KR200435743Y1 - The Dressing pad of Polyuretane - Google Patents
The Dressing pad of Polyuretane Download PDFInfo
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- KR200435743Y1 KR200435743Y1 KR2020060024201U KR20060024201U KR200435743Y1 KR 200435743 Y1 KR200435743 Y1 KR 200435743Y1 KR 2020060024201 U KR2020060024201 U KR 2020060024201U KR 20060024201 U KR20060024201 U KR 20060024201U KR 200435743 Y1 KR200435743 Y1 KR 200435743Y1
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- polyurethane foam
- ointment
- sheet
- dressing
- agent
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- 229920005830 Polyurethane Foam Polymers 0.000 claims abstract description 32
- 239000011496 polyurethane foam Substances 0.000 claims abstract description 32
- 239000002674 ointment Substances 0.000 claims abstract description 24
- 239000011148 porous material Substances 0.000 claims abstract description 6
- 229920001730 Moisture cure polyurethane Polymers 0.000 claims abstract description 4
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 4
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 4
- 125000005442 diisocyanate group Chemical group 0.000 claims abstract description 4
- 229920000570 polyether Polymers 0.000 claims abstract description 4
- 229920005862 polyol Polymers 0.000 claims abstract description 4
- 150000003077 polyols Chemical class 0.000 claims abstract description 4
- 239000004094 surface-active agent Substances 0.000 claims abstract description 4
- 239000003906 humectant Substances 0.000 claims description 2
- 239000004604 Blowing Agent Substances 0.000 claims 1
- 239000003242 anti bacterial agent Substances 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 abstract description 11
- 230000028327 secretion Effects 0.000 abstract description 5
- 210000000416 exudates and transudate Anatomy 0.000 abstract description 4
- -1 and the like Substances 0.000 abstract description 3
- 239000004599 antimicrobial Substances 0.000 abstract description 3
- 239000004088 foaming agent Substances 0.000 abstract description 3
- 230000003020 moisturizing effect Effects 0.000 abstract description 3
- 230000035699 permeability Effects 0.000 abstract description 2
- 239000000654 additive Substances 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 206010052428 Wound Diseases 0.000 description 19
- 208000027418 Wounds and injury Diseases 0.000 description 19
- 239000003814 drug Substances 0.000 description 6
- 229940079593 drug Drugs 0.000 description 6
- 239000006260 foam Substances 0.000 description 3
- KDCGOANMDULRCW-UHFFFAOYSA-N 7H-purine Chemical compound N1=CNC2=NC=NC2=C1 KDCGOANMDULRCW-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 208000004210 Pressure Ulcer Diseases 0.000 description 2
- 230000003111 delayed effect Effects 0.000 description 2
- 208000015181 infectious disease Diseases 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 206010063560 Excessive granulation tissue Diseases 0.000 description 1
- 206010035664 Pneumonia Diseases 0.000 description 1
- 206010048629 Wound secretion Diseases 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 210000001126 granulation tissue Anatomy 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229920006264 polyurethane film Polymers 0.000 description 1
- 230000001012 protector Effects 0.000 description 1
- 230000037390 scarring Effects 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- 210000001519 tissue Anatomy 0.000 description 1
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/02—Adhesive bandages or dressings
- A61F13/0246—Adhesive bandages or dressings characterised by the skin-adhering layer
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0241—Containing particulates characterized by their shape and/or structure
- A61K8/0245—Specific shapes or structures not provided for by any of the groups of A61K8/0241
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L26/00—Chemical aspects of, or use of materials for, wound dressings or bandages in liquid, gel or powder form
- A61L26/0061—Use of materials characterised by their function or physical properties
- A61L26/0066—Medicaments; Biocides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F2013/00361—Plasters
- A61F2013/00655—Plasters adhesive
- A61F2013/00719—Plasters adhesive adhesives for use on wounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F2013/00361—Plasters
- A61F2013/00727—Plasters means for wound humidity control
- A61F2013/00731—Plasters means for wound humidity control with absorbing pads
- A61F2013/0074—Plasters means for wound humidity control with absorbing pads containing foams
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Epidemiology (AREA)
- Engineering & Computer Science (AREA)
- Geometry (AREA)
- Physics & Mathematics (AREA)
- Birds (AREA)
- Dermatology (AREA)
- Biomedical Technology (AREA)
- Heart & Thoracic Surgery (AREA)
- Vascular Medicine (AREA)
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- Materials Engineering (AREA)
- Materials For Medical Uses (AREA)
Abstract
본 고안은 디이소시아네이트와 폴리에테르폴리올을 반응하여 합성한 폴리우레탄프레폴리머와 발포제, 가교제, 보습제, 항균제, 계면활성제 등을 첨가하여 제조하며, 미세하고 다수의 통공(pore)형태로 구성된 폴리우레탄폼 시트(1)와, 상기 폴리우레탄폼 시트(1)의 상부에 원형, 삼각형, 사각형, 육각형상에서 선택된 어느 하나의 형상으로 돌출되도록 형성된 연고약제(2)와, 상기연고약제(2)의 상부에 적층된 투명이형지(3)로 구성되어 환부(창상)치료첨부제로서 드레싱 교치 시에 달라붙지 않고 환부의 삼출물 흡수력이 뛰어나고 분비물이 증발되는 고투습도와 친수성으로 보습기능이 우수한 폴리우레탄폼 드레싱 시트에 관한 것이다.The present invention is prepared by adding a polyurethane prepolymer synthesized by reacting a diisocyanate with a polyether polyol, a foaming agent, a crosslinking agent, a moisturizing agent, an antimicrobial agent, a surfactant, and the like, and a polyurethane foam composed of a plurality of pores. Sheet (1), ointment (2) formed on the top of the polyurethane foam sheet (1) to protrude in any one shape selected from the shape of a circle, triangle, square, hexagon , and the top of the ointment (2) It is composed of laminated transparent release paper (3) and is a wound (wound) treatment additive.It does not stick to the dressing when teaching, and it has excellent absorbency of exudates of the affected area and high moisture permeability and hydrophilic property that secretion evaporates. It is about.
폴리우레탄폼 드레싱제, 드레싱패드. Polyurethane foam dressings, dressing pads.
Description
도 1 내지 도 3은 본 고안의 폴리우레탄폼 드레싱 시트 상세도1 to 3 is a detailed view of the polyurethane foam dressing sheet of the present invention
도 4 내지 도 8은 본 고안의 폴리우레탄폼 드레싱 시트의 다양한 무늬 예 4 to 8 are various examples of the pattern of the polyurethane foam dressing sheet of the present invention
<도면의 부호 설명><Description of the symbols in the drawing>
폴리우레탄폼시트(1), 연고약제(2), 투명이형지(3).Polyurethane foam sheet (1), ointment (2), transparent release paper (3).
본 고안은 창상, 화상, 욕창 등의 상처를 입은 피부에 사용되며 폴리우레탄폼 시트의 상부에 다양한 무늬와 다양한 형태의 연고 약제가 구비된 폴리우레탄폼 드레싱 시트에 관한 것이다.The present invention relates to a polyurethane foam dressing sheet which is used for wounds, wounds, bedsores and the like, and has various patterns and ointments of various forms on top of the polyurethane foam sheet.
일반적으로 피부에 상처가 낫을 경우 외부자극으로부터 상처를 보호하며 상처의 수분손실을 막아주도록 드레싱제로 거즈 드레싱제와 친수성 폴리우레탄폼 드레싱제가 있다. Generally, a gauze dressing agent and a hydrophilic polyurethane foam dressing agent are used as dressing agents to protect the wound from external stimuli and to prevent the loss of moisture when the wound is healed.
그러나 거즈 드레싱제는 상처분비물의 흡수 속도는 빠르나, 건소한 상태로 유지시 드레싱제가 상처 면에 밀착되어 거즈 드레싱제의 제거시 상처의 피부 일부와 함께 제거되어 신생조직의 손상 및 통증을 수반하는 문제점이 있어, 축축한 상 태를 유지하기 위하여 자주 거즈드레싱을 교체하여야하는 번거러움이 있으며, 또한 친수성 폴리우레탄폼 드레싱제는 우수한 흡수도를 갖고 있고, 적절한 습윤상태를 유지함과 동시에 상처 면에 미부착되는 장점이 있어 많이 애용되고 있다.However, the gauze dressing is fast in absorbing the wound secretion, but when it is kept in a dry state, the dressing agent adheres to the wound surface, and when the gauze dressing agent is removed, the gauze dressing is removed along with a part of the skin of the wound, thereby causing damage and pain of the new tissue. In order to maintain a moist condition, the gauze dressing needs to be replaced frequently, and the hydrophilic polyurethane foam dressing agent has an excellent absorbency, and maintains proper wet state and is not attached to the wound surface. There is a lot and is used habitually.
일반적으로 폴리우레탄폼 드레싱제는 환부 드레싱에 약제가 환부를 덮게 되어 환부 분비물 흡수가 차단, 지연, 감염(화농)이 발생 육아조직형성 및 가피형성이 지연되어 치료가 지연 흉터가 크게 남게 된다. In general, the polyurethane foam dressing agent covers the affected area with the wound dressing, so that the secretion of absorbed secretions is blocked, delayed, and infection (purine) occurs.
국내공개특허공보 공개번호 제10-2006-59385호에는 미세포아와 고점도삼출액 흡수수단이 형성된 미세다공성 폴리우레탄 필름의 상처면 접촉층과, 상기 접촉층의 상부에 접합된 지지층으로 구성된 창상피복용 드레싱제가 기재되어 있고, Korean Laid-Open Patent Publication No. 10-2006-59385 discloses a wound dressing comprising a wound surface contact layer of a microporous polyurethane film in which microblasts and high viscosity effluent absorption means are formed, and a support layer bonded on top of the contact layer. I'm listed,
동 공보 공개번호 제10-2005-91229호에는 삼출물을 흡수한 후 팽윤으로 인한 친수폼의 물성저하를 개선한 네트형 필름이 접합 되거나, 직선, 곡선, 원, 타원형 다각형 또는 이들의 조합으로 된 필름으로 구성된 폼 드레싱제가 공개되어 있으나, Publication No. 10-2005-91229 discloses a net-like film which improves the properties of hydrophilic foams due to swelling after absorbing exudates, or a film made of straight, curved, circular, elliptical polygons, or a combination thereof. Foam dressing composition consisting of the public,
상기와 같은 종래의 환부 드레싱은 약제를 환부에 바르고 그 위에 환부보호제 거즈, 드래싱폼등으로 드레싱을 하고 있으나, 이로 인하여 거즈는 환부에 달라붙어 아프고 피가 날수 있고 가피가 탈락되어 치료가 지연되고 흉터가 크게 남게 되는 문제점이 있어 왔다.Conventional wound dressings as described above are applied to the affected area with the drug applied to the wound protector gauze, dressing foam, etc. Due to this, the gauze sticks to the affected area, sore and bleeding, peeling off the skin delayed treatment and scarring There has been a problem that remains large.
상기와 같은 문제점을 해결하고자, 본 고안은 폴리우레탄폼 드레싱 시트 위에 일정량의 연고 약제를 도포하여 제조하여, 연고 약제도포무늬와 무늬 사이 공간과 무늬 크기 연고 약제량은 환부상태에 따라 선정 적용하여 사용하고, 약제는 흡수되지 않고 액상의 삼출액만을 흡수되도록 제조한 폴리우레탄폼 드레싱시트위에 환부에 알맞은 무늬와 연고약제종류, 약제의 량을 도포하여 얇은 폴리프로필렌필름(이형제)으로 덮어서 제조한 폴리우레탄폼 드레싱 시트를 제공하는 것이 본 고안이 이루고자하는 기술적 과제인 것이다.In order to solve the above problems, the present invention is produced by applying a certain amount of ointment on the polyurethane foam dressing sheet, the amount of the ointment drug coating pattern and the pattern between the pattern and the size of the ointment is selected and applied according to the affected condition Polyurethane foam prepared by covering a thin polypropylene film (releasing agent) by applying appropriate amount of pattern, ointment, and drug to the affected area on the polyurethane foam dressing sheet manufactured to absorb only liquid exudates without absorbing the drug. Providing a dressing sheet is a technical problem to be achieved by the present invention.
상기와 같은 목적을 달성하기 위하여, 본 고안은 디이소시아네이트와 폴리에테르폴리올을 반응하여 합성한 폴리우레탄프레폴리머와 발포제, 가교제, 보습제, 항균제, 계면활성제등을 첨가하여 제조하며, 미세하고 다수의 통공(pore)형태로 구성된 폴리우레탄폼 시트(1)와, 상기 폴리우레탄폼 시트(1)의 상부에 원형, 삼각형, 사각형, 육각형상에서 선택된 어느 하나의 형상으로 돌출 되도록 형성된 연고약제(2)와, 상기연고약제(2)의 상부에 적층된 투명이형지(3)로 구성되어 환부(창상)치료첨부제로서 드레싱 교치 시에 달라붙지 않고 환부의 삼출물 흡수력이 뛰어나고 분비물이 증발되는 고투습도와 친수성으로 보습기능이 우수한 폴리우레탄폼 드레싱 시트에 관한 것이다.In order to achieve the above object, the present invention is prepared by adding a polyurethane prepolymer synthesized by reacting a diisocyanate and a polyether polyol, a foaming agent, a crosslinking agent, a humectant, an antimicrobial agent, a surfactant, and the like, and a plurality of pores. Polyurethane foam sheet (1) configured in the form of (pore) , ointment (2) formed to protrude in any one shape selected from a circle, triangle, square, hexagonal shape on the polyurethane foam sheet (1), Consisting of transparent release paper (3) laminated on top of the ointment (2) as a treatment for wound (wound), it does not stick to the dressing maturity, has excellent exuding ability of exudates of the affected area, and moisturizing with high moisture permeability and hydrophilicity that secretions are evaporated. It relates to a polyurethane foam dressing sheet excellent in function.
본 고안의 폴리우레탄폼 드레싱 시트 위에 일정량의 연고약제를 도포하는 것으로 도포무늬와 방법 종류는 다양하게 구성할 수 있으며, 적용은 환부의 상태에 따라 적의 선정하여 적용하며, 보다 상세히 설명하면, 연고약제 도포무늬와 무늬 사이 공간과 무늬크기 연고약제량은 환부상태에 따라 선정 적용한다.By applying a certain amount of ointment on the polyurethane foam dressing sheet of the present invention, the application pattern and the method can be configured in various ways, the application is appropriately selected according to the condition of the affected area, and in more detail, ointment The spacing between the coated pattern and the pattern and the size of the patterned ointment are chosen according to the affected condition.
본 고안의 폴리우레탄폼 드레싱시트는 약제는 흡수되지 않고 액상의 삼출액만을 흡수되도록 제조한 상부표면에 환부에 알맞은 무늬와 연고약제종류, 약제의 량을 도포하여 얇은 폴리프로필렌필름으로 덮어서 제조한다.The polyurethane foam dressing sheet according to the present invention is manufactured by covering a thin polypropylene film by applying a suitable pattern to the affected part, a kind of ointment, and an amount of the drug on the upper surface prepared to absorb only the liquid exudant without absorbing the drug.
이하 본 고안을 도면을 참고하여 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in detail with reference to the accompanying drawings.
도 1 내지 도 3은 본 고안의 폴리우레탄폼 드레싱 시트 상세도, 도 4 내지 도 8은 본 고안의 폴리우레탄폼 드레싱 시트의 다양한 무늬 예를 도시한 것이며, 폴리우레탄폼시트(1), 연고약제(2), 투명이형지(3)를 나타낸 것임을 알 수 있다.1 to 3 is a detailed view of the polyurethane foam dressing sheet of the present invention, Figures 4 to 8 show various examples of the pattern of the polyurethane foam dressing sheet of the present invention, polyurethane foam sheet (1), ointment (2), It can be seen that the transparent release paper (3) is shown.
구조를 살펴보면, 도 1 내지 도 3에 도시된 바와 같이, 디이소시아네이트와 폴리에테르폴리올을 반응하여 합성한 폴리우레탄프레폴리머와 발포제, 가교제, 보습제, 항균제, 계면활성제등을 첨가하여 제조하며, 미세하고 다수의 통공(pore)형태로 구성된 폴리우레탄폼 시트(1)와, 상기 폴리우레탄폼 시트(1)의 상부에 원형, 삼각형, 사각형, 육각형상에서 선택된 어느 하나의 형상으로 돌출 되도록 형성된 연고약제(2)와, 상기연고약제(2)의 상부에 적층된 투명이형지(3)로 구성된 폴리우레탄폼 드레싱 시트의 구조인 것이다.Looking at the structure, as shown in Figures 1 to 3, prepared by adding a polyurethane prepolymer and a foaming agent, a crosslinking agent, a moisturizing agent, an antimicrobial agent, a surfactant and the like synthesized by reacting diisocyanate and polyether polyol, Polyurethane foam sheet (1) consisting of a plurality of pores (pore), and ointment agent formed to protrude in any one shape selected from the shape of a circle, triangle, square, hexagon on the polyurethane foam sheet (2) ) And a polyurethane foam dressing sheet composed of
사용방법을 설명하면,Explain how to use
상기와 같이, 폴리우레탄폼 시트(1)의 상부에 원형, 삼각형, 사각형, 육각형상에서 선택된 어느 하나의 형상으로 돌출되어 설치된 연고약제(2)로 구성된 폴리우레탄폼 드레싱시트의 상부에 이형지(미도시)로 적층된 투명이형지(3)로 구성된 폴리우레탄폼 드레싱 시트를 욕창, 화상, 창상 등의 원인에 따라 연고약제의 종류를 달리하고, 상처의 크기나 깊이에 따라 적당한 무늬(상처가 깊고 크면, 농도가 짙은 무늬를 갖고, 상처가 얇고, 가벼우면 농도가 옅은 무늬)를 선택하여 투명이형지(3)를 제거한 후에 연고약제(2)부분이 상처에 닿게 하여 부착하는 것이다.As described above, the release paper (not shown) on the upper portion of the polyurethane foam dressing sheet consisting of the ointment (2) installed protruding in any one shape selected from a circle, triangle, square, hexagonal shape on the upper portion of the polyurethane foam sheet (1). Polyurethane foam dressing sheet consisting of transparent release paper (3) laminated with a different type of ointment depending on the cause of bedsores, burns, wounds, etc., and according to the size and depth of the wound (when the wound is deep and large, It has a thick pattern, and the wound is thin, and if the weight is light, the pattern is thick.) After removing the transparent release paper (3), the ointment (2) part is attached to the wound.
상기와 같은 본 고안은 다양한 무늬로 다양한 연고약제를 도포하면 환부 분 비물을 즉시 흡수 증발하고 도포한 연고약제가 환부에 전이되어 감염(화농)을 예방하며 육아조직 및 가피형성을 촉진하여 탁월한 치료 효과를 얻을 수 있다.The present invention as described above, the application of various ointments in a variety of patterns immediately absorb evaporation of the affected secretion, and the applied ointment is transferred to the affected area to prevent infection (pneumonia), promote granulation tissue and skin formation, excellent therapeutic effect Can be obtained.
Claims (1)
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KR2020060024201U KR200435743Y1 (en) | 2006-09-08 | 2006-09-08 | The Dressing pad of Polyuretane |
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KR2020060024201U KR200435743Y1 (en) | 2006-09-08 | 2006-09-08 | The Dressing pad of Polyuretane |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101426740B1 (en) | 2014-02-18 | 2014-08-05 | 주식회사 원바이오젠 | Dressing containing punched adhesive film and its manufacturing method |
KR101575178B1 (en) | 2014-06-10 | 2015-12-07 | (주)시지바이오 | Charcoal wound dressing and manufacturing method thereof |
-
2006
- 2006-09-08 KR KR2020060024201U patent/KR200435743Y1/en not_active IP Right Cessation
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101426740B1 (en) | 2014-02-18 | 2014-08-05 | 주식회사 원바이오젠 | Dressing containing punched adhesive film and its manufacturing method |
KR101575178B1 (en) | 2014-06-10 | 2015-12-07 | (주)시지바이오 | Charcoal wound dressing and manufacturing method thereof |
WO2015190768A1 (en) * | 2014-06-10 | 2015-12-17 | 주식회사 시지바이오 | Charcoal dressing material and method for producing same |
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