KR20040107192A - Composite of synthetic fiber yarn and the manufacture method to use pure silver, nature inorganic matter complex - Google Patents

Composite of synthetic fiber yarn and the manufacture method to use pure silver, nature inorganic matter complex Download PDF

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KR20040107192A
KR20040107192A KR1020030038134A KR20030038134A KR20040107192A KR 20040107192 A KR20040107192 A KR 20040107192A KR 1020030038134 A KR1020030038134 A KR 1020030038134A KR 20030038134 A KR20030038134 A KR 20030038134A KR 20040107192 A KR20040107192 A KR 20040107192A
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nanoparticles
natural
particle size
pure silver
synthetic fiber
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KR100506945B1 (en
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전영호
박판호
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전영호
박판호
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    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/08—Melt spinning methods
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/60—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/62—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters

Abstract

PURPOSE: A composition of synthetic fiber grey yarn is characterized by using complex of pure silver and natural inorganic material, radiating far infrared ray and anion, having antibacterial property and antimold property and intercepting water vein waves and electron wave. CONSTITUTION: A composition of synthetic fiber grey yarn is obtained by the steps of: preparing pure silver having 20-200nm of size, 56nm of average particle size and 97nm of particle size of 90%; preparing complex(50nm-2μm) comprised of natural submarine minerals radiating anion and natural minerals radiating far infrared ray; concentrating the pure silver and the complex into 15-40wt.% in producing polyester chip master batch; and then mixing and melt-spinning normal synthetic fiber chip, nylon or polypropylene chip to manufacture the complex into 1-5wt.% based on final grey yarn.

Description

순은,천연무기물 복합체를 이용한 합성섬유원사의 조성물 및 그 제조방법{Composite of synthetic fiber yarn and the manufacture method to use pure silver, nature inorganic matter complex}Synthetic fiber yarn and the manufacture method to use pure silver, nature inorganic matter complex}

본 발명은 순은, 천연무기물 복합체를 이용한 합성섬유(나일론,폴리프로필렌,폴리에스터)원사의 조성물 및 그 제조방법에 관한 것으로, 더욱 상세하게는 나일론, 폴리프로필렌, 폴리에스터 등과 같은 합성섬유에 나노입자의 순은, 나노입자의 천연무기물을 첨가하여 방사한 합성섬유원사의 조성물 및 그 제조방법에 관한 것이다.The present invention relates to a composition of a synthetic fiber (nylon, polypropylene, polyester) yarn using a pure silver, natural inorganic composites and a method of manufacturing the same, more specifically, nanoparticles in synthetic fibers such as nylon, polypropylene, polyester, etc. The present invention relates to a composition of synthetic fiber yarn spun by adding a natural inorganic material of nanoparticles and a method for producing the same.

주지하는 바와 생활주변에 사용하는 각종의 섬유는 대부분이 나일론, 폴리프로필렌, 폴리에스터 등과 같은 합성섬유를 주성분으로 한다.As is well known, various kinds of fibers used for living are mainly composed of synthetic fibers such as nylon, polypropylene, polyester and the like.

상기와 같은 합성섬유는 비교적 가격이 저렴한 등의 장점이 있으나 흡습성의 결핍으로 인하여 정전기가 많이 발생되고, 인체에서 분비되는 땀, 지방, 단백질 등 유기물이 부착되면 세균의 서식을 유리하게 하여 미생물의 번식시킴으로써 악취를발생시키는 등 인체에 많은 나쁜 영향을 주는 단점이 있다.Such synthetic fibers have advantages such as relatively low cost, but due to the lack of hygroscopicity, a lot of static electricity is generated, and when organic matter such as sweat, fat, and protein secreted by the human body is attached, it favors the breeding of microorganisms to propagate microorganisms. By doing so, there is a disadvantage of causing a lot of bad effects on the human body, such as generating a bad smell.

종래 상기와 같은 단점들 중에 정전기 방지와 전자파 차폐효과를 극대화 시키기위하여 황화구리를 흡착시킨 섬유가 있다.Among the above disadvantages, there is a fiber that adsorbs copper sulfide to maximize the antistatic and electromagnetic shielding effect.

또한, 은의 고유한 효과인 원적외선 방출, 은이온 방출, 항균 및 항곰팡이, 수맥파 차단, 전자파 차단 작용을 이용하기 위하여 원사에 은을 코팅한 합성섬유원사가 최근에 생산/공급되고 있다,In addition, in order to take advantage of silver's inherent effects such as far-infrared radiation, silver ion release, antibacterial and antifungal, water wave blocking, electromagnetic shielding action, a synthetic fiber yarn coated with silver on the yarn has recently been produced / provided.

그러나 은이 코팅된 원사는 촉감이 좋지 않고, 마모가 빨라서 단기간에 본래의 기능이 상실되는 등의 단점이 있다.However, the silver-coated yarn is not good to the touch, and wear is fast, so that the original function is lost in a short time.

상기 외에도 섬유에 항균, 원적외선발생, 음이온발생을 위하여 각종의 유기물분말을 사용하였다.In addition to the above, various organic powders were used for antibacterial, far-infrared, and negative ion generation in the fiber.

그러나 대부분은 합성섬유원사로 제직된 원단에 코팅 또는 염색과 같은 2차적인 가공수단을 통하여 처리함으로써 본래의 기능이 상실되는 등의 문제점이 있었다.However, most of them have problems such as loss of original function by treating the fabric woven with synthetic fiber yarn through secondary processing means such as coating or dyeing.

상기와 같은 문제점을 해결하기 위한 본 발명의 목적은 항균, 정전기방지, 음이온발생, 원적외선발생에 따른 효과를 영구적으로 구할 수 있는 나일론, 폴리프로필렌, 폴리에스터 등과 같은 합성섬유원사의 조성물을 제공하고, 그에 따른 원사제조방법을 제공하는데 소기의 목적이 있다.An object of the present invention for solving the above problems is to provide a composition of synthetic fiber yarns such as nylon, polypropylene, polyester, etc., which can permanently obtain the effects of antibacterial, antistatic, negative ion generation, far infrared generation, The purpose is to provide a method for manufacturing yarn accordingly.

도 1의 가,나,다는 본 발명에 따른 합성섬유사의 방사 공정도1, b, b spinning process diagram of synthetic fiber yarn according to the present invention

상기의 목적을 달성하기 위한 본 발명의 특징은 나일론, 폴리프로필렌, 폴리에스터 등과 같은 합성섬유원사를 방사할 때 나노입자의 순은과 나노입자의 천연무기물을 함유하는 복합체를 적정비로 혼합하여 방사한 것으로, 이하 실시예에 따라 더욱 상세하게 설명하면 다음과 같다.A feature of the present invention for achieving the above object is that when spinning a synthetic fiber yarn such as nylon, polypropylene, polyester, etc., the composite containing the pure silver of the nanoparticles and natural inorganic matter of the nanoparticles is mixed and spun at an appropriate ratio When described in more detail according to the following examples.

본 발명에 사용되는 물질은 순은, 음이온영구발생을 위한 천연무기물, 원적외선영구발생을 위한 천연무기물이 사용된다.As the material used in the present invention, sterling silver, natural minerals for the generation of anion permanently, and natural minerals for the generation of far-infrared permanent are used.

상기한 순은의 나노입자는 20nm~200nm이며, 평균입도는 56nm, 90%입도 97nm이며, 입도분석표 및 SEM입자 사진은 아래 도시된 표와 같다.The nanoparticles of the pure silver is 20nm ~ 200nm, the average particle size is 56nm, 90% particle size 97nm, the particle size analysis table and SEM particle picture is shown in the table shown below.

또, 음이온영구발생을 위한 천연무기물은 해저광물로서 SiO253.1%, Al2O311.8%, Fe2O33.95% , MgO 2.98% , Na2O 1.72% , 기타 CaO , K2O 와 미량의 Cu , Zn 등의 산화물을 함유한 무기분말로 음이온 발생수는 CC당 25,000개에서 55,000개 범위로 영구발생하며,In addition, natural inorganic minerals for the generation of anions are subsea minerals with SiO 2 53.1%, Al 2 O 3 11.8%, Fe 2 O 3 3.95%, MgO 2.98%, Na 2 O 1.72%, other CaO, K 2 O and trace amounts Inorganic powder containing oxides of Cu, Zn, etc., anion generating water is permanently generated in the range of 25,000 to 55,000 per CC,

또한, 원적외선영구발생을 위한 천연무기물을 대부분의 기능성 광물질 (예:맥반석, 심성화강암, 옥석류 등)로서 인체에 유익한 원적외선에너지를 영구 발생 시키며, 분말의 색상이 백색도가 없으므로 본 특허출원에서는 흑체(Black Body) 대비 약 93% 의 방사율을 가진 백색도의 조합 광물로서 SiO272.3% , Al2O314.4% , K2O 4.85% , 기타 미량의 Fe2O3, CaO , MgO , Na2O 등으로 구성된 원적외선 영구발생광물질을 상기한 천연무기물입자는 나노입자 50nm~2㎛이하가 되도록 준비하며, 무기물입자 입도분석표는 아래 표와 같다.In addition, natural minerals for the generation of far-infrared permanent permanent generation of far-infrared energy, which is beneficial to the human body as most functional minerals (eg, elvan, deep granite, gemstones, etc.). It is a combination mineral of whiteness with an emissivity of about 93% compared to black body), SiO 2 72.3%, Al 2 O 3 14.4%, K 2 O 4.85%, other trace amounts of Fe 2 O 3 , CaO, MgO, Na 2 O, etc. The natural inorganic particles, the far-infrared permanently generated minerals composed of the nanoparticles are prepared to be less than 50nm ~ 2㎛, inorganic particle size analysis table is shown in the table below.

상기와 같이 준비된 나노입자의 순은과 나노입자의 천연무기물들을 함유하는 복합체를 나일론, 폴리프로필렌, 폴리에스터 등과 같은 합성섬유칩과 적정비로 혼합하여 방사하는 것으로 실시예에 따라 상세하게 설명한다.The composite containing pure silver of the nanoparticles prepared as described above and natural inorganic matters of the nanoparticles will be described in detail according to the embodiment by spinning with a suitable ratio with a synthetic fiber chip such as nylon, polypropylene, polyester and the like.

실시예 1Example 1

순은의 나노입자 (20nm~200nm와, 평균입도는 56nm, 90% 입도 97nm)와, 음이온영구발생을 위한 천연무기물은 해저광물과, 원적외선영구발생을 위한 천연무기물의 나노입자 (50nm~2㎛)의 복합체를 폴리에스터칩 마스터 배치제조과정에서 WT%로 15%-40%사이에 적정치 농축한 폴리에스터칩(Pellt) 또는 나일론이나 폴리프로필렌칩을 마련하여 일반 폴리에스터칩(PET) 또는 나일론, 폴리프로필렌칩을 WT%로 최종원사기준으로 종합복합체 WT가 1%-5%사이로 제조되도록 혼합용융방사하는 것으로, 도 1을 참조한다.(상기 WT%란. 단위 중량비%를 말한다. 예를들어 WT%로 3%-4%로의 의미는 분말의 중량이 합성섬유원사 중량의 3%-4%를 말한다.)Sterling silver nanoparticles (20nm ~ 200nm, average particle size: 56nm, 90% particle size 97nm), natural minerals for anion permanent generation, sea minerals, and nanoparticles of natural inorganics for far infrared permanent generation (50nm ~ 2㎛) Of polyester chips or nylon or polypropylene chips by concentrating an appropriate concentration between 15% and 40% of WT% in a polyester chip master batch manufacturing process. The polypropylene chip is mixed melt-spun so that the composite composite WT is produced between 1% and 5% by WT% based on the final yarn. (See the above WT%. The unit weight ratio is%.) WT% to 3% -4% means that the weight of the powder is 3% -4% of the weight of the synthetic fiber yarn.)

상기 최종 복합체의 입자 현미경 사진은 아래와 같다.Particle micrographs of the final composite are as follows.

상기 WT% 15% 농축 폴리에스터칩(Pellt)의 현미경사진은 아래와 같다.Photomicrographs of the WT% 15% concentrated polyester chip (Pellt) are as follows.

실시예 2Example 2

순은의 나노입자 (20nm~200nm와, 평균입도는 56nm, 90% 입도 97nm)와, 음이온영구발생을 위한 천연무기물은 해저광물과,원적외선영구발생을 위한 천연무기물의 나노입자 (50nm~2㎛)의 복합체를 WT%로 15-40% 에틸렌글리칩 폴리에스터 컴파운드중합하여 방사하는 것으로, 도2를 참조한다.Pure silver nanoparticles (20nm ~ 200nm, average particle size 56nm, 90% particle size 97nm), natural minerals for negative ion generation, sea minerals and nanoparticles (50nm ~ 2㎛) for far infrared permanent generation The composite is spun at 15-40% ethylene glycol chip polyester compound in WT% to spin, see FIG.

실시예3Example 3

순은의 나노입자 (20nm~200nm와, 평균입도는 56nm, 90% 입도 97nm)와, 음이온영구발생을 위한 천연무기물은 해저광물과,원적외선영구발생을 위한 천연무기물의 나노입자 (50nm~2㎛)의 복합체를 폴리에스터칩(건조)을 용융압출시 사이드피딩(Side Feeding)방법으로 방사하는 것으로, 도2를 참조한다.Pure silver nanoparticles (20nm ~ 200nm, average particle size 56nm, 90% particle size 97nm), natural minerals for negative ion generation, sea minerals and nanoparticles (50nm ~ 2㎛) for far infrared permanent generation Of the composite of the polyester chip (dry) is spun by melt-extrusion side feed (Side Feeding) method, see FIG.

이상 실시예와 같이 하여 방사된 원사의 현미경 사진은 아래와 같으며, 기능성 입자의 고른분포와 확산을 확인할 수 있다.The micrograph of the yarn spun as in the above embodiment is as follows, and even distribution and diffusion of the functional particles can be confirmed.

이상과 같은 본 발명은 순은과 천연무기물을 나일론, 폴리프로필렌, 폴리에스터와 같은 합성섬유원사의 조성물로하여 방사함으로써 합성섬유원사에 상기물질을 코팅하는 종래의 단점을 해결하고 합성섬유원사의 수명이 다할 때 까지 은의 고유한 효과인 원적외선 방출, 은이온 방출, 항균 및 항곰팡이, 수맥파 차단, 전자파 차단과, 천연무기물의 항균, 정전기방지, 전자파 차폐, 원적외선, 음이온을 발생시키는 효과를 지속시킬 수 있는 매우 유익한 발명이다.The present invention as described above solves the conventional disadvantage of coating the material on the synthetic fiber yarn by spinning the pure silver and natural inorganic materials as a composition of synthetic fiber yarns such as nylon, polypropylene, polyester and the life of the synthetic fiber yarn The unique effects of silver such as far infrared radiation, silver ion release, antibacterial and antifungal, water wave blocking, electromagnetic wave blocking, and antimicrobial, antistatic, electromagnetic wave shielding, far infrared rays and negative ions can be generated. It is a very beneficial invention.

Claims (4)

나노입자 20nm~200nm이며, 평균입도는 56nm, 90%입도 97nm 순은과, 나노입자 50nm~2㎛이하가 되는 음이온영구발생을 위한 천연해저광물질과, 나노입자 50nm~2㎛이하가 되는 원적외선영구발생을 위한 천연광물질(맥반석, 심성화강암, 옥석류 등)을 WT%로 15%-40%사이에 적정치 농축한 폴리에스터칩(Pellt) 또는 나일론, 폴리프로필렌칩과,Nanoparticles 20nm ~ 200nm, average particle size 56nm, 90% particle size 97nm pure silver, natural submarine minerals for negative ion generation that nanoparticles 50nm ~ 2㎛ or less, and far infrared permanent generation that nanoparticles 50nm ~ 2㎛ or less Polyester chips or nylon and polypropylene chips, in which natural minerals (such as elvan, deep granite, and jade) are concentrated in a WT% between 15% and 40%, 상기에 일반 폴리에스터칩(Pellt) 또는 나일론이나 폴리프로필렌칩을 WT%로 최종원사기준으로 종합복합체 WT가 1%-5%사이로 되는 것을 특징으로 하는 순은, 천연무기물 복합체를 이용한 합성섬유원사의 조성물.The composition of a pure silver, synthetic fiber yarn using a natural inorganic composite, characterized in that the composite polyester WT is between 1% -5% on the basis of the final yarn in the general polyester chip (Pellt) or nylon or polypropylene chip in WT% . 순은의 나노입자 (20nm~200nm와, 평균입도는 56nm, 90% 입도 97nm)와, 음이온영구발생을 위한 천연무기물은 해저광물과, 원적외선영구발생을 위한 천연무기물의 나노입자 (50nm~2㎛)의 복합체를 폴리에스터칩 마스터 배치제조과정에서 WT%로 15%-40%사이에 적정치 농축한 폴리레스터칩(Pellt) 또는 나일론이나 폴리프로필렌칩을 마련하는 단계와;Sterling silver nanoparticles (20nm ~ 200nm, average particle size: 56nm, 90% particle size 97nm), natural minerals for anion permanent generation, sea minerals, and nanoparticles of natural inorganics for far infrared permanent generation (50nm ~ 2㎛) Preparing a composite of polyester chips, and preparing a polyester chip or a nylon or polypropylene chip in which WT% is appropriately concentrated between 15% and 40% in a master batch manufacturing process; 상기 단계에서 일반 합성섬유칩(PET) 또는 나일론이나 폴리프로필렌칩을 WT%로 최종원사기준으로 종합복합체 WT가 1%-5%사이로 제조되도록 혼합용융방사하는 것을 특징으로 하는 순은,천연무기물 복합체를 이용한 합성섬유원사의 제조방법.In this step, pure silver, natural inorganic composites, characterized in that the mixed melt spinning so that the composite composite WT is produced between 1% -5% general synthetic fiber chip (PET) or nylon or polypropylene chip in WT% based on the final yarn Method for producing synthetic fiber yarns used. 제 2항에 있어서, 순은의 나노입자 (20nm~200nm와, 평균입도는 56nm, 90% 입도 97nm)와, 음이온영구발생을 위한 천연무기물은 해저광물과,원적외선영구발생을 위한 천연무기물의 나노입자 (50nm~2㎛)의 복합체를 WT%로 15-40%로 에틸렌글리칩 폴리에스터 컴파운드중합하여 방사하는 것을 특징으로 하는 순은,천연무기물 복합체를 이용한 합성섬유원사의 제조방법.The nanoparticles of claim 2, wherein the nanoparticles of pure silver (20nm ~ 200nm, the average particle size is 56nm, 90% particle size 97nm), the natural minerals for the anion permanent generation is a seabed mineral, nanoparticles of natural inorganics for the generation of far infrared permanent A method of producing synthetic fiber yarn using a pure silver, natural inorganic composite, characterized in that the (50nm ~ 2㎛) composite of WT% to 15-40% by ethylene glycol chip polyester polymerized spinning. 제 2항에 있어서, 순은의 나노입자 (20nm~200nm와, 평균입도는 56nm, 90% 입도 97nm)와, 음이온영구발생을 위한 천연무기물은 해저광물과,원적외선영구발생을 위한 천연무기물의 나노입자 (50nm~2㎛)의 복합체를 폴리에스터칩(건조) 또는 나일론이나 폴리프로필렌칩을 용융압출시 사이드피딩(Side Feeding)방법으로 방사하는 것을 특징으로 하는 특징으로 하는 순은,천연무기물 복합체를 이용한 합성섬유원사의 제조방법.The nanoparticles of claim 2, wherein the nanoparticles of pure silver (20nm ~ 200nm, the average particle size is 56nm, 90% particle size 97nm), the natural minerals for the anion permanent generation is a seabed mineral, nanoparticles of natural inorganics for the generation of far infrared permanent Synthesis using pure silver and natural inorganic composites, characterized in that the (50nm ~ 2㎛) composites are spun into polyester chips (dry) or nylon or polypropylene chips by side feeding method during melt extrusion Manufacturing method of fiber yarn.
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KR100786171B1 (en) * 2006-06-16 2007-12-21 (주)광진상사 A monofilament from antibiotic master batch and tray for food packing using the same
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Cited By (6)

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KR100532872B1 (en) * 2004-04-02 2005-12-01 주식회사 효성 Skin-core type and multi-functional complex fiber and manufacturing method thereof
KR100786171B1 (en) * 2006-06-16 2007-12-21 (주)광진상사 A monofilament from antibiotic master batch and tray for food packing using the same
KR100848775B1 (en) * 2006-11-08 2008-07-28 채수길 The method of ability plastics thread
KR101133106B1 (en) * 2009-04-17 2012-04-06 (주)토리다 Antimicrobial polyester fiber with a modified cross-section and preparation thereof
KR100925261B1 (en) * 2009-07-21 2009-11-05 이종두 Quantum Energy Occurrence Material Using Plastics Master Batch and Bedclothes Manufacturing Method
WO2021002679A1 (en) * 2019-07-02 2021-01-07 엘지전자 주식회사 Antibacterial composition, filter using same, and home appliance comprising filter

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