KR20040079263A - A Water Softer Containing Silver Antibacterial Ceramic Ball - Google Patents

A Water Softer Containing Silver Antibacterial Ceramic Ball Download PDF

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KR20040079263A
KR20040079263A KR1020030014348A KR20030014348A KR20040079263A KR 20040079263 A KR20040079263 A KR 20040079263A KR 1020030014348 A KR1020030014348 A KR 1020030014348A KR 20030014348 A KR20030014348 A KR 20030014348A KR 20040079263 A KR20040079263 A KR 20040079263A
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water
exchange resin
ion exchange
ceramic ball
silver
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KR1020030014348A
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Korean (ko)
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정승훈
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주식회사 승광
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Publication of KR20040079263A publication Critical patent/KR20040079263A/en

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/42Treatment of water, waste water, or sewage by ion-exchange
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/50Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/02Odour removal or prevention of malodour

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Treatment Of Water By Ion Exchange (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

PURPOSE: A water softener containing silver based antibacterial ceramic balls is provided to obtain water that is safe to the human body and beneficial to health by having functions of water softening, malodor removing and disinfection treatment. CONSTITUTION: In a water softener for softening water as city water is passing through water softening can(10) in which ion exchange resin(20) is filled, the water softener containing silver based antibacterial ceramic balls is characterized in that 3 to 20 wt.% of silver based antibacterial ceramic balls(30) having superior deodorizing and sterilizing effects and size of 1 to 10 mm for 100 wt.% of the ion exchange resin is injected into the water softening can, wherein the silver based antibacterial ceramic balls are injected into an upper part of the ion exchange resin inside the water softening can, and wherein a mixture of the silver based antibacterial ceramic balls and the ion exchange resin is filled in the water softening can.

Description

은계 항균 세라믹볼을 함유한 연수기 {A Water Softer Containing Silver Antibacterial Ceramic Ball}Water Softer Containing Silver Antibacterial Ceramic Ball

본 발명은 수돗물의 연수기능 뿐만 아니라 탈취 및 살균기능을 갖는 연수기에 관한 것으로, 보다 상세하게는 기존 연수기의 한계인 수돗물을 단순히 목욕용수 또는 세척수나 보일러수 정도로 연수시키는 수준에서 벗어나 연수기능 뿐만 아니라 악취 제거 및 살균 처리까지도 가능한 은계 항균 세라믹볼이 함유된 연수기에 관한것이다.The present invention relates to a softener having a deodorizing and sterilizing function as well as a softening function of tap water, and more specifically, the tap water, which is the limitation of the conventional softener, is simply not watered as a bath water or a washing water or a boiler water. The present invention relates to a water softener containing silver antibacterial ceramic balls that can be removed and sterilized.

인간이 마실 음용수를 재생하는 정수기와 달리, 연수기는 인체 피부에 민감한 금속성 물질과 목욕시 불쾌감을 내는 석회성분을 포함하여 기타 경수 성분을 통상 연수통의 이온교환수지를 통해 제거할 수 있어, 온천욕을 하는 것처럼 부드럽고 깨끗한 물을 재생시킬 수 있다.Unlike water purifiers that regenerate drinking water for humans, water softeners can remove other hard water components, including metallic substances sensitive to human skin and lime components that are unpleasant when bathing, through ion exchange resins in soft water baths. You can regenerate soft, clean water as you do.

즉, 불순물 중 이온상으로 존재하는 것을 연수통의 이온교환수지로 용이하게 제거할 수 있는데, 이온의 대표적인 것은 칼슘, 마그네슘, 나트륨, 중탄산, 황산, 염소, 이산화규소, 철, 망간 등으로 조성된 물을 식염수로 재생한 연수통의 양이온교환수지에 통과시키면, 경수의 원인인 양이온 중 많은 비율을 차지하고 선택성이 큰 마그네슘, 칼슘이온 등이 양이온교환수지의 나트륨이온과 교환되어 원하는 연수를 얻을 수 있다.In other words, the impurities present in the ionic phase can be easily removed by the ion exchange resin in the soft water tank. The representative ions are composed of calcium, magnesium, sodium, bicarbonate, sulfuric acid, chlorine, silicon dioxide, iron, and manganese. When water is passed through a cation exchange resin in a soft water tank regenerated with saline, magnesium, calcium ions, etc., which take up a large proportion of the cations that cause hard water and have high selectivity, are exchanged with sodium ions of the cation exchange resin to obtain desired soft water. .

그러나 기존의 연수기의 경우 전처리필터에서 잔류염소를 제거하기는 하나, 전처리필터에 제거되지 못한 미세한 유기물이 이온교환수지가 채워진 연수기의 내통인 연수통에 쌓이면서 부패되기 쉽고, 따라서 연수처리가 이루어지는 연수통 자체에서 유기물 부패에 의해 악취가 발생될 뿐만 아니라 미생물 번식의 원천이 된다는 문제점이 있었다.However, in the case of the conventional water softener, the residual chlorine is removed from the pretreatment filter, but the fine organic matter which is not removed from the pretreatment filter is easily accumulated in the soft water tank, which is the inner cylinder of the water softener filled with ion exchange resin, and thus the soft water treatment tank Odor is not only generated by the decay of organic matter in itself, there was a problem that becomes a source of microbial propagation.

이에 본 발명은 이러한 사정을 감안하여 개발된 것으로, 기존 연수기의 한계인 수돗물을 단순히 목욕용수 또는 세척수나 보일러수 정도로 연수시키는 수준에서벗어나, 연수기능 뿐만 아니라 악취 제거 및 살균 처리까지도 가능하여 인체에 안전하고 건강에도 유익한 물을 사용할 수 있는 은계 항균 세라믹볼이 함유된 연수기를 제공함에 그 목적이 있다.Therefore, the present invention was developed in view of such circumstances, and it is possible to remove tap water, which is the limit of the existing water softener, in the water level of bath water or washing water or boiler water. The purpose of the present invention is to provide a water softener containing silver-based antibacterial ceramic balls that can use water beneficial to health.

도 1a 및 도 1b는 본 발명에 따라 항균 세라믹볼을 이온교환수지 상층과 투입한 상태와 이온교환수지와 함께 혼합 투입한 상태의 연수기의 연수통 개략도.Figure 1a and Figure 1b is a schematic view of the water softener of the water softener in a state in which the antimicrobial ceramic ball is added with the ion exchange resin upper layer and mixed with the ion exchange resin according to the present invention.

도 2는 본 발명에 적용되는 항균 세라믹볼의 종류별 살균력 실험그래프.Figure 2 is a graph of the sterilization power of the antimicrobial ceramic ball applied to the present invention.

* 도면의 주요부분에 대한 부호의 설명 *Explanation of symbols on the main parts of the drawings

10 : 연수통 20 : 이온교환수지10: soft water tank 20: ion exchange resin

30 : 은계 항균 세라믹볼30: silver antibacterial ceramic ball

상기의 목적을 달성하기 위한 본 발명의 연수기는 이온교환수지가 채워진 연수통을 통해 수돗물이 통과되면서 연수처리되는 연수기에 있어서, 탈취 및 살균효과가 우수한 1-10㎜ 크기의 은계 항균 세라믹볼을 상기 이온교환수지 100wt%에 대해 3-20wt%의 첨가비율로 함께 상기 연수통에 투입된 것을 특징으로 한다.The water softener of the present invention for achieving the above object is a soft water treatment machine which is treated with tap water through a soft water tank filled with an ion exchange resin, the deodorizing and sterilizing effect of the 1-10 mm size of the antimicrobial ceramic ball It is characterized in that it is added to the soft water tank together with the addition ratio of 3-20wt% relative to 100wt% of the ion exchange resin.

특히 은계 항균 세라믹볼은 연수통 내의 이온교환수지 상부에 투입되거나, 또는 연수통 내의 이온교환수지와 함께 혼합 충진된 것을 특징으로 한다.In particular, the silver-based antibacterial ceramic ball is added to the upper portion of the ion exchange resin in the soft water container, or is mixed and filled with the ion exchange resin in the soft water container.

이하, 본 발명에 따라 탈취 및 살균효과가 우수한 은계 항균 세라믹볼을 연수통에 이온교환수지와 함께 일정비율로 투입시킨 연수기의 바람직한 실시예를 첨부도면을 참조하여 상세히 설명한다.Hereinafter, with reference to the accompanying drawings, a preferred embodiment of a softener in which a silver-based antimicrobial ceramic ball having excellent deodorizing and sterilizing effects is introduced into a soft water tank together with an ion exchange resin at a predetermined ratio.

도 1a 및 도 1b는 본 발명에 따라 은계 항균 세라믹볼(30)을 연수통(10)의 이온교환수지(20) 상층과 투입한 상태 및 상기 이온교환수지(20)와 함께 혼합 투입한 상태의 연수통(10) 구조를 개략적으로 도시한 것이며, 도 2는 본 발명에 적용되는 은계 항균 세라믹볼(30)의 종류별 살균력 실험결과에 대한 그래프를 도시한 것이다.1A and 1B illustrate a state in which the silver-based antimicrobial ceramic ball 30 is added to the upper layer of the ion exchange resin 20 of the soft water container 10 and mixed with the ion exchange resin 20 according to the present invention. The structure of the soft water container 10 is schematically illustrated, and FIG. 2 shows a graph of a sterilization force test result for each type of silver-based antibacterial ceramic ball 30 applied to the present invention.

잘 알다시피 누구나 젊고 건강하면 피부의 살균력이 높으나 피로로 저항력이약해지면 피부의 살균력이 저하되면서 감기나 질병에 감염되기 쉽다. 따라서 항균제를 적절하게 이용하면 만성피로에 상당한 효과를 발휘할 수 있는데, 특히 화장실 악취나 자동차 에어컨 악취, 빌딩 특유의 악취 등에 항균제를 사용하여 세균의 대사 악취나 세균에 의한 분해 생성물이 악취를 발생하는 경우가 적지 않으므로 이때도 항균제가 필요하다.As everyone knows, young and healthy people have high skin disinfection, but when the resistance to fatigue is weakened, the skin's sterilization power is lowered and it is easy to be infected with cold or disease. Therefore, the proper use of antimicrobial agents can have a significant effect on chronic fatigue. Especially, when an antibacterial agent is used for odors in toilets, car air conditioners, buildings, etc. Since there is not a small amount of antibacterial agent is required at this time.

특히, 항균제로서 은계 항균 세라믹볼(30)을 혼합하여 사용함으로서 유기물 부패에 의한 냄새의 소취와 미생물에 대한 살균력 및 항균력을 높일 수 있으며, 본 발명에서는 이러한 은계 항균 세라믹볼(30)을 연수기에 맞게 1-10㎜ 크기로 형성시켜 이를 연수통(10)의 이온교환수지(20)에 대해 적정비율로 첨가시킴으로서 기존의 연수기에서 기대하기 힘든 연수처리되는 수돗물의 탈취 및 살균효과를 제공할 수 있다.In particular, by using a combination of the silver antimicrobial ceramic ball 30 as an antimicrobial agent can increase the deodorization of the odor due to organic decay and microbial and antimicrobial power to microorganisms, in the present invention to match the silver antimicrobial ceramic ball 30 to the water softener Forming a size of 1-10mm by adding it in an appropriate ratio for the ion exchange resin 20 of the water softener 10 can provide a deodorizing and sterilizing effect of the tap water that is difficult to expect in the conventional water softener.

즉, 본 발명에 사용되는 무기계 항균제인 은계 항균 세라믹볼은 세균에 대해 항균효과가 우수하고 안정성이 높으며, 효과의 지속성이 우수하고 반영구적으로 지속되면서 비교적 고온에서도 사용할 수 있어 냉,온수를 함께 연수처리하는 연수기에 적용하는데 아무런 문제가 없다.In other words, the silver antimicrobial ceramic ball, which is an inorganic antimicrobial agent used in the present invention, has excellent antibacterial effect and high stability against bacteria, and can be used at relatively high temperatures while maintaining excellent effects and lasting semi-permanently. There is no problem applying to the water softener.

(실험예 1) 은계 항균 세라믹볼 자체 실험Experimental Example 1 Silver-based Antibacterial Ceramic Ball Experiment

우선, 은계 항균 세라믹볼 100g을 연수통(10)에 적용시키지 않고 자연상태에서 미생물 배양액 자체의 변화를 관찰하는 실험을 하였다.First, the experiment was performed to observe the change in the microbial culture itself in the natural state without applying 100g of the silver-based antibacterial ceramic ball to the soft water tank (10).

즉, 자연상태 및 은계 항균 세라믹볼(30) 100g을 사용한 각각의 검체에 대해미생물, 미생물(대장균군)을 인위적 배양한 배양액 1ℓ를 투입하고, 각각의 검체를 암소에서 24시간 방치한 후 검액을 채수한다. 그리고 인큐베이터(Incubator)에서 37±0.5℃온도로 48±2시간 가량 배양하여 자연상태 및 은계 항균 세라믹볼(30)에서의 미생물에 대한 살균력 및 발생 억제력을 수질오염공정시험법에 의거 확인하였으며, 실험결과는 아래의 표 1과 같다.That is, 1 l of culture medium artificially cultured microorganisms and microorganisms (E. coli) was added to each specimen using 100 g of natural and silver antimicrobial ceramic balls 30, and each specimen was left in a cow for 24 hours, and then Take it. Incubator was incubated at 37 ± 0.5 ° C. for 48 ± 2 hours to determine the bactericidal and suppressive effects of microorganisms in natural and silver antimicrobial ceramic balls (30) based on the water pollution process test method. The results are shown in Table 1 below.

자연상태Natural state 은계 항균 세라믹볼(100g)Silver Antibacterial Ceramic Ball (100g) 초기Early 2.4×103 2.4 × 10 3 24시간 경과24 hours 2.7×103 2.7 × 10 3 66 살균력(%)Sterilization (%) 증가increase 99.7599.75

(실험예 2) 연수기의 이온교환수지와 함께 투입시켜 살균력 실험Experimental Example 2 Test of Sterilization by Injecting with Ion Exchange Resin of Water Softener

각각의 검체에 미생물을 인위적으로 배양하여 통수시킨 후 24시간 정체시키며, 이때 배양액은 초기에 1ℓ이고 방류후에는 2ℓ를 투입한다. 각각의 검체에서 연수기 내통인 연수통(10)에 들어있는 수돗물을 자연하중에 의해 방류시켰다.Each sample is incubated with artificial microorganisms and passed through for 24 hours. At this time, the culture solution is initially 1 L and 2 L is added after discharge. In each sample, the tap water contained in the soft water tank (10), which is an internal water softener, was discharged by natural load.

그리고 초기 500㎖를 방류후 검액을 채수하고, 인큐베이터에서 37±0.5℃온도로 48±2시간 가량 배양하여 미생물에 대한 살균력 및 발생 억제력을 역시 수질오염공정시험법에 의거 확인하였으며, 그 실험결과는 아래의 표 2와 같다.After discharging the initial 500ml, the sample solution was collected and incubated for 48 ± 2 hours at 37 ± 0.5 ℃ in the incubator, and the bactericidal power and the inhibition of microorganism were also confirmed by the water pollution process test method. Table 2 below.

연수기에 적용후 살균력 실험Sterilization test after application to water softener 이온교환수지Ion exchange resin 이온교환수지 + 항균 세라믹볼(200g)Ion Exchange Resin + Antibacterial Ceramic Ball (200g) 상층에 투입Commit to the upper tier 혼합 충진Mixed filling 초기Early 3.4×106 3.4 × 10 6 24시간 경과24 hours 7.4×105 7.4 × 10 5 2.3×105 2.3 × 10 5 7.0×104 7.0 × 10 4 살균력(%)Sterilization (%) 78.2478.24 93.2493.24 97.9497.94

이온교환수지(20)와 함께 연수통(10)에 투입되는 은계 항균 세라믹볼(30)의 투입량을 계산하면, 이온교환수지 100㎖ = 86.7g이므로 5ℓ= 4,340g이며, 항균 세라믹볼의 무게 = 200g이므로 결과적으로 이온교환수지량에 대한 항균 세라믹볼의 투입량은 (200g ÷4,340g)×100 = 4.6% ≒ 5%(w/w) ≒ 5wt%이다.Calculating the amount of the silver-based antimicrobial ceramic ball 30 to be introduced into the soft water tank 10 together with the ion exchange resin 20, the ion exchange resin 100ml = 86.7g, so 5L = 4,340g, the weight of the antibacterial ceramic ball = As a result, the amount of antimicrobial ceramic balls added to the amount of ion exchange resin was (200g ÷ 4,340g) x 100 = 4.6% 5% (w / w) 5wt%.

위의 실험예 1,2를 통해 알 수 있듯이, 은계 항균 세라믹볼(30)을 함유하지 않는 자연상태의 경우 초기의 살균력이 조금은 있는 것으로 나타났으나, 이는 이온교환수지(20)의 공극에 의한 초기의 일시적인 감소 현상 및 온도의 영향으로 대장균군이 활성화되지 못해 나타난 현상으로, 시간이 경과함에 따라 이온교환수지(20)의 공극에 기생하면서 유입되는 유기물을 영양분으로 하여 점차 증가할 것으로 추정됨을 알 수 있다.As can be seen through Experimental Examples 1 and 2 above, in the case of the natural state does not contain the silver-based antimicrobial ceramic ball 30, there was a slight initial sterilization power, but this is due to the pores of the ion exchange resin (20) It is a phenomenon that E. coli was not activated due to the temporary decrease in temperature and the influence of temperature at the early stage, and it is estimated that as time passes, the organic substances introduced while parasitic in the pores of the ion exchange resin 20 will increase gradually as nutrients. Can be.

따라서 실험에 사용된 은계 항균 세라믹볼(30)은 항균력 및 소취력이 이미 인증된 상태이며, 이온교환수지(20)와 혼합하여 연수기의 연수통(10)에 적용시 살균력은 아래의 표 3과 같이 약 90%로 우수하게 나타난 것을 알 수 있었다.Therefore, the antimicrobial and deodorizing power of the silver-based antimicrobial ceramic ball 30 used in the experiment has already been certified, and the sterilizing power when applied to the soft water tank 10 of the water softener by mixing with the ion exchange resin 20 is shown in Table 3 below. As can be seen that about 90% was excellent.

자체 실험Self experiment 연수통에 적용Applied to soft water tank 상부에 투입Commitment to the upper part 혼합 충진Mixed filling 제거율(%)% Removal 99.7599.75 93.2493.24 97.9497.94

즉, 항균력 및 살균력을 보다 향상시키기 위해서는 이온교환수지(20)와 혼합하여 연수기의 연수통(10)에 투입하는 것이 바람직한 것을 알 수 있다.That is, in order to further improve the antimicrobial and bactericidal power, it can be seen that it is preferable to mix the ion exchange resin 20 and to put it in the soft water tank 10 of the water softener.

위의 실험결과는 은계 항균 세라믹볼(30)의 초기 항균력만을 실험한 결과로 검체 지름은 5㎜ 이었으며, 특히 은계 항균 세라믹볼(30)의 크기가 커지는 경우 동일 무게에 대한 표면적이 감소하여 살균력이 저하되면서 연수통(10)의 하부에 몰리는 현상이 우려된다.The above test results are the results of the experiment of the initial antimicrobial power of the silver-based antimicrobial ceramic ball 30, the sample diameter was 5mm, especially when the size of the silver-based antimicrobial ceramic ball 30 is large, the surface area for the same weight is reduced, the sterilization power While deteriorating, the phenomenon of being driven to the lower part of the soft water container 10 is concerned.

따라서 은계 항균 세라믹볼(30)의 투입량은 3-20wt% 내외로 적용시킬 수 있으나, 살균력에서는 아래의 표 4에서 보는 바와 같이 5-10wt%의 첨가범위에서 가장 효과적인 것으로 나타났으며, 이는 첨가되는 은계 항균 세라믹볼(30)가 5wt%이면 살균력이 떨어지고 20wt% 이상이면 살균력도 떨어지면서 가격도 비싸므로 실용적이지 못해 결과적으로 이온교환수지(20)에 대해 은계 항균 세라믹볼(30)을 5-15wt% 범위로 첨가시키는 것이 바람직하다고 판단된다.Therefore, the dosage of the silver-based antibacterial ceramic ball 30 can be applied to about 3-20wt%, but the sterilization power was shown to be most effective in the addition range of 5-10wt% as shown in Table 4 below, which is added If the silver antibacterial ceramic ball 30 is 5wt%, the sterilization power is lowered. If the antimicrobial ceramic ball 30 is more than 20wt%, the sterilization power is also low and the price is not practical. As a result, 5-15wt of the silver antibacterial ceramic ball 30 with respect to the ion exchange resin 20 is obtained. It is judged that it is desirable to add it in% range.

투입량(wt%)Input amount (wt%) 33 55 1010 1515 2020 초기Early 2.8×104 2.8 × 10 4 24시간 경과24 hours 3.2×103 3.2 × 10 3 1.1×103 1.1 × 10 3 1.1×103 1.1 × 10 3 1.2×103 1.2 × 10 3 1.4×103 1.4 × 10 3 실균력(%)Actual strength (%) 88.688.6 96.196.1 96.196.1 95.795.7 95.095.0

이상에서 설명한 바와 같이 본 발명에 따른 은계 항균 세라믹볼이 함유된 연수기에 의하면, 이온교환수지에 대해 적정크기와 비율로 은계 항균 세라믹볼을 첨가시킴으로서 기존 연수기의 한계인 수돗물을 단순히 목욕용수 또는 세척수나 보일러수 정도로 연수시키는 수준에서 벗어나 연수기능 뿐만 아니라 악취 제거 및 살균 처리까지도 가능하여 인체에 유익한 기능수 수준의 물이 제공될 수 있을 것으로 기대된다.As described above, according to the water softener containing the silver antimicrobial ceramic ball according to the present invention, by adding the silver antimicrobial ceramic ball in an appropriate size and proportion to the ion exchange resin, tap water, which is the limit of the conventional softener, is simply used for bathing water or washing water or the like. It is expected that water of functional water level, which is beneficial to the human body, can be provided by not only softening water, but also removing odor and sterilizing.

Claims (3)

이온교환수지(20)가 채워진 연수통(10)을 통해 수돗물이 통과되면서 연수처리되는 연수기에 있어서,In the water softener in which the tap water is passed through the soft water tank 10 filled with the ion exchange resin 20, the soft water is treated. 탈취 및 살균효과가 우수한 1-10㎜ 크기의 은계 항균 세라믹볼(30)을 상기 이온교환수지(20) 100wt%에 대해 3-20wt%의 첨가비율로 함께 상기 연수통(10)에 투입된 것을 특징으로 하는 은계 항균 세라믹볼이 함유된 연수기.1-10 mm sized antimicrobial ceramic ball 30 having excellent deodorizing and sterilizing effect is added to the soft water container 10 together at an addition ratio of 3-20 wt% to 100 wt% of the ion exchange resin 20. Water softener containing silver antibacterial ceramic ball. 제 1항에 있어서,The method of claim 1, 상기 은계 항균 세라믹볼(30)은 연수통(10) 내의 이온교환수지(20) 상부에 투입된 것을 특징으로 하는 은계 항균 세라믹볼이 함유된 연수기.The silver-based antimicrobial ceramic ball 30 is a softener containing silver-based antimicrobial ceramic ball, characterized in that it is injected into the upper portion of the ion exchange resin 20 in the soft water container (10). 제 1항에 있어서,The method of claim 1, 상기 은계 항균 세라믹볼(30)은 연수통(10) 내의 이온교환수지(20)와 함께 혼합 충진된 것을 특징으로 하는 은계 항균 세라믹볼이 함유된 연수기.The silver-based antimicrobial ceramic ball 30 is a softener containing silver-based antibacterial ceramic ball, characterized in that the mixture is filled with the ion exchange resin (20) in the soft water tank (10).
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102015014616A1 (en) 2015-11-12 2017-05-18 Diehl Metering Gmbh Ion exchanger for the treatment of water

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102015014616A1 (en) 2015-11-12 2017-05-18 Diehl Metering Gmbh Ion exchanger for the treatment of water

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