carbon linked dendrimers

둥근 바닥 플라스크에 브로모페닐폴피린다이머(bromophenyl porphyrin dimer) (0.66 mmol)를 넣고 THF 25 mL에 녹인다. 질소하에서 n-BuLi (3.3 mmol, 5 equiv.)을 넣고 -78℃에서 1시간동안 교반한다. 반응용기에 ZnCl2 (13.2 mmol, 20 equiv.) 를 가하고 실온에서 교반한다. 다른 플라스크에 덴드론(dendron) (0.66 mmol)과 Pd(PPh3)4 (1.32mmol, 2 equiv.)를 THF 25 mL에 녹이고 실온에서 30분동안 교반한 후 porphyrin이 있는 플라스크에 섞는다. 실온에서 12시간동안 교반한 후 유기용매를 모두 증발시키고 남아있는 물질을 THF/EtOH 혼합용매 50 mL에 녹인 후 KOH 수용액을 가하고 4시간동안 환류시킨다. CH2Cl2로 추출한 후 용매를 모두 증발시키고 관 크로마토그래피(Silica)로 분리한다.In a round bottom flask, bromophenyl porphyrin dimer (0.66 mmol) is added and dissolved in 25 mL of THF. Add n- BuLi (3.3 mmol, 5 equiv.) Under nitrogen and stir at −78 ° C. for 1 hour. ZnCl 2 (13.2 mmol, 20 equiv.) Is added to the reaction vessel and stirred at room temperature. In another flask, dendron (0.66 mmol) and Pd (PPh 3 ) 4 (1.32 mmol, 2 equiv.) Are dissolved in 25 mL of THF, stirred at room temperature for 30 minutes, and mixed in a flask with porphyrin. After stirring for 12 hours at room temperature, the organic solvent is evaporated, and the remaining material is dissolved in 50 mL of THF / EtOH mixed solvent, and then KOH aqueous solution is added and refluxed for 4 hours. After extraction with CH 2 Cl 2 , the solvents are all evaporated and separated by column chromatography (Silica).

에테르 가교 덴드리머(Ether-bridged dendrimer)의 제조 방법Process for preparing ether-bridged dendrimer

둥근 바닥 플라스크에 페놀폴피린다이머(phenol porphyrin dimer)(1.3 mmol)와 K2CO3 (13.0 mmol, 10 equiv), 18-crown-6 (0.65 mmol, 0.5 equiv.)를 넣고 아세톤 250 mL를 넣어 녹인다. 반응용기에 덴드론 (1.6 mmol, 1.2 equiv.)을 넣고 12시간동안 환류한다. 유기용매를 모두 증발시키고 남아있는 물질을 THF/EtOH 혼합용매 100 mL에 녹인 후 KOH 수용액을 가하고 4시간동안 환류시킨다. CH2Cl2로 추출한 후 용매를 모두 증발시키고 관 크로마토그래피(Silica)로 분리한다.Add phenol porphyrin dimer (1.3 mmol), K 2 CO 3 (13.0 mmol, 10 equiv), 18-crown-6 (0.65 mmol, 0.5 equiv.) To a round bottom flask, and add 250 mL of acetone. Dissolve. Add dendron (1.6 mmol, 1.2 equiv.) To the reaction vessel and reflux for 12 hours. All organic solvents are evaporated and the remaining material is dissolved in 100 mL of THF / EtOH mixed solvent. Then, KOH aqueous solution is added and refluxed for 4 hours. After extraction with CH 2 Cl 2 , the solvents are all evaporated and separated by column chromatography (Silica).

Ar-Ar 링크된 폴피린다이머(Ar-Ar linked porphyrin dimer)의 제조 방법Method for preparing Ar-Ar linked porphyrin dimer

둥근 바닥 플라스크에 이오도페닐폴피린 (1.2 mmol)을 넣고 DMF 50 mL에 녹인 후 구리분말(copper powder) (6.0 mmol, 5 equiv.)를 넣고 12시간 동안 환류시킨다. 용매를 증발시키고 관 크로마토그래피(Silica)로 분리한다.Iodophenylpolpyrine (1.2 mmol) was added to a round bottom flask, dissolved in 50 mL of DMF, and then copper powder (6.0 mmol, 5 equiv.) Was added thereto and refluxed for 12 hours. The solvent is evaporated and separated by column chromatography (Silica).

Ln-착물 제조 방법Ln-complex preparation method

둥근 바닥 플라스크에 폴피린(0.65 mmol)과 란타나이드(III)클로라이드 헥사하이드레이트(lanthanide(III) chloride hexahydrate)(0.72 mmol, 1.1 equiv.)를 넣고 클로로포름/메탄올=1/1혼합 용매 50mL에 녹인 후 4시간 동안 환류시킨다. 감압하에서 용매를 제거하고 건조시킨 후 CH2Cl2-메탄올로 재결정한다.In a round-bottom flask, polpyrine (0.65 mmol) and lanthanide (III) chloride hexahydrate (0.72 mmol, 1.1 equiv.) Were added and dissolved in 50 mL of chloroform / methanol = 1/1 mixed solvent. Reflux for 4 hours. The solvent is removed under reduced pressure, dried and then recrystallized from CH 2 Cl 2 -methanol.

Ln 착물을 함유하는 고분자블렌드물Polymer Blends Containing Ln Complexes

Ln(III) 착물 을 불소치환되거나 또는 불소치환되지 않은 폴리메타아크릴레이트, 폴리스티렌, 폴리이미드, 폴리아미드, 폴리에테르, 폴리에스테르 등의 고분자 재료에 고분자재료에 대해 3중량％, 5중량％, 10중량％, 15중량％, 18중량％, 20중량％를 전체고형분의 무게의 10배의 무게에 해당하는 클로로포름 용매에 녹여 용액을 만든후 이 용액을 스핀코우팅 방법으로 석영기판(quartz)에 코팅하고 건조하여 고분자 블렌드물의 박막을 제조한다.Ln (III) complex 3% by weight, 5% by weight, 10% by weight, or 15% by weight of the polymer material in a polymer material such as polymethacrylate, polystyrene, polyimide, polyamide, polyether, polyester, etc. %, 18% by weight, 20% by weight is dissolved in a chloroform solvent corresponding to 10 times the weight of the total solids to make a solution. The solution is coated on a quartz substrate by spin coating and dried to blend the polymer. Prepare a thin film of water.

다음은 본 발명에 따른 중간체 및 최종 목적생성물의 제조를 위한 반응식과 실시예를 구체적으로 보여준다. 각 실시예의 반응조건은 상기에 기재한 각 단계의 화합물의 제조방법에 의해 제조한다.The following shows in detail the reaction schemes and examples for the preparation of intermediates and end products according to the invention. The reaction conditions of each example are prepared by the method for preparing the compound of each step described above.

먼저, 본 발명에 따른 중간체 및 최종 목적생성물의 반응식은 다음 과 같다. First, the reaction scheme of the intermediate and the final target product according to the present invention is as follows.

[반응식 1]Scheme 1

[반응식 2] Scheme 2

[반응식 3]Scheme 3

[반응식 4]Scheme 4

[반응식5] [Scheme 5]

[반응식6] Scheme 6

[반응식 7]Scheme 7

[반응식 8]Scheme 8

[반응식 9]Scheme 9

[반응식 10]Scheme 10

[반응식 11]Scheme 11

[반응식 12]Scheme 12

[반응식 13] Scheme 13

[반응식 14] Scheme 14

[반응식 15] Scheme 15

[반응식 16]Scheme 16

[반응식 17] Scheme 17

[반응식 18] Scheme 18

[반응식 19]Scheme 19

[반응식 20] Scheme 20

[반응식 21] Scheme 21

[반응식 22] Scheme 22

[반응식 23] Scheme 23

[반응식 24] Scheme 24

[반응식 25] Scheme 25

[반응식 26]Scheme 26

[반응식 27] Scheme 27

[반응식 28] Scheme 28

[반응식 29]Scheme 29

[반응식 30] Scheme 30

[반응식 31] Scheme 31

[반응식 32] Scheme 32

[반응식 33] Scheme 33

[반응식 34] Scheme 34

[반응식 35]Scheme 35

[반응식 36]Scheme 36

[반응식 37]Scheme 37

[반응식 38]Scheme 38

[반응식 39] Scheme 39

[반응식 40] Scheme 40

[반응식 41]Scheme 41

[반응식 42] Scheme 42

[반응식 43] Scheme 43

[반응식 44]Scheme 44

[반응식 45] Scheme 45

[반응식 46] Scheme 46

[반응식 47] Scheme 47

[반응식 48] Scheme 48

[반응식 49] Scheme 49

[반응식 50] Scheme 50

[반응식 51] Scheme 51

[반응식 52] Scheme 52

[반응식 53]Scheme 53

[반응식 54]Scheme 54

[반응식 55]Scheme 55

[반응식 56]Scheme 56

[반응식 57]Scheme 57

[반응식 58]Scheme 58

[반응식 59]Scheme 59

[반응식 60]Scheme 60

[반응식 61]Scheme 61

[반응식 62]Scheme 62

[반응식 63]Scheme 63

[반응식 64]Scheme 64

이하는, 상기의 반응식에 따른 중간체 및 최종 목적생성물을 합성하는 구체적 합성의 실시예를 나타낸 것이다. 하기의 실시예에서, 덴드리머는 3세대 댄드리머와 4세대 댄드리머를 가지는 목적생성물은 그 반응조건 및 출발물질이 덴드리머의 구조를 제외하고는 실질적으로 동일하므로 덴드리머의 구조는 특정하지 않고 통칭하여 덴드리머라고 한다.The following shows examples of specific synthesis for synthesizing intermediates and end products according to the above reaction scheme. In the following examples, the dendrimer is a target product having a third-generation and a fourth-generation dandrimer, the reaction conditions and starting materials are substantially the same except for the structure of the dendrimer, so the structure of the dendrimer is not specified and collectively referred to as a dendrimer It is called.

실시예 1 : Example 1:

5-(4-에티닐페닐)-15-(4-메톡시카르보닐페닐)-10,20-디페닐폴피린-Pt5- (4-ethynylphenyl) -15- (4-methoxycarbonylphenyl) -10,20-diphenylpolpyrine-Pt

(5-(4-Ethynylphenyl)-15-(4-methoxycarbonylphenyl)-10,20-diphenylporp-hyrin-Pt)(5- (4-Ethynylphenyl) -15- (4-methoxycarbonylphenyl) -10,20-diphenylporp-hyrin-Pt)

5-(4-Ethynylphenyl)-15-(4-methoxycarbonylphenyl)-10,20-diphenylporphyrin을 사용하여 Pt-porphyrin 제조방법으로 합성한다. [반응식 1] Pt-porphyrin was synthesized using 5- (4-Ethynylphenyl) -15- (4-methoxycarbonylphenyl) -10,20-diphenylporphyrin. Scheme 1

1H NMR (CDCl3) δ 3.33 (s, 1H, CH), 4.12 (s, 3H, OCH3), 7.77 (m, 6H, Ar-H), 7.92 (d, 2H, Ar-H), 8.23 (m, 4H, Ar-H), 8.24 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.87 (m, 4H, β-pyrrole), 8.94 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 3.33 (s, 1H, CH), 4.12 (s, 3H, OCH 3 ), 7.77 (m, 6H, Ar-H), 7.92 (d, 2H, Ar-H), 8.23 (m, 4H, Ar-H), 8.24 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.87 (m, 4H, β -pyrrole), 8.94 (m, 4H, β-pyrrole).

실시예 2 :Example 2:

5-(4-에티닐페닐)-15-(4-메톡시카르보닐페닐)-10,20-디메시틸폴피린-Pt5- (4-ethynylphenyl) -15- (4-methoxycarbonylphenyl) -10,20-dimethoxylpolpyrine-Pt

(5-(4-Ethynylphenyl)-15-(4-methoxycarbonylphenyl)-10,20-dimesitylporp- hyrin-Pt)(5- (4-Ethynylphenyl) -15- (4-methoxycarbonylphenyl) -10,20-dimesitylporp- hyrin-Pt)

5-(4-Ethynylphenyl)-15-(4-methoxycarbonylphenyl)-10,20-dimesitylporphyrin을 사용하여 Pt-porphyrin 제조방법으로 합성한다. [반응식 2] Pt-porphyrin was synthesized using 5- (4-Ethynylphenyl) -15- (4-methoxycarbonylphenyl) -10,20-dimesitylporphyrin. Scheme 2

1H NMR (CDCl3) δ 1.87 (s, 6H, CH3), 2.65 (s, 12H, CH3), 3.33 (s, 1H, CH), 4.12 (s, 3H, OCH3), 7.30 (s, 4H, Ar-H), 7.92 (d, 2H, Ar-H), 8.24 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.87 (m, 4H, β-pyrrole), 8.94 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 6H, CH 3 ), 2.65 (s, 12H, CH 3 ), 3.33 (s, 1H, CH), 4.12 (s, 3H, OCH 3 ), 7.30 (s , 4H, Ar-H), 7.92 (d, 2H, Ar-H), 8.24 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H ), 8.87 (m, 4H, β-pyrrole), 8.94 (m, 4H, β-pyrrole).

실시예 3 :Example 3:

5,10,15-트리(4-브로모페닐)-20-(4-이오도페닐)폴피린-Zn5,10,15-tri (4-bromophenyl) -20- (4-iodophenyl) polpyrine-Zn

(5,10,15-Tri(4-bromophenyl)-20-(4-iodophenyl)porphyrin-Zn)(5,10,15-Tri (4-bromophenyl) -20- (4-iodophenyl) porphyrin-Zn)

5,10,15-Tri(4-bromophenyl)-20-(4-iodophenyl)porphyrin을 사용하여 Zn-porphy- rin 제조방법으로 합성한다. [반응식 3] 5,10,15-Tri (4-bromophenyl) -20- (4-iodophenyl) porphyrin was used to synthesize Zn-porphyrin. Scheme 3

1H NMR (CDCl3) δ 7.92 (m, 6H, Ar-H), 7.95 (d, 2H, Ar-H), 8.02 (d, 2H, Ar-H), 8.08 (m, 6H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.83 (d, 2H, b-pyrrole). 1 H NMR (CDCl 3 ) δ 7.92 (m, 6H, Ar-H), 7.95 (d, 2H, Ar-H), 8.02 (d, 2H, Ar-H), 8.08 (m, 6H, Ar-H ), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.83 (d, 2H, b-pyrrole).

실시예 4 :Example 4:

5,10,15-트리(4-브로모페닐)-20-(4-이오도페닐)폴피린-Pt5,10,15-tri (4-bromophenyl) -20- (4-iodophenyl) polpyrine-Pt

(5,10,15-Tri(4-bromophenyl)-20-(4-iodophenyl)porphyrin-Pt)(5,10,15-Tri (4-bromophenyl) -20- (4-iodophenyl) porphyrin-Pt)

5,10,15-Tri(4-bromophenyl)-20-(4-iodophenyl)porphyrin을 사용하여 Pt-porphy- rin 제조방법으로 합성한다. [반응식 4] 5,10,15-Tri (4-bromophenyl) -20- (4-iodophenyl) porphyrin was used to synthesize Pt-porphyrin. Scheme 4

1H NMR (CDCl3) δ 7.92 (m, 6H, Ar-H), 7.95 (d, 2H, Ar-H), 8.02 (d, 2H, Ar-H), 8.08 (m, 6H, Ar-H), 8.87 (m, 4H, β-pyrrole), 8.94 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 7.92 (m, 6H, Ar-H), 7.95 (d, 2H, Ar-H), 8.02 (d, 2H, Ar-H), 8.08 (m, 6H, Ar-H ), 8.87 (m, 4H, β-pyrrole), 8.94 (m, 4H, β-pyrrole).

실시예 5 :Example 5:

5,10,15-트리(3,5-디브로모페닐)-20-(4-이오도페닐)폴피린-Zn5,10,15-tri (3,5-dibromophenyl) -20- (4-iodophenyl) polpyrine-Zn

(5,10,15-Tri(3,5-dibromophenyl)-20-(4-iodophenyl)porphyrin-Zn)(5,10,15-Tri (3,5-dibromophenyl) -20- (4-iodophenyl) porphyrin-Zn)

5,10,15-Tri(3,5-dibromophenyl)-20-(4-iodophenyl)porphyrin을 사용하여 Zn-po- rphyrin 제조방법으로 합성한다. [반응식 5] 5,10,15-Tri (3,5-dibromophenyl) -20- (4-iodophenyl) porphyrin was used to synthesize Zn-po-phyrrin. Scheme 5

1H NMR (CDCl3) δ 7.95 (d, 2H, Ar-H), 8.02 (d, 2H, Ar-H), 8.47 (d, 3H, Ar-H), 8.50 (d, 6H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 7.95 (d, 2H, Ar-H), 8.02 (d, 2H, Ar-H), 8.47 (d, 3H, Ar-H), 8.50 (d, 6H, Ar-H ), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole).

실시예 6 :Example 6:

5,10,15-트리(3,5-디브로모페닐)-20-(4-이오도페닐)폴피린-Pt5,10,15-tri (3,5-dibromophenyl) -20- (4-iodophenyl) polpyrine-Pt

(5,10,15-Tri(3,5-dibromophenyl)-20-(4-iodophenyl)porphyrin-Pt)(5,10,15-Tri (3,5-dibromophenyl) -20- (4-iodophenyl) porphyrin-Pt)

5,10,15-Tri(3,5-dibromophenyl)-20-(4-iodophenyl)porphyrin을 사용하여 Pt-po- rphyrin 제조방법으로 합성한다. [반응식 6] 5,10,15-Tri (3,5-dibromophenyl) -20- (4-iodophenyl) porphyrin was used to synthesize Pt-porphyrin. Scheme 6

1H NMR (CDCl3) δ 7.95 (d, 2H, Ar-H), 8.02 (d, 2H, Ar-H), 8.47 (d, 3H, Ar-H), 8.50 (d, 6H, Ar-H), 8.79 (s, 4H, β-pyrrole), 8.85 (d, 2H, β-pyrrole), 8.92 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 7.95 (d, 2H, Ar-H), 8.02 (d, 2H, Ar-H), 8.47 (d, 3H, Ar-H), 8.50 (d, 6H, Ar-H ), 8.79 (s, 4H, β-pyrrole), 8.85 (d, 2H, β-pyrrole), 8.92 (d, 2H, β-pyrrole).

실시예 7 :Example 7:

5,10,15-트리(4-메톡시페닐)-20-(4-이오도페닐)폴피린-Zn5,10,15-tri (4-methoxyphenyl) -20- (4-iodophenyl) polpyrine-Zn

(5,10,15-Tri(4-methoxyphenyl)-20-(4-iodophenyl)porphyrin-Zn)(5,10,15-Tri (4-methoxyphenyl) -20- (4-iodophenyl) porphyrin-Zn)

5,10,15-Tri(4-methoxyphenyl)-20-(4-iodophenyl)porphyrin을 사용하여 Zn-porp- hyrin 제조방법으로 합성한다. [반응식 7] 5,10,15-Tri (4-methoxyphenyl) -20- (4-iodophenyl) porphyrin was used to synthesize Zn-porp-hyrin. Scheme 7

1H NMR (CDCl3) δ 4.10 (s, 9H, CH3), 7.25 (d, 6H, Ar-H), 7.95 (d, 2H, Ar-H), 8.02 (d, 2H, Ar-H), 8.17 (d, 6H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 4.10 (s, 9H, CH 3 ), 7.25 (d, 6H, Ar-H), 7.95 (d, 2H, Ar-H), 8.02 (d, 2H, Ar-H) , 8.17 (d, 6H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole).

실시예 8 :Example 8:

5,10,15-트리(4-메톡시페닐)-20-(4-이오도페닐)폴피린-Pt5,10,15-tri (4-methoxyphenyl) -20- (4-iodophenyl) polpyrine-Pt

(5,10,15-Tri(4-methoxyphenyl)-20-(4-iodophenyl)porphyrin-Pt)(5,10,15-Tri (4-methoxyphenyl) -20- (4-iodophenyl) porphyrin-Pt)

5,10,15-Tri(4-methoxyphenyl)-20-(4-iodophenyl)porphyrin을 사용하여 Pt-porp- hyrin 제조방법으로 합성한다. [반응식 8] 5,10,15-Tri (4-methoxyphenyl) -20- (4-iodophenyl) porphyrin was used to synthesize Pt-porp-hyrin. Scheme 8

1H NMR (CDCl3) δ 4.10 (s, 9H, CH3), 7.25 (d, 6H, Ar-H), 7.95 (d, 2H, Ar-H), 8.02 (d, 2H, Ar-H), 8.17 (d, 6H, Ar-H), 8.79 (s, 4H, β-pyrrole), 8.85 (d, 2H, β-pyrrole), 8.92 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 4.10 (s, 9H, CH 3 ), 7.25 (d, 6H, Ar-H), 7.95 (d, 2H, Ar-H), 8.02 (d, 2H, Ar-H) , 8.17 (d, 6H, Ar-H), 8.79 (s, 4H, β-pyrrole), 8.85 (d, 2H, β-pyrrole), 8.92 (d, 2H, β-pyrrole).

실시예 9 :Example 9:

5,10,15-트리(4-하이드록시페닐)-20-(4-이오도페닐)폴피린-Zn5,10,15-tri (4-hydroxyphenyl) -20- (4-iodophenyl) polpyrine-Zn

(5,10,15-Tri(4-hydroxyphenyl)-20-(4-iodophenyl)porphyrin-Zn)(5,10,15-Tri (4-hydroxyphenyl) -20- (4-iodophenyl) porphyrin-Zn)

둥근 바닥 플라스크에 5,10,15-tri(4-dihydroxyphenyl)-20-(4-iodophenyl)- porphyrin-Zn을 넣고 CH2Cl2를 넣어 녹이고, BBr3를 가하고 실온에서 교반한다. 용매를 모두 증발시키고, methanol/water로 재결정한다. [반응식 9] 5,10,15-tri (4-dihydroxyphenyl) -20- (4-iodophenyl) -porphyrin-Zn is added to a round bottom flask, and CH 2 Cl 2 is added thereto, BBr 3 is added thereto, and the mixture is stirred at room temperature. Evaporate all solvents and recrystallize from methanol / water. Scheme 9

1H NMR (CDCl3) δ 7.17 (d, 6H, Ar-H), 7.95 (d, 2H, Ar-H), 8.02 (d, 2H, Ar-H), 8.04 (d, 6H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 7.17 (d, 6H, Ar-H), 7.95 (d, 2H, Ar-H), 8.02 (d, 2H, Ar-H), 8.04 (d, 6H, Ar-H ), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole).

실시예 10 :Example 10

5,10,15-트리(4-하이드록시페닐)-20-(4-이오도페닐)폴피린-Pt5,10,15-tri (4-hydroxyphenyl) -20- (4-iodophenyl) polpyrine-Pt

(5,10,15-Tri(4-hydroxyphenyl)-20-(4-iodophenyl)porphyrin-Pt)(5,10,15-Tri (4-hydroxyphenyl) -20- (4-iodophenyl) porphyrin-Pt)

둥근 바닥 플라스크에 5,10,15-tri(4-hydroxyphenyl)-20-(4-iodophenyl)- porphyrin-Pt을 넣고 CH2Cl2를 넣어 녹이고, BBr3를 가하고 실온에서 교반한다. 용매를 모두 증발시키고, methanol/water로 재결정한다. [반응식 10] 5,10,15-tri (4-hydroxyphenyl) -20- (4-iodophenyl) -porphyrin-Pt is added to a round-bottomed flask, and CH 2 Cl 2 is added to dissolve it. BBr 3 is added thereto and stirred at room temperature. Evaporate all solvents and recrystallize from methanol / water. Scheme 10

1H NMR (CDCl3) δ 7.17 (d, 6H, Ar-H), 7.95 (d, 2H, Ar-H), 8.02 (d, 2H, Ar-H), 8.04 (d, 6H, Ar-H), 8.79 (s, 4H, β-pyrrole), 8.85 (d, 2H, β-pyrrole), 8.92 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 7.17 (d, 6H, Ar-H), 7.95 (d, 2H, Ar-H), 8.02 (d, 2H, Ar-H), 8.04 (d, 6H, Ar-H ), 8.79 (s, 4H, β-pyrrole), 8.85 (d, 2H, β-pyrrole), 8.92 (d, 2H, β-pyrrole).

실시예 11 :Example 11:

5,10,15-트리(3,5-디메톡시페닐)-20-(4-이오도페닐)폴피린-Zn5,10,15-tri (3,5-dimethoxyphenyl) -20- (4-iodophenyl) polpyrine-Zn

(5,10,15-Tri(3,5-dimethoxyphenyl)-20-(4-iodophenyl)porphyrin-Zn)(5,10,15-Tri (3,5-dimethoxyphenyl) -20- (4-iodophenyl) porphyrin-Zn)

5,10,15-Tri(3,5-dimethoxyphenyl)-20-(4-iodophenyl)porphyrin을 사용하여 Zn- porphyrin 제조방법으로 합성한다. [반응식 11] 5,10,15-Tri (3,5-dimethoxyphenyl) -20- (4-iodophenyl) porphyrin was used to synthesize Zn-porphyrin. Scheme 11

1H NMR (CDCl3) δ 4.11 (s, 18H, CH3), 7.42 (s, 3H, Ar-H), 7.78 (s, 6H, Ar-H), 7.95 (d, 2H, Ar-H), 8.02 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 4.11 (s, 18H, CH 3 ), 7.42 (s, 3H, Ar-H), 7.78 (s, 6H, Ar-H), 7.95 (d, 2H, Ar-H) , 8.02 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole).

실시예 12 :Example 12:

5,10,15-트리(3,5-디메톡시페닐)-20-(4-이오도페닐)폴피린-Pt5,10,15-tri (3,5-dimethoxyphenyl) -20- (4-iodophenyl) polpyrine-Pt

(5,10,15-Tri(3,5-dimethoxyphenyl)-20-(4-iodophenyl)porphyrin-Pt)(5,10,15-Tri (3,5-dimethoxyphenyl) -20- (4-iodophenyl) porphyrin-Pt)

5,10,15-Tri(3,5-dimethoxyphenyl)-20-(4-iodophenyl)porphyrin을 사용하여 Pt- porphyrin 제조방법으로 합성한다. [반응식 12] 5,10,15-Tri (3,5-dimethoxyphenyl) -20- (4-iodophenyl) porphyrin was used to synthesize Pt-porphyrin. Scheme 12

1H NMR (CDCl3) δ 4.11 (s, 18H, CH3), 7.42 (s, 3H, Ar-H), 7.78 (s, 6H, Ar-H), 7.95 (d, 2H, Ar-H), 8.02 (d, 2H, Ar-H), 8.79 (s, 4H, β-pyrrole), 8.85 (d, 2H, β-pyrrole), 8.92 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 4.11 (s, 18H, CH 3 ), 7.42 (s, 3H, Ar-H), 7.78 (s, 6H, Ar-H), 7.95 (d, 2H, Ar-H) , 8.02 (d, 2H, Ar-H), 8.79 (s, 4H, β-pyrrole), 8.85 (d, 2H, β-pyrrole), 8.92 (d, 2H, β-pyrrole).

실시예 13 :Example 13:

5,10,15-트리(3,5-디하이드록시페닐)-20-(4-이오도페닐)폴피린-Zn5,10,15-tri (3,5-dihydroxyphenyl) -20- (4-iodophenyl) polpyrine-Zn

(5,10,15-Tri(3,5-dihydroxyphenyl)-20-(4-iodophenyl)porphyrin-Zn)(5,10,15-Tri (3,5-dihydroxyphenyl) -20- (4-iodophenyl) porphyrin-Zn)

둥근 바닥 플라스크에 5,10,15-tri(3,5-dihydroxyphenyl)-20-(4-iodophenyl)- porphyrin-Zn을 넣고 CH2Cl2를 넣어 녹이고, BBr3를 가하고 실온에서 교반한다. 용매를 모두 증발시키고, methanol/water로 재결정한다. [반응식 13] Add 5,10,15-tri (3,5-dihydroxyphenyl) -20- (4-iodophenyl) -porphyrin-Zn to a round bottom flask, add CH 2 Cl 2 to dissolve it, add BBr 3 , and stir at room temperature. Evaporate all solvents and recrystallize from methanol / water. Scheme 13

1H NMR (CDCl3) δ 7.42 (s, 3H, Ar-H), 7.78 (s, 6H, Ar-H) , 7.95 (d, 2H, Ar-H), 8.02 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 7.42 (s, 3H, Ar-H), 7.78 (s, 6H, Ar-H), 7.95 (d, 2H, Ar-H), 8.02 (d, 2H, Ar-H ), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole).

실시예 14 :Example 14

5,10,15-트리(3,5-디하이드록시페닐)-20-(4-이오도페닐)폴피린-Pt5,10,15-tri (3,5-dihydroxyphenyl) -20- (4-iodophenyl) polpyrine-Pt

둥근 바닥 플라스크에 5,10,15-tri(3,5-dihydroxyphenyl)-20-(4-iodophenyl)- porphyrin-Pt을 넣고 CH2Cl2를 넣어 녹이고, BBr3를 가하고 실온에서 교반한다. 용매를 모두 증발시키고, 메탄올/물로 재결정한다. [반응식 14] 5,10,15-tri (3,5-dihydroxyphenyl) -20- (4-iodophenyl) -porphyrin-Pt is added to a round bottom flask, and CH 2 Cl 2 is added to dissolve it, BBr 3 is added thereto, and the mixture is stirred at room temperature. All solvents are evaporated and recrystallized from methanol / water. Scheme 14

1H NMR (CDCl3) δ 7.42 (s, 3H, Ar-H), 7.78 (s, 6H, Ar-H), 7.95 (d, 2H, Ar-H), 8.02 (d, 2H, Ar-H), 8.79 (s, 4H, β-pyrrole), 8.85 (d, 2H, β-pyrrole), 8.92 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 7.42 (s, 3H, Ar-H), 7.78 (s, 6H, Ar-H), 7.95 (d, 2H, Ar-H), 8.02 (d, 2H, Ar-H ), 8.79 (s, 4H, β-pyrrole), 8.85 (d, 2H, β-pyrrole), 8.92 (d, 2H, β-pyrrole).

실시예 15 :Example 15:

페닐-(4-브로모페닐) 에타인 링크된 폴피린 다이머 (MPhenyl- (4-bromophenyl) ethane linked polpyrine dimer (M 1One =2H, M= 2H, M 22 =2H)= 2H)

(Phnyl-(4-bromophenyl) ethyne linked porphyrin dimer)(M(Phnyl- (4-bromophenyl) ethyne linked porphyrin dimer) (M 1One =2H, M= 2H, M 2 2 =2H)= 2H)

5,15-Diphenyl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(4-bromophenyl)-20-iodophenylporphyrin (M2=2H)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 15] 5,15-Diphenyl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (4-bromophenyl) -20-iodophenylporphyrin (M 2 = 2H ) To synthesize ethyne linked porphyrin dimer. Scheme 15

1H NMR (CDCl3) δ 4.12 (s, 3H, OCH3), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.08 (m, 6H, Ar-H), 8.23 (m, 6H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 4.12 (s, 3H, OCH 3 ), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H) , 8.05 (d, 2H, Ar-H), 8.08 (m, 6H, Ar-H), 8.23 (m, 6H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H , Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole).

실시예 16 :Example 16:

페닐-(4-브로모페닐) 에타인 링크된 폴피린 다이머 (Phnyl-(4-bromophenyl) ethyne linked porphyrin dimer) (MPhnyl- (4-bromophenyl) ethyne linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =Zn)= Zn)

5,15-Diphenyl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(4-bromophenyl)-20-iodophenylporphyrin (M2=Zn)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 15] 5,15-Diphenyl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (4-bromophenyl) -20-iodophenylporphyrin (M 2 = Zn ) To synthesize ethyne linked porphyrin dimer. Scheme 15

1H NMR (CDCl3) δ 4.12 (s, 3H, OCH3), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.94 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.11 (m, 6H, Ar-H), 8.23 (m, 6H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.77 (m, 6H, β-pyrrole), 8.85 (m, 6H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 4.12 (s, 3H, OCH 3 ), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.94 (m, 6H, Ar-H) , 8.05 (d, 2H, Ar-H), 8.11 (m, 6H, Ar-H), 8.23 (m, 6H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H , Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.77 (m, 6H, β-pyrrole), 8.85 (m, 6 H, β-pyrrole).

실시예 17 :Example 17:

페닐-(4-브로모페닐) 에타인 링크된 폴피린 다이머 (Phnyl-(4-bromophenyl) ethyne linked porphyrin dimer) (MPhnyl- (4-bromophenyl) ethyne linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =Pt)= Pt)

5,15-Diphenyl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(4-bromophenyl)-20-iodophenylporphyrin (M2=Pt)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 15] 5,15-Diphenyl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (4-bromophenyl) -20-iodophenylporphyrin (M 2 = Pt ) To synthesize ethyne linked porphyrin dimer. Scheme 15

1H NMR (CDCl3) δ 4.12 (s, 3H, OCH3), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.08 (m, 6H, Ar-H), 8.23 (m, 6H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.78 (m, 8H, β-pyrrole), 8.85 (m, 6H, β-pyrrole), 8.92 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 4.12 (s, 3H, OCH 3 ), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H) , 8.05 (d, 2H, Ar-H), 8.08 (m, 6H, Ar-H), 8.23 (m, 6H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H , Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.78 (m, 8H, β-pyrrole), 8.85 (m, 6H, β-pyrrole), 8.92 (d, 2 H, β-pyrrole).

실시예 18 :Example 18:

페닐-(4-브로모페닐) 에타인 링크된 폴피린 다이머 (Phnyl-(4-bromophenyl) ethyne linked porphyrin dimer) (MPhnyl- (4-bromophenyl) ethyne linked porphyrin dimer (M 1One =Zn, M= Zn, M 22 =Zn)= Zn)

5,15-Diphenyl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Zn)과 5,10,15-tri(4-bromophenyl)-20-iodophenylporphyrin (M2=Zn)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 15] 5,15-Diphenyl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Zn) and 5,10,15-tri (4-bromophenyl) -20-iodophenylporphyrin (M 2 = Zn ) To synthesize ethyne linked porphyrin dimer. Scheme 15

1H NMR (CDCl3) δ 4.12 (s, 3H, OCH3), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.08 (m, 6H, Ar-H), 8.23 (m, 6H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.31 (d, 2H, Ar-H), 8.46 (d, 2H, Ar-H), 8.71 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.79 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 4.12 (s, 3H, OCH 3 ), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H) , 8.05 (d, 2H, Ar-H), 8.08 (m, 6H, Ar-H), 8.23 (m, 6H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H , Ar-H), 8.31 (d, 2H, Ar-H), 8.46 (d, 2H, Ar-H), 8.71 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.79 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole).

실시예 19 :Example 19:

페닐-(4-브로모페닐) 에타인 링크된 폴피린 다이머 (Phnyl-(4-bromophenyl) ethyne linked porphyrin dimer) (MPhnyl- (4-bromophenyl) ethyne linked porphyrin dimer (M 1One =Zn, M= Zn, M 22 =Pt)= Pt)

5,15-Diphenyl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Zn)과 5,10,15-tri(4-bromophenyl)-20-iodophenylporphyrin (M2=Pt)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 15] 5,15-Diphenyl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Zn) and 5,10,15-tri (4-bromophenyl) -20-iodophenylporphyrin (M 2 = Pt ) To synthesize ethyne linked porphyrin dimer. Scheme 15

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.14 (m, 6H, Ar-H), 8.23 (m, 6H, Ar-H), 8.29 (d, 2H, Ar-H), 8.30 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.78 (m, 4H, β-pyrrole), 8.79 (s, 4H, β-pyrrole), 8.84 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole), 8.92 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H ), 8.05 (d, 2H, Ar-H), 8.14 (m, 6H, Ar-H), 8.23 (m, 6H, Ar-H), 8.29 (d, 2H, Ar-H), 8.30 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.78 (m, 4H, β-pyrrole), 8.79 (s, 4H, β-pyrrole) , 8.84 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole), 8.92 (d, 2H, β-pyrrole).

실시예 20 :Example 20:

페닐-(4-브로모페닐) 에타인 링크된 폴피린 다이머 (Phnyl-(4-bromophenyl) ethyne linked porphyrin dimer) (MPhnyl- (4-bromophenyl) ethyne linked porphyrin dimer (M 1One =Pt, M= Pt, M 22 =Zn)= Zn)

5,15-Diphenyl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Pt)과 5,10,15-tri(4-bromophenyl)-20-iodophenylporphyrin (M2=Zn)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 15] 5,15-Diphenyl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Pt) and 5,10,15-tri (4-bromophenyl) -20-iodophenylporphyrin (M 2 = Zn ) To synthesize ethyne linked porphyrin dimer. Scheme 15

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.10 (m, 6H, Ar-H), 8.23 (m, 6H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.36 (d, 2H, Ar-H), 8.48 (d, 2H, Ar-H), 8.71 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.89 (m, 4H, β-pyrrole), 8.95 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H ), 8.05 (d, 2H, Ar-H), 8.10 (m, 6H, Ar-H), 8.23 (m, 6H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.36 (d, 2H, Ar-H), 8.48 (d, 2H, Ar-H), 8.71 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole) , 8.83 (d, 2H, β-pyrrole), 8.89 (m, 4H, β-pyrrole), 8.95 (m, 4H, β-pyrrole).

실시예 21 :Example 21:

페닐-(4-브로모페닐) 에타인 링크된 폴피린 다이머 (Phnyl-(4-bromophenyl) ethyne linked porphyrin dimer) (MPhnyl- (4-bromophenyl) ethyne linked porphyrin dimer (M 1One =Pt, M= Pt, M 22 =Pt)= Pt)

5,15-Diphenyl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Pt)과 5,10,15-tri(4-bromophenyl)-20-iodophenylporphyrin (M2=Pt)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 15] 5,15-Diphenyl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Pt) and 5,10,15-tri (4-bromophenyl) -20-iodophenylporphyrin (M 2 = Pt ) To synthesize ethyne linked porphyrin dimer. Scheme 15

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.14 (m, 6H, Ar-H), 8.23 (m, 6H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.36 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.78 (s, 4H, β-pyrrole), 8.84 (d, 2H, β-pyrrole), 8.89 (m, 4H, β-pyrrole), 8.92 (d, 2H, β-pyrrole), 8.95 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H ), 8.05 (d, 2H, Ar-H), 8.14 (m, 6H, Ar-H), 8.23 (m, 6H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.36 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.78 (s, 4H, β-pyrrole), 8.84 (d, 2H, β-pyrrole) , 8.89 (m, 4H, β-pyrrole), 8.92 (d, 2H, β-pyrrole), 8.95 (m, 4H, β-pyrrole).

실시예 22 :Example 22:

메시틸-(4-브로모페닐) 에타인 링크된 폴피린 다이머(Mesityl-(4-bromo- phenyl) ethyne linked porphyrin dimer) (MMesityl- (4-bromophenyl) ethyne linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =2H) = 2H)

5,15-Dimesityl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(4-bromophenyl)-20-iodophenylporphyrin (M2=2H)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 16] 5,15-Dimesityl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (4-bromophenyl) -20-iodophenylporphyrin (M 2 = 2H ) To synthesize ethyne linked porphyrin dimer. Scheme 16

1H NMR (CDCl3) δ1.87 (s, 6H, CH3), 2.65 (s, 12H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.08 (m, 6H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 6H, CH 3 ), 2.65 (s, 12H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 6H, Ar—H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.08 (m, 6H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole).

실시예 23 :Example 23:

메시틸-(4-브로모페닐) 에타인 링크된 폴피린 다이머(Mesiyl-(4-bromo- phenyl) ethyne linked porphyrin dimer) (MMesylyl- (4-bromophenyl) ethyne linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =Zn) = Zn)

5,15-Dimesityl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(4-bromophenyl)-20-iodophenylporphyrin (M2=Zn)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 16] 5,15-Dimesityl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (4-bromophenyl) -20-iodophenylporphyrin (M 2 = Zn ) To synthesize ethyne linked porphyrin dimer. Scheme 16

1H NMR (CDCl3) δ1.87 (s, 6H, CH3), 2.65 (s, 12H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.09 (m, 6H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.72 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.84 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 6H, CH 3 ), 2.65 (s, 12H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 6H, Ar—H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.09 (m, 6H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.72 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.84 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole).

실시예 24 :Example 24:

메시틸-(4-브로모페닐) 에타인 링크된 폴피린 다이머(Mesiyl-(4-bromo- phenyl) ethyne linked porphyrin dimer) (MMesylyl- (4-bromophenyl) ethyne linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =Pt) = Pt)

5,15-Dimesityl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(4-bromophenyl)-20-iodophenylporphyrin (M2=Pt)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 16] 5,15-Dimesityl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (4-bromophenyl) -20-iodophenylporphyrin (M 2 = Pt ) To synthesize ethyne linked porphyrin dimer. Scheme 16

1H NMR (CDCl3) δ1.87 (s, 6H, CH3), 2.65 (s, 12H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.11 (m, 6H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (m, 4H, Ar-H), 8.45 (d, 2H, Ar-H), 8.78 (m, 4H, β-pyrrole), 8.79 (s, 4H, β-pyrrole), 8.84 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole), 8.93 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 6H, CH 3 ), 2.65 (s, 12H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 6H, Ar—H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.11 (m, 6H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (m, 4H, Ar-H), 8.45 (d, 2H, Ar-H), 8.78 (m, 4H, β-pyrrole), 8.79 (s, 4H, β-pyrrole), 8.84 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole), 8.93 (d, 2H, β-pyrrole).

실시예 25 :Example 25:

메시틸-(4-브로모페닐) 에타인 링크된 폴피린 다이머(Mesiyl-(4-bromo- phenyl) ethyne linked porphyrin dimer) (MMesylyl- (4-bromophenyl) ethyne linked porphyrin dimer (M 1One =Zn, M= Zn, M 22 =Zn) = Zn)

5,15-Dimesityl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Zn)과 5,10,15-tri(4-bromophenyl)-20-iodophenylporphyrin (M2=Zn)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 16] 5,15-Dimesityl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Zn) and 5,10,15-tri (4-bromophenyl) -20-iodophenylporphyrin (M 2 = Zn ) To synthesize ethyne linked porphyrin dimer. Scheme 16

1H NMR (CDCl3) δ1.87 (s, 6H, CH3), 2.65 (s, 12H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.10 (m, 6H, Ar-H), 8.26 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.34 (d, 2H, Ar-H), 8.44 (d, 2H, Ar-H), 8.71 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.79 (m, 6H, β-pyrrole), 8.83 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 6H, CH 3 ), 2.65 (s, 12H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 6H, Ar—H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.10 (m, 6H, Ar-H), 8.26 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.34 (d, 2H, Ar-H), 8.44 (d, 2H, Ar-H), 8.71 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.79 (m, 6H, β-pyrrole), 8.83 (m, 4H, β-pyrrole).

실시예 26 :Example 26:

메시틸-(4-브로모페닐) 에타인 링크된 폴피린 다이머(Mesiyl-(4-bromo- phenyl) ethyne linked porphyrin dimer) (MMesylyl- (4-bromophenyl) ethyne linked porphyrin dimer (M 1One =Zn, M= Zn, M 22 =Pt) = Pt)

5,15-Dimesityl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Zn)과 5,10,15-tri(4-bromophenyl)-20-iodophenylporphyrin (M2=Pt)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 16] 5,15-Dimesityl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Zn) and 5,10,15-tri (4-bromophenyl) -20-iodophenylporphyrin (M 2 = Pt ) To synthesize ethyne linked porphyrin dimer. Scheme 16

1H NMR (CDCl3) δ1.87 (s, 6H, CH3), 2.65 (s, 12H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.14 (m, 6H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (m, 4H, Ar-H), 8.45 (d, 2H, Ar-H), 8.78 (m, 4H, β-pyrrole), 8.79 (s, 4H, β-pyrrole), 8.84 (m, 6H, β-pyrrole), 8.91 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 6H, CH 3 ), 2.65 (s, 12H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 6H, Ar—H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.14 (m, 6H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (m, 4H, Ar-H), 8.45 (d, 2H, Ar-H), 8.78 (m, 4H, β-pyrrole), 8.79 (s, 4H, β-pyrrole), 8.84 (m, 6H, β-pyrrole), 8.91 (d, 2H, β-pyrrole).

실시예 27 :Example 27:

메시틸-(4-브로모페닐) 에타인 링크된 폴피린 다이머(Mesiyl-(4-bromo- phenyl) ethyne linked porphyrin dimer) (MMesylyl- (4-bromophenyl) ethyne linked porphyrin dimer (M 1One =Pt, M= Pt, M 22 =Zn) = Zn)

5,15-Dimesityl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Pt)과 5,10,15-tri(4-bromophenyl)-20-iodophenylporphyrin (M2=Zn)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 16] 5,15-Dimesityl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Pt) and 5,10,15-tri (4-bromophenyl) -20-iodophenylporphyrin (M 2 = Zn ) To synthesize ethyne linked porphyrin dimer. Scheme 16

1H NMR (CDCl3) δ1.87 (s, 6H, CH3), 2.65 (s, 12H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.07 (m, 6H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.41 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.70 (s, 4H, b-pyrrole), 8.75 (d, 2H, b-pyrrole), 8.83 (d, 2H, b-pyrrole), 8.86 (m, 4H, b-pyrrole), 8.93 (m, 4H, b-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 6H, CH 3 ), 2.65 (s, 12H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 6H, Ar—H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.07 (m, 6H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.41 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.70 (s, 4H, b-pyrrole), 8.75 (d, 2H, b-pyrrole), 8.83 (d, 2H, b-pyrrole), 8.86 (m, 4H, b-pyrrole), 8.93 (m, 4H, b-pyrrole).

실시예 28 :Example 28:

메시틸-(4-브로모페닐) 에타인 링크된 폴피린 다이머(Mesityl-(4-bromo- phenyl) ethyne linked porphyrin dimer) (MMesityl- (4-bromophenyl) ethyne linked porphyrin dimer (M 1One =Pt, M= Pt, M 22 =Pt) = Pt)

5,15-Dimesityl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Pt)과 5,10,15-tri(4-bromophenyl)-20-iodophenylporphyrin (M2=Pt)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 16] 5,15-Dimesityl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Pt) and 5,10,15-tri (4-bromophenyl) -20-iodophenylporphyrin (M 2 = Pt ) To synthesize ethyne linked porphyrin dimer. Scheme 16

1H NMR (CDCl3) δ1.87 (s, 6H, CH3), 2.65 (s, 12H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.12 (m, 6H, Ar-H), 8.29 (d, 2H, Ar-H), 8.33 (d, 2H, Ar-H), 8.35 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.79 (s, 4H, β-pyrrole), 8.85 (d, 2H, β-pyrrole), 8.87 (m, 4H, β-pyrrole), 8.92 (d, 6H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 6H, CH 3 ), 2.65 (s, 12H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 6H, Ar—H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.12 (m, 6H, Ar-H), 8.29 (d, 2H, Ar-H), 8.33 (d, 2H, Ar-H), 8.35 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.79 (s, 4H, β-pyrrole), 8.85 (d, 2H, β-pyrrole), 8.87 (m, 4H, β-pyrrole), 8.92 (d, 6H, β-pyrrole).

실시예 29 :Example 29:

페닐-(3,5-디브로모페닐) 에타인링크된 폴피린 다이머(Phenyl-(3,5-dibromo- phenyl) ethyne linked porphyrin dimer) (MPhenyl- (3,5-dibromophenyl) ethyne linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =2H)= 2H)

5,15-Diphenyl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(3,5-dibromophenyl)-20-iodophenylporphyrin (M2=2H)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 17] 5,15-Diphenyl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (3,5-dibromophenyl) -20-iodophenylporphyrin (M 2 = 2H) to synthesize ethyne linked porphyrin dimer. Scheme 17

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.23 (m, 4H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.50 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H ), 8.23 (m, 4H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.50 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole) , 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole).

실시예 30 :Example 30:

Phenyl-(3,5-dibromophenyl) ethyne linked porphyrin dimer (MPhenyl- (3,5-dibromophenyl) ethyne linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =Zn)= Zn)

5,15-Diphenyl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(3,5-dibromophenyl)-20-iodophenylporphyrin (M2=Zn)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 17] 5,15-Diphenyl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (3,5-dibromophenyl) -20-iodophenylporphyrin (M 2 = Zn) to synthesize ethyne linked porphyrin dimer. Scheme 17

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.23 (m, 4H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.50 (d, 2H, Ar-H), 8.71 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.82 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H ), 8.23 (m, 4H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.50 (d, 2H, Ar-H), 8.71 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole) , 8.78 (m, 4H, β-pyrrole), 8.82 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole).

실시예 31 :Example 31:

Phenyl-(3,5-dibromophenyl) ethyne linked porphyrin dimer (MPhenyl- (3,5-dibromophenyl) ethyne linked porphyrin dimer (M 1One =Zn, M= Zn, M 22 =Pt)= Pt)

5,15-Diphenyl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(3,5-dibromophenyl)-20-iodophenylporphyrin (M2=Pt)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 17] 5,15-Diphenyl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (3,5-dibromophenyl) -20-iodophenylporphyrin (M 2 = Pt) to synthesize ethyne linked porphyrin dimer. Scheme 17

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.23 (m, 4H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.54 (d, 2H, Ar-H), 8.78 (m, 8H, β-pyrrole), 8.85 (m, 6H, β-pyrrole), 8.92 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H ), 8.23 (m, 4H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.54 (d, 2H, Ar-H), 8.78 (m, 8H, β-pyrrole), 8.85 (m, 6H, β-pyrrole) , 8.92 (d, 2H, β-pyrrole).

실시예 32 :Example 32:

Phenyl-(3,5-dibromophenyl) ethyne linked porphyrin dimer (MPhenyl- (3,5-dibromophenyl) ethyne linked porphyrin dimer (M 1One =Zn, M= Zn, M 22 =Zn)= Zn)

5,15-Diphenyl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Zn)과 5,10,15-tri(3,5-dibromophenyl)-20-iodophenylporphyrin (M2=Zn)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 17] 5,15-Diphenyl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Zn) and 5,10,15-tri (3,5-dibromophenyl) -20-iodophenylporphyrin (M 2 = Zn) to synthesize ethyne linked porphyrin dimer. Scheme 17

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.23 (m, 4H, Ar-H), 8.27 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.34 (d, 2H, Ar-H), 8.46 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.51 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.77 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.86 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H ), 8.23 (m, 4H, Ar-H), 8.27 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.34 (d, 2H, Ar-H), 8.46 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.51 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole) , 8.77 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.86 (m, 4H, β-pyrrole).

실시예 33 :Example 33:

Phenyl-(3,5-dibromophenyl) ethyne linked porphyrin dimer (MPhenyl- (3,5-dibromophenyl) ethyne linked porphyrin dimer (M 1One =Zn, M= Zn, M 22 =Pt)= Pt)

5,15-Diphenyl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(3,5-dibromophenyl)-20-iodophenylporphyrin (M2=2H)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 17] 5,15-Diphenyl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (3,5-dibromophenyl) -20-iodophenylporphyrin (M 2 = 2H) to synthesize ethyne linked porphyrin dimer. Scheme 17

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.23 (m, 4H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (m, 4H, Ar-H), 8.46 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.54 (d, 2H, Ar-H), 8.79 (m, 8H, β-pyrrole), 8.85 (d, 6H, β-pyrrole), 8.91 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H ), 8.23 (m, 4H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (m, 4H, Ar-H), 8.46 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.54 (d, 2H, Ar-H), 8.79 (m, 8H, β-pyrrole), 8.85 (d, 6H, β-pyrrole), 8.91 (d, 2H, β-pyrrole) .

실시예 34 :Example 34:

Phenyl-(3,5-dibromophenyl) ethyne linked porphyrin dimer (MPhenyl- (3,5-dibromophenyl) ethyne linked porphyrin dimer (M 1One =Pt, M= Pt, M 22 =Zn)= Zn)

5,15-Diphenyl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Pt)과 5,10,15-tri(3,5-dibromophenyl)-20-iodophenylporphyrin (M2=Zn)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 17] 5,15-Diphenyl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Pt) and 5,10,15-tri (3,5-dibromophenyl) -20-iodophenylporphyrin (M 2 = Zn) to synthesize ethyne linked porphyrin dimer. Scheme 17

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.27 (m, 6H, Ar-H), 8.29 (d, 2H, Ar-H), 8.36 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.49 (d, 2H, Ar-H), 8.50 (d, 2H, Ar-H), 8.71 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.86 (m, 4H, β-pyrrole), 8.94 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H ), 8.27 (m, 6H, Ar-H), 8.29 (d, 2H, Ar-H), 8.36 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.49 (d, 2H, Ar-H), 8.50 (d, 2H, Ar-H), 8.71 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole) , 8.86 (m, 4H, β-pyrrole), 8.94 (m, 4H, β-pyrrole).

실시예 35 :Example 35:

Phenyl-(3,5-dibromophenyl) ethyne linked porphyrin dimer (MPhenyl- (3,5-dibromophenyl) ethyne linked porphyrin dimer (M 1One =Pt, M= Pt, M 22 =Pt)= Pt)

5,15-Diphenyl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Pt)과 5,10,15-tri(3,5-dibromophenyl)-20-iodophenylporphyrin (M2=Pt)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 17] 5,15-Diphenyl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Pt) and 5,10,15-tri (3,5-dibromophenyl) -20-iodophenylporphyrin (M 2 = Pt) to synthesize ethyne linked porphyrin dimer. Scheme 17

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.27 (m, 4H, Ar-H), 8.29 (d, 2H, Ar-H), 8.31 (d, 2H, Ar-H), 8.36 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.48 (d, 2H, Ar-H), 8.53 (d, 2H, Ar-H), 8.79 (s, 4H, β-pyrrole), 8.86 (d, 6H, β-pyrrole), 8.93 (m, 6H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H ), 8.27 (m, 4H, Ar-H), 8.29 (d, 2H, Ar-H), 8.31 (d, 2H, Ar-H), 8.36 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.48 (d, 2H, Ar-H), 8.53 (d, 2H, Ar-H), 8.79 (s, 4H, β-pyrrole), 8.86 (d, 6H, β-pyrrole) , 8.93 (m, 6H, β-pyrrole).

실시예 36 :Example 36:

메시틸-(3,5-디브로모페닐) 에타인링크된 폴피린다이머(Mesityl-(3,5-di- bromophenyl) ethyne linked porphyrin dimer) (MMesityl- (3,5-dibromophenyl) ethyne linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =2H)= 2H)

5,15-Dimesityl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(3,5-dibromophenyl)-20-iodophenylporphyrin (M2=2H)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 18] 5,15-Dimesityl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (3,5-dibromophenyl) -20-iodophenylporphyrin (M 2 = 2H) to synthesize ethyne linked porphyrin dimer. Scheme 18

1H NMR (CDCl3) δ1.87 (s, 6H, CH3), 2.65 (s, 12H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.50 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 6H, CH 3 ), 2.65 (s, 12H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 6H, Ar—H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.50 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole).

실시예 37 :Example 37:

Mesityl-(3,5-dibromophenyl) ethyne linked porphyrin dimer (MMesityl- (3,5-dibromophenyl) ethyne linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =Zn)= Zn)

5,15-Dimesityl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(3,5-dibromophenyl)-20-iodophenylporphyrin (M2=Zn)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 18] 5,15-Dimesityl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (3,5-dibromophenyl) -20-iodophenylporphyrin (M 2 = Zn) to synthesize ethyne linked porphyrin dimer. Scheme 18

1H NMR (CDCl3) δ1.87 (s, 6H, CH3), 2.65 (s, 12H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.51 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.74 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.84 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 6H, CH 3 ), 2.65 (s, 12H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 6H, Ar—H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.51 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.74 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.84 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole).

실시예 38 :Example 38:

Mesityl-(3,5-dibromophenyl) ethyne linked porphyrin dimer (MMesityl- (3,5-dibromophenyl) ethyne linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =Pt)= Pt)

5,15-Dimesityl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(3,5-dibromophenyl)-20-iodophenylporphyrin (M2=Pt)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 18] 5,15-Dimesityl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (3,5-dibromophenyl) -20-iodophenylporphyrin (M 2 = Pt) to synthesize ethyne linked porphyrin dimer. Scheme 18

1H NMR (CDCl3) δ1.87 (s, 6H, CH3), 2.65 (s, 12H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (m, 6H, Ar-H), 8.45 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.54 (d, 2H, Ar-H), 8.78 (m, 4H, β-pyrrole), 8.79 (s, 4H, β-pyrrole), 8.85 (m, 6H, β-pyrrole), 8.92 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 6H, CH 3 ), 2.65 (s, 12H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 6H, Ar—H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (m, 6H, Ar-H), 8.45 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.54 (d, 2H, Ar-H), 8.78 (m, 4H, β-pyrrole), 8.79 (s, 4H, β-pyrrole), 8.85 (m, 6H, β-pyrrole), 8.92 (d, 2H, β-pyrrole).

실시예 39 :Example 39:

Mesityl-(3,5-dibromophenyl) ethyne linked porphyrin dimer (MMesityl- (3,5-dibromophenyl) ethyne linked porphyrin dimer (M 1One =Zn, M= Zn, M 22 =Zn)= Zn)

5,15-Dimesityl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Zn)과 5,10,15-tri(3,5-dibromophenyl)-20-iodophenylporphyrin (M2=Zn)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 18] 5,15-Dimesityl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Zn) and 5,10,15-tri (3,5-dibromophenyl) -20-iodophenylporphyrin (M 2 = Zn) to synthesize ethyne linked porphyrin dimer. Scheme 18

1H NMR (CDCl3) δ1.87 (s, 6H, CH3), 2.65 (s, 12H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (m, 4H, Ar-H), 8.31 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.52 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.77 (m, 6H, β-pyrrole), 8.85 (m, 6H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 6H, CH 3 ), 2.65 (s, 12H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 6H, Ar—H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (m, 4H, Ar-H), 8.31 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.52 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.77 (m, 6H, β-pyrrole), 8.85 (m, 6H, β-pyrrole).

실시예 40 :Example 40:

Mesityl-(3,5-dibromophenyl) ethyne linked porphyrin dimer (MMesityl- (3,5-dibromophenyl) ethyne linked porphyrin dimer (M 1One =Zn, M= Zn, M 22 =Pt)= Pt)

5,15-Dimesityl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Zn)과 5,10,15-tri(3,5-dibromophenyl)-20-iodophenylporphyrin (M2=Pt)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 18] 5,15-Dimesityl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Zn) and 5,10,15-tri (3,5-dibromophenyl) -20-iodophenylporphyrin (M 2 = Pt) to synthesize ethyne linked porphyrin dimer. Scheme 18

1H NMR (CDCl3) δ1.87 (s, 6H, CH3), 2.65 (s, 12H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.31 (d, 2H, Ar-H), 8.34 (d, 2H, Ar-H), 8.46 (m, 4H, Ar-H), 8.53 (d, 2H, Ar-H), 8.78 (m, 8H, β-pyrrole), 8.85 (m, 6H, β-pyrrole), 8.91 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 6H, CH 3 ), 2.65 (s, 12H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 6H, Ar—H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.31 (d, 2H, Ar-H), 8.34 (d, 2H, Ar-H), 8.46 (m, 4H, Ar-H), 8.53 (d, 2H, Ar-H), 8.78 (m, 8H, β-pyrrole), 8.85 (m, 6H, β-pyrrole), 8.91 (d, 2H, β-pyrrole).

실시예 41 :Example 41:

Mesityl-(3,5-dibromophenyl) ethyne linked porphyrin dimer (MMesityl- (3,5-dibromophenyl) ethyne linked porphyrin dimer (M 1One =Pt, M= Pt, M 22 =Zn)= Zn)

5,15-Dimesityl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Pt)과 5,10,15-tri(3,5-dibromophenyl)-20-iodophenylporphyrin (M2=Zn)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 18] 5,15-Dimesityl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Pt) and 5,10,15-tri (3,5-dibromophenyl) -20-iodophenylporphyrin (M 2 = Zn) to synthesize ethyne linked porphyrin dimer. Scheme 18

1H NMR (CDCl3) δ1.87 (s, 6H, CH3), 2.65 (s, 12H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.28 (m, 4H, Ar-H), 8.36 (d, 2H, Ar-H), 8.47 (m, 3H, Ar-H), 8.51 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.77 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.86 (m, 4H, β-pyrrole), 8.94 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 6H, CH 3 ), 2.65 (s, 12H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 6H, Ar—H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.28 (m, 4H, Ar-H), 8.36 (d, 2H, Ar-H), 8.47 (m, 3H, Ar-H), 8.51 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.77 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.86 (m, 4H, β-pyrrole), 8.94 (m, 4H, β-pyrrole).

실시예 42 :Example 42:

Mesityl-(3,5-dibromophenyl) ethyne linked porphyrin dimer (MMesityl- (3,5-dibromophenyl) ethyne linked porphyrin dimer (M 1One =Pt, M= Pt, M 22 =Pt)= Pt)

5,15-Dimesityl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Pt)과 5,10,15-tri(3,5-dibromophenyl)-20-iodophenylporphyrin (M2=Pt)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 18] 5,15-Dimesityl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Pt) and 5,10,15-tri (3,5-dibromophenyl) -20-iodophenylporphyrin (M 2 = Pt) to synthesize ethyne linked porphyrin dimer. Scheme 18

1H NMR (CDCl3) δ1.87 (s, 6H, CH3), 2.65 (s, 12H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.33 (d, 2H, Ar-H), 8.37 (d, 2H, Ar-H), 8.48 (m, 3H, Ar-H), 8.54 (d, 2H, Ar-H), 8.79 (s, 4H, β-pyrrole), 8.86 (m, 6H, β-pyrrole), 8.91 (d, 2H, β-pyrrole), 8.94 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 6H, CH 3 ), 2.65 (s, 12H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 6H, Ar—H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.33 (d, 2H, Ar-H), 8.37 (d, 2H, Ar-H), 8.48 (m, 3H, Ar-H), 8.54 (d, 2H, Ar-H), 8.79 (s, 4H, β-pyrrole), 8.86 (m, 6H, β-pyrrole), 8.91 (d, 2H, β-pyrrole), 8.94 (m, 4H, β-pyrrole).

실시예 43 :Example 43:

페닐-(4-하이드록시페닐) 에타인링크된 폴피린 다이머(Phenyl-(4-hydroxy- phenyl) ethyne linked porphyrin dimer) (MPhenyl- (4-hydroxyphenyl) ethyne linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =2H) = 2H)

5,15-Diphenyl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(4-hydroxyphenyl)-20-iodophenylporphyrin (M2=2H)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 19] 5,15-Diphenyl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (4-hydroxyphenyl) -20-iodophenylporphyrin (M 2 = 2H ) To synthesize ethyne linked porphyrin dimer. Scheme 19

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.17 (d, 2H, Ar-H), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (m, 4H, Ar-H), 8.23 (m, 2H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.17 (d, 2H, Ar-H), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H ), 8.05 (m, 4H, Ar-H), 8.23 (m, 2H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole) , 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole).

실시예 44 :Example 44:

Phenyl-(4-hydroxyphenyl) ethyne linked porphyrin dimer (MPhenyl- (4-hydroxyphenyl) ethyne linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =Zn)= Zn)

5,15-Diphenyl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(4-hydroxyphenyl)-20-iodophenylporphyrin (M2=Zn)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 19] 5,15-Diphenyl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (4-hydroxyphenyl) -20-iodophenylporphyrin (M 2 = Zn ) To synthesize ethyne linked porphyrin dimer. Scheme 19

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.17 (d, 2H, Ar-H), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.04 (m, 4H, Ar-H), 8.23 (m, 2H, Ar-H), 8.28 (m, 4H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.85 (m, 6H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.17 (d, 2H, Ar-H), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H ), 8.04 (m, 4H, Ar-H), 8.23 (m, 2H, Ar-H), 8.28 (m, 4H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.85 (m, 6H, β-pyrrole) .

실시예 45 :Example 45:

Phenyl-(4-hydroxyphenyl) ethyne linked porphyrin dimer (MPhenyl- (4-hydroxyphenyl) ethyne linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =Pt)= Pt)

5,15-Diphenyl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(4-hydroxyphenyl)-20-iodophenylporphyrin (M2=Pt)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 19] 5,15-Diphenyl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (4-hydroxyphenyl) -20-iodophenylporphyrin (M 2 = Pt ) To synthesize ethyne linked porphyrin dimer. Scheme 19

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.17 (d, 2H, Ar-H), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.04 (m, 4H, Ar-H), 8.23 (m, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.34 (m, 4H, Ar-H), 8.45 (d, 2H, Ar-H), 8.78 (m, 8H, β-pyrrole), 8.85 (m, 6H, β-pyrrole), 8.92 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.17 (d, 2H, Ar-H), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H ), 8.04 (m, 4H, Ar-H), 8.23 (m, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.34 (m, 4H, Ar-H), 8.45 (d, 2H, Ar-H), 8.78 (m, 8H, β-pyrrole), 8.85 (m, 6H, β-pyrrole), 8.92 (d, 2H, β-pyrrole).

실시예 46 :Example 46:

Phenyl-(4-hydroxyphenyl) ethyne linked porphyrin dimer (MPhenyl- (4-hydroxyphenyl) ethyne linked porphyrin dimer (M 1One =Zn, M= Zn, M 22 =Zn)= Zn)

5,15-Diphenyl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Zn)과 5,10,15-tri(4-hydroxyphenyl)-20-iodophenylporphyrin (M2=Zn)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 19] 5,15-Diphenyl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Zn) and 5,10,15-tri (4-hydroxyphenyl) -20-iodophenylporphyrin (M 2 = Zn ) To synthesize ethyne linked porphyrin dimer. Scheme 19

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.17 (d, 2H, Ar-H), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (m, 4H, Ar-H), 8.23 (m, 2H, Ar-H), 8.29 (m, 6H, Ar-H), 8.46 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.77 (m, 6H, β-pyrrole), 8.85 (m, 6H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.17 (d, 2H, Ar-H), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H ), 8.05 (m, 4H, Ar-H), 8.23 (m, 2H, Ar-H), 8.29 (m, 6H, Ar-H), 8.46 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.77 (m, 6H, β-pyrrole), 8.85 (m, 6H, β-pyrrole).

실시예 47 :Example 47:

Phenyl-(4-hydroxyphenyl) ethyne linked porphyrin dimer (MPhenyl- (4-hydroxyphenyl) ethyne linked porphyrin dimer (M 1One =Zn, M= Zn, M 22 =Pt)= Pt)

5,15-Diphenyl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Zn)과 5,10,15-tri(4-hydroxyphenyl)-20-iodophenylporphyrin (M2=Pt)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 19] 5,15-Diphenyl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Zn) and 5,10,15-tri (4-hydroxyphenyl) -20-iodophenylporphyrin (M 2 = Pt ) To synthesize ethyne linked porphyrin dimer. Scheme 19

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.17 (d, 2H, Ar-H), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (m, 4H, Ar-H), 8.23 (m, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.34 (m, 4H, Ar-H), 8.46 (d, 2H, Ar-H), 8.77 (m, 4H, β-pyrrole), 8.79 (s, 4H, β-pyrrole), 8.85 (m, 6H, β-pyrrole), 8.92 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.17 (d, 2H, Ar-H), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H ), 8.05 (m, 4H, Ar-H), 8.23 (m, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.34 (m, 4H, Ar-H), 8.46 (d, 2H, Ar-H), 8.77 (m, 4H, β-pyrrole), 8.79 (s, 4H, β-pyrrole), 8.85 (m, 6H, β-pyrrole), 8.92 (d, 2H, β-pyrrole) .

실시예 48 :Example 48:

Phenyl-(4-hydroxyphenyl) ethyne linked porphyrin dimer (MPhenyl- (4-hydroxyphenyl) ethyne linked porphyrin dimer (M 1One =Pt, M= Pt, M 22 =Zn)= Zn)

5,15-Diphenyl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Pt)과 5,10,15-tri(4-hydroxyphenyl)-20-iodophenylporphyrin (M2=Zn)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 19] 5,15-Diphenyl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Pt) and 5,10,15-tri (4-hydroxyphenyl) -20-iodophenylporphyrin (M 2 = Zn ) To synthesize ethyne linked porphyrin dimer. Scheme 19

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.17 (d, 2H, Ar-H), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (m, 4H, Ar-H), 8.23 (m, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (m, 4H, Ar-H), 8.48 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.87 (m, 4H, β-pyrrole), 8.94 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.17 (d, 2H, Ar-H), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H ), 8.05 (m, 4H, Ar-H), 8.23 (m, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (m, 4H, Ar-H), 8.48 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.87 (m, 4H, β-pyrrole) , 8.94 (m, 4H, β-pyrrole).

실시예 49 :Example 49:

Phenyl-(4-hydroxyphenyl) ethyne linked porphyrin dimer (MPhenyl- (4-hydroxyphenyl) ethyne linked porphyrin dimer (M 1One =Pt, M= Pt, M 22 =Pt)= Pt)

5,15-Diphenyl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Pt)과 5,10,15-tri(4-hydroxyphenyl)-20-iodophenylporphyrin (M2=Pt)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 19] 5,15-Diphenyl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Pt) and 5,10,15-tri (4-hydroxyphenyl) -20-iodophenylporphyrin (M 2 = Pt ) To synthesize ethyne linked porphyrin dimer. Scheme 19

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.17 (d, 2H, Ar-H), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.04 (m, 4H, Ar-H), 8.23 (m, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.35 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.79 (s, 4H, β-pyrrole), 8.85 (d, 2H, β-pyrrole), 8.88 (m, 4H, β-pyrrole), 8.94 (m, 4H, β-pyrrole), 8.92 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.17 (d, 2H, Ar-H), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H ), 8.04 (m, 4H, Ar-H), 8.23 (m, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.35 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.79 (s, 4H, β-pyrrole), 8.85 (d, 2H, β-pyrrole), 8.88 (m, 4H, β-pyrrole) , 8.94 (m, 4H, β-pyrrole), 8.92 (d, 2H, β-pyrrole).

실시예 50 :Example 50:

메시틸-(4-하이드록시페닐) 에타인링크된 폴피린 다이머(Mesityl-(4- hydroxyphenyl) ethyne linked porphyrin dimer) (MMesityl- (4-hydroxyphenyl) ethyne linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =2H)= 2H)

5,15-Dimesityl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(4-hydroxyphenyl)-20-iodophenylporphyrin (M2=2H)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 20] 5,15-Dimesityl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (4-hydroxyphenyl) -20-iodophenylporphyrin (M 2 = 2H ) To synthesize ethyne linked porphyrin dimer. Scheme 20

1H NMR (CDCl3) δ1.87 (s, 3H, CH3), 2.65 (s, 6H, CH3), 4.12 (s, 3H, OCH3), 7.17 (d, 2H, Ar-H), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (m, 4H, Ar-H), 8.28 (m, 4H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (m, 6H, β-pyrrole), 8.84 (m, 6H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 3H, CH 3 ), 2.65 (s, 6H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.17 (d, 2H, Ar—H), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (m, 4H, Ar-H), 8.28 (m, 4H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (m, 6H, β-pyrrole), 8.84 (m, 6H, β-pyrrole).

실시예 51 :Example 51:

Mesityl-(4-hydroxyphenyl) ethyne linked porphyrin dimer (MMesityl- (4-hydroxyphenyl) ethyne linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =Zn)= Zn)

5,15-Dimesityl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(4-hydroxyphenyl)-20-iodophenylporphyrin (M2=Zn)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 20] 5,15-Dimesityl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (4-hydroxyphenyl) -20-iodophenylporphyrin (M 2 = Zn ) To synthesize ethyne linked porphyrin dimer. Scheme 20

1H NMR (CDCl3) δ1.87 (s, 3H, CH3), 2.65 (s, 6H, CH3), 4.12 (s, 3H, OCH3), 7.17 (d, 2H, Ar-H), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (m, 4H, Ar-H), 8.27 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 3H, CH 3 ), 2.65 (s, 6H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.17 (d, 2H, Ar—H), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (m, 4H, Ar-H), 8.27 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole).

실시예 52 :Example 52:

Mesityl-(4-hydroxyphenyl) ethyne linked porphyrin dimer (MMesityl- (4-hydroxyphenyl) ethyne linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =Pt)= Pt)

5,15-Dimesityl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(4-hydroxyphenyl)-20-iodophenylporphyrin (M2=Pt)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 20] 5,15-Dimesityl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (4-hydroxyphenyl) -20-iodophenylporphyrin (M 2 = Pt ) To synthesize ethyne linked porphyrin dimer. Scheme 20

1H NMR (CDCl3) δ1.87 (s, 3H, CH3), 2.65 (s, 6H, CH3), 4.12 (s, 3H, OCH3), 7.17 (d, 2H, Ar-H), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (m, 4H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (m, 4H, Ar-H), 8.45 (d, 2H, Ar-H), 8.78 (m, 8H, β-pyrrole), 8.85 (m, 6H, β-pyrrole), 8.91 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 3H, CH 3 ), 2.65 (s, 6H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.17 (d, 2H, Ar—H), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (m, 4H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (m, 4H, Ar-H), 8.45 (d, 2H, Ar-H), 8.78 (m, 8H, β-pyrrole), 8.85 (m, 6H, β-pyrrole), 8.91 (d, 2H, β-pyrrole).

실시예 53 :Example 53:

Mesityl-(4-hydroxyphenyl) ethyne linked porphyrin dimer (MMesityl- (4-hydroxyphenyl) ethyne linked porphyrin dimer (M 1One =Zn, M= Zn, M 22 =Zn)= Zn)

5,15-Dimesityl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Zn)과 5,10,15-tri(4-hydroxyphenyl)-20-iodophenylporphyrin (M2=Zn)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 20] 5,15-Dimesityl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Zn) and 5,10,15-tri (4-hydroxyphenyl) -20-iodophenylporphyrin (M 2 = Zn ) To synthesize ethyne linked porphyrin dimer. Scheme 20

1H NMR (CDCl3) δ1.87 (s, 3H, CH3), 2.65 (s, 6H, CH3), 4.12 (s, 3H, OCH3), 7.17 (d, 2H, Ar-H), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (m, 4H, Ar-H), 8.28 (m, 4H, Ar-H), 8.33 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.79 (m, 4H, β-pyrrole), 8.85 (m, 6H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 3H, CH 3 ), 2.65 (s, 6H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.17 (d, 2H, Ar—H), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (m, 4H, Ar-H), 8.28 (m, 4H, Ar-H), 8.33 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.79 (m, 4H, β-pyrrole), 8.85 (m, 6H, β-pyrrole).

실시예 54 :Example 54:

Mesityl-(4-hydroxyphenyl) ethyne linked porphyrin dimer (MMesityl- (4-hydroxyphenyl) ethyne linked porphyrin dimer (M 1One =Zn, M= Zn, M 22 =Pt)= Pt)

5,15-Dimesityl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Zn)과 5,10,15-tri(4-hydroxyphenyl)-20-iodophenylporphyrin (M2=Pt)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 20] 5,15-Dimesityl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Zn) and 5,10,15-tri (4-hydroxyphenyl) -20-iodophenylporphyrin (M 2 = Pt ) To synthesize ethyne linked porphyrin dimer. Scheme 20

1H NMR (CDCl3) δ1.87 (s, 3H, CH3), 2.65 (s, 6H, CH3), 4.12 (s, 3H, OCH3), 7.17 (d, 2H, Ar-H), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (m, 4H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (m, 4H, Ar-H), 8.45 (d, 2H, Ar-H), 8.79 (m, 8H, β-pyrrole), 8.87 (m, 6H, β-pyrrole), 8.92 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 3H, CH 3 ), 2.65 (s, 6H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.17 (d, 2H, Ar—H), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (m, 4H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (m, 4H, Ar-H), 8.45 (d, 2H, Ar-H), 8.79 (m, 8H, β-pyrrole), 8.87 (m, 6H, β-pyrrole), 8.92 (d, 2H, β-pyrrole).

실시예 55 :Example 55:

Mesityl-(4-hydroxyphenyl) ethyne linked porphyrin dimer (MMesityl- (4-hydroxyphenyl) ethyne linked porphyrin dimer (M 1One =Pt, M= Pt, M 22 =Zn)= Zn)

5,15-Dimesityl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Pt)과 5,10,15-tri(4-hydroxyphenyl)-20-iodophenylporphyrin (M2=Zn)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 20] 5,15-Dimesityl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Pt) and 5,10,15-tri (4-hydroxyphenyl) -20-iodophenylporphyrin (M 2 = Zn ) To synthesize ethyne linked porphyrin dimer. Scheme 20

1H NMR (CDCl3) δ1.87 (s, 3H, CH3), 2.65 (s, 6H, CH3), 4.12 (s, 3H, OCH3), 7.17 (d, 2H, Ar-H), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (m, 4H, Ar-H), 8.29 (m, 4H, Ar-H), , 8.36 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.87 (m, 4H, β-pyrrole), 8.94 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 3H, CH 3 ), 2.65 (s, 6H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.17 (d, 2H, Ar—H), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (m, 4H, Ar-H), 8.29 (m, 4H, Ar-H),, 8.36 (d, 2H , Ar-H), 8.49 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.87 (m, 4H, β-pyrrole), 8.94 (m, 4H, β-pyrrole).

실시예 56 :Example 56:

Mesityl-(4-hydroxyphenyl) ethyne linked porphyrin dimer (MMesityl- (4-hydroxyphenyl) ethyne linked porphyrin dimer (M 1One =Pt, M= Pt, M 22 =Pt)= Pt)

5,15-Dimesityl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Pt)과 5,10,15-tri(4-hydroxyphenyl)-20-iodophenylporphyrin (M2=Pt)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 20] 5,15-Dimesityl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Pt) and 5,10,15-tri (4-hydroxyphenyl) -20-iodophenylporphyrin (M 2 = Pt ) To synthesize ethyne linked porphyrin dimer. Scheme 20

1H NMR (CDCl3) δ1.87 (s, 3H, CH3), 2.65 (s, 6H, CH3), 4.12 (s, 3H, OCH3), 7.17 (d, 2H, Ar-H), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (m, 4H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.36 (d, 2H, Ar-H), 8.48 (d, 2H, Ar-H), 8.79 (s, 4H, β-pyrrole), 8.85 (d, 2H, β-pyrrole), 8.87 (m, 4H, β-pyrrole), 8.91 (d, 2H, β-pyrrole), 8.94 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 3H, CH 3 ), 2.65 (s, 6H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.17 (d, 2H, Ar—H), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (m, 4H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.36 (d, 2H, Ar-H), 8.48 (d, 2H, Ar-H), 8.79 (s, 4H, β-pyrrole), 8.85 (d, 2H, β-pyrrole), 8.87 (m, 4H, β-pyrrole), 8.91 (d, 2H, β-pyrrole), 8.94 (m, 4H, β-pyrrole).

실시예 57 :Example 57:

Phenyl-(3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (MPhenyl- (3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =2H)= 2H)

5,15-Diphenyl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(3,5-dihydroxyphenyl)-20-iodophenylporphyrin (M2=2H)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 21] 5,15-Diphenyl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (3,5-dihydroxyphenyl) -20-iodophenylporphyrin (M 2 = 2H) to synthesize ethyne linked porphyrin dimer. Scheme 21

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.23 (m, 2H, Ar-H), 8.29 (m, 5H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H ), 8.23 (m, 2H, Ar-H), 8.29 (m, 5H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole) , 8.85 (m, 4H, β-pyrrole).

실시예 58 :Example 58:

페닐-(3,5-디하이드록시페닐) 에타인링크된 폴피린 다이머(Phenyl-(3,5- dihydroxyphenyl) ethyne linked porphyrin dimer) (MPhenyl- (3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =Zn)= Zn)

5,15-Diphenyl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(3,5-dihydroxyphenyl)-20-iodophenylporphyrin (M2=Zn)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 21] 5,15-Diphenyl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (3,5-dihydroxyphenyl) -20-iodophenylporphyrin (M 2 = Zn) to synthesize ethyne linked porphyrin dimer. Scheme 21

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.21 (m, 2H, Ar-H), 8.29 (m, 5H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.86 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H ), 8.21 (m, 2H, Ar-H), 8.29 (m, 5H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole) , 8.86 (m, 4H, β-pyrrole).

실시예 59 :Example 59:

Phenyl-(3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (MPhenyl- (3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =Pt)= Pt)

5,15-Diphenyl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(3,5-dihydroxyphenyl)-20-iodophenylporphyrin (M2=Pt)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 21] 5,15-Diphenyl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (3,5-dihydroxyphenyl) -20-iodophenylporphyrin (M 2 = Pt) to synthesize ethyne linked porphyrin dimer. Scheme 21

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.28 (m, 5H, Ar-H), 8.36 (d, 2H, Ar-H), 8.49 (d, 4H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.88 (m, 4H, β-pyrrole), 8.94 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H ), 8.28 (m, 5H, Ar-H), 8.36 (d, 2H, Ar-H), 8.49 (d, 4H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.88 (m, 4H, β-pyrrole), 8.94 (m, 4H, β-pyrrole).

실시예 60 :Example 60:

Phenyl-(3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (MPhenyl- (3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (M 1One =Zn, M= Zn, M 22 =Zn)= Zn)

5,15-Diphenyl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Zn)과 5,10,15-tri(3,5-dihydroxyphenyl)-20-iodophenylporphyrin (M2=Zn)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 21] 5,15-Diphenyl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Zn) and 5,10,15-tri (3,5-dihydroxyphenyl) -20-iodophenylporphyrin (M 2 = Zn) to synthesize ethyne linked porphyrin dimer. Scheme 21

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.21 (m, 2H, Ar-H), 8.29 (m, 5H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.48 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (m, 6H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H ), 8.21 (m, 2H, Ar-H), 8.29 (m, 5H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.48 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (m, 6H, β-pyrrole) .

실시예 61 :Example 61:

Phenyl-(3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (MPhenyl- (3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (M 1One =Zn, M= Zn, M 22 =Pt)= Pt)

5,15-Diphenyl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Zn)과 5,10,15-tri(3,5-dihydroxyphenyl)-20-iodophenylporphyrin (M2=Pt)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 21] 5,15-Diphenyl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Zn) and 5,10,15-tri (3,5-dihydroxyphenyl) -20-iodophenylporphyrin (M 2 = Pt) to synthesize ethyne linked porphyrin dimer. Scheme 21

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.23 (m, 2H, Ar-H), 8.29 (m, 5H, Ar-H), 8.31 (m, 4H, Ar-H), 8.43 (d, 2H, Ar-H), 8.54 (d, 2H, Ar-H), 8.77 (m, 4H, β-pyrrole), 8.79 (s, 4H, β-pyrrole), 8.85 (m, 6H, β-pyrrole), 8.92 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H ), 8.23 (m, 2H, Ar-H), 8.29 (m, 5H, Ar-H), 8.31 (m, 4H, Ar-H), 8.43 (d, 2H, Ar-H), 8.54 (d, 2H, Ar-H), 8.77 (m, 4H, β-pyrrole), 8.79 (s, 4H, β-pyrrole), 8.85 (m, 6H, β-pyrrole), 8.92 (d, 2H, β-pyrrole) .

실시예 62 :Example 62:

Phenyl-(3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (MPhenyl- (3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (M 1One =Pt, M= Pt, M 22 =Zn)= Zn)

5,15-Diphenyl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Pt)과 5,10,15-tri(3,5-dihydroxyphenyl)-20-iodophenylporphyrin (M2=Zn)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 21] 5,15-Diphenyl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Pt) and 5,10,15-tri (3,5-dihydroxyphenyl) -20-iodophenylporphyrin (M 2 = Zn) to synthesize ethyne linked porphyrin dimer. Scheme 21

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.27 (m, 5H, Ar-H), 8.35 (d, 2H, Ar-H), 8.49 (m, 4H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.88 (m, 4H, β-pyrrole), 8.95 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H ), 8.27 (m, 5H, Ar-H), 8.35 (d, 2H, Ar-H), 8.49 (m, 4H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.88 (m, 4H, β-pyrrole), 8.95 (m, 4H, β-pyrrole).

실시예 63 :Example 63:

Phenyl-(3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (MPhenyl- (3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (M 1One =Pt, M= Pt, M 22 =Pt)= Pt)

5,15-Diphenyl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Pt)과 5,10,15-tri(3,5-dihydroxyphenyl)-20-iodophenylporphyrin (M2=Pt)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 21] 5,15-Diphenyl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Pt) and 5,10,15-tri (3,5-dihydroxyphenyl) -20-iodophenylporphyrin (M 2 = Pt) to synthesize ethyne linked porphyrin dimer. Scheme 21

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.27 (m, 5H, Ar-H), 8.32 (d, 2H, Ar-H), 8.36 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.53 (d, 2H, Ar-H), 8.79 (s, 4H, β-pyrrole), 8.84 (d, 2H, β-pyrrole), 8.87 (m, 4H, β-pyrrole), 8.92 (d, 2H, β-pyrrole), 8.94 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H ), 8.27 (m, 5H, Ar-H), 8.32 (d, 2H, Ar-H), 8.36 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.53 (d, 2H, Ar-H), 8.79 (s, 4H, β-pyrrole), 8.84 (d, 2H, β-pyrrole), 8.87 (m, 4H, β-pyrrole), 8.92 (d, 2H, β-pyrrole) , 8.94 (m, 4H, β-pyrrole).

실시예 64 :Example 64:

Mesityl-(3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (MMesityl- (3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =2H)= 2H)

5,15-Dimesityl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(3,5-dihydroxyphenyl)-20-iodophenylporphyrin (M2=2H)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 22] 5,15-Dimesityl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (3,5-dihydroxyphenyl) -20-iodophenylporphyrin (M 2 = 2H) to synthesize ethyne linked porphyrin dimer. Scheme 22

1H NMR (CDCl3) δ1.87 (s, 3H, CH3), 2.65 (s, 6H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (m, 5H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 3H, CH 3 ), 2.65 (s, 6H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 2H, Ar—H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (m, 5H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole).

실시예 65 :Example 65:

Mesityl-(3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (MMesityl- (3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =Zn)= Zn)

5,15-Dimesityl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(3,5-dihydroxyphenyl)-20-iodophenylporphyrin (M2=Zn)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 22] 5,15-Dimesityl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (3,5-dihydroxyphenyl) -20-iodophenylporphyrin (M 2 = Zn) to synthesize ethyne linked porphyrin dimer. Scheme 22

1H NMR (CDCl3) δ1.87 (s, 3H, CH3), 2.65 (s, 6H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (m, 5H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.50 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 3H, CH 3 ), 2.65 (s, 6H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 2H, Ar—H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (m, 5H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.50 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole).

실시예 66 :Example 66:

Mesityl-(3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (MMesityl- (3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =Pt)= Pt)

5,15-Dimesityl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(3,5-dihydroxyphenyl)-20-iodophenylporphyrin (M2=Pt)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 22] 5,15-Dimesityl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (3,5-dihydroxyphenyl) -20-iodophenylporphyrin (M 2 = Pt) to synthesize ethyne linked porphyrin dimer. Scheme 22

1H NMR (CDCl3) δ1.87 (s, 3H, CH3), 2.65 (s, 6H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (m, 5H, Ar-H), 8.32 (m, 4H, Ar-H), 8.45 (d, 2H, Ar-H), 8.53 (d, 2H, Ar-H), 8.79 (m, 8H, β-pyrrole), 8.85 (m, 6H, β-pyrrole), 8.91 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 3H, CH 3 ), 2.65 (s, 6H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 2H, Ar—H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (m, 5H, Ar-H), 8.32 (m, 4H, Ar-H), 8.45 (d, 2H, Ar-H), 8.53 (d, 2H, Ar-H), 8.79 (m, 8H, β-pyrrole), 8.85 (m, 6H, β-pyrrole), 8.91 (d, 2H, β-pyrrole).

실시예 67 :Example 67:

Mesityl-(3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (MMesityl- (3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (M 1One =Zn, M= Zn, M 22 =Zn)= Zn)

5,15-Dimesityl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Zn)과 5,10,15-tri(3,5-dihydroxyphenyl)-20-iodophenylporphyrin (M2=Zn)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 22] 5,15-Dimesityl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Zn) and 5,10,15-tri (3,5-dihydroxyphenyl) -20-iodophenylporphyrin (M 2 = Zn) to synthesize ethyne linked porphyrin dimer. Scheme 22

1H NMR (CDCl3) δ1.87 (s, 3H, CH3), 2.65 (s, 6H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.27 (m, 5H, Ar-H), 8.32 (d, 2H, Ar-H), 8.44 (d, 2H, Ar-H), 8.50 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.81 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 3H, CH 3 ), 2.65 (s, 6H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 2H, Ar—H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.27 (m, 5H, Ar-H), 8.32 (d, 2H, Ar-H), 8.44 (d, 2H, Ar-H), 8.50 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.81 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole).

실시예 68 :Example 68:

Mesityl-(3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (MMesityl- (3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (M 1One =Zn, M= Zn, M 22 =Pt)= Pt)

5,15-Dimesityl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Zn)과 5,10,15-tri(3,5-dihydroxyphenyl)-20-iodophenylporphyrin (M2=Pt)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 22] 5,15-Dimesityl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Zn) and 5,10,15-tri (3,5-dihydroxyphenyl) -20-iodophenylporphyrin (M 2 = Pt) to synthesize ethyne linked porphyrin dimer. Scheme 22

1H NMR (CDCl3) δ1.87 (s, 3H, CH3), 2.65 (s, 6H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (m, 5H, Ar-H), 8.32 (d, 2H, Ar-H), 8.44 (d, 2H, Ar-H), 8.53 (d, 2H, Ar-H), 8.79 (m, 8H, β-pyrrole), , 8.85 (m, 4H, β-pyrrole), 8.88 (d, 2H, β-pyrrole), 8.92 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 3H, CH 3 ), 2.65 (s, 6H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 2H, Ar—H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (m, 5H, Ar-H), 8.32 (d, 2H, Ar-H), 8.44 (d, 2H, Ar-H), 8.53 (d, 2H, Ar-H), 8.79 (m, 8H, β-pyrrole), 8.85 (m, 4H, β-pyrrole), 8.88 (d, 2H, β-pyrrole), 8.92 (d, 2 H, β-pyrrole).

실시예 69 :Example 69:

Mesityl-(3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (MMesityl- (3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (M 1One =Pt, M= Pt, M 22 =Zn)= Zn)

5,15-Dimesityl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Pt)과 5,10,15-tri(3,5-dihydroxyphenyl)-20-iodophenylporphyrin (M2=Zn)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 22] 5,15-Dimesityl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Pt) and 5,10,15-tri (3,5-dihydroxyphenyl) -20-iodophenylporphyrin (M 2 = Zn) to synthesize ethyne linked porphyrin dimer. Scheme 22

1H NMR (CDCl3) δ1.87 (s, 3H, CH3), 2.65 (s, 6H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.36 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.51 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.88 (m, 4H, β-pyrrole), 8.93 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 3H, CH 3 ), 2.65 (s, 6H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 2H, Ar—H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.36 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.51 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.88 (m, 4H, β-pyrrole), 8.93 (m, 4H, β-pyrrole).

실시예 70 :Example 70:

Mesityl-(3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (MMesityl- (3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (M 1One =Pt, M= Pt, M 22 =Pt)= Pt)

5,15-Dimesityl-10-(4-ethynylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Pt)과 5,10,15-tri(3,5-dihydroxyphenyl)-20-iodophenylporphyrin (M2=Pt)을 사용하여 ethyne linked porphyrin dimer의 제조 방법으로 합성한다. [반응식 22] 5,15-Dimesityl-10- (4-ethynylphenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Pt) and 5,10,15-tri (3,5-dihydroxyphenyl) -20-iodophenylporphyrin (M 2 = Pt) to synthesize ethyne linked porphyrin dimer. Scheme 22

1H NMR (CDCl3) δ1.87 (s, 3H, CH3), 2.65 (s, 6H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (m, 4H, Ar-H), 8.31 (d, 2H, Ar-H), 8.35 (d, 2H, Ar-H), 8.51 (d, 2H, Ar-H), 8.53 (d, 2H, Ar-H), 8.80 (s, 4H, β-pyrrole), 8.86 (d, 2H, β-pyrrole), 8.91 (m, 10H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 3H, CH 3 ), 2.65 (s, 6H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 2H, Ar—H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (m, 4H, Ar-H), 8.31 (d, 2H, Ar-H), 8.35 (d, 2H, Ar-H), 8.51 (d, 2H, Ar-H), 8.53 (d, 2H, Ar-H), 8.80 (s, 4H, β-pyrrole), 8.86 (d, 2H, β-pyrrole), 8.91 (m, 10H, β-pyrrole).

실시예 71 :Example 71:

페닐 에타인, C-C 직접링크된 덴드리머(Phenyl ethyne, C-C direct linked dendrimer) (MPhenyl ethyne, C-C direct linked dendrimer (M 1One =2H, M= 2H, M 22 =2H)= 2H)

Phenyl-(4-bromophenyl) ethyne linked porphyrin dimer (M1=2H, M2=2H)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 23] Phenyl- (4-bromophenyl) ethyne linked porphyrin dimer (M 1 = 2H, M 2 = 2H) is synthesized by the method of producing CC direct linked dendrimer. Scheme 23

실시예 72 :Example 72:

Phenyl ethyne, C-C direct linked dendrimer (MPhenyl ethyne, C-C direct linked dendrimer (M 1One =2H, M= 2H, M 22 =Zn)= Zn)

Phenyl-(4-bromophenyl) ethyne linked porphyrin dimer (M1=2H, M2=Zn)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 23] Phenyl- (4-bromophenyl) ethyne linked porphyrin dimer (M 1 = 2H, M 2 = Zn) was used to synthesize CC direct linked dendrimer. Scheme 23

실시예 73 :Example 73:

Phenyl ethyne, C-C direct linked dendrimer (MPhenyl ethyne, C-C direct linked dendrimer (M 1One =2H, M= 2H, M 22 =Pt)= Pt)

Phenyl-(4-bromophenyl) ethyne linked porphyrin dimer (M1=2H, M2=Pt)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 23] Phenyl- (4-bromophenyl) ethyne linked porphyrin dimer (M 1 = 2H, M 2 = Pt) was used to synthesize CC direct linked dendrimer. Scheme 23

실시예 74 :Example 74:

Phenyl ethyne, C-C direct linked dendrimer (MPhenyl ethyne, C-C direct linked dendrimer (M 1One =Zn, M= Zn, M 22 =Zn)= Zn)

Phenyl-(4-bromophenyl) ethyne linked porphyrin dimer (M1=Zn, M2=Zn)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 23] Phenyl- (4-bromophenyl) ethyne linked porphyrin dimer (M 1 = Zn, M 2 = Zn) is synthesized by the method of producing CC direct linked dendrimer. Scheme 23

실시예 75 :Example 75:

Phenyl ethyne, C-C direct linked dendrimer (MPhenyl ethyne, C-C direct linked dendrimer (M 1One =Zn, M= Zn, M 22 =Pt)= Pt)

Phenyl-(4-bromophenyl) ethyne linked porphyrin dimer (M1=Zn, M2=Pt)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 23] Phenyl- (4-bromophenyl) ethyne linked porphyrin dimer (M 1 = Zn, M 2 = Pt) was synthesized by the method of producing CC direct linked dendrimer. Scheme 23

실시예 76 :Example 76:

Phenyl ethyne, C-C direct linked dendrimer (MPhenyl ethyne, C-C direct linked dendrimer (M 1One =Pt, M= Pt, M 22 =Zn)= Zn)

Phenyl-(4-bromophenyl) ethyne linked porphyrin dimer (M1=Pt, M2=Zn)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 23] Phenyl- (4-bromophenyl) ethyne linked porphyrin dimer (M 1 = Pt, M 2 = Zn) was used to synthesize CC direct linked dendrimer. Scheme 23

실시예 77 :Example 77:

Phenyl ethyne, C-C direct linked dendrimer (MPhenyl ethyne, C-C direct linked dendrimer (M 1One =Pt, M= Pt, M 22 =Pt)= Pt)

Phenyl-(4-bromophenyl) ethyne linked porphyrin dimer (M1=Pt, M2=Pt)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 23] Phenyl- (4-bromophenyl) ethyne linked porphyrin dimer (M 1 = Pt, M 2 = Pt) is synthesized by the method of producing CC direct linked dendrimer. Scheme 23

실시예 78 :Example 78:

메시틸 에타인, C-C 직접링크된 덴드리머(Mesityl ethyne, C-C direct linked dendrimer) (MMesityl ethyne, C-C direct linked dendrimer (M 1One =2H, M= 2H, M 22 =2H)= 2H)

Mesityl-(4-bromophenyl) ethyne linked porphyrin dimer (M1=2H, M2=2H)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 24] Mesityl- (4-bromophenyl) ethyne linked porphyrin dimer (M 1 = 2H, M 2 = 2H) is synthesized by the method of producing CC direct linked dendrimer. Scheme 24

실시예 79 :Example 79:

Mesityl ethyne, C-C direct linked dendrimer (MMesityl ethyne, C-C direct linked dendrimer (M 1One =2H, M= 2H, M 22 =Zn)= Zn)

Mesityl-(4-bromophenyl) ethyne linked porphyrin dimer (M1=2H, M2=Zn)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다.[반응식 24] Mesityl- (4-bromophenyl) ethyne linked porphyrin dimer (M 1 = 2H, M 2 = Zn) is synthesized by the method of producing CC direct linked dendrimer. Scheme 24

실시예 80 :Example 80:

Mesityl ethyne, C-C direct linked dendrimer (MMesityl ethyne, C-C direct linked dendrimer (M 1One =2H, M= 2H, M 22 =Pt)= Pt)

Mesityl-(4-bromophenyl) ethyne linked porphyrin dimer (M1=2H, M2=Pt)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다.[반응식 24] Mesityl- (4-bromophenyl) ethyne linked porphyrin dimer (M 1 = 2H, M 2 = Pt) is synthesized by the method of producing CC direct linked dendrimer. Scheme 24

실시예 81 :Example 81:

Mesityl ethyne, C-C direct linked dendrimer (MMesityl ethyne, C-C direct linked dendrimer (M 1One =Zn, M= Zn, M 22 =Zn)= Zn)

Mesityl-(4-bromophenyl) ethyne linked porphyrin dimer (M1=Zn, M2=Zn)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다.[반응식 24] Mesityl- (4-bromophenyl) ethyne linked porphyrin dimer (M 1 = Zn, M 2 = Zn) is synthesized by the method of producing CC direct linked dendrimer. Scheme 24

실시예 82 :Example 82:

Mesityl ethyne, C-C direct linked dendrimer (MMesityl ethyne, C-C direct linked dendrimer (M 1One =Zn, M= Zn, M 22 =Pt)= Pt)

Mesityl-(4-bromophenyl) ethyne linked porphyrin dimer (M1=Zn, M2=Pt)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다.[반응식 24] Mesityl- (4-bromophenyl) ethyne linked porphyrin dimer (M 1 = Zn, M 2 = Pt) is synthesized by the method of producing CC direct linked dendrimer. Scheme 24

실시예 83 :Example 83:

Mesityl ethyne, C-C direct linked dendrimer (MMesityl ethyne, C-C direct linked dendrimer (M 1One =Pt, M= Pt, M 22 =Zn)= Zn)

Mesityl-(4-bromophenyl) ethyne linked porphyrin dimer (M1=Pt, M2=Zn)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다.[반응식 24] Mesityl- (4-bromophenyl) ethyne linked porphyrin dimer (M 1 = Pt, M 2 = Zn) was synthesized by the method of producing CC direct linked dendrimer. Scheme 24

실시예 84 :Example 84:

Mesityl ethyne, C-C direct linked dendrimer (MMesityl ethyne, C-C direct linked dendrimer (M 1One =Pt, M= Pt, M 22 =Pt)= Pt)

Mesityl-(4-bromophenyl) ethyne linked porphyrin dimer (M1=Pt, M2=Pt)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다.[반응식 24] Mesityl- (4-bromophenyl) ethyne linked porphyrin dimer (M 1 = Pt, M 2 = Pt) is synthesized by the method of producing a CC direct linked dendrimer. Scheme 24

실시예 85 :Example 85:

페닐 에타인, (3,5)-C-C 직접링크된 덴드리머(Phenyl ethyne, (3,5)-C-C direct linked dendrimer) (MPhenyl ethyne, (3,5) -C-C direct linked dendrimer (M 1One =2H, M= 2H, M 22 =2H)= 2H)

Phenyl-(3,5-dibromophenyl) ethyne linked porphyrin dimer (M1=2H, M2=2H)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 25] Phenyl- (3,5-dibromophenyl) ethyne linked porphyrin dimer (M 1 = 2H, M 2 = 2H) is synthesized by the method of producing a CC direct linked dendrimer. Scheme 25

실시예 86 :Example 86:

Phenyl ethyne, (3,5)-C-C direct linked dendrimer (MPhenyl ethyne, (3,5) -C-C direct linked dendrimer (M 1One =2H, M= 2H, M 2 2 =Zn)= Zn)

Phenyl-(3,5-dibromophenyl) ethyne linked porphyrin dimer (M1=2H, M2=Zn)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 25] Phenyl- (3,5-dibromophenyl) ethyne linked porphyrin dimer (M 1 = 2H, M 2 = Zn) is synthesized by the method of producing CC direct linked dendrimer. Scheme 25

실시예 87 :Example 87:

Phenyl ethyne, (3,5)-C-C direct linked dendrimer (MPhenyl ethyne, (3,5) -C-C direct linked dendrimer (M 1One =2H, M= 2H, M 2 2 =Pt)= Pt)

Phenyl-(3,5-dibromophenyl) ethyne linked porphyrin dimer (M1=2H, M2=Pt)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 25] Phenyl- (3,5-dibromophenyl) ethyne linked porphyrin dimer (M 1 = 2H, M 2 = Pt) was synthesized by the method of producing CC direct linked dendrimer. Scheme 25

실시예 88 :Example 88:

Phenyl ethyne, (3,5)-C-C direct linked dendrimer (MPhenyl ethyne, (3,5) -C-C direct linked dendrimer (M 1One =Zn, M= Zn, M 2 2 =Zn)= Zn)

Phenyl-(3,5-dibromophenyl) ethyne linked porphyrin dimer (M1=Zn, M2=Zn)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 25] Phenyl- (3,5-dibromophenyl) ethyne linked porphyrin dimer (M 1 = Zn, M 2 = Zn) is synthesized by the method of producing a CC direct linked dendrimer. Scheme 25

실시예 89 :Example 89:

Phenyl ethyne, (3,5)-C-C direct linked dendrimer (MPhenyl ethyne, (3,5) -C-C direct linked dendrimer (M 1One =Zn, M= Zn, M 2 2 =Pt)= Pt)

Phenyl-(3,5-dibromophenyl) ethyne linked porphyrin dimer (M1=Zn, M2=Pt)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 25] Phenyl- (3,5-dibromophenyl) ethyne linked porphyrin dimer (M 1 = Zn, M 2 = Pt) is synthesized by the method of producing a CC direct linked dendrimer. Scheme 25

실시예 90 :Example 90:

Phenyl ethyne, (3,5)-C-C direct linked dendrimer (MPhenyl ethyne, (3,5) -C-C direct linked dendrimer (M 1One =Pt, M= Pt, M 2 2 =Zn)= Zn)

Phenyl-(3,5-dibromophenyl) ethyne linked porphyrin dimer (M1=Pt, M2=Zn)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 25] Phenyl- (3,5-dibromophenyl) ethyne linked porphyrin dimer (M 1 = Pt, M 2 = Zn) is synthesized by the method of producing a CC direct linked dendrimer. Scheme 25

실시예 91 :Example 91:

Phenyl ethyne, (3,5)-C-C direct linked dendrimer (MPhenyl ethyne, (3,5) -C-C direct linked dendrimer (M 1One =Pt, M= Pt, M 2 2 =Pt)= Pt)

Phenyl-(3,5-dibromophenyl) ethyne linked porphyrin dimer (M1=Pt, M2=Pt)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 25] Phenyl- (3,5-dibromophenyl) ethyne linked porphyrin dimer (M 1 = Pt, M 2 = Pt) is synthesized by the method of producing a CC direct linked dendrimer. Scheme 25

실시예 92 :Example 92:

메시틸 에타인,(3,5)-C-C 직접링크된 덴드리머(Mesityl ethyne,(3,5)-C-C direct linked dendrimer) (MMesityl ethyne, (3,5) -C-C direct linked dendrimer (M 1One =2H, M= 2H, M 22 =2H)= 2H)

Mesityl-(3,5-dibromophenyl) ethyne linked porphyrin dimer (M1=2H, M2=2H)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 26] Mesityl- (3,5-dibromophenyl) ethyne linked porphyrin dimer (M 1 = 2H, M 2 = 2H) is synthesized by the method of producing a CC direct linked dendrimer. Scheme 26

실시예 93 :Example 93:

Mesityl ethyne,(3,5)-C-C direct linked dendrimer (MMesityl ethyne, (3,5) -C-C direct linked dendrimer (M 1One =2H, M= 2H, M 2 2 =Zn)= Zn)

Mesityl-(3,5-dibromophenyl) ethyne linked porphyrin dimer (M1=2H, M2=Zn)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 26] Mesityl- (3,5-dibromophenyl) ethyne linked porphyrin dimer (M 1 = 2H, M 2 = Zn) is synthesized by the method of producing a CC direct linked dendrimer. Scheme 26

실시예 94 :Example 94:

Mesityl ethyne,(3,5)-C-C direct linked dendrimer (MMesityl ethyne, (3,5) -C-C direct linked dendrimer (M 1One =2H, M= 2H, M 2 2 =Pt)= Pt)

Mesityl-(3,5-dibromophenyl) ethyne linked porphyrin dimer (M1=2H, M2=Pt)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 26] Mesityl- (3,5-dibromophenyl) ethyne linked porphyrin dimer (M 1 = 2H, M 2 = Pt) is synthesized by the method of producing a CC direct linked dendrimer. Scheme 26

실시예 95 :Example 95:

Mesityl ethyne,(3,5)-C-C direct linked dendrimer (MMesityl ethyne, (3,5) -C-C direct linked dendrimer (M 1One =Zn, M= Zn, M 2 2 =Zn)= Zn)

Mesityl-(3,5-dibromophenyl) ethyne linked porphyrin dimer (M1=Zn, M2=Zn)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 26] Mesityl- (3,5-dibromophenyl) ethyne is synthesized using a method of producing a CC direct linked dendrimer using a linked porphyrin dimer (M 1 = Zn, M 2 = Zn). Scheme 26

실시예 96 :Example 96:

Mesityl ethyne,(3,5)-C-C direct linked dendrimer (MMesityl ethyne, (3,5) -C-C direct linked dendrimer (M 1One =Zn, M= Zn, M 2 2 =Pt)= Pt)

Mesityl-(3,5-dibromophenyl) ethyne linked porphyrin dimer (M1=Zn, M2=Pt)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 26] Mesityl- (3,5-dibromophenyl) ethyne is synthesized by a method of producing a CC direct linked dendrimer using a linked porphyrin dimer (M 1 = Zn, M 2 = Pt). Scheme 26

실시예 97 :Example 97:

Mesityl ethyne,(3,5)-C-C direct linked dendrimer (MMesityl ethyne, (3,5) -C-C direct linked dendrimer (M 1One =Pt, M= Pt, M 2 2 =Zn)= Zn)

Mesityl-(3,5-dibromophenyl) ethyne linked porphyrin dimer (M1=Pt, M2=Zn)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 26] Mesityl- (3,5-dibromophenyl) ethyne is synthesized by the method of producing CC direct linked dendrimer using linked porphyrin dimer (M 1 = Pt, M 2 = Zn). Scheme 26

실시예 98 :Example 98:

Mesityl ethyne,(3,5)-C-C direct linked dendrimer (MMesityl ethyne, (3,5) -C-C direct linked dendrimer (M 1One =Pt, M= Pt, M 2 2 =Pt)= Pt)

Mesityl-(3,5-dibromophenyl) ethyne linked porphyrin dimer (M1=Pt, M2=Pt)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 26] Mesityl- (3,5-dibromophenyl) ethyne linked porphyrin dimer (M 1 = Pt, M 2 = Pt) is synthesized by the method of producing CC direct linked dendrimer. Scheme 26

실시예 99 :Example 99:

페닐 에타인, 에테르-브릿지드된 덴드리머(Phenyl ethyne, ether-bridged dendrimer) (MPhenyl ethyne, ether-bridged dendrimer (M 1One =2H, M= 2H, M 22 =2H)= 2H)

Phenyl-(4-hydroxyphenyl) ethyne linked porphyrin dimer (M1=2H, M2=2H)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 27] Phenyl- (4-hydroxyphenyl) ethyne linked porphyrin dimer (M 1 = 2H, M 2 = 2H) is synthesized by the method for preparing ether-bridged dendrimer. Scheme 27

실시예 100 :Example 100:

Phenyl ethyne, ether-bridged dendrimer (MPhenyl ethyne, ether-bridged dendrimer (M 1One =2H, M= 2H, M 22 =Zn)= Zn)

Phenyl-(4-hydroxyphenyl) ethyne linked porphyrin dimer (M1=2H, M2=Zn)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 27] Phenyl- (4-hydroxyphenyl) ethyne linked porphyrin dimer (M 1 = 2H, M 2 = Zn) was used to synthesize ether-bridged dendrimer. Scheme 27

실시예 101 :Example 101:

Phenyl ethyne, ether-bridged dendrimer (MPhenyl ethyne, ether-bridged dendrimer (M 1One =2H, M= 2H, M 22 =Pt)= Pt)

Phenyl-(4-hydroxyphenyl) ethyne linked porphyrin dimer (M1=2H, M2=Pt)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 27] Phenyl- (4-hydroxyphenyl) ethyne is synthesized by the ether-bridged dendrimer production method using linked porphyrin dimer (M 1 = 2H, M 2 = Pt). Scheme 27

실시예 102 :Example 102:

Phenyl ethyne, ether-bridged dendrimer (MPhenyl ethyne, ether-bridged dendrimer (M 1One =Zn, M= Zn, M 22 =Zn)= Zn)

Phenyl-(4-hydroxyphenyl) ethyne linked porphyrin dimer (M1=Zn, M2=Zn)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 27] Phenyl- (4-hydroxyphenyl) ethyne linked porphyrin dimers (M 1 = Zn, M 2 = Zn) were used to synthesize ether-bridged dendrimers. Scheme 27

실시예 103 :Example 103:

Phenyl ethyne, ether-bridged dendrimer (MPhenyl ethyne, ether-bridged dendrimer (M 1One =Zn, M= Zn, M 22 =Pt)= Pt)

Phenyl-(4-hydroxyphenyl) ethyne linked porphyrin dimer (M1=Zn, M2=Pt)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 27] Phenyl- (4-hydroxyphenyl) ethyne linked porphyrin dimer (M 1 = Zn, M 2 = Pt) is synthesized by the method of preparing ether-bridged dendrimer. Scheme 27

실시예 104 :Example 104:

Phenyl ethyne, ether-bridged dendrimer (MPhenyl ethyne, ether-bridged dendrimer (M 1One =Pt, M= Pt, M 22 =Zn)= Zn)

Phenyl-(4-hydroxyphenyl) ethyne linked porphyrin dimer (M1=Pt, M2=Zn)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 27] Phenyl- (4-hydroxyphenyl) ethyne was synthesized using ether-bridged dendrimer by using a linked porphyrin dimer (M 1 = Pt, M 2 = Zn). Scheme 27

실시예 105 :Example 105:

Phenyl ethyne, ether-bridged dendrimer (MPhenyl ethyne, ether-bridged dendrimer (M 1One =Pt, M= Pt, M 22 =Pt)= Pt)

Phenyl-(4-hydroxyphenyl) ethyne linked porphyrin dimer (M1=Pt, M2=Pt)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 27] Phenyl- (4-hydroxyphenyl) ethyne is synthesized by using ether-bridged dendrimers using linked porphyrin dimers (M 1 = Pt, M 2 = Pt). Scheme 27

실시예 106 :Example 106:

Mesityl ethyne, ether-bridged dendrimer (MMesityl ethyne, ether-bridged dendrimer (M 1One =2H, M= 2H, M 22 =2H)= 2H)

Mesityl-(4-hydroxyphenyl) ethyne linked porphyrin dimer (M1=2H, M2=2H)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 28] Mesityl- (4-hydroxyphenyl) ethyne linked porphyrin dimer (M 1 = 2H, M 2 = 2H) is synthesized by the method of preparing ether-bridged dendrimer. Scheme 28

실시예 107 :Example 107:

Mesityl ethyne, ether-bridged dendrimer (MMesityl ethyne, ether-bridged dendrimer (M 1One =2H, M= 2H, M 22 =Zn)= Zn)

Mesityl-(4-hydroxyphenyl) ethyne linked porphyrin dimer (M1=2H, M2=Zn)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 28] Mesityl- (4-hydroxyphenyl) ethyne linked porphyrin dimer (M 1 = 2H, M 2 = Zn) is used to synthesize ether-bridged dendrimer. Scheme 28

실시예 108 :Example 108:

Mesityl ethyne, ether-bridged dendrimer (MMesityl ethyne, ether-bridged dendrimer (M 1One =2H, M= 2H, M 22 =Pt)= Pt)

Mesityl-(4-hydroxyphenyl) ethyne linked porphyrin dimer (M1=2H, M2=Pt)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 28] Mesityl- (4-hydroxyphenyl) ethyne linked porphyrin dimer (M 1 = 2H, M 2 = Pt) is used to synthesize ether-bridged dendrimer. Scheme 28

실시예 109 :Example 109:

Mesityl ethyne, ether-bridged dendrimer (MMesityl ethyne, ether-bridged dendrimer (M 1One =Zn, M= Zn, M 22 =Zn)= Zn)

Mesityl-(4-hydroxyphenyl) ethyne linked porphyrin dimer (M1=Zn, M2=Zn)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 28] Mesityl- (4-hydroxyphenyl) ethyne is synthesized by using ether-bridged dendrimers using linked porphyrin dimers (M 1 = Zn, M 2 = Zn). Scheme 28

실시예 110 :Example 110:

Mesityl ethyne, ether-bridged dendrimer (MMesityl ethyne, ether-bridged dendrimer (M 1One =Zn, M= Zn, M 22 =Pt)= Pt)

Mesityl-(4-hydroxyphenyl) ethyne linked porphyrin dimer (M1=Zn, M2=Pt)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 28] Mesityl- (4-hydroxyphenyl) ethyne is synthesized by using ether-bridged dendrimer using M-P-diphenyl (M 1 = Zn, M 2 = Pt). Scheme 28

실시예 111 :Example 111:

Mesityl ethyne, ether-bridged dendrimer (MMesityl ethyne, ether-bridged dendrimer (M 1One =Pt, M= Pt, M 22 =Zn)= Zn)

Mesityl-(4-hydroxyphenyl) ethyne linked porphyrin dimer (M1=Pt, M2=Zn)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 28] Mesityl- (4-hydroxyphenyl) using ethyne linked porphyrin dimer (M 1 = Pt, M 2 = Zn) is synthesized by the method of ether-bridged dendrimer. Scheme 28

실시예 112 :Example 112:

Mesityl ethyne, ether-bridged dendrimer (MMesityl ethyne, ether-bridged dendrimer (M 1One =Pt, M= Pt, M 22 =Pt)= Pt)

Mesityl-(4-hydroxyphenyl) ethyne linked porphyrin dimer (M1=Pt, M2=Pt)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 28] Mesityl- (4-hydroxyphenyl) using ethyne linked porphyrin dimer (M 1 = Pt, M 2 = Pt) is synthesized by the method of ether-bridged dendrimer. Scheme 28

실시예 113 :Example 113:

페닐 에타인, (3,5)-에테르 브릿지드된 덴드리머(Phenyl ethyne, (3,5)-ether-bridged dendrimer) (MPhenyl ethyne, (3,5) -ether-bridged dendrimer (M 1One =2H, M= 2H, M 22 =2H)= 2H)

Phenyl-(3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (M1=2H, M2=2H)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 29] Phenyl- (3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (M 1 = 2H, M 2 = 2H) was used to synthesize ether-bridged dendrimer. Scheme 29

실시예 114 :Example 114:

Phenyl ethyne, (3,5)-ether-bridged dendrimer (MPhenyl ethyne, (3,5) -ether-bridged dendrimer (M 1One =2H, M= 2H, M 22 =Zn)= Zn)

Phenyl-(3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (M1=2H, M2=Zn)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 29] Phenyl- (3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (M 1 = 2H, M 2 = Zn) was used to synthesize ether-bridged dendrimer. Scheme 29

실시예 115 :Example 115:

Phenyl ethyne, (3,5)-ether-bridged dendrimer (MPhenyl ethyne, (3,5) -ether-bridged dendrimer (M 1One =2H, M= 2H, M 22 =Pt)= Pt)

Phenyl-(3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (M1=2H, M2=Pt)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 29] Phenyl- (3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (M 1 = 2H, M 2 = Pt) is synthesized by the method for preparing ether-bridged dendrimer. Scheme 29

실시예 116 :Example 116:

Phenyl ethyne, (3,5)-ether-bridged dendrimer (MPhenyl ethyne, (3,5) -ether-bridged dendrimer (M 1One =Zn, M= Zn, M 22 =Zn)= Zn)

Phenyl-(3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (M1=Zn, M2=Zn)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 29] Phenyl- (3,5-dihydroxyphenyl) ethyne is synthesized by a method of preparing ether-bridged dendrimers using linked porphyrin dimer (M 1 = Zn, M 2 = Zn). Scheme 29

실시예 117 :Example 117:

Phenyl ethyne, (3,5)-ether-bridged dendrimer (MPhenyl ethyne, (3,5) -ether-bridged dendrimer (M 1One =Zn, M= Zn, M 22 =Pt)= Pt)

Phenyl-(3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (M1=Zn, M2=Pt)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 29] Phenyl- (3,5-dihydroxyphenyl) ethyne was synthesized using ether-bridged dendrimer by using a linked porphyrin dimer (M 1 = Zn, M 2 = Pt). Scheme 29

실시예 118 :Example 118:

Phenyl ethyne, (3,5)-ether-bridged dendrimer (MPhenyl ethyne, (3,5) -ether-bridged dendrimer (M 1One =Pt, M= Pt, M 22 =Zn)= Zn)

Phenyl-(3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (M1=Pt, M2=Zn)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 29] Phenyl- (3,5-dihydroxyphenyl) ethyne is synthesized by a method of preparing ether-bridged dendrimer using linked porphyrin dimer (M 1 = Pt, M 2 = Zn). Scheme 29

실시예 119 :Example 119:

Phenyl ethyne, (3,5)-ether-bridged dendrimer (MPhenyl ethyne, (3,5) -ether-bridged dendrimer (M 1One =Pt, M= Pt, M 22 =Pt)= Pt)

Phenyl-(3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (M1=Pt, M2=Pt)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 29] Phenyl- (3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (M 1 = Pt, M 2 = Pt) was synthesized by the method for preparing ether-bridged dendrimer. Scheme 29

실시예 120 :Example 120:

메시틸 에타인,(3,5)-에테르 브릿지드된 덴드리머(Mesityl ethyne,(3,5)-ether- bridged dendrimer) (MMesityl ethyne, (3,5) -ether-bridged dendrimer (M 1One =2H, M= 2H, M 22 =2H)= 2H)

Mesityl-(3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (M1=2H, M2=2H)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 30] Mesityl- (3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (M 1 = 2H, M 2 = 2H) is synthesized by the method for preparing ether-bridged dendrimer. Scheme 30

실시예 121 :Example 121:

Mesityl ethyne,(3,5)-ether-bridged dendrimer (MMesityl ethyne, (3,5) -ether-bridged dendrimer (M 1One =2H, M= 2H, M 22 =Zn)= Zn)

Mesityl-(3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (M1=2H, M2=Zn)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 30] Mesityl- (3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (M 1 = 2H, M 2 = Zn) was used to synthesize ether-bridged dendrimer. Scheme 30

실시예 122 :Example 122:

Mesityl ethyne,(3,5)-ether-bridged dendrimer (MMesityl ethyne, (3,5) -ether-bridged dendrimer (M 1One =2H, M= 2H, M 22 =Pt)= Pt)

Mesityl-(3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (M1=2H, M2=Pt)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 30] Mesityl- (3,5-dihydroxyphenyl) ethyne is synthesized by the method of preparing ether-bridged dendrimer using linked porphyrin dimer (M 1 = 2H, M 2 = Pt). Scheme 30

실시예 123 :Example 123:

Mesityl ethyne,(3,5)-ether-bridged dendrimer (MMesityl ethyne, (3,5) -ether-bridged dendrimer (M 1One =Zn, M= Zn, M 22 =Zn)= Zn)

Mesityl-(3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (M1=Zn, M2=Zn)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 30] Mesityl- (3,5-dihydroxyphenyl) ethyne is synthesized by the method of preparing ether-bridged dendrimer using linked porphyrin dimer (M 1 = Zn, M 2 = Zn). Scheme 30

실시예 124 :Example 124:

Mesityl ethyne,(3,5)-ether-bridged dendrimer (MMesityl ethyne, (3,5) -ether-bridged dendrimer (M 1One =Zn, M= Zn, M 22 =Pt)= Pt)

Mesityl-(3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (M1=Zn, M2=Pt)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 30] Mesityl- (3,5-dihydroxyphenyl) ethyne is synthesized using ether-bridged dendrimer by using a linked porphyrin dimer (M 1 = Zn, M 2 = Pt). Scheme 30

실시예 125 :Example 125:

Mesityl ethyne,(3,5)-ether-bridged dendrimer (MMesityl ethyne, (3,5) -ether-bridged dendrimer (M 1One =Pt, M= Pt, M 22 =Zn)= Zn)

Mesityl-(3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (M1=Pt, M2=Zn)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 30] Mesityl- (3,5-dihydroxyphenyl) ethyne is synthesized using ether-bridged dendrimer by using a linked porphyrin dimer (M 1 = Pt, M 2 = Zn). Scheme 30

실시예 126 :Example 126:

Mesityl ethyne,(3,5)-ether-bridged dendrimer (MMesityl ethyne, (3,5) -ether-bridged dendrimer (M 1One =Pt, M= Pt, M 22 =Pt)= Pt)

Mesityl-(3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (M1=Pt, M2=Pt)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 30] Use Mesityl- (3,5-dihydroxyphenyl) ethyne linked porphyrin dimer (M 1 = Pt, M 2 = Pt) is synthesized by the method of ether-bridged dendrimer. Scheme 30

실시예 127 :Example 127:

5-(4-이오도페닐)-15-(4-메톡시카르보닐페닐)-10,20-디페닐폴피린-Pt5- (4-iodophenyl) -15- (4-methoxycarbonylphenyl) -10,20-diphenylpolpyrine-Pt

(5-(4-Iodophenyl)-15-(4-methoxycarbonylphenyl)-10,20-diphenylporphyrin-Pt)(5- (4-Iodophenyl) -15- (4-methoxycarbonylphenyl) -10,20-diphenylporphyrin-Pt)

5-(4-Iodophenyl)-15-(4-methoxycarbonylphenyl)-10,20-diphenylporphyrin을 사용하여 Pt-porphyrin 제조 방법으로 합성한다. [반응식 31] Pt-porphyrin was synthesized using 5- (4-Iodophenyl) -15- (4-methoxycarbonylphenyl) -10,20-diphenylporphyrin. Scheme 31

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.77 (m, 6H, Ar-H), 7.95 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.27 (m, 4H, Ar-H), 8.29 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.88 (m, 4H, β-pyrrole), 8.94 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.77 (m, 6H, Ar-H), 7.95 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H ), 8.27 (m, 4H, Ar-H), 8.29 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.88 (m, 4H, β-pyrrole), 8.94 (m, 4H, β-pyrrole).

실시예 128 :Example 128:

5-(4-이오도페닐)-15-(4-메톡시카르보닐페닐)-10,20-디메시틸폴피린-Pt5- (4-iodophenyl) -15- (4-methoxycarbonylphenyl) -10,20-dimethoxylpolpyrine-Pt

(5-(4-Iodophenyl)-15-(4-methoxycarbonylphenyl)-10,20-dimesitylporphyrin-Pt)(5- (4-Iodophenyl) -15- (4-methoxycarbonylphenyl) -10,20-dimesitylporphyrin-Pt)

5-(4-Iodophenyl)-15-(4-methoxycarbonylphenyl)-10,20-dimesitylporphyrin을 사용하여 Pt-porphyrin 제조 방법으로 합성한다. [반응식 32] Pt-porphyrin was synthesized using 5- (4-Iodophenyl) -15- (4-methoxycarbonylphenyl) -10,20-dimesitylporphyrin. Scheme 32

1H NMR (CDCl3) δ 1.87 (s, 6H, CH3), 2.65 (s, 12H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 4H, Ar-H), 7.95 (d, 2H, Ar-H), 8.06 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.88 (m, 4H, β-pyrrole), 8.94 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 6H, CH 3 ), 2.65 (s, 12H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 4H, Ar-H), 7.95 (d, 2H, Ar-H), 8.06 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.88 (m, 4H, β -pyrrole), 8.94 (m, 4H, β-pyrrole).

실시예 129 :Example 129:

페닐-(4-브로모페닐) Ar-Ar 링크된 폴피린 다이머(Phenyl-(4-bromophenyl) Ar-Ar linked porphyrin dimer) (M 1 =2H, M 2 =2H) Phenyl- (4-bromophenyl) Ar-Ar linked porphyrin dimer (M 1 = 2H, M 2 = 2H)

5,15-Diphenyl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(4-bromophenyl)-20-(4-iodophenyl)porphyrin (M2=2H)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 33] 5,15-Diphenyl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (4-bromophenyl) -20- (4-iodophenyl) porphyrin (M 2 = 2H) to synthesize Ar-Ar linked porphyrin dimer manufacturing method. Scheme 33

1H NMR (CDCl3) δ 4.12 (s, 3H, OCH3), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.08 (m, 6H, Ar-H), 8.23 (m, 6H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 4.12 (s, 3H, OCH 3 ), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H) , 8.05 (d, 2H, Ar-H), 8.08 (m, 6H, Ar-H), 8.23 (m, 6H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H , Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole).

실시예 130 :Example 130:

Phenyl-(4-bromophenyl) Ar-Ar linked porphyrin dimer (MPhenyl- (4-bromophenyl) Ar-Ar linked porphyrin dimer (M 1One =2H, M= 2H, M 2 2 =Zn)= Zn)

5,15-Diphenyl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(4-bromophenyl)-20-(4-iodophenyl)porphyrin (M2=Zn)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 33] 5,15-Diphenyl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (4-bromophenyl) -20- (4-iodophenyl) porphyrin (M 2 = Zn) to synthesize Ar-Ar linked porphyrin dimer manufacturing method. Scheme 33

1H NMR (CDCl3) δ 4.12 (s, 3H, OCH3), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.94 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.11 (m, 6H, Ar-H), 8.23 (m, 6H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.77 (m, 6H, β-pyrrole), 8.85 (m, 6H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 4.12 (s, 3H, OCH 3 ), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.94 (m, 6H, Ar-H) , 8.05 (d, 2H, Ar-H), 8.11 (m, 6H, Ar-H), 8.23 (m, 6H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H , Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.77 (m, 6H, β-pyrrole), 8.85 (m, 6 H, β-pyrrole).

실시예 131 :Example 131:

Phenyl-(4-bromophenyl) Ar-Ar linked porphyrin dimer (MPhenyl- (4-bromophenyl) Ar-Ar linked porphyrin dimer (M 1One =2H, M= 2H, M 2 2 =Pt)= Pt)

5,15-Diphenyl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(4-bromophenyl)-20-(4-iodophenyl)porphyrin (M2=Pt)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 33] 5,15-Diphenyl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (4-bromophenyl) -20- (4-iodophenyl) porphyrin (M 2 = Pt) was used to synthesize Ar-Ar linked porphyrin dimer. Scheme 33

1H NMR (CDCl3) δ 4.12 (s, 3H, OCH3), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.08 (m, 6H, Ar-H), 8.23 (m, 6H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.78 (m, 8H, β-pyrrole), 8.85 (m, 6H, β-pyrrole), 8.92 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 4.12 (s, 3H, OCH 3 ), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H) , 8.05 (d, 2H, Ar-H), 8.08 (m, 6H, Ar-H), 8.23 (m, 6H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H , Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.78 (m, 8H, β-pyrrole), 8.85 (m, 6H, β-pyrrole), 8.92 (d, 2 H, β-pyrrole).

실시예 132 :Example 132:

Phenyl-(4-bromophenyl) Ar-Ar linked porphyrin dimer (MPhenyl- (4-bromophenyl) Ar-Ar linked porphyrin dimer (M 1One =Zn, M= Zn, M 2 2 =Zn)= Zn)

5,15-Diphenyl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Zn)과 5,10,15-tri(4-bromophenyl)-20-(4-iodophenyl)porphyrin (M2=Zn)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 33] 5,15-Diphenyl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Zn) and 5,10,15-tri (4-bromophenyl) -20- (4-iodophenyl) porphyrin (M 2 = Zn) to synthesize Ar-Ar linked porphyrin dimer manufacturing method. Scheme 33

1H NMR (CDCl3) δ 4.12 (s, 3H, OCH3), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.08 (m, 6H, Ar-H), 8.23 (m, 6H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.31 (d, 2H, Ar-H), 8.46 (d, 2H, Ar-H), 8.71 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.79 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 4.12 (s, 3H, OCH 3 ), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H) , 8.05 (d, 2H, Ar-H), 8.08 (m, 6H, Ar-H), 8.23 (m, 6H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H , Ar-H), 8.31 (d, 2H, Ar-H), 8.46 (d, 2H, Ar-H), 8.71 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.79 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole).

실시예 133 :Example 133:

Phenyl-(4-bromophenyl) Ar-Ar linked porphyrin dimer (MPhenyl- (4-bromophenyl) Ar-Ar linked porphyrin dimer (M 1One =Zn, M= Zn, M 2 2 =Pt)= Pt)

5,15-Diphenyl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Zn)과 5,10,15-tri(4-bromophenyl)-20-(4-iodophenyl)porphyrin (M2=Pt)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 33] 5,15-Diphenyl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Zn) and 5,10,15-tri (4-bromophenyl) -20- (4-iodophenyl) porphyrin (M 2 = Pt) was used to synthesize Ar-Ar linked porphyrin dimer. Scheme 33

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.14 (m, 6H, Ar-H), 8.23 (m, 6H, Ar-H), 8.29 (d, 2H, Ar-H), 8.30 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.78 (m, 4H, β-pyrrole), 8.79 (s, 4H, β-pyrrole), 8.84 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole), 8.92 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H ), 8.05 (d, 2H, Ar-H), 8.14 (m, 6H, Ar-H), 8.23 (m, 6H, Ar-H), 8.29 (d, 2H, Ar-H), 8.30 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.78 (m, 4H, β-pyrrole), 8.79 (s, 4H, β-pyrrole) , 8.84 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole), 8.92 (d, 2H, β-pyrrole).

실시예 134 :Example 134:

Phenyl-(4-bromophenyl) Ar-Ar linked porphyrin dimer (MPhenyl- (4-bromophenyl) Ar-Ar linked porphyrin dimer (M 1One =Pt, M= Pt, M 2 2 =Zn)= Zn)

5,15-Diphenyl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Pt)과 5,10,15-tri(4-bromophenyl)-20-(4-iodophenyl)porphyrin (M2=Zn)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 33] 5,15-Diphenyl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Pt) and 5,10,15-tri (4-bromophenyl) -20- (4-iodophenyl) porphyrin (M 2 = Zn) to synthesize Ar-Ar linked porphyrin dimer manufacturing method. Scheme 33

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.10 (m, 6H, Ar-H), 8.23 (m, 6H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.36 (d, 2H, Ar-H), 8.48 (d, 2H, Ar-H), 8.71 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.89 (m, 4H, β-pyrrole), 8.95 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H ), 8.05 (d, 2H, Ar-H), 8.10 (m, 6H, Ar-H), 8.23 (m, 6H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.36 (d, 2H, Ar-H), 8.48 (d, 2H, Ar-H), 8.71 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole) , 8.83 (d, 2H, β-pyrrole), 8.89 (m, 4H, β-pyrrole), 8.95 (m, 4H, β-pyrrole).

실시예 135 :Example 135:

Phenyl-(4-bromophenyl) Ar-Ar linked porphyrin dimer (MPhenyl- (4-bromophenyl) Ar-Ar linked porphyrin dimer (M 1One =Pt, M= Pt, M 2 2 =Pt)= Pt)

5,15-Diphenyl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Pt)과 5,10,15-tri(4-bromophenyl)-20-(4-iodophenyl)porphyrin (M2=Pt)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 33] 5,15-Diphenyl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Pt) and 5,10,15-tri (4-bromophenyl) -20- (4-iodophenyl) porphyrin (M 2 = Pt) was used to synthesize Ar-Ar linked porphyrin dimer. Scheme 33

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.14 (m, 6H, Ar-H), 8.23 (m, 6H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.36 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.78 (s, 4H, β-pyrrole), 8.84 (d, 2H, β-pyrrole), 8.89 (m, 4H, β pyrrole), 8.92 (d, 2H, β-pyrrole), 8.95 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H ), 8.05 (d, 2H, Ar-H), 8.14 (m, 6H, Ar-H), 8.23 (m, 6H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.36 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.78 (s, 4H, β-pyrrole), 8.84 (d, 2H, β-pyrrole) , 8.89 (m, 4H, β-pyrrole), 8.92 (d, 2H, β-pyrrole), 8.95 (m, 4H, β-pyrrole).

실시예 136 :Example 136:

페닐-(4-브로모페닐) Ar-Ar 링크된 폴피린 다이머(Mesityl-(4-bromophenyl) Ar-Ar linked porphyrin dimer) (M 1 =2H, M 2 =2H) Mesityl- (4-bromophenyl) Ar-Ar linked porphyrin dimer (M 1 = 2H, M 2 = 2H)

5,15-Dimesityl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(4-bromophenyl)-20-(4-iodophenyl)porphyrin (M2=2H)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 34] 5,15-Dimesityl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (4-bromophenyl) -20- (4-iodophenyl) porphyrin (M 2 = 2H) to synthesize Ar-Ar linked porphyrin dimer manufacturing method. Scheme 34

1H NMR (CDCl3) δ1.87 (s, 6H, CH3), 2.65 (s, 12H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.08 (m, 6H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 6H, CH 3 ), 2.65 (s, 12H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 6H, Ar—H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.08 (m, 6H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole).

실시예 137 :Example 137:

Mesityl-(4-bromophenyl) Ar-Ar linked porphyrin dimer (MMesityl- (4-bromophenyl) Ar-Ar linked porphyrin dimer (M 1One =2H, M= 2H, M 2 2 =Zn)= Zn)

5,15-Dimesityl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(4-bromophenyl)-20-(4-iodophenyl)porphyrin (M2=Zn)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 34] 5,15-Dimesityl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (4-bromophenyl) -20- (4-iodophenyl) porphyrin (M 2 = Zn) to synthesize Ar-Ar linked porphyrin dimer manufacturing method. Scheme 34

1H NMR (CDCl3) δ1.87 (s, 6H, CH3), 2.65 (s, 12H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.09 (m, 6H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.72 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.84 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 6H, CH 3 ), 2.65 (s, 12H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 6H, Ar—H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.09 (m, 6H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.72 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.84 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole).

실시예 138 :Example 138:

Mesityl-(4-bromophenyl) Ar-Ar linked porphyrin dimer (MMesityl- (4-bromophenyl) Ar-Ar linked porphyrin dimer (M 1One =2H, M= 2H, M 2 2 =Pt)= Pt)

5,15-Dimesityl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(4-bromophenyl)-20-(4-iodophenyl)porphyrin (M2=Pt)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 34] 5,15-Dimesityl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (4-bromophenyl) -20- (4-iodophenyl) porphyrin (M 2 = Pt) was used to synthesize Ar-Ar linked porphyrin dimer. Scheme 34

1H NMR (CDCl3) δ1.87 (s, 6H, CH3), 2.65 (s, 12H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.11 (m, 6H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (m, 4H, Ar-H), 8.45 (d, 2H, Ar-H), 8.78 (m, 4H, β-pyrrole), 8.79 (s, 4H, β-pyrrole), 8.84 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole), 8.93 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 6H, CH 3 ), 2.65 (s, 12H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 6H, Ar—H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.11 (m, 6H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (m, 4H, Ar-H), 8.45 (d, 2H, Ar-H), 8.78 (m, 4H, β-pyrrole), 8.79 (s, 4H, β-pyrrole), 8.84 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole), 8.93 (d, 2H, β-pyrrole).

실시예 139 :Example 139:

Mesityl-(4-bromophenyl) Ar-Ar linked porphyrin dimer (MMesityl- (4-bromophenyl) Ar-Ar linked porphyrin dimer (M 1One =Zn, M= Zn, M 2 2 =Zn)= Zn)

5,15-Dimesityl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Zn)과 5,10,15-tri(4-bromophenyl)-20-(4-iodophenyl)porphyrin (M2=Zn)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 34] 5,15-Dimesityl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Zn) and 5,10,15-tri (4-bromophenyl) -20- (4-iodophenyl) porphyrin (M 2 = Zn) to synthesize Ar-Ar linked porphyrin dimer manufacturing method. Scheme 34

1H NMR (CDCl3) δ1.87 (s, 6H, CH3), 2.65 (s, 12H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.10 (m, 6H, Ar-H), 8.26 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.34 (d, 2H, Ar-H), 8.44 (d, 2H, Ar-H), 8.71 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.79 (m, 6H, β-pyrrole), 8.83 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 6H, CH 3 ), 2.65 (s, 12H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 6H, Ar—H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.10 (m, 6H, Ar-H), 8.26 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.34 (d, 2H, Ar-H), 8.44 (d, 2H, Ar-H), 8.71 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.79 (m, 6H, β-pyrrole), 8.83 (m, 4H, β-pyrrole).

실시예 140 :Example 140:

Mesityl-(4-bromophenyl) Ar-Ar linked porphyrin dimer (MMesityl- (4-bromophenyl) Ar-Ar linked porphyrin dimer (M 1One =Zn, M= Zn, M 2 2 =Pt)= Pt)

5,15-Dimesityl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Zn)과 5,10,15-tri(4-bromophenyl)-20-(4-iodophenyl)porphyrin (M2=Pt)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 34] 5,15-Dimesityl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Zn) and 5,10,15-tri (4-bromophenyl) -20- (4-iodophenyl) porphyrin (M 2 = Pt) was used to synthesize Ar-Ar linked porphyrin dimer. Scheme 34

1H NMR (CDCl3) δ1.87 (s, 6H, CH3), 2.65 (s, 12H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.14 (m, 6H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (m, 4H, Ar-H), 8.45 (d, 2H, Ar-H), 8.78 (m, 4H, β-pyrrole), 8.79 (s, 4H, β-pyrrole), 8.84 (m, 6H, β-pyrrole), 8.91 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 6H, CH 3 ), 2.65 (s, 12H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 6H, Ar—H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.14 (m, 6H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (m, 4H, Ar-H), 8.45 (d, 2H, Ar-H), 8.78 (m, 4H, β-pyrrole), 8.79 (s, 4H, β-pyrrole), 8.84 (m, 6H, β-pyrrole), 8.91 (d, 2H, β-pyrrole).

실시예 141 :Example 141:

Mesityl-(4-bromophenyl) Ar-Ar linked porphyrin dimer (MMesityl- (4-bromophenyl) Ar-Ar linked porphyrin dimer (M 1One =Pt, M= Pt, M 2 2 =Zn)= Zn)

5,15-Dimesityl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Pt)과 5,10,15-tri(4-bromophenyl)-20-(4-iodophenyl)porphyrin (M2=Zn)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 34] 5,15-Dimesityl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Pt) and 5,10,15-tri (4-bromophenyl) -20- (4-iodophenyl) porphyrin (M 2 = Zn) to synthesize Ar-Ar linked porphyrin dimer manufacturing method. Scheme 34

1H NMR (CDCl3) δ1.87 (s, 6H, CH3), 2.65 (s, 12H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.07 (m, 6H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.41 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.70 (s, 4H, b-pyrrole), 8.75 (d, 2H, b-pyrrole), 8.83 (d, 2H, b-pyrrole), 8.86 (m, 4H, b-pyrrole), 8.93 (m, 4H, b-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 6H, CH 3 ), 2.65 (s, 12H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 6H, Ar—H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.07 (m, 6H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.41 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.70 (s, 4H, b-pyrrole), 8.75 (d, 2H, b-pyrrole), 8.83 (d, 2H, b-pyrrole), 8.86 (m, 4H, b-pyrrole), 8.93 (m, 4H, b-pyrrole).

실시예 142 :Example 142:

Mesityl-(4-bromophenyl) Ar-Ar linked porphyrin dimer (MMesityl- (4-bromophenyl) Ar-Ar linked porphyrin dimer (M 1One =Pt, M= Pt, M 2 2 =Pt)= Pt)

5,15-Dimesityl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Pt)과 5,10,15-tri(4-bromophenyl)-20-(4-iodophenyl)porphyrin (M2=Pt)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 34] 5,15-Dimesityl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Pt) and 5,10,15-tri (4-bromophenyl) -20- (4-iodophenyl) porphyrin (M 2 = Pt) was used to synthesize Ar-Ar linked porphyrin dimer. Scheme 34

1H NMR (CDCl3) δ1.87 (s, 6H, CH3), 2.65 (s, 12H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.12 (m, 6H, Ar-H), 8.29 (d, 2H, Ar-H), 8.33 (d, 2H, Ar-H), 8.35 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.79 (s, 4H, β-pyrrole), 8.85 (d, 2H, β-pyrrole), 8.87 (m, 4H, β-pyrrole), 8.92 (d, 6H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 6H, CH 3 ), 2.65 (s, 12H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 6H, Ar—H), 7.87 (d, 2H, Ar-H), 7.92 (m, 6H, Ar-H), 8.05 (d, 2H, Ar-H), 8.12 (m, 6H, Ar-H), 8.29 (d, 2H, Ar-H), 8.33 (d, 2H, Ar-H), 8.35 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.79 (s, 4H, β-pyrrole), 8.85 (d, 2H, β-pyrrole), 8.87 (m, 4H, β-pyrrole), 8.92 (d, 6H, β-pyrrole).

실시예 143 :Example 143:

Phenyl-(3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (MPhenyl- (3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =2H)= 2H)

5,15-Diphenyl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(3,5-dibromophenyl)-20-(4-iodophenyl)porphyrin (M2=2H)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 35] 5,15-Diphenyl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (3,5-dibromophenyl) -20- (4-iodophenyl ) is synthesized by using Ar-Ar linked porphyrin dimer using porphyrin (M 2 = 2H). Scheme 35

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.23 (m, 4H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.50 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H ), 8.23 (m, 4H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.50 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole) , 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole).

실시예 144 :Example 144:

Phenyl-(3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (MPhenyl- (3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =Zn)= Zn)

5,15-Diphenyl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(3,5-dibromophenyl)-20-(4-iodophenyl)porphyrin (M2=Zn)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 35] 5,15-Diphenyl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (3,5-dibromophenyl) -20- (4-iodophenyl ) is synthesized by using Ar-Ar linked porphyrin dimer using porphyrin (M 2 = Zn). Scheme 35

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.23 (m, 4H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.50 (d, 2H, Ar-H), 8.71 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.82 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H ), 8.23 (m, 4H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.50 (d, 2H, Ar-H), 8.71 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole) , 8.78 (m, 4H, β-pyrrole), 8.82 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole).

실시예 145 :Example 145:

Phenyl-(3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (MPhenyl- (3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =Pt)= Pt)

5,15-Diphenyl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(3,5-dibromophenyl)-20-(4-iodophenyl)porphyrin (M2=Pt)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 35] 5,15-Diphenyl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (3,5-dibromophenyl) -20- (4-iodophenyl ) is synthesized by using Ar-Ar linked porphyrin dimer using porphyrin (M 2 = Pt). Scheme 35

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.23 (m, 4H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.54 (d, 2H, Ar-H), 8.78 (m, 8H, β-pyrrole), 8.85 (m, 6H, β-pyrrole), 8.92 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H ), 8.23 (m, 4H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.54 (d, 2H, Ar-H), 8.78 (m, 8H, β-pyrrole), 8.85 (m, 6H, β-pyrrole) , 8.92 (d, 2H, β-pyrrole).

실시예 146 :Example 146:

Phenyl-(3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (MPhenyl- (3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M 1One =Zn, M= Zn, M 22 =Zn)= Zn)

5,15-Diphenyl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Zn)과 5,10,15-tri(3,5-dibromophenyl)-20-(4-iodophenyl)porphyrin (M2=Zn)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 35] 5,15-Diphenyl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Zn) and 5,10,15-tri (3,5-dibromophenyl) -20- (4-iodophenyl ) is synthesized by using Ar-Ar linked porphyrin dimer using porphyrin (M 2 = Zn). Scheme 35

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.23 (m, 4H, Ar-H), 8.27 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.34 (d, 2H, Ar-H), 8.46 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.51 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.77 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.86 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H ), 8.23 (m, 4H, Ar-H), 8.27 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.34 (d, 2H, Ar-H), 8.46 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.51 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole) , 8.77 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.86 (m, 4H, β-pyrrole).

실시예 147 :Example 147:

Phenyl-(3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (MPhenyl- (3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M 1One =Zn, M= Zn, M 22 =Pt)= Pt)

5,15-Diphenyl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Zn)과 5,10,15-tri(3,5-dibromophenyl)-20-(4-iodophenyl)porphyrin (M2=Pt)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 35] 5,15-Diphenyl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Zn) and 5,10,15-tri (3,5-dibromophenyl) -20- (4-iodophenyl ) is synthesized by using Ar-Ar linked porphyrin dimer using porphyrin (M 2 = Pt). Scheme 35

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.23 (m, 4H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (m, 4H, Ar-H), 8.46 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.54 (d, 2H, Ar-H), 8.79 (m, 8H, β-pyrrole), 8.85 (d, 6H, β-pyrrole), 8.91 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H ), 8.23 (m, 4H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (m, 4H, Ar-H), 8.46 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.54 (d, 2H, Ar-H), 8.79 (m, 8H, β-pyrrole), 8.85 (d, 6H, β-pyrrole), 8.91 (d, 2H, β-pyrrole) .

실시예 148 :Example 148:

Phenyl-(3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (MPhenyl- (3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M 1One =Pt, M= Pt, M 22 =Zn)= Zn)

5,15-Diphenyl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Pt)과 5,10,15-tri(3,5-dibromophenyl)-20-(4-iodophenyl)porphyrin (M2=Zn)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 35] 5,15-Diphenyl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Pt) and 5,10,15-tri (3,5-dibromophenyl) -20- (4-iodophenyl ) is synthesized by using Ar-Ar linked porphyrin dimer using porphyrin (M 2 = Zn). Scheme 35

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.27 (m, 6H, Ar-H), 8.29 (d, 2H, Ar-H), 8.36 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.49 (d, 2H, Ar-H), 8.50 (d, 2H, Ar-H), 8.71 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.86 (m, 4H, β-pyrrole), 8.94 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H ), 8.27 (m, 6H, Ar-H), 8.29 (d, 2H, Ar-H), 8.36 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.49 (d, 2H, Ar-H), 8.50 (d, 2H, Ar-H), 8.71 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole) , 8.86 (m, 4H, β-pyrrole), 8.94 (m, 4H, β-pyrrole).

실시예 149 :Example 149:

Phenyl-(3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (MPhenyl- (3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M 1One =Pt, M= Pt, M 22 =Pt)= Pt)

5,15-Diphenyl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Pt)과 5,10,15-tri(3,5-dibromophenyl)-20-(4-iodophenyl)porphyrin (M2=Pt)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 35] 5,15-Diphenyl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Pt) and 5,10,15-tri (3,5-dibromophenyl) -20- (4-iodophenyl ) is synthesized by using Ar-Ar linked porphyrin dimer using porphyrin (M 2 = Pt). Scheme 35

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.27 (m, 4H, Ar-H), 8.29 (d, 2H, Ar-H), 8.31 (d, 2H, Ar-H), 8.36 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.48 (d, 2H, Ar-H), 8.53 (d, 2H, Ar-H), 8.79 (s, 4H, β-pyrrole), 8.86 (d, 6H, β-pyrrole), 8.93 (m, 6H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.77 (m, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H ), 8.27 (m, 4H, Ar-H), 8.29 (d, 2H, Ar-H), 8.31 (d, 2H, Ar-H), 8.36 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.48 (d, 2H, Ar-H), 8.53 (d, 2H, Ar-H), 8.79 (s, 4H, β-pyrrole), 8.86 (d, 6H, β-pyrrole) , 8.93 (m, 6H, β-pyrrole).

실시예 150 :Example 150:

Mesityl-(3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (MMesityl- (3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =2H)= 2H)

5,15-Dimesityl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(3,5-dibromophenyl)-20-(4-iodophenyl)porphyrin (M2=2H)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 36] 5,15-Dimesityl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (3,5-dibromophenyl) -20- (4-iodophenyl ) is synthesized by using Ar-Ar linked porphyrin dimer using porphyrin (M 2 = 2H). Scheme 36

1H NMR (CDCl3) δ1.87 (s, 6H, CH3), 2.65 (s, 12H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.50 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 6H, CH 3 ), 2.65 (s, 12H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 6H, Ar—H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.50 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole).

실시예 151 :Example 151:

Mesityl-(3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (MMesityl- (3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =Zn)= Zn)

5,15-Dimesityl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(3,5-dibromophenyl)-20-(4-iodophenyl)porphyrin (M2=Zn)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 36] 5,15-Dimesityl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (3,5-dibromophenyl) -20- (4-iodophenyl ) is synthesized by using Ar-Ar linked porphyrin dimer using porphyrin (M 2 = Zn). Scheme 36

1H NMR (CDCl3) δ1.87 (s, 6H, CH3), 2.65 (s, 12H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.51 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.74 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.84 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 6H, CH 3 ), 2.65 (s, 12H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 6H, Ar—H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.51 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.74 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.84 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole).

실시예 152 :Example 152:

Mesityl-(3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (MMesityl- (3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =Pt)= Pt)

5,15-Dimesityl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(3,5-dibromophenyl)-20-(4-iodophenyl)porphyrin (M2=Pt)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 36] 5,15-Dimesityl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (3,5-dibromophenyl) -20- (4-iodophenyl ) is synthesized by using Ar-Ar linked porphyrin dimer using porphyrin (M 2 = Pt). Scheme 36

1H NMR (CDCl3) δ1.87 (s, 6H, CH3), 2.65 (s, 12H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (m, 6H, Ar-H), 8.45 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.54 (d, 2H, Ar-H), 8.78 (m, 4H, β-pyrrole), 8.79 (s, 4H, β-pyrrole), 8.85 (m, 6H, β-pyrrole), 8.92 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 6H, CH 3 ), 2.65 (s, 12H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 6H, Ar—H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (m, 6H, Ar-H), 8.45 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.54 (d, 2H, Ar-H), 8.78 (m, 4H, β-pyrrole), 8.79 (s, 4H, β-pyrrole), 8.85 (m, 6H, β-pyrrole), 8.92 (d, 2H, β-pyrrole).

실시예 153 :Example 153:

Mesityl-(3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (MMesityl- (3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M 1One =Zn, M= Zn, M 22 =Zn)= Zn)

5,15-Dimesityl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Zn)과 5,10,15-tri(3,5-dibromophenyl)-20-(4-iodophenyl)porphyrin (M2=Zn)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 36] 5,15-Dimesityl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Zn) and 5,10,15-tri (3,5-dibromophenyl) -20- (4-iodophenyl ) is synthesized by using Ar-Ar linked porphyrin dimer using porphyrin (M 2 = Zn). Scheme 36

1H NMR (CDCl3) δ1.87 (s, 6H, CH3), 2.65 (s, 12H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (m, 4H, Ar-H), 8.31 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.52 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.77 (m, 6H, β-pyrrole), 8.85 (m, 6H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 6H, CH 3 ), 2.65 (s, 12H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 6H, Ar—H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (m, 4H, Ar-H), 8.31 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.47 (d, 1H, Ar-H), 8.52 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.77 (m, 6H, β-pyrrole), 8.85 (m, 6H, β-pyrrole).

실시예 154 :Example 154:

Mesityl-(3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (MMesityl- (3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M 1One =Zn, M= Zn, M 22 =Pt)= Pt)

5,15-Dimesityl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Zn)과 5,10,15-tri(3,5-dibromophenyl)-20-(4-iodophenyl)porphyrin (M2=Pt)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 36] 5,15-Dimesityl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Zn) and 5,10,15-tri (3,5-dibromophenyl) -20- (4-iodophenyl ) is synthesized by using Ar-Ar linked porphyrin dimer using porphyrin (M 2 = Pt). Scheme 36

1H NMR (CDCl3) δ1.87 (s, 6H, CH3), 2.65 (s, 12H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.31 (d, 2H, Ar-H), 8.34 (d, 2H, Ar-H), 8.46 (m, 4H, Ar-H), 8.53 (d, 2H, Ar-H), 8.78 (m, 8H, β-pyrrole), 8.85 (m, 6H, β-pyrrole), 8.91 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 6H, CH 3 ), 2.65 (s, 12H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 6H, Ar—H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.31 (d, 2H, Ar-H), 8.34 (d, 2H, Ar-H), 8.46 (m, 4H, Ar-H), 8.53 (d, 2H, Ar-H), 8.78 (m, 8H, β-pyrrole), 8.85 (m, 6H, β-pyrrole), 8.91 (d, 2H, β-pyrrole).

실시예 155 :Example 155:

Mesityl-(3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (MMesityl- (3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M 1One =Pt, M= Pt, M 22 =Zn)= Zn)

5,15-Dimesityl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Pt)과 5,10,15-tri(3,5-dibromophenyl)-20-(4-iodophenyl)porphyrin (M2=Zn)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 36] 5,15-Dimesityl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Pt) and 5,10,15-tri (3,5-dibromophenyl) -20- (4-iodophenyl ) is synthesized by using Ar-Ar linked porphyrin dimer using porphyrin (M 2 = Zn). Scheme 36

1H NMR (CDCl3) δ1.87 (s, 6H, CH3), 2.65 (s, 12H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.28 (m, 4H, Ar-H), 8.36 (d, 2H, Ar-H), 8.47 (m, 3H, Ar-H), 8.51 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.77 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.86 (m, 4H, β-pyrrole), 8.94 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 6H, CH 3 ), 2.65 (s, 12H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 6H, Ar—H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.28 (m, 4H, Ar-H), 8.36 (d, 2H, Ar-H), 8.47 (m, 3H, Ar-H), 8.51 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.77 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.86 (m, 4H, β-pyrrole), 8.94 (m, 4H, β-pyrrole).

실시예 156 :Example 156:

Mesityl-(3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (MMesityl- (3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M 1One =Pt, M= Pt, M 22 =Pt)= Pt)

5,15-Dimesityl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Pt)과 5,10,15-tri(3,5-dibromophenyl)-20-(4-iodophenyl)porphyrin (M2=Pt)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 36] 5,15-Dimesityl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Pt) and 5,10,15-tri (3,5-dibromophenyl) -20- (4-iodophenyl ) is synthesized by using Ar-Ar linked porphyrin dimer using porphyrin (M 2 = Pt). Scheme 36

1H NMR (CDCl3) δ1.87 (s, 6H, CH3), 2.65 (s, 12H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 6H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.33 (d, 2H, Ar-H), 8.37 (d, 2H, Ar-H), 8.48 (m, 3H, Ar-H), 8.54 (d, 2H, Ar-H), 8.79 (s, 4H, β-pyrrole), 8.86 (m, 6H, β-pyrrole), 8.91 (d, 2H, β-pyrrole), 8.94 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 6H, CH 3 ), 2.65 (s, 12H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 6H, Ar—H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.33 (d, 2H, Ar-H), 8.37 (d, 2H, Ar-H), 8.48 (m, 3H, Ar-H), 8.54 (d, 2H, Ar-H), 8.79 (s, 4H, β-pyrrole), 8.86 (m, 6H, β-pyrrole), 8.91 (d, 2H, β-pyrrole), 8.94 (m, 4H, β-pyrrole).

실시예 157 :Example 157:

페닐-(4-하이드록시페닐) Ar-Ar 링크된 폴피린 다이머(Phenyl-(4-hydroxy- phenyl) Ar-Ar linked porphyrin dimer) (MPhenyl- (4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =2H) = 2H)

5,15-Diphenyl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(4-hydroxyphenyl)-20-(4-iodophenyl)porphyrin (M2=2H)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 37] 5,15-Diphenyl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (4-hydroxyphenyl) -20- (4-iodophenyl) porphyrin (M 2 = 2H) to synthesize Ar-Ar linked porphyrin dimer manufacturing method. Scheme 37

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.17 (d, 2H, Ar-H), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (m, 4H, Ar-H), 8.23 (m, 2H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.17 (d, 2H, Ar-H), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H ), 8.05 (m, 4H, Ar-H), 8.23 (m, 2H, Ar-H), 8.28 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole) , 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole).

실시예 158 :Example 158:

Phenyl-(4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (MPhenyl- (4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =Zn)= Zn)

5,15-Diphenyl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(4-hydroxyphenyl)-20-(4-iodophenyl)porphyrin (M2=Zn)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 37] 5,15-Diphenyl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (4-hydroxyphenyl) -20- (4-iodophenyl) porphyrin (M 2 = Zn) to synthesize Ar-Ar linked porphyrin dimer manufacturing method. Scheme 37

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.17 (d, 2H, Ar-H), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.04 (m, 4H, Ar-H), 8.23 (m, 2H, Ar-H), 8.28 (m, 4H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.85 (m, 6H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.17 (d, 2H, Ar-H), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H ), 8.04 (m, 4H, Ar-H), 8.23 (m, 2H, Ar-H), 8.28 (m, 4H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.85 (m, 6H, β-pyrrole) .

실시예 159 :Example 159:

Phenyl-(4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (MPhenyl- (4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =Pt)= Pt)

5,15-Diphenyl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(4-hydroxyphenyl)-20-(4-iodophenyl)porphyrin (M2=Pt)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 37] 5,15-Diphenyl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (4-hydroxyphenyl) -20- (4-iodophenyl) porphyrin (M 2 = Pt) was used to synthesize Ar-Ar linked porphyrin dimer. Scheme 37

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.17 (d, 2H, Ar-H), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.04 (m, 4H, Ar-H), 8.23 (m, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.34 (m, 4H, Ar-H), 8.45 (d, 2H, Ar-H), 8.78 (m, 8H, β-pyrrole), 8.85 (m, 6H, β-pyrrole), 8.92 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.17 (d, 2H, Ar-H), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H ), 8.04 (m, 4H, Ar-H), 8.23 (m, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.34 (m, 4H, Ar-H), 8.45 (d, 2H, Ar-H), 8.78 (m, 8H, β-pyrrole), 8.85 (m, 6H, β-pyrrole), 8.92 (d, 2H, β-pyrrole).

실시예 160 :Example 160:

Phenyl-(4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (MPhenyl- (4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1One =Zn, M= Zn, M 22 =Zn)= Zn)

5,15-Diphenyl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Zn)과 5,10,15-tri(4-hydroxyphenyl)-20-(4-iodophenyl)porphyrin (M2=Zn)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 37] 5,15-Diphenyl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Zn) and 5,10,15-tri (4-hydroxyphenyl) -20- (4-iodophenyl) porphyrin (M 2 = Zn) to synthesize Ar-Ar linked porphyrin dimer manufacturing method. Scheme 37

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.17 (d, 2H, Ar-H), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (m, 4H, Ar-H), 8.23 (m, 2H, Ar-H), 8.29 (m, 6H, Ar-H), 8.46 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.77 (m, 6H, β-pyrrole), 8.85 (m, 6H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.17 (d, 2H, Ar-H), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H ), 8.05 (m, 4H, Ar-H), 8.23 (m, 2H, Ar-H), 8.29 (m, 6H, Ar-H), 8.46 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.77 (m, 6H, β-pyrrole), 8.85 (m, 6H, β-pyrrole).

실시예 161 :Example 161:

Phenyl-(4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (MPhenyl- (4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1One =Zn, M= Zn, M 22 =Pt)= Pt)

5,15-Diphenyl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Zn)과 5,10,15-tri(4-hydroxyphenyl)-20-(4-iodophenyl)porphyrin (M2=Pt)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 37] 5,15-Diphenyl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Zn) and 5,10,15-tri (4-hydroxyphenyl) -20- (4-iodophenyl) porphyrin (M 2 = Pt) was used to synthesize Ar-Ar linked porphyrin dimer. Scheme 37

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.17 (d, 2H, Ar-H), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (m, 4H, Ar-H), 8.23 (m, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.34 (m, 4H, Ar-H), 8.46 (d, 2H, Ar-H), 8.77 (m, 4H, β-pyrrole), 8.79 (s, 4H, β-pyrrole), 8.85 (m, 6H, β-pyrrole), 8.92 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.17 (d, 2H, Ar-H), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H ), 8.05 (m, 4H, Ar-H), 8.23 (m, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.34 (m, 4H, Ar-H), 8.46 (d, 2H, Ar-H), 8.77 (m, 4H, β-pyrrole), 8.79 (s, 4H, β-pyrrole), 8.85 (m, 6H, β-pyrrole), 8.92 (d, 2H, β-pyrrole) .

실시예 162 :Example 162:

Phenyl-(4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (MPhenyl- (4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1One =Pt, M= Pt, M 22 =Zn)= Zn)

5,15-Diphenyl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Pt)과 5,10,15-tri(4-hydroxyphenyl)-20-(4-iodophenyl)porphyrin (M2=Zn)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 37] 5,15-Diphenyl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Pt) and 5,10,15-tri (4-hydroxyphenyl) -20- (4-iodophenyl) porphyrin (M 2 = Zn) to synthesize Ar-Ar linked porphyrin dimer manufacturing method. Scheme 37

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.17 (d, 2H, Ar-H), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (m, 4H, Ar-H), 8.23 (m, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (m, 4H, Ar-H), 8.48 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.87 (m, 4H, β-pyrrole), 8.94 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.17 (d, 2H, Ar-H), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H ), 8.05 (m, 4H, Ar-H), 8.23 (m, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (m, 4H, Ar-H), 8.48 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.87 (m, 4H, β-pyrrole) , 8.94 (m, 4H, β-pyrrole).

실시예 163 :Example 163:

Phenyl-(4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (MPhenyl- (4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1One =Pt, M= Pt, M 22 =Pt)= Pt)

5,15-Diphenyl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Pt)과 5,10,15-tri(4-hydroxyphenyl)-20-(4-iodophenyl)porphyrin (M2=Pt)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 37] 5,15-Diphenyl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Pt) and 5,10,15-tri (4-hydroxyphenyl) -20- (4-iodophenyl) porphyrin (M 2 = Pt) was used to synthesize Ar-Ar linked porphyrin dimer. Scheme 37

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.17 (d, 2H, Ar-H), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.04 (m, 4H, Ar-H), 8.23 (m, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.35 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.79 (s, 4H, β-pyrrole), 8.85 (d, 2H, β-pyrrole), 8.88 (m, 4H, β-pyrrole), 8.94 (m, 4H, β-pyrrole), 8.92 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.17 (d, 2H, Ar-H), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H ), 8.04 (m, 4H, Ar-H), 8.23 (m, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.35 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.79 (s, 4H, β-pyrrole), 8.85 (d, 2H, β-pyrrole), 8.88 (m, 4H, β-pyrrole) , 8.94 (m, 4H, β-pyrrole), 8.92 (d, 2H, β-pyrrole).

실시예 164 :Example 164:

메시틸-(4-하이드록시페닐) Ar-Ar 링크된 폴피린다이머(Mesityl-(4-hydroxy phenyl) Ar-Ar linked porphyrin dimer) (MMesityl- (4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =2H)= 2H)

5,15-Dimesityl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(4-hydroxyphenyl)-20-(4-iodophenyl)porphyrin (M2=2H)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 38] 5,15-Dimesityl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (4-hydroxyphenyl) -20- (4-iodophenyl) porphyrin (M 2 = 2H) to synthesize Ar-Ar linked porphyrin dimer manufacturing method. Scheme 38

1H NMR (CDCl3) δ1.87 (s, 3H, CH3), 2.65 (s, 6H, CH3), 4.12 (s, 3H, OCH3), 7.17 (d, 2H, Ar-H), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (m, 4H, Ar-H), 8.28 (m, 4H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (m, 6H, β-pyrrole), 8.84 (m, 6H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 3H, CH 3 ), 2.65 (s, 6H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.17 (d, 2H, Ar—H), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (m, 4H, Ar-H), 8.28 (m, 4H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (m, 6H, β-pyrrole), 8.84 (m, 6H, β-pyrrole).

실시예 165 :Example 165:

Mesityl-(4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (MMesityl- (4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =Zn)= Zn)

5,15-Dimesityl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(4-hydroxyphenyl)-20-(4-iodophenyl)porphyrin (M2=Zn)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 38] 5,15-Dimesityl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (4-hydroxyphenyl) -20- (4-iodophenyl) porphyrin (M 2 = Zn) to synthesize Ar-Ar linked porphyrin dimer manufacturing method. Scheme 38

1H NMR (CDCl3) δ1.87 (s, 3H, CH3), 2.65 (s, 6H, CH3), 4.12 (s, 3H, OCH3), 7.17 (d, 2H, Ar-H), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (m, 4H, Ar-H), 8.27 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 3H, CH 3 ), 2.65 (s, 6H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.17 (d, 2H, Ar—H), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (m, 4H, Ar-H), 8.27 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole).

실시예 166 :Example 166:

Mesityl-(4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (MMesityl- (4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =Pt)= Pt)

5,15-Dimesityl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(4-hydroxyphenyl)-20-(4-iodophenyl)porphyrin (M2=Pt)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 38] 5,15-Dimesityl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (4-hydroxyphenyl) -20- (4-iodophenyl) porphyrin (M 2 = Pt) was used to synthesize Ar-Ar linked porphyrin dimer. Scheme 38

1H NMR (CDCl3) δ1.87 (s, 3H, CH3), 2.65 (s, 6H, CH3), 4.12 (s, 3H, OCH3), 7.17 (d, 2H, Ar-H), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (m, 4H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (m, 4H, Ar-H), 8.45 (d, 2H, Ar-H), 8.78 (m, 8H, β-pyrrole), 8.85 (m, 6H, β-pyrrole), 8.91 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 3H, CH 3 ), 2.65 (s, 6H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.17 (d, 2H, Ar—H), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (m, 4H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (m, 4H, Ar-H), 8.45 (d, 2H, Ar-H), 8.78 (m, 8H, β-pyrrole), 8.85 (m, 6H, β-pyrrole), 8.91 (d, 2H, β-pyrrole).

실시예 167 :Example 167:

Mesityl-(4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (MMesityl- (4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1One =Zn, M= Zn, M 22 =Zn)= Zn)

5,15-Dimesityl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Zn)과 5,10,15-tri(4-hydroxyphenyl)-20-(4-iodophenyl)porphyrin (M2=Zn)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 38] 5,15-Dimesityl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Zn) and 5,10,15-tri (4-hydroxyphenyl) -20- (4-iodophenyl) porphyrin (M 2 = Zn) to synthesize Ar-Ar linked porphyrin dimer manufacturing method. Scheme 38

1H NMR (CDCl3) δ1.87 (s, 3H, CH3), 2.65 (s, 6H, CH3), 4.12 (s, 3H, OCH3), 7.17 (d, 2H, Ar-H), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (m, 4H, Ar-H), 8.28 (m, 4H, Ar-H), 8.33 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.79 (m, 4H, β-pyrrole), 8.85 (m, 6H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 3H, CH 3 ), 2.65 (s, 6H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.17 (d, 2H, Ar—H), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (m, 4H, Ar-H), 8.28 (m, 4H, Ar-H), 8.33 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.79 (m, 4H, β-pyrrole), 8.85 (m, 6H, β-pyrrole).

실시예 168 :Example 168:

Mesityl-(4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (MMesityl- (4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1One =Zn, M= Zn, M 22 =Pt)= Pt)

5,15-Dimesityl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Zn)과 5,10,15-tri(4-hydroxyphenyl)-20-(4-iodophenyl)porphyrin (M2=Pt)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 38] 5,15-Dimesityl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Zn) and 5,10,15-tri (4-hydroxyphenyl) -20- (4-iodophenyl) porphyrin (M 2 = Pt) was used to synthesize Ar-Ar linked porphyrin dimer. Scheme 38

1H NMR (CDCl3) δ1.87 (s, 3H, CH3), 2.65 (s, 6H, CH3), 4.12 (s, 3H, OCH3), 7.17 (d, 2H, Ar-H), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (m, 4H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (m, 4H, Ar-H), 8.45 (d, 2H, Ar-H), 8.79 (m, 8H, β-pyrrole), 8.87 (m, 6H, β-pyrrole), 8.92 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 3H, CH 3 ), 2.65 (s, 6H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.17 (d, 2H, Ar—H), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (m, 4H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (m, 4H, Ar-H), 8.45 (d, 2H, Ar-H), 8.79 (m, 8H, β-pyrrole), 8.87 (m, 6H, β-pyrrole), 8.92 (d, 2H, β-pyrrole).

실시예 169 :Example 169:

Mesityl-(4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (MMesityl- (4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1One =Pt, M= Pt, M 22 =Zn)= Zn)

5,15-Dimesityl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Pt)과 5,10,15-tri(4-hydroxyphenyl)-20-(4-iodophenyl)porphyrin (M2=Zn)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 38] 5,15-Dimesityl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Pt) and 5,10,15-tri (4-hydroxyphenyl) -20- (4-iodophenyl) porphyrin (M 2 = Zn) to synthesize Ar-Ar linked porphyrin dimer manufacturing method. Scheme 38

1H NMR (CDCl3) δ1.87 (s, 3H, CH3), 2.65 (s, 6H, CH3), 4.12 (s, 3H, OCH3), 7.17 (d, 2H, Ar-H), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (m, 4H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.36 (d, 2H, Ar-H), 8.48 (d, 2H, Ar-H), 8.79 (s, 4H, β-pyrrole), 8.85 (d, 2H, β-pyrrole), 8.87 (m, 4H, β-pyrrole), 8.91 (d, 2H, β-pyrrole), 8.94 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 3H, CH 3 ), 2.65 (s, 6H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.17 (d, 2H, Ar—H), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (m, 4H, Ar-H), 8.29 (d, 2H, Ar-H), 8.32 (d, 2H, Ar-H), 8.36 (d, 2H, Ar-H), 8.48 (d, 2H, Ar-H), 8.79 (s, 4H, β-pyrrole), 8.85 (d, 2H, β-pyrrole), 8.87 (m, 4H, β-pyrrole), 8.91 (d, 2H, β-pyrrole), 8.94 (m, 4H, β-pyrrole).

실시예 170 :Example 170:

Mesityl-(4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (MMesityl- (4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1One =Pt, M= Pt, M 22 =Pt)= Pt)

5,15-Dimesityl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Pt)과 5,10,15-tri(4-hydroxyphenyl)-20-(4-iodophenyl)porphyrin (M2=Pt)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 38] 5,15-Dimesityl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Pt) and 5,10,15-tri (4-hydroxyphenyl) -20- (4-iodophenyl) porphyrin (M 2 = Pt) was used to synthesize Ar-Ar linked porphyrin dimer. Scheme 38

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.23 (m, 2H, Ar-H), 8.29 (m, 5H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H ), 8.23 (m, 2H, Ar-H), 8.29 (m, 5H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole) , 8.85 (m, 4H, β-pyrrole).

실시예 171 :Example 171:

페닐-(3,5-디하이드록시페닐) Ar-Ar 링크된 폴피린다이머(Phenyl-(3,5-di- hydroxyphenyl) Ar-Ar linked porphyrin dimer) (MPhenyl- (3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =2H)= 2H)

5,15-Diphenyl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(3,5-dihydroxyphenyl)-20-(4-iodophenyl)porphyrin (M2= 2H)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 39] 5,15-Diphenyl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (3,5-dihydroxyphenyl) -20- (4-iodophenyl ) is synthesized by using Ar-Ar linked porphyrin dimer using porphyrin (M 2 = 2H). Scheme 39

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.21 (m, 2H, Ar-H), 8.29 (m, 5H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.86 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H ), 8.21 (m, 2H, Ar-H), 8.29 (m, 5H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole) , 8.86 (m, 4H, β-pyrrole).

실시예 172 :Example 172:

Phenyl-(3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (MPhenyl- (3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =Zn)= Zn)

5,15-Diphenyl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(3,5-dihydroxyphenyl)-20-(4-iodophenyl)porphyrin (M2= Zn)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 39] 5,15-Diphenyl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (3,5-dihydroxyphenyl) -20- (4-iodophenyl ) is synthesized by using Ar-Ar linked porphyrin dimer using porphyrin (M 2 = Zn). Scheme 39

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.28 (m, 5H, Ar-H), 8.36 (d, 2H, Ar-H), 8.49 (d, 4H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.88 (m, 4H, β-pyrrole), 8.94 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H ), 8.28 (m, 5H, Ar-H), 8.36 (d, 2H, Ar-H), 8.49 (d, 4H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.88 (m, 4H, β-pyrrole), 8.94 (m, 4H, β-pyrrole).

실시예 173 :Example 173:

Phenyl-(3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (MPhenyl- (3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =Pt)= Pt)

5,15-Diphenyl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(3,5-dihydroxyphenyl)-20-(4-iodophenyl)porphyrin (M2= Pt)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 39] 5,15-Diphenyl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (3,5-dihydroxyphenyl) -20- (4-iodophenyl ) is synthesized by using Ar-Ar linked porphyrin dimer using porphyrin (M 2 = Pt). Scheme 39

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.21 (m, 2H, Ar-H), 8.29 (m, 5H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.48 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (m, 6H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H ), 8.21 (m, 2H, Ar-H), 8.29 (m, 5H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.48 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (m, 6H, β-pyrrole) .

실시예 174 :Example 174:

Phenyl-(3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (MPhenyl- (3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1One =Zn, M= Zn, M 22 =Zn)= Zn)

5,15-Diphenyl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Zn)과 5,10,15-tri(3,5-dihydroxyphenyl)-20-(4-iodophenyl)porphyrin (M2= Zn)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 39] 5,15-Diphenyl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Zn) and 5,10,15-tri (3,5-dihydroxyphenyl) -20- (4-iodophenyl ) is synthesized by using Ar-Ar linked porphyrin dimer using porphyrin (M 2 = Zn). Scheme 39

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.23 (m, 2H, Ar-H), 8.29 (m, 5H, Ar-H), 8.31 (m, 4H, Ar-H), 8.43 (d, 2H, Ar-H), 8.54 (d, 2H, Ar-H), 8.77 (m, 4H, β-pyrrole), 8.79 (s, 4H, β-pyrrole), 8.85 (m, 6H, β-pyrrole), 8.92 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H ), 8.23 (m, 2H, Ar-H), 8.29 (m, 5H, Ar-H), 8.31 (m, 4H, Ar-H), 8.43 (d, 2H, Ar-H), 8.54 (d, 2H, Ar-H), 8.77 (m, 4H, β-pyrrole), 8.79 (s, 4H, β-pyrrole), 8.85 (m, 6H, β-pyrrole), 8.92 (d, 2H, β-pyrrole) .

실시예 175 :Example 175:

Phenyl-(3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (MPhenyl- (3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1One =Zn, M= Zn, M 22 =Pt)= Pt)

5,15-Diphenyl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Zn)과 5,10,15-tri(3,5-dihydroxyphenyl)-20-(4-iodophenyl)porphyrin (M2= Pt)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 39] 5,15-Diphenyl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Zn) and 5,10,15-tri (3,5-dihydroxyphenyl) -20- (4-iodophenyl ) is synthesized by using Ar-Ar linked porphyrin dimer using porphyrin (M 2 = Pt). Scheme 39

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.27 (m, 5H, Ar-H), 8.35 (d, 2H, Ar-H), 8.49 (m, 4H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.88 (m, 4H, β-pyrrole), 8.95 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H ), 8.27 (m, 5H, Ar-H), 8.35 (d, 2H, Ar-H), 8.49 (m, 4H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.88 (m, 4H, β-pyrrole), 8.95 (m, 4H, β-pyrrole).

실시예 176 :Example 176:

Phenyl-(3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (MPhenyl- (3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1One =Pt, M= Pt, M 22 =Zn)= Zn)

5,15-Diphenyl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Pt)과 5,10,15-tri(3,5-dihydroxyphenyl)-20-(4-iodophenyl)porphyrin (M2= Zn)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 39] 5,15-Diphenyl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Pt) and 5,10,15-tri (3,5-dihydroxyphenyl) -20- (4-iodophenyl ) is synthesized by using Ar-Ar linked porphyrin dimer using porphyrin (M 2 = Zn). Scheme 39

1H NMR (CDCl3) δ4.12 (s, 3H, OCH3), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.27 (m, 5H, Ar-H), 8.32 (d, 2H, Ar-H), 8.36 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.53 (d, 2H, Ar-H), 8.79 (s, 4H, β-pyrrole), 8.84 (d, 2H, β-pyrrole), 8.87 (m, 4H, β-pyrrole), 8.92 (d, 2H, β-pyrrole), 8.94 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ4.12 (s, 3H, OCH 3 ), 7.77 (m, 3H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H ), 8.27 (m, 5H, Ar-H), 8.32 (d, 2H, Ar-H), 8.36 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.53 (d, 2H, Ar-H), 8.79 (s, 4H, β-pyrrole), 8.84 (d, 2H, β-pyrrole), 8.87 (m, 4H, β-pyrrole), 8.92 (d, 2H, β-pyrrole) , 8.94 (m, 4H, β-pyrrole).

실시예 177 :Example 177:

Phenyl-(3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (MPhenyl- (3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1One =Pt, M= Pt, M 22 =Pt)= Pt)

5,15-Diphenyl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Pt)과 5,10,15-tri(3,5-dihydroxyphenyl)-20-(4-iodophenyl)porphyrin (M2= Pt)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 39] 5,15-Diphenyl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Pt) and 5,10,15-tri (3,5-dihydroxyphenyl) -20- (4-iodophenyl ) is synthesized by using Ar-Ar linked porphyrin dimer using porphyrin (M 2 = Pt). Scheme 39

1H NMR (CDCl3) δ1.87 (s, 3H, CH3), 2.65 (s, 6H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (m, 5H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 3H, CH 3 ), 2.65 (s, 6H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 2H, Ar—H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (m, 5H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.76 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole).

실시예 178 :Example 178:

메시틸-(3,5-디하이드록시페닐) Ar-Ar 링크된 폴피린다이머(Mesityl-(3,5-di hydroxyphenyl) Ar-Ar linked porphyrin dimer) (MMesityl- (3,5-di hydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =2H)= 2H)

5,15-Dimesityl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(3,5-dihydroxyphenyl)-20-(4-iodophenyl)porphyrin (M2= 2H)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 40] 5,15-Dimesityl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (3,5-dihydroxyphenyl) -20- (4-iodophenyl ) is synthesized by using Ar-Ar linked porphyrin dimer using porphyrin (M 2 = 2H). Scheme 40

1H NMR (CDCl3) δ1.87 (s, 3H, CH3), 2.65 (s, 6H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (m, 5H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.50 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 3H, CH 3 ), 2.65 (s, 6H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 2H, Ar—H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (m, 5H, Ar-H), 8.32 (d, 2H, Ar-H), 8.45 (d, 2H, Ar-H), 8.50 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.78 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole).

실시예 179 :Example 179:

Mesityl-(3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (MMesityl- (3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =Zn)= Zn)

5,15-Dimesityl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(3,5-dihydroxyphenyl)-20-(4-iodophenyl)porphyrin (M2= Zn)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 40] 5,15-Dimesityl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (3,5-dihydroxyphenyl) -20- (4-iodophenyl ) is synthesized by using Ar-Ar linked porphyrin dimer using porphyrin (M 2 = Zn). Scheme 40

1H NMR (CDCl3) δ1.87 (s, 3H, CH3), 2.65 (s, 6H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (m, 5H, Ar-H), 8.32 (m, 4H, Ar-H), 8.45 (d, 2H, Ar-H), 8.53 (d, 2H, Ar-H), 8.79 (m, 8H, β-pyrrole), 8.85 (m, 6H, β-pyrrole), 8.91 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 3H, CH 3 ), 2.65 (s, 6H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 2H, Ar—H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (m, 5H, Ar-H), 8.32 (m, 4H, Ar-H), 8.45 (d, 2H, Ar-H), 8.53 (d, 2H, Ar-H), 8.79 (m, 8H, β-pyrrole), 8.85 (m, 6H, β-pyrrole), 8.91 (d, 2H, β-pyrrole).

실시예 180 :Example 180:

Mesityl-(3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (MMesityl- (3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1One =2H, M= 2H, M 22 =Pt)= Pt)

5,15-Dimesityl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=2H)과 5,10,15-tri(3,5-dihydroxyphenyl)-20-(4-iodophenyl)porphyrin (M2= Pt)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 40] 5,15-Dimesityl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = 2H) and 5,10,15-tri (3,5-dihydroxyphenyl) -20- (4-iodophenyl ) is synthesized by using Ar-Ar linked porphyrin dimer using porphyrin (M 2 = Pt). Scheme 40

1H NMR (CDCl3) δ1.87 (s, 3H, CH3), 2.65 (s, 6H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.27 (m, 5H, Ar-H), 8.32 (d, 2H, Ar-H), 8.44 (d, 2H, Ar-H), 8.50 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.81 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 3H, CH 3 ), 2.65 (s, 6H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 2H, Ar—H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.27 (m, 5H, Ar-H), 8.32 (d, 2H, Ar-H), 8.44 (d, 2H, Ar-H), 8.50 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.81 (m, 4H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.85 (m, 4H, β-pyrrole).

실시예 181 :Example 181:

Mesityl-(3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (MMesityl- (3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1One =Zn, M= Zn, M 22 =Zn)= Zn)

5,15-Dimesityl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Zn)과 5,10,15-tri(3,5-dihydroxyphenyl)-20-(4-iodophenyl)porphyrin (M2= Zn)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 40] 5,15-Dimesityl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Zn) and 5,10,15-tri (3,5-dihydroxyphenyl) -20- (4-iodophenyl ) is synthesized by using Ar-Ar linked porphyrin dimer using porphyrin (M 2 = Zn). Scheme 40

1H NMR (CDCl3) δ1.87 (s, 3H, CH3), 2.65 (s, 6H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (m, 5H, Ar-H), 8.32 (d, 2H, Ar-H), 8.44 (d, 2H, Ar-H), 8.53 (d, 2H, Ar-H), 8.79 (m, 8H, β-pyrrole), , 8.85 (m, 4H, β-pyrrole), 8.88 (d, 2H, β-pyrrole), 8.92 (d, 2H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 3H, CH 3 ), 2.65 (s, 6H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 2H, Ar—H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (m, 5H, Ar-H), 8.32 (d, 2H, Ar-H), 8.44 (d, 2H, Ar-H), 8.53 (d, 2H, Ar-H), 8.79 (m, 8H, β-pyrrole), 8.85 (m, 4H, β-pyrrole), 8.88 (d, 2H, β-pyrrole), 8.92 (d, 2 H, β-pyrrole).

실시예 182 :Example 182:

Mesityl-(3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (MMesityl- (3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1One =Zn, M= Zn, M 22 =Pt)= Pt)

5,15-Dimesityl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Zn)과 5,10,15-tri(3,5-dihydroxyphenyl)-20-(4-iodophenyl)porphyrin (M2= Pt)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 40] 5,15-Dimesityl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Zn) and 5,10,15-tri (3,5-dihydroxyphenyl) -20- (4-iodophenyl ) is synthesized by using Ar-Ar linked porphyrin dimer using porphyrin (M 2 = Pt). Scheme 40

1H NMR (CDCl3) δ1.87 (s, 3H, CH3), 2.65 (s, 6H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.36 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.51 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.88 (m, 4H, β-pyrrole), 8.93 (m, 4H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 3H, CH 3 ), 2.65 (s, 6H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 2H, Ar—H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (d, 2H, Ar-H), 8.36 (d, 2H, Ar-H), 8.49 (d, 2H, Ar-H), 8.51 (d, 2H, Ar-H), 8.70 (s, 4H, β-pyrrole), 8.75 (d, 2H, β-pyrrole), 8.83 (d, 2H, β-pyrrole), 8.88 (m, 4H, β-pyrrole), 8.93 (m, 4H, β-pyrrole).

실시예 183 :Example 183:

Mesityl-(3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (MMesityl- (3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1One =Pt, M= Pt, M 22 =Zn)= Zn)

5,15-Dimesityl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Pt)과 5,10,15-tri(3,5-dihydroxyphenyl)-20-(4-iodophenyl)porphyrin (M2= Zn)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 40] 5,15-Dimesityl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Pt) and 5,10,15-tri (3,5-dihydroxyphenyl) -20- (4-iodophenyl ) is synthesized by using Ar-Ar linked porphyrin dimer using porphyrin (M 2 = Zn). Scheme 40

1H NMR (CDCl3) δ1.87 (s, 3H, CH3), 2.65 (s, 6H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (m, 4H, Ar-H), 8.31 (d, 2H, Ar-H), 8.35 (d, 2H, Ar-H), 8.51 (d, 2H, Ar-H), 8.53 (d, 2H, Ar-H), 8.80 (s, 4H, β-pyrrole), 8.86 (d, 2H, β-pyrrole), 8.91 (m, 10H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 3H, CH 3 ), 2.65 (s, 6H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 2H, Ar—H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (m, 4H, Ar-H), 8.31 (d, 2H, Ar-H), 8.35 (d, 2H, Ar-H), 8.51 (d, 2H, Ar-H), 8.53 (d, 2H, Ar-H), 8.80 (s, 4H, β-pyrrole), 8.86 (d, 2H, β-pyrrole), 8.91 (m, 10H, β-pyrrole).

실시예 184 :Example 184:

Mesityl-(3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (MMesityl- (3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1One =Pt, M= Pt, M 22 =Pt)= Pt)

5,15-Dimesityl-10-(4-iodophenyl)-20-(4-methoxycarbonylphenyl)porphyrin (M1=Pt)과 5,10,15-tri(3,5-dihydroxyphenyl)-20-(4-iodophenyl)porphyrin (M2= Pt)를 사용하여 Ar-Ar linked porphyrin dimer 제조 방법으로 합성한다. [반응식 40] 5,15-Dimesityl-10- (4-iodophenyl) -20- (4-methoxycarbonylphenyl) porphyrin (M 1 = Pt) and 5,10,15-tri (3,5-dihydroxyphenyl) -20- (4-iodophenyl ) is synthesized by using Ar-Ar linked porphyrin dimer using porphyrin (M 2 = Pt). Scheme 40

1H NMR (CDCl3) δ1.87 (s, 3H, CH3), 2.65 (s, 6H, CH3), 4.12 (s, 3H, OCH3), 7.30 (s, 2H, Ar-H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (m, 4H, Ar-H), 8.31 (d, 2H, Ar-H), 8.35 (d, 2H, Ar-H), 8.51 (d, 2H, Ar-H), 8.53 (d, 2H, Ar-H), 8.80 (s, 4H, β-pyrrole), 8.86 (d, 2H, β-pyrrole), 8.91 (m, 10H, β-pyrrole). 1 H NMR (CDCl 3 ) δ 1.87 (s, 3H, CH 3 ), 2.65 (s, 6H, CH 3 ), 4.12 (s, 3H, OCH 3 ), 7.30 (s, 2H, Ar—H), 7.87 (d, 2H, Ar-H), 8.05 (d, 2H, Ar-H), 8.29 (m, 4H, Ar-H), 8.31 (d, 2H, Ar-H), 8.35 (d, 2H, Ar-H), 8.51 (d, 2H, Ar-H), 8.53 (d, 2H, Ar-H), 8.80 (s, 4H, β-pyrrole), 8.86 (d, 2H, β-pyrrole), 8.91 (m, 10H, β-pyrrole).

실시예 185 :Example 185:

페닐 Ar-Ar, C-C 직접링크된 덴드리머(Phenyl Ar-Ar, C-C direct linked dendrimer) (MPhenyl Ar-Ar, C-C direct linked dendrimer (M 1One =2H, M= 2H, M 22 =2H)= 2H)

Phenyl-(4-bromophenyl) Ar-Ar linked porphyrin dimer (M1=2H, M2=2H)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 41] Phenyl- (4-bromophenyl) Ar-Ar linked porphyrin dimer (M 1 = 2H, M 2 = 2H) using the synthesis method of the CC direct linked dendrimer. Scheme 41

실시예 186 :Example 186:

Phenyl Ar-Ar, C-C direct linked dendrimer (MPhenyl Ar-Ar, C-C direct linked dendrimer (M 1One =2H, M= 2H, M 22 =Zn)= Zn)

Phenyl-(4-bromophenyl) Ar-Ar linked porphyrin dimer (M1=2H, M2=Zn)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 41] Phenyl- (4-bromophenyl) Ar-Ar linked porphyrin dimer (M 1 = 2H, M 2 = Zn) is synthesized by the method of producing a CC direct linked dendrimer. Scheme 41

실시예 187 :Example 187:

Phenyl Ar-Ar, C-C direct linked dendrimer (MPhenyl Ar-Ar, C-C direct linked dendrimer (M 1One =2H, M= 2H, M 22 =Pt)= Pt)

Phenyl-(4-bromophenyl) Ar-Ar linked porphyrin dimer (M1=2H, M2=Pt)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 41] Phenyl- (4-bromophenyl) Ar-Ar linked porphyrin dimer (M 1 = 2H, M 2 = Pt) using the synthesis method of the CC direct linked dendrimer. Scheme 41

실시예 188 :Example 188:

Phenyl Ar-Ar, C-C direct linked dendrimer (MPhenyl Ar-Ar, C-C direct linked dendrimer (M 1One =Zn, M= Zn, M 22 =Zn)= Zn)

Phenyl-(4-bromophenyl) Ar-Ar linked porphyrin dimer (M1=Zn, M2=Zn)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 41] Phenyl- (4-bromophenyl) Ar-Ar linked porphyrin dimer (M 1 = Zn, M 2 = Zn) is synthesized by the method of producing a CC direct linked dendrimer. Scheme 41

실시예 189 :Example 189:

Phenyl Ar-Ar, C-C direct linked dendrimer (MPhenyl Ar-Ar, C-C direct linked dendrimer (M 1One =Zn, M= Zn, M 22 =Pt)= Pt)

Phenyl-(4-bromophenyl) Ar-Ar linked porphyrin dimer (M1=Zn, M2=Pt)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 41] Phenyl- (4-bromophenyl) Ar-Ar linked porphyrin dimer (M 1 = Zn, M 2 = Pt) using the synthesis method of the CC direct linked dendrimer. Scheme 41

실시예 190 :Example 190:

Phenyl Ar-Ar, C-C direct linked dendrimer (MPhenyl Ar-Ar, C-C direct linked dendrimer (M 1One =Pt, M= Pt, M 22 =Zn)= Zn)

Phenyl-(4-bromophenyl) Ar-Ar linked porphyrin dimer (M1=Pt, M2=Zn)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 41] Phenyl- (4-bromophenyl) Ar-Ar linked porphyrin dimer (M 1 = Pt, M 2 = Zn) was synthesized by a method for producing a CC direct linked dendrimer. Scheme 41

실시예 191 :Example 191:

Phenyl Ar-Ar, C-C direct linked dendrimer (MPhenyl Ar-Ar, C-C direct linked dendrimer (M 1One =Pt, M= Pt, M 22 =Pt)= Pt)

Phenyl-(4-bromophenyl) Ar-Ar linked porphyrin dimer (M1=Pt, M2=Pt)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 41] Phenyl- (4-bromophenyl) Ar-Ar linked porphyrin dimer (M 1 = Pt, M 2 = Pt) using the synthesis method of the CC direct linked dendrimer. Scheme 41

실시예 192 :Example 192:

메시틸 Ar-Ar, C-C 직접링크된 덴드리머(Mesityl Ar-Ar, C-C direct linked dendrimer) (MMesityl Ar-Ar, C-C direct linked dendrimer (M 1One =2H, M= 2H, M 22 =2H)= 2H)

Mesityl-(4-bromophenyl) Ar-Ar linked porphyrin dimer (M1=2H, M2=2H)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 42] Mesityl- (4-bromophenyl) Ar-Ar linked porphyrin dimer (M 1 = 2H, M 2 = 2H) is synthesized by the method for producing CC direct linked dendrimer. Scheme 42

실시예 193 :Example 193:

Mesityl Ar-Ar, C-C direct linked dendrimer (MMesityl Ar-Ar, C-C direct linked dendrimer (M 1One =2H, M= 2H, M 22 =Zn)= Zn)

Mesityl-(4-bromophenyl) Ar-Ar linked porphyrin dimer (M1=2H, M2=Zn)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 42] Mesityl- (4-bromophenyl) Ar-Ar linked porphyrin dimer (M 1 = 2H, M 2 = Zn) is synthesized by the method of producing a CC direct linked dendrimer. Scheme 42

실시예 194 :Example 194:

Mesityl Ar-Ar, C-C direct linked dendrimer (MMesityl Ar-Ar, C-C direct linked dendrimer (M 1One =2H, M= 2H, M 22 =Pt)= Pt)

Mesityl-(4-bromophenyl) Ar-Ar linked porphyrin dimer (M1=2H, M2=Pt)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 42] Mesityl- (4-bromophenyl) Ar-Ar linked porphyrin dimer (M 1 = 2H, M 2 = Pt) using the synthesis method of the CC direct linked dendrimer. Scheme 42

실시예 195 :Example 195:

Mesityl Ar-Ar, C-C direct linked dendrimer (MMesityl Ar-Ar, C-C direct linked dendrimer (M 1One =Zn, M= Zn, M 22 =Zn)= Zn)

Mesityl-(4-bromophenyl) Ar-Ar linked porphyrin dimer (M1=Zn, M2=Zn)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 42] Mesityl- (4-bromophenyl) Ar-Ar linked porphyrin dimer (M 1 = Zn, M 2 = Zn) using the synthesis method of the CC direct linked dendrimer. Scheme 42

실시예 196 :Example 196:

Mesityl Ar-Ar, C-C direct linked dendrimer (MMesityl Ar-Ar, C-C direct linked dendrimer (M 1One =Zn, M= Zn, M 22 =Pt)= Pt)

Mesityl-(4-bromophenyl) Ar-Ar linked porphyrin dimer (M1=Zn, M2=Pt)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 42] Mesityl- (4-bromophenyl) Ar-Ar linked porphyrin dimer (M 1 = Zn, M 2 = Pt) using the synthesis method of the CC direct linked dendrimer. Scheme 42

실시예 197 :Example 197:

Mesityl Ar-Ar, C-C direct linked dendrimer (MMesityl Ar-Ar, C-C direct linked dendrimer (M 1One =Pt, M= Pt, M 22 =Zn)= Zn)

Mesityl-(4-bromophenyl) Ar-Ar linked porphyrin dimer (M1=Pt, M2=Zn)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 42] Mesityl- (4-bromophenyl) Ar-Ar linked porphyrin dimer (M 1 = Pt, M 2 = Zn) is synthesized by a method for producing CC direct linked dendrimer. Scheme 42

실시예 198 :Example 198:

Mesityl Ar-Ar, C-C direct linked dendrimer (MMesityl Ar-Ar, C-C direct linked dendrimer (M 1One =Pt, M= Pt, M 22 =Pt)= Pt)

Mesityl-(4-bromophenyl) Ar-Ar linked porphyrin dimer (M1=Pt, M2=Pt)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 42] Mesityl- (4-bromophenyl) Ar-Ar linked porphyrin dimer (M 1 = Pt, M 2 = Pt) using the synthesis method of the CC direct linked dendrimer. Scheme 42

실시예 199 :Example 199:

페닐 Ar-Ar, (3,5)-C-C 직접링크된 덴드리머(Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer (MPhenyl Ar-Ar, (3,5) -C-C direct linked dendrimer (M 1One =2H, M= 2H, M 22 =2H)= 2H)

Phenyl-(3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M1=2H, M2=2H)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 43] Phenyl- (3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M 1 = 2H, M 2 = 2H) using the synthesis method of the CC direct linked dendrimer. Scheme 43

실시예 200 :Example 200:

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer (MPhenyl Ar-Ar, (3,5) -C-C direct linked dendrimer (M 1One =2H, M= 2H, M 22 =Zn)= Zn)

Phenyl-(3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M1=2H, M2=Zn)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 43] Phenyl- (3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M 1 = 2H, M 2 = Zn) is synthesized by the method of producing a CC direct linked dendrimer. Scheme 43

실시예 201 :Example 201:

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer (MPhenyl Ar-Ar, (3,5) -C-C direct linked dendrimer (M 1One =2H, M= 2H, M 22 =Pt)= Pt)

Phenyl-(3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M1=2H, M2=Pt)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 43] Phenyl- (3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M 1 = 2H, M 2 = Pt) using the synthesis method of the CC direct linked dendrimer. Scheme 43

실시예 202 :Example 202:

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer (MPhenyl Ar-Ar, (3,5) -C-C direct linked dendrimer (M 1One =Zn, M= Zn, M 22 =Zn)= Zn)

Phenyl-(3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M1=Zn, M2=Zn)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 43] Phenyl- (3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M 1 = Zn, M 2 = Zn) is synthesized by the method of producing a CC direct linked dendrimer. Scheme 43

실시예 203 :Example 203:

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer (MPhenyl Ar-Ar, (3,5) -C-C direct linked dendrimer (M 1One =Zn, M= Zn, M 22 =Pt)= Pt)

Phenyl-(3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M1=Zn, M2=Pt)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 43] Phenyl- (3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M 1 = Zn, M 2 = Pt) using the synthesis method of the CC direct linked dendrimer. Scheme 43

실시예 204 :Example 204:

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer (MPhenyl Ar-Ar, (3,5) -C-C direct linked dendrimer (M 1One =Pt, M= Pt, M 22 =Zn)= Zn)

Phenyl-(3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M1=Pt, M2=Zn)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 43] Phenyl- (3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M 1 = Pt, M 2 = Zn) was synthesized by a method for producing CC direct linked dendrimer. Scheme 43

실시예 205 :Example 205:

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer (MPhenyl Ar-Ar, (3,5) -C-C direct linked dendrimer (M 1One =Pt, M= Pt, M 22 =Pt)= Pt)

Phenyl-(3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M1=Pt, M2=Pt)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 43] Phenyl- (3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M 1 = Pt, M 2 = Pt) using the synthesis method of the CC direct linked dendrimer. Scheme 43

실시예 206 :Example 206:

메시틸 Ar-Ar, (3,5)-C-C 직접링크된 덴드리머(Mesityl Ar-Ar,(3,5)-C-C direct linked dendrimer) (MMesityl Ar-Ar, (3,5) -C-C direct linked dendrimer (M 1One =2H, M= 2H, M 22 =2H)= 2H)

Mesityl-(3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M1=2H, M2=2H)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 44] Mesityl- (3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M 1 = 2H, M 2 = 2H) using the synthesis method of the CC direct linked dendrimer. Scheme 44

실시예 207 :Example 207:

Mesityl Ar-Ar,(3,5)-C-C direct linked dendrimer (MMesityl Ar-Ar, (3,5) -C-C direct linked dendrimer (M 1One =2H, M= 2H, M 22 =Zn)= Zn)

Mesityl-(3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M1=2H, M2=Zn)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 44] Mesityl- (3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M 1 = 2H, M 2 = Zn) is synthesized by the method of producing CC direct linked dendrimer. Scheme 44

실시예 208 :Example 208:

Mesityl Ar-Ar,(3,5)-C-C direct linked dendrimer (MMesityl Ar-Ar, (3,5) -C-C direct linked dendrimer (M 1One =2H, M= 2H, M 22 =Pt)= Pt)

Mesityl-(3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M1=2H, M2=Pt)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 44] Mesityl- (3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M 1 = 2H, M 2 = Pt) using the synthesis method of the CC direct linked dendrimer. Scheme 44

실시예 209 :Example 209:

Mesityl Ar-Ar,(3,5)-C-C direct linked dendrimer (MMesityl Ar-Ar, (3,5) -C-C direct linked dendrimer (M 1One =Zn, M= Zn, M 22 =Zn)= Zn)

Mesityl-(3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M1=Zn, M2=Zn)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 44] Mesityl- (3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M 1 = Zn, M 2 = Zn) is synthesized by the method of producing a CC direct linked dendrimer. Scheme 44

실시예 210 :Example 210:

Mesityl Ar-Ar,(3,5)-C-C direct linked dendrimer (MMesityl Ar-Ar, (3,5) -C-C direct linked dendrimer (M 1One =Zn, M= Zn, M 22 =Pt)= Pt)

Mesityl-(3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M1=Zn, M2=Pt)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 44] Mesityl- (3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M 1 = Zn, M 2 = Pt) using the synthesis method of the CC direct linked dendrimer. Scheme 44

실시예 211 :Example 211:

Mesityl Ar-Ar,(3,5)-C-C direct linked dendrimer (MMesityl Ar-Ar, (3,5) -C-C direct linked dendrimer (M 1One =Pt, M= Pt, M 22 =Zn)= Zn)

Mesityl-(3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M1=Pt, M2=Zn)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 44] Mesityl- (3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M 1 = Pt, M 2 = Zn) is synthesized by a method for producing CC direct linked dendrimer. Scheme 44

실시예 212 :Example 212:

Mesityl Ar-Ar,(3,5)-C-C direct linked dendrimer (MMesityl Ar-Ar, (3,5) -C-C direct linked dendrimer (M 1One =Pt, M= Pt, M 22 =Pt)= Pt)

Mesityl-(3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M1=Pt, M2=Pt)를 사용하여 C-C direct linked dendrimer의 제조 방법으로 합성한다. [반응식 44] Mesityl- (3,5-dibromophenyl) Ar-Ar linked porphyrin dimer (M 1 = Pt, M 2 = Pt) using the synthesis method of the CC direct linked dendrimer. Scheme 44

실시예 213 :Example 213:

페닐 Ar-Ar, 에테르브릿지드 덴드리머(Phenyl Ar-Ar, ether-bridged dendrimer) (MPhenyl Ar-Ar, ether-bridged dendrimer (M 1One =2H, M= 2H, M 22 =2H)= 2H)

Phenyl-(4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M1=2H, M2=2H)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다.Phenyl- (4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1 = 2H, M 2 = 2H) using the synthesis method of ether-bridged dendrimer.

실시예 214 :Example 214:

Phenyl Ar-Ar, ether-bridged dendrimer (MPhenyl Ar-Ar, ether-bridged dendrimer (M 1One =2H, M= 2H, M 22 =Zn)= Zn)

Phenyl-(4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M1=2H, M2=Zn)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 45] Phenyl- (4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1 = 2H, M 2 = Zn) using the synthesis method of ether-bridged dendrimer. Scheme 45

실시예 215 :Example 215:

Phenyl Ar-Ar, ether-bridged dendrimer (MPhenyl Ar-Ar, ether-bridged dendrimer (M 1One =2H, M= 2H, M 22 =Pt)= Pt)

Phenyl-(4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M1=2H, M2=Pt)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 45] Phenyl- (4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1 = 2H, M 2 = Pt) using the synthesis method of ether-bridged dendrimer. Scheme 45

실시예 216 :Example 216:

Phenyl Ar-Ar, ether-bridged dendrimer (MPhenyl Ar-Ar, ether-bridged dendrimer (M 1One =Zn, M= Zn, M 22 =Zn)= Zn)

Phenyl-(4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M1=Zn, M2=Zn)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 45] Phenyl- (4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1 = Zn, M 2 = Zn) using the synthesis method of ether-bridged dendrimer. Scheme 45

실시예 217 :Example 217:

Phenyl Ar-Ar, ether-bridged dendrimer (MPhenyl Ar-Ar, ether-bridged dendrimer (M 1One =Zn, M= Zn, M 22 =Pt)= Pt)

Phenyl-(4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M1=Zn, M2=Pt)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 45] Phenyl- (4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1 = Zn, M 2 = Pt) using the synthesis method of ether-bridged dendrimer. Scheme 45

실시예 218 :Example 218:

Phenyl Ar-Ar, ether-bridged dendrimer (MPhenyl Ar-Ar, ether-bridged dendrimer (M 1One =Pt, M= Pt, M 22 =Zn)= Zn)

Phenyl-(4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M1=Pt, M2=Zn)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 45] Phenyl- (4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1 = Pt, M 2 = Zn) using the synthesis method of ether-bridged dendrimer. Scheme 45

실시예 219 :Example 219:

Phenyl Ar-Ar, ether-bridged dendrimer (MPhenyl Ar-Ar, ether-bridged dendrimer (M 1One =Pt, M= Pt, M 22 =Pt)= Pt)

Phenyl-(4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M1=Pt, M2=Pt)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 45] Phenyl- (4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1 = Pt, M 2 = Pt) using the synthesis method of ether-bridged dendrimer. Scheme 45

실시예 220 :Example 220:

메시틸 Ar-Ar, 에테르-브릿지드 덴드리머(Mesityl Ar-Ar, ether-bridged dendrimer) (MMesityl Ar-Ar, ether-bridged dendrimer (M 1One =2H, M= 2H, M 22 =2H)= 2H)

Mesityl-(4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M1=2H, M2=2H)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 46] Mesityl- (4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1 = 2H, M 2 = 2H) using the synthesis method of ether-bridged dendrimer. Scheme 46

실시예 221 :Example 221:

Mesityl Ar-Ar, ether-bridged dendrimer (MMesityl Ar-Ar, ether-bridged dendrimer (M 1One =2H, M= 2H, M 22 =Zn)= Zn)

Mesityl-(4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M1=2H, M2=Zn)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 46] Mesityl- (4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1 = 2H, M 2 = Zn) using the synthesis method of ether-bridged dendrimer. Scheme 46

실시예 222 :Example 222:

Mesityl Ar-Ar, ether-bridged dendrimer (MMesityl Ar-Ar, ether-bridged dendrimer (M 1One =2H, M= 2H, M 22 =Pt)= Pt)

Mesityl-(4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M1=2H, M2=Pt)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 46] Mesityl- (4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1 = 2H, M 2 = Pt) using the synthesis method of ether-bridged dendrimer. Scheme 46

실시예 223 :Example 223:

Mesityl Ar-Ar, ether-bridged dendrimer (MMesityl Ar-Ar, ether-bridged dendrimer (M 1One =Zn, M= Zn, M 22 =Zn)= Zn)

Mesityl-(4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M1=Zn, M2=Zn)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 46] Mesityl- (4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1 = Zn, M 2 = Zn) using the synthesis method of ether-bridged dendrimer. Scheme 46

실시예 224 :Example 224:

Mesityl Ar-Ar, ether-bridged dendrimer (MMesityl Ar-Ar, ether-bridged dendrimer (M 1One =Zn, M= Zn, M 22 =Pt)= Pt)

Mesityl-(4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M1=Zn, M2=Pt)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 46] Mesityl- (4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1 = Zn, M 2 = Pt) using the synthesis method of ether-bridged dendrimer. Scheme 46

실시예 225 :Example 225:

Mesityl Ar-Ar, ether-bridged dendrimer (MMesityl Ar-Ar, ether-bridged dendrimer (M 1One =Pt, M= Pt, M 22 =Zn)= Zn)

Mesityl-(4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M1=Pt, M2=Zn)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 46] Mesityl- (4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1 = Pt, M 2 = Zn) was used to synthesize ether-bridged dendrimer. Scheme 46

실시예 226 :Example 226:

Mesityl Ar-Ar, ether-bridged dendrimer (MMesityl Ar-Ar, ether-bridged dendrimer (M 1One =Pt, M= Pt, M 22 =Pt)= Pt)

Mesityl-(4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M1=Pt, M2=Pt)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 46] Mesityl- (4-hydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1 = Pt, M 2 = Pt) using the synthesis method of ether-bridged dendrimer. Scheme 46

실시예 227 :Example 227:

페닐 Ar-Ar, (3,5)-에테르브릿지드 덴드리머(Phenyl Ar-Ar, (3,5)-ether- bridged dendrimer) (MPhenyl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1One =2H, M= 2H, M 22 =2H)= 2H)

Phenyl-(3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M1=2H, M2=2H)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 47] Phenyl- (3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1 = 2H, M 2 = 2H) using the synthesis method of ether-bridged dendrimer. Scheme 47

실시예 228 :Example 228:

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer (MPhenyl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1One =2H, M= 2H, M 22 =Zn)= Zn)

Phenyl-(3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M1=2H, M2=Zn)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 47] Phenyl- (3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1 = 2H, M 2 = Zn) using the synthesis method of ether-bridged dendrimer. Scheme 47

실시예 229 :Example 229:

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer (MPhenyl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1One =2H, M= 2H, M 22 =Pt)= Pt)

Phenyl-(3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M1=2H, M2=Pt)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 47] Phenyl- (3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1 = 2H, M 2 = Pt) using the synthesis method of ether-bridged dendrimer. Scheme 47

실시예 230 :Example 230:

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer (MPhenyl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1One =Zn, M= Zn, M 22 =Zn)= Zn)

Phenyl-(3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M1=Zn, M2=Zn)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 47] Phenyl- (3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1 = Zn, M 2 = Zn) using the synthesis method of ether-bridged dendrimer. Scheme 47

실시예 231 :Example 231:

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer (MPhenyl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1One =Zn, M= Zn, M 22 =Pt)= Pt)

Phenyl-(3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M1=Zn, M2=Pt)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 47] Phenyl- (3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1 = Zn, M 2 = Pt) using the synthesis method of ether-bridged dendrimer. Scheme 47

실시예 232 :Example 232:

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer (MPhenyl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1One =Pt, M= Pt, M 22 =Zn)= Zn)

Phenyl-(3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M1=Pt, M2=Zn)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 47] Phenyl- (3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1 = Pt, M 2 = Zn) was used to synthesize ether-bridged dendrimer. Scheme 47

실시예 233 :Example 233:

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer (MPhenyl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1One =Pt, M= Pt, M 22 =Pt)= Pt)

Phenyl-(3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M1=Pt, M2=Pt)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 47] Phenyl- (3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1 = Pt, M 2 = Pt) using the synthesis method of ether-bridged dendrimer. Scheme 47

실시예 234 :Example 234:

메시틸 Ar-Ar, (3,5)-에테르브릿지드 덴드리머(Mesityl Ar-Ar, (3,5)-ether- bridged dendrimer) (MMesityl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1One =2H, M= 2H, M 22 =2H)= 2H)

Mesityl-(3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M1=2H, M2=2H)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 48] Mesityl- (3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1 = 2H, M 2 = 2H) using the synthesis method of ether-bridged dendrimer. Scheme 48

실시예 235 :Example 235:

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer (MMesityl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1One =2H, M= 2H, M 22 =Zn)= Zn)

Mesityl-(3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M1=2H, M2=Zn)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 48] Mesityl- (3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1 = 2H, M 2 = Zn) was used to synthesize ether-bridged dendrimer. Scheme 48

실시예 236 :Example 236:

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer (MMesityl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1One =2H, M= 2H, M 22 =Pt)= Pt)

Mesityl-(3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M1=2H, M2=Pt)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 48] Mesityl- (3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1 = 2H, M 2 = Pt) using the synthesis method of ether-bridged dendrimer. Scheme 48

실시예 237 :Example 237:

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer (MMesityl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1One =Zn, M= Zn, M 22 =Zn)= Zn)

Mesityl-(3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M1=Zn, M2=Zn)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 48] Mesityl- (3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1 = Zn, M 2 = Zn) using the synthesis method of ether-bridged dendrimer. Scheme 48

실시예 238 :Example 238:

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer (MMesityl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1One =Zn, M= Zn, M 22 =Pt)= Pt)

Mesityl-(3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M1=Zn, M2=Pt)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 48] Mesityl- (3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1 = Zn, M 2 = Pt) using the synthesis method of ether-bridged dendrimer. Scheme 48

실시예 239 :Example 239:

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer (MMesityl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1One =Pt, M= Pt, M 22 =Zn)= Zn)

Mesityl-(3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M1=Pt, M2=Zn)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 48] Mesityl- (3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1 = Pt, M 2 = Zn) was used to synthesize ether-bridged dendrimer. Scheme 48

실시예 240 :Example 240:

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer (MMesityl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1One =Pt, M= Pt, M 22 =Pt)= Pt)

Mesityl-(3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M1=Pt, M2=Pt)를 사용하여 ether-bridged dendrimer의 제조 방법으로 합성한다. [반응식 48] Mesityl- (3,5-dihydroxyphenyl) Ar-Ar linked porphyrin dimer (M 1 = Pt, M 2 = Pt) using the synthesis method of ether-bridged dendrimer. Scheme 48

실시예 241 :Example 241:

페닐에타인, C-C 직접링크된 덴드리머-Er(III) 착물Phenylethane, C-C Directlinked Dendrimer-Er (III) Complex

(Phenyl ethyne, C-C direct linked dendrimer-Er(III) complex (Phenyl ethyne, C-C direct linked dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =2H, Ln=Er))= 2H, Ln = Er))

Phenyl ethyne, C-C direct linked dendrimer (M1=2H, M2=2H)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 49] Phenyl ethyne, CC direct linked dendrimer (M 1 = 2H, M 2 = 2H) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 49

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 242 :Example 242:

페닐에타인, C-C 직접링크된 덴드리머-Yb(III) 착물Phenylethane, C-C Directlinked Dendrimer-Yb (III) Complex

(Phenyl ethyne, C-C direct linked dendrimer-Yb(III) complex (Phenyl ethyne, C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =2H, Ln=Yb))= 2H, Ln = Yb))

Phenyl ethyne, C-C direct linked dendrimer (M1=2H, M2=2H)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 49] Phenyl ethyne, CC direct linked dendrimer (M 1 = 2H, M 2 = 2H) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 49

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 243 :Example 243:

페닐에타인, C-C 직접링크된 덴드리머-Nd(III) 착물Phenylethane, C-C Directlinked Dendrimer-Nd (III) Complex

(Phenyl ethyne, C-C direct linked dendrimer-Nd(III) complex (Phenyl ethyne, C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =2H, Ln=Nd))= 2H, Ln = Nd))

Phenyl ethyne, C-C direct linked dendrimer (M1=2H, M2=2H)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 49] Phenyl ethyne, CC direct linked dendrimer (M 1 = 2H, M 2 = 2H) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 49

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 244 :Example 244:

Phenyl ethyne, C-C direct linked dendrimer-Er(III) complex Phenyl ethyne, C-C direct linked dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Phenyl ethyne, C-C direct linked dendrimer (M1=2H, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 49] Phenyl ethyne, CC direct linked dendrimer (M 1 = 2H, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 49

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 245 :Example 245:

Phenyl ethyne, C-C direct linked dendrimer-Yb(III) complex Phenyl ethyne, C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Phenyl ethyne, C-C direct linked dendrimer (M1=2H, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 49] Phenyl ethyne, CC direct linked dendrimer (M 1 = 2H, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 49

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 246 :Example 246:

Phenyl ethyne, C-C direct linked dendrimer-Nd(III) complex Phenyl ethyne, C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Phenyl ethyne, C-C direct linked dendrimer (M1=2H, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 49] Phenyl ethyne, CC direct linked dendrimer (M 1 = 2H, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 49

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 247 :Example 247:

Phenyl ethyne, C-C direct linked dendrimer-Er(III) complex Phenyl ethyne, C-C direct linked dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Phenyl ethyne, C-C direct linked dendrimer (M1=2H, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 49] Phenyl ethyne, CC direct linked dendrimer (M 1 = 2H, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 49

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 248 :Example 248:

Phenyl ethyne, C-C direct linked dendrimer-Yb(III) complex Phenyl ethyne, C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Phenyl ethyne, C-C direct linked dendrimer (M1=2H, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 49] Phenyl ethyne, CC direct linked dendrimer (M 1 = 2H, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 49

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 249 :Example 249:

Phenyl ethyne, C-C direct linked dendrimer-Nd(III) complex Phenyl ethyne, C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Phenyl ethyne, C-C direct linked dendrimer (M1=2H, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 49] Phenyl ethyne, CC direct linked dendrimer (M 1 = 2H, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 49

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 250 :Example 250:

Phenyl ethyne, C-C direct linked dendrimer-Er(III) complex Phenyl ethyne, C-C direct linked dendrimer-Er (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Phenyl ethyne, C-C direct linked dendrimer (M1=Zn, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 49] Phenyl ethyne, CC direct linked dendrimer (M 1 = Zn, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 49

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 251 :Example 251:

Phenyl ethyne, C-C direct linked dendrimer-Yb(III) complex Phenyl ethyne, C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Phenyl ethyne, C-C direct linked dendrimer (M1=Zn, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 49] Phenyl ethyne, CC direct linked dendrimer (M 1 = Zn, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 49

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 252 :Example 252:

Phenyl ethyne, C-C direct linked dendrimer-Nd(III) complex Phenyl ethyne, C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Phenyl ethyne, C-C direct linked dendrimer (M1=Zn, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 49] Phenyl ethyne, CC direct linked dendrimer (M 1 = Zn, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 49

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 253 :Example 253:

Phenyl ethyne, C-C direct linked dendrimer-Er(III) complex Phenyl ethyne, C-C direct linked dendrimer-Er (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Phenyl ethyne, C-C direct linked dendrimer (M1=Zn, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 49] Phenyl ethyne, CC direct linked dendrimer (M 1 = Zn, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 49

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 254 :Example 254:

Phenyl ethyne, C-C direct linked dendrimer-Yb(III) complex Phenyl ethyne, C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Phenyl ethyne, C-C direct linked dendrimer (M1=Zn, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 49] Phenyl ethyne, CC direct linked dendrimer (M 1 = Zn, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 49

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 255 :Example 255:

Phenyl ethyne, C-C direct linked dendrimer-Nd(III) complex Phenyl ethyne, C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Phenyl ethyne, C-C direct linked dendrimer (M1=Zn, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 49] Phenyl ethyne, CC direct linked dendrimer (M 1 = Zn, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 49

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 256 :Example 256:

Phenyl ethyne, C-C direct linked dendrimer-Er(III) complex Phenyl ethyne, C-C direct linked dendrimer-Er (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Phenyl ethyne, C-C direct linked dendrimer (M1=Pt, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 49] Phenyl ethyne, CC direct linked dendrimer (M 1 = Pt, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 49

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 257 :Example 257:

Phenyl ethyne, C-C direct linked dendrimer-Yb(III) complex Phenyl ethyne, C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Phenyl ethyne, C-C direct linked dendrimer (M1=Pt, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 49] Phenyl ethyne, CC direct linked dendrimer (M 1 = Pt, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 49

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 258 :Example 258:

Phenyl ethyne, C-C direct linked dendrimer-Nd(III) complex Phenyl ethyne, C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Phenyl ethyne, C-C direct linked dendrimer (M1=Pt, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다.[반응식 49] Phenyl ethyne, CC direct linked dendrimer (M 1 = Pt, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 49

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 259 :Example 259:

Phenyl ethyne, C-C direct linked dendrimer-Er(III) complex Phenyl ethyne, C-C direct linked dendrimer-Er (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Phenyl ethyne, C-C direct linked dendrimer (M1=Pt, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 49] Phenyl ethyne, CC direct linked dendrimer (M 1 = Pt, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 49

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 260 :Example 260:

Phenyl ethyne, C-C direct linked dendrimer-Yb(III) complex Phenyl ethyne, C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Phenyl ethyne, C-C direct linked dendrimer (M1=Pt, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 49] Phenyl ethyne, CC direct linked dendrimer (M 1 = Pt, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 49

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 261 :Example 261:

Phenyl ethyne, C-C direct linked dendrimer-Nd(III) complex Phenyl ethyne, C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Phenyl ethyne, C-C direct linked dendrimer (M1=Pt, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 49] Phenyl ethyne, CC direct linked dendrimer (M 1 = Pt, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 49

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 262 :Example 262:

메시틸 에타인, C-C 직접링크된 덴드리머-Er(III) 착물Mesityl ethane, C-C directly linked dendrimer-Er (III) complex

(Mesityl ethyne, C-C direct linked dendrimer-Er(III) complex (Mesityl ethyne, C-C direct linked dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =2H, Ln=Er))= 2H, Ln = Er))

Mesityl ethyne, C-C direct linked dendrimer (M1=2H, M2=2H)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 50] Mesityl ethyne, CC direct linked dendrimer (M 1 = 2H, M 2 = 2H) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 50

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 263 :Example 263:

메시틸 에타인, C-C 직접링크된 덴드리머-Yb(III) 착물Mesityl ethane, C-C directly linked dendrimer-Yb (III) complex

(Mesityl ethyne, C-C direct linked dendrimer-Yb(III) complex (Mesityl ethyne, C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =2H, Ln=Yb))= 2H, Ln = Yb))

Mesityl ethyne, C-C direct linked dendrimer (M1=2H, M2=2H)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 50] Mesityl ethyne, CC direct linked dendrimer (M 1 = 2H, M 2 = 2H) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 50

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 264 :Example 264:

메시틸 에타인, C-C 직접링크된 덴드리머-Nd(III) 착물Mesityl ethane, C-C directly linked dendrimer-Nd (III) complex

(Mesityl ethyne, C-C direct linked dendrimer-Nd(III) complex (Mesityl ethyne, C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =2H, Ln=Nd))= 2H, Ln = Nd))

Mesityl ethyne, C-C direct linked dendrimer (M1=2H, M2=2H)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 50] Mesityl ethyne, CC direct linked dendrimer (M 1 = 2H, M 2 = 2H) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 50

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 265 :Example 265:

Mesityl ethyne, C-C direct linked dendrimer-Er(III) complex Mesityl ethyne, C-C direct linked dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Mesityl ethyne, C-C direct linked dendrimer (M1=2H, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 50] Mesityl ethyne, CC direct linked dendrimer (M 1 = 2H, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 50

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 266 :Example 266:

Mesityl ethyne, C-C direct linked dendrimer-Yb(III) complex Mesityl ethyne, C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Mesityl ethyne, C-C direct linked dendrimer (M1=2H, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 50] Mesityl ethyne, CC direct linked dendrimer (M 1 = 2H, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 50

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 267 :Example 267:

Mesityl ethyne, C-C direct linked dendrimer-Nd(III) complex Mesityl ethyne, C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Mesityl ethyne, C-C direct linked dendrimer (M1=2H, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 50] Mesityl ethyne, CC direct linked dendrimer (M 1 = 2H, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 50

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 268 :Example 268:

Mesityl ethyne, C-C direct linked dendrimer-Er(III) complex Mesityl ethyne, C-C direct linked dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Mesityl ethyne, C-C direct linked dendrimer (M1=2H, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 50] Mesityl ethyne, CC direct linked dendrimer (M 1 = 2H, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 50

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 269 :Example 269:

Mesityl ethyne, C-C direct linked dendrimer-Yb(III) complex Mesityl ethyne, C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Mesityl ethyne, C-C direct linked dendrimer (M1=2H, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 50] Mesityl ethyne, CC direct linked dendrimer (M 1 = 2H, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 50

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 270 :Example 270:

Mesityl ethyne, C-C direct linked dendrimer-Nd(III) complex Mesityl ethyne, C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Mesityl ethyne, C-C direct linked dendrimer (M1=2H, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 50] Mesityl ethyne, CC direct linked dendrimer (M 1 = 2H, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 50

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 271 :Example 271:

Mesityl ethyne, C-C direct linked dendrimer-Er(III) complex Mesityl ethyne, C-C direct linked dendrimer-Er (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Mesityl ethyne, C-C direct linked dendrimer (M1=Zn, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 50] Mesityl ethyne, CC direct linked dendrimer (M 1 = Zn, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 50

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 272 :Example 272:

Mesityl ethyne, C-C direct linked dendrimer-Yb(III) complex Mesityl ethyne, C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Mesityl ethyne, C-C direct linked dendrimer (M1=Zn, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 50] Mesityl ethyne, CC direct linked dendrimer (M 1 = Zn, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 50

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 273 :Example 273:

Mesityl ethyne, C-C direct linked dendrimer-Nd(III) complex Mesityl ethyne, C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Mesityl ethyne, C-C direct linked dendrimer (M1=Zn, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 50] Mesityl ethyne, CC direct linked dendrimer (M 1 = Zn, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 50

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 274 :Example 274:

Mesityl ethyne, C-C direct linked dendrimer-Er(III) complex Mesityl ethyne, C-C direct linked dendrimer-Er (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Mesityl ethyne, C-C direct linked dendrimer (M1=Zn, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 50] Mesityl ethyne, CC direct linked dendrimer (M 1 = Zn, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 50

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 275 :Example 275:

Mesityl ethyne, C-C direct linked dendrimer-Yb(III) complex Mesityl ethyne, C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Mesityl ethyne, C-C direct linked dendrimer (M1=Zn, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 50] Mesityl ethyne, CC direct linked dendrimer (M 1 = Zn, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 50

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 276 :Example 276:

Mesityl ethyne, C-C direct linked dendrimer-Nd(III) complex Mesityl ethyne, C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Mesityl ethyne, C-C direct linked dendrimer (M1=Zn, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 50] Mesityl ethyne, CC direct linked dendrimer (M 1 = Zn, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 50

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 277 :Example 277:

Mesityl ethyne, C-C direct linked dendrimer-Er(III) complex Mesityl ethyne, C-C direct linked dendrimer-Er (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Mesityl ethyne, C-C direct linked dendrimer (M1=Pt, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 50] Mesityl ethyne, CC direct linked dendrimer (M 1 = Pt, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 50

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 278 :Example 278:

Mesityl ethyne, C-C direct linked dendrimer-Yb(III) complex Mesityl ethyne, C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Mesityl ethyne, C-C direct linked dendrimer (M1=Pt, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 50] Mesityl ethyne, CC direct linked dendrimer (M 1 = Pt, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 50

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 279 :Example 279:

Mesityl ethyne, C-C direct linked dendrimer-Nd(III) complex Mesityl ethyne, C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Mesityl ethyne, C-C direct linked dendrimer (M1=Pt, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 50] Mesityl ethyne, CC direct linked dendrimer (M 1 = Pt, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 50

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 280 :Example 280:

Mesityl ethyne, C-C direct linked dendrimer-Er(III) complex Mesityl ethyne, C-C direct linked dendrimer-Er (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Mesityl ethyne, C-C direct linked dendrimer (M1=Pt, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 50] Mesityl ethyne, CC direct linked dendrimer (M 1 = Pt, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 50

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 281 :Example 281:

Mesityl ethyne, C-C direct linked dendrimer-Yb(III) complex Mesityl ethyne, C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Mesityl ethyne, C-C direct linked dendrimer (M1=Pt, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 50] Mesityl ethyne, CC direct linked dendrimer (M 1 = Pt, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 50

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 282 :Example 282:

Mesityl ethyne, C-C direct linked dendrimer-Nd(III) complex Mesityl ethyne, C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Mesityl ethyne, C-C direct linked dendrimer (M1=Pt, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 50] Mesityl ethyne, CC direct linked dendrimer (M 1 = Pt, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 50

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 283 :Example 283:

페닐 에타인, (3,5)-C-C 직접링크된 덴드리머-Er(III) 착물 Phenyl ethane, (3,5) -C-C directly linked dendrimer-Er (III) complex

(Phenyl ethyne, (3,5)-C-C direct linked dendrimer-Er(III) complex)(Phenyl ethyne, (3,5) -C-C direct linked dendrimer-Er (III) complex)

(M(M 1One =2H, M= 2H, M 22 =2H, Ln=Er)= 2H, Ln = Er)

Phenyl ethyne, (3,5)-C-C direct linked dendrimer (M1=2H, M2=2H)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 51] Phenyl ethyne, (3,5) -CC direct linked dendrimer (M 1 = 2H, M 2 = 2H) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 51

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 284 :Example 284:

페닐 에타인, (3,5)-C-C 직접링크된 덴드리머-Yb(III) 착물 Phenyl ethane, (3,5) -C-C directly linked dendrimer-Yb (III) complex

(Phenyl ethyne, (3,5)-C-C direct linked dendrimer-Yb(III) complex )(Phenyl ethyne, (3,5) -C-C direct linked dendrimer-Yb (III) complex)

(M(M 1One =2H, M= 2H, M 22 =2H, Ln=Yb)= 2H, Ln = Yb)

Phenyl ethyne, (3,5)-C-C direct linked dendrimer (M1=2H, M2=2H)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 51] Phenyl ethyne, (3,5) -CC direct linked dendrimer (M 1 = 2H, M 2 = 2H) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 51

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 285 :Example 285:

페닐 에타인, (3,5)-C-C 직접링크된 덴드리머-Nd(III) 착물 Phenyl ethane, (3,5) -C-C directly linked dendrimer-Nd (III) complex

(Phenyl ethyne, (3,5)-C-C direct linked dendrimer-Nd(III) complex) (Phenyl ethyne, (3,5) -C-C direct linked dendrimer-Nd (III) complex)

(M(M 1One =2H, M= 2H, M 22 =2H, Ln=Nd)= 2H, Ln = Nd)

Phenyl ethyne, (3,5)-C-C direct linked dendrimer (M1=2H, M2=2H)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 51] Phenyl ethyne, (3,5) -CC direct linked dendrimer (M 1 = 2H, M 2 = 2H) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 51

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 286 :Example 286:

Phenyl ethyne, (3,5)-C-C direct linked dendrimer-Er(III) complex Phenyl ethyne, (3,5) -C-C direct linked dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Phenyl ethyne, (3,5)-C-C direct linked dendrimer (M1=2H, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 51] Phenyl ethyne, (3,5) -CC direct linked dendrimer (M 1 = 2H, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 51

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 287 :Example 287:

Phenyl ethyne, (3,5)-C-C direct linked dendrimer-Yb(III) complex Phenyl ethyne, (3,5) -C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Phenyl ethyne, (3,5)-C-C direct linked dendrimer (M1=2H, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 51] Phenyl ethyne, (3,5) -CC direct linked dendrimer (M 1 = 2H, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 51

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 288 :Example 288:

Phenyl ethyne, (3,5)-C-C direct linked dendrimer-Nd(III) complex Phenyl ethyne, (3,5) -C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Phenyl ethyne, (3,5)-C-C direct linked dendrimer (M1=2H, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 51] Phenyl ethyne, (3,5) -CC direct linked dendrimer (M 1 = 2H, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 51

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 289 :Example 289:

Phenyl ethyne, (3,5)-C-C direct linked dendrimer-Er(III) complex Phenyl ethyne, (3,5) -C-C direct linked dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Phenyl ethyne, (3,5)-C-C direct linked dendrimer (M1=2H, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 51] Phenyl ethyne, (3,5) -CC direct linked dendrimer (M 1 = 2H, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 51

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 290 :Example 290:

Phenyl ethyne, (3,5)-C-C direct linked dendrimer-Yb(III) complex Phenyl ethyne, (3,5) -C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Phenyl ethyne, (3,5)-C-C direct linked dendrimer (M1=2H, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 51] Phenyl ethyne, (3,5) -CC direct linked dendrimer (M 1 = 2H, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 51

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 291 :Example 291:

Phenyl ethyne, (3,5)-C-C direct linked dendrimer-Nd(III) complex Phenyl ethyne, (3,5) -C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Phenyl ethyne, (3,5)-C-C direct linked dendrimer (M1=2H, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 51] Phenyl ethyne, (3,5) -CC direct linked dendrimer (M 1 = 2H, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 51

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 292 :Example 292:

Phenyl ethyne, (3,5)-C-C direct linked dendrimer-Er(III) complex Phenyl ethyne, (3,5) -C-C direct linked dendrimer-Er (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Phenyl ethyne, (3,5)-C-C direct linked dendrimer (M1=Zn, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 51] Phenyl ethyne, (3,5) -CC direct linked dendrimer (M 1 = Zn, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 51

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 293 :Example 293:

Phenyl ethyne, (3,5)-C-C direct linked dendrimer-Yb(III) complex Phenyl ethyne, (3,5) -C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Phenyl ethyne, (3,5)-C-C direct linked dendrimer (M1=Zn, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 51] Phenyl ethyne, (3,5) -CC direct linked dendrimer (M 1 = Zn, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 51

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 294 :Example 294:

Phenyl ethyne, (3,5)-C-C direct linked dendrimer-Nd(III) complex Phenyl ethyne, (3,5) -C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Phenyl ethyne, (3,5)-C-C direct linked dendrimer (M1=Zn, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 51] Phenyl ethyne, (3,5) -CC direct linked dendrimer (M 1 = Zn, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 51

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 295 :Example 295:

Phenyl ethyne, (3,5)-C-C direct linked dendrimer-Er(III) complex Phenyl ethyne, (3,5) -C-C direct linked dendrimer-Er (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Phenyl ethyne, (3,5)-C-C direct linked dendrimer (M1=Zn, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 51] Phenyl ethyne, (3,5) -CC direct linked dendrimer (M 1 = Zn, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 51

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 296 :Example 296:

Phenyl ethyne, (3,5)-C-C direct linked dendrimer-Yb(III) complex Phenyl ethyne, (3,5) -C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Phenyl ethyne, (3,5)-C-C direct linked dendrimer (M1=Zn, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 51] Phenyl ethyne, (3,5) -CC direct linked dendrimer (M 1 = Zn, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 51

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 297 :Example 297:

Phenyl ethyne, (3,5)-C-C direct linked dendrimer-Nd(III) complex Phenyl ethyne, (3,5) -C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Phenyl ethyne, (3,5)-C-C direct linked dendrimer (M1=Zn, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 51] Phenyl ethyne, (3,5) -CC direct linked dendrimer (M 1 = Zn, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 51

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 298 :Example 298:

Phenyl ethyne, (3,5)-C-C direct linked dendrimer-Er(III) complex Phenyl ethyne, (3,5) -C-C direct linked dendrimer-Er (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Phenyl ethyne, (3,5)-C-C direct linked dendrimer (M1=Pt, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 51] Phenyl ethyne, (3,5) -CC direct linked dendrimer (M 1 = Pt, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 51

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 299 :Example 299:

Phenyl ethyne, (3,5)-C-C direct linked dendrimer-Yb(III) complex Phenyl ethyne, (3,5) -C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Phenyl ethyne, (3,5)-C-C direct linked dendrimer (M1=Pt, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 51] Phenyl ethyne, (3,5) -CC direct linked dendrimer (M 1 = Pt, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 51

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 300 :Example 300:

Phenyl ethyne, (3,5)-C-C direct linked dendrimer-Nd(III) complex Phenyl ethyne, (3,5) -C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Phenyl ethyne, (3,5)-C-C direct linked dendrimer (M1=Pt, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 51] Phenyl ethyne, (3,5) -CC direct linked dendrimer (M 1 = Pt, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 51

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 301 :Example 301:

Phenyl ethyne, (3,5)-C-C direct linked dendrimer-Er(III) complex Phenyl ethyne, (3,5) -C-C direct linked dendrimer-Er (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Phenyl ethyne, (3,5)-C-C direct linked dendrimer (M1=Pt, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 51] Phenyl ethyne, (3,5) -CC direct linked dendrimer (M 1 = Pt, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 51

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 302 :Example 302:

Phenyl ethyne, (3,5)-C-C direct linked dendrimer-Yb(III) complex Phenyl ethyne, (3,5) -C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Phenyl ethyne, (3,5)-C-C direct linked dendrimer (M1=Pt, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 51] Phenyl ethyne, (3,5) -CC direct linked dendrimer (M 1 = Pt, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 51

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 303 :Example 303:

Phenyl ethyne, (3,5)-C-C direct linked dendrimer-Nd(III) complex Phenyl ethyne, (3,5) -C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Phenyl ethyne, (3,5)-C-C direct linked dendrimer (M1=Pt, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 51] Phenyl ethyne, (3,5) -CC direct linked dendrimer (M 1 = Pt, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 51

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 304 :Example 304:

메시틸 에타인, (3,5)-C-C 직접링크된 덴드리머-Er(III) 착물 Mesityl ethane, (3,5) -C-C directly linked dendrimer-Er (III) complex

(Mesityl ethyne, (3,5)-C-C direct linked dendrimer-Er(III) complex)(Mesityl ethyne, (3,5) -C-C direct linked dendrimer-Er (III) complex)

(M(M 1One =2H, M= 2H, M 22 =2H, Ln=Er)= 2H, Ln = Er)

Mesityl ethyne, (3,5)-C-C direct linked dendrimer (M1=2H, M2=2H)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 52] Mesityl ethyne, (3,5) -CC direct linked dendrimer (M 1 = 2H, M 2 = 2H) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 52

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 305 :Example 305:

메시틸 에타인, (3,5)-C-C 직접링크된 덴드리머-Yb(III) 착물 Mesityl ethane, (3,5) -C-C directly linked dendrimer-Yb (III) complex

(Mesityl ethyne, (3,5)-C-C direct linked dendrimer-Yb(III) complex )(Mesityl ethyne, (3,5) -C-C direct linked dendrimer-Yb (III) complex)

(M(M 1One =2H, M= 2H, M 22 =2H, Ln=Yb)= 2H, Ln = Yb)

Mesityl ethyne, (3,5)-C-C direct linked dendrimer (M1=2H, M2=2H)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 52] Mesityl ethyne, (3,5) -CC direct linked dendrimer (M 1 = 2H, M 2 = 2H) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 52

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 306 :Example 306:

메시틸 에타인, (3,5)-C-C 직접링크된 덴드리머-Nd(III) 착물 Mesityl ethane, (3,5) -C-C directly linked dendrimer-Nd (III) complex

(Mesityl ethyne, (3,5)-C-C direct linked dendrimer-Nd(III) complex)(Mesityl ethyne, (3,5) -C-C direct linked dendrimer-Nd (III) complex)

(M(M 1One =2H, M= 2H, M 22 =2H, Ln=Nd)= 2H, Ln = Nd)

Mesityl ethyne, (3,5)-C-C direct linked dendrimer (M1=2H, M2=2H)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 52] Mesityl ethyne, (3,5) -CC direct linked dendrimer (M 1 = 2H, M 2 = 2H) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 52

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 307 :Example 307:

Mesityl ethyne, (3,5)-C-C direct linked dendrimer-Er(III) complex Mesityl ethyne, (3,5) -C-C direct linked dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Mesityl ethyne, (3,5)-C-C direct linked dendrimer (M1=2H, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 52] Mesityl ethyne, (3,5) -CC direct linked dendrimer (M 1 = 2H, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 52

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 308 :Example 308:

Mesityl ethyne, (3,5)-C-C direct linked dendrimer-Yb(III) complex Mesityl ethyne, (3,5) -C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Mesityl ethyne, (3,5)-C-C direct linked dendrimer (M1=2H, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 52] Mesityl ethyne, (3,5) -CC direct linked dendrimer (M 1 = 2H, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 52

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 309 :Example 309:

Mesityl ethyne, (3,5)-C-C direct linked dendrimer-Nd(III) complex Mesityl ethyne, (3,5) -C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Mesityl ethyne, (3,5)-C-C direct linked dendrimer (M1=2H, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 52] Mesityl ethyne, (3,5) -CC direct linked dendrimer (M 1 = 2H, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 52

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 310 :Example 310:

Mesityl ethyne, (3,5)-C-C direct linked dendrimer-Er(III) complex Mesityl ethyne, (3,5) -C-C direct linked dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Mesityl ethyne, (3,5)-C-C direct linked dendrimer (M1=2H, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 52] Mesityl ethyne, (3,5) -CC direct linked dendrimer (M 1 = 2H, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 52

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 311 :Example 311:

Mesityl ethyne, (3,5)-C-C direct linked dendrimer-Yb(III) complex Mesityl ethyne, (3,5) -C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Mesityl ethyne, (3,5)-C-C direct linked dendrimer (M1=2H, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 52] Mesityl ethyne, (3,5) -CC direct linked dendrimer (M 1 = 2H, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 52

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 312 :Example 312:

Mesityl ethyne, (3,5)-C-C direct linked dendrimer-Nd(III) complex Mesityl ethyne, (3,5) -C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Mesityl ethyne, (3,5)-C-C direct linked dendrimer (M1=2H, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 52] Mesityl ethyne, (3,5) -CC direct linked dendrimer (M 1 = 2H, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 52

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 313 :Example 313:

Mesityl ethyne, (3,5)-C-C direct linked dendrimer-Er(III) complex Mesityl ethyne, (3,5) -C-C direct linked dendrimer-Er (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Mesityl ethyne, (3,5)-C-C direct linked dendrimer (M1=Zn, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 52] Mesityl ethyne, (3,5) -CC direct linked dendrimer (M 1 = Zn, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 52

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 314 :Example 314:

Mesityl ethyne, (3,5)-C-C direct linked dendrimer-Yb(III) complex Mesityl ethyne, (3,5) -C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Mesityl ethyne, (3,5)-C-C direct linked dendrimer (M1=Zn, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 52] Mesityl ethyne, (3,5) -CC direct linked dendrimer (M 1 = Zn, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 52

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 315 :Example 315:

Mesityl ethyne, (3,5)-C-C direct linked dendrimer-Nd(III) complex Mesityl ethyne, (3,5) -C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Mesityl ethyne, (3,5)-C-C direct linked dendrimer (M1=Zn, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 52] Mesityl ethyne, (3,5) -CC direct linked dendrimer (M 1 = Zn, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 52

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 316 :Example 316:

Mesityl ethyne, (3,5)-C-C direct linked dendrimer-Er(III) complex Mesityl ethyne, (3,5) -C-C direct linked dendrimer-Er (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Mesityl ethyne, (3,5)-C-C direct linked dendrimer (M1=Zn, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 52] Mesityl ethyne, (3,5) -CC direct linked dendrimer (M 1 = Zn, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 52

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 317 :Example 317:

Mesityl ethyne, (3,5)-C-C direct linked dendrimer-Yb(III) complex Mesityl ethyne, (3,5) -C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Mesityl ethyne, (3,5)-C-C direct linked dendrimer (M1=Zn, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 52] Mesityl ethyne, (3,5) -CC direct linked dendrimer (M 1 = Zn, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 52

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 318 :Example 318:

Mesityl ethyne, (3,5)-C-C direct linked dendrimer-Nd(III) complex Mesityl ethyne, (3,5) -C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Mesityl ethyne, (3,5)-C-C direct linked dendrimer (M1=Zn, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 52] Mesityl ethyne, (3,5) -CC direct linked dendrimer (M 1 = Zn, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 52

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 319 :Example 319:

Mesityl ethyne, (3,5)-C-C direct linked dendrimer-Er(III) complex Mesityl ethyne, (3,5) -C-C direct linked dendrimer-Er (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Mesityl ethyne, (3,5)-C-C direct linked dendrimer (M1=Pt, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 52] Mesityl ethyne, (3,5) -CC direct linked dendrimer (M 1 = Pt, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 52

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 320 :Example 320:

Mesityl ethyne, (3,5)-C-C direct linked dendrimer-Yb(III) complex Mesityl ethyne, (3,5) -C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Mesityl ethyne, (3,5)-C-C direct linked dendrimer (M1=Pt, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 52] Mesityl ethyne, (3,5) -CC direct linked dendrimer (M 1 = Pt, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 52

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 321 :Example 321:

Mesityl ethyne, (3,5)-C-C direct linked dendrimer-Nd(III) complex Mesityl ethyne, (3,5) -C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Mesityl ethyne, (3,5)-C-C direct linked dendrimer (M1=Pt, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 52] Mesityl ethyne, (3,5) -CC direct linked dendrimer (M 1 = Pt, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 52

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 322 :Example 322:

Mesityl ethyne, (3,5)-C-C direct linked dendrimer-Er(III) complex Mesityl ethyne, (3,5) -C-C direct linked dendrimer-Er (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Mesityl ethyne, (3,5)-C-C direct linked dendrimer (M1=Pt, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 52] Mesityl ethyne, (3,5) -CC direct linked dendrimer (M 1 = Pt, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 52

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 323 :Example 323:

Mesityl ethyne, (3,5)-C-C direct linked dendrimer-Yb(III) complex Mesityl ethyne, (3,5) -C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Mesityl ethyne, (3,5)-C-C direct linked dendrimer (M1=Pt, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 52] Mesityl ethyne, (3,5) -CC direct linked dendrimer (M 1 = Pt, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 52

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 324 :Example 324:

Mesityl ethyne, (3,5)-C-C direct linked dendrimer-Nd(III) complex Mesityl ethyne, (3,5) -C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Mesityl ethyne, (3,5)-C-C direct linked dendrimer (M1=Pt, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 52] Mesityl ethyne, (3,5) -CC direct linked dendrimer (M 1 = Pt, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 52

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 325 :Example 325:

페닐 에타인, 에테르-브릿지드 덴드리머-Er(III) 착물(Phenyl ethyne, ether-bridged dendrimer-Er(III) complex)(MPhenyl ethyne, ether-bridged dendrimer-Er (III) complex (M) 1One =2H, M= 2H, M 22 =2H, Ln=Er)= 2H, Ln = Er)

Phenyl ethyne, ether-bridged dendrimer (M1=2H, M2=2H)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 53] Phenyl ethyne, ether-bridged dendrimer (M 1 = 2H, M 2 = 2H) and erbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 53

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 326 :Example 326:

페닐 에타인, 에테르-브릿지드 덴드리머-Yb(III) 착물(Phenyl ethyne, ether-bridged dendrimer-Yb(III) complex)(MPhenyl ethyne, ether-bridged dendrimer-Yb (III) complex (M) 1One =2H, M= 2H, M 22 =2H, Ln=Yb)= 2H, Ln = Yb)

Phenyl ethyne, ether-bridged dendrimer (M1=2H, M2=2H)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 53] Phenyl ethyne, ether-bridged dendrimer (M 1 = 2H, M 2 = 2H) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 53

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 327 :Example 327:

페닐 에타인, 에테르-브릿지드 덴드리머-Nd(III) 착물(Phenyl ethyne, ether-bridged dendrimer-Nd(III) complex)(MPhenyl ethyne, ether-bridged dendrimer-Nd (III) complex (M) 1One =2H, M= 2H, M 22 =2H, Ln=Nd)= 2H, Ln = Nd)

Phenyl ethyne, ether-bridged dendrimer (M1=2H, M2=2H)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 53] Phenyl ethyne, ether-bridged dendrimer (M 1 = 2H, M 2 = 2H) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 53

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 328 :Example 328:

Phenyl ethyne, ether-bridged dendrimer-Er(III) complex Phenyl ethyne, ether-bridged dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Phenyl ethyne, ether-bridged dendrimer (M1=2H, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 53] Phenyl ethyne, ether-bridged dendrimer (M 1 = 2H, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 53

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 329 :Example 329:

Phenyl ethyne, ether-bridged dendrimer-Yb(III) complex Phenyl ethyne, ether-bridged dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Phenyl ethyne, ether-bridged dendrimer (M1=2H, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 53] Phenyl ethyne, ether-bridged dendrimer (M 1 = 2H, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 53

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 330 :Example 330:

Phenyl ethyne, ether-bridged dendrimer-Nd(III) complex Phenyl ethyne, ether-bridged dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Phenyl ethyne, ether-bridged dendrimer (M1=2H, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 53] Phenyl ethyne, ether-bridged dendrimer (M 1 = 2H, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 53

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 331 :Example 331:

Phenyl ethyne, ether-bridged dendrimer-Er(III) complex Phenyl ethyne, ether-bridged dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Phenyl ethyne, ether-bridged dendrimer (M1=2H, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 53] Phenyl ethyne, ether-bridged dendrimer (M 1 = 2H, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 53

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 332 :Example 332:

Phenyl ethyne, ether-bridged dendrimer-Yb(III) complex Phenyl ethyne, ether-bridged dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Phenyl ethyne, ether-bridged dendrimer (M1=2H, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 53] Phenyl ethyne, ether-bridged dendrimer (M 1 = 2H, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 53

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 333 :Example 333:

Phenyl ethyne, ether-bridged dendrimer-Nd(III) complex Phenyl ethyne, ether-bridged dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Phenyl ethyne, ether-bridged dendrimer (M1=2H, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 53] Phenyl ethyne, ether-bridged dendrimer (M 1 = 2H, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 53

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 334 :Example 334:

Phenyl ethyne, ether-bridged dendrimer-Er(III) complex Phenyl ethyne, ether-bridged dendrimer-Er (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Phenyl ethyne, ether-bridged dendrimer (M1=Zn, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 53] Phenyl ethyne, ether-bridged dendrimer (M 1 = Zn, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 53

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 335 :Example 335:

Phenyl ethyne, ether-bridged dendrimer-Yb(III) complex Phenyl ethyne, ether-bridged dendrimer-Yb (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Phenyl ethyne, ether-bridged dendrimer (M1=Zn, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 53] Phenyl ethyne, ether-bridged dendrimer (M 1 = Zn, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 53

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 336 :Example 336:

Phenyl ethyne, ether-bridged dendrimer-Nd(III) complex Phenyl ethyne, ether-bridged dendrimer-Nd (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Phenyl ethyne, ether-bridged dendrimer (M1=Zn, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 53] Phenyl ethyne, ether-bridged dendrimer (M 1 = Zn, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 53

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 337 :Example 337:

Phenyl ethyne, ether-bridged dendrimer-Er(III) complex Phenyl ethyne, ether-bridged dendrimer-Er (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Phenyl ethyne, ether-bridged dendrimer (M1=Zn, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 53] Phenyl ethyne, ether-bridged dendrimer (M 1 = Zn, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 53

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 338 :Example 338:

Phenyl ethyne, ether-bridged dendrimer-Yb(III) complex Phenyl ethyne, ether-bridged dendrimer-Yb (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Phenyl ethyne, ether-bridged dendrimer (M1=Zn, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 53] Phenyl ethyne, ether-bridged dendrimer (M 1 = Zn, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 53

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 339 :Example 339:

Phenyl ethyne, ether-bridged dendrimer-Nd(III) complex Phenyl ethyne, ether-bridged dendrimer-Nd (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Phenyl ethyne, ether-bridged dendrimer (M1=Zn, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 53] Phenyl ethyne, ether-bridged dendrimer (M 1 = Zn, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 53

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 340 :Example 340:

Phenyl ethyne, ether-bridged dendrimer-Er(III) complex Phenyl ethyne, ether-bridged dendrimer-Er (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Phenyl ethyne, ether-bridged dendrimer (M1=Pt, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 53] Phenyl ethyne, ether-bridged dendrimer (M 1 = Pt, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 53

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 341 :Example 341:

Phenyl ethyne, ether-bridged dendrimer-Yb(III) complex Phenyl ethyne, ether-bridged dendrimer-Yb (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Phenyl ethyne, ether-bridged dendrimer (M1=Pt, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 53] Phenyl ethyne, ether-bridged dendrimer (M 1 = Pt, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 53

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 342 :Example 342:

Phenyl ethyne, ether-bridged dendrimer-Nd(III) complex Phenyl ethyne, ether-bridged dendrimer-Nd (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Phenyl ethyne, ether-bridged dendrimer (M1=Pt, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 53] Phenyl ethyne, ether-bridged dendrimer (M 1 = Pt, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 53

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 343 :Example 343:

Phenyl ethyne, ether-bridged dendrimer-Er(III) complex Phenyl ethyne, ether-bridged dendrimer-Er (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Phenyl ethyne, ether-bridged dendrimer (M1=Pt, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 53] Phenyl ethyne, ether-bridged dendrimer (M 1 = Pt, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 53

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 344 :Example 344:

Phenyl ethyne, ether-bridged dendrimer-Yb(III) complex Phenyl ethyne, ether-bridged dendrimer-Yb (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Phenyl ethyne, ether-bridged dendrimer (M1=Pt, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 53] Phenyl ethyne, ether-bridged dendrimer (M 1 = Pt, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 53

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 345 :Example 345:

Phenyl ethyne, ether-bridged dendrimer-Nd(III) complex Phenyl ethyne, ether-bridged dendrimer-Nd (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Phenyl ethyne, ether-bridged dendrimer (M1=Pt, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 53] Phenyl ethyne, ether-bridged dendrimer (M 1 = Pt, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 53

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 346 :Example 346:

메시틸 에타인, 에테르-브릿지드 덴드리머-Er(III) 착물(Mesityl ethyne, ether-bridged dendrimer-Er(III) complex)(MMesityl ethyne, ether-bridged dendrimer-Er (III) complex (M) 1One =2H, M= 2H, M 22 =2H, Ln=Er)= 2H, Ln = Er)

Mesityl ethyne, ether-bridged dendrimer (M1=2H, M2=2H)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 54] Mesityl ethyne, ether-bridged dendrimer (M 1 = 2H, M 2 = 2H) and erbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 54

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 347 :Example 347:

메시틸 에타인, 에테르-브릿지드 덴드리머-Yb(III) 착물(Mesityl ethyne, ether-bridged dendrimer-Yb(III) complex)(MMesityl ethyne, ether-bridged dendrimer-Yb (III) complex (M) 1One =2H, M= 2H, M 22 =2H, Ln=Yb)= 2H, Ln = Yb)

Mesityl ethyne, ether-bridged dendrimer (M1=2H, M2=2H)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 54] Mesityl ethyne, ether-bridged dendrimer (M 1 = 2H, M 2 = 2H) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 54

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 348 :Example 348:

메시틸 에타인, 에테르-브릿지드 덴드리머-Nd(III) 착물(Mesityl ethyne, ether-bridged dendrimer-Nd(III) complex)(MMesityl ethyne, ether-bridged dendrimer-Nd (III) complex (M) 1One =2H, M= 2H, M 22 =2H, Ln=Nd)= 2H, Ln = Nd)

Mesityl ethyne, ether-bridged dendrimer (M1=2H, M2=2H)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 54] Mesityl ethyne, ether-bridged dendrimer (M 1 = 2H, M 2 = 2H) and neodymium chloride hexahydrate were synthesized by the Ln-complex production method. Scheme 54

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 349 :Example 349:

Mesityl ethyne, ether-bridged dendrimer-Er(III) complex Mesityl ethyne, ether-bridged dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Mesityl ethyne, ether-bridged dendrimer (M1=2H, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 54] Mesityl ethyne, ether-bridged dendrimer (M 1 = 2H, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 54

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 350 :Example 350:

Mesityl ethyne, ether-bridged dendrimer-Yb(III) complex Mesityl ethyne, ether-bridged dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Mesityl ethyne, ether-bridged dendrimer (M1=2H, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 54] Mesityl ethyne, ether-bridged dendrimer (M 1 = 2H, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 54

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 351 :Example 351:

Mesityl ethyne, ether-bridged dendrimer-Nd(III) complex Mesityl ethyne, ether-bridged dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Mesityl ethyne, ether-bridged dendrimer (M1=2H, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 54] Mesityl ethyne, ether-bridged dendrimer (M 1 = 2H, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 54

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 352 :Example 352:

Mesityl ethyne, ether-bridged dendrimer-Er(III) complex Mesityl ethyne, ether-bridged dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Mesityl ethyne, ether-bridged dendrimer (M1=2H, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 54] Mesityl ethyne, ether-bridged dendrimer (M 1 = 2H, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 54

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 353 :Example 353:

Mesityl ethyne, ether-bridged dendrimer-Yb(III) complex Mesityl ethyne, ether-bridged dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Mesityl ethyne, ether-bridged dendrimer (M1=2H, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 54] Mesityl ethyne, ether-bridged dendrimer (M 1 = 2H, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 54

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 354 :Example 354:

Mesityl ethyne, ether-bridged dendrimer-Nd(III) complex Mesityl ethyne, ether-bridged dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Mesityl ethyne, ether-bridged dendrimer (M1=2H, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 54] Mesityl ethyne, ether-bridged dendrimer (M 1 = 2H, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 54

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 355 :Example 355:

Mesityl ethyne, ether-bridged dendrimer-Er(III) complex Mesityl ethyne, ether-bridged dendrimer-Er (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Mesityl ethyne, ether-bridged dendrimer (M1=Zn, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 54] Mesityl ethyne, ether-bridged dendrimer (M 1 = Zn, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 54

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 356 :Example 356:

Mesityl ethyne, ether-bridged dendrimer-Yb(III) complex Mesityl ethyne, ether-bridged dendrimer-Yb (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Mesityl ethyne, ether-bridged dendrimer (M1=Zn, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 54] Mesityl ethyne, ether-bridged dendrimer (M 1 = Zn, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 54

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 357 :Example 357:

Mesityl ethyne, ether-bridged dendrimer-Nd(III) complex Mesityl ethyne, ether-bridged dendrimer-Nd (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Mesityl ethyne, ether-bridged dendrimer (M1=Zn, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 54] Mesityl ethyne, ether-bridged dendrimer (M 1 = Zn, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 54

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 358 :Example 358:

Mesityl ethyne, ether-bridged dendrimer-Er(III) complex Mesityl ethyne, ether-bridged dendrimer-Er (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Mesityl ethyne, ether-bridged dendrimer (M1=Zn, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 54] Mesityl ethyne, ether-bridged dendrimer (M 1 = Zn, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 54

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 359 :Example 359:

Mesityl ethyne, ether-bridged dendrimer-Yb(III) complex Mesityl ethyne, ether-bridged dendrimer-Yb (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Mesityl ethyne, ether-bridged dendrimer (M1=Zn, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 54] Mesityl ethyne, ether-bridged dendrimer (M 1 = Zn, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 54

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 360 :Example 360:

Mesityl ethyne, ether-bridged dendrimer-Nd(III) complex Mesityl ethyne, ether-bridged dendrimer-Nd (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Mesityl ethyne, ether-bridged dendrimer (M1=Zn, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 54] Mesityl ethyne, ether-bridged dendrimer (M 1 = Zn, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 54

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 361 :Example 361:

Mesityl ethyne, ether-bridged dendrimer-Er(III) complex Mesityl ethyne, ether-bridged dendrimer-Er (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Mesityl ethyne, ether-bridged dendrimer (M1=Pt, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 54] Mesityl ethyne, ether-bridged dendrimer (M 1 = Pt, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 54

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 362 :Example 362:

Mesityl ethyne, ether-bridged dendrimer-Yb(III) complex Mesityl ethyne, ether-bridged dendrimer-Yb (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Mesityl ethyne, ether-bridged dendrimer (M1=Pt, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 54] Mesityl ethyne, ether-bridged dendrimer (M 1 = Pt, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 54

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 363 :Example 363:

Mesityl ethyne, ether-bridged dendrimer-Nd(III) complex Mesityl ethyne, ether-bridged dendrimer-Nd (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Mesityl ethyne, ether-bridged dendrimer (M1=Pt, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 54] Mesityl ethyne, ether-bridged dendrimer (M 1 = Pt, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 54

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 364 :Example 364:

Mesityl ethyne, ether-bridged dendrimer-Er(III) complex Mesityl ethyne, ether-bridged dendrimer-Er (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Mesityl ethyne, ether-bridged dendrimer (M1=Pt, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 54] Mesityl ethyne, ether-bridged dendrimer (M 1 = Pt, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 54

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 365 :Example 365:

Mesityl ethyne, ether-bridged dendrimer-Yb(III) complex Mesityl ethyne, ether-bridged dendrimer-Yb (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Mesityl ethyne, ether-bridged dendrimer (M1=Pt, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 54] Mesityl ethyne, ether-bridged dendrimer (M 1 = Pt, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 54

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 366 :Example 366:

Mesityl ethyne, ether-bridged dendrimer-Nd(III) complex Mesityl ethyne, ether-bridged dendrimer-Nd (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Mesityl ethyne, ether-bridged dendrimer (M1=Pt, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 54] Mesityl ethyne, ether-bridged dendrimer (M 1 = Pt, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 54

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 367 :Example 367:

페닐 에타인, (3,5)-에테르-브릿지드 덴드리머-Er(III) 착물(Phenyl ethyne, (3,5)-ether-bridged dendrimer-Er(III) complex)(MPhenyl ethyne, (3,5) -ether-bridged dendrimer-Er (III) complex (M), phenyl ethane, (3,5) -ether-bridged dendrimer-Er (III) complex 1One =2H, M= 2H, M 2 2 =2H, Ln=Er)= 2H, Ln = Er)

Phenyl ethyne, (3,5)-ether-bridged dendrimer (M1=2H, M2=2H)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 55] Phenyl ethyne, (3,5) -ether-bridged dendrimer (M 1 = 2H, M 2 = 2H) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 55

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 368 :Example 368:

페닐 에타인, (3,5)-에테르-브릿지드 덴드리머-Yb(III) 착물(Phenyl ethyne, (3,5)-ether-bridged dendrimer-Yb(III) complex)(MPhenyl ethyne, (3,5) -ether-bridged dendrimer-Yb (III) complex (M), phenyl ethane, (3,5) -ether-bridged dendrimer-Yb (III) complex 1One =2H, M= 2H, M 2 2 =2H, Ln=Yb)= 2H, Ln = Yb)

Phenyl ethyne, (3,5)-ether-bridged dendrimer (M1=2H, M2=2H)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 55] Phenyl ethyne, (3,5) -ether-bridged dendrimer (M 1 = 2H, M 2 = 2H) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 55

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 369 :Example 369:

페닐 에타인, (3,5)-에테르-브릿지드 덴드리머-Nd(III) 착물(Phenyl ethyne, (3,5)-ether-bridged dendrimer-Nd(III) complex)(MPhenyl ethyne, (3,5) -ether-bridged dendrimer-Nd (III) complex, (M, 3,5) -ether-bridged dendrimer-Nd (III) complex 1One =2H, M= 2H, M 2 2 =2H, Ln=Nd)= 2H, Ln = Nd)

Phenyl ethyne, (3,5)-ether-bridged dendrimer (M1=2H, M2=2H)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 55] Phenyl ethyne, (3,5) -ether-bridged dendrimer (M 1 = 2H, M 2 = 2H) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 55

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 370 :Example 370:

Phenyl ethyne, (3,5)-ether-bridged dendrimer-Er(III) complex Phenyl ethyne, (3,5) -ether-bridged dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Phenyl ethyne, (3,5)-ether-bridged dendrimer (M1=2H, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 55] Phenyl ethyne, (3,5) -ether-bridged dendrimer (M 1 = 2H, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 55

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 371 :Example 371:

Phenyl ethyne, (3,5)-ether-bridged dendrimer-Yb(III) complex Phenyl ethyne, (3,5) -ether-bridged dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Phenyl ethyne, (3,5)-ether-bridged dendrimer (M1=2H, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 55] Phenyl ethyne, (3,5) -ether-bridged dendrimer (M 1 = 2H, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 55

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 372 :Example 372:

Phenyl ethyne, (3,5)-ether-bridged dendrimer-Nd(III) complex Phenyl ethyne, (3,5) -ether-bridged dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Phenyl ethyne, (3,5)-ether-bridged dendrimer (M1=2H, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 55] Phenyl ethyne, (3,5) -ether-bridged dendrimer (M 1 = 2H, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 55

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 373 :Example 373:

Phenyl ethyne, (3,5)-ether-bridged dendrimer-Er(III) complex Phenyl ethyne, (3,5) -ether-bridged dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Phenyl ethyne, (3,5)-ether-bridged dendrimer (M1=2H, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 55] Phenyl ethyne, (3,5) -ether-bridged dendrimer (M 1 = 2H, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 55

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 374 :Example 374:

Phenyl ethyne, (3,5)-ether-bridged dendrimer-Yb(III) complex Phenyl ethyne, (3,5) -ether-bridged dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Phenyl ethyne, (3,5)-ether-bridged dendrimer (M1=2H, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 55] Phenyl ethyne, (3,5) -ether-bridged dendrimer (M 1 = 2H, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 55

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 375 :Example 375:

Phenyl ethyne, (3,5)-ether-bridged dendrimer-Nd(III) complex Phenyl ethyne, (3,5) -ether-bridged dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Phenyl ethyne, (3,5)-ether-bridged dendrimer (M1=2H, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 55] Phenyl ethyne, (3,5) -ether-bridged dendrimer (M 1 = 2H, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 55

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 376 :Example 376:

Phenyl ethyne, (3,5)-ether-bridged dendrimer-Er(III) complex Phenyl ethyne, (3,5) -ether-bridged dendrimer-Er (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Phenyl ethyne, (3,5)-ether-bridged dendrimer (M1=Zn, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 55] Phenyl ethyne, (3,5) -ether-bridged dendrimer (M 1 = Zn, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 55

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 377 :Example 377:

Phenyl ethyne, (3,5)-ether-bridged dendrimer-Yb(III) complex Phenyl ethyne, (3,5) -ether-bridged dendrimer-Yb (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Phenyl ethyne, (3,5)-ether-bridged dendrimer (M1=Zn, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 55] Phenyl ethyne, (3,5) -ether-bridged dendrimer (M 1 = Zn, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 55

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 378 :Example 378:

Phenyl ethyne, (3,5)-ether-bridged dendrimer-Nd(III) complex Phenyl ethyne, (3,5) -ether-bridged dendrimer-Nd (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Phenyl ethyne, (3,5)-ether-bridged dendrimer (M1=Zn, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 55] Phenyl ethyne, (3,5) -ether-bridged dendrimer (M 1 = Zn, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 55

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 379 :Example 379:

Phenyl ethyne, (3,5)-ether-bridged dendrimer-Er(III) complex Phenyl ethyne, (3,5) -ether-bridged dendrimer-Er (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Phenyl ethyne, (3,5)-ether-bridged dendrimer (M1=Zn, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 55] Phenyl ethyne, (3,5) -ether-bridged dendrimer (M 1 = Zn, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 55

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 380 :Example 380:

Phenyl ethyne, (3,5)-ether-bridged dendrimer-Yb(III) complex Phenyl ethyne, (3,5) -ether-bridged dendrimer-Yb (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Phenyl ethyne, (3,5)-ether-bridged dendrimer (M1=Zn, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 55] Phenyl ethyne, (3,5) -ether-bridged dendrimer (M 1 = Zn, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 55

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 381 :Example 381:

Phenyl ethyne, (3,5)-ether-bridged dendrimer-Nd(III) complex Phenyl ethyne, (3,5) -ether-bridged dendrimer-Nd (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Phenyl ethyne, (3,5)-ether-bridged dendrimer (M1=Zn, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 55] Phenyl ethyne, (3,5) -ether-bridged dendrimer (M 1 = Zn, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 55

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 382 :Example 382:

Phenyl ethyne, (3,5)-ether-bridged dendrimer-Er(III) complex Phenyl ethyne, (3,5) -ether-bridged dendrimer-Er (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Phenyl ethyne, (3,5)-ether-bridged dendrimer (M1=Pt, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 55] Phenyl ethyne, (3,5) -ether-bridged dendrimer (M 1 = Pt, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 55

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 383 :Example 383:

Phenyl ethyne, (3,5)-ether-bridged dendrimer-Yb(III) complex Phenyl ethyne, (3,5) -ether-bridged dendrimer-Yb (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Phenyl ethyne, (3,5)-ether-bridged dendrimer (M1=Pt, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 55] Phenyl ethyne, (3,5) -ether-bridged dendrimer (M 1 = Pt, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 55

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 384 :Example 384:

Phenyl ethyne, (3,5)-ether-bridged dendrimer-Nd(III) complex Phenyl ethyne, (3,5) -ether-bridged dendrimer-Nd (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Phenyl ethyne, (3,5)-ether-bridged dendrimer (M1=Pt, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 55] Phenyl ethyne, (3,5) -ether-bridged dendrimer (M 1 = Pt, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 55

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 385 :Example 385:

Phenyl ethyne, (3,5)-ether-bridged dendrimer-Er(III) complex Phenyl ethyne, (3,5) -ether-bridged dendrimer-Er (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Phenyl ethyne, (3,5)-ether-bridged dendrimer (M1=Pt, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 55] Phenyl ethyne, (3,5) -ether-bridged dendrimer (M 1 = Pt, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 55

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 386 :Example 386:

Phenyl ethyne, (3,5)-ether-bridged dendrimer-Yb(III) complex Phenyl ethyne, (3,5) -ether-bridged dendrimer-Yb (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Phenyl ethyne, (3,5)-ether-bridged dendrimer (M1=Pt, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 55] Phenyl ethyne, (3,5) -ether-bridged dendrimer (M 1 = Pt, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 55

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 387 :Example 387:

Phenyl ethyne, (3,5)-ether-bridged dendrimer-Nd(III) complex Phenyl ethyne, (3,5) -ether-bridged dendrimer-Nd (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Phenyl ethyne, (3,5)-ether-bridged dendrimer (M1=Pt, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 55] Phenyl ethyne, (3,5) -ether-bridged dendrimer (M 1 = Pt, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 55

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 388 :Example 388:

메시틸 에타인, (3,5)-에테르-브릿지드 덴드리머-Er(III) 착물(Mesityl ethyne, (3,5)-ether-bridged dendrimer-Er(III) complex) (MMesityl ethyne, (3,5) -ether-bridged dendrimer-Er (III) complex (M, 3,5) -ether-bridged dendrimer-Er (III) complex 1One =2H, M= 2H, M 2 2 =2H, Ln=Er)= 2H, Ln = Er)

Mesityl ethyne, (3,5)-ether-bridged dendrimer (M1=2H, M2=2H)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 56] Mesityl ethyne, (3,5) -ether-bridged dendrimer (M 1 = 2H, M 2 = 2H) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 56

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 389 :Example 389:

메시틸 에타인, (3,5)-에테르-브릿지드 덴드리머-Yb(III) 착물(Mesityl ethyne, (3,5)-ether-bridged dendrimer-Yb(III) complex)(MMesityl ethyne, (3,5) -ether-bridged dendrimer-Yb (III) complex (M, 3,5) -ether-bridged dendrimer-Yb (III) complex 1One =2H, M= 2H, M 2 2 =2H, Ln=Yb)= 2H, Ln = Yb)

Mesityl ethyne, (3,5)-ether-bridged dendrimer (M1=2H, M2=2H)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 56] Mesityl ethyne, (3,5) -ether-bridged dendrimer (M 1 = 2H, M 2 = 2H) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 56

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 390 :Example 390:

메시틸 에타인, (3,5)-에테르-브릿지드 덴드리머-Nd(III) 착물(Mesityl ethyne, (3,5)-ether-bridged dendrimer-Nd(III) complex)(MMesityl ethyne, (3,5) -ether-bridged dendrimer-Nd (III) complex (M, 5) -ether-bridged dendrimer-Nd (III) complex 1One =2H, M= 2H, M 2 2 =2H, Ln=Nd)= 2H, Ln = Nd)

Mesityl ethyne, (3,5)-ether-bridged dendrimer (M1=2H, M2=2H)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 56] Mesityl ethyne, (3,5) -ether-bridged dendrimer (M 1 = 2H, M 2 = 2H) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 56

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 391 :Example 391:

Mesityl ethyne, (3,5)-ether-bridged dendrimer-Er(III) complex Mesityl ethyne, (3,5) -ether-bridged dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Mesityl ethyne, (3,5)-ether-bridged dendrimer (M1=2H, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 56] Mesityl ethyne, (3,5) -ether-bridged dendrimer (M 1 = 2H, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 56

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 392 :Example 392:

Mesityl ethyne, (3,5)-ether-bridged dendrimer-Yb(III) complex Mesityl ethyne, (3,5) -ether-bridged dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Mesityl ethyne, (3,5)-ether-bridged dendrimer (M1=2H, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 56] Mesityl ethyne, (3,5) -ether-bridged dendrimer (M 1 = 2H, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 56

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 393 :Example 393:

Mesityl ethyne, (3,5)-ether-bridged dendrimer-Nd(III) complex Mesityl ethyne, (3,5) -ether-bridged dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Mesityl ethyne, (3,5)-ether-bridged dendrimer (M1=2H, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 56] Mesityl ethyne, (3,5) -ether-bridged dendrimer (M 1 = 2H, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 56

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 394 :Example 394:

Mesityl ethyne, (3,5)-ether-bridged dendrimer-Er(III) complex Mesityl ethyne, (3,5) -ether-bridged dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Mesityl ethyne, (3,5)-ether-bridged dendrimer (M1=2H, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 56] Mesityl ethyne, (3,5) -ether-bridged dendrimer (M 1 = 2H, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 56

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 395 :Example 395:

Mesityl ethyne, (3,5)-ether-bridged dendrimer-Yb(III) complex Mesityl ethyne, (3,5) -ether-bridged dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Mesityl ethyne, (3,5)-ether-bridged dendrimer (M1=2H, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 56] Mesityl ethyne, (3,5) -ether-bridged dendrimer (M 1 = 2H, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 56

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 396 :Example 396:

Mesityl ethyne, (3,5)-ether-bridged dendrimer-Nd(III) complex Mesityl ethyne, (3,5) -ether-bridged dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Mesityl ethyne, (3,5)-ether-bridged dendrimer (M1=2H, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 56] Mesityl ethyne, (3,5) -ether-bridged dendrimer (M 1 = 2H, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 56

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 397 :Example 397:

Mesityl ethyne, (3,5)-ether-bridged dendrimer-Er(III) complex Mesityl ethyne, (3,5) -ether-bridged dendrimer-Er (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Mesityl ethyne, (3,5)-ether-bridged dendrimer (M1=Zn, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 56] Mesityl ethyne, (3,5) -ether-bridged dendrimer (M 1 = Zn, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 56

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 398 :Example 398:

Mesityl ethyne, (3,5)-ether-bridged dendrimer-Yb(III) complex Mesityl ethyne, (3,5) -ether-bridged dendrimer-Yb (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Mesityl ethyne, (3,5)-ether-bridged dendrimer (M1=Zn, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 56] Mesityl ethyne, (3,5) -ether-bridged dendrimer (M 1 = Zn, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 56

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 399 :Example 399:

Mesityl ethyne, (3,5)-ether-bridged dendrimer-Nd(III) complex Mesityl ethyne, (3,5) -ether-bridged dendrimer-Nd (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Mesityl ethyne, (3,5)-ether-bridged dendrimer (M1=Zn, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 56] Mesityl ethyne, (3,5) -ether-bridged dendrimer (M 1 = Zn, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 56

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 400 :Example 400:

Mesityl ethyne, (3,5)-ether-bridged dendrimer-Er(III) complex Mesityl ethyne, (3,5) -ether-bridged dendrimer-Er (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Mesityl ethyne, (3,5)-ether-bridged dendrimer (M1=Zn, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 56] Mesityl ethyne, (3,5) -ether-bridged dendrimer (M 1 = Zn, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 56

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 401 :Example 401:

Mesityl ethyne, (3,5)-ether-bridged dendrimer-Yb(III) complex Mesityl ethyne, (3,5) -ether-bridged dendrimer-Yb (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Mesityl ethyne, (3,5)-ether-bridged dendrimer (M1=Zn, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 56] Mesityl ethyne, (3,5) -ether-bridged dendrimer (M 1 = Zn, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 56

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 402 :Example 402:

Mesityl ethyne, (3,5)-ether-bridged dendrimer-Nd(III) complex Mesityl ethyne, (3,5) -ether-bridged dendrimer-Nd (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Mesityl ethyne, (3,5)-ether-bridged dendrimer (M1=Zn, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 56] Mesityl ethyne, (3,5) -ether-bridged dendrimer (M 1 = Zn, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 56

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 403 :Example 403:

Mesityl ethyne, (3,5)-ether-bridged dendrimer-Er(III) complex Mesityl ethyne, (3,5) -ether-bridged dendrimer-Er (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Mesityl ethyne, (3,5)-ether-bridged dendrimer (M1=Pt, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 56] Mesityl ethyne, (3,5) -ether-bridged dendrimer (M 1 = Pt, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 56

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 404 :Example 404:

Mesityl ethyne, (3,5)-ether-bridged dendrimer-Yb(III) complex Mesityl ethyne, (3,5) -ether-bridged dendrimer-Yb (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Mesityl ethyne, (3,5)-ether-bridged dendrimer (M1=Pt, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 56] Mesityl ethyne, (3,5) -ether-bridged dendrimer (M 1 = Pt, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 56

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 405 :Example 405:

Mesityl ethyne, (3,5)-ether-bridged dendrimer-Nd(III) complex Mesityl ethyne, (3,5) -ether-bridged dendrimer-Nd (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Mesityl ethyne, (3,5)-ether-bridged dendrimer (M1=Pt, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 56] Mesityl ethyne, (3,5) -ether-bridged dendrimer (M 1 = Pt, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 56

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 406 :Example 406:

Mesityl ethyne, (3,5)-ether-bridged dendrimer-Er(III) complex Mesityl ethyne, (3,5) -ether-bridged dendrimer-Er (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Mesityl ethyne, (3,5)-ether-bridged dendrimer (M1=Pt, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 56] Mesityl ethyne, (3,5) -ether-bridged dendrimer (M 1 = Pt, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 56

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 407 :Example 407:

Mesityl ethyne, (3,5)-ether-bridged dendrimer-Yb(III) complex Mesityl ethyne, (3,5) -ether-bridged dendrimer-Yb (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Mesityl ethyne, (3,5)-ether-bridged dendrimer (M1=Pt, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 56] Mesityl ethyne, (3,5) -ether-bridged dendrimer (M 1 = Pt, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 56

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 408 :Example 408:

Mesityl ethyne, (3,5)-ether-bridged dendrimer-Nd(III) complex Mesityl ethyne, (3,5) -ether-bridged dendrimer-Nd (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Mesityl ethyne, (3,5)-ether-bridged dendrimer (M1=Pt, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 56] Mesityl ethyne, (3,5) -ether-bridged dendrimer (M 1 = Pt, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 56

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 409 :Example 409:

페닐 Ar-Ar, C-C 직접링크된 덴드리머-Er(III) 착물(Phenyl Ar-Ar, C-C direct linked dendrimer-Er(III) complex)(MPhenyl Ar-Ar, C-C direct linked dendrimer-Er (III) complex (M) 1One =2H, M= 2H, M 22 =2H, Ln=Er)= 2H, Ln = Er)

Phenyl Ar-Ar, C-C direct linked dendrimer (M1=2H, M2=2H)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 57] Phenyl Ar-Ar, CC direct linked dendrimer (M 1 = 2H, M 2 = 2H) and erbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 57

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 410 :Example 410:

페닐 Ar-Ar, C-C 직접링크된 덴드리머-Yb(III) 착물(Phenyl Ar-Ar, C-C direct linked dendrimer-Yb(III) complex)(MPhenyl Ar-Ar, C-C direct linked dendrimer-Yb (III) complex (M) 1One =2H, M= 2H, M 22 =2H, Ln=Yb)= 2H, Ln = Yb)

Phenyl Ar-Ar, C-C direct linked dendrimer (M1=2H, M2=2H)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 57] Phenyl Ar-Ar, CC direct linked dendrimer (M 1 = 2H, M 2 = 2H) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 57

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 411 :Example 411:

페닐 Ar-Ar, C-C 직접링크된 덴드리머-Nd(III) 착물(Phenyl Ar-Ar, C-C direct linked dendrimer-Nd(III) complex)(MPhenyl Ar-Ar, C-C direct linked dendrimer-Nd (III) complex (M) 1One =2H, M= 2H, M 22 =2H, Ln=Nd)= 2H, Ln = Nd)

Phenyl Ar-Ar, C-C direct linked dendrimer (M1=2H, M2=2H)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 57] Phenyl Ar-Ar, CC direct linked dendrimer (M 1 = 2H, M 2 = 2H) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 57

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 412 :Example 412:

Phenyl Ar-Ar, C-C direct linked dendrimer-Er(III) complex Phenyl Ar-Ar, C-C direct linked dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Phenyl Ar-Ar, C-C direct linked dendrimer (M1=2H, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 57] Phenyl Ar-Ar, CC direct linked dendrimer (M 1 = 2H, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 57

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 413 :Example 413:

Phenyl Ar-Ar, C-C direct linked dendrimer-Yb(III) complex Phenyl Ar-Ar, C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Phenyl Ar-Ar, C-C direct linked dendrimer (M1=2H, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 57] Phenyl Ar-Ar, CC direct linked dendrimer (M 1 = 2H, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 57

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 414 :Example 414:

Phenyl Ar-Ar, C-C direct linked dendrimer-Nd(III) complex Phenyl Ar-Ar, C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Phenyl Ar-Ar, C-C direct linked dendrimer (M1=2H, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 57] Phenyl Ar-Ar, CC direct linked dendrimer (M 1 = 2H, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 57

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 415 :Example 415:

Phenyl Ar-Ar, C-C direct linked dendrimer-Er(III) complex Phenyl Ar-Ar, C-C direct linked dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Phenyl Ar-Ar, C-C direct linked dendrimer (M1=2H, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 57] Phenyl Ar-Ar, CC direct linked dendrimer (M 1 = 2H, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 57

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 416 :Example 416:

Phenyl Ar-Ar, C-C direct linked dendrimer-Yb(III) complex Phenyl Ar-Ar, C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Phenyl Ar-Ar, C-C direct linked dendrimer (M1=2H, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 57] Phenyl Ar-Ar, CC direct linked dendrimer (M 1 = 2H, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 57

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 417 :Example 417:

Phenyl Ar-Ar, C-C direct linked dendrimer-Nd(III) complex Phenyl Ar-Ar, C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Phenyl Ar-Ar, C-C direct linked dendrimer (M1=2H, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 57] Synthesis of Ln-complex using Phenyl Ar-Ar, CC direct linked dendrimer (M 1 = 2H, M 2 = Pt) and neodymium chloride hexahydrate. Scheme 57

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 418 :Example 418:

Phenyl Ar-Ar, C-C direct linked dendrimer-Er(III) complex Phenyl Ar-Ar, C-C direct linked dendrimer-Er (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Phenyl Ar-Ar, C-C direct linked dendrimer (M1=Zn, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 57] Phenyl Ar-Ar, CC direct linked dendrimer (M 1 = Zn, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 57

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 419 :Example 419:

Phenyl Ar-Ar, C-C direct linked dendrimer-Yb(III) complex Phenyl Ar-Ar, C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Phenyl Ar-Ar, C-C direct linked dendrimer (M1=Zn, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 57] Phenyl Ar-Ar, CC direct linked dendrimer (M 1 = Zn, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 57

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 420 :Example 420:

Phenyl Ar-Ar, C-C direct linked dendrimer-Nd(III) complex Phenyl Ar-Ar, C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Phenyl Ar-Ar, C-C direct linked dendrimer (M1=Zn, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 57] Phenyl Ar-Ar, CC direct linked dendrimer (M 1 = Zn, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 57

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 421 :Example 421:

Phenyl Ar-Ar, C-C direct linked dendrimer-Er(III) complex Phenyl Ar-Ar, C-C direct linked dendrimer-Er (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Phenyl Ar-Ar, C-C direct linked dendrimer (M1=Zn, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 57] Phenyl Ar-Ar, CC direct linked dendrimer (M 1 = Zn, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 57

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 422 :Example 422:

Phenyl Ar-Ar, C-C direct linked dendrimer-Yb(III) complex Phenyl Ar-Ar, C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Phenyl Ar-Ar, C-C direct linked dendrimer (M1=Zn, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 57] Phenyl Ar-Ar, CC direct linked dendrimer (M 1 = Zn, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 57

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 423 :Example 423:

Phenyl Ar-Ar, C-C direct linked dendrimer-Nd(III) complex Phenyl Ar-Ar, C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Phenyl Ar-Ar, C-C direct linked dendrimer (M1=Zn, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 57] Phenyl Ar-Ar, CC direct linked dendrimer (M 1 = Zn, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 57

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 424 :Example 424:

Phenyl Ar-Ar, C-C direct linked dendrimer-Er(III) complex Phenyl Ar-Ar, C-C direct linked dendrimer-Er (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Phenyl Ar-Ar, C-C direct linked dendrimer (M1=Pt, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 57] Phenyl Ar-Ar, CC direct linked dendrimer (M 1 = Pt, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 57

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 425 :Example 425:

Phenyl Ar-Ar, C-C direct linked dendrimer-Yb(III) complex Phenyl Ar-Ar, C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Phenyl Ar-Ar, C-C direct linked dendrimer (M1=Pt, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 57] Phenyl Ar-Ar, CC direct linked dendrimer (M 1 = Pt, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 57

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 426 :Example 426:

Phenyl Ar-Ar, C-C direct linked dendrimer-Nd(III) complex Phenyl Ar-Ar, C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Phenyl Ar-Ar, C-C direct linked dendrimer (M1=Pt, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 57] Phenyl Ar-Ar, CC direct linked dendrimer (M 1 = Pt, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 57

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 427 :Example 427:

Phenyl Ar-Ar, C-C direct linked dendrimer-Er(III) complex Phenyl Ar-Ar, C-C direct linked dendrimer-Er (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Phenyl Ar-Ar, C-C direct linked dendrimer (M1=Pt, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 57] Phenyl Ar-Ar, CC direct linked dendrimer (M 1 = Pt, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 57

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 428 :Example 428:

Phenyl Ar-Ar, C-C direct linked dendrimer-Yb(III) complex Phenyl Ar-Ar, C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Phenyl Ar-Ar, C-C direct linked dendrimer (M1=Pt, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 57] Phenyl Ar-Ar, CC direct linked dendrimer (M 1 = Pt, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 57

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 429 :Example 429:

Phenyl Ar-Ar, C-C direct linked dendrimer-Nd(III) complex Phenyl Ar-Ar, C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Phenyl Ar-Ar, C-C direct linked dendrimer (M1=Pt, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 57] Phenyl Ar-Ar, CC direct linked dendrimer (M 1 = Pt, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 57

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 430 :Example 430:

메시틸 Ar-Ar, C-C 직접링크된 덴드리머-Er(III) 착물(Mesityl Ar-Ar, C-C direct linked dendrimer-Er(III) complex)(MMesityl Ar-Ar, C-C direct linked dendrimer-Er (III) complex (M) 1One =2H, M= 2H, M 22 =2H, Ln=Er)= 2H, Ln = Er)

Mesityl Ar-Ar, C-C direct linked dendrimer (M1=2H, M2=2H)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 58] Mesityl Ar-Ar, CC direct linked dendrimer (M 1 = 2H, M 2 = 2H) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 58

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 431 :Example 431

메시틸 Ar-Ar, C-C 직접링크된 덴드리머-Yb(III) 착물(Mesityl Ar-Ar, C-C direct linked dendrimer-Yb(III) complex)(MMesityl Ar-Ar, C-C direct linked dendrimer-Yb (III) complex (M) 1One =2H, M= 2H, M 22 =2H, Ln=Yb)= 2H, Ln = Yb)

Mesityl Ar-Ar, C-C direct linked dendrimer (M1=2H, M2=2H)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 58] Mesityl Ar-Ar, CC direct linked dendrimer (M 1 = 2H, M 2 = 2H) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 58

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 432 :Example 432:

메시틸 Ar-Ar, C-C 직접링크된 덴드리머-Nd(III) 착물(Mesityl Ar-Ar, C-C direct linked dendrimer-Nd(III) complex)(MMesityl Ar-Ar, C-C direct linked dendrimer-Nd (III) complex (M) 1One =2H, M= 2H, M 22 =2H, Ln=Nd)= 2H, Ln = Nd)

Mesityl Ar-Ar, C-C direct linked dendrimer (M1=2H, M2=2H)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 58] Mesityl Ar-Ar, CC direct linked dendrimer (M 1 = 2H, M 2 = 2H) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 58

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 433 :Example 433:

Mesityl Ar-Ar, C-C direct linked dendrimer-Er(III) complex Mesityl Ar-Ar, C-C direct linked dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Mesityl Ar-Ar, C-C direct linked dendrimer (M1=2H, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 58] Mesityl Ar-Ar, CC direct linked dendrimer (M 1 = 2H, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 58

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 434 :Example 434:

Mesityl Ar-Ar, C-C direct linked dendrimer-Yb(III) complex Mesityl Ar-Ar, C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Mesityl Ar-Ar, C-C direct linked dendrimer (M1=2H, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 58] Mesityl Ar-Ar, CC direct linked dendrimer (M 1 = 2H, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 58

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 435 :Example 435:

Mesityl Ar-Ar, C-C direct linked dendrimer-Nd(III) complex Mesityl Ar-Ar, C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Mesityl Ar-Ar, C-C direct linked dendrimer (M1=2H, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 58] Mesityl Ar-Ar, CC direct linked dendrimer (M 1 = 2H, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 58

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 436 :Example 436:

Mesityl Ar-Ar, C-C direct linked dendrimer-Er(III) complex Mesityl Ar-Ar, C-C direct linked dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Mesityl Ar-Ar, C-C direct linked dendrimer (M1=2H, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 58] Mesityl Ar-Ar, CC direct linked dendrimer (M 1 = 2H, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 58

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 437 :Example 437:

Mesityl Ar-Ar, C-C direct linked dendrimer-Yb(III) complex Mesityl Ar-Ar, C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Mesityl Ar-Ar, C-C direct linked dendrimer (M1=2H, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 58] Mesityl Ar-Ar, CC direct linked dendrimer (M 1 = 2H, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 58

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 438 :Example 438:

Mesityl Ar-Ar, C-C direct linked dendrimer-Nd(III) complex Mesityl Ar-Ar, C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Mesityl Ar-Ar, C-C direct linked dendrimer (M1=2H, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 58] Mesityl Ar-Ar, CC direct linked dendrimer (M 1 = 2H, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 58

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 439 :Example 439:

Mesityl Ar-Ar, C-C direct linked dendrimer-Er(III) complex Mesityl Ar-Ar, C-C direct linked dendrimer-Er (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Mesityl Ar-Ar, C-C direct linked dendrimer (M1=Zn, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 58] Mesityl Ar-Ar, CC direct linked dendrimers (M 1 = Zn, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 58

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 440 :Example 440:

Mesityl Ar-Ar, C-C direct linked dendrimer-Yb(III) complex Mesityl Ar-Ar, C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Mesityl Ar-Ar, C-C direct linked dendrimer (M1=Zn, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 58] Mesityl Ar-Ar, CC direct linked dendrimers (M 1 = Zn, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 58

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 441 :Example 441:

Mesityl Ar-Ar, C-C direct linked dendrimer-Nd(III) complex Mesityl Ar-Ar, C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Mesityl Ar-Ar, C-C direct linked dendrimer (M1=Zn, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 58] Mesityl Ar-Ar, CC direct linked dendrimers (M 1 = Zn, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 58

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 442 :Example 442:

Mesityl Ar-Ar, C-C direct linked dendrimer-Er(III) complex Mesityl Ar-Ar, C-C direct linked dendrimer-Er (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Mesityl Ar-Ar, C-C direct linked dendrimer (M1=Zn, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 58] Mesityl Ar-Ar, CC direct linked dendrimer (M 1 = Zn, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 58

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 443 :Example 443:

Mesityl Ar-Ar, C-C direct linked dendrimer-Yb(III) complex Mesityl Ar-Ar, C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Mesityl Ar-Ar, C-C direct linked dendrimer (M1=Zn, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 58] Mesityl Ar-Ar, CC direct linked dendrimer (M 1 = Zn, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 58

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 444 :Example 444:

Mesityl Ar-Ar, C-C direct linked dendrimer-Nd(III) complex Mesityl Ar-Ar, C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Mesityl Ar-Ar, C-C direct linked dendrimer (M1=Zn, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 58] Mesityl Ar-Ar, CC direct linked dendrimer (M 1 = Zn, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 58

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 445 :Example 445:

Mesityl Ar-Ar, C-C direct linked dendrimer-Er(III) complex Mesityl Ar-Ar, C-C direct linked dendrimer-Er (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Mesityl Ar-Ar, C-C direct linked dendrimer (M1=Pt, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 58] Mesityl Ar-Ar, CC direct linked dendrimers (M 1 = Pt, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 58

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 446 :Example 446:

Mesityl Ar-Ar, C-C direct linked dendrimer-Yb(III) complex Mesityl Ar-Ar, C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Mesityl Ar-Ar, C-C direct linked dendrimer (M1=Pt, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 58] Mesityl Ar-Ar, CC direct linked dendrimer (M 1 = Pt, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 58

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 447 :Example 447:

Mesityl Ar-Ar, C-C direct linked dendrimer-Nd(III) complex Mesityl Ar-Ar, C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Mesityl Ar-Ar, C-C direct linked dendrimer (M1=Pt, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 58] Mesityl Ar-Ar, CC direct linked dendrimer (M 1 = Pt, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 58

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 448 :Example 448:

Mesityl Ar-Ar, C-C direct linked dendrimer-Er(III) complex Mesityl Ar-Ar, C-C direct linked dendrimer-Er (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Mesityl Ar-Ar, C-C direct linked dendrimer (M1=Pt, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 58] Mesityl Ar-Ar, CC direct linked dendrimers (M 1 = Pt, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 58

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 449 :Example 449:

Mesityl Ar-Ar, C-C direct linked dendrimer-Yb(III) complex Mesityl Ar-Ar, C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Mesityl Ar-Ar, C-C direct linked dendrimer (M1=Pt, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 58] Mesityl Ar-Ar, CC direct linked dendrimer (M 1 = Pt, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 58

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 450 :Example 450:

Mesityl Ar-Ar, C-C direct linked dendrimer-Nd(III) complex Mesityl Ar-Ar, C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Mesityl Ar-Ar, C-C direct linked dendrimer (M1=Pt, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 58] Mesityl Ar-Ar, CC direct linked dendrimer (M 1 = Pt, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 58

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 451 :Example 451:

페닐 Ar-Ar,(3,5)-C-C 직접링크된 덴드리머-Er(III)착물(Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer-Er(III)complex)(MPhenyl Ar-Ar, (3,5) -C-C direct linked dendrimer-Er (III) complex) (M 1One =2H, M= 2H, M 22 =2H, Ln=Er)= 2H, Ln = Er)

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=2H, M2=2H)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 59] Phenyl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = 2H, M 2 = 2H) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 59

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 452 :Example 452:

페닐 Ar-Ar,(3,5)-C-C 직접링크된 덴드리머-Yb(III)착물(Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer-Yb(III)complex)(MPhenyl Ar-Ar, (3,5) -C-C direct linked dendrimer-Yb (III) complex) (M 1One =2H,M= 2H, M 22 =2H, Ln=Yb)= 2H, Ln = Yb)

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=2H, M2=2H)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 59] Phenyl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = 2H, M 2 = 2H) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 59

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 453 :Example 453:

페닐 Ar-Ar,(3,5)-C-C 직접링크된 덴드리머-Nd(III)착물(Phenyl Ar-Ar, (3,5) -C-C direct linked dendrimer-Nd(III) complex)(MPhenyl Ar-Ar, (3,5) -C-C direct linked dendrimer-Nd (III) complex) (M 1One =2H, M= 2H, M 22 =2H, Ln=Nd)= 2H, Ln = Nd)

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=2H, M2=2H)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 59] Phenyl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = 2H, M 2 = 2H) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 59

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 454 :Example 454:

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer-Er(III) complex Phenyl Ar-Ar, (3,5) -C-C direct linked dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=2H, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 59] Phenyl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = 2H, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 59

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 455 :Example 455:

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer-Yb(III) complex Phenyl Ar-Ar, (3,5) -C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=2H, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 59] Phenyl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = 2H, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 59

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 456 :Example 456:

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer-Nd(III) complex Phenyl Ar-Ar, (3,5) -C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=2H, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 59] Phenyl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = 2H, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 59

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 457 :Example 457:

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer-Er(III) complex Phenyl Ar-Ar, (3,5) -C-C direct linked dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=2H, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 59] Phenyl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = 2H, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 59

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 458 :Example 458:

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer-Yb(III) complex Phenyl Ar-Ar, (3,5) -C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=2H, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 59] Phenyl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = 2H, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 59

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 459 :Example 459:

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer-Nd(III) complex Phenyl Ar-Ar, (3,5) -C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=2H, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 59] Phenyl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = 2H, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 59

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 460 :Example 460:

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer-Er(III) complex Phenyl Ar-Ar, (3,5) -C-C direct linked dendrimer-Er (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=Zn, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 59] Phenyl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = Zn, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 59

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 461 :Example 461:

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer-Yb(III) complex Phenyl Ar-Ar, (3,5) -C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=Zn, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 59] Phenyl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = Zn, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 59

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 462 :Example 462:

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer-Nd(III) complex Phenyl Ar-Ar, (3,5) -C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=Zn, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 59] Phenyl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = Zn, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 59

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 463 :Example 463:

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer-Er(III) complex Phenyl Ar-Ar, (3,5) -C-C direct linked dendrimer-Er (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=Zn, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 59] Phenyl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = Zn, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 59

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 464 :Example 464:

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer-Yb(III) complex Phenyl Ar-Ar, (3,5) -C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=Zn, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 59] Phenyl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = Zn, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 59

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 465 :Example 465:

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer-Nd(III) complex Phenyl Ar-Ar, (3,5) -C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=Zn, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 59] Phenyl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = Zn, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 59

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 466 :Example 466:

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer-Er(III) complex Phenyl Ar-Ar, (3,5) -C-C direct linked dendrimer-Er (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=Pt, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 59] Phenyl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = Pt, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 59

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 467 :Example 467:

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer-Yb(III) complex Phenyl Ar-Ar, (3,5) -C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=Pt, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 59] Phenyl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = Pt, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 59

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 468 :Example 468:

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer-Nd(III) complex Phenyl Ar-Ar, (3,5) -C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=Pt, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 59] Phenyl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = Pt, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 59

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 469 :Example 469:

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer-Er(III) complex Phenyl Ar-Ar, (3,5) -C-C direct linked dendrimer-Er (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=Pt, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 59] Phenyl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = Pt, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 59

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 470 :Example 470:

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer-Yb(III) complex Phenyl Ar-Ar, (3,5) -C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=Pt, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 59] Phenyl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = Pt, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 59

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 471 :Example 471:

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer-Nd(III) complex Phenyl Ar-Ar, (3,5) -C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Phenyl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=Pt, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 59] Phenyl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = Pt, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 59

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 472 :Example 472:

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer-Er(III) complex Mesityl Ar-Ar, (3,5) -C-C direct linked dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =2H, Ln=Er)= 2H, Ln = Er)

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=2H, M2=2H)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 60] Mesityl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = 2H, M 2 = 2H) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 60

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 473 :Example 473:

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer-Yb(III) complex Mesityl Ar-Ar, (3,5) -C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =2H, Ln=Yb)= 2H, Ln = Yb)

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=2H, M2=2H)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 60] Mesityl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = 2H, M 2 = 2H) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 60

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 474 :Example 474:

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer-Nd(III) complex Mesityl Ar-Ar, (3,5) -C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =2H, Ln=Nd)= 2H, Ln = Nd)

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=2H, M2=2H)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 60] Mesityl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = 2H, M 2 = 2H) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 60

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 475 :Example 475:

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer-Er(III) complex Mesityl Ar-Ar, (3,5) -C-C direct linked dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=2H, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 60] Mesityl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = 2H, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 60

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 476 :Example 476:

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer-Yb(III) complex Mesityl Ar-Ar, (3,5) -C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=2H, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 60] Mesityl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = 2H, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 60

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 477 :Example 477:

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer-Nd(III) complex Mesityl Ar-Ar, (3,5) -C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=2H, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 60] Mesityl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = 2H, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 60

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 478 :Example 478:

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer-Er(III) complex Mesityl Ar-Ar, (3,5) -C-C direct linked dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=2H, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 60] Mesityl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = 2H, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 60

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 479 :Example 479:

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer-Yb(III) complex Mesityl Ar-Ar, (3,5) -C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=2H, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 60] Mesityl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = 2H, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 60

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 480 :Example 480:

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer-Nd(III) complex Mesityl Ar-Ar, (3,5) -C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=2H, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 60] Mesityl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = 2H, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 60

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 481 :Example 481:

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer-Er(III) complex Mesityl Ar-Ar, (3,5) -C-C direct linked dendrimer-Er (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=Zn, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 60] Mesityl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = Zn, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 60

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 482 :Example 482:

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer-Yb(III) complex Mesityl Ar-Ar, (3,5) -C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=Zn, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 60] Mesityl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = Zn, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 60

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 483 :Example 483:

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer-Nd(III) complex Mesityl Ar-Ar, (3,5) -C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=Zn, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 60] Mesityl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = Zn, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 60

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 484 :Example 484:

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer-Er(III) complex Mesityl Ar-Ar, (3,5) -C-C direct linked dendrimer-Er (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=Zn, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 60] Mesityl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = Zn, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 60

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 485 :Example 485:

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer-Yb(III) complex Mesityl Ar-Ar, (3,5) -C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=Zn, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 60] Mesityl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = Zn, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 60

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 486 :Example 486:

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer-Nd(III) complex Mesityl Ar-Ar, (3,5) -C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=Zn, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 60] Mesityl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = Zn, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 60

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 487 :Example 487:

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer-Er(III) complex Mesityl Ar-Ar, (3,5) -C-C direct linked dendrimer-Er (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=Pt, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 60] Mesityl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = Pt, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 60

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 488 :Example 488:

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer-Yb(III) complex Mesityl Ar-Ar, (3,5) -C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=Pt, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 60] Mesityl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = Pt, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 60

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 489 :Example 489:

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer-Nd(III) complex Mesityl Ar-Ar, (3,5) -C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=Pt, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 60] Mesityl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = Pt, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 60

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 490 :Example 490:

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer-Er(III) complex Mesityl Ar-Ar, (3,5) -C-C direct linked dendrimer-Er (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=Pt, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 60] Mesityl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = Pt, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 60

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 491 :Example 491:

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer-Yb(III) complex Mesityl Ar-Ar, (3,5) -C-C direct linked dendrimer-Yb (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=Pt, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 60] Mesityl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = Pt, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 60

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 492 :Example 492:

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer-Nd(III) complex Mesityl Ar-Ar, (3,5) -C-C direct linked dendrimer-Nd (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Mesityl Ar-Ar, (3,5)-C-C direct linked dendrimer (M1=Pt, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 60] Mesityl Ar-Ar, (3,5) -CC direct linked dendrimer (M 1 = Pt, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 60

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 493 :Example 493:

Phenyl Ar-Ar, ether-bridged dendrimer-Er(III) complex Phenyl Ar-Ar, ether-bridged dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =2H, Ln=Er)= 2H, Ln = Er)

Phenyl Ar-Ar, ether-bridged dendrimer (M1=2H, M2=2H)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 61] Phenyl Ar-Ar, ether-bridged dendrimer (M 1 = 2H, M 2 = 2H) and erbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 61

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 494 :Example 494:

Phenyl Ar-Ar, ether-bridged dendrimer-Yb(III) complex Phenyl Ar-Ar, ether-bridged dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =2H, Ln=Yb)= 2H, Ln = Yb)

Phenyl Ar-Ar, ether-bridged dendrimer (M1=2H, M2=2H)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 61] Phenyl Ar-Ar, ether-bridged dendrimer (M 1 = 2H, M 2 = 2H) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 61

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 495 :Example 495:

Phenyl Ar-Ar, ether-bridged dendrimer-Nd(III) complex Phenyl Ar-Ar, ether-bridged dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =2H, Ln=Nd)= 2H, Ln = Nd)

Phenyl Ar-Ar, ether-bridged dendrimer (M1=2H, M2=2H)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 61] Phenyl Ar-Ar, ether-bridged dendrimer (M 1 = 2H, M 2 = 2H) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 61

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 496 :Example 496:

Phenyl Ar-Ar, ether-bridged dendrimer-Er(III) complex Phenyl Ar-Ar, ether-bridged dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Phenyl Ar-Ar, ether-bridged dendrimer (M1=2H, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 61] Phenyl Ar-Ar, ether-bridged dendrimer (M 1 = 2H, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 61

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 497 :Example 497:

Phenyl Ar-Ar, ether-bridged dendrimer-Yb(III) complex Phenyl Ar-Ar, ether-bridged dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Phenyl Ar-Ar, ether-bridged dendrimer (M1=2H, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 61] Phenyl Ar-Ar, ether-bridged dendrimer (M 1 = 2H, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 61

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 498 :Example 498:

Phenyl Ar-Ar, ether-bridged dendrimer-Nd(III) complex Phenyl Ar-Ar, ether-bridged dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Phenyl Ar-Ar, ether-bridged dendrimer (M1=2H, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 61] Phenyl Ar-Ar, ether-bridged dendrimer (M 1 = 2H, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 61

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 499 :Example 499:

Phenyl Ar-Ar, ether-bridged dendrimer-Er(III) complex Phenyl Ar-Ar, ether-bridged dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Phenyl Ar-Ar, ether-bridged dendrimer (M1=2H, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 61] Phenyl Ar-Ar, ether-bridged dendrimer (M 1 = 2H, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 61

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 500 :Example 500:

Phenyl Ar-Ar, ether-bridged dendrimer-Yb(III) complex Phenyl Ar-Ar, ether-bridged dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Phenyl Ar-Ar, ether-bridged dendrimer (M1=2H, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 61] Phenyl Ar-Ar, ether-bridged dendrimer (M 1 = 2H, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 61

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 501 :Example 501:

Phenyl Ar-Ar, ether-bridged dendrimer-Nd(III) complex Phenyl Ar-Ar, ether-bridged dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Phenyl Ar-Ar, ether-bridged dendrimer (M1=2H, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 61] Phenyl Ar-Ar, ether-bridged dendrimer (M 1 = 2H, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 61

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 502 :Example 502:

Phenyl Ar-Ar, ether-bridged dendrimer-Er(III) complex Phenyl Ar-Ar, ether-bridged dendrimer-Er (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Phenyl Ar-Ar, ether-bridged dendrimer (M1=Zn, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 61] Phenyl Ar-Ar, ether-bridged dendrimer (M 1 = Zn, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 61

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 503 :Example 503:

Phenyl Ar-Ar, ether-bridged dendrimer-Yb(III) complex Phenyl Ar-Ar, ether-bridged dendrimer-Yb (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Phenyl Ar-Ar, ether-bridged dendrimer (M1=Zn, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 61] Phenyl Ar-Ar, ether-bridged dendrimer (M 1 = Zn, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 61

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 504 :Example 504:

Phenyl Ar-Ar, ether-bridged dendrimer-Nd(III) complex Phenyl Ar-Ar, ether-bridged dendrimer-Nd (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Phenyl Ar-Ar, ether-bridged dendrimer (M1=Zn, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 61] Phenyl Ar-Ar, ether-bridged dendrimer (M 1 = Zn, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 61

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 505 :Example 505:

Phenyl Ar-Ar, ether-bridged dendrimer-Er(III) complex Phenyl Ar-Ar, ether-bridged dendrimer-Er (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Phenyl Ar-Ar, ether-bridged dendrimer (M1=Zn, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 61] Phenyl Ar-Ar, ether-bridged dendrimer (M 1 = Zn, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 61

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 506 :Example 506:

Phenyl Ar-Ar, ether-bridged dendrimer-Yb(III) complex Phenyl Ar-Ar, ether-bridged dendrimer-Yb (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Phenyl Ar-Ar, ether-bridged dendrimer (M1=Zn, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 61] Phenyl Ar-Ar, ether-bridged dendrimer (M 1 = Zn, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 61

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 507 :Example 507:

Phenyl Ar-Ar, ether-bridged dendrimer-Nd(III) complex Phenyl Ar-Ar, ether-bridged dendrimer-Nd (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Phenyl Ar-Ar, ether-bridged dendrimer (M1=Zn, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 61] Phenyl Ar-Ar, ether-bridged dendrimer (M 1 = Zn, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 61

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 508 :Example 508:

Phenyl Ar-Ar, ether-bridged dendrimer-Er(III) complex Phenyl Ar-Ar, ether-bridged dendrimer-Er (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Phenyl Ar-Ar, ether-bridged dendrimer (M1=Pt, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 61] Phenyl Ar-Ar, ether-bridged dendrimer (M 1 = Pt, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 61

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 509 :Example 509:

Phenyl Ar-Ar, ether-bridged dendrimer-Yb(III) complex Phenyl Ar-Ar, ether-bridged dendrimer-Yb (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Phenyl Ar-Ar, ether-bridged dendrimer (M1=Pt, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 61] Phenyl Ar-Ar, ether-bridged dendrimer (M 1 = Pt, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 61

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 510 :Example 510:

Phenyl Ar-Ar, ether-bridged dendrimer-Nd(III) complex Phenyl Ar-Ar, ether-bridged dendrimer-Nd (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Phenyl Ar-Ar, ether-bridged dendrimer (M1=Pt, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 61] Phenyl Ar-Ar, ether-bridged dendrimer (M 1 = Pt, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 61

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 511 :Example 511:

Phenyl Ar-Ar, ether-bridged dendrimer-Er(III) complex Phenyl Ar-Ar, ether-bridged dendrimer-Er (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Phenyl Ar-Ar, ether-bridged dendrimer (M1=Pt, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 61] Phenyl Ar-Ar, ether-bridged dendrimer (M 1 = Pt, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 61

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 512 :Example 512:

Phenyl Ar-Ar, ether-bridged dendrimer-Yb(III) complex Phenyl Ar-Ar, ether-bridged dendrimer-Yb (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Phenyl Ar-Ar, ether-bridged dendrimer (M1=Pt, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 61] Phenyl Ar-Ar, ether-bridged dendrimer (M 1 = Pt, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 61

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 513 :Example 513:

Phenyl Ar-Ar, ether-bridged dendrimer-Nd(III) complex Phenyl Ar-Ar, ether-bridged dendrimer-Nd (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Phenyl Ar-Ar, ether-bridged dendrimer (M1=Pt, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 61] Phenyl Ar-Ar, ether-bridged dendrimer (M 1 = Pt, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 61

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 514 :Example 514:

Mesityl Ar-Ar, ether-bridged dendrimer-Er(III) complex Mesityl Ar-Ar, ether-bridged dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =2H, Ln=Er)= 2H, Ln = Er)

Mesityl Ar-Ar, ether-bridged dendrimer (M1=2H, M2=2H)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 62] Mesityl Ar-Ar, ether-bridged dendrimer (M 1 = 2H, M 2 = 2H) and erbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 62

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 515 :Example 515:

Mesityl Ar-Ar, ether-bridged dendrimer-Yb(III) complex Mesityl Ar-Ar, ether-bridged dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =2H, Ln=Yb)= 2H, Ln = Yb)

Mesityl Ar-Ar, ether-bridged dendrimer (M1=2H, M2=2H)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 62] Mesityl Ar-Ar, ether-bridged dendrimer (M 1 = 2H, M 2 = 2H) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 62

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 516 :Example 516:

Mesityl Ar-Ar, ether-bridged dendrimer-Nd(III) complex Mesityl Ar-Ar, ether-bridged dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =2H, Ln=Nd)= 2H, Ln = Nd)

Mesityl Ar-Ar, ether-bridged dendrimer (M1=2H, M2=2H)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 62] Mesityl Ar-Ar, ether-bridged dendrimer (M 1 = 2H, M 2 = 2H) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 62

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 517 :Example 517:

Mesityl Ar-Ar, ether-bridged dendrimer-Er(III) complex Mesityl Ar-Ar, ether-bridged dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Mesityl Ar-Ar, ether-bridged dendrimer (M1=2H, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 62] Mesityl Ar-Ar, ether-bridged dendrimer (M 1 = 2H, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 62

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 518 :Example 518:

Mesityl Ar-Ar, ether-bridged dendrimer-Yb(III) complex Mesityl Ar-Ar, ether-bridged dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Mesityl Ar-Ar, ether-bridged dendrimer (M1=2H, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 62] Mesityl Ar-Ar, ether-bridged dendrimer (M 1 = 2H, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 62

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 519 :Example 519:

Mesityl Ar-Ar, ether-bridged dendrimer-Nd(III) complex Mesityl Ar-Ar, ether-bridged dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Mesityl Ar-Ar, ether-bridged dendrimer (M1=2H, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 62] Mesityl Ar-Ar, ether-bridged dendrimer (M 1 = 2H, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 62

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 520 :Example 520:

Mesityl Ar-Ar, ether-bridged dendrimer-Er(III) complex Mesityl Ar-Ar, ether-bridged dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Mesityl Ar-Ar, ether-bridged dendrimer (M1=2H, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 62] Mesityl Ar-Ar, ether-bridged dendrimer (M 1 = 2H, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 62

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 521 :Example 521:

Mesityl Ar-Ar, ether-bridged dendrimer-Yb(III) complex Mesityl Ar-Ar, ether-bridged dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Mesityl Ar-Ar, ether-bridged dendrimer (M1=2H, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 62] Mesityl Ar-Ar, ether-bridged dendrimer (M 1 = 2H, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 62

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 522 :Example 522:

Mesityl Ar-Ar, ether-bridged dendrimer-Nd(III) complex Mesityl Ar-Ar, ether-bridged dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Mesityl Ar-Ar, ether-bridged dendrimer (M1=2H, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 62] Mesityl Ar-Ar, ether-bridged dendrimer (M 1 = 2H, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 62

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 523 :Example 523:

Mesityl Ar-Ar, ether-bridged dendrimer-Er(III) complex Mesityl Ar-Ar, ether-bridged dendrimer-Er (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Mesityl Ar-Ar, ether-bridged dendrimer (M1=Zn, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 62] Mesityl Ar-Ar, ether-bridged dendrimer (M 1 = Zn, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 62

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 524 :Example 524:

Mesityl Ar-Ar, ether-bridged dendrimer-Yb(III) complex Mesityl Ar-Ar, ether-bridged dendrimer-Yb (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Mesityl Ar-Ar, ether-bridged dendrimer (M1=Zn, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 62] Mesityl Ar-Ar, ether-bridged dendrimer (M 1 = Zn, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 62

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 525 :Example 525:

Mesityl Ar-Ar, ether-bridged dendrimer-Nd(III) complex Mesityl Ar-Ar, ether-bridged dendrimer-Nd (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Mesityl Ar-Ar, ether-bridged dendrimer (M1=Zn, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 62] Mesityl Ar-Ar, ether-bridged dendrimer (M 1 = Zn, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 62

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 526 :Example 526:

Mesityl Ar-Ar, ether-bridged dendrimer-Er(III) complex Mesityl Ar-Ar, ether-bridged dendrimer-Er (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Mesityl Ar-Ar, ether-bridged dendrimer (M1=Zn, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 62] Mesityl Ar-Ar, ether-bridged dendrimer (M 1 = Zn, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 62

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 527 :Example 527:

Mesityl Ar-Ar, ether-bridged dendrimer-Yb(III) complex Mesityl Ar-Ar, ether-bridged dendrimer-Yb (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Mesityl Ar-Ar, ether-bridged dendrimer (M1=Zn, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 62] Mesityl Ar-Ar, ether-bridged dendrimer (M 1 = Zn, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 62

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 528 :Example 528:

Mesityl Ar-Ar, ether-bridged dendrimer-Nd(III) complex Mesityl Ar-Ar, ether-bridged dendrimer-Nd (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Mesityl Ar-Ar, ether-bridged dendrimer (M1=Zn, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 62] Mesityl Ar-Ar, ether-bridged dendrimer (M 1 = Zn, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 62

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 529 :Example 529:

Mesityl Ar-Ar, ether-bridged dendrimer-Er(III) complex Mesityl Ar-Ar, ether-bridged dendrimer-Er (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Mesityl Ar-Ar, ether-bridged dendrimer (M1=Pt, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 62] Mesityl Ar-Ar, ether-bridged dendrimer (M 1 = Pt, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 62

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 530 :Example 530:

Mesityl Ar-Ar, ether-bridged dendrimer-Yb(III) complex Mesityl Ar-Ar, ether-bridged dendrimer-Yb (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Mesityl Ar-Ar, ether-bridged dendrimer (M1=Pt, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 62] Mesityl Ar-Ar, ether-bridged dendrimer (M 1 = Pt, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 62

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 531 :Example 531:

Mesityl Ar-Ar, ether-bridged dendrimer-Nd(III) complex Mesityl Ar-Ar, ether-bridged dendrimer-Nd (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Mesityl Ar-Ar, ether-bridged dendrimer (M1=Pt, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 62] Mesityl Ar-Ar, ether-bridged dendrimer (M 1 = Pt, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 62

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 532 :Example 532:

Mesityl Ar-Ar, ether-bridged dendrimer-Er(III) complex Mesityl Ar-Ar, ether-bridged dendrimer-Er (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Mesityl Ar-Ar, ether-bridged dendrimer (M1=Pt, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 62] Mesityl Ar-Ar, ether-bridged dendrimer (M 1 = Pt, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 62

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 533 :Example 533:

Mesityl Ar-Ar, ether-bridged dendrimer-Yb(III) complex Mesityl Ar-Ar, ether-bridged dendrimer-Yb (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Mesityl Ar-Ar, ether-bridged dendrimer (M1=Pt, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 62] Mesityl Ar-Ar, ether-bridged dendrimer (M 1 = Pt, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 62

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 534 :Example 534:

Mesityl Ar-Ar, ether-bridged dendrimer-Nd(III) complex Mesityl Ar-Ar, ether-bridged dendrimer-Nd (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Mesityl Ar-Ar, ether-bridged dendrimer (M1=Pt, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 62] Mesityl Ar-Ar, ether-bridged dendrimer (M 1 = Pt, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex production method. Scheme 62

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 535 :Example 535:

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer-Er(III) complex Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =2H, Ln=Er)= 2H, Ln = Er)

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=2H, M2=2H)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 63] Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = 2H, M 2 = 2H) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 63

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 536 :Example 536:

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer-Yb(III) complex Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =2H, Ln=Yb)= 2H, Ln = Yb)

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=2H, M2=2H)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 63] Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = 2H, M 2 = 2H) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 63

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 537 :Example 537:

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer-Nd(III) complex Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =2H, Ln=Nd)= 2H, Ln = Nd)

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=2H, M2=2H)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 63] Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = 2H, M 2 = 2H) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 63

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 538 :Example 538:

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer-Er(III) complex Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=2H, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 63] Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = 2H, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 63

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 539 :Example 539:

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer-Yb(III) complex Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=2H, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 63] Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = 2H, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 63

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 540 :Example 540:

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer-Nd(III) complex Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=2H, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 63] Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = 2H, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 63

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 541 :Example 541:

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer-Er(III) complex Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=2H, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 63] Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = 2H, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 63

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 542 :Example 542:

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer-Yb(III) complex Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=2H, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 63] Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = 2H, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 63

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 543 :Example 543:

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer-Nd(III) complex Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=2H, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 63] Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = 2H, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 63

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 544 :Example 544:

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer-Er(III) complex Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer-Er (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=Zn, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 63] Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = Zn, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 63

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 545 :Example 545:

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer-Yb(III) complex Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer-Yb (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=Zn, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 63] Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = Zn, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 63

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 546 :Example 546:

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer-Nd(III) complex Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer-Nd (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=Zn, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 63] Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = Zn, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 63

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 547 :Example 547:

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer-Er(III) complex Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer-Er (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=Zn, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 63] Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = Zn, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 63

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 548 :Example 548:

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer-Yb(III) complex Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer-Yb (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=Zn, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 63] Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = Zn, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 63

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 549 :Example 549:

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer-Nd(III) complex Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer-Nd (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=Zn, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 63] Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = Zn, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 63

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 550 :Example 550:

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer-Er(III) complex Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer-Er (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=Pt, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 63] Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = Pt, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 63

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 551 :Example 551:

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer-Yb(III) complex Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer-Yb (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=Pt, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 63] Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = Pt, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 63

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 552 :Example 552:

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer-Nd(III) complex Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer-Nd (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=Pt, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 63] Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = Pt, M 2 = Zn) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 63

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 553 :Example 553:

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer-Er(III) complex Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer-Er (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=Pt, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 63] Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = Pt, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 63

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 554 :Example 554:

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer-Yb(III) complex Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer-Yb (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=Pt, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 63] Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = Pt, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 63

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 555 :Example 555:

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer-Nd(III) complex Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer-Nd (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Phenyl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=Pt, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 63] Phenyl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = Pt, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 63

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 556 :Example 556:

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer-Er(III) complex Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =2H, Ln=Er)= 2H, Ln = Er)

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=2H, M2=2H)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 64] Synthesis of Ln-complex using Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = 2H, M 2 = 2H) and erbium chloride hexahydrate. Scheme 64

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 557 :Example 557:

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer-Yb(III) complex Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =2H, Ln=Yb)= 2H, Ln = Yb)

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=2H, M2=2H)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 64] Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = 2H, M 2 = 2H) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 64

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 558 :Example 558:

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer-Nd(III) complex Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =2H, Ln=Nd)= 2H, Ln = Nd)

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=2H, M2=2H)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 64] Synthesis of Ln-complex using Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = 2H, M 2 = 2H) and neodymium chloride hexahydrate. Scheme 64

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 559 :Example 559:

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer-Er(III) complex Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=2H, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 64] Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = 2H, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 64

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 560 :Example 560:

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer-Yb(III) complex Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=2H, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 64] Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = 2H, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 64

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 561 :Example 561:

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer-Nd(III) complex Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=2H, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 64] Synthesis of Ln-complex using Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = 2H, M 2 = Zn) and neodymium chloride hexahydrate. Scheme 64

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 562 :Example 562:

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer-Er(III) complex Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer-Er (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=2H, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 64] Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = 2H, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 64

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 563 :Example 563:

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer-Yb(III) complex Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer-Yb (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=2H, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 64] Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = 2H, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 64

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 564 :Example 564:

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer-Nd(III) complex Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer-Nd (III) complex

(M(M 1One =2H, M= 2H, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=2H, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 64] Synthesis of Ln-complex using Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = 2H, M 2 = Pt) and neodymium chloride hexahydrate. Scheme 64

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 565 :Example 565:

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer-Er(III) complex Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer-Er (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=Zn, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 64] Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = Zn, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 64

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 566 :Example 566:

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer-Yb(III) complex Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer-Yb (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=Zn, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 64] Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = Zn, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 64

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 567 :Example 567:

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer-Nd(III) complex Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer-Nd (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=Zn, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 64] Synthesis of Ln-complex using Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = Zn, M 2 = Zn) and neodymium chloride hexahydrate. Scheme 64

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 568 :Example 568:

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer-Er(III) complex Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer-Er (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=Zn, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 64] Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = Zn, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 64

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 569 :Example 569:

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer-Yb(III) complex Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer-Yb (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Yb)= Pt, Ln = Yb)

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=Zn, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 64] Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = Zn, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 64

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 570 :Example 570:

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer-Nd(III) complex Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer-Nd (III) complex

(M(M 1One =Zn, M= Zn, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=Zn, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 64] Synthesis of Ln-complex using Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = Zn, M 2 = Pt) and neodymium chloride hexahydrate. Scheme 64

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 571 :Example 571:

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer-Er(III) complex Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer-Er (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Er)= Zn, Ln = Er)

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=Pt, M2=Zn)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 64] Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = Pt, M 2 = Zn) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 64

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 572 :Example 572:

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer-Yb(III) complex Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer-Yb (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Yb)= Zn, Ln = Yb)

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=Pt, M2=Zn)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 64] Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = Pt, M 2 = Zn) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 64

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 573 :Example 573:

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer-Nd(III) complex Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer-Nd (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Zn, Ln=Nd)= Zn, Ln = Nd)

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=Pt, M2=Zn)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 64] Synthesis of Ln-complex using Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = Pt, M 2 = Zn) and neodymium chloride hexahydrate. Scheme 64

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 574 :Example 574:

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer-Er(III) complex Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer-Er (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Er)= Pt, Ln = Er)

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=Pt, M2=Pt)와 erbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 64] Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = Pt, M 2 = Pt) and erbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 64

λem (λex = 442 nm, powder, 25℃) 1530 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 1530 nm.

실시예 575 :Example 575:

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer-Yb(III) complex Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer-Yb (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Yb) = Pt, Ln = Yb)

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=Pt, M2=Pt)와 ytterbium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 64] Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = Pt, M 2 = Pt) and ytterbium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 64

λem (λex = 442 nm, powder, 25℃) 978 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 978 nm.

실시예 576 :Example 576:

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer-Nd(III) complex Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer-Nd (III) complex

(M(M 1One =Pt, M= Pt, M 22 =Pt, Ln=Nd)= Pt, Ln = Nd)

Mesityl Ar-Ar, (3,5)-ether-bridged dendrimer (M1=Pt, M2=Pt)와 neodymium chloride hexahydrate를 사용하여 Ln-착물 제조 방법으로 합성한다. [반응식 64] Mesityl Ar-Ar, (3,5) -ether-bridged dendrimer (M 1 = Pt, M 2 = Pt) and neodymium chloride hexahydrate were synthesized by Ln-complex preparation. Scheme 64

λem (λex = 442 nm, powder, 25℃) 890, 1065, 1340 nm.λ em (λ ex = 442 nm, powder, 25 ° C.) 890, 1065, 1340 nm.

실시예 577 :Example 577:

희토류 착화합물의 발광 특성: Luminescent Properties of Rare Earth Complexes:

메시틸 Ar-Ar, (3,5)-에테르 브릿지드 덴드리머-Ln(III) 착물을 폴리메타아크릴레이트의 고분자 재료에 고분자재료에 대해 3중량％, 5중량％, 10중량％, 15중량％, 18중량％, 20중량％를 전체고형분의 무게의 10배의 무게에 해당하는 클로로포름 용매에 녹여 용액을 만든다. 이 용액을 스핀코우팅 방법으로 석영기판(quartz)에 고분자 박막을 제조하였다. 얻어진 박막에 대해 헬륨-카드늄(He-Cd) 레이저의 442nm 파장의 레이저 빔을 조사해서, 어븀이온의 발광 특징인 4I13/2 -＞ 4I15/2의 전자전이에 해당하는 1530 nm 파장의 발광세기를 측정하였고, 이터븀이온(Yb)의 발광 특징인 4F3/2 -＞ 4I11/2의 전자전이에 해당하는 978 nm 파장의 발광세기를 측정하였으며, Nd이온의 경우는 발광 특징인 2F5/2 -＞ 4 F7/2의 전자전이에 해당하는 1065 nm 파장의 발광세기를 측정하였다. 착화합물의 함량의 증가에 따라 발광의 세기가 증가되었으며, 착화합물의 함량을 20％까지 증가시켰을 때에 희토류이온의 최대발광파장의 발광세기가 어븀, 이터븀 및 니오비윰 각각 115배, 95배 및 120배로 증가되었다. 희토류 착화합물이 도핑된 고분자 박막들은 희토류이온이 도핑된 실리카의 발광세기 보다는 180배 내지 200배정도 이상의 높은 발광 세기를 나타내는 것으로 높은 광증폭효과를 나타낼 수 있음을 알 수 있었다.Mesityl Ar-Ar, (3,5) -ether bridged dendrimer-Ln (III) complexes to the polymer material of the polymethacrylate 3% by weight, 5% by weight, 10% by weight, 15% by weight , 18% by weight, 20% by weight in a chloroform solvent equivalent to 10 times the weight of the total solid content to make a solution. This solution was spin-coated to prepare a polymer thin film on a quartz substrate. The resulting thin film was irradiated with a 442 nm wavelength laser beam of a helium cadmium (He-Cd) laser, and a wavelength of 1530 nm corresponding to an electron transition of 4 I 13 / 2- > 4 I 15/2 , which is a luminescence characteristic of erbium ions. The emission intensity of was measured, and the emission intensity of 978 nm wavelength corresponding to the electron transition of 4 F 3 / 2- > 4 I 11/2 , which is the light emission characteristic of ytterbium ion (Yb), was measured. The light emission intensity of the 1065 nm wavelength corresponding to the electron transition of 2 F 5 / 2- > 4 F 7/2 , which is a light emission characteristic, was measured. The intensity of luminescence increased with the increase of the amount of the complex compound, and when the content of the complex compound was increased to 20%, the luminescence intensity of the maximum emission wavelength of rare earth ions was 115 times, 95 times, and 120 times, respectively. Increased by 2X. The polymer thin films doped with the rare earth complex compound exhibited a high light amplification effect by showing a light emission intensity of about 180 to 200 times higher than that of the rare earth ion doped silica.

본 발명에 의해서, 기존의 광섬유 실리카에 도핑 되는 Er3+ 농도가 100-1000 ppm 정도 이상이 되면 Er+3 이온간의 상호작용에 의해 비발광 프로세스가 주로 일어나서 광증폭 효율이 급격히 떨어져 실리카 광섬유에 Er3+을 도핑 하는 방법으로는 고이득 광증폭이 불가능하고 따라서 평면도파로형 광집적회로 형태로 30 dB 정도의 광증폭을 기대하기가 어렵고,According to the present invention, when the Er 3+ concentration doped in the conventional optical fiber silica is about 100-1000 ppm or more, the non-luminescence process mainly occurs due to the interaction between the Er +3 ions, so that the optical amplification efficiency drops sharply and the Er It is not possible to achieve high gain optical amplification by doping 3+ , so it is difficult to expect about 30 dB of optical amplification in the form of a planar waveguide optical integrated circuit.

또한 최근까지 고분자 광증폭 소재 개발을 위해, Er3+ 희토류 이온이나 킬레이트 착화합물을 무기 또는 고분자 매질에 도핑하는 방식의 주인-손님계(host-guest system)에서는 매질에 대한 희토류 금속들의 낮은 용해도 때문에 도핑 농도가 제한되므로 높은 광증폭 효과를 기대할 수 없고 또한 고농도로 도입할 경우 이온-이온의 응집은 물론 희토류 이온-실리카 간의 상 분리가 일어나 광증폭 효과를 오히려 저하시키는 문제점이 있었지만,Also, until recently, in the development of polymeric optically amplified materials, in the host-guest system of doping Er 3+ rare earth ions or chelate complexes to inorganic or polymeric media, doping is due to the low solubility of the rare earth metals in the media. Due to the limited concentration, high optical amplification effects cannot be expected, and when introduced at high concentrations, there is a problem in that the amplification of the ion-ions as well as the phase separation between the rare earth ions and the silica cause the optical amplification effect to be lowered.

본 발명의 화합물의 경우는 분자공학을 이용하여 자연광합성의 원리인 집광 효과를 나타내고, 고분자 매질에 우수한 용해도를 가지며, 희토류 금속의 뭉침이 없어서 이온-이온간의 상호작용이 없는 덴드리머형 폴피린 희토류 이온 착화합물 구조로서, 다양한 희토류 금속을 이용하여 광물리적 특성을 제어할 수 있음을 알 수 있다.In the case of the compound of the present invention, dendrimer-type polypyrine rare earth ions exhibiting a light condensing effect, which is a principle of natural photosynthesis, excellent solubility in a polymer medium, and no agglomeration of rare earth metals due to the molecular engineering, and there is no interaction between ions and ions As the complex structure, it can be seen that various rare earth metals can be used to control the photophysical properties.

또한 본 발명의 실시예에서 보듯이 희토류 이온을 달리하여 사용하면 발광파장을 제어할 수 있어서 다양한 파장을 이용한 응용분야를 적용할 수 있는데, 예를 들면 Yb 착화합물은 발광파장이 985nm 부근의 파장에서 발광이 일어나도록 조절이되고, Nd 착화합물의 경우는 1064nm 부근의 파장에서 발광이 일어나서 이 부근의 파장을 사용할 수 있으며, Er의 경우는 1530nm부근의 파장에서 발광이 일어난다. 또한 상기의 희토류이온을 달리할 경우에 있어서, 리간드로 2H-폴피린이나 Zn-폴피린 대신에 Pt-폴피린을 리간드로 사용하는 경우에는 발광의 세기가 수십배이상 증가되는 효과를 가지며(그림 2에서는 Pt-폴피린은 Zn-폴피린에 비해 약 78배), 특히 덴드론 형태의 리간드를 함유하는 희토류 착염들은 집광효과로 발광세기가 그림 3에서 보듯이 매우 증가되는 효과를 가지는 것임을 알 수 있어, 우수한 발광효율과 발광강도를 가지는 신규한 화합물을 제공할 수 있는 것임을 알 수 있다.In addition, as shown in the embodiment of the present invention, by using different rare earth ions, it is possible to control the emission wavelength, so that an application field using various wavelengths can be applied. For example, the Yb complex compound emits light at a wavelength around 985 nm. In the case of the Nd complex, light emission occurs at a wavelength near 1064 nm, and a wavelength in the vicinity thereof can be used. In the case of Er, light emission occurs at a wavelength near 1530 nm. In addition, when the rare earth ions are different from each other, when Pt-polpyrine is used as a ligand instead of 2H-polpyrine or Zn-polpyrine, the intensity of luminescence is increased by several orders of magnitude (Fig. 2). Pt-polpyrin is about 78 times higher than Zn-polpyrin), especially rare earth complex salts containing ligands of dendron form have a condensing effect, which shows that the luminescence intensity is greatly increased as shown in Fig. 3. It can be seen that it is possible to provide a novel compound having excellent luminous efficiency and luminous intensity.

도1은 희토류금속에 따른 특이 발광 파장 그래프.1 is a graph showing a specific emission wavelength according to the rare earth metal.

도2는 금속리간드에 따른 발광세기의 비교 그래프.2 is a comparative graph of luminescence intensity according to metal ligands.

도3은 금속리간드에 따른 발광세기의 비교 그래프.3 is a comparative graph of luminescence intensity according to metal ligands.

Claims (18)

하기 화학식 1을 갖는 에너지 전달 현상을 이용한 덴드리머형 금속폴피린 희토류 이온 착화합물Having the formula Dendrimer-type metalpyrphyrin rare earth ion complex using energy transfer phenomenon [화학식 1][Formula 1] 청구항 1에 있어서, 상기 덴드리머형 폴피린 희토류 이온 착화합물은 하기 화학식 2를 갖는 Metalloporphyrin-lanthanide 착물임을 특징으로 하는 덴드리머형 금속폴피린 희토류 이온 착화합물.The dendrimer-type metal pyrphyrin rare earth ion complex of claim 1, wherein the dendrimer-type phosphorine rare earth ion complex is a metalloporphyrin-lanthanide complex having the formula (2). [화학식 2] [Formula 2] 청구항 1에 있어서, 상기 덴드리머형 폴피린 희토류 이온 착화합물은 하기 화학구조식 3을 갖는 Metalloporphyrin-lanthanide 착물임을 특징으로 하는 덴드리머형 금속폴피린 희토류 이온 착화합물.The method of claim 1, wherein the dendrimer-type porphyrin rare earth ion complex is characterized in that the metalloporphyrin-lanthanide complex having the formula Dendrimer-type metalpyrroline rare earth ion complex compounds. [화학식 3][Formula 3] 청구항 1에 있어서, 상기 덴드리머형 폴피린 희토류 이온 착화합물은 하기 화학식 4를 갖는 Metalloporphyrin-lanthanide 착물임을 특징으로 하는 덴드리머형 금속폴피린 희토류 이온 착화합물The method of claim 1, wherein the dendrimer-type porphyrin rare earth ion complex is characterized in that the metalloporphyrin-lanthanide complex having the formula Dendrimer-type metal pyrroline rare earth ion complex [화학식 4][Formula 4] 청구항 1에 있어서, 상기 덴드리머형 폴피린 희토류 이온 착화합물은 하기 화학식 5를 갖는 Metalloporphyrin-lanthanide 착물임을 특징으로 하는 덴드리머형 금속폴피린 희토류 이온 착화합물The method of claim 1, wherein the dendrimer-type porphyrin rare earth ion complex is characterized in that the metalloporphyrin-lanthanide complex having the formula Dendrimer-type metal pyrroline rare earth ion complex [화학식 5][Formula 5] 청구항 1에 있어서, 상기 덴드리머형 폴피린 희토류 이온 착화합물은 하기 화학식 6을 갖는 Metalloporphyrin-lanthanide 착물임을 특징으로 하는 덴드리머형 금속폴피린 희토류 이온 착화합물The method of claim 1, wherein the dendrimer-type porphyrin rare earth ion complex is characterized in that the metalloporphyrin-lanthanide complex having the formula Dendrimer-type metal pyrroline rare earth ion complex [화학식 6][Formula 6] 청구항 1에 있어서, 상기 덴드리머형 폴피린 희토류 이온 착화합물은 하기 화학식 7을 갖는 Metalloporphyrin-lanthanide 착물임을 특징으로 하는 덴드리머형 금속폴피린 희토류 이온 착화합물The method of claim 1, wherein the dendrimer-type porphyrin rare earth ion complex is a metalloporphyrin-lanthanide complex having the formula Dendrimer-type metal pyrroline rare earth ion complex [화학식 7][Formula 7] 청구항 1에 있어서, 상기 덴드리머형 폴피린 희토류 이온 착화합물은 하기 화학식 8을 갖는 Metalloporphyrin-lanthanide 착물임을 특징으로 하는 덴드리머형 금속폴피린 희토류 이온 착화합물The method of claim 1, wherein the dendrimer-type porphyrin rare earth ion complex is characterized in that the metalloporphyrin-lanthanide complex having the formula Dendrimer-type metal pyrroline rare earth ion complex [화학식 8][Formula 8] 청구항 1에 있어서, 상기 덴드리머형 폴피린 희토류 이온 착화합물은 하기 화학식 9를 갖는 Metalloporphyrin-lanthanide 착물임을 특징으로 하는 덴드리머형 금속폴피린 희토류 이온 착화합물The method of claim 1, wherein the dendrimer-type porphyrin rare earth ion complex is a metalloporphyrin-lanthanide complex having the formula Dendrimer-type metal pyrroline rare earth ion complex [화학식 9][Formula 9] 청구항 1에 있어서, 상기 덴드리머형 폴피린 희토류 이온 착화합물은 하기 화학식 10을 갖는 Metalloporphyrin-lanthanide 착물임을 특징으로 하는 덴드리머형 금속폴피린 희토류 이온 착화합물.The method of claim 1, wherein the dendrimer-type porphyrin rare earth ion complex is a metalloporphyrin-lanthanide complex having the formula Dendrimer-type metalpyrroline rare earth ion complex compounds. [화학식 10][Formula 10] 청구항 1에 있어서, 상기 덴드리머형 폴피린 희토류 이온 착화합물은 하기 화학식 11을 갖는 Metalloporphyrin-lanthanide 착물임을 특징으로 하는 덴드리머형 금속폴피린 희토류 이온 착화합물.The method according to claim 1, wherein the dendrimer-type pole porphyrin complex is a rare earth ion to the dendrimer and the metal pole porphyrin complex rare earth ion characterized in that Metalloporphyrin-lanthanide complex having the formula (11). [화학식 11][Formula 11] 청구항 1에 있어서, 상기 덴드리머형 폴피린 희토류 이온 착화합물은 하기 화학식 12를 갖는 Metalloporphyrin-lanthanide 착물임을 특징으로 하는 덴드리머형 금속폴피린 희토류 이온 착화합물.The method of claim 1, wherein the dendrimer-type porphyrin rare earth ion complex is a metalloporphyrin-lanthanide complex having the formula Dendrimer-type metalpyrroline rare earth ion complex compounds. [화학식 12][Formula 12] 청구항 1에 있어서, 상기 덴드리머형 폴피린 희토류 이온 착화합물은 하기 화학식 13을 갖는 Metalloporphyrin-lanthanide 착물임을 특징으로 하는 덴드리머형 금속폴피린 희토류 이온 착화합물.The method of claim 1, wherein the dendrimer-type porphyrin rare earth ion complex is a metalloporphyrin-lanthanide complex having the formula Dendrimer-type metalpyrroline rare earth ion complex compounds. [화학식 13][Formula 13] 청구항 1에 있어서, 상기 덴드리머형 폴피린 희토류 이온 착화합물은 하기 화학식 14를 갖는 Metalloporphyrin-lanthanide 착물임을 특징으로 하는 덴드리머형 금속폴피린 희토류 이온 착화합물.The method of claim 1, wherein the dendrimer-type porphyrin rare earth ion complex is a metalloporphyrin-lanthanide complex having the formula Dendrimer-type metalpyrroline rare earth ion complex compounds. [화학식 14][Formula 14] 청구항 1에 있어서, 상기 덴드리머형 폴피린 희토류 이온 착화합물은 하기 화학식 15를 갖는 Metalloporphyrin-lanthanide 착물임을 특징으로 하는 덴드리머형 금속폴피린 희토류 이온 착화합물.The method of claim 1, wherein the dendrimer-type porphyrin rare earth ion complex is a metalloporphyrin-lanthanide complex having the formula Dendrimer-type metalpyrroline rare earth ion complex compounds. [화학식 15][Formula 15] 청구항 1에 있어서, 상기 덴드리머형 폴피린 희토류 이온 착화합물은 하기 화학식 16을 갖는 Metalloporphyrin-lanthanide 착물임을 특징으로 하는 덴드리머형 금속폴피린 희토류 이온 착화합물.The method of claim 1, wherein the dendrimer-type porphyrin rare earth ion complex is characterized in that the metalloporphyrin-lanthanide complex having the formula Dendrimer-type metalpyrroline rare earth ion complex compounds. [화학식 16][Formula 16] 청구항 1에 있어서, 상기 덴드리머형 폴피린 희토류 이온 착화합물은 하기 화학식 17을 갖는 Metalloporphyrin-lanthanide 착물임을 특징으로 하는 덴드리머형 금속폴피린 희토류 이온 착화합물.The method of claim 1, wherein the dendrimer-type porphyrin rare earth ion complex is a metalloporphyrin-lanthanide complex having the formula Dendrimer-type metalpyrroline rare earth ion complex compounds. [화학식 17][Formula 17] 제1항 내지 제17항중의 어느 한 항의 금속폴피린 희토류 이온 착화합물을 함유하는 광증폭용 고분자 블렌드물.An optically amplified polymer blend containing the metalpolpyrine rare earth ion complex compound according to any one of claims 1 to 17.
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GB2619448A (en) * 2022-03-23 2023-12-06 Univ Jiangsu Porphyrin zinc europium phosphorus cluster material, preparation method therefor and application thereof
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