KR20040081093A - Tube shape sealing material and a process for preparation thereof - Google Patents

Tube shape sealing material and a process for preparation thereof Download PDF

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Publication number
KR20040081093A
KR20040081093A KR1020040063217A KR20040063217A KR20040081093A KR 20040081093 A KR20040081093 A KR 20040081093A KR 1020040063217 A KR1020040063217 A KR 1020040063217A KR 20040063217 A KR20040063217 A KR 20040063217A KR 20040081093 A KR20040081093 A KR 20040081093A
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South Korea
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resin
sealing material
tube
sealant
extrusion die
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KR1020040063217A
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Korean (ko)
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KR100566333B1 (en
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권태신
이민희
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헨켈홍성주식회사
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • C09K3/10Materials in mouldable or extrudable form for sealing or packing joints or covers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • C09K3/12Materials for stopping leaks, e.g. in radiators, in tanks

Abstract

PURPOSE: A tube-type sealing material sealing material and its preparation method are provided, to obtain a sealing material which is not effervescent, has suitably low ductility and malleability and can maintain solidity even when charged between the components of structure. CONSTITUTION: The tube-type sealing material comprises a cylindrical or polygonal tube(2) which comprises a thermoplastic synthetic resin and has a hollow(1); and a cohesive and adhesive sealant(3) which is coated on the surface of the tube uniformly. Preferably the thermoplastic synthetic resin is selected from the group consisting of a poly(vinyl chloride) (PVC) resin, a polyethylene (PE) resin, a polypropylene (PP) resin, a polyacryl resin, a poly(vinyl acetate) (PVA) resin, a polystyrene (PS) resin, an acrylonitrile-butadiene-styrene (ABS) resin, a polyamide resin and a polycarbonate resin.

Description

튜브형 실링재 및 그 제조방법{Tube shape sealing material and a process for preparation thereof}Tube shape sealing material and a process for preparation

본 발명은 차량, 건축물, 기계류등 각종 금속구조물의 부품사이의 간극에 충전하여 그 부품사이를 밀봉(실링), 점착, 접착하여 수밀(水密), 기밀(氣密), 방청, 완충효과를 얻게하거나 부품사이의 일정간극을 유지토록하여 방열, 내열, 방음, 차음 및 보온효과를 얻게하는 점착제겸 접착제가 원주면에 도포된 튜브형 실링재와 그 실링재를 제조하는 방법을 제공코저하는 것이다.The present invention fills the gap between parts of various metal structures, such as vehicles, buildings, and machinery, and seals, seals, and glues the parts to obtain a watertight, airtight, rustproof, and cushioning effect. Or to provide a method of manufacturing a tubular sealing material and a method of manufacturing the sealing material coated with a pressure-sensitive adhesive and adhesive on the circumferential surface to obtain a heat dissipation, heat resistance, sound insulation, sound insulation and heat insulation effect by maintaining a constant gap between the parts.

현재까지 차량을 비롯한 각종 금속구조물의 부품사이의 간극에 충전하여 밀봉(실링), 점착, 접착, 수밀, 기밀, 방청, 완충, 방열, 내열, 보온, 차음 또는 방음효과를 얻기위한 실링재(충전재)로는, 본 출원인이 2003.01.03자 선출원한 출원번호 제10-2003-0000397호 "내열 및 내한성을 갖는 불건성의 점착제겸 실런트 조성물"에 나타나 있는 바와같은 조성물을 실런트로 사용하여 그것만으로 원기둥형이나 모기둥형의 실링재를 만들어서 그것들을 직접 구조물 부품사이의 간극에 충전하도록된 실링재이거나, 원통형 폴리에틸렌 발포체를 심재로하여 그 표면에 상기 조성물로된 실런트를 도포한 것으로된 실링재(충전재)이거나, 현재 외국에서 수입되고 있는 폴리비닐클로라이드(PVC)를 원료로하여 원기둥이나 모기둥형으로 발포한 발포체의 둘레면에 점착성겸 접착성을 갖는 실런트를 도포한 것으로된 실링재이거나, 또는 공개특허공보 10-2004-002534(출원번호 제10-2002-0057273)호에 나타나 있는 바와같이, 에틸렌프로필렌디엔메틸렌(EPDM)고무를 원료로하여 전체가 원기둥형이나모기둥형으로 발포하거나 중앙에 중공부가 있는 원기둥형이나 모기둥형으로 발포한 튜브의 표면에, 나이론사, 폴리에스터사 또는 아라미드사중에서 선택된 섬유사로 직조한 편직물을 적층한 다음, 그위에서 그것을 감싸도록 점착성겸 접착성을 갖는 실런트를 도포한 것으로된 실링재가 있으나, 상기 선출원된 점착제겸 실런트 조성물로된 실런트만으로 성형된 기둥형 실링재는 그것을 사용시에 점착성 및 접착성은 유지되나 그것이 너무 연성이어서 흘러내리기 쉬워서 부품사이의 간극을 유지, 지탱하는 것이 어려운 결점이 있으며, 상기 기둥형의 폴리에틸렌 발포체를 심재로한 표면에 상기 실런트 조성물로된 실런트를 도포한 것으로된 실링재는 심재로서 사용된 기둥형 폴리에틸렌 발포체가 적도부근과 같은 120℃이상의 극열상황에서도 견딜 수 있는 내열성을 필요로하는 차량에 적용했을 경우에는 심재인 폴리에틸렌(PE)발포체가 내열성이 부족하여 120℃이상의 고온에서는 용융되어 흘러내리므로 실링재로서의 역할을 못하게 되는 결점이 있었고, 또한 상기에서 기둥형으로 발포된 PVC발포체의 둘레에 점착성겸 접착성을 갖는 실런트를 도포한 것으로된 실링재는 PVC 구조물 부품사이의 간극에 충전 적용시에 적절하게 압착되어 간극을 지탱할 수 있도록 적절하게 발포할 수 있는 기술이 부족하여 발포된 PVC발포체의 강도가 너무 약하거나 너무 강하여 그것으로 제조된 실링재를 구조물 부품사이의 간극에 적용시에 지지하기가 어렵거나 구조물 부품사이의 간극에 삽입하기가 어려운 결점이 있게되며, 따라서 그와같은 적용조건에 알맞게 발포되어 실링재로서 적절한 형태가 된 것으로는 현재 수입에만 의존하고 있고 또한 PVC발포체를 국내에서 생산한다고 하더라도 PVC를 발포하기 위해서는 발포제와 기타 첨가제를 첨가해야함은 물론 발포를 위한 가열조건이 까다로워서 제조공정이 복잡하고 재료가 많이 소요되어 원가상승의 요인이 되는 결점이 있었다.Sealing materials (fillers) to fill the gaps between parts of various metal structures, including vehicles, to obtain sealing, sealing, adhesion, watertightness, airtightness, rustproofing, shock absorbing, heat dissipation, heat insulation, sound insulation, or sound insulation As a sealant, a composition such as that described in the application number 10-2003-0000397, which is filed by the applicant as of January 03, 2003, is used as a sealant. It is a sealing material made by forming a pillar-shaped sealing material and filling them directly in the gap between structural parts, or a sealing material (filling material) obtained by applying a sealant of the composition on the surface of a cylindrical polyethylene foam as a core material, or currently in foreign countries. Adhesiveness and adhesion to the circumferential surface of the foam foamed in cylinder or mosquito form using imported polyvinyl chloride (PVC) as a raw material It is a sealing material coated with a sealant having a property, or as disclosed in Korean Patent Application Publication No. 10-2004-002534 (Application No. 10-2002-0057273), based on ethylene propylene diemethylene (EPDM) rubber On the surface of the tube foamed in the form of a cylinder or a mosque in its entirety, or in a cylinder or mosque with a hollow in the center, a knitted fabric made of nylon, polyester or aramid yarn is laminated. There is a sealing material which is coated with a sealant having adhesiveness and adhesiveness so as to surround it from above, but the columnar sealing material formed only with the sealant made of the above-described adhesive and sealant composition maintains its adhesiveness and adhesiveness when it is used, but it is too soft It is easy to flow down, and it is difficult to maintain and support the clearance between parts, and the pillar The sealing material of which the sealant of the said sealant composition was apply | coated to the surface made from the type | mold polyethylene foam core material requires the heat resistance which the columnar polyethylene foam used as a core material can withstand in extreme heat conditions of 120 degreeC or more, such as near an equator. When applied to a vehicle, the polyethylene (PE) foam, which is a core material, lacks heat resistance, and melts and flows down at a high temperature of 120 ° C. or higher, so that it does not function as a sealing material. Sealing material, which is coated with adhesive and adhesive sealant, is insufficiently compressed to adequately squeeze the gap between parts of the PVC structure when filling is applied to support the gap. Is too weak or too strong to seal the structure There are drawbacks to application in the gaps between the parts which are difficult to support or difficult to insert into the gaps between the structural parts. Therefore, foams that are suitable for such application conditions are now shaped appropriately as sealing materials and depend only on imports. In addition, even if PVC foam is produced in Korea, foaming agent and other additives must be added to foam the PVC, and the heating conditions for foaming are difficult, which leads to a cost increase due to the complicated manufacturing process and high material consumption. .

또한 상기한 기둥이나 튜브형의 EPDM의 발포체에 편직물과 실런트를 적층 도포한 것으로된 실링재는 그 구성중 발포체 표면에 적층한 편직물을 사용하지 않으면 EPDM의 연성과 전성이 너무 강하여 실링재로서의 역할을 할 수가 없을 뿐더라 그 결점을 보강하기위해서 편직물을 사용하게되면 여러종류의 원재료를 사용해야하고 제조공정이 복잡하고 까다로워서 원가상승요인이 됨은 물론 단시간에 양산이 어려운 결점이 있었다.In addition, the sealing material obtained by laminating and coating the knitted fabric and the sealant on the foam of the pillar or tube-shaped EPDM described above cannot be used as a sealing material because the ductility and malleability of the EPDM is too strong unless the knitted fabric laminated on the foam surface is used. In addition, the use of knitted fabrics to reinforce the shortcomings requires the use of various kinds of raw materials, and the manufacturing process is complicated and difficult, resulting in cost increase and short-term mass production.

본 발명은 상기한 바와같이, 점착성을 갖는 조성물로된 실런트만을 사용하여 만들어진 원기둥이나 모기둥형태의 실링재와 기둥형 폴리에틸렌 심재표면에 점착성겸 접착성을 갖는 실런트를 도포한 실리재나, 기둥형 PVC발포체 표면에 점착성겸 접착성을 갖는 실런트를 도포하여된 실링재나, 기둥형 EPDM발포체 표면에 나이론사, 폴리에스트사 또는 아라미드사로 직조된 편직물을 적층한 다음, 그것을 감싸는 점착성겸 접착성이 있는 실런트를 도포한 것으로된 실링재들의 결점을 개선하여 연성과 전성이 실링재로 사용하기에 알맞고 발포시키지 않아도 되며 별도의 보강제로서 편직물을 표면에 적층한 다음 실런트를 도포할 필요가 없이 직접 실링재 본체에 점착성겸 접착성을 띄는 실런트를 도포하기만 하면 실링재로 사용이 가능하고 더구나 중앙에는 중공부로된 튜브형태로되어 구조물의 부품사이의 간극에 적용시에 압착에의해 납작하게 수축되기가 쉬우면서 탄성도 우수하여 부품사이의 점착, 접착 및 간극 유지역할등이 모두 우수함은 물론, 원재료를 PVC를 비롯한 열가소성 수지만 사용하므로 단순한 원재료의 사용에 따른 재료 절감과 재활용이 가능한 장점이 있으며 발포시키지 않고 중공형 튜브만으로만 성형하면 되므로 제조공정의 단순화에 따른 제조원가 절감등의 효과와 특징이 있는 실링재와, 그 실링재를 간편하게 제조하는 제조방법을 제공코저하는 것으로서, 이를 첨부된 도면을 참조하면서 실례를 들어 상세히 설명하면 다음과 같다.As described above, the present invention provides a cylindrical or molar-type sealing material made of only a sealant made of a tacky composition and a silly material coated with a tacky and adhesive sealant on the surface of a column-shaped polyethylene core, or a columnar PVC foam. Laminating a woven fabric of nylon, polyester, or aramid yarn on the surface of the sealing material or the columnar EPDM foamed body, and then applying the adhesive and adhesive sealant covering the adhesive material. It improves the defects of the sealing materials, so that the ductility and malleability is suitable for use as the sealing material and does not need to be foamed, and it is adhesive and adhesive to the sealing material body directly without the need of laminating the knitted fabric on the surface as a separate reinforcement and then applying the sealant It can be used as a sealing material just by applying a sealant. It has a hollow tube shape, which is easily contracted by compression when applied to the gap between parts of the structure, and has excellent elasticity. It also has excellent adhesion, adhesion, and gap retention roles among the parts. As it uses only PVC and thermoplastic resins, it has the advantage of saving materials and recycling by using simple raw materials.Since only forming a hollow tube without foaming, it is a sealing material that has the effects and features such as reduction of manufacturing cost due to the simplification of the manufacturing process. And, to provide a manufacturing method for easily manufacturing the sealing material, it will be described in detail by way of example with reference to the accompanying drawings as follows.

도 1a 는 본 발명에 따른 튜브형 실링재의 일예시 사시도.Figure 1a is a perspective view of one example of a tubular sealing material according to the present invention.

도 1b 는 본 발명에 따른 튜브형 실링재의 타예시 사시도.Figure 1b is a perspective view of another example of the tubular sealing material according to the present invention.

도 2 는 본 발명에 따른 튜브형 실링재의 제조장치 요부 단면도.Figure 2 is a sectional view of the main portion of the manufacturing apparatus of the tubular sealing material according to the present invention.

도 3 은 본 발명에 따른 튜브형 실링재의 제조장치 요부 사시도.Figure 3 is a perspective view of the main portion of the manufacturing apparatus of the tubular sealing material according to the present invention.

*도면 중 주요부분에 대한 부호의 설명** Description of the symbols for the main parts of the drawings *

1 : 중공부 2,2'... : 튜브1: hollow part 2,2 '...: tube

3 : 실런트 4 : 이형지3: sealant 4: release paper

10 : 스크류 20 : 호퍼10: screw 20: hopper

30 : 히터 40 : 감속기30: heater 40: reducer

50 : 원료 60 : 압출다이50: raw material 60: extrusion die

70 : 투입구 80 : 배출구70: inlet 80: outlet

E : 압출기 M : 모터E: Extruder M: Motor

본 발명은, 폴리비닐클로라이드수지(PVC), 폴리에틸렌수지(PE), 폴리프로필렌수지(PP), 폴리아크릴수지, 초산비닐수지(PVAc), 폴리스틸렌수지(PS), ABS수지, 폴리아미드수지, 폴리카보네이트수지와 같은 열가소성 합성수지중에서 선택된 어느한가지의 열가소성 합성수지로된 원통형이나 다각형의 중공부(1)를 갖는 튜브(2)의 표면에 점착성 및 접착성을 갖는 실런트(3)를 균일하게 도포한 것으로 구성되는 실링재로서, 이 실링재는 제조와 동시에 그 표면을 이형지(4)로 보호하였다가 실링재로 사용시에 이형지(4)는 제거하고 구조물 부품사이의 간극에 적용하면 된다.The present invention, polyvinyl chloride resin (PVC), polyethylene resin (PE), polypropylene resin (PP), polyacrylic resin, vinyl acetate resin (PVAc), polystyrene resin (PS), ABS resin, polyamide resin, poly Consists of uniformly applying a sealant (3) having adhesiveness and adhesion to the surface of the tube (2) having a cylindrical or polygonal hollow portion (1) made of any one thermoplastic synthetic resin selected from thermoplastic synthetic resins such as carbonate resin. As a sealing material to be used, this sealing material may be manufactured and protected at the same time as the surface of the release paper 4, and then, when used as a sealing material, the release paper 4 may be removed and applied to the gap between the structural parts.

이상과 같이 구성되는 본 발명 실링재는 열가소성 합성수지로되어 있으면서 중공형 튜브(2)로서 발포되지 않은 성형물이기 때문에 각종 구조물 부품사이에 적용시에 그 간극을 유지시켜주는 힘이 강하게되고 구조물 부품사이의 간극에 충전된 후에는 튜브가 압착되면서 간극에 끼어있게되어 원형으로 복귀시키려는 힘에의해부품사이의 점착력과 접착력을 배가시켜주는 탁월한 효과를 얻게 된다.Since the sealing material of the present invention constituted as described above is a molded product which is made of thermoplastic synthetic resin and is not foamed as a hollow tube (2), the force for maintaining the gap when applied between various structural parts becomes strong, and the gap between structural parts After being filled in, the tube is crimped and pinched in the gaps, resulting in an excellent effect of doubling the adhesion and adhesion between parts by the force to return to a circular shape.

또한 본 발명 실링재는 제조공정이 간편한 특징이 있는 것으로서 이를 상세히 설명하면 다음과 같다.In addition, the sealing material of the present invention is characterized as having a simple manufacturing process as follows.

즉 스크류(10)가 내장되고 외주면에 히터(30)가 외삽된 압출기(E)를 히터(30)로 가열하면서 압출기 상부의 호퍼(20)를 통하여 점착성겸 접착성 실런트 조성용 원료(50)를 투입하여 가열용융되게 함과 동시에 감속기(40)가 부착된 모터(M)의 감속작동에 의해 스크류(10)를 회전시켜 압출다이(60)를 통하여 가열용융된 원료(50)를 연속 압출시키면서 상기 압출기(E)와 직각방향으로 설치된 압출다이(60)의 일측 투입구(70)를 통하여 열가소성 합성수지로 사출성형된 중공부(1)를 갖는 다수개의 튜브(2)(2')...를 공급하여 압출다이(60)의 타측 배출구(80)로 연속 퇴출시키므로서 튜브(2)가 압출다이(60)속을 통과하는동안 스크류에 의해 압출다이(60)로 배출되는 용융실런트(3)속을 튜브(2)가 통과하게되어 이때 튜브(2)의 표면에 실런트(3)가 자연적으로 도포되게되고 실런트(3)가 상온에서 쉽게 냉각경화되므로서 튜브(2)표면에 점착성겸 접착성을 갖는 실런트(3)가 도포된 실링재를 얻게 되는 것이다.That is, the raw material 50 for the adhesive and adhesive sealant composition is introduced through the hopper 20 on the top of the extruder while the extruder E having the screw 10 embedded therein and the heater 30 extrapolated to the outer circumferential surface is heated by the heater 30. By rotating the screw 10 by the deceleration operation of the motor M to which the reducer 40 is attached, thereby simultaneously extruding the heated and melted raw material 50 through the extrusion die 60. By supplying a plurality of tubes (2) (2 ') having a hollow portion (1) injection molded into a thermoplastic synthetic resin through the one side inlet 70 of the extrusion die 60 installed at right angles to (E) The tube is passed through the melt sealant 3 discharged to the extrusion die 60 by a screw while the tube 2 passes through the extrusion die 60 while being continuously discharged to the other outlet 80 of the extrusion die 60. (2) is passed through and the sealant (3) is naturally applied to the surface of the tube (2) and the sealant (3) It is easy to obtain a sealing material coated with a sealant 3 having adhesiveness and adhesiveness on the surface of the tube 2 while being easily cured at room temperature.

이상과 같이 구성된 본 발명 튜브형 실링재는 발포성이 아니고 연성과 전성도 적당한 정도로 낮아서 구조물 부품사이에 충전하더라도 견고성이 유지되어 부품의 간극을 지속적으로 유지하게되는 효과가 있고, 따라서 실링재의 실런트(3)에의해 그 실링재가 충전되어 접촉된 부품들의 점착성 및 접착성을 극히 양호하게하는 효과가 있으며, 또한 본 발명 실링재 제조방법은 실런트(3)원료를 용융 압출기(E)에의해 용융공급하면서 열가소성 합성수지 튜브(2)를 통과시켜 튜브(2)의 표면에 실런트(3)가 도포되게하므로서 간편하고 균일하게 튜브(2)표면에 실런트가 도포된 실링재를 얻는 효과도 있는 것이다.The tubular sealing material of the present invention configured as described above is not foamable and has low ductility and malleability to a moderate degree, so that the hardness is maintained even when filling between structural parts, and thus the gap of the parts is continuously maintained. The sealing material is filled with the effect of making the adhesion and adhesion of the parts in contact with the extremely good, and also the sealing material manufacturing method of the present invention, while supplying the sealant (3) raw material by the melt extruder (E) thermoplastic synthetic resin tube ( By passing the sealant 3 on the surface of the tube 2 through 2), it is also effective to obtain a sealing material coated with the sealant on the surface of the tube 2 simply and uniformly.

Claims (3)

열가소성 합성수지로된 원통형이나 다각형의 중공부(1)를 갖는 튜브(2)의 표면에 점착성 및 접착성을 갖는 실런트(3)를 균일하게 도포하는 것으로 구성됨을 특징으로하는 튜브형 실링재.A tubular sealing material, characterized by uniformly applying a sealant (3) having adhesiveness and adhesion to a surface of a tube (2) having a cylindrical or polygonal hollow portion (1) made of thermoplastic synthetic resin. 제1항에 있어서, 열가소성 합성수지로는 폴리비닐클로라이드수지(PVC), 폴리에틸렌수지(PE), 폴리프로필렌수지(PP), 폴리아크릴수지, 초산비닐수지(PVAc), 폴리스틸렌수지(PS), ABS수지, 폴리아미드수지, 폴리카보네이트수지와 같은 열가소성 수지중에서 선택됨을 특징으로하는 튜브형 실링재.The method of claim 1, wherein the thermoplastic synthetic resin is polyvinyl chloride resin (PVC), polyethylene resin (PE), polypropylene resin (PP), polyacrylic resin, vinyl acetate resin (PVAc), polystyrene resin (PS), ABS resin And a thermoplastic resin such as polyamide resin and polycarbonate resin. 제1항에 있어서, 튜브(2)의 표면에 실런트(3)를 도포하여된 실링재는, 스크류(10)가 내장되고 외주면에 히터(30)가 외삽된 압출기(E)를 히터(30)로 가열하면서 압출기 상부의 호퍼(20)를 통하여 점착성겸 접착성 실런트 조성용 원료(50)를 투입하여 가열용융되게 함과 동시에 감속기(40)가 부착된 모터(M)의 감속작동에 의해 스크류(10)를 회전시켜 압출다이(60)를 통하여 가열용융된 원료(50)를 연속 압출시키면서 상기 압출기(E)와 직각방향으로 설치된 압출다이(60)의 일측 투입구(70)를 통하여 열가소성 합성수지로 사출성형된 중공부(1)를 갖는 다수개의 튜브(2)(2')...를 공급하여 압출다이(60)의 타측 배출구(80)로 연속 퇴출시키므로서 튜브(2)가 압출다이(60)속을 통과하는동안 스크류에 의해 압출다이(60)로 배출되는 용융실런트(3)속을 튜브(2)가 통과하게되어 이때 튜브(2)의 표면에 실런트(3)가 자연적으로 도포되게되고 튜브(2)표면에 도포된 실런트(3)가 상온에서 쉽게 냉각경화되게하는 방법으로 제조함을 특징으로하는 튜브형 실링재 제조방법.The sealing material of Claim 1 which apply | coated the sealant 3 to the surface of the tube 2, The extruder E with which the screw 10 was built-in and the heater 30 extrapolated to the outer peripheral surface by the heater 30 is carried out. While heating, the raw material 50 for the adhesive and adhesive sealant composition is introduced through the hopper 20 on the extruder to be heated and melted, and at the same time, the screw 10 is operated by the deceleration operation of the motor M to which the reducer 40 is attached. Injection molding into a thermoplastic synthetic resin through the inlet 70 of one side of the extrusion die 60 installed at right angles with the extruder E while continuously extruding the heated and melted raw material 50 through the extrusion die 60 by rotating the The tube 2 is fed into the extrusion die 60 by supplying a plurality of tubes 2 (2 ') ... having a hollow part 1 and continuously exiting to the other outlet 80 of the extrusion die 60. While passing through the tube 2 passes through the melt sealant 3 discharged to the extrusion die 60 by the screw at this time Bracket (2) on the surface sealant (3) and to be naturally applied to the tube (2) the sealant method for producing a tubular sealing member, characterized by (3) is produced by a method that causes hardening easily cooled at room temperature applied to the surface of the.
KR1020040063217A 2004-08-11 2004-08-11 Tube shape sealing material and a process for preparation thereof KR100566333B1 (en)

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