KR20040069720A - Methods of coating on rods and rods therefor - Google Patents
Methods of coating on rods and rods therefor Download PDFInfo
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- KR20040069720A KR20040069720A KR1020030006243A KR20030006243A KR20040069720A KR 20040069720 A KR20040069720 A KR 20040069720A KR 1020030006243 A KR1020030006243 A KR 1020030006243A KR 20030006243 A KR20030006243 A KR 20030006243A KR 20040069720 A KR20040069720 A KR 20040069720A
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- titanium
- coating
- coated
- fishing
- fishing rod
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- 238000000576 coating method Methods 0.000 title claims abstract description 98
- 239000011248 coating agent Substances 0.000 title claims abstract description 88
- 238000000034 method Methods 0.000 title claims abstract description 20
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 69
- 239000010936 titanium Substances 0.000 claims abstract description 69
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 69
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000007789 gas Substances 0.000 claims abstract description 24
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000001301 oxygen Substances 0.000 claims abstract description 21
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 21
- 230000035484 reaction time Effects 0.000 claims abstract description 16
- 229910052786 argon Inorganic materials 0.000 claims abstract description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 8
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims description 23
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 7
- 239000006200 vaporizer Substances 0.000 claims description 2
- NMJKIRUDPFBRHW-UHFFFAOYSA-N titanium Chemical compound [Ti].[Ti] NMJKIRUDPFBRHW-UHFFFAOYSA-N 0.000 claims 2
- 239000003086 colorant Substances 0.000 abstract description 2
- 238000004040 coloring Methods 0.000 abstract 2
- -1 acryl Chemical group 0.000 abstract 1
- 238000001704 evaporation Methods 0.000 abstract 1
- 238000002844 melting Methods 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- 230000000704 physical effect Effects 0.000 abstract 1
- 238000001771 vacuum deposition Methods 0.000 description 8
- 239000010408 film Substances 0.000 description 7
- 238000005452 bending Methods 0.000 description 5
- 239000012495 reaction gas Substances 0.000 description 5
- 238000007740 vapor deposition Methods 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 238000007747 plating Methods 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 229920003002 synthetic resin Polymers 0.000 description 3
- 239000000057 synthetic resin Substances 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 230000003763 resistance to breakage Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/0021—Reactive sputtering or evaporation
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K87/00—Fishing rods
- A01K87/008—Fishing rods with attached auxiliary devices, e.g. for keeping the rod afloat or for line cutting
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/14—Metallic material, boron or silicon
- C23C14/16—Metallic material, boron or silicon on metallic substrates or on substrates of boron or silicon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/24—Vacuum evaporation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental Sciences (AREA)
- Marine Sciences & Fisheries (AREA)
- Animal Husbandry (AREA)
- Biodiversity & Conservation Biology (AREA)
- Physical Vapour Deposition (AREA)
Abstract
Description
본 발명은 낚시대, 낚시찌, 낚시찌톱 중 어느 하나인 피 코팅물의 표면에 내구성이 높고 부러짐에 대한 저항성, 균형성(굴곡계수, 굴곡강도)을 향상시킴은 물론, 진공증착기내에 반응가스를 주입하고 코팅시간을 선택적으로 조절하여 특정한 색상을 갖도록 코팅하는 방법 및 그 방법으로 코팅된 낚시대에 관한 것이다.The present invention improves the durability and balance (bending coefficient, flexural strength) and resistance to breakage on the surface of the coated material, which is one of fishing rods, bobbers and bobbers, as well as injecting and coating reaction gas into the vacuum deposition machine. The present invention relates to a method of coating a specific color by selectively adjusting the time, and a fishing rod coated with the method.
종래의 합성수지 등으로 제작된 낚싯대의 표면으로 다양한 색상이나 무늬 등을 표현하기 위해서는 여러 종류의 금속을 증착 도금한 후 실크 인쇄에 의한 인쇄층을 형성한 후 신나 등을 약품을 사용해 일정 부분을 닦아 냄으로서 완성된 무늬를 표현하고 투명한 마감재를 이용해 도장하는 방법(등록번호 10-1992-0002767)등이 사용되었으나 이러한 방법은 낚싯대의 사용함에 따라 도금된 금속 층이 도장재 내면에서 분리되어 보이게 흉하게 되는 문제점이 있었다.To express various colors and patterns on the surface of a fishing rod made of conventional synthetic resin, etc., various types of metals are deposited and plated, and then a printing layer is formed by silk printing, and then a thinner is cleaned using a chemical such as thinner. As a method of expressing the finished pattern and painting using a transparent finishing material (Registration No. 10-1992-0002767), etc. have been used, but this method has a problem that the plated metal layer is separated from the inner surface of the coating material and becomes unsightly by the use of a fishing rod. there was.
진공 증착에 의한 도금 방법은 플라스틱이나 천, 종이, 유리 목재 등에도 도금이 가능하며 가공비가 저렴하고 공해가 없으며 연마를 필요치 않을 만큼 균일한 반사율의 높은 막을 형성할 수 있음으로 많이 사용되고 있다.Plating method by vacuum deposition is widely used because it can be plated on plastic, cloth, paper, glass, wood, etc., and the processing cost is low, there is no pollution, and it is possible to form a film with high uniform reflectivity so that polishing is not necessary.
진공 증착 방법에 따라 형성된 도금 층은 타 도금 방법에 비해 내마모성 및 내식성이 떨어지는 단점이 있다. 그러나 종래의 낚싯대에 표면에 행하던 증착 도금 방법은 비교적 표면이 매끄러운 합성수지재로 제조된 낚싯대 표면으로 직접 금속증착을 행함으로서 쉽게 분리되어 표현된 무늬나 색상을 오래도록 지속하기가 어려웠다.The plating layer formed by the vacuum deposition method has a disadvantage in that wear resistance and corrosion resistance are inferior to other plating methods. However, the deposition plating method used on the surface of a conventional fishing rod has been difficult to maintain a pattern or color that is easily separated and expressed by performing metal deposition directly on a fishing rod surface made of a synthetic resin material having a relatively smooth surface.
본 발명의 낚시대는 내구성이 높고 부러짐에 대한 저항성, 균형성을 향상시키고, 입질 및 라인 플레이(line play; 낚시에 걸린 물고기를 지치게 하는 동작)에 대한 민감성을 제공함은 물론, 우발적인 하중에 항복하고, 그 우발적인 하중이 제거되었을 때 원래의 형상으로 복원되는 복원력을 갖도록 하는 낚시대의 티타늄 코팅방법 및 티타늄이 코팅된 낚시대를 제공함에 그 목적이 있다.The fishing rod of the present invention is durable and improves resistance to breakage, balance, provides sensitivity to mouth play and line play, and surrenders to accidental loads. It is an object of the present invention to provide a titanium coating method for fishing rods and a titanium-coated fishing rod to have a restoring force restored to its original shape when the accidental load is removed.
상기 목적을 달성하기 위한 본 발명의 낚시대 티타늄 코팅방법 구성은, 진공증착기내에 낚시대, 낚시찌, 낚시찌톱 중 어느 하나인 피 코팅물과 티타늄전극을 구비시키는 단계; 상기 피 코팅물과 티타늄전극이 구비된 진공증착기 내부를 진공도 10-4∼10-7Torr가 될 때까지 진공화시키는 단계; 상기 10-4∼10-7Torr로 진공화 된 진공증착기에 피 코팅물의 코팅색상을 조절하기 위하여 산소, 아르곤, 질소 중 어느 하나 또는 2가지가 혼합된 가스를 공급함과 동시에 상기 티타늄전극에 고압의 전압을 인가하여 상기 가스를 이온화시키면서 티타늄이 용융 증발되게 하여 그 이온화된 가스와 용융 증발된 티타늄이 10∼35분 동안 반응하며 피 코팅물의 표면에 코팅되게 하는 단계;로 이루어진다.The fishing rod titanium coating method configuration of the present invention for achieving the above object comprises the steps of: providing a coating material and any one of the fishing rod, bobber, fishing bobbin and titanium electrode in the vacuum evaporator; Evacuating the inside of the vacuum evaporator provided with the coating material and the titanium electrode until the vacuum degree is 10 -4 to 10 -7 Torr; In order to control the coating color of the coating material to the vacuum evaporator vacuumized to 10 -4 to 10 -7 Torr, one or two of oxygen, argon, and nitrogen are mixed and a high pressure is supplied to the titanium electrode. Applying a voltage to ionize the gas and causing the titanium to melt evaporate so that the ionized gas and the melt evaporated titanium react for 10 to 35 minutes and are coated on the surface of the coating.
그리고, 상기 피 코팅물은 표면에 아크릴 또는 우레탄 중 어느 하나가 코팅된 것이다.And, the coating material is one of acrylic or urethane coated on the surface.
상기 피 코팅물의 코팅색상을 진주 색으로 하기 위하여 진공증착기에 산소를 280∼800sccm 범위로 공급하고, 상기 이온화된 가스와 용융 증발된 티타늄의 반응시간을 15∼35분으로 한다.In order to make the coating color of the coating material pearly, oxygen is supplied to the vacuum vapor deposition machine in the range of 280 to 800 sccm, and the reaction time of the ionized gas and the molten evaporated titanium is set to 15 to 35 minutes.
상기 피 코팅물의 코팅색상을 투명무지개 색으로 하기 위하여 진공증착기에 아르곤 250∼700sccm과 산소 280∼800sccm 범위로 공급하고, 상기 이온화된 가스와 용융 증발된 티타늄의 반응시간은 12∼18분으로 한다.In order to change the coating color of the coating material into a transparent rainbow color, a vacuum evaporator was supplied in a range of 250 to 700 sccm of argon and 280 to 800 sccm of oxygen, and the reaction time of the ionized gas and molten evaporated titanium was 12 to 18 minutes.
상기 피 코팅물의 코팅색상을 진주 색으로 하기 위하여 진공증착기에 아르곤 250∼700sccm과 산소 280∼800sccm 범위로 공급하고, 상기 이온화된 가스와 용융 증발된 티타늄의 반응시간은 20∼35분으로 한다.In order to change the coating color of the coating material into pearl color, a vacuum evaporator was supplied in the range of 250 to 700 sccm of argon and 280 to 800 sccm of oxygen, and the reaction time of the ionized gas and molten evaporated titanium was 20 to 35 minutes.
한편 본 발명에 따른 낚시대는, 통상의 낚시대, 낚시찌, 낚시찌톱 중 어느 하나인 피 코팅물의 표면에 티타늄이 투명무지개 색으로 코팅된 것;On the other hand, the fishing rod according to the present invention, the coating of any one of the usual fishing rod, fishing bobber, fishing bobber, titanium coated with a transparent rainbow color;
낚시대, 낚시찌, 낚시찌톱 중 어느 하나인 피 코팅물의 표면에 티타늄이 진주 색으로 코팅된 것;Pearlescent coating of titanium on the surface of the coating to be any of fishing rods, bobbers and bobbins;
아크릴 또는 우레탄 중 어느 하나가 코팅된 통상의 낚시대, 낚시찌, 낚시찌톱 중 어느 하나인 피 코팅물의 표면에 티타늄이 투명무지개 색으로 코팅된 것;Titanium is coated in transparent rainbow color on the surface of the coating to be any one of a common fishing rod, bobber and bobber top coated with either acrylic or urethane;
아크릴 또는 우레탄 중 어느 하나가 코팅된 통상의 낚시대, 낚시찌, 낚시찌톱 중 어느 하나인 피 코팅물의 표면에 티타늄이 진주 색으로 코팅된 것이다.Titanium is pearl-coated on the surface of the coated object, which is one of conventional fishing rods, bobbers and bobbins coated with either acrylic or urethane.
상기와 같은 특징을 갖는 본 발명에 따른 낚시대의 티타늄 코팅방법을 더욱 상세하게 설명하면 다음과 같다.Referring to the titanium coating method of the fishing rod according to the present invention having the characteristics as described above in more detail.
상기 진공증착법은 통상의 활성화 반응성 진공증착법으로서 진공증착에서 증발금속입자와 반응가스의 반응확률을 향상시키기 위하여 반응가스를 이온화시킴으로서, 화학물의 증착이 이루어지게 하는 것으로, 본 발명에서 사용되는 진공증착기(챔버)는 막대형 티타늄 타겟에 편향된 전자빔을 충돌시킴으로서 상기 타겟이 용융되며 증발되도록 한다.The vacuum deposition method is a conventional activated reactive vacuum deposition method to ionize the reaction gas in order to improve the reaction probability of the evaporated metal particles and the reaction gas in the vacuum deposition, the vapor deposition of the chemical is made, the vacuum vapor deposition apparatus used in the present invention ( Chamber) impinges the electron beam deflected on the rod-shaped titanium target, causing the target to melt and evaporate.
이때 상기 진공증착기내에 반응가스를 주입하면 전압이 인가된 방전프로브에 의해 반응가스가 이온화하여 글로우 방전(glow discharge)이 발생하고 이것에 의해 반응된 화합물이 피 코팅물에 증착하는 방식이다.At this time, when the reaction gas is injected into the vacuum evaporator, the reaction gas is ionized by the discharge probe to which the voltage is applied, thereby generating a glow discharge, and the reacted compound is deposited on the coating.
이와 같은 방식의 진공증착법은 내식성과 내열성 및 내마모성 등의 특성을 가지는 박막형성을 가능하게 하고 순수금속 막은 물론, 산화 막이나 질화 막 및 탄화 막 등으로도 자유롭게 코팅할 수 있다.The vacuum deposition method in this manner enables the formation of a thin film having characteristics such as corrosion resistance, heat resistance, and abrasion resistance, and can be freely coated with an oxide film, a nitride film, a carbonized film, etc. as well as a pure metal film.
이상의 방법은 금속, 기계분야는 물론 전 산업분야에서 널리 사용되고 있는 것으로서 그 일 예로 안경테에 티타늄을 코팅하여 사용하는 기술이 있다. 그러나 상기의 기술은 단순히 목적물의 표면에 견고성을 부여하기 위하여 티타늄을 코팅하는 것에 불과할 뿐 색상을 부여하지는 못하였다.The above method is widely used in the field of metals, machinery as well as all industries. For example, there is a technique of coating titanium on an eyeglass frame. However, the above technique is merely coating the titanium to give a firmness to the surface of the object, it did not give a color.
본 발명은 상기 타타늄 코팅이 가지는 견고성은 물론, 컬러(색상)화를 부여하고자 하는 것으로서 그의 코팅 방법을 각 단계별로 나누어 상세하게 설명하면 다음과 같다.The present invention is intended to give the color (color) of course as well as the rigidity of the titanium coating is described in detail by dividing its coating method in each step.
(제1단계)(Step 1)
본 발명에 따른 제1단계는 자전 및 공전이 가능한 진공증착기내에 낚시대, 낚시찌, 낚시찌톱 중 어느 하나인 피 코팅물과 티타늄전극을 구비시키는 단계로서 이는 상기에서 설명한 바와 같이 피 코팅물에 목적성분을 진공증착 할 때에 통상적으로 하는 방법으로서 더 이상의 구체적인 설명은 생략한다.The first step according to the present invention is to provide a coating material and a titanium electrode, which is any one of a fishing rod, a bobber, a fishing saw, and a titanium electrode in a vacuum evaporator capable of rotating and rotating. As a conventional method for vacuum deposition, further detailed descriptions are omitted.
(제2단계)(Step 2)
본 발명에 따른 제2단계는 진공증착기 내부의 진공도를 유지하는 단계로서, 이는 상기 피 코팅물과 티타늄전극이 구비된 진공증착기 내부에 아르곤가스를 주입하고 배기시키는 방식으로 진공도 10-4∼10-7Torr가 될 때까지 진공화시킨다.A second step according to the present invention is a step of maintaining a degree of vacuum within the vacuum evaporator, which is the to-be-coating and the titanium electrode in a manner that the degree of vacuum injection, and exhausting the argon gas into the vacuum evaporator comprising 10-4 to 10- Vacuum until 7 Torr.
이때 진공증착기 내부의 진공도가 상기 10-4Torr보다 낮으면 코팅 막과 피 코팅물 사이의 흡착력이 약해서 코팅 막이 박리 될 우려가 있고, 반대로 진공증착기 내부의 진공도가 상기 10-7Torr보다 높으면 이는 필요이상임으로 진공증착기내부를 진공화시키는데 소요되는 시간이 길어져 코팅시간이 지연되는 문제점이 발생한다. 따라서, 진공증착기 내부의 진공도는 10-4∼10-7Torr가 바람직하다.At this time, there is a fear that the degree of vacuum within the vacuum evaporator is a weak attractive force between the coating film is peeled off of 10 -4 Torr, if the coating film is lower than the blood and the coating, which is opposed to the degree of vacuum within the vacuum evaporator is higher than the required 10 -7 Torr As a result, the time required for evacuating the inside of the vacuum evaporator becomes long, resulting in a delay in coating time. Therefore, the vacuum degree inside the vacuum evaporator is preferably 10 -4 to 10 -7 Torr.
(제3단계)(Step 3)
본 발명에 따른 제3단계는 상기 10-4∼10-7Torr로 진공화 된 진공증착기의 티타늄전극에 고압의 전압을 인가하여 티타늄이 용융 증발되게 함과 동시에 피 코팅물의 컬러화를 위하여 산소, 아르곤, 질소 중 어느 하나 또는 2가지가 혼합된 혼합가스를 공급하여 이온화시키면서 그 이온화된 가스와 용융 증발된 티타늄이 10∼35분 동안 반응하며 피 코팅물의 표면에 코팅되게 하는 단계이다.In the third step according to the present invention, by applying a high voltage to the titanium electrode of the vacuum vaporizer vacuumed to 10 -4 to 10 -7 Torr, titanium is melted and evaporated and oxygen, argon is used to color the coating. In addition, the ionized gas and molten evaporated titanium react with each other for 10 to 35 minutes while being ionized by supplying a mixed gas in which one or two of nitrogen are mixed and coated on the surface of the coating target.
상기 제3단계의 코팅방법에서 피 코팅물에 코팅되는 티타늄의 색상을 진주 색으로 하기 위해서는 진공증착기에 산소를 280∼800sccm 범위로 공급하고, 상기 이온화된 가스와 용융 증발된 티타늄의 반응시간을 15∼35분 동안 한다.In order to make the color of titanium coated on the coating material in the third step of the coating method to be pearl color, oxygen is supplied to the vacuum vapor deposition machine in the range of 280 to 800 sccm, and the reaction time between the ionized gas and the molten evaporated titanium is 15. Do it for 35 minutes.
상기 피 코팅물에 티타늄 코팅을 함에 있어 소정의 산소 공급과 반응시간을 확보해 주는 이유는, 티타늄 코팅을 컬러화 하는데 필요하기 때문이며 특히 진주 색의 티타늄코팅을 하기 위해서는 산소공급량을 280∼800sccm 범위로 하고 반응시간을 15∼35분으로 해야한다.The reason for securing a predetermined oxygen supply and reaction time in applying the titanium coating to the coating is because it is necessary to color the titanium coating, and in particular, in order to perform pearl-colored titanium coating, the oxygen supply is in the range of 280 to 800 sccm. The reaction time should be 15 to 35 minutes.
상기 산소공급량을 280∼800sccm 범위로 하고 반응시간을 15∼35분으로 하는 이유는, 그 이하를 유지하거나 그 이상을 유지하게 되면 티타늄 코팅의 색상이 진주 색을 유지하지 못함은 물론, 코팅의 두께가 목적하는 두께를 유지하지 못하기 때문이다.The reason why the oxygen supply amount is in the range of 280 to 800 sccm and the reaction time is 15 to 35 minutes is that if the amount is kept below or above, the color of the titanium coating does not maintain the pearl color, as well as the thickness of the coating. This is because it does not maintain the desired thickness.
그리고, 상기 피 코팅물의 코팅색상을 투명무지개 색으로 하기 위해서는 진공증착기에 아르곤 250∼700sccm과 산소 280∼800sccm 범위로 공급하고, 상기 이온화된 가스와 용융 증발된 티타늄의 반응시간을 12∼18분 동안 한다. 상기 아르곤을250∼700sccm 공급하는 이유는, 진공증착기의 진공도를 목적하는 정도로 조절하기 위함이다.In addition, in order to make the coating color of the coating material into a transparent rainbow color, a vacuum evaporator was supplied in a range of 250 to 700 sccm of argon and 280 to 800 sccm of oxygen, and the reaction time of the ionized gas and molten evaporated titanium was 12 to 18 minutes. do. The reason for supplying the argon 250 to 700 sccm is to adjust the degree of vacuum of the vacuum evaporator to the desired degree.
또, 상기 산소공급량을 280∼800sccm 범위로 하고 반응시간을 12∼18분으로 하는 이유는, 전술한 바와 같이 그 이하를 유지하거나 그 이상을 유지하게 되면 티타늄 코팅의 색상이 투명무지개 색을 유지하지 못함은 물론, 코팅의 두께가 목적하는 두께를 유지하지 못하기 때문이다.The reason why the oxygen supply amount is in the range of 280 to 800 sccm and the reaction time is 12 to 18 minutes is as described above. If the amount is kept below or above, the color of the titanium coating does not maintain the transparent rainbow color. Of course, because the thickness of the coating does not maintain the desired thickness.
또한, 피 코팅물의 코팅색상을 진주 색으로 하기 위하여 진공증착기에 아르곤 250∼700sccm과 산소 280∼800sccm 범위로 공급하고, 상기 이온화된 가스와 용융 증발된 티타늄의 반응시간을 20∼35분 동안 하는데, 아르곤을 250∼700sccm 공급하는 이유는, 상기와 마찬가지로 진공증착기의 진공도를 목적하는 정도로 조절하기 위함이다.In addition, in order to make the coating color of the coating to be pearl color, a vacuum evaporator is supplied in the range of 250 to 700 sccm of argon and 280 to 800 sccm of oxygen, and the reaction time of the ionized gas and the molten evaporated titanium is 20 to 35 minutes. The reason for supplying 250-700 sccm of argon is to adjust the vacuum degree of a vacuum evaporator to the desired degree similarly to the above.
또, 상기 산소공급량을 280∼800sccm 범위로 하고 반응시간을 20∼35으로 하는 이유는, 전술한 바와 같이 그 이하를 유지하거나 그 이상을 유지하게 되면 티타늄 코팅의 색상이 진주 색을 유지하지 못함은 물론, 코팅의 두께가 목적하는 두께를 유지하지 못하기 때문이다.In addition, the oxygen supply is in the range of 280 to 800 sccm and the reaction time is 20 to 35. The reason why the color of the titanium coating does not maintain the pearl color is maintained when it is kept below or above. Of course, the thickness of the coating does not maintain the desired thickness.
단 상기 피 코팅물의 티타늄코팅에서 진공증착기의 온도는 공히 상온을 유지하면 되고, 또, 피 코팅물은 그 재질이 합성수지이거나 탄소봉 또는 스테인레스 중 어느 하나이며, 그들의 표면에 아크릴 또는 우레탄 중 어느 하나가 코팅된 것에 티타늄을 코팅해도 된다.However, in the titanium coating of the coating object, the temperature of the vacuum vapor deposition machine may be maintained at room temperature, and the coating material may be made of synthetic resin, carbon rod, or stainless steel, and either of acrylic or urethane may be coated on their surface. You may coat titanium with the old one.
이상에서 설명한 것 외에도 피 코팅물의 티타늄코팅 색상은 금색 또는 은색으로 조절할 수 있는데, 그 코팅을 하기 위한 가스공급 및 코팅시간 등은 하기 표 1에 나타내었다.In addition to the above-described titanium coating color of the coating can be adjusted to gold or silver, the gas supply and coating time for the coating is shown in Table 1 below.
이하 표1에서는 피 코팅물에 티타늄코팅을 하면서 각 색상을 연출할 때에 선택되는 사용가스, 진공도, 진공증착기 온도, 코팅시간 등을 나타낸다.Table 1 below shows the gas used, the degree of vacuum, the temperature of the vacuum evaporator, the coating time, etc., which are selected to produce each color while coating the coating.
하기 표2에서는 소재별 피 코팅물에 티타늄코팅을 실시하기 전/후의 굴곡시험을 한 결과를 나타내었다.Table 2 below shows the results of the bending test before and after performing titanium coating on the coating material for each material.
하기 표3에서는 소재별 피 코팅물에 티타늄코팅을 실시하기 전/후의 굴곡시험을 한 결과를 그래프로 나타내었다.Table 3 shows the results of the bending test before and after performing the titanium coating on the coating material for each material.
하기 표4에서는 낚시대의 각 실린더 크기에 따라 티타늄코팅을 실시하기 전/후의 굴곡시험을 한 결과를 나타내었다.Table 4 shows the results of the bending test before and after the titanium coating according to the size of each cylinder of the fishing rod.
하기 표5에서는 낚시대의 각 실린더 크기에 따라 티타늄코팅을 실시하기 전/후의 굴곡시험을 한 결과를 그래프로 나타내었다.Table 5 shows the results of the bending test before and after performing the titanium coating according to the size of each cylinder of the fishing rod.
상술한 바와 같은 본 발명은 낚시대, 낚시찌, 낚시찌톱 중 어느 하나인 피 코팅물에 티타늄을 코팅함으로서, 내식성, 내마모성, 저항성, 균형성 굴곡강도 등을 향상시키고, 또, 코팅된 피 코팅물의 표면을 컬러화시킴으로서 외관의 미감을 향상시키는 등의 효과가 있다.The present invention as described above, by coating titanium on the coating material of any one of the fishing rod, bobber, fishing bobbin, to improve the corrosion resistance, abrasion resistance, resistance, balance flexural strength, and also to improve the surface of the coated coating By colorizing, there is an effect of improving the aesthetic appearance.
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